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This paper was prepared for presentation at the SPE Oil and Gas India Conference and Exhibition held in Mumbai, India, 46 April 2017.
This paper was selected for presentation by an SPE program committee following review of information contained in an abstract submitted by the author(s). Contents
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Abstract
The hydraulic fracturing industry is a fast-growing industry but the conventional hydraulic fracturing
technique uses a large amount of water and a lot of harmful chemicals in order to extract more
hydrocarbons from the formation which give rise to a large number of problems. Canada based GasFrac
Energy developed an innovative alternative to hydraulic fracturing which utilizes propane based gel or
gelled LPG as a fracturing fluid to fracture the formation. Propane is a very clean fluid, ecofriendly and
can be recovered almost 100% after the fracturing process is completed.
As compared to conventional hydraulic fracturing technique, LPG fracturing provides a better fracturing
length. A precursor to the poor fracturing performance is poor recovery of the fracturing fluid, often less
than 50% of the fracturing fluid is recovered. This unrecovered fluid occupies the pore spaces of the
reservoir matrix and becomes immobile resulting in blocking the passage for hydrocarbons. Therefore,
the recovery of hydrocarbons by conventional hydraulic fracturing job is much less than that of propane
fracturing, where the recovery of fracturing fluid is almost 100%.
This paper will discuss about various aspects of Propane Fracturing, safety aspects during field application
of this technology and its prospects in a country like India which is trying to revive its oil and gas
production and has a huge potential hydrocarbon reserves including much of its reserves still unexplored.
Introduction
LPG fracturing is one of those rare technology breakthroughs in the oil and gas industry that can deliver
both economic and environmental benefits for producers.
There is no use of costly materials like CO2 and N2 in LPG fracturing process, since it provides a consistent
viscosity when gelled with proprietary chemicals nor does it require any special cooldown or venting of
equipment. LPG is stored at ambient temperature and can be easily available as it is an abundant by-
product of natural gas industry.
Using LPG also reduces the need to flare production to clean up the traditional fracturing fluids, reducing
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CO2 emissions. Because propane liquid is half the specific gravity of water, there is reduced trucking to
the site and no trucking to transport post stimulation which can reduce truck traffic by up to 90%.
LPGs high volatility, low weight, and high recovery potential make it a good fracturing agent. Use of
LPG as a hydraulic fracturing fluid also inhibits formation damage which can occur during hydraulic
fracturing with conventional fluids. Using propane not only minimizes formation damage, but also
eliminates the need to source water for hydraulic fracturing, recover flowback fluids to the surface and
dispose of the flowback fluids. As a result of the elimination of hydraulic fracturing source water, truck
traffic to and from the wellsite would be greatly reduced. In addition, since LPG is less reactive with the
formation matrix, it is therefore less likely to mobilize constituents which could increase NORM levels in
the flowback fluid.
Gel Potentially Damaging Reactive with Non-Damaging Inert with the Formation
Formation Clays/Salts Clays/Salts
During the stimulation operation, monitoring wells with micro-seismic detectors are used to record
seismic events generated and thus verify the final extension of the cracks. Other monitoring techniques
are also used, such as real-time monitoring of the bottom hole pressure and the quantity of fluid injected.
Once the stimulation has been achieved, the cracks created must be kept open after the pressure drops. To
this end, proppants (solid particles) are injected along with the liquid propane. If the particles are of a
density close to that of the fluid injected, then no chemical additives are needed (chemicals are added to
SPE-185441-MS 3
It should be of utmost imporatnce that LPG must be maintained in liquid phase during all stages of
fracturing process, particularly at reservoir conditions so that it can be used as an efficient carrier of
proppant.
LPG Propane liquid and vapour phases are in the 100% Propane Liquid-Vapour Saturation diagram (Fig.
2). Propane exixts as a liquid above the saturation line; while below the saturation line propane is a vapour.
Propane is stored at ambient temperature, and in the case of ambient temperature of 70F, the minimum
storage pressure of 125 psi required to maintain propane as a liquid.
Surface tension
Surface tension exhibited by the fracturing fluid greatly impacts capillary pressure effects in the reservoir.
Selecting a fluid with a low surface tension will reduce the pressure needed to mobilize fracturing fluid
forclean-up. Fig.5. compares the surface tension of common fracturing fluids to that of LPG products.
