Yumuak poliretan kpk ve bunun iin retim yntemi

WO 2011024413 A1
ZET

Verilen yumuak poliretan kpk, bir ara yast veya koltuk arkal olarak kullanlmak zere
dayankl, dk younluklu yumuak bir poliretan kpk olup, gl mekanik zelliklere
sahiptir. Bahsedilen yumuak poliretan kpn imalat iin bir yntem de salanmaktadr. Verilen
yumuak poliretan kp, bir organik poliizosiyanat (A), bir poliol (B), bir zincir uzatma maddesi (C),
bir katalizr (D) ve bir kpkletirici madde (E) ieren bir sv karmn reaksiyona sokulmas ve
kprtlmesi ile retilir. Salanan yumuak poliretan kpn ekirdek younluu 25 kg / m ile 35 kg
/ m arasndadr. Bahsedilen organik poliizosiyanat (A), ktlece% 70-90 bir difenilmetan diizosiyanat
(A-1) ve% 10-30 orannda bir polimetilen polifenilen poliizosiyanat (A-2) ierir. Ad geen difenilmetan
diizosiyanat (A-1),% 50-100 2,4-difenilmetan diizosiyanat ve 2,2-difenilmetan diizosiyanat ierir.

HAK TALEPLERI (5) u dilden evrildi: Japonca

1. Organic polyisocyanate (A), the polyol (B), the chain extender (C), and a catalyst (D), and
a flexible polyurethane foam which is obtained by reacting foam mixture containing the
foaming agent (E), the soft polyurethane There core density of the foam is in the range of
25 ~ 35kg / m 3, and the organic polyisocyanate (A) is, the organic polyisocyanate (A) with
respect to 100 mass%, 70 to 90% by weight of diphenylmethane diisocyanate (A-1) and, it
is intended to contain a 10-30% by weight of polymethylene polyphenylene polyisocyanate
(A-2), and, (A-1) 2,4-diphenylmethane diisocyanate and 2,2- flexible polyurethane foam
which is characterized by containing a diphenylmethane diisocyanate 50-100%.

2. The diphenylmethane diisocyanate (A-1) is 2,4-diphenylmethane diisocyanate

having a 2,2-diphenylmethane diisocyanate 50 to 90%, and wherein the NCO
content and the chlorine ion concentration of 32% or more is 5ppm or less The
flexible polyurethane foam according to claim 1 to be.

3. Claim wherein the polyol (B) is characterized in that has a nominal average
functionality in the range of 2-4, it is one that is and having a number average
molecular weight in the range from 3000 to 8000 flexible polyurethane foam
according to 1 or 2.

m 3,
4. That the core density is 25 ~ 35kg / wet heat compression set of 25% or less,
100% or more elongation, tear strength 4.5N / cm 2 or more, a range of 25%
compressive stress of 80 ~ 120N The flexible polyurethane foam according to
any one of 3 claims 1, wherein.

5. The method for producing a flexible polyurethane foam according to any one of
claims 1 to 4.

AIKLAMA u dilden evrildi: Japonca

Flexible polyurethane foam and a method of manufacturing the same

The present invention relates to flexible polyurethane foams, more particularly, to a flexible
polyurethane foam which can be suitably used for a seat back and a seat cushion for a vehicle for a
vehicle.

Conventionally, flexible polyurethane foam, since it is excellent in cushioning properties, addition of

such a cushion member such as furniture, are widely used in automobile seats.

Foam physical properties, the production method of the moldability and flexible polyurethane foams
with excellent and surface cure properties, specifically for example, polyhydroxyl compounds, organic
polyisocyanate, catalyst, foam stabilizer, and a blowing agent (water) and additives a method of
reacting with have been proposed, as a flexible polyurethane foam, technique using a toluene
diisocyanate in the isocyanate component are already widely known (Patent Document 1). However,
the freezing point of the toluene diisocyanate is as high as about 17 at normal pressure, heated to
become solidified in the winter, there is a need for temperature control. Also, the production site,
sometimes the health of the worker due to the toluene diisocyanate is a problem.

