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Reading a 400,000-year record of earthquake

frequency for an intraplate fault


Randolph T. Williamsa,1, Laurel B. Goodwina, Warren D. Sharpb, and Peter S. Mozleyc
a
Department of Geoscience, University of WisconsinMadison, Madison, WI 53706; bBerkeley Geochronology Center, Berkeley, CA 94709; and cEarth and
Environmental Science, New Mexico Institute of Mining and Technology, Socorro, NM 87801

Edited by Barbara A. Romanowicz, University of California, Berkeley, CA, and approved March 21, 2017 (received for review October 31, 2016)

Our understanding of the frequency of large earthquakes at research has shown that many seismogenic plate-boundary faults
timescales longer than instrumental and historical records is based around the world exhibit quasiperiodic failure (1417), compara-
mostly on paleoseismic studies of fast-moving plate-boundary tively slow recurrence rates in conjunction with short paleoseismic
faults. Similar study of intraplate faults has been limited until now, records have until now prevented robust assessment of earthquake
because intraplate earthquake recurrence intervals are generally recurrence intervals for intraplate faults. We address this fun-
long (10s to 100s of thousands of years) relative to conventional damental knowledge gap by using a significantly different ap-
paleoseismic records determined by trenching. Long-term varia- proach; direct dating of coseismic veins preserved as part of the
tions in the earthquake recurrence intervals of intraplate faults long-term rock record.
therefore are poorly understood. Longer paleoseismic records for We studied an exhumed section of the Loma Blanca normal
intraplate faults are required both to better quantify their earth- fault, which juxtaposes <2.6 Ma sediments and sandstones
quake recurrence intervals and to test competing models of earth- against 5.3- to 1.8-Ma fluvial sands in the Socorro Basin of the Rio

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quake frequency (e.g., time-dependent, time-independent, and Grande rift of New Mexico (18) (Fig. 1). Maximum displacement

EARTH, ATMOSPHERIC,
clustered). We present the results of U-Th dating of calcite veins across the Loma Blanca fault is 500 m (21). Fault-scarp mor-
in the Loma Blanca normal fault zone, Rio Grande rift, New Mex- phology and offset Pleistocene terrace deposits preserved in other
ico, United States, that constrain earthquake recurrence intervals locations along the fault record a history of recurrent, surface-
over much of the past 550 kathe longest direct record of seis- rupturing earthquakes (18). Assuming rupture of the entire
mic frequency documented for any fault to date. The 13 distinct
23-km-long fault trace, earthquake magnitudes estimated for the
seismic events delineated by this effort demonstrate that
Loma Blanca fault are 6.26.9 (22). This magnitude is a min-
for >400 ka, the Loma Blanca fault produced periodic large earth-
imum estimate, because it neglects possible multifault events,
quakes, consistent with a time-dependent model of earthquake
which may produce larger earthquakes (23).
recurrence. However, this time-dependent series was interrupted
Within the exhumed section of the fault, sand injectites and
by a cluster of earthquakes at 430 ka. The carbon isotope com-
calcite veins are largely restricted to the hanging wall damage
position of calcite formed during this seismic cluster records rapid
degassing of CO2, suggesting an interval of anomalous fluid
zone near and within a relay zone between two fault segments
source. In concert with U-Th dates recording decreased recurrence
(Fig. 1, South Fracture Zone) (20). Sand injectites in this area
intervals, we infer seismicity during this interval records fault- record early, coseismic fluid overpressure and/or liquefaction,
valve behavior. These data provide insight into the long-term seis- which occurred during ground shaking before lithification. Cal-
mic behavior of the Loma Blanca fault and, by inference, other cite veins postdate cementation of the sand injectites. They occur
intraplate faults. in dominant fault-strike-subparallel and subordinate fault-strike-
subperpendicular sets. The veins are hosted by extension frac-
earthquake | fault | geochronology | seismic | hazard tures, exhibit crack-seal microstructures, and commonly contain

