Professional Documents
Culture Documents
PHYSICS
Sol.1. (C) ray will be still totally internally reflected at interface.
1
n2
As n2 decreases , i C
sin also decreases, so condition i iC is still satisfied and there
n1
will be still total internal reflection at interface. If angle of incidence is increased then ray will be
still totally internally reflected at interface because i iC .
Sol.2. (B) 2eV
KEmax h max 3 1 2eV
Sol.3. (C) 100 cm
A B C D
F F
30 20 30 10
10
AD=30+10+20+30+10=100cm
Sol.4. (B) conduction
As atoms in the spoon vibrates about their equilibrium positions and transfer energy from one end
to other end. This process is conduction.
Sol.5. (B) along +y axis dq dE
P
dq
Consider any two symmetric dipole elements, net contribution due to these elements at point P is
along +y axis . Similarly by principle of superposition we can say that net electric field at P is
directed along +y axis.
Sol.6. (D) 8 kR 2
KEi PEi KE f PE f
1 2 1 2
0 k OA R KE f k OB R
2 2
1 2 1 2
k 5 R R KE f k R R
2 2
2
KE f 8kR
Sol.7. (B) 9 J
1 1 (3)(6) 2
U Ceq V 2 3 9J
2 2 (3 6)
Sol.8. (A) experiences a force directed along the radial direction only.
Circular motion is a special case in gravitational field. There may be straight line,elliptical paths,
but force will be always directed toward the centre of the sphere.
Sol.9. (C) speed is maximum at t=4s.
t 3 t 0, 2, 4 t 1
x A x0 x A
v 0 vmax v 0
mg
Sol.10. (A)
k
kx kx F.B.D. of lower rod
kx kx
T2 2mg
kx kx 2mg
mg
x
k
T2 2mg
T1 mg T1 mg
Sol.11. (C) 9
We consider two possible cases:
Case I Case II
nC
5
nB nB
4 4
nA
5 nA
nC
nC nA 4 5 9
nA nC 1
Sol.12. (A) 0.6 m / s
By momentum conservation
(10 103 )1000 (10 103 ) 400 10v
v 0.6m / s
Sol.13. (B) AP AQ
Q
P
N
O
A Q P
For complimentary angles range ON is same for P and Q as points O and N are on same
horizontal plane. From figure AP AQ
Sol.14. (D) 60 Hz
Second overtone n=3 f3 3f0 60Hz
Sol.15. (B) 4m / s 2
2 d2x 2
x slope (t ) 2t 2 4
dt
Sol.16. (C) 1s
In one time constant 63% change occurs in the value of current .The 63% of maximum current is
1.26 A .It is obvious from graph that current 1.26A corresponds to time which is slightly greater
than 0.9sec. Hence option having 1s is most appropriate.
Sol.17. (C) zero
a
b
At the position of smaller loop, Magnetic field due to larger loop is parallel to plane of smaller
loop. Due to larger loop, magnetic flux linked with smaller loop is zero. Hence mutual induction
is zero.
1 Mi2 0 Mi2 M 0
Sol.18. (D) 3 m / s
1 1
Impulse during t=2 to t=4 is 3 2 5 4 3 5 0
2 2
Impulse =change in momentum
mv f mvi 0 v f vi 3 speed 3
Sol.19. (D) 10
8
5 1
aQ i ,aP 5i 8 j arel aP aQ 6i 8 j , arel 10
Sol.20. (A) pressure of 85cm of Hg
Pgas Patm P 76cm of Hg 9cm of Hg 85cm of Hg
Sol.21. (C) work done by gas is negative
PV
Volume does not remain constant throughout the process AB . As T ,temperature
nRT
decreases initially as both P and V decreases .By area under curve ,net work done is negative.