Therefore, flexible polyurethane foams with low vapor pressure diphenylmethane diisocyanate in
polyisocyanate component has also been proposed (Patent Document 2). However, the freezing point
of the main component is a conventional diphenylmethane diisocyanate 4,4'-diphenylmethane
diisocyanate is further increased compared to about 38 and toluene diisocyanate under normal
pressure, it is necessary to pre-processing such as prepolymerisation, as a result because it is a very
high viscosity, there is a problem of limited due worsening and production facilities conditions of
workability. In addition, all diphenylmethane diisocyanate (2,2'-diphenylmethane diisocyanate
(hereinafter abbreviated as 2,2'-MDI), 2,4- diphenylmethane diisocyanate (hereinafter abbreviated as
2,4-MDI) and 4,4'-diphenylmethane diisocyanate ( hereinafter abbreviated as 4,4'-MDI), if hereinafter
referred to as pure MDI) content of 2,2'-MDI and 2,4-MDI in (hereinafter abbreviated as isomer ratio) is
low as a generic term, the storage stability there is a problem such as that sex is worse.

Therefore, the MDI isocyanate for flexible polyurethane foams, isomer ratio, and the amount of pure
MDI in the total isocyanate (pure MDI and polymeric MDI) (hereinafter abbreviated as di content) me
was used which was modified with a polyol with high organic polyisocyanate what exists (Patent
Document 3). However, by modifying the isocyanate component with a polyol, the viscosity becomes
high, because the NCO content is low, to obtain a flexible polyurethane foam having a like low density
and high elasticity performance was very difficult. Furthermore, it did not have been described for the
chloride ion concentration of the isocyanate composition.

In the invention so far, the use of only the diphenylmethane diisocyanate as the organic
polyisocyanate component low-density products, such as used as a seatback for a vehicle, ie the
molding of soft urethane foam 25-35kg / m3 as the core density is difficult It was. That is, mechanical
properties such as withstand fog ring, was not flexible polyurethane foam which satisfies the durability
as a cushioning material.
Patent Publication No. 2001-172356 Patent Publication No. 2005-194486 WO2008 / 136179 JP

The present invention has been made in view of the problems of the conventional art described above,
and an object thereof is to provide a cushion for a vehicle, a low density as a seatback, robust
mechanical properties, a process for producing a flexible polyurethane foam having a durability.

The present inventors have found, as a result of extensive research to achieve the above object,
comprises an organic polyisocyanate (A), the polyol (B), the chain extender (C), the catalyst (D) and
foaming agent (E) The mixture is reacted foaming found that a flexible polyurethane foam obtained
which can achieve the above object of, and have completed the present invention.

That is, the flexible polyurethane foam and its manufacturing method of the present invention are the
following. (1) Organic polyisocyanate (A), the polyol (B), the chain extender (C), and a catalyst (D),
and a flexible polyurethane foam which is obtained by reacting foam mixture containing the foaming
m 3,
agent (E), The core density of the flexible polyurethane foam is in the range of 25 ~ 35kg / and the
organic polyisocyanate (A) is, with respect to the organic polyisocyanate (A) 100 wt%, 70 to 90 wt% of
diphenylmethane diisocyanate (A-1), 10 to 30% by weight polymethylene polyphenylene
polyisocyanate (A-2) and is intended to contain and, and, (A-1) 2,4-diphenylmethane diisocyanate and
2 , flexible polyurethane foam which is characterized by containing 2-diphenylmethane diisocyanate
50-100%. (2) the diphenylmethane diisocyanate (A-1) is 2,4-diphenylmethane diisocyanate having a
2,2-diphenylmethane diisocyanate 50 to 90%, that more NCO content of 32% and the chlorine ion
concentration is 5ppm or less The flexible polyurethane foam according to the above (1),
characterized in. (3) and wherein the polyol (B) is, has a nominal average functionality in the range of
2-4, it is one that is and having a number average molecular weight in the range from 3000 to 8000
The flexible polyurethane foam according to the above (1) or (2) to be. (4) core density is 25 ~ 35kg / m
3,
wet heat compression set of 25% or less, is more than 100% growth rate, tear strength of 4.5N /
cm 2 or more, the range of 25% compressive stress of 80 ~ 120N The flexible polyurethane foam
according to any one of (1) to (3), characterized in that it is. (5) The method for producing a flexible
polyurethane foam according to any one of (1) to (4).