Significance
R ecent increases in the rate of seismicity associated with
subsurface wastewater injection have generated substantial
interest in the seismic cycles of intraplate faults (14). Un- U-Th dating of coseismic calcite veins in the Loma Blanca fault,
fortunately, increasing seismicity in the continental interior has New Mexico, quantifies an earthquake history spanning more
outpaced our understanding of the processes that govern natural than 400,000 years, the longest paleoseismic record ever
earthquake recurrence on these faults. The seismic cycles of documented for any fault. Data show that earthquakes on the
plate boundary faults are much better known, although the exact Loma Blanca fault generally occurred at regular intervals,
nature of their earthquake recurrence distributions remains rather than aperiodically as previously hypothesized for faults
much debated (5, 6). At the heart of this debate lies a funda- in similar tectonic environments. However, periodic earth-
mental question: Are seismogenic faults ever controlled by a quake slip was interrupted by a relatively brief interval of in-
stress-renewal process that can be approximated by elastic re- creased earthquake frequency. Stable isotope data indicative
of rapid CO2 degassing suggest this interval was associated
bound theory? The latter states that stress buildup will be ac-
with elevated pore-fluid pressure. The Loma Blanca fault thus
commodated elastically until shear stress on the fault reaches a
provides a record of naturally induced seismicity during
threshold value that will allow failure.
which fault-valve behavior is inferred to have reduced earth-
If seismogenic faults are governed by a renewal process, then
quake recurrence intervals.
elastic rebound theory predicts that earthquakes will be pro-
duced quasiperiodically (7) (i.e., occur at regular intervals and Author contributions: R.T.W. designed research; R.T.W., L.B.G., and P.S.M. performed research;
therefore be time-dependent) with steady tectonic loading. R.T.W. and W.D.S. contributed new reagents/analytic tools; R.T.W., L.B.G., W.D.S., and
However, an alternative view posits that spatial and temporal P.S.M. analyzed data; and R.T.W., L.B.G., W.D.S., and P.S.M. wrote the paper.
variations in fault strength and/or mechanical interactions be- The authors declare no conflict of interest.
tween adjacent faults can lead to either a random or a clustered This article is a PNAS Direct Submission.
distribution of seismic events for a given fault (813). This view has 1
To whom correspondence should be addressed. Email: rtwilliams@wisc.edu.
led to greater use of time-independent and clustered earth- This article contains supporting information online at www.pnas.org/lookup/suppl/doi:10.
quake recurrence models. Although an increasingly large body of 1073/pnas.1617945114/-/DCSupplemental.

www.pnas.org/cgi/doi/10.1073/pnas.1617945114 PNAS Early Edition | 1 of 6


collapse at depth, also driving the upward migration of fluids (25,
Rio Salado 28). Although the exact mechanism responsible for fluid migration
and vein formation in the Loma Blanca fault zone remains un-
known, previous research has shown that fluids precipitating cal-
cite cements in this and other basin-margin faults of the Rio
New Grande rift likely originated from several kilometers beneath the
Mexico current exposures (29). Because postseismic fluid flow has been
Tsp shown to begin as little as a few days after normal fault rupture
(25), the timing of calcite precipitation is a reasonable proxy for
the timing of individual earthquakes.
The timing of vein precipitation can be accurately determined
using U-Th geochronology if the calcite (i) has favorable U and
Loma B

common Th (232Th) concentrations and (ii) formed in the past


600,000 years. We used this approach to determine the ages of
the first calcite deposited at the base of each distinct generation
lanc

of calcite in veins to constrain the timing of coseismic fracture


Qss openinga proxy for the timing of seismic failure (Fig. 2). By
a Fault

constraining the timing of individual earthquakes, we can cal-


culate recurrence intervals between successive earthquakes. Vein
samples obtained from the South Fracture Zone of the Loma
Blanca fault (Fig. 1) had undergone previous microstructural and
QTsa stable isotope analyses (20). We resampled these veins for U-Th
geochronology using the scheme shown in Fig. 2B. In rare cases
where samples of different veins showed temporal overlap within
Loma Pelada F

analytical uncertainty, stable isotope values were compared.


