Chuyên đề Hoá Hữu cơ - Lớp 11 chuyên Hoá - Trường THPT chuyên Lê Quý Đôn PDF

Chuyn Ho Hu c - Lp 11 chuyn Ho - Trng THPT chuyn L Qu n
LI M U
Phng php trc nghim khch quan l mt hnh thc kim tra c s dng rng ri nhiu
nc trn th gii. y l mt phng php o lng kin thc ton din. Vi h thng cu hi vi
nhiu la chn, phng php ny loi b c tnh trng hc t, hc lch, quay cp s dng ti liu
trong lc thi c, trnh c tiu cc trong vic coi thi, chm thi.
Tuy nhin, i a s hc sinh chng ta vn cha quen vi cch lm bi thi trc nghim, vn cha
c cch gii nhanh gn mt bi ton ho hc trong khi thi gian lm mt bi thi qu ngn.
gip cc bn nm vng phng php gii ton, cho php gii nhanh chng cc bi ton phc
tp, chng ti xin gii thiu vi cc bn " Mt s phng php gii nhanh cc bi ton ho hc hu c
" m chng ti trch lu c trong qu trnh hc.
BAN BIN TP - 11 HO
http://ebook.top1.vn Ti liu chia s trn mng

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MT S PHNG PHP GII NHANH

Phng php 1: NH LUT BO TON
Nguyn tc : S dng nh lut bo ton vt cht tnh khi lng cc cht.
I/ Phng php bo ton khi lng
1. C s : nh lut bo ton khi lng
Trong phn ng ho hc, tng khi lng cc cht tham gia phn ng bng tng cc khi lng
cc cht to thnh.
Phn ng ho hc : A + B C + D
mA + mB = mC + mD
2. Phm vi p dng : p dng cho tt c cc trng hp cn tnh khi lng ca mt cht m c th
bit hoc bit c khi lng cc cht cn li.
3. V d minh ho :
VD1 : Cho 2,83 g hn hp 2 ru 2 chc tc dng va vi Na th thot ra 0,896 lit H2 (ktc) v m g
mui khan. Gi tr m (g) l :
A. 5,49 B. 4,95 C. 5,94 D. 4,59
Gii :
+) Cch gii thng thng :
Gi CT ca ru th nht l : R(OH)2 ( a mol )
ru th hai l : R'(OH)2 ( b mol )
PTP : R(OH)2 + 2Na R(ONa)2 + H2
(mol) a a a
R'(OH)2 + 2Na R'(ONa)2 + H2
(mol) b b b
Theo gi thit ta c : (R+34)a + (R'+34)b = 2,83
v a + b = 0,04
Ra + R'b = 2,83 - 34(a+b) = 1,47
Khi lng mui to thnh l : m = (R+78)a + (R'+78)b = Ra + R'b + 78(a+B)
= 4,59 (g)
+) Cch gii nhanh :
Gi CT chung ca 2 ru l : R(OH)2
R(OH)2 + 2 Na R(ONa)2 +H2
0,08 0,04
p dng nh lut bo ton khi lng ta c :
m = 2,83 + 0,08.23 - 0,04.2 = 4,59 (g)
VD2 : Cho 4,2 g hn hp gm CH3OH, C6H5OH v CH3COOH tc dng vi Na va thy thot ra
0,672 lit H2 (ktc) v 1 dung dch X. C cn dung dch X ta thu c cht rn Y. Khi lng (g) Y l :
A. 2,55 B. 5,52 C. 5,25 D. 5,05
Gii : Do c 3 cht trn u cha 1 nguyn t H linh ng nn :
0,672
nNa= 2nH2 = 2. =0,06 mol
22,4
p dng nh lut bo ton khi lng ta c :

mY = 4,2 + 0,06.23 - 0,03.2 = 5,52 (g)

II/ Phng php bo ton nguyn t
1.C s : nh lut bo ton nguyn t
Tng khi lng ca mt nguyn t trc phn ng bng tng khi lng ca nguyn t
sau phn ng.
2. Phm vi ng dng: C th p dng trong nhiu trng hp, nhng thng dng nht trong cc bi
ton t chy.
3. V d minh ho :
VD1 : t chy hon ton m g hn hp cc hirocacbon : C3H4, C2H6, C4H8 th thu c 12,98g CO2
v 5,76g H2O. Vy m (g) c gi tr :
A. 1,48 B. 8,14 C. 4,18 D. Khng xc nh
Gii :
+) Cch gii thng thng :
C2H6 + 7/2 O2 2CO2 + 3H2O
(mol) x 3,5x 2x 3x
C3H4 + 4O2 3CO2 + 2H2O
(mol) y 4y 3y 2y
C4H8 + 6O2 4CO2 + 4H2O
(mol) z 6z 4z 4z
Theo PTP v bi ta c h:
2x + 3y +4z = 12,98 : 44 = 0,295
3x + 2y + 4z =5,76 : 18 = 0,32
30x + 40y + 56 z + 32( 3,5x + 4y + 6z) = 12,98 + 5,76
Gii h phng trnh ta c : x = 0,05 ; y = 0,025 ; z = 0,03
Khi lng hn hp l : m = 0,05.30 + 0,025.40 + 0,03.56 = 4,18 (g)
+) Cch gii nhanh : p dng nh lut bo ton nguyn t :
5,76 12,98
mY = mC + mH = .2 + .12 =4,18g
18 44
VD2 : Tch nc hon ton t hn hp Y gm ru A, B ta c hn hp X gm cc olefin. Nu t
chy hon ton Y th thu c 0,66g CO2. Khi t chy hon ton X th tng khi lng CO2 v H2O
(g) l :
A. 0,903 B. 0,39 C. 0,94 D. 0,93
Gii : Y tch nc to thnh X :
nC(X) =nC(Y) nCO2(X)=nCO2(Y)=0,66/44 =0,015 mol
M khi t chy X th nCO2 = nH2O = 0,015 (mol)

Tng khi lng CO2 v H2O l : m = 0,66 + 0,015.18 = 0,93(g)

Phng php 2 : QUY I NHIU CHT THNH MT CHT
Nguyn tc : a hn hp cc cht v mt cht c cng thc trung bnh sau da vo gi tr
trung bnh va tm c kt lun v cht cn xc nh.
I/ Phng php khi lng mol trung bnh M
m
1. C s : S dng cng thc : M = hh
nhh
ri sau dng M xc nh M ca cc cht ban u M1< M < M2 vi M1 < M2.
2. Phm vi ng dng : p dng rng ri cho cc bi tp ho hu c
3. V d minh ho :
VD1 : Hn hp A gm 2 ankanal X, Y c tng s mol l 0,25mol. Khi cho hn hp A tc dng vi
dung dch AgNO3/NH3 d th to ra 86,4g kt ta v khi lng dung dch AgNO3 gim 77,5g. Bit
Mx<My . CTCT ca X l :
A. CH3CHO B. HCHO C. C2H5CHO D. Kt qa khc
Gii : V khi lng Ag tch ra l 86,4g m khi lng dung dch gim 77,5g nn
Khi lng 2 anehit l : 86,4 - 77,5 = 8,9 (g)
8,9
M= = 35,6( g / mol ) m MX < M < My MX < 35,6 MX = 30. X l HCHO.
0,25
VD2 : Mt hn hp X gm 2 ankin l ng ng k tip nhau. Nu cho 5,6 lit hn hp X i qua dung
dch Br2 th thy khi lng bnh tng 8,6g. CTPT ca 2 ankin :
A. C3H4 , C4H6 B. C4H6 , C5H8 C. C2H2 , C3H4 D. Kt qu khc
Gii : Theo ra ta c : mankin = 8,6 g .
5,6
S mol ca ankin l : nankin = = 0,25(mol )
22,4
8,6
Khi lng phn t trung bnh ca 2 ankin l : M = = 34,4( g / mol )
0,25
M1 < 34,4 < M2 vi 2 ankin k tip
M1 = 26 v M2 = 40 . CTPT ca 2 ankin l : C2H2 v C3H4
II/ Phng php s nguyn t cacbon trung bnh n
1. C s : t CT ca cc cht cng thuc mt dy ng ng di dng CT chung ca dy nhng thay
n bng n .Sau tnh n v kt lun v s nguyn t C ca cc cht : n1 < n < n2.
2. Pham vi ng dng : Dng gii cc bi ton v cc cht thuc cng mt dy ng ng c bit l
cc cht ng ng lin tip.
3. V d minh ho :
VD1: C 2 axit hu c no : A l axit n chc v B l axit a chc. Hn hp X cha 0,3 mol hn hp
A v B. t chy hon ton X th thu c 11,2 lit CO2(kc) Vy CTPT ca A l :
A. CH3COOH B. HCOOH C. C2H5COOH D. Kt qu khc
Gii : S nguyn t C trung bnh ca A v B l :
0,5
n= 1,667 S nguyn t C ca A < 1,667
0,3
S nguyn t C ca A = 1 A l HCOOH
VD2 : t chy hon ton hn hp 2 hirocacbon ng ng c khi lng phn t hn km nhau
28vC ta thu c 4,48 lit CO2 (kc) v 5,4g H2O. CTPT ca 2 hp cht l :
A. C3H4 , C5H8 B. C2H4 , C4H8 C. CH4 , C3H8 D. C2H2 , C4H6
4,48 5,4
Gii : nCO2 = = 0,2(mol ) nH 2O = = 0,3(mol )
22,4 18
Do nH2O > nCO2 nn hirocacbon l ankan.
Gi CT chung ca 2 ankan l : Cn H 2 n+ 2
3n + 1
Cn H 2 n+ 2 + O2 nCO2 + (n + 1) H 2O
2
0,2 0,3
n 0 ,2
= n = 2 Vy n1 = 1 v n2 = 3. CT ca 2 hirocacbon l CH4 v C3H8.
n +1 0 ,3
III/ Phng php gc hirocacbon trung bnh : R
1. C s : t CT ca cc hp cht cn tm di dng cng thc c cha R . Sau tin hnh xc nh
gc R . Bin lun R1 ,R2 theo : R1 < R < R2
2. Phm vi ng dng : Thng dng cho bi ton v R cha nhm chc, c bit l axit, este.
3. V d minh ho :
VD1 : Hn hp X gm 2 este A, B ng phn vi nhau v u to ra t axit n chc v ru n
chc. Cho 2,2g hn hp X bay hi 136,5oC v 1atm th thu c 840ml hi este. Mt khc, em thu
phn hon ton 26,4g hn hp X bng 100ml dung dch NaOH 20% (d=1,2g/ml) ri em c cn th thu
c 33,8g cht rn khan. Vy CTPT ca este l :
A. C2H4O2 B. C3H6O2 C. C4H8O2 D. C5H10O2
Gii : A, B l este n chc.
0,84
nX = = 0,025(mol )
0,082(273 + 136,5)
2,2
M este = = 88( g / mol )
0,025
neste thu phn = 26,4 : 88 = 0,3 (mol)
100.20.1,2
nNaOH = = 0,6(mol ) NaOH d
100.40
mmui = 33,8 - (0,6-0,3).40 = 21,8 (g)
21,8
M muoi = 72,66 = R + 68 R = 5,66 R1 < 5,66 < R2 R1 = 1
0,3
R1 ng vi -H m R1 + 44 + R1' = 88 R1' = 43 ng vi C3H7-

CTPT ca este l : HCOOC3H7 hay C4H8O2
VD2 : Cho 3,55 g hn hp cc amin n chc tc dng va 0,1 mol HCl. Xc nh CT ca amin c
phn t khi b nht.
A. CH3NH2 B. C2H5NH2 C. CH3NHCH3 D. Kt qu khc
Gii : Gi CT chung l : RNH 2
RNH 2 + HCl RNH 3Cl
3,55
M RNH 2 = = 35,5 R = 19,5 R1 < R = 19,5 R1 = 15
0,1
R1 ng vi CH3-
Ngoi ra phng php trung bnh cn c m rng tnh ton cho c hn hp cc cht
thuc dy ng ng khc nhau, tnh s lin kt trung bnh, ho tr trung bnh ...

Phng php 3 : QUY I MT CHT THNH NHIU CHT
Nguyn tc : Chuyn cht cn xc nh thnh 2 hay nhiu cht xc nh c, ri sau vit
phng trnh phn ng bnh thng, xc nh yu t cn tm...
V d :
VD1 : Khi t chy hon ton mt polime X (to thnh do ng trng hp 2,3-imetyl butaien v
acrilo nitrin CH2=CH-CN) vi lng O2 va thy to thnh mt hn hp kh nng p sut xc
nh cha 57,69% CO2 v V. T l 2 loi monome l
A. 3/5 B. 3/3 C. 1/3 D. 3/2
Gii :
+) Cch 1: Tch polime thnh 2 monome ban u :
17
P chy : C6 H 10 + O2 6CO2 + 5 H 2O
2
x 6x 5x
15 3 1
CH 2 = CH CN + O2 3CO2 + H 2O + N 2
4 2 2
y 3y 3/2y y/2
Ta c:
6 x + 3 y 57,69
= 600 x + 300 y = 634,59 x + 288,45 y
11x + 5 y 100
11,55 y = 34,59 x
:
y = 3x
x 1
=
y 3
+) Cch 2: Tch polime thnh cc nguyn t ri vit s chy :
(- CH2 - C(CH3) = C(CH3) - CH2 -)x(- CH2 - CH(CN) - )y
(6x + 3y) C (6x + 3y) CO2

(10x + 3y) H (5x + 3y/2) H2O
y N y/2 N2
%CO2 57,69 6x + 3y x 1
Do : = = =
100 100 3 y y y 3
6 x + 3 y + 5x + +
2 2

Phng php 4 : TNG GIM KHI LNG
Nguyn tc : Da vo tng gim khi lng khi chuyn t cht ny sang cht khc xc nh khi
lng mt hn hp hay mt cht.
C th :
- Da vo phng trnh tnh thay i khi lng khi 1 mol A 1 mol B
- Da vo s thay i khi lng trong bi tnh s mol ca A, B
- Dng s mol tnh cc phn ng khc.
Phm vi : Dng cho nhiu bi ton hu c nhng ch yu l cc hp cht c nhm chc axit, ru,
anehit, este, amino axit. C th :
i vi ru : Xt phn ng vi NaOH :
R(OH)x + xK R(OK)x + x/2 H2
Hay ROH + K ROK + H2
khi lng tng 39 - 1 = 38 g
i vi axit : Xt phn ng vi NaOH :
R(COOH)x + xNaOH R(COONa)x + xH2O
Hay RCOOH + NaOH RCOONa + H2O
khi lng tng 22 g
i vi anehit : Xt phn ng trng gng : RCHO+Ag2O RCOOH+ 2Ag
khi lng tng 16 g
i vi este : Phn ng x phng ho :
RCOOR' + NaOH RCOONa + R'OH
i vi amin : Xt phn ng vi HCl
RNH2 + HCl RNH3Cl
khi lng tng 36,5 g
V d minh ho :
VD1 : Cho 20,15 g hn hp 2 axit no n chc tc dng va vi dung dch Na2CO3 th thu c
V(l) CO2 v dung dch mui. C cn dung dch thu c 28,95 g mui. Gi tr V(l) ktc l :
A. 4,84 B. 4,48 C. 2,24 D. 2,42
Gii : Vn dng phng php tng gim khi lng :
Gi CTTQ trung bnh ca 2 axit l : RCOOH
PTP : 2 RCOOH + Na 2CO3 2 RCOONa + CO 2 + H 2O
Theo ptp ta c : 2 mol axit to ra 2 mui th c 1 mol CO2 bay ra v m tng 2.(23-1)=44 (g) .
8,8
Theo bi : mtng = 28,95 - 20,15 = 8,81 (g) nCO2 = = 0,2(mol ) VCO2 = 4,48l
44
VD2 : Khi thu phn hon ton 0,05 mol este ca 1 axit a chc vi 1 ru n chc tiu tn ht 5,6 g
KOH. Mt khc, khi thu phn 5,475g este th tiu tn ht 4,2g KOH v thu c 6,225g mui. Vy
CTCT ca este l :
A. (COOC2H5)2 B. (COOCH3)2 C. (COOC3H7)2 D. Kq khc
Gii : nKOH = 5,6 / 56 = 0,1 mol.
nKOH = 2neste este 2 chc to t axit 2 chc v ru n chc.
Gi CT este l : R(COOR')2
R(COOR')2 + 2KOH R(COOK)2 + 2R'OH
(mol) 1 2 1
(mol) 0,0375 0,075
mtng = 2 (39 - R') g
m tng = 6,225 - 5,475 = 0,75 g
0,0375 (78 - 2R') = 0,75
R' = 29 R' l C2H5 -
5,475
M este = = 146 R + (44 + 29).2 = 146 R = 0
0,0375
CT ng l : (COOC2H5)2

Phng php 5 : GII PHNG TRNH NGHIM NGUYN
Nguyn tc :
- Xc nh s mol ca cc cht sau a v dng phng trnh nghim nguyn
an1 + bn2 = c (a, b, c l h s nguyn; n1, n2 : s nguyn t C ca cc cht)
- Da vo iu kin tn ti ca cc cht kt lun v nghim
Phm vi : c p dng rng ri trong gii ton ho hc
V d minh ho :
VD1 : Mt hn hp gm 2 hirocacbon mch h. Cho 1,68 l hn hp i qua dung dch Br2 d th cn
li 1,12l kh v khi lng Br2 phn ng l 4g. Nu t chy 1,08g hn hp ri cho ton b sn phm
chy hp th vo dung dch Ca(OH)2 d th c 12,5g kt ta. CT ca 2 hirocacbon l :
A. C2H6 , C2H4 B. C3H6 , CH4 C. C3H6 , C2H6 D. C2H4 , CH4
Gii : nh/c ko no = (1,68-1,12)/22,4 = 0,025(mol)
nBr2 = 4/ 160 = 0,025 (mol) nh/c ko no = nBr2 h/c ko no l anken
nankan = 1,12 / 22,4 = 0,05 (mol).
Gi m, n ln lt l s nguyn t C trong ankan v anken (m 1, n 2). Trong qua trnh t chy th :
mC mCO2 nC nCO2
0,05m 0,05m 0,025n 0,025n
CO2 + Ca(OH)2 CaCO3 + H2O
(mol) 0,125 0,125
0,05m + 0,025n = 0,125 2m + n = 5 n khng chia ht cho 2
m n 2 v n < 5 n = 3 v m = 1. Vy 2 cht cn tm l : C3H6 v CH4
VD2 : Hn hp A gm mt hirocacbon no mch h v mt ankin c tng s mol l 0,3 mol. Khi cho
hn hp qua dung dch Br2 th thy lng Br2 phn ng l 32 gam, tng khi lng ca 0,15 mol hn
hp ban u l 4,3 gam. Xc nh cng thc phn t ca cc cht trong hn hp.
Gii: nBr2=32:160=0,2(mol)
Gi cng thc ca hai hirocacbon l CnH2n+2 v CmH2m-2
Phn ng vi Br2: CmH2m-2 +2Br2 CmH2m-2Br4
0,1 0,2
S mol ankan l: 0,3-0.1=0,2(mol)
Khi lng ca 0,3 mol hn hp l: 4,3.2=8,6 gam
Ta c phng trnh : (14n+2)0,2+(14m-2)0,1=8,6
2n+m=6
Gii phng trnh nghim nguyn ta c :n=2 m=2.
Vy cng thc ca 2 hidrocacbon l : C2H6 v C2H2

Phng php 6 : BIN LUN
Nguyn tc : Da vo mt s tnh cht c trng, da vo mt s lin kt bin lun suy ra CTCT
cht cn tm m khng cn phi lm ton phc tp.
Phm vi : Ch p dng trong mt s trng hp n gin hoc c bit, khng c tnh tng qut.
V d minh ho :
VD1 : Chia m g anehit thnh 2 phn bng nhau :
P1 : b t chy thu c nCO2 = nH2O
P2 : tc dng va vi AgNO3/NH3 d cho Ag vi t l nanehit : nAg = 1 : 4
Vy anehit no l :
A. Anehit fomic B. Anehit hai chc no
C. Anehit n chc no D. Khng xc nh c
Gii :
- T sn phm chy anehit c 1 lin kt c 1 nhm chc -CHO.
- T phn ng vi AgNO3/NH3 anehit l HCHO.
Ch :
Bin lun v s nhm chc :
- Chc anehit :
+ nu nanehit : nAg = 1 : 2 anehit n chc no
+ nu nanehit : nAg = 1 : 4 HCHO hoc anehit 2 chc
- Chc este :
+ nu neste : nNaOH = 1 : 1 este n chc
+ nu neste : nNaOH = 1 : 2 este n chc ca phenol hoc este 2 chc
- Chc ru :
+ nu nNa : nru = 1 : 1 ru n chc
+ nu nNa : nru = 2 : 1 ru 2 chc
- Chc amin :
+ nHCl : namin = 1 : 1 amin n chc
+ nHCl : namin = 2 : 1 amin 2 chc
- Chc axit :
+ nu nNaHCO3 : naxit = 1 : 1 axit n chc
+ nu nNaHCO3 : naxit = 2 : 1 axit 2 chc
Xc nh s lin kt : Khi t chy 1 hp cht m :
- nCO2 = nH2O c 1 lin kt
- nCO2 < nH2O khng c lin kt
- nCO2 > nH2O c nhiu hn 1 lin kt
VD2 : t chy 1,7 g este X cn 2,52 lit O2 (ktc) thu c CO2 v H2O trong nCO2 : nH2O = 2.
un nng 0,01 mol X vi dung dch NaOH th cn 0,02 mol. X cha chc este, khng phn ng vi
Na, khng kh Ag2O/NH3 . Xc nh CTPT X
Gii : Do nNaOH : neste = 2 : 1 c th l este ca phenol hoc este 2 chc .
Nhng theo p n th X ch c 2 nguyn t O ng vi 1 chc este
X l este n chc ca phenol X c s nguyn t C > 6.
X ch c th l A.

Phng php 7 : TH KT QU
Nguyn tc : Dng kt qu ngi ta ta cho th vo cc iu kin m bi ton a ra kt qu ng.
Phm vi : C th p dng cho ni dung mi trng hp nhng ch nn th cc trng hp phc tp.
V d minh ho :
VD1 : Hai cht hu c A, B (C, H, O) u c 53,33% O theo khi lng. Khi lng phn t ca B gp
1,5 ln khi lng phn t A. t chy ht 0,04 mol hn hp A, B cn 0,1 mol O2. Mt khc, khi
cho s mol bng nhau ca A, B tc dng vi lng d dung dch NaOH th khi lng mui to thnh
t B gp 1,952 lng mui to thnh t A . CTPT A, B l :
A. C2H4O2 v C3H6O2 B. C2H4O2 v C3H6O2
C. C2H2O2 v C3H6O2 D. C4H8O2 v C5H12O2
Gii :
+) Cch 1 : Da vo gi thit : MB = 1,5 MA th ta c :
A. 60 v 90 B. 60 v 74 C. 58 v 74 D. 58 v 104
T suy ra kt qu ng l A.
+) Cch 2 : Da vo gi thit %O = 53,33%. Gi CT chung ca A, B l : CxHyOz
16 z 53,33
Ta c : = 12 x + y = 14 z
12 x + y 46,67
z = 1 th x = 1 ; y = 2 CT nguyn ca A , B l : (CH2O)n. Ch c p n A .
VD2 : Xc nh CTPT ca phenol cha 13,11 % khi lng Oxi :
A. C7H8O B. C8H10O C. C9H12O D. Kq khc
Gii : Th tnh %O trong cc cht ta c :
A. 14,81% B. 13,11% C. 11,76%
Vy chn p n A.