Flexible polyurethane foams of the present invention is to use only environmentally tenderness tail
Pure MDI polymeric MDI as the isocyanate starting material, core density 25 ~ 35kg / m3, wet heat
compression set of 25% or less, 100% or more elongation, tear strength 4.5N / cm 2 or more, a 25%
compressive stress of having physical properties of 80 ~ 120N. This has a good ride comfort, and it is
possible to obtain a seat cushion and a seat back for a flexible polyurethane foam for vehicles
withstand fog ring.

In the case of producing the flexible polyurethane foam of the present invention, because it does not
use tolylene diisocyanate because volatility is high harmful to the human body and environmentally
friendly.

Hereinafter, the present invention will be described with reference to its preferred embodiments in
more detail.
The flexible polyurethane foam of the present invention, an organic polyisocyanate (A), the polyol (B),
the chain extender (C), the catalyst (D) and soft polyurethane made the mixture is reacted foam
containing blowing agent (E) The foam, the core density of the flexible polyurethane foam is in the
range of 25 ~ 35kg / m3, and the organic polyisocyanate (A) is, with respect to the organic
polyisocyanate (A) 100 wt%, 70 and ~ 90% by weight of diphenylmethane diisocyanate (A-1), and is
characterized in that it is those containing 10 to 30% by weight of polymethylene polyphenylene
polyisocyanate (A-2). Furthermore, the diphenylmethane diisocyanate (A-1) is, it is characterized by
2,4-diphenylmethane diisocyanate and 2,2-diphenylmethane diisocyanate is one that has 50 to 100
percent.

Also, the isocyanate group content in the organic polyisocyanate (A) (NCO content) is preferably in the
range of more than 32% by weight. Such NCO content is less than the lower limit, there is a tendency
that the expansion ratio is less likely to be low density will be lowered.

In the pure MDI in accordance with the present invention, it is necessary that the content of isomers
MDI is 50 to 100 mass%, more preferably 55 to 100 mass%, particularly preferably from 55 to 65 wt
%.

The ratio of isomers MDI in Pure MDI according to the present invention increases 25% compressive
stress of the flexible urethane foam obtained is less than 50 mass%, and wet heat compression strain
becomes unsuitable as a flexible polyurethane foam for exceeds 25%. Also, wet heat compression
strain when the content of the isomers MDI is more than 90 mass% is preferably not more than 90
mass% for exceeds 25%.

Isomer MDI according to the present invention, conventionally although was difficult to obtain from
problems in production techniques in recent years makes it possible to obtain, can obtain an organic
polyisocyanate of various compositions.

The diphenylmethane diisocyanate Examples of the synthesis method of reacting a polyoxyethylene

polyoxypropylene polyol is not particularly limited, a method of the total amount charged prepolymer of
an MDI and a polyol, reacting with some and polyol MDI Method for mixing the rest of the MDI from
the like can be applied.