P A
B
V
2 3
Sol.22. (A) 20 kgm s
dKE
Pall F.v ma.v 100 103 20i 10 j .10i 20
dt
Sol.23. (C) It remains stationary
Maximum possible friction force F frictionMax. 0.5 2 g 10 N
Maximum applied force Fapplied Max. 8 1 8 N
F F
applied Max. frictionMax. so the block will remain stationary
Sol.24. (A) 84kPa
V 6 0.004
p B 2100 10 84 kPa
V 100
2
m2 R 2
Sol.25. (D) m1R
3
2 2
AC 2R R2
I I ABC I AOC mi R 2 m2 R 2 mi m2 m1 R 2 m2
12 12 3
Sol.26. (A) dark
Path difference 13.5 13 12 n 12
So there will be minima.
Sol.27. (A) It will be clockwise
As collision is elastic ,so after collision ball moves towards left with speed v .As walls and
ground are smooth ,there is no tangential torque on the ball. Only normal forces and mg force
pass through the centre of the ball ,so their torques about the centre are zero. Torques on the ball
about its centre is zero . By I ,angular acceleration is zero hence angular velocity does not
change.
Sol.28. (A) electron
mv
R v ,q and B are same so Rm
qB
Mass of electron is minimum for given options.
Sol.29. (C) 8 Nm
1
iAB sin 90 o 2 2 2 2 8 Nm
2
2
Sol.30. (A) 84 m
Result should have only two significant numbers (same as 12m).
Sol.31. (C) 27 C 18V
i
6F
6
3F 6
18
i 1 .5 A and V2 R2i 6 1.5 9V ; q2 3 9 27C
66
x
Sol.32. (B)
0 t
Initially velocity is constant ,so slope of x-t graph is constant and finite .Finally velocity becomes
zero hence slope of x-t graph becomes zero.
Sol.33(C) 20m 3
mg airVg 26 g 1.3Vg V 20m 3
Sol.34. (D) 5
3
0V R
Since equivalent internal resistance of equivalent cell across the external resistor R is 2 3 5
,Hence power delivered to R will be maximum if R 5
1
Sol.35. (A)
4
l l RA 1 VA R A I 1
RA 2
,RB 2
2R R RB 4 VB RB I 4
Sol.36. (A) Al
Sol.37. (A) 7 kgm2s1
L 2 2 2 sin 90o 3 3 3 sin 0o 1 1 1sin 90o 8 1 7
2V 2
Sol.38. (A)
3R
2 2
V V V 2 2V 2
P
Req R R 3R 3R
2 2
Sol.39. (C) A 0, B 1, C 0
A0 1 F 1
B 1
C 0 1
100
A r
kpcos p kpcos 0
r2 r2
k p cos k p
VA 2
r2 r
Sol.47. (C)
b a
2 2
R
B1 .A1 B2 .A 2 Bb 2 cos 0o Ba 2 cos 180o B b 2 a 2 b 2 a 2 t
d
dt b a
2 2
i
R R R
F
Sol.48. (C)
MR
F sin 30O
O
F cos 30O 30
120O
C
MR 2 F
I F sin 300 R
2 MR
Sol.49. (C) acceleration may be zero at t=2
Let us consider an example in which particle is projected vertically upward from ground at t=0
and it reaches highest point at t=2.
Then at that instant(t=2) velocity v=0 but acceleration=g. Here displacement is non zero for the
duration t=0 to t=2. For t>2 the ball again acquires velocity. In this example options(A),(B) and
(D) are incorrect.
Let us consider another example in which a particle is moving on horizontal plane and it comes to
rest permanently at t=1 ,then this is the one of the special case in which acceleration of particle is
zero at t=2.
Sol.50. (C) 4i 2j m / s
v 1 v 0
e separation y vy 2
vapproach y 2 40
SnCl62 4 6(7) 2 48
6 set of electrons octahedral
Sol.53. (B) H2S < NH3 < H2O < HF
Sol.54. (D) BF3
BF3 can form bond also in addition to bond. As F is more electronegative and octate in B
is not complete.
Sol.55. (D) H2O
H2O will act as Brnsted acid as provided H+ ion.