Qsa Ages were considered distinct if carbon or oxygen isotope (13C
and 18O) values differed by >1.5 or if the samples were
collected from two distinct generations of crack-seal calcite from
South the same vein. Otherwise, veins of overlapping age were inferred
Fracture Zone to have formed at the same time and an error-weighted mean
au

Arro

age was calculated.


lt

10656
yo

Tpl Ch Qac Results


ant
e 0.5 km U-Th dates for 20 samples of calcite (including replicates of
selected samples) from veins in the Loma Blanca fault zone
3416
document 13 distinct earthquakes since 550 ka (Fig. 3A). Four
Fig. 1. Simplified geologic map of an exhumed section of the Loma Blanca of these events define a pronounced cluster recording increased
fault overlain on satellite imagery (map data: Google, Landsat/Copernicus). earthquake frequency at 430 ka. Two of the veins formed
Fault is dashed where inferred. (Inset) Location of detailed map in New during the earthquake cluster exhibit markedly higher 13C values
Mexico. Geologic units: Qac (yellow), Quaternary alluvium; QSa (brown), relative to older and younger veins (Fig. 3C). These high 13C
Quaternary unit A; Qss (uncolored), stabilized Holocene deposits; QTsa values are consistent with rapid, postseismic fluid flow and
(blue), axial stream deposits; Tpl (gray), Popotosa Formation; Tsp (green), degassing of CO2-rich fluids (22). We calculate a long-term re-
piedmont slope and alluvial fan deposits. The box outlines the South Frac-
currence interval for background earthquake activity of 40 7 ka
ture Zone of ref. 20, within which dated veins were collected. Geologic data
are from ref. 19.
over the 390- to 150-ka period and a shorter recurrence interval
of 511 ka for the earthquake cluster near 430 ka. Because ages
of events associated with the cluster cannot be distinguished
multiple generations of calcite cement (Fig. 2). Both vein density within analytical uncertainty, the range given represents the ap-
and cumulative aperture increase with proximity to the relay. parent recurrence interval and also a maximum possible re-
The dominant vein set is perpendicular to the minimum stress currence interval that incorporates the uncertainties of the oldest
shown by numerical modeling to develop in relay zones during and youngest events in the cluster. To further evaluate the validity
failure (24). Collectively, the distribution, orientation, and mi- of the long-term recurrence interval calculated for the period
from 390150 ka, we calculated a recurrence interval for the
crostructure of the veins suggest they record failure in response
entire record using the average age of events in the earthquake
to coseismic fluid overpressure during dynamic rupture across
cluster (Fig. 3B). The latter recurrence interval is 46 6 ka,
the relay (Fig. 2A) (20). Vein sealing thus records precipitation
within error of the recurrence interval calculated for the period
of calcite during postseismic fluid migration. from 390150 ka.
Postseismic fluid flow along faults is a well-documented phe- To provide a quantitative measure of periodicity, we calculated
nomenon (25). This effect appears to be most pronounced in the coefficient of variation (COV) for the long-term recurrence
seismogenic normal faults like the Loma Blanca, in which docu- interval from 390150 ka as well as for the entire dataset using
mented postseismic fluid discharge volumes are up to 10 times the average age of the clustered events. Perfectly periodic
those resulting from similarly sized earthquakes on strike-slip or earthquakes would yield a COV of 0, whereas random or clus-
reverse faults (25). Several conceptual models have been proposed tered earthquakes would yield values of 1 and >1, respectively
to explain postseismic fluid migration from depth along normal (9). The COVs calculated for the period of 390150 ka and for
faults. For example, where faults transect overpressured reser- the entire record (using the average age of cluster events) are
voirs, coseismic increases in fault permeability may provide a 0.43 and 0.40, respectively, indicating quasiperiodic earthquake
mechanism for pressure release via the upward migration of fluids activity. The measured recurrence intervals therefore support a
(26, 27). Alternatively, postseismic increases in the least com- time-dependent model of earthquake recurrence for the Loma
pressive horizontal stress around normal faults may promote pore Blanca fault.

2 of 6 | www.pnas.org/cgi/doi/10.1073/pnas.1617945114 Williams et al.


A C Coseismic Opening

Fluid
Infiltration
Post-Seismic Sealing
2

F1 F1
Crystal Growth From Fracture Walls
B Coseismic Reopening
Generation Two
Generation One F2
Fluid
Fracture Infiltration
Opening / Sealing
on
Increments Post-Seismic Resealing
Directi

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EARTH, ATMOSPHERIC,
Growth

F1 F1 F2 F2 F1
5 mm
Fig. 2. (A) Outcrop photo of cross-cutting relationship between two largely sealed calcite veins in the hanging wall damage zone. Numbers denote order of
formation of cross-cutting veins. Open and closed arrows show open and sealed sections of the vein, respectively. Arrow head on card is 5 cm long. Photo
from ref. 20. (B) Plane light photomicrograph showing composite calcite vein with two generations of cement. Dashed line highlights boundary between
cement generations and arrows show the inferred calcite growth direction. Each generation of calcite cement corresponds to a distinct earthquake event as
shown in C. Subsamples were collected from the base of each generation of calcite (F1 and F2) for U-Th analyses. A and B are modified from ref. 20. (C)
Schematic illustration of spatial and temporal relationships between fault slip, fracture opening, and sealing recorded in calcite veins. F1 and F2 denote the
earliest cements precipitated following successive fault slip events, and therefore record the approximate timing of coseismic fracture opening.