Capillary Pressure
When we select the fracturing fluid ,the significance of the capillary pressure is mostly overlooked. Pores
and fractures are blocked usually due to the high capillary pressure of the reservoir rock,which obstructs
the flow of hydrocarbon into the created fractures, there by significantly reducing productivity.
Unfortunately, once in place, these trapped are very hard to remove.
Each reservoir has its unique capillary pressure ased upon the formation and fluid. The capillary threshold
pressure, must be overcome before flow occurs, this defines the pressure differential needed to mobilize
the fracturing fluid.
Estimated capillary threshold pressures are displayed in Fig. 6 for a range of surface tension values at
various flow path dimensions. For example, water would be comparable to 70 dynes/cm, then surface
tension modified water such as a methanol-water at 40 dynes/m and a low surface tension liquid such as
a liquified petroleum gas at 7 dynes/cm. All contact angles are presumed at zero degrees.
In the above figure 7 it is shown that effective fracture length is more in propane fracturing compared to
that of hydaulic fracturing. In Hydraulic fracturing due to Clay swelling and blockage of water in the pores
results in shorter effective fracture length. In propane fracture effective fracture length is almost equal to
the propped fracture length.
Comparision of Production
As we have seen that effective fracture length is more in LPG fracturing technique, we can say that from
the same fracture more amount of hydrocarbons can be recovered compared to conventional fracturing.
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Clean up Efficiency
Fracturing fluid clean up from the formation depends upon the surface tension of fluids and from the
vertical length of tubing to wellhead it depends upon specific gravity of fluid. From formation to wellbore
low surface tension of LPG reduces the pressure needed to mobilize the fluid. Since the specific gravity
of LPG is .51 almost as half of water, so there is no issue of loading of well. So, better cleanup is achieved
in case of propane fracturing.
Proppant Settling
Figure 12 shows Propane fracturing equipment setup. The simplified operation of the area is very summarily
explained in the following section.
Area 1: liquid propane feed and injection line at medium pressure
The area for liquid propane injection at medium pressure is the upstream part of the production line. It is
made of four main parts:
Liquid propane tankers which are central and key to the module
A low- pressure pump (LP)
A silo under pressure used to mix proppant into the LPG
A nitrogen gas feed.
Area 2: liquid propane injection line at high pressure
Area 2, which is the high pressure injecion of propane, covers a larger surface area than area 1, but has
only two main elements:
A series of high pressure compressors (HP)
A high-pressure injection line that directs flows to either the well or the flare line
Area 3: "Flow back" (or recovery) line
The flow back line processes all of the fluids coming up out of the well after fracturing and separates the
different components (water, oil, gas) and manages each as most appropriate. This line can also serve as
a blowdown system, in which case, the fluid does not go through the different lines described here, but is
sent directly to the flare. The flow back module can be divided into a series of units that make up the
processing line:
Valves and manifold for upstream flow management,
Phase separation modules (heating, decanting, cooling),
Storage tanks
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(delayed ignition-explosion), toxic cloud (no-ignition), safe dispersion are the outcome cases of any leak
of hazardous material leakage.
Leakage in Medium Pressure lines (area 1)
Medium pressure lines leakages occur at the discharge of the tanks or in the flowlines. Each outflow valves
of tanks contribute to the pressure in the flow lines. Reducing the flow rate decreases the pressure and can
prevent the leakage.
Table 3 shows different risk identification and preventive measures for each risk.
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Environmental Impact
Impact on Water Resources
No portable water is used in this process.
Pure propane stimulation does not need chemical additives. Unlike water, propane does not change
the geochemical balance of the natural source rock and does not dissolve any mineral or organic
elements that are normally found in solid form.
The main item for attention concerning the preservation of water resources is the possibility of
uncontrolled hydrocarbon contamination underground (discontinuity underground due to faults or
leaks). Whilst propane is not toxic in and of itself, it can transport hydrocarbons (liquid or gas) and
other substances (oil, H2S, metals etc.), often in small amounts, but that may have toxic/ecotoxic
potential specific to each site. Special attention should be paid to the detection and of sizable faults
in the area of the planned operation.