KT LUN
Phng php trc nghim l mt phng php nh gi c trnh hc sinh kh khch quan.
Trong qu trnh lm bi trc nghim th mi chng ta s t mnh tm c nhng phng php ph hp
vi mnh, vi tng bi, c bit l nhng phng php gii ngn gn khng ng ...
Trn y, ch l mt s phng php m chng ti rt ra c trong vic gii ton ho hc bng
phng php trc nghim. Chc hn s c mt vo ch thiu st. Rt mong c s ng gp ca cc
bn chng ta c mt ti liu gi tr rong vic dy v hc. Xin trn trng cm n.
BAN BIN TP - 11 HO

CHNG I: HIROCACBON
Cu 1: t chy mt lng hircacbon A c m gam nc v 1,95m gam CO2. A thuc dy ng
ng:
A. Ankan B.Anken C.Ankin D. Aren
Cu 2: Hn hp p gm a cht hircacbon mch h A1, A2, ...An c dng CnHm trong m lp thnh
mt cp s cng c tng l 32 v cng sai dm = 4. Cc hircacbon c phn t lng ln lt l M1,
M2 ...Ma trong tng s phn t lng l 212 v t M1 n Ma-1 to thnh mt cp s cng c cng
sai dM = 16. Cng thc phn t cc hircacbon l:
A.C2H4, C3H8, C4H10, C5H10 B.C2H2,C3H6, C4H10, C5H12
C.C3H4, C3H8, C5H12, C5H8 D.C2H2, C3H6, C4H10, C6H14
Cu 3: Ankan X c cacbon chim 83,33% khi lng phn t. Khi X tc dng vi brm un nng c
chiu sng c th to ra 4 dn xut ng phn cha 1 nguyn t brm trong phn t. Tn ng ca X
l:
A.n-pentan B.iso-Butan C.2-metyl Butan D.2,2-imetyl propan
Cu 4: Oxi ha hon ton 0,244lt (ktc)ca xicloankan X thu c 1,76 gam kh CO2. Bit X lm mt
mu dung dch brm. X l:
A.Xiclopropan B.Xiclobutan C. Metyl xiclopropan D. Metyl xiclobutan
Cu 5: Cht no sau y khng phi l ng phn ca cc cht cn li:
A.Xiclobutan B.Butan C.Metylxiclopropan D.cis-Buten-2
Cu 6: t chy mt s mol nh nhau ca 3 hircacbon A, B, C thu c lng CO2 nh nhau, cn t
l gia s mol H2O v CO2 i vi A, B, C ln lt l 0,5 : 1 : 1,5 . Vy A, B, C ln lt l :
A.C2H4; C3H6; C4H8 B. C2H6; C2H4; C2H2
C.C3H8; C3H6; C3H4 D. C2H2; C2H4; C2H6
Cu 7: A, B, C l 3 hircacbon kh iu kin thng v lin tip trong dy ng ng. Bit phn t
lng ca C gp i phn t lng ca A. l:
A.CH4; C3H6; C3H8 B.C2H4; C3H6; C4H8
C. C2H2; C3H4; C4H6 D.C2H6; C3H6; C4H10
Cu 8: Trong mt bnh kn cha hn hp kh gm hiddroocacbon A v hir c Ni lm xc tc(th tch
khng ng k). Nung nng bnh mt thi gian thu c mt kh B duy nht. cng nhit , p sut
trong bnh trc khi nung nng gp 3 ln p sut sau khi nung nng. t chy mt lng B thu c
8,8 gam CO2 v 5,4 gam H2O. Cng thc phn t ca X l:
A.C2H2 B.C2H4 C. C3H4 D. C4H4
Cu 9: Mt hn hp gm C2H2; C3H8 v CH4. t chy 11 gam hn hp thu c 12,6 gam nc.
Bit 0,5 mol hn hp phn ng va vi 0,625mol Br2 .Phn trm th tch cc kh trn ln lt l:
A. 50%; 25%; 25% B.25%; 25%; 50% C.33,3%; 33,3%; 33,3% D.16%; 32%; 52%
Cu 10: t chy hon ton 6,8 gam mt ankaien A thu c hn hp sn phm hi gm 11,2 lt
CO2 (ktc) v m gam nc. Dn hn hp sn phm qua bnh (1) ng dung dch axit sunfuric c, sau
qua bnh(2) ng dung dch nc vi trong d. cng thc phn t ca A , tng khi lng bnh
(1) v kt ta bnh (2) l:
A. C5H8 ;7,2g ;50g B.C4H8; 3,6g; 50g C.C5H8; 3,6g; 50g D.C4H8; 7,3g; 50g
Cu 11: t chy hon ton a lt hn hp A gm 2 hircacbon l cht kh iu kin thng v c
khi lng phn t hn km nhau 28 vC. Sn phm chy c hp th hon ton vo dung dch
Ca(OH)2 d thy c 30 gam kt ta, khi lng bnh tng ln 22,2gam. cng thc phn t v thnh
phn phn trm theo th tch ca mi hiddroocacbon trong hn hp A l:
A.C2H6: 75%; C3H8: 25% B.CH4:75%; C3H8: 25%
C. C2H4:50%; C4H8: 50% D.CH4: 50%; C3H8:50%

Cu 12: t chy hon ton mt hn hp gm CH4 v H2 cn 1mol O2. Phn trm theo th tch ca
CH4 va H2 trong hn hp ln lt l:
A. 50% v 50% B. 66,7% v 33,3% C. 33,3% v 66,7% D.87,7% v 12,3%
Cu 13: Cho cc cu sau:
a, Benzen thuc loi ankan v c kh nng tham gia phn ng th halogen.
b, Benzen tham gia phn ng th halogen d hn ankan.
c, Bezenc kh nng tham gia phn ng th tng i d hn phn ng cng.
d, Cc ng ng ca benzen lm mt mu thuc tm khi un nng.
e, Cc nguyn t trong phn t benzen cng nm trn mt mt phng.
Nhng cu ng l:
A.a, b, c, d B.c, d, e C.a, b, d, e D.a, c, d, e
Cu 14: t chy hon ton 4,48 lt hn hp kh gm propan v mt hircacbon khng no Y thy
sinh ra 22gam CO2 v 10,8gam nc. Th tch khng kh cn dng , t chy hn hp (bit trong
khng kh oxi chim 20% th tch v cc th tch o ktc)v cng thc phn t caY l:
A.17,92lt ; C2H4 B.17,92lt ; C3H6 C.89,6lt ; C2H4 D.89,6lt ; C3H6
Cu 15: A, B l 2 hircacbon kh diu kin thng, khi phn hy u to cacbon v hir vi th
tch H2 gp 3 ln th tch hiddroocacbon ban u (trong cng iu kin ). A v B c th l:
A.Hai ng ng ca nhau
B. u cha 2 nguyn t cacbon trong phn t
C. u cha 6 nguyn t hir trong phn t
D. u cha 3 nguyn t hir trong phn t
Cu 16: t chy hon ton 2lt hn hp gm C2H2 v mt hircacbon A thu c 4lt hi H2O (cc
th tch o cng iu kin). Cng thc phn t ca A v phn trm theo th tch ca mi cht trong
hn hp l:
A.C2H4 ; 50% C2H2 ,50% C2H4 B. C2H4 ; 40% C2H2 ,60% C2H4
C. C2H6; 50% C2H2 ,50% C2H6 D. C2H6; 40% C2H2 ,60% C2H6
Cu 17: Hn hp X gm H2 v C2H2 c t khi so vi H2 bng 5,8.Dn 1,792lt X(ktc) qua bt Ni
nung nng cho n khi cc phn ng xy ra hon ton . Phn trm theo th tch mi kh trong hn hp
X v t khi ca kh thu c so vi H2 l:
A. 40% H2; 60% C2H2; 29 B. 40% H2; 60% C2H2; 14,5
C. 60% H2; 40% C2H2; 29 D. 60% H2; 40% C2H2; 14,5
b: t chy ht a mol ankan A thu c khng qu 6a mol CO2.Clo ha A theo t l mol 1 : 1 c
mt dn xut monoclo duy nht. A c tn l:
A. Etan B2-metylpropan C. n-hexan D. 2,2-imetyl propan
Cu 19: t chy hon ton 3,4gam mt ankaien lin hp khng nhnh X thu c 5,6lt kh
CO2(ktc) . X c tn l:
A. Butaien-1,3 B.Pentaien-1,3 C.metylButaien-1,3 D.hexaien-1,3
Cu20: Bn hircacbon u l cht kh iu kin thng. Khi phn hy mi cht trn thnh cacbon
v hir, th tch kh thu c u gp 2 ln th tch ban u. Chng l:
A.CH4, C2H4, C2H6, C3H4 B. CH4, C2H4, C3H4, C4H4
C.C2H4, C2H6, C3H4, C4H4 D. C2H6, C3H4, C4H4, C5H6
Cu 21: Ha hi hon ton 0,295gam mt hircacbon A c mt th tch hi bng vi th tch CO2
thu c khi t chy ht cng lng hircacbon A (cc th tch o cng iu kin).
hiddroocacbon A l:
A.Anken B. Ankin C.CH4 D.C3H6
Cu 22: Mt hircacbon A c cng thc phn t l C9H10. C bao nhiu ng phn bit Ac cha
vng benzen ?
A. 5 B. 4 C. 7 D.6
Cu 23: hir ha mt hircacbon cha no mch h thnh no phi dng 1 th tch H2 bng th
tch hiddroocacbon ny. Mt khc t chy mt th tch hi hircacbon ny thu c 10 th tch hn
hp CO2 v hi nc (cc th tch o cng diu kin ). hiddroocacbon ny l:
A.C2H4 B.C5H8 C.C3H6 D.C5H10
Cu 24: Hircacbon X c cng thc phn t C4H10 khng lm mt mu dung dch brm. Khi un
nng X trong dung dch thuc tm to thnh hp cht C7H5KO2 (Y).Cho Y tc dng vi dung dch
axit HCl to thnh hp cht C7H6O2. X c tn gi l:
A.Etyl benzen B. 1,3-imetylbenzen C.1,2-imetylbenzen D.1,4-imetylbenzen
Cu 25: X l dn xut clo ca hircacbon A. Phn t lng ca X l 113 vC. t chy X thu c
CO2, hi nc v kh clo, trong th tch CO2 v hi nc l bng nhau. A c cng thc phn t :
A.C3H8 B. C3H6 C. C4H8 D.Av B u ng
Cu 26: Mt hn hp X gm 1 ankan Av 1 ankin B c cng s nguyn t cacbon. Trn X vi H2
c hn hp Y.Khi cho Y qua Pt nung nng th thu c kh Z c t khi i vi CO2 bng 1 (phn
ng hon ton) .Bit rng VX = 6,72lt v VH2 = 4,48lt. cng thc phn t v s mol ca A, B trong
hn hp X(cc kh o ktc) l:
A.C3H8: 0,2mol ; C2H6: 0,1mol B. C3H8: 0,2mol ; C3H4: 0,1mol
C. C2H2: 0,1mol ; C3H4: 0,2 mol D. C2H6: 0,2mol ; C2H2: 0,1mol
Cu 27: t chy hon ton 9,9 gam cht hu c A gm 3 nguyn t C, H, Cl sn phm to thnh cho
qua bnh ng H2SO4 m c v Ca(OH)2 th thy khi lng cc bnh ny tng ln lt l 3,6gam v
8,8gam .Bit phn t A cha 2 nguyn t Cl. Cng thc phn t ca A l:
A.CH2Cl2 B.C2H4Cl2 C. C3H4Cl2 D. C3H6Cl2
Cu 28: t chy 3lt hn hp kh gm 2 hircacbon no k tip trong dy ng ng ,dn sn phm
ln lt qua bnh (1) ng CaCl2 khan ri bnh (2) ng dung dch KOH. Sau th nghim khi lng
bnh (1) tng 6,43gam, binh (2) tng 9,82gam.Cng thc v hm lng phn trm theo th tch ca 2
hiddroocacbon trong hn hp l(cc kh o ktc)
A.CH4:50% ; C2H6:50% B. C2H6: 50% ; C3H8: 50%
C.CH4: 33,3% ; C2H6: 66,7% D. C2H6:33,3% ; C3H8: 66,7%
Cu 29: C 3 cht A, B, C, l ng phn cu to ca nhau c cng thc phn t l C4H8.
+ A, C lm mt mu dung dch Br2 nhanh chng (ngay c trong bng ti).
+ B khng lm nht mu brm
+ Khi cng Br2, A c th to 2 sn phm
+ Sn phm cng brm t C c 1 nguyn t cacbon bt i.
Vy A, B, C ln lt l:
A.Buten-2; Xiclobutan; Buten-1 B.Buten-2; Metyl xiclopropan; 2-metyl propen
C.Metylpropen; Xiclobutan; Buten-1 D.Metylxiclopropan; Xiclobutan; 2-metylpropan
Cu 30: Gi tn hiddroocacbon c CTCT nh sau:
CH3 CH C C CH2 CH3
CH(CH3)2
A.2-iso propylhexin-3 B. 2-iso propylhexin-4
C. 5,6-imetylheptin-3 D. 5-iso propylhexin-3
Cu 30: Cho 5cm3 CxHy th kh vi 30cm3 O2 ly d vo kh nhin k. Sau khi bt tia la in v
lm lnh, trong kh nhin k cn 20cm3 m 15cm3 b hp th bi KOH. Phn cn li b hp th bi
phtpho. Cng thc phn t ca hircacbon l:
Cu 31: T khi ca mt hn hp kh gm mtan v tan so vi khng kh bng 0,6. S lt oxi t
chy hon ton 3lt hn hp v khi lng mi sn phm sinh ra (th tch cc kh o ktc)l:
A.6,45lt; 6,48gam CO2; 5,062gam H2O B. 2,15lt; 21,6gam CO2; 1,687gam H2O
C. 48,16lt; 48,4gam CO2; 37,8gam H2O D.144,48lt; 145,4gam CO2; 113,8gam H2O
Cu 32: X v Y l 2 hircacbon c cng cng thc phn t C5H8; X l monome dng trng hp
thnh caosu iso pren; Y c mch cacbon phn nhnh v to kt ta vi dung dch Ag2O/NH3.
Cng thc cu to ln lt ca Xv Y l:
A.CH2 = CH CH2 CH = CH2; CH C CH2 CH2 CH3
B.CH2 = C (CH3) CH2 = CH2 ; CH3 C C CH2 CH3
C. CH2 = C(CH3)2 CH2 = CH2 ; CH C CH(CH3) CH3
D. CH2 = CH = CH CH2 CH3 ; CH3 C C CH2 CH3
Cu 33: Hircacbon A cha vng benzen tronh phn t khng c kh nng lm mt mu dung dch
brm. Phn trm khi lng ca cacbon trong A l 90%. Khi lng mol phn t ca A nh hn
160gam. Bit khi tc dng vi brm theo t l 1 : 1 trong iu kin un nng c bt st hoc khng c
bt st. Mi trng hp u to mt dn xut monobrm duy nht. Tn ca A l:
A.Metyl benzen B. isopropylbenzen C.Etyl benzen D.1,3,5-trimetyl benzen
a, Ankaien l nhng hircacbon khng no, mch h c 2 lin kt i trong phn t
b, Nhng hircacbon c 2 lin kt i trong phn t l ankanien-1,3
c, Nhng hircacbon khng no c 2 lin kt i trong phn t l ankaien
d, Nhng hircacbon c kh nng cng hp vi 2 phn t hir thuc loi ankaien
e, Ankaien lin hp l nhng hircacbon khng no, mch h, trong phn t c 2 lin kt i
cnh nhau
g, Nhng hircacbon khng no, mch h, trong phn t c 2 lin kt i cch nhau 1 lin kt n
gi l ankaien lin hp.
Nhng cu ng l:
A.b, c, d, g B. a, g C.a, b, g, e. D.a, d, g
Cu 35: Trn 10ml hircacbon kh vi mt lng O2 d ri lm n hn hp ny bng tia la in.
Lm cho hi nc ngng t th th tch ca hn hp thu c sau phn ng gim i 30ml. Phn cn li
i qua dung dch KOH th th tch ca hn hp gim 40ml. Cng thc phn t ca hircacbon l:
A.C2H6 B.C3H6 C. C4H6 D.C4H8
Cu 36: Khi t 1lt kh X, cn 5lt kh oxi, sau phn ng thu c 3lt CO2 v 4lt hi nc , bit th
tch cc kh c o cng iu kin nhit v p sut . Cng thc phn t ca X l:
A. C2H6 B.C2H6O C.C3H8 D.C3H8O
Cu 37: t chy hon ton a gam hircacbon X thu c a gam nc. X khng tc dng vi dung
dch brm hoc vi brm khi c bt st v un nng. X tc dng vi brm un nng to thnh dn
xut duy nht cha 1 nguyn t brm trong phn t. T khi hi ca X so vi khng kh c gi tr trong
khong t 5 : 6. Tn ca X l:
A.1,3,5-trimetylbenzen B.1,3,5-trietylbenzen
C. Hexametylbenzen D. p-i isopropylbenzen
Cu 38: C mt hn hp X gm hircacbon A v CO2 .Cho 0,5lt hn hp X vi 2,5lt O2 (ly d)
vo trong 1 kh nhin k. Sau khi bt tia la in thu c 3,4lt hn hp kh v hi, tip tc lm lnh
th ch cn1,8lt v sau khi cho qua KOH ch cn 0,5lt. Cng thc phn t A l:
A.C2H6 B.C3H6 C. C3H8 D.C3H4
Cu 39: C mt hn hp Y gm hircacbon A v N2. t 300cm hn hp Y v 725cm3 O2 ly d
3
trong mt kh nhin k ngi ta thu c 1100cm3 hn hp kh. Cho hn hp ny lm lnh, th tch

cn 650cm3 v sau tip tc li qua KOH th ch cn 200cm3. Cng thc phn t A l:
Cu 40: t chy mt hn hp gm 2 hircacbon ng ng k tip A, B thu c VCO2 : VH2O = 12 :
23. Cng thc phn t v phn trm th tch ca 2 hircacbon l:
A.CH4: 10% ; C2H6: 90% B.CH4: 90% ; C2H6: 10%
C. CH4: 50% ; C2H6: 50% D.C2H6: 50% ; C3H6: 50%
Cu 41: Hn hp kh X gm O2 v O3 c t khi so vi H2 bng 20. t chy hon ton V(lt) CH4
cn 2,8lt hn hp X, bit th tch cc kh ktc. Th tch V l gi tr no sau y:
A.1,65lt B.1,55lt C. 1,75lt D.1,45lt
Cu 42: Mt hn hp 2 ankin t cho ra 13,2gam CO2 v 0,36gam nc . Tnh khi lng Br2 c th
cng vo hn hp ni trn .
A.8gam B.32gam C.16gam D.khng d kin
Cu 43: t chy mt hn hp X gm 2 hircacbon ng ng k tip, thu c 22gam CO2 v
5,4gam H2O. Xc nh dy ng ng, cng thc phn t ca A,B v s mol ca A, B
A.Ankin; C3H4: 0,1 mol; C4H6: 0,1mol B.Anken; C2H4: 0,2mol; C3H6: 0,2mol
C.Ankin; C2H2: 0,1mol; C3H4: 0,1mol D.Anken; C3H6: 0,1mol; C4H8: 0,2mol
Cu 44: Hn hp kh A gm propan v hir.Cho thm vo hn hp A mt lng O2 ly d ri a
vo kh nhin k. Sau khi bt tia la in v lm lnh, gim th tch kh trong kh nhin k trc v
sau th nghim bng 2,55 ln th tch hn hp kh A. Phn trm th tch cc kh trong hn hp A ln
lt l:
A. 70%; 30% B. 30%; 70% C. 40%; 60% D. 60%; 40%
Cu 45: Mt hn hp X c V = 2,688lt (ktc) gm 1 ankin v H2. Khi cho hn hp X qua Ni nung
nng, phn ng hon ton cho ra hircacbon B c t khi i vi CO2 bng 1. Xc nh cng thc
phn t ca A. Nu cho hn hp X ni trn qua 0,5lt nc Br2 0,2M , tnh nng mol ca dung dch
Br2 cn li:
A. C3H4; 0,05M B. C2H2; 0,05M C. C4H6; 0,06M D.C3H4; 0,04M
a, Ankan c ng phn mch cacbon.
b, Ankan v xicloankan l ng phn ca nhau.
c, Xicloankan lm mt mu dung dch brm
d, Hircacbon no la hircacbon ch c lin kt n trong phn t.
e, Hircacbon no l hircacbon lm mt mu dung dch brm.
g, Hircacbon no l hircacbon khng c mch vng.
Nhng cu ng l:
A. a, d B.a, c, d, g C. a, c, d D.c, d, g
Cu 47: Cho 5,6lt kh C2H6 (ktc) tc dng vi Cl2 c iu ch t126,4 KMnO4 khi tc dng vi
axit HCl. Lc phn ng kt thc ton b cc kh thu c cho vo nc. S lt dung dch NaOH 2M
dng trung ha dung dch va thu c l: (cc phn ng xy ra hon ton)
A. 0,75lt B. 1,5lt C.1,25lt D. 2,5lt
Cu 48: Mt hn hp X gm ankan A v anken B c cng s nguyn t C v u th kh ktc. Khi
cho hn hp X i qua nc Br2 d, th th tch kh Y cn li bng th tch X, cn khi lng Y bng
15/29 khi lng ca X. Cc th tch kh o trong cng diu kin nhit v p sut. Cng thc phn
t ca A, B v thnh phn % theo th tch ca hn hp X l:
A.C3H8: 50%; C3H6: 50% B.C2H6: 50%; C2H4: 50%
C.C3H8: 75%; C3H6: 25% D.C2H6: 75%; C2H4: 25%
Cu 49: t chy 13,7ml hn hp A gm metan, propan v cacbon(II)oxit, ta thu c 25,7ml kh CO2
cng diu kin nhit v p sut. Phn trm th tch propan trong hn hp A v hn hp A so vi
nit l:
A.43,8%; nh hn B.43,8%; nng hn C.21,9%; nh hn D.21,9%; nng hn
a, Stiren c tn l vinylbenzen hoc phenylaxetilen.
b, Stiren c tn l vinylbenzen hoc phenyletilen.
c, Cc nguyn t trong phn t stiren cng nm trn mt mt phng.
d, Stiren va c tnh cht ging anken va c tnh cht ging benzen.
e, Naphtalen c mi thm nh.
g, Stiren khng lm mt mu dung dch thuc tm.
Nhng cu ng l:
A.a, c, d B. a, b, c, e C. b, c, d, e D.b, c, e, g
Cu 51: Cho mt bnh thp kn dung tch 2lt cha sn 1lt ncv 1 lt hircacbon khng tan trong
nc 0oC; 1,344 atm. Ngi ta cho vo bnh 15,5lt O2 (ktc) vi 26,4gam hn hp canxi cacbua ri
phng tia la in phn ng chy xy ra hon ton a v 0oC p sut lc ny 3,18 atm v thu c
1lt dung dch Ca(HCO3)2 0,28M v 2gam kt ta. Coi th tch cht rn v p sut hi nc khng
ng k. Cng thc phn t ca hircacbon l:
A. C2H6 B.C3H8 C.C3H6 D.C4H10
a, Du m l hn hp cc hircacbon khc nhau.
b, Kh thin nhin v kh du m c thnh phn cc cht tng t nhau.
c,Chng ct thng ch c th tch c du m thnh cc phn on du m(l hn hp cc
hircacbon ) c nhit si gn nhau.
d, Chng ct thng c th tch c du m thnh cc phn on cha cc hircacbon ring
bit.
Nhng cu sai l:
A. a, b, c B.d C. a, c D. b, d
Cu 53: Trong mt bnh kn cha hn hp gm hircacbon X, mch h v kh hir c Ni lm xc
tc (th tch Ni khng ng k). Nung nng bnh mt thi gian, thu c mt kh B duy nht. cng
nhit , p sut trong bnh trc khi nung nng gp 3 ln p sut sau khi nung nng. t chy mt
lng B thu c 4,4gam CO2 v 2,7gam H2O. Cng thc phn t ca X l :
Cu 54: t chy 1 hircacbon X ta thu c s mol nc ln hn 1,5 ln s mol CO2 . Vy X c th
l :
A. Anken B.Ankin C.ankan vng c 1 lin kt i D. CH4.
Cu 55: Trong phng th nghim nu c ha cht th nn dng phng php g iu ch metan
vi thit b n gin nht
A. Nung CH3COONa + NaOH CH4 + Na2CO3
B. phng php griguard
C. nhit phn C3H8
D. Al 4C3 + H2O Al (OH)3 + CH4
Cu 56: Hp cht X t chy cho s mol CO2 bng s mol H2O. X c th l :
1, Axit no n chc 2, Ancol 3, Xicloankan 4, Anken
5, Ru khng no 1 ni i
A.1,2,3,4,5 B.1,2,5 C.2,3,5 D.4,5 E.2,3,4
Cu 57: Cht no sau y c ng phn cis-trans
1, CH2 CH2 2, CH3 C = CH C6H5 3, CH3 CH = N OH
CH3
4, CH3 CH = CH C6H5 5, CH3 N = N C 6 H5
A.1,2,3,4,5 B.2,3,4 C.3,4,5 D.2,4,5
Cu 58: Phn ng no sau y c kh nng to ra CH4
1.CH3COOH + NaOH (d)
2.CH4 + Cl2
3.CH2(COONa)2 + Ca(OH)2
4. Al4C3 + H2O
A.1,2,3,4 B.3,4 C.1,3,4 D.1,2,3
Cu 59: Trong cc pht biu sau v phn ng gia etylen v clo . Pht biu no ng:
A.Trong ngn la phn ng cho ra 1,2- icloetan
B.Vi nh sng khuych tn cho ra 1,1-icloetan
C. Vi nh sng khuych tn cho ra C v HCl
D.Vi nh sng khuych tn cho ra 1,2-icloetan
Cu 60: Da vo bn lin kt HX : X l halogen trong cc HX gm HF, HCl, HBr, HI . HX no
cng vo lin kt i ca anken d nht:
A.HF B.HCl C.HBr D.HI
Cu 61: Mt hn hp gm 2 ankin khi t chy cho ra 13,2g CO2 v 3,6g H2O . Tnh khi lng
Brm c th cng vo hn hp ni trn
A.8g B. Khng d kin C.32g D.16g
Cu 62: t chy mt hidrocacbon A thu c s mol nc bng s mol CO2 v s mol CO2 < 5
ln s mol A. Xc nh CTPT, CTCT ca A , bit A cho kt ta vi AgNO3/NH3
A.C3H4, CH3 C CH B.C4H6, CH3 C C CH3
C. C4H6, CH3 CH2 C CH D.C5H8, HC C CH2 CH2 CH3
Cu 63: Trong cc d kin sau
1, Phn ng th 1H bng 1Cl ch chho mt sn phm th duy nht
2, Phn t benzen l hnh lc gic u phng
3, Trong phn ng cng Cl2 ,6 nguyn t Cl cng cng lc
4, Phn ng phn hu vi Cl2 cho ra C v HCl
D kin no cho thy trong benzen 6C v 6H u tng ng vi nhau
A.1,2,3 B.1,2 C.3,4 D.1,3
Cu 64: Khi nitro ho axit benzen sunfomic bng HNO3 + H2SO4 ta thu c sn phm chnh l
A. o- benzen sunfomic axit
B. m- benzen sunfomic axit
C. 3,5-initro benzen sunfomic axit
D.2,4,6 trinitro benzen sunfomic axit
Cu 65: Nhn nh s sau
A(buten-1) HCl X NaOH Y H2SO4 Z(spc)
Vy Z l:
A. iisobutyl ete B. Buten-2 C. 2-metyl propen D. etyl metyl ete
Cu 67: Hirat ho 5,6g propen xc tc H2SO4 thu c m gam hn hp hai ru A,B .Bit c 65%
v 15% propen ban u tham gia phn ng to A, B. Gi tr m l:
A.12g B.6g C.9,75g D.2,25g
Cu 68: un 14,8gam butanol-2 vi H2SO4 c 1700 c hn hp hai anken A, B ng phn c
th tch ktc ln lt l 1,12 v 2,24. A l ankin no:
A. Buten-2 B. Buten-1 C.2-metyl propen D.Etylen
Cu 69: Hiu sut ca phn ng hidrat trong cu trn l
A.25% B.50% C.75% D.85%
Cu 70: Phn ng sau c h s cn bng l:
CH2 CH2 + KMnO4 + H2O C2H4(OH)2 + KOH + MnO2
A.2,3,4-3,2,2 B.4,2,3-2,3,2 C.3,2,4-3,2,2 D.4,6,8-6,4,4
D kin sau dng cho cu 71-72-73 : t chy m gam hircacbon A th kh iu kin thng
c CO2 v m g H2O
Cu 71: A c th thuc dy ng ng no
A.ankan B.anken C.ankandien D. aren
Cu 72: Ch ra pht biu ng
A. C th iu ch A t phn ng tch nc t ru n chc no
B. A c c ti a 3 lin kt pi trong phn t
C. A l monome iu ch cao su tng hp
D. t chy A lun thu c s mol CO2 b hn s mol nc
Cu 73: Trong bnh kn cha hn hp X gm hircacbon ( th kh iu kin thng) v O2. t
chy A thu c hn hp Y c phn trm th tch l 80% CO2 v 20% hi H2O (cn O2 d)
A c cng thc phn t l :
A.C6H8 B.C2H4 C.CH4 D.C3H4
Cu 74: X l hircacbon th kh ( iu kin thng). t X cho s mol CO2 b hn s mol H
X phn nhnh v khng lm mt mu Br2. CTPT c th ph hp vi X l:
Cu 75: t chy hon ton hn hp A gm c C2H4, C2H6 ,C4H8, thu c (m+2)gam nc v
(m+28)gam CO2. Gi tr m l:
A.18g B.16g C.10g D.7g
D kin sau dng cho cu 76-77-78 : Cho cc cht sau: etan(1), etylen(2), axetilen(3). Hy sp xp
cc cht theo th t tng dn
Cu 76: di lin kt C-C ln nht l:
A.1 B.2 C.3 D.3 cht bng nhau
Cu 77: di lin kt C-H ln nht l:
Cu 78: phn cc ca lin kt C-H ln nht l:
Cu 79: Hircacbon no di y l ng ng ca nhau
CH3
I II III IV
A.I, II ,III B.I, II, IV C.II, III, IV D.I, III, IV
Cu 80: Hircacbon X th kh iu kin thng, khi t chy hon ton m gam X thu c
m gam H2O. S ng phn ca X l
A.4 B.5 C.6 D.7
Cu 81: X, Y, Z l 3 hircacbon kh iu kin thng khi phn hu mi cht X, Y, Z u to ra
C v H2. Th tch H2 lun gp 3 ln th tch hircacbon b phn hy v X, Y, Z khng phi ng
phn. Cng thc phn t ca 3 cht l:
A.CH4, C2H4, C3H4 B. C2H6, C3H6, C4H6 C. C2H4 C2H6 C3H8 D.Kt qu khc
Cu 82: Nu t CnH2n+2-2k (k0) l cng thc phn t tng qut ca hircacbon th k0 l:
A. Tng s lin kt i
B. Tng s lin kt i bng tng s lin kt ba
C. Tng s lin kt pi
D. Tng s lin kt pi v vng
E. kt qu khc
Cu 83: Cho cc ankan CH4, C2H6, C3H8, C4H10, C5H12, C6H14, C7H16, C8H18. Ankan no tn ti mt
ng phn tc dng vi Clo theo t l 1:1 cho ra monocloankan duy nht:
A. C2H6, C3H8, C4H10, C6H14 B. CH4, C2H6, C5H12, C8H18
C. CH4, C3H8, C5H12, C8H18
D. C2H6, C5H12, C4H10, C6H14 E. Kt qu khc
Cu 84: Ngi ta trn hircacbon A vi lng d kh H2 c hn hp kh B. t chy ht 4,8gam
kh B to ra 13,2gam CO2. Mt khc 4,8gam B lm mt mu dung dch cha 32gam brm.
CTPT A l :
A.C3H4 B.C2H2 C.C3H6 D.C4H8 E.Kt qu khc
Cu 85: Hn hp A gm 1 ankan v 1 anken. t chy hn hp A th c a mol H2O , b mol CO2.