Sol.56. (B) 0.354 gm
pOH pK b log
NH 4Cl pOH log K log NH 4Cl pOH log NH 4Cl
b
NH 3 NH 3 NH 3 Kb
14 9.45 log
NH 4Cl log 3 0.47
NH 3 Kb
log1014 (log109 log3) log
NH 4Cl log
1014
log
NH4Cl 1014 NH 4Cl
NH3 Kb 109 3 NH3 Kb 109 3 NH 3 Kb
1014 1014
9 3 b 4
NH K NH Cl 9
0.011.85 105 NH 4Cl 0.35
10 3 10 3
2 Kp
Sol.57. (D)
1 2 K p
2 HI ( g ) H 2 ( g ) I 2 ( g )
At eq.2(1 x ) x x
Total moles at equilibrium =2-2x+x+x=2 ,here x= degree of dissociation
x x 2
P x2 x 2 Kp
2 2
K p 2 2
2 Kp x
4 1 x P 2 4 1 x 1 x 1 2 K p
4
Sol.58. (C) 171
6g 60
A 6% solution of sucrose C22H22O11 conc.= 0.06ml 1 molel 1
100 ml 342
30
For unknown solution conc.= 3 g per 100cc 30 gl 1 mole l 1
m
60 30 30 342
For isotropic solution m 171
342 m 60
Sol.59. (D) 491 kJ
CH 3COOH 2O2 2CO2 2 H 2O
869 2 395 2 285 f H ( CH 3COOH )
Simplification gives
2 434.5 2 395 2 285 S H (CH 3COOH )
1
or 434.5 395 285 f H 491 f H
2
Sol.60. (B) Sulphur
Sol.61. (A) Cathode is Lead dioxide (PbO2) and anode is Lead (Pb)
Sol.62. (D) ( Ssystem+ S surrounding ) > 0
Sol.63. (A) PVm=RT
At low pressure & high pressure V is very high ,thus a2 and b are negligible, finally reduced
Vm
eq. PVm=RT
Sol.64. (D)
t 3/4
A 0
If t1/2 vs. A0 is constant ,it is radioactive decay hence is not of zero order. Thus answer
will be
t 3/ 4
A 0
Two chiral centre of plane of symmetry so it is meso compound.
Sol.71. (C) 2 ethyl-3 methyl pentanal
OH
Sol.72. (A)
CHCl3 aq. NaOH
In Reimer-Tieman ,phenol reacts with CHCl3 & aq. KOH/NaOH to give Selicil Aldehyde.
Sol.73. (B) B < S < P < F
I.P. in period increases left to right.
I.P. in group up to down decreases.
Sol.74. (B)
20 Carbocation will be more stable than 10
Substituted carbocation will more stable than simple.
Sol.75. (A) Be3N2
Sol.76. (C) Cannizzaro reaction
Sol.77. (C) BN
Sol.78. (C) i > iv > ii > iii
Acidity 1
basicty
Sol.79. (C) (i),(ii)
Br
(i)
H
Br
(ii)
Sol.80. (A) iii < i < iv < ii
Acidic strength electron withdrawing group strength.
1 1 1
R H I
I H R
Sol.81. (A) Only I effect
Due to SIR effect NO2 group goes out of plane of the paper (-I).
Sol.82. (C) AgNO3
Sol.83. (A) 6-ethyl-2-methyl-5-propyldecane
CH3
(4)
H CH2 CH2 CH CH3
(3) (2) (1)
CH2 CH3 H
Sol.84. (B) D-fructose
CHO CHO CH2 OH
OH
OH O
OH OH
OH
OH
base base OH
OH OH OH
OH OH OH
CH2OH CH2 OH CH2OH
D Manose D Glucose D Fructose
O
Sol.85. (B) Benzoquionone
NH Cr O
H SO 4 2
2 4
2 7
Benzoquinone
O
Conjugated diketones
Sol.86. (C) 19 ,
H
H H
H C H
H
H H H
19 and H
Sol.87. (B) (i) and (iii)
As a plane of symmetry exist in compound(ii),there is no chirality in it. Hence (i) &(iii) will be
optically active.