Incidentally, the flow resistance, hardness, may also be used in combination some other isocyanate
the purpose of foaming speed adjustment. Examples, o- xylylene diisocyanate, m- xylylene
diisocyanate, p- xylylene aromatic diisocyanates such as isocyanate, hexamethylene diisocyanate, 2-
methyl-1,5-pentane diisocyanate, 3-methyl-1,5 - aliphatic diisocyanates such as pentane diisocyanate,
isophorone diisocyanate, hydrogenated diphenylmethane diisocyanate, hydrogenated toluene
diisocyanate, hydrogenated xylylene diisocyanate, and diisocyanates such as alicyclic diisocyanates
such as cyclohexyl diisocyanate, biuret modified products of these diisocyanates, isocyanurates
modified products, uretonimine modified products, carbodiimide-modified products, polyol-modified
products thereof.
As the polyol (B) according to the present invention, but are not limited to, easily expresses the
physical properties of the flexible polyurethane foam, the nominal average functionality of 2-6 and a
number average molecular weight of 3,000 to 8,000 polyether those mainly composed of polyol is
preferred.

Such polyether polyols can be used known ones, for example, a number average molecular weight of
700 less than the low molecular weight polyols, low molecular weight polyamines, as initiator of low
molecular weight amino alcohols, ethylene oxide, propylene oxide and alkylene oxide and the like,
include those obtained by adding a cyclic ether such as tetrahydrofuran. Such initiators include
ethylene glycol, 1,2-propanediol, 1,3-propanediol, 1,2-butanediol, 1,3-butanediol, 1,4-butanediol, and
1,5- pentanediol, 2-methyl-1,5-pentanediol, 3-methyl-1,5-pentanediol, 1,6-hexanediol, neopentyl
glycol, 1,8-octanediol, 1,9-nonane diol, 2,2-diethyl-1,3-propanediol, 2-n- butyl-2-ethyl-1,3-propanediol,
2,2,4-trimethyl-1,3-pentanediol, 2-ethyl -1 , 3-hexanediol, 2-n- hexadecane-1,2-ethylene glycol, 2-n-
eicosane-1,2-ethylene glycol, 2-n- octacosane-1,2-ethylene glycol, diethylene glycol, dipropylene
glycol , 1,4-cyclohexanedimethanol, ethylene oxide or propylene oxide adduct of bisphenol A,
hydrogenated bisphenol A, 3- hydroxy-2,2-dimethylpropyl 3-hydroxy-2,2-dimethyl propionate, tri
trimethylol propane, glycerine, low molecular weight polyols such as pentaerythritol; aniline,
ethylenediamine, propylenediamine, toluenediamine, meta-phenylenediamine,
diphenylmethanediamine, low molecular weight amines such as xylylenediamine; monoethanolamine,
diethanolamine, triethanolamine low molecular weight amino alcohols such as N-
methyldiethanolamine and the like my be mentioned.

Such polyether polyols include water; propylene glycol, dipropylene glycol, glycerol,
trimethylolpropane, pentaerythritol, polyols such as sorbitol; diethanolamine, triethanolamine, amino
alcohols such as tripropanolamine; or ethylenediamine, 1,6-hexane diamine, triethylenetetramine,
aniline, I can also be toluylenediamine, ethylene oxide to amines such as methylene-bis-aniline,
obtained by ring-opening addition of propylene oxide or the like to block or random.

Further, for the purpose of adjusting hardness, it can be further used in combination with polymer
polyol were prepared by polymerizing a vinyl monomer in the usual way in a polyol. Such polymer
polyol, using the same polyether polyol by polymerizing a vinyl monomer in the presence of a radical
initiator include those obtained by stably dispersing. Further, as the vinyl monomer, such as
acrylonitrile, styrene, vinylidene chloride, hydroxyalkyl, methacrylate, include alkyl methacrylate,
acrylonitrile Among them, styrene is preferred. Specific examples of such polymer polyols, Asahi Glass
Urethane Co., Ltd. of EL-910, EL-923, can be mentioned by Sanyo Chemical Industries, Ltd. of FA-
728R and the like.