We note that the age of event 13 represents the error-weighted combining distinct events where U-Th ages and stable isotope
mean of two distinct veins, whose carbon isotope values differed by compositions are similar. Any of these scenarios would lead to
values near our threshold of >1.5. If treated as distinct events, errors in earthquake recurrence intervals and COV calculated
the recurrence intervals for the period from 390150 ka and for from our U-Th data.
the entire record (using the average age of cluster events) become To evaluate our interpretation that earthquake recurrence was
34 8 ka and 41 7 ka, respectively, within error of our original largely time-dependent in light of the fact that we might have
estimates. The COVs then become 0.59 and 0.52, respectively. missed events, we constructed simple Monte Carlo simulations
to test the hypothesis that our calculated COV reflects incom-
Discussion plete, random sampling of a record of time-independent (COV =
Sources of Uncertainty. Our analysis assumes that the dated calcite 1) or clustered (COV > 1) earthquake recurrence (Methods).
veins were formed in response to seismic fault slip. It is, however, These simulations allow us to conclude at the 95% confidence
conceivable that damage zone fracturing was slip related but level that the time-dependent COVs calculated from the Loma
subsequent calcite precipitation was controlled by other factors, Blanca earthquake record cannot result from random sampling of
such as climatic variations associated with glacial cycling. We a time-independent or clustered record (Fig. 4). This result holds
have tested this hypothesis by comparing our U-Th dates with even if the two ages comprised by our event 13 are treated as
the Devils Hole climate record, which provides a continuous distinct events, albeit at the 90% confidence level for the interval
from 390150 ka. In summary, although we cannot be certain
record of glacial cycling over the last 500 ka (30). This com-
how missing events may alter the absolute value of the COV
parison shows no correlation between the timing of vein for-
calculated for the Loma Blanca fault, we can conclude based on
mation and glacial/interglacial cycles. This result is consistent
the apparent COV that the underlying recurrence on the fault was
with previous work showing that calcite in the Loma Blanca fault time-dependent. Even if only the largest earthquakes on the Loma
zone was controlled by upward migrating, endogenic fluids rather Blanca fault were recorded by veins, then those largest earth-
than shallow, meteorically derived fluids (20, 29). quakes must have occurred quasiperiodically through time.
Uncertainty in our quantification of the Loma Blanca record
arises from the fact that we could not sample all of the numerous Implications for the Seismic Cycle of Intraplate Faults. The pro-
veins in the damage zone. As we have no means of estimating nounced cluster of earthquakes at 430 ka shows that long-term
exactly how many events are recorded in the fault zone, it is periodic (time-dependent) fault failure may be interrupted by
possible that some were not sampled. It is also possible that only transient increases in earthquake frequency of nearly 1 order of
seismic events above a particular magnitude resulted in damage magnitude (Fig. 3B). Moreover, the average age of the clustered
zone fracturing and vein formation, such that not all events were events fits in the long-term earthquake history of the Loma
recorded. Finally, missing events may result from erroneously Blanca fault, indicating that such substantial increases in the rate of

Williams et al. PNAS Early Edition | 3 of 6


A earthquake recurrence intervals on some plate-boundary faults
14 Recurrence Interval ~40 7 ka (1417). However, other plate-boundary faults exhibit random
12 COV = 0.43 or clustered earthquakes over time scales of thousands of years
(813). Previous work has hypothesized that a continuum of
Event Number

