Professional Documents
Culture Documents
GHS09 environment
GHS07
42.2.13
Page 2/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 18.05.2016 Version number 1 Revision: 18.05.2016
(Contd. of page 1)
1,2-Benzisothiazolin-3-one solution
- Hazard statements
H332 Harmful if inhaled.
H317 May cause an allergic skin reaction.
H351 Suspected of causing cancer.
H335 May cause respiratory irritation.
H410 Very toxic to aquatic life with long lasting effects.
- Precautionary statements
P102 Keep out of reach of children.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P391 Collect spillage.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
- Additional information:
EUH401 To avoid risks to human health and the environment, comply with the instructions for use.
In case of unconsciousness bring patient into stable side position for transport.
(Contd. on page 3)
GB
42.2.13
Page 3/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 18.05.2016 Version number 1 Revision: 18.05.2016
(Contd. of page 2)
- After skin contact
Rinse opened eye for several minutes under running water. Then consult doctor.
42.2.13
Page 4/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 18.05.2016 Version number 1 Revision: 18.05.2016
(Contd. of page 3)
Open and handle container with care.
- Information about protection against explosions and fires: Keep breathing equipment ready.
- 7.2 Conditions for safe storage, including any incompatibilities
- Storage
- Requirements to be met by storerooms and containers: Store in cool location.
- Information about storage in one common storage facility: Store away from foodstuffs.
- Further information about storage conditions: Keep container tightly sealed.
42.2.13
Page 5/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 18.05.2016 Version number 1 Revision: 18.05.2016
(Contd. of page 4)
- Odour: Characteristic
- Change in condition
Melting point/Melting range: Not applicable
Boiling point/Boiling range: Not applicable
- Flash point: no flash point up to 110.0 C
- Ignition temperature:
Decomposition temperature: not determined.
- Danger of explosion: Product is not explosive.
- Density at 20 C 1.127 g/cm
- Evaporation rate not determined.
- Solubility in / Miscibility with
Water: Fully miscible
- Partition coefficient (n-octanol/water): Kow logP = 2.86 at 23 C
- Viscosity:
dynamic: Not determined.
kinematic: Not determined.
- Solvent content:
Organic solvents: 4.0 %
Water: 60.0 %
42.2.13
Page 6/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 18.05.2016 Version number 1 Revision: 18.05.2016
(Contd. of page 5)
131860-33-8 azoxystrobin
Oral LD50 > 5000 mg/kg (rat)
Dermal LD50 > 2000 mg/kg (rat)
Inhalative LC50 0.7 mg/l air (rat)
- NOAEL ( no observable adverse effect level )
1897-45-6 chlorothalonil (ISO)
Oral NOAEL (2y) 2.7 mg/kg bw/d (rat)
Effects: kidney and (fore)stomach (pre-neoplastic and neoplastic lesions);
fore-stomach tumours in rats and mice, kidney tumours in rats.
NOAEL 1.5 mg/kg bw/day (rat)
90 days
Dermal NOAEL < 60 mg/kg bw/day (rat)
28 days
131860-33-8 azoxystrobin
Oral NOAEL (2y) 18 mg/kg bw/d (rat)
37 mg/kg bw/d (mouse)
NOAEL 90-day 21 mg/kg bw/day (rat)
1-year 25 mg/kg bw/day (dogs)
Dermal NOAEL 21 day 1000 mg/kg bw/day (rat)
- ADI (acceptable daily intake)
1897-45-6 chlorothalonil (ISO)
ADI 0.015 mg/kg/bw ( man ) (--)
- Primary irritant effect:
- Skin corrosion/irritation Based on available data, the classification criteria are not met.
- Serious eye damage/irritation Based on available data, the classification criteria are not met.
- Respiratory or skin sensitisation
May cause an allergic skin reaction.
- CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
- Germ cell mutagenicity Based on available data, the classification criteria are not met.
- Carcinogenicity
Suspected of causing cancer.
- Reproductive toxicity Based on available data, the classification criteria are not met.
- STOT-single exposure
May cause respiratory irritation.
- STOT-repeated exposure Based on available data, the classification criteria are not met.
- Aspiration hazard Based on available data, the classification criteria are not met.
42.2.13
Page 7/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 18.05.2016 Version number 1 Revision: 18.05.2016
(Contd. of page 6)
1897-45-6 chlorothalonil (ISO)
NOEC 0.29 mg/l (Lemna gibba)
FISH: LC50 (96h) 0.052 mg/l (Lepomis macrochirus)
0.038 mg/l (O. mykiss)
DAPHNIA: EC50 (24h) 0.0085 mg/l (Daphnia magna)
131860-33-8 azoxystrobin
NOEC (33-day) 0.147 mg/l (Phimephales Promelas)
FISH: LC50 (24h) 0.47 mg/l (O. mykiss)
EC50 0.23 mg/l (Daphnia magna)
ErC50 (72h) 0.146 mg/l (algae Navicula pelliculosa)
ErC50 (14d) 3.2 mg/l (Lemna gibba)
- 12.2 Persistence and degradability
- Environmental toxicity
1897-45-6 chlorothalonil (ISO)
LC50 (14d) 268.5 mg a.s./kg soil (Earthworm)
oral LD50 > 40 g/bee (bees)
contact LD50 > 63 g/bee (bees)
LD50 > 2000 mg/kg bw (birds)
131860-33-8 azoxystrobin
LC50 283 mg a.s./kg soil (Earthworm)
oral LD50 >25 g/bee (bees)
contact LD50 >200 g/bee (bees)
LD50 >2000 mg/kg (bobwhite quail)
- 12.4 Mobility in soil
131860-33-8 azoxystrobin
koc 423 ml/g (--)
Low mobility
- Behaviour in environmental systems:
- Ecotoxical effects:
- Remark: Very toxic for fish
- DT 50 ( active ingredient )
1897-45-6 chlorothalonil (ISO)
DT50 15.7 days (soil)
Not persistent in soil
< 1 days (water)
Not persistent in water
131860-33-8 azoxystrobin
DT50 84.5 days (soil)
Moderate persistence
205 days (water)
Stable in water
- Additional ecological information:
- General notes:
Water danger class 3 (German Regulation) (Self-assessment): extremely hazardous for water.
(Contd. on page 8)
GB
42.2.13
Page 8/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 18.05.2016 Version number 1 Revision: 18.05.2016
(Contd. of page 7)
Do not allow product to reach ground water, water bodies or sewage system, even in small quantities.
Danger to drinking water if even extremely small quantities leak into soil.
Also poisonous for fish and plankton in water bodies.
Very toxic for aquatic organisms
42.2.13
Page 9/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 18.05.2016 Version number 1 Revision: 18.05.2016
(Contd. of page 8)
42.2.13
Page 10/10
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 18.05.2016 Version number 1 Revision: 18.05.2016
(Contd. of page 9)
Skin Corr. 1B: Skin corrosion/irritation Category 1B
Eye Dam. 1: Serious eye damage/eye irritation Category 1
Skin Sens. 1: Skin sensitisation Category 1
Carc. 2: Carcinogenicity Category 2
STOT SE 3: Specific target organ toxicity (single exposure) Category 3
Aquatic Acute 1: Hazardous to the aquatic environment - acute aquatic hazard Category 1
Aquatic Chronic 1: Hazardous to the aquatic environment - long-term aquatic hazard Category 1
- Sources This MSDS has been prepared based on data provided by EC Regulation 1107/2009
- * Data compared to the previous version altered.
GB
42.2.13