Impact on Air resources
The possibility of propane leaks or environmental release (pressure relief valves) from the flow
back or injection line (propane itself is not a greenhouse gas, but it can react with other components
in the atmosphere and contribute in a secondary manner to greenhouse gas).
The presence of potentially toxic gas associated with propane when the large tank is emptied (H2S,
benzene, etc.).
The flare contributes to CO2 production which is primary greenhouse gas.
Impact of Soil quality
The absence of chemical additives limits the risk of accidental spills on the surface, and the fact
that wastewater holding ponds are not used is also a favourable point. Liquid propane is not a
pollutant in itself and it vaporizes in contact with the atmosphere.
The main items for attention are those intrinsic to all types of oil exploration: Risks linked to
accidental spills of the tanks of wastewater and oil produced.
Impact on Health
The fact that chemicals are not used considerably limits any health impacts that might result from
the implementation of the operational sector
The release of potentially toxic gases that are present in the large tank and drained by propane
associated with propane when the large tank is emptied (H2S, benzene, etc.) can be matter of
attention.
SPE-185441-MS 15
Challenges in India
The challenges faced by India in its efforts to revive upstream activity are informed by a set of
characteristics which can be summed up as follows:
India is a net oil importing/oil dependent country.
The country has a high concentration of acreage with a small number of players (such as the main
NOCs).
There is declining upstream activity.
Oil production (usually from NOCs) is stagnating
By 2040, India's dependence on imported oil will rise to 90 percent, says a report released by International
Energy Agency at the end of November 2015.
Indias dependency on imported oil is likely to grow as it tries to achieve double-digit economic growth
and its consumption increases. Currently, per capita, Indias energy use is only a third of the global
average. That means, its got a lot of room to grow. According to International Energy Agency, between
2013 and 2040, the growth of demand for oil in India will be the highest in the world.
On the gas side of things, in 2014-2015, India imported about 36 percent of its gas needs. But its going
up. From April-October of 2015, India imported 37 percent of its gas needs. For the same period in 2016,
it imported 39 percent.
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25000
20000
15000
10000
5000
0
2009-10 2010-11 2011-12 2012-13 2013-14 2014-15 2015-16
Production Consumption
Fig 13 Production and Consumption of LPG (Financial Year Wise) in 000 Tonnes
Import/Export of LPG
10000
9000
8000
7000
6000
5000
4000
3000
2000
1000
0
2009-10 2010-11 2011-12 2012-13 2013-14 2014-15 2015-16
Import Export
Fig.14 Production and Consumption of LPG (Financial Year Wise) in 000 Tonnes
SPE-185441-MS 17
The graph (fig. 14) shows the imports and export of LPG in each successive year from 2009-10 to 2015-
16. As it is very clear from the graph that India is an importer of LPG to meet its domestic and industrial
needs. India imports LPG based on long term contracts from major Middle Eastern producers: Saudi
Aramco, Qatars Tasweeq, Abu Dhabi Oil Co. and Kuwait Petroleum Corp.
However, according to Indian oil ministrys research arm, Indias LPG demand 60% butane and 40%
propane had been expected to increase 3.5% to 18 million mt in fiscal year 2015/16. With this estimates,
the industry predicts to grow around 5% to 6%, in same year.
Note: On an average a propane fracturing job requires 180 tonnes of LPG.
Drilling Intensity
The following table depicts examples of drilling intensity (as indicative of upstream activity) from
countries within regions which have ratios of less than 1, but focusing on basins with some of the highest
exploration investments. A very basic comparison of similarly sized basins in India suggests that upstream
activity in India is underperforming. For example, the Vindhyan (162,000 km2) and Ganga (186,000 km2)
basins are comparable in size of acreage to the Pearl River Mouth basin in China. However, drilling
intensity for the Vindhyan is 1 well per 17,364 km2 and for the Ganga basin it is 1 well per 23,992 km2,
compared with a much more efficient 1 per 1,190 km2 for the Pearl River Mouth basin.
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Environmental Challenges
India is home to an extraordinary variety of climatic regions, ranging from tropical in the south to
temperate and alpine in the Himalayan north, where elevated regions receive sustained winter snowfall.
The nation's climate is strongly influenced by the Himalayas and the Thar Desert. Such variable climatic
conditions reduce the efficiency of the equipment and makes the job difficult and sometimes, even
uneconomically viable.