As the catalyst (C) used in the present invention, it is possible to use various known urethanization
catalysts and trimerization catalysts in the art. Triethylamine Representative examples, tripropylamine,
tributylamine, N- methylmorpholine, N- ethylmorpholine, dimethylbenzylamine, N, N, N ', N'-
tetramethyl hexamethylenediamine, N, N, N', N ', N' '- pentamethyl diethylene triamine, triethylene
diamine, bis - (2-dimethylaminoethyl) ether, 1,8-diaza - bicyclo (5,4,0) tertiary amine -7-undecene and
the like, dimethyl ethanol amine, N- trioxyethylene -N, N- dimethylamine, N, N- dimethyl--N- reactive
tertiary amines or their organic acid salts such as hexanol amine, 1-methylcarbamoyl-imidazole, 2-
methylimidazole, 1 , 2-dimethyl imidazole, 2,4-dimethyl imidazole, 1-butyl-2-methylimidazole and the
like imidazoles compounds of stannous octoate, dibutyl tin dilaurate, organic metal compounds such
as zinc naphthenate, 2,4,6 tris (dimethylaminomethyl) phenol, 2,4,6-tris (dialkylaminoalkyl) hexahydro
-S- triazine, potassium acetate, and a trimerization catalyst such as potassium 2-ethylhexanoate. The
reaction mild to the and, the balance of high cure properties, it is preferable to use at least imidazole
and ether group-containing tertiary amine compound as a catalyst, particularly preferred catalyst is
1,2-dimethyl-imidazole and bis - (2-dimethyl- a combination of the amino ethyl) ether.

Blowing agent used in the present invention (D) are those in which foaming by carbon dioxide gas
generated by the reaction of isocyanate groups with water, vaporizing the foaming at the time of
carbon dioxide for the purpose of low density are mixed in a liquid foam It can also be used in
combination scheme. The amount of water is 2-20 parts by weight is preferable with respect to the
polyisocyanate composition 100 parts by mass. When used in combination with liquefied carbon
dioxide gas preferably 0.5 to 6 parts by weight based on the polyisocyanate composition 100 parts by
weight as the amount.

Foam stabilizer used in the present invention (E) is a known organosilicon-based surfactants in the art,
for example, Dow Corning Toray Co. SZ-1328E, SZ-1325E, SZ-1336E, SZ- 1346E, Momentibu made
of Corporation Y-10366, L-3430, L-3420, L-3151, L-3415, Evonik made of Company B-8737LF2, B-
8724LF2, B-8734LF2, B-8715LF2, Shin-Etsu Chemical Co., Ltd. Made of F-122, and the like. The
amount of these foam stabilizers is 0.1 to 3 parts by mass with respect to the polyisocyanate
composition 100 parts by weight is preferred.

It is also possible to add a diethanolamine or triethanolamine for the purpose of stabilizing the cell for
the present invention. The preferred amount added is from 0.1 to 5 parts by weight per 100 parts by
weight polyol component.

The invention according to need, trichloroethyl phosphate, trichloropropyl phosphate, phosphoric

typified these condensation type - halogen-based liquid flame retardant, solid flame retardant
represented by the melamine powder, conductive typified by Ketjen Black Sexual carbon, plasticizers
such as dioctyl phthalate, anti-oxidants, ultraviolet absorbers, coloring agents, and can be used
internal release agents and other auxiliaries. Note These aids are usually used by adding to the polyol,
aid having no active hydrogen reactive with the isocyanate can also be previously mixed into the
polyisocyanate composition.

The equivalent ratio (NCO / NCO-reactive groups) include 0.5 to 1.5 (isocyanate index of the total
isocyanate-reactive groups of the isocyanate-reactive compound containing a total isocyanate groups
with water in the polyisocyanate composition of the present invention preferably has (NCO INDEX) =
50 to 150), and more preferably 0.7 to 1.2 (isocyanate index (NCO INDEX) = 70 ~ 120).