Hi t s T = a/b c gi tr trong khong no:
A.1,2< T < 1,5 B. 1< T < 2 C.1 T 2 D.1 T 2,5 E.Kt qu khc
Cu 86: Cho s chuyn ho sau: CH2 = CH CH3 A phenol. Vy A l:
A.C6H5ONa B.C6H5Cl C.cumen D.toluen E.Kt qu khc
Cu 87: Kh no sau y khi t cho nhit lng nhiu nht:
A.C4H10 B.CH4 C.C2H2 D.isooctan
Cu 88: Vi cng thc C4H8 c s ng phn l
A.3 B.4 C.5 D.6 E.Kt qu khc
Cu 89: C 6H10 c bao nhiu ng phn ankin to kt ta vi AgNO3
A.1 B.2 C.3 D.4 E.5
D kin sau dng cho cu 90-91: Hn hp X gm 15 anken ( th lng hay rn) ng tch. t
chy hon ton cho 10 mol CO2. Hir ho hon ton X th c hn hp Y gm cc ankan, t
chy hon ton hn hp ankan th s mol H2O thu c l 12 mol
Cu 90: em Y t chy hon ton th s mol CO2 thu c l :
A.8 mol B. 10 mol C. 12 mol D. 15 mol E.Kt qu khc
Cu 91: S mol H2 cn hir ho hon ton X l:
A. 10 mol B. 2 mol C.12mol D. 6mol E. Kt qu khc
Cu 92: Cho isooctan tc dng vi clo (nh sng) th c th thu c bao nhiu sn phm th monoclo
A.8 B.18 C.4 D.7 E.kt qu khc

Cu 93: Hn hp X gm mt ankin th kh v H2 c t khi hi so vi CH4 l 0,425 . Nung nng X
(Ni,to) phn ng xy ra hon ton . Sau phn ng thu c kh c t khi hi so vi CH4 l 0,5.
Cho Y qua dung dch Br2 , khi lng bnh tng thm l:
A.8g B.16g C.khng tng D.32g E. Khng xc nh c
Cu 94: Hn hp X gm 0,2 mol propylen v xiclopropan c cng th tch. Hn hp Y c 0,4 mol H2
ktc . Trn X ,y vi xc tc Ni sau mt thi gian thu c hn hp Z . t chy hon ton Z thu
c s mol nc l
A.18 B.9 C.4,5 D.27 E. Khng xc nh c
Cu 95: Hn hp hircacbon c cng s nguyn t C . t chy hon ton 1 mol hn hp thu c
S mol CO2 = S mol H2O < 5
Bit cc hircacbon trong hn hp phn nhnh . Cng thc phn t ph hp l:
A.C2H4, C2H6 B.C3H6 C.C4H8 D.C5H10
E.Khng xc nh c
Cu 96: CTPT ca mt hircacbon l C5H8 . Hircacbon ny c thuc dy ng ng:
A.Ankin B.Ankandien C.Xicloanken D.ixicloankan *E. Tt c u ng
Cu 97: Thuc th no sau y c th phn bit c 3 cht lng : benzen, toluen, stiren.
A.Br2 B.HNO3 C.KMnO4 D. Khng th phn bit
Cu 98: Cho isobuten vo dung dch HBr c ho tan NaCl , CH3OH c th to ra s sn phm l:
A.1 B.2 C.3 D.4 E.5
Cu 99: Cho A l C3H4BrCl . B qua cc ng phn hnh hc, quang hc th A c s cng thc cu
to ph hp l ph hp l:
A.8 B.9 C.10 D.11 E.12
Cu 100: Mt trong s tiu chun nh gi cht lng s dng xng l ch s octan. Vy hp cht
isooctan l:
A.2,3- imetyl hexan B.2,2,4-trimetyl hexan C.2,2,3 tri metyl butan
D.xiclo hexan E.tetrametyl pentan
Cu 101: Hn hp gm 15 anken ch th rn hoc th lng v c s nguyn t C khc nhau. Hi

trong hn hp c t nht bao nhiu hircacbon th rn
A.1 B.2 C.3 D.4 E. Khng c
Cu 102: Cho phn ng sau:
Propen + Cl2 CCl4 X
X l:
A. ClCH CH CH3 B. CH2 CCl CH3 C. ClCH = CH CH3
D. ClCH2 CH CH2 E. Khng phn ng
Cu 102:: Nhit phn hon ton 8,8 g C3H8 gi s ch xy ra 2 phn ng
C 3 H8 C2H4 + CH4
C 3 H8 C 3 H6 + H2
Ly hn hp sau phn ng em t chy thu c s mol CO2 l
A.0,2 B.0,4 C.0,6 D.0,8 E.khng xc nh c
Cu 103:: Hidrocacbon no sau y khi t chy s sinh ra nCO2 : n H2O = 1 : 4

Cu 104: T khi ca hn hp kh C3H8 v C4H10 i vi hir l 25,5. Thnh phn % th tch hn hp
kh l:
A.50 v 50 B.25 v 75 C.45 v 55
D.20 v 80 E. Kt qu khc
Cu 105: T khi hi ca metan va oxi so vi hir l 40/3. Khi t chy hon ton hn hp trn, sau
phn 5ng thu c sn phm v cht d l:
A. CH4 , CO2 , H2O B.O2 , CO2 , H2O C.CO2 , H2O
D.H2 , CO2 ,O2 E.Khng xc nh c
Cu 106: Xt s chuyn ha:
+H2O
C3H5Br3 X + .
- 0
OH ,p,t
NH3
X + Ag2O Ag + .
X + Na H2 + .
Vy cng thc cu to ph hp ca C3H5Br3 l:
Br
A. CH2 CH2 CH2 B.CH3 C CH
Br Br Br Br
Br Br
C. CH3 CH2 C Br D. CH CH CH3
Br Br Br
E.Kt qu khc
Cu 107: Cho s chuyn ha :
X + H2O HgSO4 X1 +H2
CH3 CH2 OH
Ni, t0
Vy X l :
A.CH CH B. CH2 = CH2
C.CH3 CH3 D. Kt qu khc
Cu 108: Mt dn xut hircacbon mch h cha 39,2% clo.Bit rng 0,01 mol cht ny lm mt mu
dung dch c 1,6 gam Br2 trong bng ti. Cng thc n gin ca dn xut ny l:
A. C4H7Cl B.C3H7Cl C.C2H5Cl
D. C4H9Cl E. Kt qu khc
Cu 109: t chy ht 1,52 gam mt hircacbon A1 mch h ri cho sn phm chy qua bnh ng
dung dch Ba(OH)2 thu c 3,94 gam kt ta v dung dch B. C cn dung dch B ri nung n khi
lng khng i th thu c 4,59 gam cht rn.Cng thc phn t hircacbon l:
A.C5H12 B.C4H8 C.C3H8
D.C5H10 E. Kt qu khc
Cu 110: t chy mt hn hp hircacbon ta thu c 2,24 lt CO2 (ktc) v 2,7gam H2O th th
tch O2 tham gia phn ng chy (ktc)l:
A. 4,48lt B.3,92lt C.5,6lt D.2,8lt E.Kt qu khc
Cu 111: Cng thc phn t ca mt hircacbon l C5H8 th hircacbon ny thuc dy ng ng:
A.Ankin B.Ankandien C.Xiclo anken D.ixilo ankan E.Tt c u ng
Cu 112 : Hn hp A gm: H2 v 2 hircacbon mt no, mt cha no. Cho A vo bnh kn c Niken
xc tc , un nng bnh mt thi gian ta thu c hn hp B.
Pht biu no sau y ng:
A. S mol A - S mol B = s mol H2 tham gia phn ng
B. Tng s mol hircacbon c trong B lun bng tng s mol hircacbon c trong A
C. S mol tiu tn, s mol CO2 v H2O to ra khi t chy hon ton A cng y ht nh t
chy hon ton B
D. C a ,b,c u ng
E. Kt qu khc
Cu 113: Crcking 560lt C4H10 (ktc)xy ra cc phn ng:
C 2 H6 + C 2 H4
to,xt,p
C4H10 CH4 + C 3 H8
H2 + C 4 H8
Ta thu c hn hp kh X c th tch 1010 lt (ktc)
Th tch (lt)C4H10 cha b crcking l:
A.60 B.100 C.80 D.450 E.Kt qu khc
Cu 114: T khi hi ca hai ng ng th hai v th ba ca dy ng ng metan so vi H2 l 18,5.
Thnh phn % v th tch ca hn hp l:
A.50 va 50 B.40 v 60 C.25 v 75
D.33,3 v 66,7 E.Kt qu khc
Cu 115: t chy hon ton hn hp hai hircacbon ng ng c khi lng phn t hn km
nhau 28vC, ta thu c 4,48 lt CO2 (ktc) v 5,4gam H2O. Cng thc phn t ca 2 hircacbon l:
A.C2H4 v C4H8 B.C2H2 v C4H6 C.C3H8 v C5H8
D.CH4 v C3H8 E.Kt qu khc
Cu 116: Hp cht A c 8 nguyn t ca hai nguyn t MA < 32. Cng thc phn t ca A:
A.C4H4 B.C3H5 C.C2H6 D. Kt qu khc
Cu 117: Hn hp D gm hp cht C2H6 v mt ankin B( th kh) trn vi nhau theo t l mol 1:1.
Thm O2 vo hn hp D c hn hp D1 c t khi hi so vi H2 =18. Cng thc phn t ca
ankin B l :
A .C3H4 B.C2H2 C.C4H6 D.C5H8 E.Kt qu khc
D kin sau dng cho cu 118-119: Mt hn hp hai anken k cn trong dy ng ng c t khi hi
so vi H2 =24,8
Cu 118: Cng thc phn t ca hai anken l:
A.C2H2 v C3H4 B.C2H4 v C4H8 C.C3H8 v C5H12 D.Kt qu khc
Cu 119: Thnh phn % v th tch trong thnh phn hn hp l:
A.30% v 70% B.35% v 65% C.60% v 40%
D.50% v 50% E.Kt qu khc
D kin sau dng cho cu 120-121: iu kin tiu chun c mt hn hp kh hidrocacbon no A v
B. T khi hi i vi hir l 12.
Cu 120: Tm khi lng CO2 v H2O sinh ra khi t 15,68 lt hn hp (ktc)
A.24,2g v 16,2 g B.48,4g v 32,4 g C.40g v 30g D.Kt qu khc
Cu 121: Cng thc phn t ca A v B l:
A.CH4 v C2H6 B.CH4 v C3H8 C.CH4 v C4H10
D.C 3 A, B, C u ng
Cu 122: Mt hn hp 2 kh hircacbon mch h .T khi hi hn hp so vi H2 = 17. ktc 400cm3
hn hp tc dng va vi 71,4cm3 dung dch Br2 0,2M v cn li 240 cm3 kh. Xc nh cng thc
phn t ca hai hircacbon :
A. C2H6; C2H2 B. C3H8; C3H4 C.C2H6; C3H4 D.C4H10; C2H2
E.Kt qu khc
D kin sau dng cho cu 123-124: Mt hn hp gm ankan v ankin. t chy hon ton hn hp
ny thu c 12,6gam H2O. Khi lng O2 cn dng cho phn ng l 36,8gam. Th tch CO2 sinh ra
bng 8/3 th tch hn hp kh ban u.
Cu 123: Tng s mol ca hn hp ban u l:
A.0,3 mol B.0,2 mol C.0,4 mol D.Kt qu khc
Cu 124: Xc nh cng thc phn t c th c ca ankan v ankin.
A.C3H8 v C2H2 B.C2H6 v C3H4
C.C4H10 v C2H2 D.C hai cu B v C
D kin sau dng cho cu 125-126: Hn hp kh A gm hai hircacbon c cng s nguyn t
cacbon ( ktc).
Cu 125: Tm t khi hi ca hn hp A i vi nit, bit rng 560 cm3 hn hp nng 1,36225gam.
A.1,9 B.2 C.1,6 D.Kt qu khc
3
Cu 126: t chy V (cm ) hn hp A, cho cc sn phm chy ln lt qua bnh (1) ng P2O5 v
bnh (2) ng Ba(OH)2 thy khi lng bnh 1 tng 2,34gam v bnh 2 tng 7,04gam. Xc nh cng
thc phn t cc hircacbon bit rng c mt hircacbon l olfin.
A.C4H8 v C4H6 B.C4H8 v C4H4 C.C4H8 v C4H2 D.c 3 cu a,b,c
D kin sau dng cho cu 127-128: Cho 10 lt hn hp kh ( 540C v 0,8064 atm) gm 2 anken li
qua bnh ng nc brom d thy khi lng bnh nc brom tng ln 16,8gam.
Cu 127: Tnh tng s mol ca 2 anken
A.0,1 mol B.0,2 mol C. 0,3 mol
D.0,4 mol E.Kt qu khc
Cu 128: Hy bin lun cc cp anken c th c trong hn hp kh ban u. Bit rng s nguyn t C
trong mi anken khng qu 5.
A.C5H10 v C2H4 B.C5H10 v C3H6
C.C5H10 v C4H8 D.Hai cu A,B ng
Cu 129: t chy hon ton 2,24lt kh C2H4 (ktc) ri hp th ton b sn phm vo dung dch cha
11,1gam Ca (OH)2. Hi sau khi hp th khi lng phn dung dch tng hay gim bao nhiu gam?
A.tng 4,8 g B.gim 2,4 g C.tng 2,4 gam
D.gim 3,6 g E.tng 3,6 g
Cu 130: Trn mt hn hp X gm 1 hircacbon kh A v H2 vi dX/H2 = 6,1818. Cho X qua Ni un
nng n khi phn ng hon ton c hn hp Y c dY/H2 =13,6. Xc nh cng thc phn t ca A.
Cu 131: Mt hircacbon X c cng thc CnH2n+2-2k. Khi t chy X ta c t l s mol ca CO2 v
H2O bng 2, ng vi k nh nht. Cng thc phn t ca A.
A.C2H4 B.C2H6 C.C2H2 n D.C6H6 E.Kt qu khc
Cu 132: Trn 0,02mol C2H2 v 0,03mol H2 vi 1,68lt O2 (ktc) np vo mt kh nhin k c dung
tch 4lt ri t chy. p sut hn hp sau phn ng khi t0 =109,2 0 C l:
A.0,392atm B.1,176atm C.0,784atm D.1,568atm E.Kt qu khc
Cu 133: Khi cho Br2 tc dng vi mt hircacbon thu c mt dn xut Brm ha duy nht c t
khi hi so vi khng kh bng 5,207. Cng thc phn t hircacbon l:
A.C5H12 B.C5H10 C.C4H8 D.C4H10 E.Khng xc nh c
Cu 134: t chy ht 0,244lt (kc) mt hircacbon no mch h, sn phm chy cho qua 1lt nc
vi trong 0,143% (D = 1gam/lt) thu c 0,1gam kt ta. Cng thc phn t ca hircacbon l :
Cu 135: Nu t CnH2n+2-2k vi k > 0 l cng thc phn t tng qut ca hircacbon th k > 0 l :
A.Tng s lin kt i B.Tng s lin kt vng C. Tng s lin kt pi
D.Tng s lin kt pi v vng E.Kt qu khc
Cu 136: T cng thc phn t tng qut ca hircacbon CnH2n+2-2k vi k > 0, ta c th suy ra cc
trng hp no sau y :
A. Nu k = 0 l ankan CnH2n+2 , n > 1 B. N u k = 1 l anken CnH2n
C. N u k = 2 l ankin CnH2n -2 D. N u k = 4 l aren CnH2n-6 E.Kt qu khc
Cu 137: Cho 2 hircacbon A v B l ng ng nhau, phn t khi c A gp i phn t khi ca B.
T khi hi ca B so vi khng kh l 0,966. T khi ca hn hp ng th tch A v B so vi kh C2H6
bng 2,1. Xc nh cng thc phn t ca A v B.
A.C6H12 v C3H6 B. C4H8 v C2H4 C. C4H12 v C2H6 D. C6H14 v C3H8
Cu 138: t chy hon ton 2,8gam mt hp cht hu c A ri cho ton b sn phm hp th
vodung dch NaOH th dung dch ny c khi lng tng thm 12,4gam, thu c 2 mui c khi
lng tng cng l 19gam v 2 mui ny c t l s mol l 1 : 1. Dy ng ng ca cht A l:
A. Ankan B.Anken C.Ankin D.Aren E.Kt qu khc
Cu 139: t chy hon ton 2,8gam cht hu c A bng 6,72lt O2 (ktc) ch to thnh kh CO2 v hi
nc c th tch bng nhau trong cng iu kin. Nu cho 2,8gam A ni trn vo dung dch Br2 d th
thu c 9,3gam sn phm cng. Cng thc phn t ca A l:
A.C2H2 B.C3H6 C.C4H8 D.C5H10 D.Kt qu khc
D kin sau dng cho cu 140-141: t chy 2lt hn hp 2 hircacbon A ,B th kh v cng dy
ng ng, cn 10lt O2 to thnh 6lt CO2 (cc kh o ktc). Bit VA = VB
Cu 140: Cng thc phn t ca A, B l:
A.C2H6 v C4H10 B. C2H4 v C4H8 C. CH4 v C5H12 D. A v C u ng
Cu 141: Nu hir ha hn hp A, B (theo cu to cu trn) th c th thu c ti a bao nhiu
anken:
A.2 B.3 C.4 D.5
Cu 142: t chy hon ton hn hp 2 hircacbon X,Y thuc cng mt dy ng ng(ankan, anken,
ankin), hp th sn phm chy vo 4,5lt dung dch Ca(OH)2 0,02M th thu c kt ta, khi lng
dung dch tng ln 3,78gam. Cho tip Ba(OH)2 d vo dung dch li thu c kt ta.Tng khi lng
kt ta l 18,85gam. S mol X bng 60% tng s mol trong X, Y hn hp. Cng thc phn t ca X, Y
ln lt l:
A.C2H2 v C3H4 B. C2H2 v C4H6 C. C3H4 v C4H6 D. C2H4 v C3H6
D kin sau dng cho cu 143-144-145: Mt hn hp gm 2 ankan c khi lng l 10,2gam. t
chy hon ton hn hp ankan ny cn dng 25,8lt O2 (ktc).
Cu 143: Tng s mol 2 ankan l:
A.0,1mol B.0,2mol C.0,3mol D.Kt qu khc
Cu 144: Khi lng CO2 v H2O to thnh:
A.30,8gam; 16,2gam B.15,4gam; 8,4gam C.30,8gam; 8,4gam D.Kt qu khc
Cu 145: Cng thc phn t ca 2 Ankan l:
A.CH4 v C4H10 B. C2H6 v C4H10 C. C3H8 v C4H10 D.C A, B, C u ng
Cu 146: t chy 3lt hn hp kh gm 2 hircacbon no k tip trong dy ng ng ,dn sn phm
ln lt qua bnh (1) ng CaCl2 khan ri bnh (2) ng dung dch KOH. Sau th nghim khi lng
bnh (1) tng 6,43gam, binh (2) tng 9,82gam.Cng thc v hm lng phn trm theo th tch ca 2
hiddroocacbon trong hn hp l(cc kh o ktc)
A.CH4:50% ; C2H6:50% B. C2H6: 50% ; C3H8: 50%
C.CH4: 33,3% ; C2H6: 66,7% D. C2H6:33,3% ; C3H8: 66,7%

CHNG II: RU- PHENOL-ANMIN
Cu 1: Mt ru no a chc X mch h c n nguyn t C v m nhm -OH trong cu to phn t. Cho

7,6 gam rc trn phn ng vi lng d Na, thu c 2,24 lt kh (ktc)
Lp biu thc lin h gia n v m.
A. 7n + 1 = 11m B. 4n + 1 = 10m
C. 7n + 4 = 12m D. 7n + 2 = 14m
p n : A
Cu 2:.Xp cc ancol benzyl di y theo th t phn ng gim dn vi HBr : C6H5-CH2OH(1) ,
p-O2N-C6H4-CH2OH (2), p-CH3O-C6H4- CH2OH (3), p-Cl-C6H4-CH2OH (4).
A. (3), (2), (4), (1) B. (2), (3), (1), (4),
C. (3), (1), (4), (2) D. (4), (3), (2), (1)
p n : C
Cu 3: Dung dch A gm : H2O, CH3OH, C2H5OH. S lin kt Hiro trong dung dch l :
A. 3 B. 6 C. 9 D. 12
p n : C.: 9
Cu 4:. un nng hn hp A gm 10 ru no n chc vi H2SO4 c 1400C. S ete thu c l :

A.30 B. 45 C. 50 D. 55
p n : D.
Cu 5: Cho 2,15 gam ru propylic tc dng vi axit axetic, to thnh este vi hiu sut 100%. Tnh
khi lng axit axetic phi dng :
A. 2,15 B. 2, 148 C. 2,16 D. 2, 17
p n : A
Cu 6: S ng phn cu to ca C8H18 l :
A. 17 B. 18 C. 19 D. 20
p n : B
Cu 7:. Cho 1 lt cn 920 tc dng vi Na d. Bit rng ru etylic nguyn cht c d = 0,8 g/ml, tnh
th tch H2 to ra ktc
A. 179,2 lt B. 224 lt C. 228,98 lt
D. 280 lt E. Kt qu khc.
p n : C
Cu 8:.Mt ru A mch h khng lm mt mu nc Br2. t chy a(lt) hi ru A cn 2,5a (lt)

cng iu kin. Xc nh cng thc cu to ca A :
A. CH3OH B. C2H5OH C. C2H4(OH)2 D. C3H5(OH)3
p n : C
Cu 9:. Sp xp theo th t mnh tng dn tnh axit ca cc cht cho sau y :