10 earthquake recurrence behavior may exist, with quasiperiodic


behavior exhibited by high slip rate, isolated structures with
8
simple geometries and aperiodic behavior characteristic of low
6 Recurrence Interval slip rate, networked fault systems with complex geometries (15).
~5-11 ka An appealing aspect of this interpretation is that it would allow
4 appropriate statistical models of earthquake recurrence to be
2 Paleoseismic Record applied to individual faults based on their geometry and geologic
Seismic Record setting in the absence of robust paleoseismic records. However,
0 our results do not support this conceptual model. As a low slip-
100 200 300 400 500 600 rate fault that is just one of many locally linked and commonly
B 12
segmented structures (19), the Loma Blanca should, per this
model, exhibit aperiodic failure. However, it records periodic
Recurrence Interval ~46 6 ka
10 seismicity over most of the 400 ka we can constrain.
COV = 0.40
Event Number

In the absence of changes in regional strain rates, variations in


8 Loma Blanca earthquake frequency must fundamentally reflect
changes in processes driving fault slip. It is likely that the ca.
6 40 ka periodicity of the long-term Loma Blanca record repre-
Cluster sents a background rate of failure during intraplate extension, as
4 similar rates have been documented for other normal faults in
the Rio Grande rift (31, 32). The dominantly time-dependent
2 nature of our earthquake chronology suggests that this back-
ground fault rupture was driven principally by a stress-renewal
0
100 200 300 400 500 600 process. The interruption of this time-dependent series by clus-
tered seismicity near 430 ka therefore must record a change in
C 5 the process driving failure. Stable isotope evidence of rapid CO2
4 degassing during postseismic fluid flow and vein precipitation
suggests that the clustered earthquakes occurred during an in-
3
13C (VPDB)

terval of anomalous fluid source. We infer that the pronounced


2 increase in earthquake frequency recorded by these veins reflects
1 a source that increased both CO2 concentration and pore-fluid
0
-1
1
-2
-3
0.9
-4 Fail to reject hypothesis
100 200 300 400 500 600
that underlying recurrence is
Age (ka) 0.8
time-independent
Critical COV Threshold

Fig. 3. Results of U-Th and 13C analyses of calcite veins. (A) Earthquake age
0.7
versus relative position within the total earthquake sequence record. Lines in
the lower left of the graph show the length of the seismic instrument record Reject hypothesis that
and the length of previous paleoseismic studies. Error bars represent 95% 0.6 underlying recurrence is
(2) confidence intervals. Error bars are not shown where uncertainties are
time-independent
less than symbol size. Trend lines show linear regression analyses of the
plotted age ranges where slope is proportional to earthquake frequency. 0.5
The COV provides an estimate of earthquake periodicity (0, perfectly peri-
odic; 1, random). The gray box shows the time interval associated with time span from
0.4 ~390 - 150 ka complete record using
clustered seismicity on the Loma Blanca fault. (B) Similar to A but showing a
average cluster age
mean age calculated from the clustered events. (C) Vein 13C [Vienna Peedee
belemnite standard (VPDB)] is shown as a function of calcite age. Uncer-
0.3
tainties in 13C analysis are less than 0.1. Two dated veins were destroyed 6 7 8 9 10 11 12 13 14 15
during sample collection before 13C analyses could be conducted. Carbon Number of Samples
isotope data were sourced in part from ref. 22.
Fig. 4. Results of Monte Carlo simulation testing the hypothesis that the
COVs calculated from our U-Th data are the result of incomplete, random
seismicity can occur within the expected interseismic period of an sampling of a time-independent (i.e., random) earthquake record. For any
otherwise time-dependent cycle (Fig. 3B). We note that clusters COV (vertical axis) calculated from a particular sample size (horizontal axis),
previously documented on plate-bounding faults are generally points falling outside the shaded area allow rejection of the null hypothesis
that a calculated COV could be the result of random sampling of a time-
separated by pronounced periods of quiescence (812). In contrast,
independent record at the 95% confidence level. Because the COVs calcu-
our results show that an earthquake cluster may be an anomaly in lated from our U-Th data plot outside of the shaded region, we reject the
an otherwise quasiperiodic record, at least on intraplate faults. hypothesis that the underlying earthquake recurrence behavior of the Loma
The time-dependent nature of the Loma Blanca earthquakes Blanca fault was time-independent. See SI Appendix for model source code
is consistent with recent work that documents quasiperiodic and results of the clustered recurrence test.