Sol.88. (A) BCl3 and AlCl3 are both Lewis acids and BCl3 is stronger than AlCl3
BCl3 and AlCl3 both are Lewis acids but BCl3 is more electron deficient than AlCl3 so BCl3 s
stronger Lewis acid than AlCl3 due to high electron negativity.(E.N. B-2.0,Al 1.5)
Sol.89. (C) I, II, IV
O
NO2
Group has -M or R effect so it cannot be used in Friedel Craft acylation ,this is deactivating &
metadirecting group in ESR.
O
O
C Cl
H3 C C Cl AlCl
3
NO2
NO2
Sol.90. (A) 4-butyl-1-ethyl-2-methylcycloheptane
Naming according to closest set of locant rule
1
6 7
5 2
4 3
4 6
5
Cl
OH
O 2N
NO2
O 2N
NO 2 OH
OH OH
Highest dipole moment
Sol.94. (A) 4
Grignard reagent will react on CO bond there are four C-O bond .These will be addition of
Grignard reagent at four positions.
HO COOEt
2mol total 4mol
O
1mol
1mol
Sol.95. (A) KO2
KO2 K O2 17 e in valance cellso unpaired electron present &show paramagmetism
SiO2 Si4 2O2 Diamagnetic
2s2 2 p6 2s 2 2 p6
TiO2 Ti4 2O2 Diamagnetic
3d 0 2s 2 2 p6
BaO2 Ba2 2O2 Diamagnetic
XeConfiguration NeConfiguration
Sol.96. (C) CH 3
Nucleophilicity order
CH 3 NH 2 OH F
Sol.97. (D) For lead +2, for tin +4
PbO 2 + Pb 2PbO, G 0 < 0
i.e. G0 is negative so reaction is fisiable i.e. for Pb,+2 Oxidation state is more stable.
SnO 2 + Sn 2SnO, G 0 > 0
i.e. G0 is positive so reaction is nonfisiable i.e. for Sn,+4 Oxidation state is more stable.
Correct answer is (D) For lead +2, for tin +4
For lead +2, for tin +4 Oxidation State are more characteristics.
Sol.98. (A) 1-Phenyl-2-butane
(i) Ph CH 2 CH CH CH 3 Geometrical isomerism.
CH 2 CH CH CH3
(ii) Ph No Geometrical isomerism
CH 2 C CH 2 CH3
(iii) Ph
No Geometrical isomerism
Ph
(iv) C CH CH3 No Geometrical isomerism
Ph
Sol.99. (C) associate
At CMC they associate.
Sol.103. (B) A = 1 , B = 1
For continuity of f(x) at x 2 & 2 , we have
lim f (x) 2 lim f (x) A B f 2
x
2
x
2
2
& lim
f (x) 2 lim
f (x) 0 f 2
x
2
x
2
2
A B 2 & A B 0 A 1, B 1
2
Sol.104. (B)
x
lim f (x) f (0)
x 0
for continuity of f(x) at x=0. 2x
a
Sol.105. (D)
ya y 0
lim sin
y a 2 cot 2a is of the form 0 .
ya y a
Using LHospital rule lim sin . tan
y a 2 2a
Sol.106. (C) lim n does not exist but lim Ln exists
n n
0 when n is odd
lim n so lim n does not exist
n 2 when n is even n
lim Ln 0 exists
n
Sol.107. (B) x 0
2
Since cos 11 xx 2 tan x is valid for 0 x ,so negative times shows the answer x 0
1
2
1
Sol.108. (A) ( 1 , 0 ) , ( - 1 ,- 4 )
dy
Slope of tangent to curve at point ( , ) is dx i.e. 3 1 which is parallel to line having slope 4.