C6H5OH(1) ;p-CH3-O-C6H4OH(2); p- NO2-C6H4OH(3);
p-CH3- COC6H4OH(4) ; p-CH3-C6H4OH(5)
A. (4) (3) (2) (1) (5) B. (2) (5) (1) (4) (3)
C. (2) (5) (4) (3) (1) D. (2) (4) (3) (5) (1)
p n:B
Cu 10:. Hn hp X c phan trn t cc rc no n chc cng dy ng ng c s nguyn t
C <=4. Khi cho X tc dung vi Na thu c 5,6 lt H2, cn khi t chy hon ton X cn 47,04 lt O2. X
cha 2 ru. X c th l :
A. CH3OH, C3H7OH B. CH3OH, C4H9OH
C. C2H5OH, C3H7OH D.Kt qu khc
p n : D
Cu 11:.Hai cht hu c A v B cng cha cc nguyn t C, H, O. Khi t chy mi cht u phi
dng mt lng oxi bng 8 ln lng oxi c trong mi cht v thu c lng kh CO2 v H2O theo t
l khi lng CO2 so vi khi lng nc =22/9. Xc nh cng thc n gin mi cht.
A. A v B :C3H6O B. A v B : C2H6O C. A v B : C3H8O
D. A v B : C4H10O E. Kt qu khc
p n : A.
Cu 12:. t chy mt ru a chc ta thu c H2O v CO2 vi t l s mol nH2O : nCO2 = 3: 2. Vy
ru l :
A. C2H6O B. C3H8O C. C2H6O2
D. C4H10O2 E. C2H6O3
p n : C.
Cu 13:. un nng t t hn hp 2 ru : C2H5OH v n-C3H7OH vi H2SO4 m c. S phn ng
xy ra :
A. 7 B. 8 C. 9 D. 10
E. Kt qu khc.
p n : C
Cu 14:. t chy hon ton 0,05 ml ru no X mch h cn 5,6 gam oxi to ra 6,6 CO2. Hy xc nh
cng thc phn t ca X.
A. C2H4(OH)2 B. C3H5(OH)3 C. C3H8O D. C3H6O
E. Kt qu khc.
p n : B.
Cu 15:. Hai hp cht hu c A, B to bi 3 nguyn t v u c 34,78% oxi v khi lng. Nhit

si A l 78,30C, ca B l 23,60C. Cng thc cu to ca A, B l :
A. C2H5OH, CH3OCH3 B. C2H5OH, C2H5OC2H5 C. CH3OH, CH3OCH3
D. C2H5OH, C3H5(OH)3 E. Kt qu khc
p n : A
Cu 16:. Cho 4 hp cht hu c A, B, C, D bn, mch cacbon lin tc. Khi lng phn t ca chng
lp thnh cp s cng. Khi t chy mt lng bt k mi cht u ch thu c CO2 v H2O. Khi
lng CO2 ln gp 1,8333 ln khi lng H2O. Cng thc cu to ca A, B, C, D l :
A. C3H8, C3H8O, C3H8O2, C3H8O3 B. C2H6, C3H8, C4H10, C5H12
C. C3H8O2, C3H8O, C3H8O3, C3H8O4 D. C3H8, C3H6, C3H4, C3H2.
E. Kt qu khc
p n : A.
Cu 17:. Pht biu no sau y ng :

(1) Phenol c tnh axit mnh hn etanol v nhn benzen ht e ca nhm -OH bng hiu ng lin hp
trong khi nhm -C2H5 li y e.
(2) Phenol c tnh axit mnh hn etanol v c minh ho bng phn ng phenol tc dng dung dch
NaOH cn etanol th khng.
(3) Tnh axit ca phenol yu hn H2CO3 v sc CO2 vo dung dch C6H5ONa ta s c phenol v
Na2CO3
(4) Phenol trong nc cho mi trng axit, qu tm ho
A. (1), (2). B. (2), (3). C. (1), (2), (3), (4) D. (1), (2), (3)
E. Kt qu khc.
p n : A.
Cu 18: t chy 1 mol 1 ru no cn 3,5 mol O2. Ru l :

A. C2H5OH B. C3H7OH C. C3H5OH
D. C3H5(OH)3 E. Kt qu khc.
p n :D
Cu 19: Polivinyl ancol l polime c th iu ch t monome no sau y :

A. CH2=CH-COOCH3 B. CH2=CH-OH C. CH2=CH-Cl
D. CH2=CH-OCOCH3 E. Kt qu khc.
p n : D
Cu 20:. Hn hp A gm 2 ru no n chc.Chia hn hp A thnh 2 phn bng nhau :

Phn 1 : Tc dng vi Na d thu c V(l) H2
Phn 2 : em t chy thu c 4,48 lt CO2 (kc) v 5,4 g H2O.
Xc nh V. (lt)
A. 1,12 B. 2,24 C. 3,36
D. 4,48 E. Kt qu khc.
p n : A.
Cu 21: Ancol C5H11OH khi oxi ho cho xeton. Cn khi tch nc cho anken m anken ny khi oxi
ho cho hn hp xeton v axit. Cng thc cu to ca ancol l :
A. (CH3)2CHCHOHCH3 B. CH3CH2CH2CH2CH2OH
C. (CH3)2COHCH2CH3 D. (CH3)2CH2CH2CH2OH
E. Kt \qu khc.
p n : A
Cu 22:.Mt hp cht cha bit cu to phn ng chm vi Na, khng b dung dch natri icromat oxi
ho. Phn ng nhanh vi axit clohric c to nn ankyl clorua cha 33,3% khi lng clo. Cng thc
cu to A l :
C. (CH3)2COHCH2CH3 D. (CH3)2CH2CH2CH2OH
E. Kt qu khc.
p n : C.

Cu 23:. Mt lng d Na tc dng vi hn hp ru etylic v phenol gii phng 6,72 lt H2. trung
ho hon ton hn hp cn 25ml dung dch KOH 40%(d=1,4 g/ml). Thnh phn % khi lng
ca phenol v ru l :
A. 40,7% v 59,3% B. 59,3% v 40,7% C. 40% v 60% D. 45,6% v 54,4%
E. Kt qu khc.
p n : B
Cu 24:. Khi ch ho 10,5 gam hirocacbon dy eten bng dung dch H2O ca KMnO4 thu c 15,2
gam ru 2 chc. Ru tc dng vi Na d gii phng 4,48 lt H2 (kc). Tnh hiu sut ca phn
ng th nht./
A. 20% B. 40% C. 60%
D. 80% E. Kt qu khc
p n : D
Cu 25:. Xc nh cng thc phn t ca ru no a chc cha 45,28% khi lng oxi.
A. C3H5(OH)3 B. C4H7(OH)3 C. C4H6(OH)4
p n : B
Cu 26:.Xc nh cng thc phenol c cha 13,11% khi lng oxi.

A.C6H6O B.C7H8O C.C8H10O D.C9H12O
E.Kt qu khc
p n :C
Cu 27:.Xc nh cht ban u trong dy sau:

C 4 H8 O C4H8Br2O C4H7Br3 C4H10O3
A.Buten-3-ol-2 B.Buten-3-ol-1 C.Buten-2-ol-1 D.2-metyl propenol
E.Kt qu khc
p n : A
Cu 28:.Xc nh cht X trong s sau:

ru isopropylic X 2,3-imetylbutan
A.(CH3)2CHCl B.CH3CH2CH2Cl C.CH2=CH-CH3 D.C3H7OC3H7
E.Kt qu khc
p n :A
Cu 29:.Trong cc cht sau:NaCl, I2, propanol, axeton cht no tan nhiu trong ru etylic?
A.Ch propanol B.Propanol v axeton C.I2,propanol,axeton D.I2
E.Kt qu khc
p n :C
Cu 30:Cht A c thnh phn C9H10O, khng phn ng vi NaOH nhng tc dng vi Na gii phng
H2.Cht A tc dng vi nc Br2 bin thnh hp cht C9H10Br2O, vi dung dch ngui ca KMnO4 to
hp cht C9H10O3. S ng phn ca A tho mn l:
A.3 B.4 C.5
D.6 E.Kt qu khc
p n :C
Cu 31:.Cho s sau: ru propylic X Y phenol

Cht Ycn tm l:
A.C6H5-i-C3H7 B.C6H5Cl C.C6H5ONa D.C6H5-n-C3H7
E.Kt qu khc
p n :A
Cu 32:Cho s sau, xc nh cht u dy:

C4H10O2 C4H8Cl2 C4H8 C4H10O
A.Butandiol-1,3 B.Butandiol-1,2 C.Butandiol-1,4 D.Butandiol-2,3
E.Kt qu khc
p n :B
Cu 33:.Khi oxi ho hon ton ru n chc ,thu c axit . trung ho 10gam axit cn 27ml
dung dch KOH 20%(d=1,18g/ml) .S cng thc ru ph hp l :
A.1 B.2 C.3
D.4 E.Kt qu khc
p n :B
Cu 34:Mt ru no n chc khi chy to nn mt th tch CO2 ln gp 8 ln th tch H2 thot ra khi

cng mt lng ru tc dng vi Na d .Tm CTCT ca ru bit trong phn t c 3 nhm -
CH3
A.(CH3)3COH B.(CH3)3C-CH2OH C.(CH3)2CH-

CH(CH3)OH D.(CH3)2CH-CH2OH E.Kt qu khc p n:A
Cu 35:.Kh thu c vi H=66,7% khi 50 gam ru no n chc tc dng vi H2SO4 c hp th

hon ton bi 1000gam KMnO4 to nn 26,1 gam kt ta .Xc nh CTPT ca ru .
A.C3H7OH B.C2H5OH C.C4H9OH D.CH3OH

E.Kt qu khc
p n: C
Cu 36:. dehidro ho hon ton 15,2 gam hn hp 2 ru no n chc ,cn 24 gam CuO.Hn hp
sn phm ,khi tc dng vi lng d Ag2O/NH3 ,to nn 86,4 gam kt ta .CTCT ca 2 ru l:
A.CH3OH ,CH3CH2CH2OH B.CH3OH,mt trong 3 ru bc hai ca C5H11OH
C.CH3OH,C2H5OH D.CH3OH,CH3CH2CH2CH2OH
E.Kt qu khc
p n: E
Cu 37:Khi nitro ho 10 gam phenol bng HNO3 50% thu c 17gam hn hp 2 hp cht nitro (2,3
ln th) trong nit chim 17%v khi lng .Xc nh hiu sut to thnh 2,4,6 -tri nitro phenol.
A.40% B.77,1% C.37,1%
D.70% E.Kt qu khc
p n :A
Cu 38:Xp cc ancol benzyl di y theo th t phn ng gim dn vi HBr : C6H5-CH2OH(1) ,

p-O2N-C6H4-CH2OH (2), p-CH3O-C6H4- CH2OH (3), p-Cl-C6H4-CH2OH (4).
A. (3), (2), (4), (1) B. (2), (3), (1), (4), C. (3), (1), (4), (2) D. (4), (3), (2), (1)
p n : C
Cu 39:Dung dch A gm : H2O, CH3OH, C2H5OH. S lin kt Hiro trong dung dch l :
A. 3 B. 6 C. 9 D. 12
E. Kt qu khc.
p n : C.
Cu 40:un nng hn hp A gm 10 ru no n chc vi H2SO4 c 1400C. S ete thu c l :

A. 35 B. 45 C. 50 D. 55
E. Kt qu khc.
p n : D.
Cu 41:.Cho mt dung dch ru trong hexan, cho Na vo dung dch c bao nhiu phn ng xy ra :
A. 1 B. 2 C. 3 D.4
E. Kt qu khc
p n : A
Cu 42:un nng t t hn hp 2 ru : C2H5OH v n-C3H7OH vi H2SO4 m c. S phn ng xy

ra :
A. 7 B. 8 C. 9 D. 10
E. Kt qu khc.
p n : C.
Cu 43:S ng phn cu to ca C8H18 l :

A. 17 B. 18 C. 19
D. 20 E. Kt qu khc
p n : B
Cu 44:. Sp xp theo th t mnh tng dn tnh axit ca cc cht cho sau y :

C6H5OH(1) p-CH3-O-C6H4OH(2) ; p- NO2-C6H4OH(3)
p-CH3- COC6H4OH(4) ; p-CH3-C6H4OH(5)
A. (4) (3) (2) (1) (5) B. (2) (5) (1) (4) (3) C. (2) (5) (4) (3) (1)
D. (2) (4) (3) (5) (1) E. Kt qu khc.
Cu 45:Hn hp X c phan trn t cc rc no n chc cng dy ng ng c s nguyn t

C <=4. Khi cho X tc dung vi Na thu c 5,6 lt H2, cn khi t chy hon ton X cn 47,04 lt O2. X
cha 2 ru. X c th l :
A. CH3OH, C3H7OH B. CH3OH, C4H9OH
C. C2H5OH, C3H7OH D. C2H5OH, C4H9OH E. Kt qu khc
p n : E.
Cu 46:.Hai cht hu c A v B cng cha cc nguyn t C, H, O. Khi t chy mi cht u phi
dng mt lng oxi bng 8 ln lng oxi c trong mi cht v thu c lng kh CO2 v H2O theo t
l khi lng CO2 so vi khi lng nc =22/9. Xc nh cng thc n gin mi cht.
A. A v B :C3H6O B. A v B : C2H6O C. A v B : C3H8O
D. A v B : C4H10O E. Kt qu khc
p n : A.
Cu 47:. t chy mt ru a chc ta thu c H2O v CO2 vi t l s mol nH2O : nCO2 = 3: 2. Vy

ru l :
A. C2H6O B. C3H8O C. C2H6O2
D. C4H10O2 E. C2H6O3
p n : C.
Cu 48:. t chy hon ton 0,05 ml ru no X mch h cn 5,6 gam oxi to ra 6,6 CO2. Hy xc nh
cng thc phn t ca X.
A. C2H4(OH)2 B. C3H5(OH)3 C. C3H8O D. C3H6O
E. Kt qu khc.
p n : B.
Cu 49:. Hai hp cht hu c A, B to bi 3 nguyn t v u c 34,78% oxi v khi lng. Nhit
si A l 78,30C, ca B l 23,60C. Cng thc cu to ca A, B l :
A. C2H5OH, CH3OCH3 B. C2H5OH, C2H5OC2H5 C. CH3OH, CH3OCH3
D. C2H5OH, C3H5(OH) E. Kt qu khc
p n : A.
Cu 50:. Cho 4 hp cht hu c A, B, C, D bn, mch C lin tc. Khi lng phn t ca chng lp
thnh cp s cng. Khi t chy mt lng bt b mi cht u ch thu c CO2 v H2O. Khi lng
CO2 ln gp 1,8333 ln khi lng H2O. Cng thc cu to ca A, B, C, D l :
A. C3H8, C3H8O, C3H8O2, C3H8O3 B. C2H6, C3H8, C4H10, C5H12
C. C3H8O2, C3H8O, C3H8O3, C3H8O4 D. C3H8, C3H6, C3H4, C3H2
E. Kt qu khc
p n : A.
Cu 51:. Pht biu no sau y ng :

(1) Phenol c tnh axit mnh hn etanol v nhn benzen ht e ca nhm -OH bng hiu ng lin hp
trong khi nhm -C2H5 li y e.
(2) Phenol c tnh axit mnh hn etanol v c minh ho bng phn ng phenol tc dng dung dch
NaOH cn etanol th khng.
(3) Tnh axit ca phenol yu hn H2CO3 v sc CO2 vo dung dch C6H5ONa ta s c phenol v
Na2CO3
(4) Phenol trong nc cho mi trng axit, qu tm ho
A. (1), (2). B. (2), (3). C. (1), (2), (3), (4) D. (1), (2), (3)
E. Kt qu khc.
p n : A.
Cu 52:. t chy 1 mol 1 ru no cn 3,5 mol O2. Ru l :

A. C2H5OH B. C3H7OH C. C3H5OH D. C3H5(OH)3
E. Kt qu khc.
p n :D
Cu 53:Polivinyl ancol l polime c th iu ch t monome no sau y :

A. CH2=CH-COOCH3 B. CH2=CH-OH C. CH2=CH-Cl
D. CH2=CH-OCOCH3 E. Kt qu khc.
p n : D
Cu 54:Hn hp A gm 2 ru no n chc.Chia hn hp A thnh 2 phn bng nhau :

Phn 1 : Tc dng vi Na d thu c V(l) H2
Phn 2 : em t chy thu c 4,48 lt CO2 (kc) v 5,4 g H2O.
Xc nh V. (lt)
A. 1,12 B. 2,24 C. 3,36
D. 4,48 E. Kt qu khc.
p n : A.
Cu 55:Ancol C5H11OH khi oxi ho cho xeton. Cn khi tch nc cho anken m anken ny khi oxi
ho cho hn hp xeton v axit. Cng thc cu to ca ancol l :
C. (CH3)2COHCH2CH3 D. (CH3)2CHCH2CH2OH E. Kt \qu khc.
p n : A
Cu 56:.Mt hp cht cha bit cu to phn ng chm vi Na, khng b dung dch natri icromat oxi
ho. Phn ng nhanh vi axit clohric c to nn ankyl clorua cha 33,3% khi lng clo. Cng thc
cu to A l :
C. (CH3)2COHCH2CH3 D. (CH3)2CH2CH2CH2OH E. Kt qu khc.
p n : C.
Cu 57:Mt lng d Na tc dng vi hn hp ru etylic v phenol gii phng 6,72 lt H2. trung
ho hon ton hn hp cn 25ml dung dch KOH 40%(d=1,4 g/ml). Thnh phn % khi lng
ca phenol v ru l :
A. 40,7% v 59,3% B. 59,3% v 40,7% C. 40% v 60% D. 45,6% v 54,4%
E. Kt qu khc.
p n : B
Cu 58:Khi ch ho 10,5 gam hirocacbon dy eten bng dung dch H2O ca KMnO4 thu c 15,2
gam ru 2 chc. Ru tc dng vi Na d gii phng 4,48 lt H2 (kc). Tnh hiu sut ca phn
ng th nht./
A. 20% B. 40% C. 60%
D. 80% E. Kt qu khc
p n : D
Cu 59:Xc nh cng thc phn t ca ru no a chc cha 45,28% khi lng oxi.
A. C3H5(OH)3 B. C4H7(OH)3 C. C4H6(OH)4
p n : B
Cu 60:Xc nh cng thc phenol c cha 13,11% khi lng oxi.
A.C6H6O B.C7H8O C.C8H10O
D.C9H12O E.Kt qu khc
p n :C
Cu 61:.Xc nh cht ban u trong dy sau:

C 4 H8 O C4H8Br2O C4H7Br3 C4H10O3
A.Buten-3-ol-2 B.Buten-3-ol-1 C.Buten-2-ol-1 D.2-metyl propenol
E.Kt qu khc
p n : A
Cu 62:. Cho ru : CH3OH, C2H5OH, C3H7OH. Ch dng thm mt cht no sau y nhn bit :
A.H2SO4 m c, 1400C B. H2SO4 m c 1700C
C. Kim loi kim D. CH3COOH , H2SO4 m c
E. Kt qu khc.
p n :C
Cu 63:.Xc nh cht X trong s sau:

ru isopropylic X 2,3-imetylbutan
A.(CH3)2CHCl B.CH3CH2CH2Cl C.CH2=CH-CH3 D.C3H7OC3H7
E.Kt qu khc
p n :A
Cu 64:Trong cc cht sau: NaCl, I2, propanol, axeton cht no tan nhiu trong ru etylic?
A.Ch propanol B.Propanol v axeton C.I2,propanol,axeton D.I2
E.Kt qu khc
p n :C
Cu 65:Cht A c thnh phn C9H10O,khng phn ng vi NaOH nhng tc dng vi Na gii phng
H2.Cht A tc dng vi nc Br2 bin thnh hp cht C9H10Br2O,vi dung dch ngui ca KMnO4 to
hp cht C9H10O3. S ng phn ca A tho mn l:
A.3 B.4 C.5 D.6
E.Kt qu khc
p n :C
Cu 66:Cho s sau: ru propylic X Y phenol

Cht Ycn tm l:
A.C6H5-i-C3H7 B.C6H5Cl C.C6H5ONa D.C6H5-n-C3H7
E.Kt qu khc
p n :A
Cu 67:Cho s sau,xc nh cht u dy:

C4H10O2 C4H8Cl2 - C4H8 C4H10O
A.Butandiol-1,3 B.Butandiol-1,2 C.Butandiol-1,4 D.Butandiol-2,3
E.Kt qu khc
p n :B
Cu 68:.Khi oxi ho hon ton ru n chc ,thu c axit . trung ho 10gam axit cn 27ml
dung dch KOH 20%(d=1,18g/ml) .S cng thc ru ph hp l :
A.1 B.2 C.3
D.4 E.Kt qu khc
p n :B
Cu 69:Cho 1 lt cn 920 tc dng vi Na d. Bit rng ru etylic nguyn cht c d = 0,8 g/ml, tnh
th tch H2 to ra ktc
A. 179,2 lt B. 224 lt C. 228,98 lt
D. 280 lt E. Kt qu khc.
p n : C
Cu 70:Mt ru A mch h khng lm mt mu nc Br2. t chy a(lt) hi ru A cn 2,5a (lt)

cng iu kin. Xc nh cng thc cu to ca A :

A. CH3OH B. C2H5OH C. C2H4(OH)2 D. C3H5(OH)3
E. Kt qu khc
p n : C
Cu 71:.Mt ru no n chc khi chy to nn mt th tch CO2 ln gp 8 ln th tch H2 thot ra khi

cng mt lng ru tc dng vi Na d .Tm CTCT ca ru bit trong phn t c 3 nhm -
CH3
A.(CH3)3COH B.(CH3)3C-CH2OH C.(CH3)2CH-CH(CH3)OH

D.(CH3)2CH-CH2OH E.Kt qu khc
p n:A
Cu 72:.Kh thu c vi H=66,7% khi 50 gam ru no n chc tc dng vi H2SO4 c hp th

hon ton bi 1000gam KMnO4 to nn 26,1 gam kt ta .Xc nh CTPT ca ru .
A.C3H7OH B.C2H5OH C.C4H9OH D.CH3OH E.Kt
qu khc
p n: C
Cu 73: dehidro ho hon ton 15,2 gam hn hp 2 ru no n chc ,cn 24 gam CuO.Hn hp
sn phm ,khi tc dng vi lng d Ag2O/NH3 ,to nn 86,4 gam kt ta .CTCT ca 2 ru l:
A.CH3OH ,CH3CH2CH2OH B.CH3OH,C2H5OH
C.CH3OH,CH3CH2CH2CH2OH D.Kt qu khc
p n: D
Cu 74:.Khi nitro ho 10 gam phenol bng HNO3 50% thu c 17gam hn hp 2 hp cht nitro (2,3
ln th) trong nit chim 17%v khi lng .Xc nh hiu sut to thnh 2,4,6 -tri nitro phenol.
A.40% B.77,1% C.37,1% D.70%
p n :A
chung cho cu 75 - 76 -77 :

C mt hn hp gm 2 ru no n chc mch h. Nu em m gam hn hp ny t chy thu c
mt lng CO2 v H2O l 4,7 gam. Cn nu em oxi ho n axit ri em trung ho bng dung dch
NaOH 0,1 M th ht 200ml. Bit mt trong 2 axit to ra c phn t lng bng phn t lng ca 1
trong 2 ru cho.
Cu 75:Cng thc 2 ru cho l :
A. CH3OH, C2H5OH B. C2H5OH, C3H7OH
C.C3H7OH, C4H9OH D. C2H5OH, C4H9OH.
p n : C.
Cu 76:Tng s ng phn ca 2 ru :
A. 4 B. 5 C. 6 D. 7
p n : C.
Cu77:. Tng khi lng ca 2 ru l :
A. 1,3g B. 1,6g C. 1,34g D. 1,7g
p n : C.
D kin sau dng cho cu 78-79-80:
Chia 22 gam ru no n chc k tip thnh 2 phn bng nhau :
*t chy hon ton phn 1 thu c V(l) CO2 v m)g) H2O
*Phn 2 cho tc dng ht vi Na thu c 3,36 lt H2(kc)
Cu 78:. Xc nh V (l):
A. 2,24 B. 3,36 C. 4,48 D. 8,96
p n : C
Cu 79:. Xc nh khi lng 2 ru :
A. 7,2g B. 1,8g C. 12,6g D. 1,8g
p n : C
Cu 80:Xc nh cng thc 2 ru :
A. CH3OH, C2H5OH B. C2H5OH, C3H7OH,
C.C3H7OH, C4H9OH D. Kt qu khc.
p n : A.
Cu 81:. Cho s : etanol -> X1->X2->axit lactic. Cht X1 l :

A. CH2=CH2 B. C2H5Cl C.CH3CHO D. C2H5CN
p n : C
Cu 82:S ng phn ca hp cht thm C7H8O l :

A. 2 B. 3 C. 4 D. 5
p n : B
Cu 83:Vit cng thc cu to c th c ca cht A c thnh phn C4H10O, khi tc dng vi HBr bin
thnh cht B c thnh phn C4H9Br. Cht B phn ng vi dung dch ru trong KOH bin thnh C c
thnh phn C4H8. Cht C tc dng vi H2O khi c mt H3PO4 to thnh cht c thnh phn C4H10O.
Sn phm oxi ho ca A khng cho phn ng trng gng. A l :
A. (CH3)2CH-CH2OH B. CH3-CHOH-CH2-CH3
C. (CH3)3C-OH D. CH3-CH2-CH2-CH2OH E. Kt qu khc
p n : B.
Cu 84:Khi hirat ho hn hp anken A thu c 2 sn phm ru. Hn hp A c th l :

A. C2H4 v C3H6 B. CH3-CH=CH-CH3, C2H4
C. CH3-CH2-CH=CH-CH2-CH3, C3H6 D. CH3-CH=CH-CH3, CH2=C(CH3)2
E. Kt qu khc.
p n : B.
Cu 85:Khi em hirat ho gia cc phn t mt hn hp 2 ru n chc, cha bit cu to, thu c
10,8 g nc v 36g hn hp ca 3 hp cht hu c c cng lng mol v thuc cng mt li hp cht
hu c. (H=100%). Cng thc ca ru l :
A. CH3OH v C2H5OH B. C4H8OH v C5H11OH
C. C2H5OH, C3H7O D. CH3OH v C3H7OH
E. Kt qu khc,
p n : A.
D kin sau dng cho cu 86-87:

Mt hn hp ru no v ng ng ca phenol c khi lng 2,82 gam. C th phn ng vi 320 g Br2
1,5%. Cng lng hn hp , khi cho tc dng vi Na (d) thu c 481 ml H2 (t0-200C)
Cu 86:. Cng thc phn t cc cht l :
A. C3H5OH v C7H8O B. CH3OH v C9H12O
C. C2H5OH v C8H10O D. C3H8O v C4H9OH E. Kt qu khc.
p n : A.
Cu 87:.% s mol ca cc cht l (cht c M ln trc )
A. 75% v 25% B. 60% v 40% C. 25% v 75%
D. 40% v 60% E. Kt qu khc.
p n : C.
Cu 88:t chy hon ton 1 mol 1 ru no cn 2,5 mol O2. Cng thc phn t ru l :
A. C2H5OH B. C3H5(OH)3 C. C2H4(OH)2
D. C3H5(OH) E. Kt qu khc.
p n : C.
Cu 89:un 132,8 gam hn hp gm 3 ru no n chc vi H2SO4 m c 1400C thu c hn

hp cc ete c s mol bng nhau v c khi lng l 111,2 gam. S mol mi ete l :
A. 0,1 B. 0,2 C. 0,3
D. 0,4 E. Kt qu khc
p n :B
Cu 90:Cho 3,38 g hn hp Y gm CH3OH, CH3COOH, C6H5OH tc dng va vi Na thy thot

ra 672 ml kh ktc. Hn hp rn Y1. Khi lng Y1 l :
A. 3,61g B. 4,7g C. 4,76g
D. 4,04g E. Kt qu khc
p n:B
Cu 91:Hn hp CH3OH, C2H5OH, phenol c khi lng 28,9g. Chia i hn hp thnh 2 phn bng
nhau lm hai th nghim. Phn mt phn ng hon ton vi Na thu c 2,806 lt H2 270C,
750mm Hg. Phn 2 phn ng va ht vi 100 ml dung dch NaOH 1M. Phn trm theo khi lng
phenol ta c l :
A. 36,87% B. 65,05% C. 76,89% D. 12,34%
E. 32,65%
p n :B
D kin sau dng cho cu 92-93-94
Chia hn hp X gm 2 ru no n chc thnh 2 phn bng nhau
Phn 1: b t chy hon ton to ra 5,6 lt CO2 (kc) v 6,3 gam H2O
Phn 2 : tc dng ht vi Na th thy thot ra V lt kh (ktc)
Cu 92:Ta c th tch V l :
A. 1,12 l B. 0,56 l C. 2,24 l D. 1,68 l
p n:A
Cu 93:Nu 2 ru n chc trn l ng ng lin tip th cng thc ca chng l :

A.C3H6O v C4H8O B.CH3OH,C2H5OH C.C4H10O,C5H12O
D.C2H5OH,C3H7OHp n :D
Cu 94:Thnh phn %theo khi lng ca 2 ru l:

A.43,4%v 56,6% B.25% v 75% C.505 v 50% D.44,77% v 55,23%
p n :A
Cu 95:t chy hon ton m gam ru C, ri cho sn phm chy vo bnh ng Ca(OH)2 d thy
khi lng bnh tng ln p gam v c t gam kt ta .Bit rng p=0,71t v t=(m+p)/1,02 th ru C l:
A.Ru etylic B.Propylen glicol 1,2 C.Glyxerin D.etylen glicol
p n:D
Cu 96:Mt ru no a chc X mch h c n nguyn t C v m nhm OH trong cu to phn t. Cho
7,6 gam rc trn phn ng vi lng d Na, thu c 2,24 lt kh (ktc)
Lp biu thc lin h gia n v m.
A. 7n + 1 = 11m B. 4n + 1 = 10m C. 7n + 4 = 12m D. 7n + 2 = 14
p n :A
Cu 97:HCHC mch h ng vi cng thc tng qut CnH2nO l :

A: axitcacboxilic no n chc B: Ancol no n chc
C: este no n chc D: andehit no n chc
p n:D
Cu 98:Ngi ta iu ch ru etylic t xenlulozo vi hiu sut ca c qu trnh l 60% th khi lng
ru thu c t 32,4 g xenlulozo l :
A: 11,04 g B: 30,67 g
C: 12,04 g D: 18.4 g
p n:A
Cu 99: Cho cc cht CH3CHO(1), C2H5OH(2), CH3COOH(3) th t sp xp theo chiu tng dn
nhit si l:
A: 2,1,3 B: 2,3,1
C: 1,2,3 D: 3,1,2
p n C
Cu 100: Cho cc dung dch sau CH3COOH, C2H4(OH)2, C3H5(OH)3, glucozo, saccarozo, C2H5OH s
lng dung dch c th ha tan c Cu(OH)2 l:
A: 4 B: 5
C: 6 D: 3
p n B
Cu 101: Cng thc cu to ca Propan-1,3-diol l:
A: HO-CH2-CH(OH)-CH2OH B: HO-CH2-CH2-CH2-OH
C: CH3-CH(OH)-CH2-CH2-OH D: HO-CH2-CH(OH)-CH3
p n B
Cu 102: Cho cc hp cht thm: C6H5OH(1), CH3-C6H3(OH)2(2), C6H5CH2OH(3).
Cht no thuc loi phenol
A: 2 v 3 B: 1
C: 1 v 2 D: 2
p n C
Cu 103: t chy hon ton 7,6g 2 ru n chc mch h lin tip trong cng dy ng ng thu
c 7,84 lt CO2(ktc) v 9g H2O cng thc phn t 2 ru l
A: CH3OH. C2H5OH B: C2H5OH, C3H7OH
C: C3H7OH, C4H9OH D: C4H9OH, C5H11OH
p n B
Cu 104: Phn ng no sau y c th xy ra:
A: C6H6 + Br2 (H2O) B: C6H5OH + Br2 (H2O)

C: CH3COOH + C6H5OH D: c 3 phn ng trn
p n B
Cu 105: Cho cc ru sau n-butylic(1), sec-butylic(2), izo-bulylic(3), tert-butylic(4) th t gim dn
nhit si l:
A: 1,2,3,4 B: 1,3,2,4

C: 4,2,3,1 D: 4,3,2,1
p n B
Cu 106: Ru no sau y khi tch nc thu c sn phm chnh l 3-Metylbuten-1
A: 2-Metylbutanol-1 B: 2-metylbutanol-2
C: 3-metylbutanol-2 D: 3-metylbutanol-1
p n D
Cu 107: Ha tan 92g ru etylic vo nc thu c 250ml dung dch A bit khi lng ring ca
ru nguyn cht l 0,8 g/ml tnh ru ca dung dch A.
A: 40 B: 46
C: 50 D: kt qu khc
ap n B
Cu 108: Tc ca nhng phn ng lm t lin kt O-H gim dn theo th t
A:Ru bc1>Ru bc2>Ru bc3 B: Ru bc2>Ru bc1>Ru bc3
C: Ru bc3>Ru bc2>Ru b1 D: khng ph thuc vo bc ru
p n A
Cu 109:: un 132,8 g hn hp 3 ru no n chc vi H2SO4c 140 C cho n khi phn ng
hon ton thu c 111,2 g hn hp cc ete c s mol bng nhau. Tnh s mol mi ete
A: 0.1 B: 0,2
C: 0,3 D: Kt qu khc
p n B
Cu 110:: Nha phenolfomandehit c iu ch bng cch un nng phenol (d) v dung dch :
A: CH3CHO trong mi trng axit B: CH3COOH trong mi trng axit
C: HCOOH trong mi trng axit D: HCHO trong mi trng axit
p n D
Cu 111; C th dng Cu(OH)2 phn bit cc cht trong nhm
A: glixerin v saccarozo B: C3H7OH v CH3CHO
C: CH3COOH v C2H3OH D: C3H5(OH)3 v C2H4(OH)2
p n : B
Cu 112; tch ring tng cht t hn hp benzen, anilin, phenol ta ch cn dng cc ho cht (dng
c, iu kin th nghim y ) l :
A. dung dch NaOH, dung dch HCl, kh CO . B. dung dch Br , dung dch NaOH, kh CO .
2 2 2
C. dung dch Br , dung dch HCl, kh CO . D. dung dch NaOH, dung dch NaCl, kh CO .
2 2 2
p n : A
Cu 113;Cho 0,1 mol ru X phn ng ht vi Na d thu c 2,24 lt kh H2 (ktc). S nhm chc -
OH ca ru X l :
A. 4. B. 3. C. 2. D. 1.
p n:C
Cu 114: Cho 11 gam hn hp hai ru no n chc, k tip nhau trong dy ng ng tc dng ht
vi Na d thu c 3,36 lt H2 (ktc). Hai ru l
A. C2H5OH v C3H7OH. B. C3H7OH v C4H9OH.
C. C4H9OH v C5H11OH. D. CH3OH v C2H5OH.
p n :D
Cu 115:Cho m gam glucoz ln men thnh ru etylic vi hiu sut 80%. Hp th hon ton kh CO2
sinh ra vo dung dch nc vi trong d thu c 20 gam kt ta. Gi tr ca m l
A. 45. B. 22,5.
C. 14,4. D. 11,25.

p n B
Cu 116: Dy gm cc cht u phn ng c vi C2H5OH l
A. Na, HBr, CuO. B. Na, Fe, HBr.
C. NaOH, Na, HBr. D. CuO, KOH, HBr.
p n A
Cu 117:Cc ru (ancol) no n chc tc dng c vi CuO nung nng to anehit l
A. ru bc 2. B. ru bc 3.
C. ru bc 1. D. ru bc 1 v ru bc 2.
p n C
Cu 118:Dy ng ng ca ru etylic c cng thc chung l
A. CnH2n +2 - x(OH)x (n x, x>1). B. CnH2n - 7OH (n 6).
C. CnH2n - 1OH (n 3). D. CnH2n + 1OH (n 1).
p n D
Cu 119: Hn hp X gm 3 ru n chc A,B,C trong B,C l 2 ru ng phn. t chy hon
ton 0,08mol X thu c 3,96 g H2O v 3,136 lt kh CO2 (ktc). S mol ru A bng 5/3 tng s mol
ru B+C. Vy cng thc phn t cc ru l :
A: CH4O v C3H8O B: CH4O v C3H6O.
C: CH4O v C3H4O D: C A,B,C u c th ng
E: c 4 cu trn u sai
p n :A
Cu 120: Cho 18,32 g 2,4,6 trinitro phenol vo mt chai bng gang c th tch khng i 560 cm3. t
kp n vo chai ri cho n 1911 C. tnh p sut trong bnh ti nhit bit rng sn phm n l
hn hp CO, CO2,N2,H2 v p sut thc t nh hn p sut l thuyt 8%.
A: 207,36 atm B: 211,968 atm
C: 201 atm D: 236,4 atm
E: tt c u sai
p n :B
Cu 121: un nng hn hp gm 2 ru no n chc vi H2SO4 m c 140 C thu c 21,6 g
H2O v 72 g hn hp 3 ete( 3 ete thu c c s mol bng nhau). CTCT 2 ru l:
A: CH3OH, CH3CH2CH2OH B: (CH3)2CHOH, CH3CH2CH2OH
C: CH3OH, C2H5OH D: (CH3)2CHOH, C2H5OH
E: C2H5OH, CH3CH2CH2OH
p n :C
Cu 122: Tch nc hon ton hn hp X thu c hn hp Y gm cc olephin. Nu t chy hon
ton X thi thu c 1,76 g CO2 th khi t chy hon ton Y tng khi lng H2O v CO2 to ra:
A: 2.,94g B 2,48g
C:1,76. g D 2,76 g
E 1,8g
p n:B
Cu 123:A v B l 2 ru no k tip nhau trong dy ng ng. Cho hn hp gm 1,6 g A v 2,3 g B
tc dng ht vi Na thu c 1,12 lt H2(dkc). CTPT 2 ru l:
A CH3OH, C2H5OH B C3H8OH, C2H5OH
C C3H8OH, C4H9OH D C4H9OH, C8H11OH
p n :A
Cu 124: Chia a g hn hp 2 ru no n chc thnh 2 phn bng nhau.
Phn 1: t hon ton thu c 2,24 lt CO2
Phn 2: tch nc hon ton thu c 2 anken. t chy hon ton 2 anken ny thu c m g H2O.
m c gi tr:
A .0,18 B .1,8
C. 8,1 D. 0,36
p n:B
Cu 125: cng thc phn t ca ru A l CnHmOx. cho A l ru no th m phi c gi tr:
A. m=2n +x B. m=2n+2-x
C. m=2n-1 -x D. m=2n+1-x
ap n B
Cu 126: t chy 1 mol ru no X mch h cn 56 lt O2(kc). Xc nh cng thc cu to ca X
A: C3H5(OH)3 B: C2H4(OH)2
C: C3H6(OH)2 D: kt qu khc
p n :B
Cu 127: Trn 1 ru metylic v ru etylic ri tin hnh un nng c mt axit H2SO4 m c ta thu
c ti a bao nhiu hp cht hu c
A.3 B.4
C.5 D.Kt qu khc
p n : D
Cu 128: Benzen khng phn ng vi Br2 nhng phenol lm mt mu Br2 rt nhanh v:
A: phenol c tnh axit.
B: tnh axit ca phenol yu hn c axit cacbonic
C: phenol l dung mi hu c phn cc hn benzen
D:do nh hng ca nhm OH cc v tr octo v para trong phenol giu in tch m to iu
kin cho Br2 tn cng
p n :D
Cu 129: un ru A n chc vi H2SO4 c thu c hp cht hu c B c dB/A= 0,7. xc nh
CTPT ca A
A. C3H5OH B .C3H7OH
C .C4H7OH D.C4H9OH
p n :B
Cu 130: Cho cc cht sau Butan-1-ol(1) pental-1-ol(2) v hexan-1-ol(3)
Sp xp cc cht theo th t tng dn kh nng tan trong trong nc :
A: 1<2<3 B:3<2<1.
C: 2<1<3 D:3<1<2
p n :B
Cu 131: Hp cht no c tnh axit mnh nht
A: phenol B: ru metylic
C: 2,4,6-Trinitrophenol D: 2,4,6-Trimetylphenol
p n:C

CHNG III: ANEHIT - AXIT ESTE
Cu 1: Tnh cht c trng cu fomandehit:

1. Cht lng 2. C mi xc
3. Rt c 4. Khng tan trong nc
tham gia cc phn ng:
5. Oxi ho 6. Kh
7. Este ho 8. Trng hp
9. Trng ngng 10. Trng bc
A. 1,3,5,7 B. 1,4,7 C. 4,7,9,10 D. 3,6,7,9
Cu 2: un este C4H6O2 vi dung dch HCl c sn phm c phn ng trng bc. E l:
A. Vinyl axetat B. Propyl fomiat C. Alyl fomiat D. a,b,c ng
Cu 3: X gm 2 axit cacboxylic no n chc ng ng k tip A v B. p (g) X tc dng va vi
100 ml NaOH 2M, phn ng xong c cn dung dch c 15 g hn hp 2 mui hu c khan. CTPT v
phn trm khi lng ca 2 axit l:
A HCOOH 43.4% V CH3COOH 56.6 %
B. HCOOH 50% V CH3COOH 50%
C. HCOOH 25% V CH3COOH 75 %
D. HCOOH 33.3% V CH3COOH 67.7 %
Cu 4: CTPT A C4H8O2 tc dng vi NaOH to thnh B c CTPT C4H7O2Na. A thuc loi:
A. Hp cht diol B. Axit cacboxylic C. Este n chc D.Khng xc nh
Cu 5: Cho s : X (anehit ) Y Z HCHO. Cc cht X, Y, Z s l :
A. HCHO, CH3ONa,CH3OH B. CH3CHO, CH3COONa,CH4
C. CH3CHO, CH3COOH, CH4 D. HCHO, CH3OH, HCOOCH3
Cu 6: Trn m1 g mt ru n chc vi m2 g 1 axit n chc, chia hn hp thnh 3 phn bng nhau :
- Phn 1 tc dng ht vi Na thot ra 3,36 l H2(ktc)
- t hon ton phn 2 c 9,6 g CO2
- Phn 3 un nng vi H2SO4 c c 10,2 g este, H=100%. t 5,1 g este c 11 g CO2 v 4,5 g
H2O. CTPT ca ru v axit l:
A. CH3OH, HCOOH B. C2H5OH, C2H5COOH
C. C2H5OH, CH3COOH D. CH3OH, C3H7COOH
Cu 7: A l este n chc, dA/CO2 =2. Thy phn A c ru B, dB/A = 0,522. A l:
A. n - propyl fomiat B. metyl axetat
C. metyl propionat D. etyl axetat
Cu 8: S ng phn amin bc 1, bc2, bc 3 ca C4H11N
A. 3,3,1 B. 4,3,1 C. 3,2,1 D. 4,1,1
Cu 9: Th t iu ch axit axetic (A) l: axetanehit (B), metan (D), axetilen (E):
A. B D E A B. D E B A
C. A B C D D. D B E A
Cu 10: Hidro ha hon ton 1,56 g 1 ankin (A) thu c 1 andehit (B). Trn (B) vi 1 andehit n
chc (C). Thm nc c 0,1 lit dung dch (D) cha (B) v (C) vi CM tng cng l 0,8M. Thm
t t vo dung dch (D) dung dch AgNO3 trong NH3 d c 21,6 g Ag. CTCT v CM ca (B) v (C)
trong dung dch (D) l:
A.CH3CHO 0,06 M, HCHO 0,02 M
B.CH3CHO 0,1 M, C2 H5OH 0,2 M
C.CH3CHO 0,1 M, HCHO 0,15 M
D.CH3CHO 0,08 M, HCHO 0.05 M
Cu 11: Nhn nh 2 hp cht : HCOOCH3 (A), CH3COOH (B). Ch ra iu sai:
A. Hn hp A,B c th cho c phn ng trng gng
B. a mol hn hp A,B tc dng va vi a mol NaOH
C. a mol hn hp A,B chy ht cho ra 2a mol CO2
D. Tt c u sai
Cu 12: Este CH3COOCH=CH2 do cc cht no sau y phn ng vi nhau to thnh :
A. CH3COOH v CH2 = CH2 B. CH3COOH v CH2 = CH - OH
C. CH3COOH v C2H2 D. CH3COOH v CH2 = CH - Cl
Cu 13: Este C c cng thc RCOOR' (R c 6 nguyn t C) c t khi hi i vi O2 b hn 4,5. Khi
x phng ha X bng dung dch NaOH c 2 mui c t l khi lng l 1.4146. CTCT ca X l:
A. HCOOC6H5 B. CH3COOC6H5 C. C2H5COOC6H5 D. C3H7COOC6H5
Cu 14: X v Y l axit cacboxylic no n chc k tip nhau trong dy ng ng. Nu cho hn hp
gm 4,6 g X v 6 g Y tc dng ht vi Na c 2,24 lit H2 (ktc). CTPT X,Y l:
A. HCOOH ,CH3COOH B. C2H5COOH, C3H7COOH
C. CH3COOH,C2H5COOH D. C3H7COOH, C4H9COOH
Cu 15: un este E (C4H6O2) vi dung dch NaOH c 1 mui c M=126. CTCT ng nht l:
A. CH3COOC2H5 B. C2H3COOCH3
C. CH3COOCH=CH2 D. CH3COOH
Cu 16: A,B l cc hp cht hu c n chc cha C,H,O. A(cng nh B) u cho phn ng trng
gng v phn ng vi NaOH. t 1 mol A (cng nh B) c khng n 3 mol CO2. A, B c th l:
A. HCOOH, CH3COOH B. HCOOH, OHC-COOH
C. HCOOCH3, OHC-COOH D. Tt c u sai
Cu 17: Cho s : HCHO A CH3-CH(OH)-COOH. A l :
A. Axit fomic B. 2-hidroxi etanal C. Ru mtylic D. Glucoz
Cu 18: X phng ha este vinyl axetat c:
A. Axetilen B. Eten C. CH2=CH-OH D. Axetandehit

Cu 19: Ru n chc X mch h tc dng vi HBr d c cht Y (C,H,O) trong Br chim
69,56%. MY< 260vC. CTPT Y l :
A. C5H10Br B. C5H8Br C. C5H10Br2 D. C5H8Br2
Cu 20: Cht A c MA< 170. t hon ton 0,486 g A c 405,2 ml CO2 v 0,27 g H2O. A tc dng
vi NaHCO3 v Na u sinh ra cht kh c s mol bng s mol A. CTCT ca A l :
A. HOC2H4COOC2H4 COOH B. HOC2H4COOCH2COCH2OH
C. A, B ng D. Kt qu khc
Cu 21: Cho cc cht CH3CH2COOH (1) ,CH3COCOOH (2), CH3CH(OH)COOH (3). Th t tng dn
tnh axit l :
A. (1) < (2) < (3) B. (1) < (3) < (2) C. (3) < (2) < (1) D. (2) < (3) < (1)
Cu 22: C 5 l ng ring bit cc cht : cumen hay iso propyl benzen (A), ancol benzylic (B) , metyl
phenyl ete (C) , benzanehit (D) v axit benzoic (E). Bit A, B, C, D, E l cc cht lng . Th t tng
dn nhit si ca cc cht trn l :
A. (A) < (C) < (D) < (B) < (E) B. (C) < (D) < (A) < (B) < (E)
C. (D) < (C) < (A) < (B) < (E) D. (D) < (A) < (C) < (B) < (E)
Cu 23: t chy hon ton 0,1 mol cht A l mui Na ca axit hu c (mch h, khng phn nhnh )
thu c H2O, Na2CO3 v 0,15 mol CO2. CTPT ca A l :
A. C4H4O2Na2 B. C3H3O6Na3 C. C2H3O2Na D. C A, B, C
Cu 24: Cc pht biu sau ,pht biu no ng :
1. Nhng cht hu c c kh nng tham gia phn ng trng gng l anehit
2. HCHO va c tnh oxi ho, va c tnh kh
3. Do nh hng y e ca nhm C=O ln nhm -OH , CH3COOH l mt axit
A. 1, 2 B. 2, 3 C. 1, 2, 3 D. p n khc
Cu 25: Axit axetic c th c iu ch bng phng php no trong cng nghip
A. Chng g B. Tng hp t axetilen
C. C A v B D. Cho Natri axetat tc dng vi H2SO4
Cu 26:Mt hp cht hu c A c CTPT l C4H6O2 v ch cha mt nhm chc. T A v cc cht v
c khc, bng 3 phn ng lin tip c th iu ch cao su Buna . CTCT ca A l :
A. HO - CH2 - C C - CH2OH B. OHC - CH2 - CH2 - CHO
C. CH3 - CH = CH - COOH D. Tt c u sai
Cu 27: Cho cc cht : axit axetic (1), phenol (2), ru tylic (3) v axit oxalic (4). Nhng cht no
phn ng c vi KOH v K2CO3
A. (1), (2), (4) B. (1), (2) , (3) C. (1), (3) ,(4) D. (1), (4)
Cu 28: C 4 l ng 4 cht hu c th lng l : ru benzylic (A), metyl phenyl ete (B),
benzanehit (C), axit axetic (D). Trong qa trnh bo qun cc cht trn, c mt l ng cht lng thy
xut hin tinh th , l l :
A. (A) B. (B) C. (C) D. (D)
Cu 29: Este A c to bi axit no 2 chc v mt ru no 3 chc. A khng cha chc no khc ngoi
chc este. Hm lng nguyn t H trong A l 2,89%. CTPT ca A l :
A. C12H10O12 B. C3H14O6 C. C10H12O9 D. p n khc
Cu 30: A l mt axit hu c n chc mch h, dn xut ca anken. t 1,72g A phi dng ht 2,016
lit O2(ktc). CTPT ca A l :
o
Cu 31: Hp cht A l este n chc, thu phn A bng NaOH ,t c cc sn phm u tham gia
phn ng trng gng. CTCT c th c ca A l :
A. CH3COOCH=CH2 B.HCOOCH3
C. HCOOCH=CH-CH3 D. C A, B, C u ng

