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Kinetics of a Reaction
PURPOSE:
The purpose of this experiment is to observe the oxidation of iodide ions by bromate ions in the
presence of acid, and thereby discern the total rate law and activation energy for the reaction.
PRE-LAB QUESTONS:
1. a)
b) The concentration of iodide ions doubled between trial 1 and trial 2, and the reaction rate
quadrupled between trial 1 and 2, therefore the reaction order for iodine is 2, because when 2x =
4, x = 2.
c) Trials 1 and 3 should be compared to determine the order of reaction with respect to persulfate
The rate law could have been predicted using the coefficients in the balanced chemical equation
because the coefficients in front of I- and S2O82- in their reaction match their exponents in the rate
law.
3.
ln K = -E2 / RT + ln A
PROCEDURE:
1. Take the mass of a beaker before and after delivering five drops of distilled or deionized
2. Add an additional 5 drops of water to the beaker and again record its mass; Repeat this step
3. Obtain 6 micro tip pipets, label them with their appropriate solutions, and fill each pipet with
its solution.
4. In a clean, 12 well reaction strip, fill number one well with the appropriate number of drops
of the first of the first five reagents listed in Experiment #1, and repeat this step for the next
two wells.
5. For the next 3 wells, repeat step 5 for the reagent amounts listed for Experiment #2, wells
7,8, and 9 for the amounts listed in Experiment #3, and wells 10,11, and 12 for the amounts
6. In well 1, add two drops of KBrO3, use a timer to find the time required for the first tint of a
blue color to appear, then repeat tis step for wells 2 and 3.
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7. Take the temperature of a reaction solution, then record the temperature for each reaction in
Data Table 2.
8. Repeat step 6 for wells 4,5, and 6, then 7,8, and 9, then 10,11, and 12, in order.
9. Rinse and dry the well strips with warm water and a cotton swab, then repeat the entire well
process for the reagent combination in Table 1 for experiments #5, #6, and #7.
10. Using the amounts listed in Table 1 Experiment #1, fill the first 6 wells with the appropriate
number of drops for the first five listed reagents, then place the reaction strip in a shallow
11. Place the Beral pipet labeled KBrO3, after filling it halfway with a 0.040 M KBrO3 solution,
12. Measure and record the temperature of the water bath, then take the pipet out of the water
13. Add two drops of KBrO3 to the first well of the reaction strip, still in the water bath, then
with a timer record the time in seconds when the first blue color appears.
14. Immediately after starting the timer, place the pipet back in the warm water bath, then repeat
15. Remove the pipet and reaction strip from the warm water bath, cool the water bath with ice
cubes, then place the reaction strip and pipet into the now cold water bath.
16. Measure and record the new temperature of the water bath, then repeat step 13 for wells 4, 5,
and 6.
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MEASUREMENTS TO BE TAKEN:
- Time in seconds required for first tint of blue color to appear in 3 trials of 7 experiments
MATERIALS:
DATA:
Data Table 2: Determine the Reaction Rate and Calculate the Rate Law
RESULTS:
After observing the oxidation of iodide ions by bromate ions in the presence of acid, I found the
total rate law for the reaction to be Rate = k [I-]1 [BrO3-]1 [H+]2. To determine this rate law, I had
to calculate the rate order for each reactant in the reaction. Furthermore, I found the reaction
rates for experiments 1 through 7 to range from 2.59x10-7 to 3.43x10-8. I also calculated the
initial concentrations, in moles per liter, for [I-], [BrO3-], and [H+] for experiments 1 through 7.
Additionally, I found the rate constant, k, along with its units for each of the seven reactions.