Process for producing a flexible polyurethane molded foams of the present invention, a flexible
polyurethane foam stock solution of the above (A) ~ (E) was injected into the mold, a method of
manufacturing a subsequent flexible polyurethane molded foam characterized in that it is foamed and
cured It can be used.
The mold temperature at the time of the injection of the foaming stock solution into a mold, usually 30
or more, preferably 40 or more, usually 70 or less as the upper limit, preferably 60 or
less. If the mold temperature at the time of injecting the foaming stock solution into the mold is less
than 30 , curing property is lowered, whereas, roughening is higher the foam surface than 70 ,
also economical due to an increase in energy costs It can be a such disadvantages.

The above foaming stock solution as the time of curing in the mold is usually 3 minutes or more,
preferably 4 minutes or longer, usually 8 minutes or less as an upper limit, preferably not more than 6
minutes. The curing time in foaming cure the foam stock solution is shorter than 3 minutes, there are
cases where curing is lowered, whereas, it is longer than 8 minutes, energy costs Kasami, also if the
resulting foam to shrink It is there.

The mixture obtained by the foaming machine is discharged into the mold, and foamed cured, then
demolding is carried out. Order to perform smoothly the demolding, the mold is also preferable that it
should be coated with a release agent beforehand. The release agent to be used may be used a
release agent commonly used in molding processing field, but are not particularly limited, from the
viewpoint of suppressing unwanted foaming of the foaming stock solution, the wax solvent in the
present invention It is preferable to use the system releasing agent. Also, it is possible to use the
product after demolding even as it is, to prevent shrink of the foam (shrinkage), conventionally known
methods in the compression or to destroy the cell under a reduced pressure, the appearance of the
product, to stabilize the dimensions I can also.

Hereinafter, the present invention will be described more specifically with reference to examples and
comparative examples, the present invention is not limited to the following examples. Unless otherwise
specified, "parts" in the sentence, "%" it is assumed to be mass. Furthermore, raw materials used in
Examples and Comparative Examples are as follows.

As you adjust the organic polyisocyanate, and describes the raw materials used in the following. MDI-
1: MDI isomers 94%, diphenylmethane diisocyanate containing 6% 4,4'-MDI, manufactured by Nippon
Polyurethane Industry Co., Ltd. MDI-2: 4,4'-MDI diphenylmethane diisocyanate containing 100%,
Nippon Polyurethane Industry Company made MDI-3: 4,4'-MDI 31%, diphenylmethane diisocyanate
containing polymeric MDI 69%, manufactured by Nippon Polyurethane Industry Co., Ltd.

As we adjust the polyol premix are described raw materials used in the following. <Polyether Polyol>
P-1: Polyoxyethylene polyoxypropylene polyols, nominal average functionality 3, a number average
molecular weight of 6000, manufactured by Sanyo Chemical Industries, Ltd. product name FA-921P-2:
polyoxyethylene polyoxypropylene polyols, the nominal average functionality 4, a number average
molecular weight of 8000, manufactured by Sanyo Chemical Industries, Ltd. product name KC-285P-
3: polyoxyethylene polyoxypropylene polyols, nominal average functionality 3, a number average
molecular weight of 3,500, manufactured by Sanyo Chemical Industries, Ltd. product name FA-103 <
catalyst> C-1: triethylenediamine 33% DPG solution, manufactured by Tosoh Corporation Name
TEDA-L33C-2: 70% bis (dimethylaminoethyl) ether, 30% dipropylene glycol, Tosoh Corp. product
name Toyocat-ET <crosslinked material> DEA: diethanolamine, manufactured by Mitsui Chemicals,
Inc. <foam stabilizer> S-1: silicone-based foam stabilizer, Momentibu product name Y-10366
In a reactor equipped with a stirrer, P-1 to 70kg, 30kg and P-2, the P-3 5kg, water 5.8kg, 0.4kg of C-1,
C-2 and 0.1kg, S- 1 was 1kg, 0.5kg charged DEA, it was possible to obtain a polyol premix by
performing the uniform mixing.