Cu 32: t chy 5,4 g ankanal c cng s mol thu c 6,72 lit CO2 (ktc). Bit t khi hi ca 2
ankanal so vi H2 l 27. CTCT ca 2 ankanal l :
A. HCHO v C4H9CHO B. CH3CHO v C3H7CHO
C. C2H5CHO v C3H7CHO D. C A v B
Cu 33: Mt anehit A c cng thc (C3H5O)n . Gi tri ca n l bao nhiu A l 1 anehit no, mch
h
A. 2 B. 4 C. 6 D. C A, B, C
Cu 34: Mt este n chc, mch h c khi lng l 12,9g tc dng va vi 150ml dung dch
KOH 1M. Sau phn ng thu c mui v anehit .CTCT ca este ny c th l : A. HCOOCH=CH-
CH2-CH3 B. CH3COOCH=CH2
C. CH3CH2COOCH=CH2 D. C A v C
Cu 35: phn bit 3 cht l : hexanol, axit acrylic, phenol ta c th dng thuc th duy nht l :
A. D2 Br2 B. Na C. NaOH D. p n khc
Cu 36: Cho 2 axit n chc A v B (s nguyn t C trong A v B u ln hn 1). Nu trn 20g dung
dch axit A 23% vi 50g dung dch axit B 20,64% c dung dch D. Trung ho dung dch D cn
200ml dung dch NaOH 1,1M. CTCT ca A, B l :
A. CH3COOH v C3H7COOH B. CH3COOH v C2H5COOH
C. CH3COOH v C2H3COOH D. C2H3COOH v C3H7COOH
Cu 37: Este B l dn xut ca benzen c CTPT l C9H8O2. B tc dng vi xt d cho 2 mui v nc,
cc mui c khi lng phn t ln hn khi lng phn t ca natri axetat. CTCT ca B l :
A. C6H5COOCH2-CH=CH2 B. CH2=CH-COO-C6H4-CH3
C. CH2=CH-COOC6H5 D. HO-C6H4-O-CH2-C CH
Cu 38: Trong cc este sau, este no thu phn thu c s mol mui bng 3 ln s mol este ban u
A. CH3COO-C6H4-COOCH3 B. C2H5COO-C6H4-OCOH
C. CH3OCO-CH2-COOC6H5 D. C A, B, C
Cu 39: Sp xp theo th t gim dn tan trong nc ca cc cht sau : HCOOH (A), HOOC-
COOH (B), C6H5COOH (C), HOOC-(CH2)4-COOH (D).
A. (A) > (B) > (C) > (D) B. (A) > (B) > (D) > (C)
C. (B) > (A) > (D) > (C) D. (B) > (A) > (C) > (D)
Cu 40: Cho m (g) hn hp A gm : HCHO, HCOOH phn ng va vi 200ml dung dch KOH
1M. Mt khc 0,5m (g) hn hp A phn ng vi Ag2O/NH3 thu c 86,4g Ag. Gi tr ca m (g) l :
A. 18,4 B. 12,2 C. 21,2 D.6
Cu 41: Thu phn hon ton 1 mol cht hu c X trong dung dch HCl sinh ra 1 mol ru no Y v x
mol axit hu c n chc Z. CTPT ca X c dng :
A. (CnH2n+1COO)xCmH2m+2-x B. (RCOO)xCmH2m+2-x
C. R(COOCmH2m+2-x)x D. Kt qu khc
Cu 42: Mt hp cht hu c A( gm C,H,O ch cha mt loi nhm chc ), c thnh phn % O theo
khi lng l 53,33%. C 0,1 mol A phn ng vi Ag2O/NH3 thu c 43,2g Ag. CTCT ca A l :
A. HCHO B. CH2(CHO)2 C. OHC - CHO D. C A v B
Cu 43: Hn hp X gm gm ru mtylic v 2 axit k tip nhau trong dy ng ng ca axit axetic
tc dng ht vi Na thu c 6,72 lit H2 (ktc). un nng hn hp X (c H2SO4 c xc tc) th cc
cht trong hn hp phn ng va vi nhau to 25g hn hp 2 este. CTPT ca 2 axit l :
Cu 44: Este ho mt ru no mt ln ru bng mt axit no n chc. Maxit = Mru (M l KLPT).
Khi lng cacbon c trong este bng mt na KLPT hai cht ban u . CTPT ca este thu c l :

Cu 45: Cho cc cht sau : C6H5OH (1), C6H5NH2 (2), C6H5COOH (3), HCOOH (4), C3H5(OH)3 (5),
HCHO (6). Nhng cht no phn ng c vi Br2 v Na :
A. (1), (3) , (4), (5), (6) B. (1), (3), (4), (6)
C. (1), (3), (4), (5) D. (1), (3), (4)
Cu 46: Cho hn hp A gm CH3COOCH=CH2 v HCOOCH3. phn bit 2 cht ta c th dng
mt thuc th duy nht l :
A. Ag2O/NH3 B. Br2 C. A,B u ng D. A, B u sai
Cu 47: ng dng ca fomanehit l :
A. Sn xut polime B. Dc phm
C. Thuc n D. C A, B, C
Cu 48: Th t tng dn nhit si no sau y c sp xp ng :
A. HCOOCH3 < CH3COOC2H5 < CH3COOH < CH3CH2CH2COOH
B. CH3COOCH3 < C2H5OH < HCHO < CH3COOH
C. C6H5COOH < C2H5OH < CH3COOH
D. C A, B, C u ng
Cu 49: Chn cu pht biu sai :
A. Cht bo nh hn nc v khng tan trong nc iu kin thng
B. Cht bo l thnh phn c bn ca t bo sng
C. Lipit c iu ch t axit bo v glixerin
D. Cht bo l este a chc no
Cu 50: CTTQ ca anehit no :
A. CnH2n+2O B. CnH2nO C. CnH2nOx D. CnH2n+2-2xOx
Cu 51: Dung dch cha khong 40% anehit fomic trong nc c gi l :
A. fomon B. fomanehit C. fomalin D. A v C ng
Cu 52: Trng thi t nhin ca HCHO :
A. rn B. kh C. lng D. B v C ng
Cu 53: Th t tng dn nhit si ca HCHO (1), CH3CHO (2), CH3COOH (3), C2H5OH (4),
CH3COOCH3 (5).
A. (3) > (5) > (4) > (2) > (1) B. (1) > (2) > (3) > (4) > (5)
C. (3) > (4) > (5) > (2) > (1) D. (5) > (3) > (4) > (2) > (1)
Cu 54: c im ca phn ng este ho gia ru v axit hu c
A. Thun nghch B. 1 chiu
C. Xc tc H2SO4 m c D. A v C
Cu 55: Hiro ho 0,1 mol cht A (C,H,O) vi xc tc Ni, to , H = 100% cn dng ht 0,3 mol kh H2.
CTCT ca A l :
A. CH3CH2CHO B. CH C-CHO
C. CH2=C=CH-CHO D. C B v C
Cu 56: Mt hp cht hu c c CTPT l C4H8O. C bao nhiu ng phn khi cng H2 (xc tc Ni, to)
cho ra ru v bao nhiu ng phn cho phn ng vi dung dch AgNO3 trong NH3 ? Cho kt qu theo
th t nh trn :
A. 3, 1 B. 3, 2 C. 5, 2 D. 4, 1
Cu 57: Trong cc pht biu sau, pht biu no sai :
1. Etanal si nhit cao hn etanol
2. Etanal cho kt ta vi dung dch AgNO3/NH3
3. Cc H C so vi -CHO c th b thay th bi Na do cc H ny c tnh linh ng
4. Etanal c th trng hp cho ra mt cht rn.
A. 1, 3 B. 3,4 C. 1,4 D. 2,3
Cu 58: Gi tn hp cht c cng thc nh sau :
HOOC-CH2-CH(CH3)-CH(CH3)-CH2-COOH
A. Axit 3,4 - imetyl hexanoic B. Axit 1,2 - imetyl hexanoic
C. Axit 3,4 - imetyl butanoic D. Axit 1,2 - imetyl butanoic
Cu 59: Sp xp cc cht sau theo th t nhit si tng dn : CH3-COO-CH3 (1), CH3-CH2-CHO
(2) , CH3-CH2-COOH (3)
A. 3, 2, 1 B. 1, 2, 3 C. 2, 3, 1 D. 2, 1, 3
Cu 60: Mt este c 10 nguyn t C khi b x phng ho cho ra hai mui v mt anehit. Chn CTCT
ca este trong cc CT sau : CH2=CH-OOC-COO-C6H5 (1), CH2=CH-COO-C6H4-CH3 (2), CH2=CH-
CH2-COO-C6H5 (3)
A. Ch c 1 B. Ch c 3 C. 1 v 3 D. C 1,2,3
Cu 61: Mt este X c CT l RCOOR' c t khi hi vi O2 nh hn 4,5. Khi x phng ho X bng
dung dch NaOH ta thu c 2 mui c t l khi lng l 1,4146. Xc nh CTCT ca X
A. HCOOC6H5 B. CH3COOC6H5 C. C2H5COOC6H5 D. Kt qu khc
Cu 62: Sp xp cc cht theo th t tng dn tnh axit. Cu no sau y ng :
A. C2H5OH < CH3COOH < C6H5OH < CO2
B. C6H5OH < CO2 < CH3COOH < C2H5OH
C. CH3COOH < C6H5OH < CO2 < C2H5OH
D. C2H5OH < C6H5OH < CO2 < CH3COOH
Cu 63: Phn ng : C4H6O2 (B) + NaOH 2 sp u c kh nng phn ng trng gng. CTCT ca B
l :
A. CH3COOCH=CH2 B. HCOOCH2CH=CH2
C. HCOOCH=CHCH3 D. HCOOC(CH3)=CH2
+ Cl2, 500oC + NaOH + CuO,to
Cu 64: Propilen A B C. Tn gi ca C l :
A. Propanol B. Propenal C. Axeton D. Axit propionic
Cu 65: Cht no to kt ta gch khi un nng vi Cu(OH)2
A. HCHO B. CH3COOH C. C hai u ng D. C hai u sai
Cu 66: phn bit ba mu ho cht ring bit :phenol, axit acrylic, axit axetic bng mt thuc th,
ngi ta nn dng thuc th no sau y :
A. Dung dch Br2 B. Dung dch Na2CO3
C. Dung dch AgNO3/NH3 D. Dung dch CaCO3
Cu 67: A l hp cht hu c tc dng vi NaOH to mui natri ca mt axit hu c v mt ru . A
l :
A. CH3COOH B. CH3COOCl C. Canxi glixerat D. Este
Cu 68: T cc cht no sau y c th iu ch axit axetic
A. C2H5OH B. CH3CHO C. CH3COONa D. Tt c u ng
Cu 69: V sao CH3COOH tan nhiu trong nc :
A. Phn t khi ln B. To c lin kt hiro vi nc
C. C tnh axit D. C A, B, C u ng
Cu 70: Trong cc phn ng sau y, phn ng no xy ra theo chiu thun
1. 2CH3COOH + Na2CO3 2CH3COONa + H2O + CO2
2. C6H5OH + NaHCO3 C6H5ONa + CO2 + H2O
3. CH3COOH + H2O C2H5OH + O2
4. CH3COONa + HCl CH3COOH + NaCl
A. 1, 4 B. 1, 3 C. 3, 4 D. 2, 3
Cu 71: Cc pht biu sau y, pht biu no ng :
A. Tr HCHO th kh, cc anehit, xeton u th lng
B. Tr HCHO v CH3CHO th kh, cc anehit v xeton u th lng
C.Tr HCHO, CH3CHO, C2H5CHO th kh, cc anehit v xeton u th lng.
D.C ba u sai
Cu 72: Sp xp cc cht theo th t tan trong nc tng dn :
A. C3H7CHO < C3H7OH < C3H8 < C3H7COOH
B. C3H7CHO < C3H8 < C3H7OH < C3H7COOH
C. C3H8 < C3H7CHO < C3H7OH < C3H7COOH
D. C3H8 < C3H7OH < C3H7CHO < C3H7COOH
Cu 73: Trong cc cht sau, cht no tc dng c vi axit iso butanoic
A. NaOH, CH3COOH B. PCl5, Cl2, NaOH
C. HCHO, AgNO3/NH3 D. Tt c u sai
Cu 74: Chn ng phn X ng vi CTPT l C4H4O bit rng X tho mn cc iu kin sau :
1. Tc dng vi dung dch AgNO3/NH3 cho 2 kt ta, 1 hu c, 1 v c
2. Lm mt mu dung dch KMnO4
3. Cng H2 cho ra Y c kh nng phn ng vi Na cho ra kh H2
A. HC C - O - CH=CH2 B. H2C=C=CH-CHO
C. HC C - CHO D. HCC-CH2-CHO
Cu 75: Chn CTCT ca 1 este X c CTPT l C4H6O2 bit rng khi thu phn X thu c 1 axit Y v
mt anehit Z. Z oxi ho cho ra Y v X c th trng hp cho ra 1 polime
A. HCOOC3H5 B. CH3COOC2H5 C. CH3COOCH=CH2 D. HCOOCH=CH2
Cu 76: Hn hp M gm 2 cht hu c A,B c t l mol tng ng l 2:1. Cht A mch h ch cha
mt loi nhm chc c iu ch t axit no X v ru no Y. B l este n chc . t hon ton cng
mt s A hoc B c cng th tch CO2 cng iu kin nhit v p sut. CTCT ca A,B theo th
t l :
A. CH3COOCH=CH2 ,C2H5COOCH3
B. C2H5COOCH3 , CH3COOCH=CH2
C. C3H7COOCH3, CH3COOCH=CH2
D. A,B ng
E. B,C ng
Cu 77: Cho hn hp 2 este n chc cu to bi 2 axit ng ng k tip tc dng hon ton vi 1,5
lit NaOH 2,4 M c dd A v ru B bc 1. C cn A c 211,2 g cht rn khan. CTCT ca 2 este l
:
A. HCOOCH(CH3)2, CH3COOCH(CH3)2
B. HCOOC2H5, CH3COOCH(CH3)2
C. HCOOC2H5, CH3COOC2H5
D. HCOOC2H5, C2H5COOC2H5
Cu 78: Xc nh CTPT ca axit hu c b vit sai : CH2O (1), C2H2O (2), C2H4O2 (3), CH2O2 (4),
C2H5O4 (5), C6H9O3 (6)
A. 1,2,5 B. 5,2,6 C. 1,5,2,6 D. Kt qu khc
Cu 79: Cho a g hn hp A gm 2 cht hu c n chc X,Y mch h cha C,H,O tc dng va ht
120 ml NaOH 1M. Hn hp 2 ru c cng s nguyn t C v 10,8 g hn hp B gm 2 mui. Cho B
tc dng hon ton vi H2SO4 d c hn hp D gm 2 axit hu c. 1/2 D tc dng va vi dd
cha 6,4 g B. CTCT X,Y:
A. CH3COOCH2CH=CH2, CH2=CHCOOCH2CH2CH3
B. CH2(COOCH3)2 , CH2=CHCOOCH=CH2
C. CH3COOCH=CH2, CH2=CHCOOCH2CH2CH3
D. A,B,C ng
Cu 80: CTG nht ca A l CH2O. Cho cng mt lng A tc dng ht vi Na, NaHCO3 th s mol
CO2 v H2 lun bng nhau v bng s mol A. CTCT A l :
A. (COOH)2 B. HOCH2CH2COOH
C. CH3CH(OH)COOH D. B, C ng
Cu 81: Hn hp A gm 2 axit hu c X,Y mch h (trong X n chc ). Ly cng s mol X,Y
.Cho X tc dng ht vi NaHCO3. Y tc dng ht vi Na2CO3 th lng CO2 thu c bng nhau.
CTCT ca X,Y ln lt l :
A. CH3COOH, C2H5COOH B. HOOCCH2COOH, CH3COOH
C. CH3COOH,HOOCCH2CH2COOH D. B v C ng
Cu 82: Cho 13,6 g X (C,H,O) tc dng va vi 300 ml dd AgNO3/NH3 2M c 43,2 g Ag, d
X/O2 = 2,125. CTCT X :
A. OHC-CH2-CH2-CHO B. CHC-CH2-CHO
C. CH3-CCH-CHO D. B,C ng
D kin sau dng cho cu 83-84: C 3 hp cht hu c A, B, C KLPT ca mi cht u nh hn 180
vC. Hp cht B c CTPT trng vi CTGN ca A. Khi t chy hon ton 15 mg A ch thu c hn
hp gm kh CO2 v hi nc, tng th tch ca chng quy v iu kin tiu chun bng 22,4 ml.
Cu 83: CTGN ca A l :
A. CH3O B.C2H6O C.CH2O D.Kt qu khc
Cu 84: Tn gi thng thng v tn gi quc t ca B l :
A. Anhit fomic, fomanhit v metanal
B. Anhit fomic v etanal
C. Fomanhit v etanal
D. Anhit fomic v metanal
D kin sau dng cho cu 85-86: Mt cht A c cha C, H, O. t chy hon ton A cn th tch xi
bng th tch CO2. Ly 21,6g A phn ng ht vi dd AgNO3 trong NH3 d thu c 25,92g Ag. Bit
1mol A to 2 mol Ag.
Cu 85: A l hp cht g ?
A. Anhit B. Ru C. Este D.Gluxit
Cu 86: CTCT ca A l :
A. HO- CH2- CH(OH) - CHO B. HOOC- CH2- CH(OH) - CHO
C. HO- CH2- CH(OH) - CHO D. Khng xc nh c
D kin sau dng cho cu 87-88: Hn hp hai este no on chc c t chy hon ton mt lng
cn 3,976 lit O2(ktc) thu c 6,38g kh CO2. Cho lng este ny tc dng va vi KOH thu c
hn hp 2 ru k tip v 3,92g mui ca mt axit hu c.
Cu 87: CTPT 2 este l :
A.C3H6O2 , C4H8O2 B.C4H8O2 ,C5H10O2
C. C2H5O2 , C3H7O2 D. Kt qu khc
Cu 88: Khi lng mi este trong hn hn hp u:
A. 1,11g v 2,2g B. 2,2g v 4,4g
C. 4,4g v 8,8g D. Kt qu khc
Cu 89: Mt hp cht A c MA<170. t chy hon ton 0,486g A sinh ra 405,2ml CO2 (ktc) v
0,272g nc .CTPT A l :
A. C6H10O5 B. C12H20O10 C.C6H12O6 D.Kt qu khc
Cu 90: Oxi ho 10,2 g hn hp 2 anhit k tip nhau trong dy ng ng, ngi ta thu c hn
hp 2 axit cacbxylic n chc. trung ho hn hp 2 axit ny cn phi dng 200ml dd NaOH 1M.
CTPT ca 2 anehit l :
A. HCHO, CH3CHO B. CH3CHO; C2H5CHO
C. C2H5CHO, C3H7CHO D. Kt qu khc
Cu 91: un nng dd fomalin vi phenol(d) c axit lm xc tc thu c plime c cu trc no sau
y:
A. Mng li khng gian B. Mch thng
C. Dng phn nhnh D.C 3 u sai
Cu 92: Trong cng nghip, sn xut gng soi v rut phch nc, ngi ta da vo phn ng ha
hc no sau y :
A. Axetilen tc dng dd AgNO3 trong NH3
B. Anhit fomic tc dng dd AgNO3 trong NH3
C. Dung dch glucoz tc dng dd AgNO3 trong NH3
D. Saccaroz tc dng dd AgNO3 trong NH3
Cu 93: Glucoz khng phn ng vi cht no sau y :
A. ( CH3O)O B.H2O C.Cu(OH)2 D. A,B,C u ng
Cu 94: Thc hin phn ng este ha gia mt axit cacboxylic no X v mt ru no Y c este mch
h A. Cho bay hi a g A trong bnh kn V=6l, nhit 136,5oC th p sut bnh l 0,56 atm. Bit a g A
phn ng hon ton vi dd NaOH c 14.6 g mui. CTCT A l :
A. CH3COOCH3 B. CH3COO(CH2)2OCOCH3
C. C2H5COO(CH2)2OCOC2H5 D. (CH3COO)3C3H5
Cu 95: Mt hp cht hu c A trong phn t c tng s nguyn t O v C khng vt qu 8, A phn
ng vi NaHSO3 theo t l s mol l 1:2. Cho 8,6g A tc dng vi dung dch AgNO3/NH3 thu c
21,6g Ag. CTPT ca A l :
A. C3H4O2 B. C4H6O2 C. C5H8O2 D. Khng xc nh
Cu 96: Cho hn hp 2 este n chc l ng phn ca nhau. cng iu kin nhit p sut 1 lit
hi X nng gp 2 ln 1 lit kh N2O. Thu phn 17,6g X bng 2 lit dung dch NaOH 0,2M thu c
dung dch Y. C cn dung dch Y thu c 22,3g cht rn l cc hp cht ca Na. CTPT ca 2 este l :
Cu 97: Cho cc nhn xt sau , nhng nhn xt no ng
1. Este nh hn nc, a s tan c trong nc
2. Este c mi thm d chu, ging mi qu chn
3. Nhm axetat l cht cm mu trong cng nghip nhum
4. Men gim c sinh ra bi vi khun Mycodermaceti
5. Dung dch cha khong 40% fomon gi l fomalin
A. 1,2,3,4,5 B. 2,3,4,5 C. 3,4,5 D.2,3,4
Cu 98: Hp cht hu c A mch h ch cha C,H,O. A phn ng vi Na thu c H2 c s mol bng
s mol ca A. A phn ng vi CuO nung nng to ra anehit. Ly 13,5g A phn ng va vi
Na2CO3 thu c 16,8g mui E v c kh CO2 bay ra. CTCT ca A l :
A. HO-CH2-CH2-COOH B. HO-CH2-CH(CH3)-COOH
C. HO-CH2-CH2-CH2-COOH D. C B v C
Cu 99: Cho cc hp cht hu c sau : HO-CH2-CH2-OH (1), OHC-CHO (2),
HO-CH2-CHO (3), HOOC-COOH (4), HOOC-CHO (5). Th t gim dn nhit si c sp xp
ng l :
A. (4) > (3) > (1) > (5) > (2) B. (4) > (5) > (1) > (3) > (2)
C. (4) > (1) > (5) > (3) > (2) D. (4) > (5) > (3) > (1) > (2)
Cu 100: Cho 5 dung dch H2SO4 (1), CH3COOH (2), CH3COONa (3), Cl3CCOOH(4), Cl3CCOONa
(5). Th t tng dn pH ca 5 dung dch l :
A. (1) < (4) < (2) < (5) < (3) B. (1) < (4) < (5) < (2) < (3)
C. (1) < (4) < (2) < (3) < (5) D. (3) < (5) < (2) < (4) < (1)
Cu 101: Cho cc cht sau : HOOC-COOH (1), HCOONH4 (2), HCOOCH3 (3), CH3COOCH=CH2
(4). Nhng hp cht no khi cho tc dng vi dung dch AgNO3/ NH3 (vi nng NH3 cao) th c th
sinh ra Ag :
A. (1),(2),(3) B. (2),(3),(4) C. (1),(2),(3),(4) D. (2),(3)
Cu 102: Cho cc cp cht sau :
1. HCHO v C6H5OH 2. H2N-CH2-COOH v H2N-(CH2)4-COOH
3. C6H5CH=CH2 v CH2=CH-CH=CH2.
Nhng cp cht no c kh nng tham gia phn ng trng hp :
A. 1 B. 2 C. 3 D. 4
Cu 103: A l hn hp gm 2 anehit c cng s nguyn t cacbon . Cho 5,1g hn hp A bay hi
250oC v 1atm th c th tch l 4,29 lit. Bit MA < MB v :
+ H2 , Ni , to
A C
+ O2 , xtc E
B D
CTPT ca E l :
Cu 104: Cho 3,5g hp cht n chc X (ch cha C, H, O) phn ng va vi dung dch
AgNO3/NH3 thu c 10,8g Ag. Bit rng tn ca n c tip u ng.
CTCT X l :
A. CH2=CH-CH2-CHO B. CH2=C(CH3)-CHO
C. CH2 - CH - CHO D. CH3 H
C=C
CH2 H CHO
Cu 105: Hp cht hu c a chc X c CTPT l C6H8O4. Thu phn X bng dung dch NaOH d thu
c mt mui v mt ru. CTCT c th c ca X l :
A. HOOC-COO-CH2-CH=CH-CH3 B. HOOC-COO-CH(CH3)-CH=CH2
C. COO - CH2 D. C A, B, C u ng
CH3 - CH
COO - CH2
Cu 106: Chn cu tr li ng trong cc pht biu di y:
1. Anhit no n chc l nhng HCHC m phn t c 1 nhm (-OH) hydroxyl lin kt vi gc
hirocacbon no
2. Anhit no n chc l nhng HCHC m phn t c 1 nhm chc anehit lin kt vi gc
hirocacbon khng no
3. Anhit no n chc l nhng HCHC m phn t c 1 nhm chc anehit lin kt vi gc
hirocacbon no
4. Anhit no n chc l nhng HCHC m phn t c 1 nhm chc cacboxyl lin kt vi gc
hirocacbon no
A. 1, 2 B. 3 C. 1, 2, 3 D.Tt c du ng
Cu 107: Chn cu tr li sai trong cc pht biu di y:
1. Anhit fomic c tn gi khc l fomandehit, fomon
2. Anhit fomic l cht kh khng mu, c mi xc kh chu, tan nhiu trong nc
3. Anhit tham gia phn ng vi dung dich NaOH to mui
4. Trong cng nghip, anhit fomic c iu ch bng phng php sau : xi ha ru metylic
bng xi khng kh nh cht xc tc ng kim loi nhit 500 -700oC
5. Tn thng thng ca anehit l : Anehit + tn ru tng ng
6. Tn quc t ca anhit no n chc : Tn ca hirocacbon no tng ng + al
7. Nhit si ca anhit cao hn nhit si ca ru tng ng
A. 1,2,3 B 4,5,7 C. 3,5,7 D. 1,5,6,7
Cu 108: Anehit c th tham gia phn ng trng gng v phn ng vi H2 ( Ni, to ) tc l :
A. Anehit ch th hin tnh kh
B. Anehit ch th hin tnh oxi ha
C. Anhit th hin c tnh kh v tnh oxi ha
D. Anehit khng th hin tnh kh hay tnh oxi ha
Cu 109: Phn bit propanol-1 , propanon v propanal ta c th dng phn ng no trong cc phn ng
sau:
1. Phn ng vi Na
2. Phn ng vi dung dch AgNO3 trong NH3
3. Phn ng vi dung dch NaHSO3
Chn p n ng nht
A. 1,2,3 B. 1,3 C. 1,2 D. 1,2 hoc 2,3
Cu 110: Trong s cc cht sau, cht no dng ngm xc ng vt
A. D2 HCHO B. D2CH3OH C. C A, B D. Kt qu khc
Cu 111: Chn cu tr li sai trong cc pht biu di y :
1. Axit cacboxylic no n chc l nhng HCHC m phn t c 1 nhm cacboxyl lin kt vi
gc hirocacbon no
2. Tn thng thng ca Axit cacboxylic l tn lin quan n ngun gc tm ra chng
3. Tn quc t ca Axit cacboxylic : Axit + tn quc t ca hirocacbon no tng ng + ic
4. Nhit si ca axt u hn hn nhit si ca ru tng ng
A. 1 B. 1, 2 C. 3 D. 3, 4
Cu 112: Chn cu tr li ng
1.Axt tham gia phn ng vi ru gi l phn ng este ha
2.Axt khng tc dng c vi Na
3.Anht phn ng H2 ( Ni , to) to axit tng ng
4.Axt tc dng vi O2 ( mi trng men gim) to ru tng ng
5.c im ca phn ng este ha l thun nghch
6.Axit phn ng vi kim loi to mui v gii phng kh H2
A. 1,2,3,4 B. 1,5,6 C. 2,5,6 D. 2,3
Cu 113: Cng thc chung ca Axt cacboxylic khng no n chc l :
A. CnH2n+1COOH B. CnH2nCOOH
C. CnH2n-1 COOH D. CnH2n-2COOH
Cu 114: Chn cu tr li sai trong cc pht biu di y
1.ESTE l sn phm ca phn ng este ha gia axt vi ru
2.Tn thng thng ca este : Tn gc hirocacbon ca ru + Tn gc axit c ui al
3.ESTE l nhng cht rn , khng mu khng mi khng v
4.ESTE c nhit si thp hn so vi cc Axt cacboxylic to nn este v este nng hn nc
nc, d tan trong nc
5.ESTE l nguyn liu sn xut si tng hp, thy tinh hu c
6.ESTE tham gia phn ng vi axit ln baz nn chng lng tnh
7.T anehit c th iu ch trc tip ra este tng ng
A.1,5,7 B.2,5,7 C. 3,4,5 D. 2,3,4,6,7
Cu 115: Mt hn hp X gm 2 ankanal ng ng k tip khi b xi ha hon ton cho ra hn hp 2
ru c khi lng ln hn khi lng X l 1g . X t chy cho ra 30,8 g CO2 . Xc nh CTPT ca 2
ankanal v khi lng ca chng
A. 9g HCHO; 4,4 g CH3CHO B. 18g HCHO; 8,8 g CH3CHO
C. 4,5g HCHO; 4,4 g CH3CHO D. 9g HCHO; 8,8 g CH3CHO