For example, Cairn India, one of the largest oil and gas exploration and production company in India has
its key assets in Rajasthan, the state whose major part is covered with desert. Even, Mangala field, which
is considered to be the largest onshore oil discovery in India in the last two decades is located in Rajasthan.
In summer season when the temperature of these regions crosses 50 degree celsius, the operations like
hydraulic fracturing, which require millions of gallons of water become very challenging due to extremely
low availability of water. In these cases, it will be better to go for a operation/job which will require either
less or no amount of water.
A lot of exploration is going on by companies like ONGC, OIL India, etc in north-eastern part of India
which has a huge potential for hydrocarbon reserves but this part of the country is not so developed and
major part of it is covered with forests and mountains. Due to poor transportation facilities in such regions,
the jobs like hydraulic fracturing which involves a large amount of water to be transported from the source
to the field become a challenging task.
In such challenges, the technique like propane fracturing provides the best solution as it requires less
amount of water so less number of trucks will be required for transportation purposes. Because of these
merits of this technology, it is best suited to both of the above discussed regions.
Government Initiatives
In a major drive to enhance the petroleum and hydrocarbon sector, Government of India has
introduced initiatives like the Hydrocarbon Exploration Licensing Policy (HELP), Marketing and
Pricing freedom for new gas production, grant of extension to the Production Sharing Contracts
and assigning the Ratna offshore field award to Oil and Natural Gas Corporation (ONGC) for
development.
SPE-185441-MS 19
The Union Cabinet has allowed state-owned oil firms to evolve their own crude oil import policies
which involve freedom to choose source companies as well as pricing for their crude oil imports,
thus allowing them to compete in the market effectively.
Mr Dharmendra Pradhan, Minister of State (Independent Charge) for Petroleum and Natural Gas
has released the Hydrocarbon Vision 2030 for North East India, with the objective of leveraging
the north-eastern regions hydrocarbon potential; enhance access to clean fuels, improve
availability of petroleum products, and facilitate economic development and to involve local
population in the economic activities in this sector.
The Government of India plans to incentivise gas production from deep-water, ultra deep-water
and high pressure-high temperature areas which are presently not exploited on account of higher
cost and risk, and also to augment the investment in nuclear power generation in the next 15 to 20
years.
The government of India proposed a plan to merge of the state- controlled oil companies, both
upstream and downstream to reduce inefficiencies and improve competitiveness globally. A
merger can create an entity that is better placed to compete globally for resources, less vulnerable
to shifts in oil prices and it would also have opportunities to save on costs and improve operational
efficiency.
Benefits: These policies of government encourage the companies present here to take risk and invest big
on new technology such as propane fracturing, without the fear of losing the investment completely. As
water is a scarce resource in India its is good to invest in technology like propane fracturing which
requires almost no water, provide long term benefits and also prevent the wastage of resource such as
water. Because of all these policies of government the companies prefer to invest on innovative ideas
which will give a long-term benefit to them and which is eco friendly in nature.
Conclusions
Propane fracturing is a better way of stimulation compared to hydraulic fracturing and CO2 fracturing. It
results in more effective fracture length, more production, better cleanup efficiency and faster frac fluid
recovery. Initial cost of doing the fracturing job is more but overall cost considering more recovery is less
in propane fracturing. Most importantly, it does not use fresh water as a frac fluid. But it also has some
limitations. High flammability of LPG is major risk in the fracturing operation. There are chances of LPG
leakage which can detected by using thermal cameras.
There are many possibilities of development and improvement in propane fracturing since it is in the early
stages of industrial application. It should be included in research programs for techno economic
performance analysis. It should be introduced in India considering the energy demand of the nation.
Acknowledgement
Authors of this paper wish to thank Society of Petroleum Engineers for giving the opportunity to present
this paper in Oil and India Conference 2017. They also want to thank Gas Frac for developing this
revolutionary technology. They also wish to thank various companies like ONGC, RIL, Schlumberger,
Cairn India, Shell for keeping them updated about the lastest technology of the industry. At last they want
to thank Department of Petroleum Engineering, Indian Institute of technology (Indian School of Mines),
Dhanbad for their continuous support and guidance.
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