Using a Krauss manufactured high pressure foaming machine, to produce a flexible polyurethane
molded foam in the following manner. Material temperature 23 2 temperature control polyol
premix, under the isocyanate component in a predetermined ratio, I was discharged into a mold that
has been controlled at 60 2 to high pressure mixing (400mm 400mm 70mm thick). After 5
minutes de from the mold it was click the form lashing. The resulting foam under temperature 23 2
and a relative humidity of 50 5%, allowed to stand for more than 16 hours. Then, it was cut to a size
required for each measurement of physical properties were measured for their physical properties. I
Table 1 shows the results. Measurement of physical properties to comply with JIS K6400. Moreover,
the "hardness measuring method A" in the JIS, the load when compressed by 25% of the foam
thickness will be referred to as a 25% compression stress.
As shown in Table 1, it was possible to obtain a flexible polyurethane foam in Examples 1-3. That is,
the proportion of (A-1), when 70-90% of the organic polyisocyanate, tear strength of 4.5N / cm or
more, the growth rate of 100% or more, soft wet heat compression residual strain is to secure a 25%
or less Form it is obtained. On the other hand, when using a polyisocyanate composition of
Comparative Example 1, it was not possible to satisfactorily fill the flexible polyurethane foam in foam
in the mold will be depressed. Further, in the case of using a polyisocyanate composition of
Comparative Example 2 becomes low expansion ratio of the foam, it was not possible to establish a
sufficient moldability. This phenomenon, that the NCO content is less than 32% is the reason.
In Table 2, the proportion of isomers MDI for the (A-1) is when 50% or more, and tear strength of
4.5N / cm or more, the growth rate of 100% or more, moist heat compression residual strain is to
secure a 25% or less flexible foam is I obtained. When less than 50 percent, would have a 25%
compressive stress exceeds the 120N, it is difficult to be used as a vehicle seat back which is the
objective.
In Table 3, since the curing property is deteriorated when the chlorine ion concentration in the organic
polyisocyanate is 5ppm or more, it was not possible to obtain a flexible polyurethane foam. In general,
when the curing is poor, it is possible to improve the cured properties by increasing the urethanization
catalyst amount, the catalyst amount is large, the catalyst odor is generated from the resulting flexible
polyurethane foam, urethane foam It does not show the product value as a product. In addition, the
catalyst in order to occupy a large weight to economic in raw materials, it is not preferable to increase
the amount of the catalyst to resolve the cure of. Note that the chloride ion concentration, it is possible
to measure in a known measuring method using an ICP or the like.

As apparent from the results shown so far, flexible polyurethane foam obtained by the method of the
present invention using a polyisocyanate composition of the present invention are all, those excellent
for the above physical properties (foam physical properties) it was confirmed that it is.

Therefore, the flexible polyurethane foam obtained by the present invention is durable, has excellent
support, etc., furniture cushioning material sofa, etc., clothing, automobiles and cushion material for a
railway vehicle, automotive interior materials, mattresses, pillows, etc. for bedding, sound-absorbing
material, sound insulation materials, household electric appliances, electronic components, industrial
sealing material, packaging material, it is useful for the grocery, etc..

PATENT ATIFLARI

Dosya
Alnt Yaplan Bavur
kabul Yayn tarihi Balk
Patent u sahibi
tarihi
Yumuak
poliretan
kpk iin
Nippon poliizosiyanat
WO2008136179A1 10 Nis 13 Kasm Poliretan bileimi ve
* 2008 2008 Sanayi bileimden
A.. yumuak
poliretan
kpk retme
yntemi
Balk mevcut
JP2001152155A *
deil
Balk mevcut
JP2001172360A *
deil
Balk mevcut
JP2001329042A *
deil
Balk mevcut
JP2003097645A *
deil
Balk mevcut
JP2004231706A *
deil
Balk mevcut
JP2004505139A *
deil
Balk mevcut
JP2006070241A *
deil
Balk mevcut
JPH0368618A *
deil
Balk mevcut
JPH02145557A *
deil
Balk mevcut
JPH10237153A *
deil