Cu 116: Cho HCHC A n chc tc dng vi dung dch AgNO3 trong NH3 cho Ag kt ta, A cng
Br2 theo t l 1:1. Hir ha hon ton A thu c 1,2 g B, lng B ny khi tc dng vi Na d cho ra
0,224 lit H2 (ktc). Xc nh CTCT ca A v B :
A. HCHO, CH3OH B. CH2=CH-CH2-CHO ,CH3-(CH2)3-OH
C. CH2=CH-CHO, CH3-(CH2)2-OH D. CH3CHO, CH3CH2OH
Cu 117: t chy hon ton 1 lng 2 este no n chc cn 3,976 lit O2 (ktc) thu c 6,38 g kh
CO2 . Cho lng este ny tc dng d vi KOH thu c hn hp 2 ru k tip v 3,92 g mui ca
axt hu c. Tm CTPT v tnh khi lng ca mi este trong hn hp .
A. C3H6O2 (1,11g); C4H8O2 (2,12g) B. C4H8O2 (1,11g); C3H6O2 (2,2g)
C. C2H4O2 (1,11g); C3H6O2 (2,12g) D. C2H4O2 (1,11g); C4H8O2 (2,2g)
Cu 118: Hai cht hu c A,B (C,H,O) u c 53,33 % oxi theo khi lng. Khi lng phn t ca B
gp 1,5 ln khi lng phn t ca A . t chy ht 0,04 mol hn hp A,B cn 0,1 mol O2 .Mt
khc khi cho s mol bng nhau ca A, B tc dng vi lng d dung dich NaOH th lng mui to t
B gp 1,952 lng mui to t A (phn ng xy ra hon ton). Tm CTPT A,B
Cu 119: t chy 1,7 g este X cn 2,52 lit O2 (ktc) thu c CO2v H2O trong nCO2: n H2O = 2
. un nng 0,01 mol X vi dung dch NaOH thy 0,02 mol NaOH tham gia phn ng . X khng cha
chc este , khng phn ng vi Na, khng kh c AgNO3 trong dung dch NH3. Xc nh CTPT X :
Cu 120: trung ho 2,49 g hn hp axt focmic v axt acrylic th cn dng 400 ml dung dch
NaOH 0,1 M. Nu cho ton b lng axit trn phn ng vi kim loi Mg d th th tch H2 (lit) thu
c iu kin chun l:
A. 0,112 B. 0,448 C. 0,224 D. 0,336
Cu 121: Hp cht c cng thc l CxHyOz c khi lng phn t 60 vC. Trong cc cht trn c cht
A tc dng c vi Na2CO3 thu c CO2 . Cht B tc dng c vi Na v c phn ng trng gng
.Cht C tc dng vi NaOH nhng khng tc dng c vi Na . Cng thc ln lt ca A,B,C l :
A. C3H7OH ; HO-CH2-CH2-CHO ; CH3COOCH3
B. C2H5COOH ; HO-CH2-CH2-CHO; C2H5COOCH3
C. CH3COOH ; HCOOCH3; HO -CH2-CHO
D. CH3COOH; HO -CH2-CHO ; HCOOCH3
Cu 122: Axt Axetic c hng s phn li Ka= 1,8.10-5 . Nu in li =1,2% th nng dung dch l
(M) :
A. 0,0653 B. 0,0845 C. 0,1235 D. 0,125
Cu 123: Trong 1 bnh kn dung tch khng i cha 1 lng O2 gp i lng cn thit t chy v
hn hp 2 este ng phn c CTPT l CnH2nO2 .Nhit v p sut trong bnh lc u l 136,5oC v
1at. Sau khi t chy hon ton 2 este gi nhit bnh 819oK, p sut trong bnh lc ny l
2,375atm . Xc nh CTPT ca 2 este :
A. CH3COOCH3; HCOOCH3 B. C4H9COOC4H9 ; C2H5COOC6H13
C. C3H7COOC3H7 ; C2H5COOC4H9 D. C2H5COOC2H5 ; HCOOC3H7
Cu 124: Trong cc cu sau y, cu no sai ?
A. Cc cht c cng khi lng phn t l ng phn ca nhau.
B. Tnh axit gim dn trong dy ng ng ca axit fomic.
C. Khi cho phenol v anilin tc dng vi dd Brm th v tr nhm th u tin l orth v para.
D. Ru etylic c nhit si cao hn hn cc Hidro Cacbon v cc dn xut Halogen tng
ng.
Cu 125: Khi t chy cc ng ng ca mt ru th t l nCO2 : nH2O tng dn khi s nguyn t
Ccbon tng dn. l dy ng ng ca:
A.Ru no n chc. B. Ru thm.
C.Ru vng no. D. Ru no.
Cu 126: Triglixerit l este ba ln este ca glixerin. Nu un nng glixerin vi hn hp ba este
RCOOH, R'COOH, R''COOH th thu c ti a bao nhiu Triglixerit?
A. 9 B. 12
C. 18 D.15
Cu 127: Cho cc cht sau: C2H5OH(1), C2H5Cl(2), CH3COOH(3), CH3COOC2H5(4).
T t tng dn nhit si l:
A.1-2-3-4 B.1-2-4-3
C.4-1-2-3 D.2-4-1-3
Cu 128: Khi oxy ho 2,2 gam 1 anehit n chc thu c 3 g axit tng ng. CTPT ca anehit l:
A.CH3CHO B.HCHO
C.C2H5CHO D.C3H7CHO
Cu 129: Oxy ho m gam hh A cha andehit propionic vi andehit axetic ta thu c hn hp B cha
hai axit tng ng. T khi hi ca B so vi A l a, a c gi tr trong khong:
A. 1.364<a<1.275 B. 1<a<1.314
C. 1.034<a<1.68 D. 1.275<a<1.364
Cu 130: Ch dng dung dch axt sunfuric c th nhn bit c nhng cht no trong s cc cht sau
y: Ru etylic, toluen, anilin, natri cacbonat, natri sunfit, natri phenolat, natri axetat.
A. toluen, anilin, natri cacbonat, natri sunfit .
B. toluen, anilin, natri sunfit, natri phenonlat.
C.Tt c cc cht trn
D. Ru etylic, toluen, anilin, natri cacbonat, natri axetat.
Cu 131: Hp cht A cha CHO trong O chim 37.21%. A ch ha mt loi nhm chc. Cho mt
mol A phn ng vi Ag2O/NH3 d thu c 4 mol Ag. CTCT ca A l: A.OHC-CH2-CH2-CHO
B.CH3-CH(CHO)2
C.HCHO D.C A v B u ng.
Cu 132: Hn hp A gm 1 ru no n chc v mt axit no n chc, chia A thnh 2 phn bng
nhau :
Phn 1: B t chy hon ton thy to 3,36l CO2(ktc).
Phn 2: c este ho hon ton v va to ra 1 este. t chy este ny th lng nc thu c
l:
A.1.8 B.2.7
C.5.4 D.1.35
Cu 133: Cho 17,4 g hn hp hai anehit n chc no k tip nhau trong dy ng ng tc dng ht
vi dung dch AgNO3/NH3 thu c 86,4 gam Ag. CTPT hai anehit l:
A.C2H5CHO v CH3CHO B.HCHO v C2H5CHO
C.HCHO v CH3CHO D.C3H7CHO v C4H9CHO
Cu 134: Cng thc ca mt anehit no c dng (C2H3O)n th cng thc phn t ca anehit l:
A.C4H6O2 B.C6H9O3
C.C2H3O D.C8H12O4
Cu 135: Cho 6 gam anehit tc dng vi dung dch AgNO3/NH3 d ta thu c 86,4 gam Ag . Cng
thc anehit l :
A. H - CHO B. HOC - CHO C. CH2 = CH - CHO D. CH3-CH2-CHO
Cu 136: t chy hon ton 0,88g hn hp 2 este ng phn ta thu c 1,76g CO2 v 0,72g H2O.
CTPT ca 2 este l :

Cu 137: Cho 4,2g este n chc no E tc dng vi dung dch NaOH ta thu c 4,76g mui Na. Vy
CTCT ca E c th l :
A. CH3 - COOCH3 B. C2H5 - COOCH3
C. HCOOCH3 D. Tt c u sai
Cu 138: A c phn ng trng gng, tc dng vi Na gii phng H2 nhng khng tc dng vi dung
dch NaOH. Vy CTCT ca A l :
A. CH3 - CH(OH) - CHO B. HO - CH2 - COOH
C. HCOOCH3 D. HCOOC2H5
Cu 139: Este ho mt ru no mt ln ru bng mt axit no n chc. Maxit = Mru (M l KLPT).
Khi lng cacbon c trong este bng mt na KLPT hai cht ban u . CTPT ca este thu c l :
Cu 140: Axit axetic c th c iu ch bng phng php no trong cng nghip
A. Chng g B. Tng hp t axetilen
C. C A v B D. Cho Natri axetat tc dng vi H2SO4
Cu 141: A l este n chc, mch h, khng tham gia phn ng trng gng , c t l mc:mo = 9 : 8 .
CTPT ca A l :
A. C3H6O2 B. C3H4O2 C. C3H2O2 D. C A, B, C
Cu 142: Pht biu no sau y sai :
1. Cht A c phn ng vi NaOH, v Na suy ra A ch c th l axit.
2. Nhit si ca HCHO nh hn nhit si ca CH3CHO.
3. Khi thc hin phn ng clo ho CH3CH2CH2COOH trong iu kin nh sng th ta thu c sn
phm chnh l CH3CH2CHClCOOH.
A. 1, 2 B. 2, 3 C. 1, 3 D. 1
Cu 143: Hai cht hu c A, B k tip nhau trong dy ng ng , bit % khi lng O trong A v B
l ln lt l 53,33% v 43,24% (MA<MB). CTPT ca A v B l :
C. CH2O3 v C2H4O3 D. C4H8O3 v C5H10O3
Cu 144: Tn theo IUPAC ca CH3 - CH(C2H5) - CH2 - CH(COOH) - CH3 l :
A. Axit 2 - etyl - 4 - metyl butanoic
B. Axit 2 - metyl - 4 -etyl butanoic
C. Axit 2 - etyl - 4 - metyl hexanoic
D. Axit 2,4 - imetyl hexanoic
Cu 145: Cho 6,8 g X (cha C,H,O) mch h, khng phn nhnh phn ng va vi 0,15 mol Ag2O
trong dung dch NH3 ,to. Xc nh CTPT ca X :
A. C4H4O B. C3H2O2 C. C2H4O D. Khng xc nh
Cu 146: Cho 4 l b mt nhn cha 4 cht ring bit l CH3COOCH=CH2, HCOONa, C6H5OH,
C2H5OH ( gi s cc cht dng dung dch ). nhn bit c 4 cht ta c th dng :
A. AgNO3 /NH3 v Br2 B. Br2 v Na
C. C A v B D. p n khc
o
Cu 147: Anehit X phn ng vi Ag2O/NH3 ,t (va ) ch thu c cc sn phm hu c v Ag.
Bit nA : nAg = 1 : 4 . CTCT c th c ca A l :
A. HCHO B. HOC - CHO C. RCHO D. C A, B
Cu 148: Mt este A n chc mch h, trong phn t cha khng qu 4 nguyn t cacbon. Cho A tc
dng vi dung dch NaOH cho mt mui c khi lng phn t bng 34/37 khi lng phn t ca
este. CTCT ph hp ca A l :
A. CH3COOCH3 B. HCOOC3H7 C. C2H5COOCH3 D. HCOOC2H5
Cu 149: Trong cc pht biu sau, pht biu no sai :
1. Axit axetic c phn ng vi Cu(OH)2 iu kin thng
2. CTCT thu gn ca anehit no l CnH2n + 1CHO
3. Axit khng no nh axit acrylic cho phn ng trng hp
4. Thu phn este trong mi trng kim l phn ng mt chiu
A. 1, 3, 4 B. 3 C. 4 D. 2
Cu 150: Th t tng dn tnh axit no sau y c sp xp ng :
A. HO-CH2-COOH < O2N-CH2-COOH < Cl-CH2-COOH < F-CH2-COOH
B. Cl-CH2-COOH < F-CH2-COOH < HO-CH2-COOH < O2N-CH2-COOH
C. HO-CH2-COOH < Cl-CH2-COOH < F-CH2-COOH < O2N-CH2-COOH
D. O2N-CH2-COOH < HO-CH2-COOH < Cl-CH2-COOH < F-CH2-COOH
Cu 151: 2 cht A, B c CTPT l C4H7ClO2
A + NaOH mui A' + NaCl + C2H5OH
B + NaOH mui B' + NaCl + C2H4(OH)2
CTCT ca A v B ln lt l :
A. ClCH2COOC2H5 v CH3COOCH2CH2Cl
B. ClCH2COOC2H5 v CH3COOCHClCH3
C. ClCH2CH2COOCH3 v CH3COOCHClCH3
D. Kt qu khc
Cu 152: Hp cht hu c A tn ti iu kin thng c CTPT C3H6O2 . A c th l :
A. Axit hay este n chc no
B. Ru 2 chc cha no c mt lin kt
C. Xeton hay anehit no n chc
D. Tt c u ng
Cu 153: Oxi ho 10,2 g hn hp 2 anehit k tip nhau trong dy ng ng ngi ta thu c 2 axit
cacboxylic no n chc. trung ho hn hp ny cn dng 200ml dung dch NaOH 1M. CTCT 2
anehit l :
A. HCHO v CH3CHO B. CH3CHO v C2H5CHO
C. C2H5CHO v C3H7CHO D. Kt qu khc
Cu 154: Trong cng nghip, sn xut gng soi v rut phch nc, ngi ta da vo phn ng ha
hc no sau y :
A. Axetilen tc dng dd AgNO3 trong NH3
B. Anhit fomic tc dng dd AgNO3 trong NH3
C. Dung dch glucoz tc dng dd AgNO3 trong NH3
D. Saccaroz tc dng dd AgNO3 trong NH3
Cu 155: Cho 3,5g hp cht n chc X (ch cha C, H, O) phn ng va vi dung dch
AgNO3/NH3 thu c 10,8g Ag. Bit rng tn ca n c tip u ng.
CTCT X l :
A. CH2=CH-CH2-CHO B. CH2=C(CH3)-CHO
C. CH2 - CH - CHO D. CH3 H
C=C
CH2 H CHO
Cu 156: t chy hon ton P g hn hp A gm 2 cht X,Y l ng ng ca anht focmic c
14,08 g CO2 . Mt khc ly P g A cho phn ng hon ton vi AgNO3 d trong dung dch NH3 thu
c 25,92 g Ag .Tnh P ?
A. 6,4 g B. 1,4 g C. 4,6 g D. 2,8 g

CHNG IV:
HP CHT CAO PHN T V VT LIU POLIME
Cu 1: Trong s cc polime di y loi no c ngun gc t xenluloz

(1) si bng (2) t tm (3) len lng cu (4) t enang
(5) t visco (6) t nilon-6 (7) t axtat (8) t nilon 6,6
A: (1), (3), (5) C: (1), (3), (5), (8)
B: (1), (5), (7) D: (1), (5), (7), (8)
p n: B
Cu 2: Saccaroz c th to ra este c 8 gc ca axit axtat trong phn t. l:
A: C20H40O27 C: C28H38O19
B: C20H38O19 D: C28H38O17
p n: B
Cu 3: Trong s cc pht biu sau pht biu no l khng ng:
A: nhit thung glucoz, fructoz, mantoz v saccaroz u ho tan Cu(OH)2 to dung
dch xanh lam.
B: Glucoz v fructoz u phn ng vi H2 (Ni, to) to poliancol.
C: Xenluloz l lun c 3 nhm -OH trong phn t.
D: Glucoz , fructoz, mantoz b oxi ho bi Cu(OH)2 cho kt ta gch.
p n: C
Cu 4: Pht biu no sau y ng :
(1)- Protit l hp cht cao phn t thin nhin c cu trc phc tp.
(2)- Protit ch c trong ng vt v ngi.
(3)- C th ngi v ng vt khng th tng hp c protit t cht v c m ch tng hp t axit
amin.
(4)- Bn i vi nhit, axit, baz kim.
A: (1), (3) C: (1), (3), (4)
B: (1), (2), (3) D: (2), (3)
p n: A
Cu 5: Nhng pht biu no sai:
(1)- Tinh bt c trong t bo thc vt.
(2)- nhn ra tinh bt ngi ta dng dung dich I2.
(3)- Tinh bt l hp cht cao phn t thin nhin.
(4)- Tinh bt l polime mch khng phn nhnh.
(5)- Tinh bt sinh ra trong c th ng vt do s ng ho kh CO2.
A: (1), (4), (5) C:(3), (4), (5)
B: (4), (5) D: Khng c
p n: B
Cu 6: Dung dch A gm HCl c pH = 2. trung ho hon ton 0,59g hn hp 2 amin n chc no,
bc 1 phi dng 1 lit dung dch A. Tm CTPT ca 2 amin:
A: CH3NH2 v C4H9NH2 C: C2H5NH2 v CH3NH2
B: C3H7NH2 D: CH3NH2 v C4H9NH2 hoc C2H5NH2
p n: D
Cu 7: t hon ton 1 amin thm bc 1 X thu c 1,568 lit kh CO2, 1,232 lit hi nc v 0,336 lit
kh tr. trung ho ht 0,05 mol X cn 200ml dung dch HCl 0,75M. Bit cc kh o iu kin tiu
chun. Xc nh CTPT ca X:
A: C6H5NH2 C: (C6H5)2NH
B: C2H5NH2 D: C7H11N3
p n: D
Cu 8 :Pht biu no sai:

A: Anilin l baz yu hn NH3 do nh hng ht e ca vng thm ln nhm NH2 bng hiu
ng lin hp.
B: Anilin khng lm i mu giy qu tm m.
C: Anilin tc dng c vi HBr v trn N cn d i e t do .
D: Nh c tnh baz nn anilin tc dng c vi dung dch Br2.
p n:D
Cu 9: Phn ng no chng t glucoz c dng mch vng:
A: Phn ng este ho vi (CH3CO)2O.
B: Phn ng cng H2 (Ni, to).
C: Phn ng vi CH3OH/HCl.
D: Ph n ng kh bng HI trong ng kn.
p n: C
Cu 10: Hexan metylen iamin phn ng vi H2SO4 cho ti a bao nhiu sn phm:
A: 2 C: 3
B: 4 D: khng c.
p n: B
Cu 11: Amin C3H7N c tt c bao nhiu ng phn:
A: 3 C: 5
B: 6 D: Kt qu khc
p n: D
Cu 12: Sp xp cc cht sau theo th t tng dn tnh baz:
(1) NH3 (2) CH3NH2 (3) C6H5NH2
(4) (CH3)2NH (5) (C6H5)2NH
A: (5), (1), (3), (4), (2)
B: (5), (3), (4), (1), (2)
C: (5), (3), (1), (2), (4)
D: (4), (2), (1), (3), (5)
p n: D
Cu 13: Khi clo ho P.V.C ta thu c mt loi t clorin cha 66,7% clo. Hi trung bnh mt phn t
clo tc dng vi bao nhiu mt xch P.V.C
A: 1 C: 2
B: 3 D: Khng xc nh
p n: C
Cu 14: Cc tin t i, tri, tetra trong tn ca chui peptit l ch:
A: Tng s lin kt peptit trong chui.
B: Tng s phn t aminoaxit to thnh chui.
C: S phn t nc to ra trong qu trnh to thnh chui.
D: C A v B.
p n: A
Cu 15: T cng thc ca xenluloz [C6H7O2(OH)3]n, ngi ta suy ra c tnh cht ho hc ng

ca xenluloz l g:
A: Mang y tnh cht ca mt ru a chc.
B: C tham gia phn ng thu phn.
C: C tnh cht ca este.
D: C A v B
p n: B
.
Cu 16: C th phn bit: lng trng trng, glixerin, glucoz bng mt ho cht duy nht l:
A: Cu(OH)2/NaOH C: AgNO3/NH3
B: Br2 D: HNO3
p n: A
Cu 17: Chn cu sai:

(1) Amino axit thng l cht rn kt tinh, c nhit nng chy cao
(2) Amino axit khng tan trong nc nhng tan c trong cc dung mi hu c.
(3) Amino monoamino monocacboxylic c M l s l, cn iamino monocacboxylic c M l s
chn.
(4) Cc i saccarit c nhit nng chy cao hn cc mono saccarit.
(5) Protit tc dng vi dung dch CuSO4 v dung dch kim cho mu vng sm.
(6) Xenluloz v amiloz pectin u c nhm -OH nhng khng tan trong nc.
A: (2), (3), (5). C: (5), (6).
B: (2), (5). D: (2), (4), (5).
p n: B
Cu 18: Mt nh my ng mt ngy x l 30 tn ma. Trong qu trnh sn xut c 1 t ma cho 65 lit

nc ma vi nng ng l 7,5% v d=1,103g/ml. C c dung dch thnh mt cha 10% ng.
T iu ch ng th. Tnh lng nc cho bay hi trong mi ngy sn xut:
A: 5,377 tn. C: 5,377 kg.
B: 18,3 tn. D: 6990,6 kg.
p n: A
Cu 19: Ngi ta tch c t mt li ng 1 mono saccarit c CTPT l C5H10O5. Cht ny tc dng

c vi H2 (Ni,to), kh c AgNO3/NH3, chuyn c Cu(OH)2 trong dung dch thnh dung dch
mu xanh lam. Cng thc cu to ca gluxit l:
A: CH2OH-(CHOH)3-CH=O
B: CH2OH-(CHOH)3-COOH
C: CH2OH-CO-(CHOH)2-CH2OH
D: Kt qa khc.
p n: A
Cu 20: Cho cc cht sau, cht no l monosaccarit:

(1) CH2OH-(CHOH)4-CH2OH
(2) CH2OH-(CHOH)4-CH=O
(3) CH2OH-CO-(CHOH)3-CH2OH
(4) CH2OH-(CHOH)4-COOH
(5) CH2OH-(CHOH)3- CH=O
A: (1), (3) C: (2), (3), (5)
B: (1), (5) D: (2), (3), (4), (5)
p n: C
Cu 21: Chn pht biu sai:

A: Bn cht cu to ho hc ca si bng l xenluloz.
B: Bn cht cu to ho hc ca t tm v len l protit.
C: Bn cht cu to ho hc ca t nilon-6 l poliamit.
D: Qun o nilon, len, t tm nn git vi x phng c kim cao.
p n: D
Cu 22: Peptit A c M=307 v cha 13,7% N. Khi thu phn mt phn thu c 2 peptit B v C. Bit
0,48g B phn ng vi 0,006 mol HCl v 0,708g C phn ng vi 0,006 mol KOH. Cng thc cu to
ca A l:
A: H2N-C2H4-CO-NH-C2H4-CO-NH-C8H8-COOH.
B: H2N-CH2-CO-NH-C2H4-CO-NH-C8H8-COOH.
C: H2N-C2H4-CO-NH-C8H8-CO-NH-C2H4-COOH.
D: H2N-C2H4-CO-NH-C2H4-CO-NH-C6H4-COOH
.p n: A
Cu 23: Khi thu phn hon ton 1 mol tri peptit X thu c 2 mol axit glutamic, 1 mol alanin v 1mol
NH3. X khng phn ng vi 2,4-initro flobenzen v c mt nhm COOH t do. Cng thc cu to
ph hp l:
A: CH3-CH2-CO-NH-CH2-CO-NH-CH-CO-NH-CH(CH3)-COOH.
CH=CH-CO-NH2.
B: HOOC-(CH2)2-CH(NH2)-CO-NH-CH(CH3)-CO-NH-CH-(CH2)2-COOH.
CO-NH2
C: NH - CH-CO - NH- CH - CO-NH-CH(CH3)-COOH
O=C
CH2- CH2 (CH2)2-CO-NH2 .
D: Kt qu khc.
.p n: C
Cu 24: Ngi ta iu ch anilin bng cch nitro ho 500g benzen ri kh hp cht nitro sinh ra. Khi
lng anilin (g) thu c l bao nhiu, bit rng hiu sut mi giai on u t 78%.
A: 346,7 C: 362,7
B: 315,9 D: kt qu khc
. p n: D
Cu 25 : Nhn xt no sau y sai:
A: Gluxit hay cacbohidrat ( Cn(H2O)m) l tn chung ch cc loi hp cht thuc loi
polihidroxi anhit hoc polihiroxi xton.
B: Gluxit hin din trong c th vi nhim v ch yu l cung cp nng lng.
C: Monosaccarit l loi ng n gin nht, khng thu phn c.
D: Polisaccarit l loi ng khi thu phn trong mi trng baz s cho nhiu monosaccarit.
E: Mi loi ng c rt nhiu ng phn do v tr tng i ca cc nhm OH trn mch
Cacbon.
.p n: D
Cu 26: Pht biu no sau y ng:
(1) polime dng sn xut t, phi c mch khng nhnh, xp song song, khng c, c kh nng
nhum mu
(2) T nhn to l loi c iu ch t nhng polime tng hp nh t: capron, clorin, terilen
(3) T visco v t axetat u l loi t thin nhin.
A: (1) C: (3)
B: (2), (3) D: c 3 cu
.p n: A
Cu 27: Cho qu tm vo phenylalanin trong nc nhn thy:

A: Qu tm ho xanh.
B: Khng xc nh c v phenylalanin khng tan trong nc.
C: Qu tm khng i mu.
D: Khng xc nh c v khng r pH
. p n: C

Cu 28: Cho cc cng thc sau:
[- NH ( CH2)6 NH CO (CH2)4 CO -]
[- NH ( CH2 )5 CO-]
[ - NH ( CH2)6 CO ]
[ - CH2 CH( C6H5) ]
[ - CO C6H5 CO O CH2 CH2 O -]
Th t sp xp ng tn gi ca cc cng thc trn l:
A: T nilon 6,6 ; t nilon -6, t nilon-7, PS, Dacron.
B: T nilon 6,6 ; PS, Dacron; t nilon-7;t nilon -6
C: Dacron; t nilon-7;t nilon -6; PS; T nilon 6,6 .
D: khng c th t no ng.
. p n: A
Cu 29: Trong lipit khng tinh khit thng cn ln mt lng nh axit monocacboxylic t do. S mg
KOH cn trung ho axit t do c trong 1g lipit gi l ch s axit ca lipit. Khi lng NaOH cn
trung ho 5 g lipit c ch s axit bng 7 l:
A: 25 g C: 0,25g
B: 0,025 g D: 0,0025 g
.p n: B
Cu 30: Hy cho bit s khc bit v c im cu to, nh ngha gia phn ng trng ngng v phn
ng trng hp:
A: Phn ng trng hp th monome ch c 1 lin kt kp v gii phng H2O, cn phn ng trng
ngng th monome c 2 lin kt kp v gii phng H2O.
B: Phn ng trng hp th monome phi c lin kt kp v khng gii phng H2O, cn phn
ng trng ngng th monome phi c t 2 nhm chc tr ln v c gii phng H2O.
C: Phn ng trng hp th monome phi c lin kt kp v gii phng H2O, cn phn ng trng
ngng th monome phi c t 2 nhm chc tr ln v c gii phng H2O.
D: Phn ng trng hp th mononme phi cha 2 nhm chc tr ln v khng gii phng H2O,
cn phn ng trng ngng th monome phi c lin kt kp v gii phng H2O.
p n: B
Cu 31: T l:
A: Nhng polime thin nhin hoc tng hp c th ko thnh si di v mnh.
B: Nhng polime tng hp c cha nhiu nhm chc amit.
C: Nhng polime c ch bin bng con ng ho hc.
D: Nhng polime c sn trong t nhin.
.p n: A
Cu 32: Ti sao t poliamit li km bn v mt ho hc :

A: C cha nhm COOH.
B: C cha lin kt peptit.
C: C cha nhm peptit.
D: C cha nhm NH2.
.p n: C

Cu 33: Nha bakelit ( mt dng ca phenolformandehit) c tnh bn c hc cao, chu c ma st, va
chm. Hy cho bit cu trc ca nha bakelit thuc loi no sau y:
A: Mch khng nhnh.
B: Mch khng gian.
C: Mch c phn nhnh.
D: c A, B, C u sai.
.p n: B
Cu 34: Hon thnh s sau:

Propanol 1 Y Z Alanin
Y, Z l nhng cht no:
A: C2H5CHO v CH2 = CHCl COOH
B: C3H7O2 v CH2Cl CH2 COOH
C: C2H5COOH v CH3CHClCOOH.
D: B v C sai.
p n: C
Cu 35: Cho cc polyme thin nhin sau:

C:(C6H10O5)n ; Y(C5H8)n; Z:(-NH-R-CO-)n
Nhn xt ng l:
A.X l xenluloz B.Y l cht do C.Z l t tm D.A,C ng
p n: D
Cu 36: Ch dng dung dch AgNO3/NH3,ta c th khng phn bit c cht no sau y:
A.glucoz v saccaroz B.glucoz v glixerin
C.saccaroz v mantoz D.glucoz v mantoz
p n:D
Cu 37: t chy hon ton 1 cht ng th thu c 1,32 g CO2 v 0,495 g H2O. Phn t khi ca
ng trn gp 1,9 ln phn t khi glucoz. Cng thc ca ng l :
A. C6H12O6 B. C12H22O11 C.(C6H10O5)n D. (C6H12O6)2
p n: B
Cu 38: Dung dch saccaroz tinh khit khng c tnh kh nhng khi un nng vi dung dch H2SO4
li c th cho c phn ng trng gng. l do:
A. c s to thnh andehyt sau phn ng .
B. Trong phn t saccaroz c cha este vinyl b thu phn.
C. Saccaroz trng gng c trong mi trng axit .
D. Saccaroz cho phn ng thu phn to glucoz v fructoz
p n: D
Cu 39:
So snh tnh baz ca cc hp cht da trn s lai ho ca N
: R-CN; RCH=N-R; RNH2
Sp xp theo th t tng dn v mnh
a). RNH2 < RCH=N-R < R-CN.
b). R-CN< RCH=N-R< RNH2.
c). RCH=N-R< RNH2< R-CN.
d). RNH2< R-CN< RCH=N-R.
p n ng : B
Cu 40:
kh nitrobenzen thnh anilin ta c th dng cc cht no sau y:
1) Kh H2 2) Mui FeSO4 3) Kh SO2 4) Fe + dd HCL
a) 1,4 b) 1,2 c)2,3 d)Ch c 4.
p n ng : d.
Cu 41 :
Sp xp cc cht sau y : CH3OH, CH3NH2, C2H5NH2 theo th t nhit si tng dn
a) CH3NH2 < C2H5NH2< CH3OH.
b) CH3OH< C2H5NH2< CH3NH2.
c) CH3NH2< CH3OH< C2H5NH2.
d) C2H5NH2< CH3NH2< CH3OH.
p n ng : a.
Cu 42:
Mt dung dch cha hai amino axit : glixin( pI = 5.97) v lixin ( pI= 9.74) ( pI: im ng
in).Nu in phn dung dch pH= 5.97 v pH= 9.74 th c hin tng g xy ra
a) pH1= 5.97 ca hai aminoaxit ng yn
pH2= 9.74 c hai i v ant
b) pH1= 5.97 glixin ng yn , lixin i v ant
pH2= 9.74 glixin i v catt , lixin ng yn.
c) pH1= 5.97 c hai i v catt
pH2= 9.74 c hai i v ant.
d) pH1= 5.97 glixin ng yn, lixin i v cat t .
pH2= 9.74 glixin i v ant, lixin ng yn.
p n ng: d.
Cu 43 :
Trong cc aminoaxit sau chn A.A trung tnh, baz, axit.
1) CH3-CH(NH2)-COOH 2) H2N-CH2- (i-butyl)-C OOH
3) HOOC- CH2- CH(NH2)-COOH 4) H2N-(CH2)4-CH(NH2)-COOH
a)1-2 trung tnh , 4 axt, 3 baz
b)1 trung tnh, 2-3-4 axit, 4 baz
c)1-2 trung tnh, 3 axit, 4 baz
d)2 trung tnh, 1-3 axit, 4 baz
p n ng : c.
Cu 44:
C bao nhiu ipeptit c th to ra t 2 A.A l alanin v glixin
a) 2 b)3 c)4 d)1
p n ng: b.
Cu 45 :

C bao nhiu tri peptit c th to ra t ba A.A : alanin, glixin, tysosi
a)9 b) 18 c) 6 d) 27
p n ng : d.
Cu 46 :Trong cc pht biu sau v s trng hp ca stiren cho ra polistiren.
1) Polistiren dng mch thng.
2) Khi trng hp stiren nu c thm 1 t divinylbenzen th cht trng hp s c c cu mng

khng gian.
3) T l ivinylbenzen : stiren cng ln th polime thu oc cng cng
Chn pht biu sai
a) Ch c 1 b) ch c 2 c) ch c 3 d) khng c pht biu no sai.

p n ng : d.
Cu 47 : Thu phn hon ton 200 gam hn hp gm t tm v lng cu th thu c 31.7 gam
glyxin.Phn trm ca glyxin trong t tm v lng cu l 43.6% v 6.6%.Thnh phn % khi lng ca
hn hp ban u l (%) :
.T tm Lng cu T tm Lng cu
A.25, 75 B. 43.6, 6.6
C.50, 50 D. Thnh phn khc.
E. Khng xc nh c.
Cu 48 :T rong cng thc C2H5O2N c bao nhiu ng phn aminoaxit :

A. 1
B. 2
C. 3
D. 4
E. 5.
p n : A
Cu 49 :
t chy mt amin thm bc nht X thu c 1.568 lt kh CO2 v 0.336 lt kh tr. trung ho ht
0.05 mol X cn dng 200 ml dung dch HCL 0.75 M. Bit cc th tch kh o ktc.Xc nh cng
thc phn t ca amin.
A. C6H5NH2 B. (C6H5)2NH2
C. C2H5NH2 D. C7H11N3
p n ng : D.
Cu 50 :
A l mt a-aminoaxit no ch cha mt nhm NH2 v mt nhm COOH. Cho 15.1 gam A tc dng
HCL d ta thu c 18.75 gam mui clohirat ca A.Vy cng thc cu to ca A l :
A. CH3-CH(NH2)-COOH. B. H2N-CH2-COOH.
C. H2N-CH2-CH2-COOH. D. CH3-CH2-CH(NH2)-COOH.
E. Kt qu khc.
p n ng : E
Cu 52 :
Nhng cht sau ay cht no l lng tnh :
A. H2N-CH2-COOH B. CH3COONH4
B. C. NaHCO3 D. (NH4)2CO3 E. Tt c u ng.
p n ng : E.
Cu 53 :
.A l hp cht hu c c cng thc phn t l C5H11O2N. un A vi dung dch NaOH thu c mt

hn hp cht c cng thc phn t l C2H4O2Na v cht hu c B, cho hi B qua CuO/to thu uc cht
hu c D c kh nng cho phn ng trang gng.
Cng thc cu to ca A la :
A. CH3(CH2)4NO2
B. H2NCH2COOCH2-CH2-CH3.
B. H2NCH2-COO-CH(CH3)2
C. D. H2NCH2-CH2-COOC2H5.
E. CH2=CH-COONH3-C2H5.
p n ng : B
Cu 54+55 :
Cho 20 gam hn hp gm 3 amin n chc no ng ng lin tip tc dng va vi dung dch HCL
1M, c cn dung dch thu c 31.68 hn hp mui.
1. Th tch dung dch HCL dng l :
A. 100 B.16 C.32 D.320 E. Kt qu khc.
p n ng : D
2. Nu 3 amin trn oc trn theo t l mol 1 : 10 : 5. Theo th t khi lng phn t tng dn th
cng thc phn t ca 3 amin l :
A. CH3NH2 ; C2H5NH2 ; C3H7NH2. B. C2H7N ; C3H9N ; C4H11N.
C. C3H9N ; C4H11N ; C5H13N. D. C3H7N ; C4H9N ; C5H11N
E Kt qu khc

p n ng : B.
Cu 56 :
Khi t cc ng ng ca metylamin . T l th tch K= V(CO2) : V(H2O) bin i nh th no theo s

lng nguyn t cacbon trong phn t ?
A. 0,4 < K< 1 B. 0.25 < K < 1
C. 0.75 < K < 1 D. 1 < K < 1.5 E. Kt qu khc.
p n ng :A.
Cu 57+58 :
C 1 loi lipit n gin ( gi s ch s axit= 7), gi thit thuc loi triolein hay glixeerin trioleat.
a) Ch s it ca lipit l :
A.86.2 B. 68.2 C.98.8 D. 57.7 E. 52.4
p n ng : A
b) Ch s x phng ho ca lipit l :
A. 177 B.157 C. 173 D.183 E.197
p n ng : E.
Cu 59 :
Cho 18.32 gam 2,4,6 trinitro phenol vo mt chai bng gang c th tch khng i 560 cm3. t kp
n vo chai ri cho n 1911 oC . Tnh p sut (atm) trong bnh ti nhit bit rng sn phm n
l hn hp CO, CO2, N2, H2 v p sut thc t nh hn p sut l thuyt 8%.
A. 207,36 B. 211,968 C. 201 D.230,4 E. Kt qu khc.
p n ng : B.
Cu 60 :
Cho cc dung dch cha cc cht sau :
X1 : C6H5NH2 X2 : CH3-NH2 X3 : H2N-CH2-COOH X4 : HOOC-CH2-CH2-CH(NH2)-COOH
X5 : H2N- (CH2)4- CH(NH2)-COOH.
Dung dch no lm giy qu tm ho xanh :
A.X1, X2, X5 B. X2, X3, X4

C. X2, X5 D. X1, X5, X4 E. Kt qu khc.
p n ng : C.
Cu 61 :
Mt gluxit X c cc phn ng din ra theo s :

0
X Cu( OH
)2 / NaOH
Dung dch xanh lam
t
Kt ta gch.
X l :
A. Glucz B Fructz
C.Saccarozo D. Mantozo E. A,D
p n ng : E.
Cu 62 : Xenlulozo trinitrat l cht d chy v n mnh, c iu ch t xenlulozo v axit nitric. Tnh

th tch(l) axit nitric 99.67% c khi lng ring 1.52g/ml cn sn xut 59,4 kg xenlulozo trinitrat
vi hiu sut 90%.
A. 27.6 B.32.5
C. 26.5 D. 32.4 E. Kt qu khc.
p n ng : E.
Cu 63 :Fructozo khng cho phn ng no sau y :
A.Cu(OH)2 B. (CH3CO)2O C.Dung dch AgNO3/NH3
D. dung dch Br2 E. H2/Ni,to
p n ng : D.
Cu 64 : Khi lng gam glucozo cn iu ch 0,1 lit ru etylic ( khi lng ring 0.8 g/ml) vi
hiu sut 80% l :
A.190 B.196.5 C.185.6 D.212 E. Kt qu khc.
p n ng : E.
Cu 65 :
Mun xt nghim s c mt ca ng glucozo trong nc tiu, ta c th dng thuc th no sau y :
A. Giy o pH B. Dung dch AgNO3
C. Thuc th Feling D. Cu(OH)2
E. C D,B,C u ng.
p n ng E.
Cu 66:Mantoz l ng c tnh kh cn saccaroz li khng c tnh kh l bi v:
A.Do gc -glucz th 2 c kh nng m vng to CH=O nguyn t C1.
B.Do isaccarit c khi lng phn t ln gp i so vi monosaccarit hp thnh n.
C. mi nguyn t C u c lin kt phn cc v cc nhm c lin kt H vi H2O
( C-O-C,O-H)
p n: A
Cu 67 Mt s bnh nhn phi tip ng vo c th theo ng tnh mch. l ng:

A.Saccarz
B.Glucz
C.Fructz
p n: B
Cu 68: nhit phng glucz, fructz(M=180) trng thi rn, trong khi axit lic c M=282
li l cht lng l bi v:
A.Do glucz, fructz(M=180) c nhiu lin kt phn cc c 5 nhm OH to lin kt H lin
phn t.
B.Do axit lic gm hu ht cc kin kt khng phn cc, ch c 1 nhm COOH l phn cc
to lin kt H lin phn t.
C.C A v B u ng.
D.L do khc.
p n: C
Cu 69: phn bit glucz v fructz, ngi ta dng ho cht no sau y:

A.dd Br2
B.dd FeCl3
C.S dng ng thi c hai dd trn.
D.Cho dd Br2 vo trc sau l dd FeCl3.
p n: D
Cu 70: u l CTCT ca nha Bakelit:

A.[-CH2-CHCl-CHCl-CHCl-]n
B.[-CO-C6H4-CO-O-CH2-CH2-]n
C.[-C6H4(OH)(CH2)-]n
D.[-CH2-CH(OH)-]n
p n: C
Cu 71: nh ngha prtit:

A.L chui hp bi nhiu -axitamin ni vi nhau bng lin kt peptit theo 1 trt t nht nh
v c cu trc khng gian c th.
B.L nhng polime c tnh do.
C.L nhng polime c dng rn ko thnh si di v mnh.
D.Do nhiu gc -glucz lin kt vi nhau nh cu ni -1,4gluczit.
p n: A
Cu 72: Ta c th chng minh glucoz c 5 nhm OH bng phn ng no di y:

A.Glucoz tc dng vi Cu(OH)2.
B.Phn ng este ho.
C.Phn ng kh Cu2+ v phn ng vi dd AgNO3/NH3.
D.Phn ng kh glucoz bng HI trong ng kn.
p n: B
Cu 73:ng phn A ca C3H6O3 va c tnh cht ca ru va c tnh cht ca axit v phn ng tch
nc ca A to ra cht B lm mt mu dd nc Br2 .Bit sn phm trng ngng ca A l [-O-(CH2)2-
CO-]n.CTCT ca A l:
A.HO-CH2-CH2-COOH
B.CH3-CH(OH)-COOH
C.Kt qu khc.
p n: A
Cu 74:Mt hp cht hu c A mch thng c CTPT l C3H10O2N2. A tc dng vi kim to thnh

NH3, mt khc A tc dng vi axit to thnh mui amin bc 1.CTCT ca A l:
A.H2N-CH2-CH2-COONH4
B.CH3-CH(NH2)-COONH4
C.C A v B u ng.
D.CTCT khc.
p n: C
Cu 75: u l sn phm chnh khi trng hp vinylclorua:

A.[-CH2-CHCl-CH2-CHCl-]n
B.[-CH2-CHCl-CHCl-CH2-]n
C.-
D.Kt qu khc.
p n: A
Cu 76: Cho 34,2g hn hp saccaroz c ln mantoz. Phn ng hon ton vi Ag2O/NH3 d thu c
0,215 g Ag. Tnh tinh khit ca saccaroz.
A: 1% C: 99% B: 90% D: 10%
p n: C
Cu 77: Mantoz cn gi l ng mch nha l ng phn ca:

A Glucoz C: fructoz
B:saccaroz D: Tinh bt
p n: B
Cu 78: Trng gng hon ton mt dung dch cha 27g glucoz. Lng AgNO3 dung l:
A: 32,4g C: 51g
B: 25,5g D: 21,7g
p n: C
Cu 79: Thu phn hon ton 1kg saccaroz thu c:

A: 1kg glucoz v 1kg fructoz.
B: 1kg glucoz.
C: 0,5 kg glucoz v 0,5 kg fructoz.
D: 526,3g glucoz v 526,3g fructoz.
p n: D
Cu 80: Cho polime [NH-(CH2)5-CO-]n tc dng vi dung dch NaOH trong iu kin thch hp. sn
phm sau phn ng l :
A.NH3 B.NH3 v C5H11COONa
C.C5H11COONa D.NH2-(CH2)-COONa
p n: D
Cu 81: Pht biu no sau y khng ng:

A. iu kin thng,glocozo,fructoz,mantoz,saccaroz u ho tan Cu(OH)2 to dung
dch xanh lam.
B. Glucoz v fructoz u tc dng vi H2(Ni,to) cho poliancol.
C. Xenlulozo lun c 3 nhm OH.
D. Glucoz,fructoz,mantoz b oxi ho bi Cu(OH)2 cho kt ta khi un nng.
p n: C
Cu 82: Gluxit A c cng thc n gin nht l CH2O,phn ng c vi Cu(OH)2 cho dung dch m
xanh lam.bit 1,2 g A tc dng hon ton vi AgNO3/NH3 cho 1,728 g Ag.
Vy A c cng thc phn t :
A. C6H12O6 B. C5H10O5 C. C12H22O11 D. (C6H10O5)n
p n: B
Cu 83 :t chy ht a mol amino axit A c 2a mol CO2 v a/2 mol N2. vy A l:

A. NH2-CH2-COOH.
B. NH2-CH2-CH2-COOH
C. A cha 2 nhm -COOH trong phn t
D. A cha 2 nhm NH2 trong phn t.
p n: A
Cu 84: Mt hp cht hu c X c % C=40,0; %H=6,7; %O=53,3. xc nh cng thc n gin nht

ca X . X l 1 mono,i,hay tri saccarit? Bit rng MX=180. cng thc cu to ca X l :
A. CH2O,monosaccarit,C5H10O5.
B. CH2O,disaccarit,C12H22O11.
C. CH2O,trisaccarit,C6H12O6.
D. kt qu khc.
p n: D
Cu 85: Tnh cht c trng ca tinh bt l :

(1)polisaccarit (2)Khng tan trong nc (3) C v ngt
Thu phn to thnh:
(4)glucoz (5)fructoz
(6)Lm chuyn mu iot thnh xanh lam
(7)Dng lm nguyn liu iu ch dextrin
Nhng tnh cht no sai:
A.2,7 B.2,6,7
C.4,6 D.3,5
p n: D


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Chuyên đề Hoá Hữu cơ - Lớp 11 chuyên Hoá - Trường THPT chuyên Lê Quý Đôn PDF

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Chuyn Ho Hu c - Lp 11 chuyn Ho - Trng THPT chuyn L Qu n

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MT S PHNG PHP GII NHANH

p dng nh lut bo ton khi lng ta c :

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M khi t chy X th nCO2 = nH2O = 0,015 (mol)

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R1 ng vi -H m R1 + 44 + R1' = 88 R1' = 43 ng vi C3H7-

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(- CH2 - C(CH3) = C(CH3) - CH2 -)x(- CH2 - CH(CN) - )y

(6x + 3y) C (6x + 3y) CO2

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trong mt kh nhin k ngi ta thu c 1100cm3 hn hp kh. Cho hn hp ny lm lnh, th tch

Cu 85: Hn hp A gm 1 ankan v 1 anken. t chy hn hp A th c a mol H2O , b mol CO2.

A.8 B.18 C.4 D.7 E.kt qu khc

Cu 101: Hn hp gm 15 anken ch th rn hoc th lng v c s nguyn t C khc nhau. Hi

Cu 103:: Hidrocacbon no sau y khi t chy s sinh ra nCO2 : n H2O = 1 : 4

C. CH3 CH2 C Br D. CH CH CH3

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CHNG II: RU- PHENOL-ANMIN

Cu 1: Mt ru no a chc X mch h c n nguyn t C v m nhm -OH trong cu to phn t. Cho

Cu 4:. un nng hn hp A gm 10 ru no n chc vi H2SO4 c 1400C. S ete thu c l :

Cu 8:.Mt ru A mch h khng lm mt mu nc Br2. t chy a(lt) hi ru A cn 2,5a (lt)

Cu 9:. Sp xp theo th t mnh tng dn tnh axit ca cc cht cho sau y :

Cu 15:. Hai hp cht hu c A, B to bi 3 nguyn t v u c 34,78% oxi v khi lng. Nhit

Cu 17:. Pht biu no sau y ng :

Cu 18: t chy 1 mol 1 ru no cn 3,5 mol O2. Ru l :

Cu 19: Polivinyl ancol l polime c th iu ch t monome no sau y :

Cu 20:. Hn hp A gm 2 ru no n chc.Chia hn hp A thnh 2 phn bng nhau :

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Cu 26:.Xc nh cng thc phenol c cha 13,11% khi lng oxi.

Cu 27:.Xc nh cht ban u trong dy sau:

Cu 28:.Xc nh cht X trong s sau:

Cu 31:.Cho s sau: ru propylic X Y phenol

Cu 32:Cho s sau, xc nh cht u dy:

Cu 34:Mt ru no n chc khi chy to nn mt th tch CO2 ln gp 8 ln th tch H2 thot ra khi

A.(CH3)3COH B.(CH3)3C-CH2OH C.(CH3)2CH-

Cu 35:.Kh thu c vi H=66,7% khi 50 gam ru no n chc tc dng vi H2SO4 c hp th

A.C3H7OH B.C2H5OH C.C4H9OH D.CH3OH

Cu 38:Xp cc ancol benzyl di y theo th t phn ng gim dn vi HBr : C6H5-CH2OH(1) ,

Cu 40:un nng hn hp A gm 10 ru no n chc vi H2SO4 c 1400C. S ete thu c l :

Cu 42:un nng t t hn hp 2 ru : C2H5OH v n-C3H7OH vi H2SO4 m c. S phn ng xy

Cu 43:S ng phn cu to ca C8H18 l :

Cu 44:. Sp xp theo th t mnh tng dn tnh axit ca cc cht cho sau y :

Cu 45:Hn hp X c phan trn t cc rc no n chc cng dy ng ng c s nguyn t

Cu 47:. t chy mt ru a chc ta thu c H2O v CO2 vi t l s mol nH2O : nCO2 = 3: 2. Vy

Cu 51:. Pht biu no sau y ng :

Cu 52:. t chy 1 mol 1 ru no cn 3,5 mol O2. Ru l :

Cu 53:Polivinyl ancol l polime c th iu ch t monome no sau y :

Cu 54:Hn hp A gm 2 ru no n chc.Chia hn hp A thnh 2 phn bng nhau :

Cu 61:.Xc nh cht ban u trong dy sau:

Cu 63:.Xc nh cht X trong s sau:

Cu 66:Cho s sau: ru propylic X Y phenol

Cu 67:Cho s sau,xc nh cht u dy:

Cu 70:Mt ru A mch h khng lm mt mu nc Br2. t chy a(lt) hi ru A cn 2,5a (lt)

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Cu 71:.Mt ru no n chc khi chy to nn mt th tch CO2 ln gp 8 ln th tch H2 thot ra khi