4 of 6 | www.pnas.org/cgi/doi/10.1073/pnas.1617945114 Williams et al.


volume, and thereby pressure, at depth. This inferred increase in Sample measurements incorporated within-run mass bias corrections using
pore-fluid pressure is interpreted to have decreased effective the known 233U/236U ratio of the spike. Faraday amplifier gains were cali-
fault strength, leading to more frequent seismic rupture, con- brated weekly using the Neptunes constant current source and switching
system. Ion counter yields (relative to Faraday collectors) were determined
sistent with fault-valve behavior (26).
during each sample measurement by cycling 229Th and 233U signals between
The geometry of normal faults and the associated stress field the ion counter and the L1 Faraday collector. Peak tails were monitored at
makes it difficult to sustain large fluid overpressures over long seven half-mass positions from m/e = 229.5241.5 while aspirating sample
time scales (27). However, previous work has shown that fault- solutions, the sum of tails from all peaks was modeled at each U and Th mass
valve behavior can occur in extensional settings where basin position, and the result subtracted from the measured intensities. Measured
stratigraphy includes low-permeability horizons at depth, as is peak heights were corrected for Faraday baselines/ion counter dark noise,
the case in the Socorro Basin beneath the Loma Blanca fault instrumental backgrounds, Faraday gains, ion counter yields, mass frac-
(33). We hypothesize that the inferred increase in CO2 content tionation, peak-tails, procedural blanks, and interfering spike isotopes.
of pore fluids may record input of volatiles exsolved from rift- Activity ratios and ages were calculated using the half-lives of ref. 36 for 238U,
ref. 37 for 232Th, and ref. 38 for 230Th and 234U. Correction for U and Th from
related magma. Such volatiles could be trapped where the fault
detritus was made assuming detritus with activity ratios of (232Th/238U) = 1.2
transects low-permeability sediment. We note that there is con- 0.5, (230Th/238U) = 1.0 0.1, and (234U/238U) = 1.0 0.1. Errors for corrected ages
siderable evidence suggesting that overpressured CO2-rich fluids are 2 and include contributions from measurement errors and the assigned
may have been responsible for modern normal-fault ruptures in uncertainties in detritus composition but not decay constant error.
the Apennines (27). In the case of the Loma Blanca fault, we
speculate that such volatiles may have been released during Monte Carlo Simulation. We used a Monte Carlo simulation (MATLAB source
crystallization of an early (and previously unrecognized) phase of code included in SI Appendix) to test the hypothesis that the periodic distri-
the currently active Socorro magma body, which lies beneath the bution of earthquakes we have documented does not reflect time-dependent
study area (34). seismicity, but instead was produced by random sampling of either a random
Our longer earthquake chronology indicates that the inferred (i.e., time-independent) or clustered earthquake distribution. Our model takes
as input an assumed mean earthquake recurrence interval and a COV, from
period of fault-valve behavior was a transient episode in the