2
( , )
So 3 2
which gives 1 .The point ( , ) lies on the curve so
1 4 0, 4 .Points are
(1,0) & (1, 4) .
Sol.109. (C) 25
a b , b c , c a a b . c b a b . b c . c a
2
a b c b . c a a b c 25
Sol.110. (C) 2x - y + 1 = 0
Equation of chord joining the points P(1,4) & (3,8) on the parabola is 2 x y 2 0 . Tangent
dy
parallel to this chord will have the slope i.e. 2 Equation of tangent at ( , ) on the curve with
dx
slope 2 is 2x - y + 1 = 0
3 3
Sol.111. (B) ,
2 4
x
dy d2y
Given y t 2 3t 2 dt . Differentiating w.r.to x, we have x 2 3x 2 & 2 x 3 . At the
0
dx dx2
d2y
point of inflection 0 & second derivative changes sign while passing through the point of inflection.
dx2
3 3
Clearly P , .
2 4
Sol.112. (C) - 2
2 x sin x 0
lim 2 x tan x lim is form.
x cos x x cos x 0
2 2
Use L Hospital Rule, we get result -2.
Sol.113. (D) 2x - y - 1 = 0
The point of intersection of the curve y x 2 with the bisector of the first quadrant i.e. y=x is
(1,1) {Neglect the point (4,0) as it does not satisfy y=x}. Equation of normal to the curve at (1,1)
is 2x y 1 .
Sol.114. (D)
2 1 y2
y5
41
Sol.116. (C) tan 1
2
Equation of curves c1 : y x 2 & c 2 : 9x 2 16y 2 25 .Let m1 & m 2 be the slope of the tangents to these
9 m1 m2 41
curve at the point of intersection (1,1) m 1 2 & m2 ,So 1 tan 1 1 tan 1
16 1 m1m 2 2
9
2
Similarly at the point of intersection (-1,1) tan 1 16 tan 1 41
2
18 2
1
16
Sol.117. (C) 1
dy d2 y
For maxima minima dx
0 2sec 2 x 1 tan x 0 x & 2
4
0
dx x
4
So x
4
is the point where function y 2 tan x tan 2 x has maximum value.
Maximum value yat x 1
4
2 2
Sol.118. (B) (a b ) 4 ab 138
Let M be the middle point of the segment AB. So M a 2 b , 24 . Since OM MA and
Length OM 3 length MA , but MA a b , 13 . So using OM 3 MA .We get
2
2 2
( a b ) 4 ab 138
Sol.119. (A) 3 sin x 4 cos x
Let x 0 So x 0.Hence f ( x ) 3sin( x ) 4 cos( x ) given ,But f is odd, so
f ( x) f ( x ) where x 0 f ( x ) 3sin x 4cos x
Sol.120. (A) continuous at x = 0 but not differentiable at x = 0
Since 2 x x tan x1 2 x ,So lim f (x) 0 f (0) f is continuous, but
1
x 0
f (x) f (0) 1
lim lim tan 1 does not exit, so not differentiable at x=0.
x 0 x 0 x 0 x
Sol.121. (B) 48
According to question 2 &
2
24 . Solving 6, 54 48
2 1
Sol.122. (C) a ,b
3 6
dy dy a
At the point of Maxima or Minima dx
0 i.e. at x 1 & x 2 ,we have 2bx 1 which is 0 at x=1
dx x
2 1 d2 y d2y
&2 . a , b , Clearly 2 0 , so minimum & 2 0 ,so maximum.
3 6 dx at x 1 dx at x 2
1
Sol.123. (C)
4
Let P be a point inside the circle z z 0 r. Probability of the point P which lies within the circle of radius
2
r
r r 4 1
is z z0 is 2
2 2 r 4
1
Sol.124. (A)
3
Required chance 5!
6! 3
1
2!