Finally, I graphed the natural log of the rate constant versus 1 divided by the temperature in
Kelvin, and used the slope of this graph to determine the reactions activation energy, which I
CALCULATIONS:
Volume of one drop = (0.03707 g / 1.00 g/mL) x (1 L / 1000 mL) = 3.707 x 10-5 L
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(3.707 x 10-5 * 0.0010 mol Na2S2O3 * 1 mol S2O32-) / (1.00 L * 1 mol Na2S2O3) =
(3.707 x 10-8 mol S2O32- * 1 mol I2 * 1 mol BrO3-) / (2 mol S2O32- * 3 mol I2) =
-[BrO3-] = (6.178 x 10-9 mol / (3.707 x 10-5 L * 12 drops)) = -[BrO3-] = 1.85 x 10-5 M
[I-] = (2 drops * 0.010 M KI) / (12 drops solution) = 0.0017 M = 1.7 x 10-3 M
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Rate1 / Rate2 = (3.43 x 10-8 M/s / 8.78 x 10-8 M/s) = [1.7 x 10-3]x / [3.4 x 10-3]x
0.391 = 0.50x
x = 1.35
x 1
y 1
z 2
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k-1 = (3.43 x 10-8 M/s) / (1.7 x 10-3 M)1 (6.7 x 10-3 M)1 (1.7 x 10-2 M)2 = 10.4 M-3 s-1
Exp. # 1 2 3 4 5 6 7
Rate = (- [BrO3-] / time) = (1.85 x 10-5 M / 601 sec) = 3.08 x 10-8 M/s
k0C = (3.08 x 10-8 M/s) / ((1.7 x 10-3 M)1 (6.7 x 10-3)1 (1.7 x 10-2)2) = 9.4 M-3 s-1
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Slope = -Ea / R
Ea = 24.8 kJ / mol
ANALYSIS:
The purpose of this lab was to use data calculated from the oxidation of iodide ions by bromate
ions in the presence of acid to calculate each aspect of the reactions rate law, and graph the
natural log of k versus 1 divided by the temperature of the reaction in Kelvin to determine the
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reactions activation energy. We therefore did the lab both to gain practice with the intricate
calculations that are required to calculate all aspects of a rate law, as well as to observe and
understand the real-world applications of kinetics problems. I learned a variety of skills and
pieces of information from this lab, but, most notably, I learned how to use data such as the
temperature at which a reaction occurred or the volume of one drop of solution to calculate
values such as a reactions activation energy or reaction rate. Furthermore, though the lab, I
gained a new understanding of what reaction rates truly signify by observing reactions in wells
that could take up to 6 minutes to finally show signs of reacting, such as gaining a blue tint. This
experiment works to teach students the mechanisms and applications of kinetics because it
allows them to manipulate reactions and collect data from them on their own, providing them
with a connection between the reactions they are witnessing and the calculations they are
performing. One specific source of error in our experiment came in the third part of the
laboratory procedure. When we immersed the reaction strips containing the six solutions in the
42.8C water, small bubbles collected around the sides of the strips, which inhibited our view of
the solutions, causing us to report slightly higher than accurate times for the reaction in data table
3. To get better results, my partners and I could change our procedure by staying more organized
and efficient though the repetitive steps, and carrying out the third part of the reaction before the
second, as the second part was easier and could be finished faster than the third. This lab is worth
repeating because now I understand the role each aspect of the lab plays in determining the
POST-LAB QUESTIONS:
1. The reaction rate changes as the concentration of of the reactants change because if a
solution has a higher concentration, and therefore more particles of solute, it will react at a
different rate than it would with less particles of solute. This is because each particle of a
solution is involved in the reaction, which greatly affects the speed at which a reaction takes
place.
2. There are three separate aspects of the rate law to be determined: the reaction rate, the rate
constant, and the rate orders. The reaction rate is found by dividing the molarity of the
reactions reactants by the time in seconds it took them to begin reacting. The rate constant is
calculated by multiplying the initial concentrations of the reactions reactants with each other
with their respective rate orders. The rate orders of the reactants are found by taking the
natural log of one reaction rate divided by another and the natural log of the rates respective
3. Reaction rate changes as temperature changes because particles move at different speeds at
different temperatures. Since temperature alters the speed of particles, it also alters the speed
of entire reactions.
4. To determine the activation energy of a reaction, you graph the natural log of k versus 1
divided by temperature of the reaction in Kelvin. You then multiply the slope of this line by
the constant 8.314 J/mol*K to find the activation energy of the reaction.
5. The reaction rate is the speech at which a reaction occurs while the specific rate constant is
the constant value, which is specific to only a particular reaction, that makes the math for the
6. A reaction catalyst acts both to speed up a reaction, therefore increasing the reaction rate, and
to decrease the minimum energy a reaction needs to reach before it can proceed, its
activation energy. When a catalyst is added to a reaction, the activation energy of that
reaction decreases because the reaction requires a lower energy than it would without the
7. My data collected from calculations over rate order and activation energy was consistent,
however the specific values of my calculated rate orders were very roughly approximated to
be the whole number rate orders I reported. The calculated orders were closer, for example,
to half integers than to full integers, such as 1.5 as a half integer versus 1 as a full integer.
The check of the rate orders did, however, give the same integers that I reported.
straight line.
8. ln (k1 /k2 ) = (-Ea /(RT2 )) (-Ea/(RT1 )) is the two point form of the Arrhenius equation. In
this equation, k is the rate constant, Ea is the activation energy, T is the temperature of the
9. Our data could be improved by carrying out more trials, which would increase the accuracy
and precision of our data, as well as give us more practice at carrying out the procedure.
Furthermore, we could have used more accurate timing device than our phone timers to
measure the time it took for reactions to proceed. This would make the time in seconds of
reactions more accurate, which would in turn make the reaction rates of the reactions more
accurate.