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EARTH, ATMOSPHERIC,
which it randomly generates 10,000 synthetic earthquake records fitting these
Loma Blanca fault history. Although our record contains only parameters. We tested the above hypothesis by randomly sampling each
two events older than the earthquake cluster, the interval be- synthetic earthquake record to assess the variability of the calculated COVs for
tween them is consistent with those observed in the younger a range of sample sizes. For example, incomplete, random sampling of a time-
record of periodic recurrence. For this reason, and because the independent earthquake record with a COV = 1 would frequently produce
long-term periodicity of earthquakes on the Loma Blanca fault is apparent COVs that are either greater or less than one. In essence, our model
similar to that of other normal faults in the Rio Grande rift, we determines the lowest (more time-dependent in appearance) COV that is likely
conclude that failure on the Loma Blanca fault was driven by a to be produced through random sampling of a time-independent or clustered
stress-renewal process for most of the recorded history. We in- earthquake distribution.
terpret the seismic cluster as a record of enhanced seismicity We used this approach to assess the variability of COVs calculated from
random samples of synthetic time-independent and clustered recurrence
caused by naturally elevated pore-fluid pressure, which drove
records. The model assumes a mean recurrence interval of 40 ka, COVs of
fault failure for a relatively short period. 1 and 1.5 for time-independent and clustered tests, respectively, and a record
of 15 earthquakes. To evaluate each sample size (we tested 615), 10,000
Methods synthetic earthquake records were randomly sampled and the COV of the
Geochemical Methodology. apparent interseismic periods in each subsample was calculated and stored.
Powder sampling. Powders were collected from vein samples that were pol- Sensitivity analyses demonstrate that model results are not affected by vari-
ished flat in a plane perpendicular to the fracture wall. A variable speed drill ations in either the assumed mean recurrence interval or the total number of
with a carbide bit (head diameter: 100 m) was used to collect 30 mg of synthetic earthquakes in each record (SI Appendix, Fig. S1).
sample powder in a fracture-wall-parallel trench at the base of each gen- We define a critical COV threshold as the fifth percentile of the 10,000
eration of cement. Sample trenches were kept 0.51 mm from the fracture calculated COVs from each model run of a given sample size. Thus, if the
wall to avoid contamination from sandstone calcite cements. Following each critical COV threshold for a given sample size is greater than that calculated
drill pass, sample powders were collected with a hypodermic needle and using our U-Th dates for the same sample size, we can reject (at the 95%
placed into static-free sample vials. All sample collection tools were thor- confidence level) the null hypothesis that the latter COV could result from
oughly rinsed with ethanol and dried between samples. random sampling of a time-independent or clustered record. In the main
U-Th analytical methods. Analyses were carried out at the Berkeley Geo- text, we consider the COV of both the time period from 390150 ka and
chronology Center. Samples were totally dissolved in 7 M HNO3 and equili- the entire Loma Blanca record using the average age of the clustered events.
brated with a mixed spike containing 229Th, 233U, and 236U. The spike was For the time-independent test, these COVs (0.43 and 0.40, respectively) are
calibrated using New Brunswick National Lab CRM145 uranium solution and both less than the critical COV thresholds (0.54 and 0.68, respectively) for the
solutions prepared from a 69-Ma U ore from Schwartzwalder Mine, Colo- same sample sizes, allowing us to reject the null hypothesis that COVs cal-
rado, United States, that has been demonstrated to yield concordant U-Pb culated using our U-Th dates could be the result of random sampling of a
ages (35) and sample-to-sample agreement of 234U/238U and 230Th/238U ra- time-independent record (Fig. 4). Similarly, the clustered recurrence test
tios. U and Th were separated from sample matrix using two stages of yields critical COV thresholds of 0.69 and 0.88 for sample sizes of 7 and 10,
HNO3HCl cation exchange chemistry followed by reaction with HNO3 and respectively, which also allows us to reject the hypothesis that our calculated
HClO4 to remove any residual organic material. Procedural backgrounds for COVs could result from random sampling of a clustered record (SI Appendix,
U and Th were measured with each batch of samples and corrections for Fig. S2).
background 230Th were applied. Procedural backgrounds for 238U, 234U, and
232
Th were negligible relative to sample amounts.
ACKNOWLEDGMENTS. We thank Christine Gopon for assistance with field
Analyses were performed using a Thermo-Fisher NEPTUNE Plus multi- work and Brian Goodman for statistical advice. We are grateful to the
collector inductively coupled plasma mass spectrometer. Purified U and Th Sevilleta National Wildlife Refuge for access to study sites. We also thank
fractions were analyzed simultaneously. Analyses were carried out in auto- two anonymous reviewers for providing constructive reviews of the
mated sequences, with each analysis consisting of a preanalysis washout, an manuscript, which greatly improved its quality. This work was supported
instrumental background measurement, a sample measurement, and a by grants from the Geological Society of America, the American Association
measurement of peak-tails. All measurements are normalized to simulta- of Petroleum Geologists, and the GDL Foundation (to R.T.W.) and a grant
neous measurements of 238U to cancel intensity fluctuations. Instrumental from the Wisconsin Alumni Research Fund (to L.B.G.). Acknowledgment is
made to the donors of the American Chemical Society Petroleum Research
backgrounds at each U and Th mass, along with Faraday collector baselines
Fund for partial support of this research. Partial support of this work was
and ion counter dark noise, were measured while aspirating the same dilute provided by National Science Foundation Grants EAR-1358514, EAR-
HNO3HF solution used to introduce samples. Sample measurements were 1358554, EAR-1358401, EAR-1358443, and EAR-1101100 (EarthScope Na-
carried out in peak-jumping mode with all masses measured on Faraday tional Office). We thank the EarthScope Awards for Geochronology Student
collectors except 230Th and 234U, which were measured with an ion counter. Research Program for its support.

Williams et al. PNAS Early Edition | 5 of 6


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