0
Sol.125. (A) 30
Given L : 3sin A 4cos B 6 & M : 4sinB 3cos A 1 in ABC ,So L M implies sin(A B) 12 2 2
1 0
sin C sin(1800 A B) C 300 or 1500 . Discard C 150 because for this value of C, A will be
2
0 3 0
less than 30 . Hence 3sin A 4cos B 4 6 a contradiction. C 30
2
1 1 a
Sol.126. (B) c a sin x
1 dx 1 dt 1 1 a
Put x
t
so I 2 2
reduces to
a 1 2
.Hence I c
a
sin
x
x x a 2
t
a
d 2 y dy 2
Sol.127. (A) ey sin x
dx 2 dx
dy
Differentiating the given relation w.r.to x, we get ey cos x 0 ,Again d.w.r.to x
dx
2
d2y dy
ey e y sin x 0
dx 2 dx
3
Sol.128. (C)
2
1 6
Given L : sin a sin b & M : cos a cos b
2
,So L M implies
2 2
cos(a b) 0
2
Given dy
dx
dy
tan & tan
3 dx 4
So, f (a) 3 , f (b) 1
x a x b
b b
d b
I e x f x f x dx
a a dx e f x dx e f x
x x
eb f b ea f a eb 3e a
a
Sol.130. (B) a 5 , b 5
1 1 2 : 3
A b 3 5 3 : b
2 6 a : 2
1 1 2:3 1 1 2:3
R 2 3R1 , R 3 2R1 0 8 9 : b 9 R3 R2 0 8 9 :b9
0 8 a 4 : 4 0 0 a 5:5 b
For no solution rankArank A b , So a 5 , b 5
Sol.131. (A) 5 x 2 3x 1 0
1 1 1 1
Required equation x2 x 0
Where 3 & 5 as , are roots of x 2 3x 5 0
5x 2 3x 1 0
h2
Sol.132. (D) 3a h
3
ah
Volume of the solid of revolution V y 2 dx (The figure is bounded by x=a,x=a+h,y=0)
a
ah
h2
x a 2 dx 3a h
2
V
a
3
c
Sol.133. (A) y 2 1 x log 1
1 x
Given diff. Eq. can be written as
dy 1 x dy dt
y
dx 2(x 1)
y 2
2(x 1)
,Let y t 2
so 2y
dx dx
.Hence eq. reduces to
1
dt 1 x 1 x dx 1
dx (x 1)
t
(x 1)
where I.F. e
(x 1)
2 c
Hence solution t.IF. Q.IF.dx c y 1 x log 1
1 x
Sol.134. (D) 10m / sec 2
dx 12 2x
x t 5t 2 7t 3 , v
dt
10t 7 5 10t 7 t
10
; a d 2
10m / s 2
dt 12
t
10
Sol.145. (C) 1 3 n 1
2
Let S n 1 4 13 40 121 364 ....... Tn 1 Tn
Rewrite Sn 1 4 13 40 121 364 ....... Tn 2 Tn 1 Tn
& Sn Sn 1 3 32 33 ....... Tn Tn 1 Tn
3n 1 3n 1
Tn 1. & Tn
3 1 2
Alternative: put options directly.
5
Sol.146. (D) ,
3 3
5
y x 2 sin x has tangent parallel to x axis at the points , and
3 3
dy 5
0 for x 0 , U , 2
dx 3 3
dy 5
0 for x ,
dx 3 3
Sol.147. (D) 9
xC 21/ 3 x 6 31/ 3 6
6 1 x9
6 x 6
xC
x 6 2 3
1/ 3 1/ 3
6
Sol.148. (B) 256
If cardinality of A=m & Cardinality of B is n ,then total no. of relations from A to B is 2mn .
Here m=4,n=2 28 256
Sol.149. (A) 0 0 .00025
Using x 2 ,we get y 4 4 which is less than ,
So 4 2 For 0.001, the 0.00025
Sol.150. (D) f 0
f (x) f (0)
f 0 lim where f (0) 0(given),So L f 0
x 0 x 0