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The most neutral (least acidic) teas were found to be from Starbucks, with the chai tea latte (with
soy milk) being the most neutral at an average pH of 7.07. The green tea by itself was generally
more neutral as compared to black tea, with Starbucks being the least acidic at pH 6.6. In terms
of cup insulation, the Dunkin Donuts medium (Styrofoam) cup was the best insulated as
compared to the paper cups from the other establishments. This cup kept the liquid within the
ideal consumption range (60C 8.3C) for nearly 44 minutes. In conclusion, the best tea for the
body (in terms of low acidity) was the chai tea with soy milk from Starbucks, and the most
insulated disposable cup was the medium Styrofoam cup from Dunkin Donuts.
Figure 4 - (From Left to Right) Starbucks Tall, Argo Tea Small, Dunkin Donuts Medium
(Styrofoam), Dunkin Donuts Small (Paper) 6
Figure 5 - a) Beaker on Hot Plate, b) Starbucks Cup Setup, c) Dunkin Donuts Cup Setup 7
3 List of Tables
Table 1 - pH Test Experimental Data 8
5 Problem Statement
The primary objective of this experiment was to find the least acidic tea (amongst black, green,
and chai tea) from three of the most popular places to buy hot beverages on campus. The pH
values for each of these tea types were collected in order to provide health-conscious consumers
with an awareness of the tea choices they have on campus as it pertains to acidity. To make this a
more thorough study, the disposable cups collected from each tea sample were also evaluated to
determine which had the best insulation. This data is critical for consumers looking to maintain
their tea (or other hot beverages) within the ideal drinking temperature range for the longest
period of time.
6 Introduction
Many people are not aware of the importance of maintaining a proper pH balance in their body
in terms of their health. The pH of the human body has been known to vary with the pH of the
foods and drinks consumed. In chemistry, pH is defined as the hydrogen ion concentration in
aqueous solution [1], and the acidity or alkalinity of a solution can be determined by measuring
its pH. The pH scale ranges from 0 to 14, 7 being defined as a neutral solution, most commonly
known as the pH for pure/distilled water. The pH is calculated by Equation 1 below:
pH log (1)
Where H+ represents the hydrogen concentration in moles per liter [2]. Solutions with high
concentration of hydrogen are considered acidic and have pH of below 7 (i.e. a higher
concentration means a lower pH value). The opposite can be said about alkaline solutions, as
they have pH above 7 denoting lower Hydrogen ion concentrations.
As seen in Figure 1,, the ideal pH level for blood in thee human boddy ranges frrom about 77.365-
7.42 [4]. It is very crritical that th
he blood staays within thhis range as when the body becomees too
acidic or alkaline, thee blood pH can
c shift, and
d could ultim
mately lead tto death of ccells in the huuman
body (wh
hich occurs around
a pH 3.5,
3 as seen in
i the figuree). The humaan body conntinually worrks to
maintain the body within
w the specified
s ran
nge. In ordder for the bbody to com
mpensate foor the
consump
ption of acid
dic foods and
d beverages, it will takee minerals ffrom bones and tissues. This
can increease the risk
ks of health problems
p inccluding toothh decay, ostteoporosis, hheart diseasee, and
diabetes [5]. The bod
dy can also use
u fat to sto
ore these acidds making itt difficult foor weight losss [6].
Based on
n this inform
mation, consu
umers shoulld be aware of the acidiity (or alkaliinity) of the food
and beveerages they consume
c on a daily basiss.
The three types of tea chosen for this experiment (black, green, and chai) are all derived from the
same plant named Camellia Sinesis. When tea leaves are processed for consumption, they go
through an oxidation stage, and the level of oxidation determines the kind of tea produced [8]. If
the leaves are oxidized for a short amount of time, these leaves become Green Tea. Due to the
low levels of oxidation, the tea is light green in color (hence the name) and subtle in flavor.
Black tea results from completely oxidized tea leaves. This has the darkest color and strongest
flavor of all tea varieties. Chai tea has similar properties to black tea in that it is essentially black
tea with spices mixed in with milk added after brewing. These added spices include mainly
ground ginger and ground cardamom, with cinnamon, star anise and/or fennel seeds, peppercorn,
nutmeg and cloves [9]. The data collected during this experiment will serve to inform tea
consumers at Northeastern University about the acidity of different teas as well as the best
insulated disposable cup around campus.
7 Procedure
7.1 Equipment Description
For the pH measurement part of the experiment, a pH meter (EcoTestr pH2) was used along with
a Pyrex 250mL beaker, an Omega liquid-in-glass thermometer (p/n GT-736580), and an
Amprobe infrared (IR) thermometer (p/n IR608A). For the temperature/insulation testing, the
measurements lab at 223 Forsyth was utilized along with 4 Omega K-Type thermocouples (p/n
KMQSS-125G-6), two Pyrex 2000mL beakers filled with tap water, two hot plates for boiling
the water, and four computer workstations with LabVIEW software installed for data collection.
The manufacturers specifications for these devices can be found in Appendices A-D. A
7.2 Calibration
The pH meter was received factory calibrated, and was used as such for the duration of the
experiments. There was no calibration solution available until the completion of the pH
measurements. The pH meter was calibrated after the measurements had been taken, and it was
found that each pH value was 0.2 higher than the actual value. Thus, each of the measured pH
values was corrected by this amount. The liquid-in-glass thermometer served as the standard for
this experiment, and was used for calibration of the thermocouples. A two-point calibration was
performed using an ice-water bath and a boiling water bath. The calibration curves are shown in
Figure 2.
The IR thermometer was difficult to properly calibrate as the readings varied greatly depending
upon where it the bath it was pointed. Thus, the IR measurements serve as relative measurements
amongst the samples tested.
120
Station1Calib.
y=0.9836x+2.1718
100
Station2Calib. Station1
y=0.9834x+3.1917
80 Station2
Station3Calib. Station3
y=0.9852x+1.4626
60 Station4
Station4Calib. Linear(Station1)
y=0.9825x+3.4813
40 Linear(Station2)
Linear(Station3)
20 Linear(Station4)
0
20 0 20 40 60 80 100 120
In the lab
b, the two 2000mL
2 beak
kers were fiilled with tapp water thenn placed on two separatte hot
plates to
o boil (as seeen in Figurre 5a). Each workstation (and
h of the cuups was assiigned to a w
correspon
nding therm
mocouple). Once
O the waater was rappidly boilingg, the LabV
VIEW VIs were
started an
nd the waterr was poured
d into each of the cups annd quickly capped usingg the provideed lid.
The therm
mocouples were
w t drinking hole, as seeen in Figurees 5b and 5c. The
mounteed through the
VI colleccted temperaature data as a function of ment was runn over the course
o time, and this experim
of about three hours (enough tim
me for the tem
mperature off the liquid iin the cups tto drop below
w the
ideal drinking rang
ge). The ro
oom temperrature was also notedd using the liquid-in--glass
thermom
meter (21C).
The main
n safety con
ncern for th
his experimeent was the handling oof hot liquidds. Heat-resistant
gloves were
w required
d to handle the
t beakers of
o boiling w
water to ensuure the handdler did not ssuffer
any injurry from the high tempeeratures. No
o other safetty concerns of significaance were rraised
during th
he course of this
t experim
ment.
8 Results
8.1 pH
H Measurem
ments
The calib
brated data collected
c forr the pH meaasurements pportion of thhe experiment can be seeen in
Table 1. The 95% co
onfidence intterval was caalculated usiing Equationn 2 below:
Confidencee Interval , (2)
1 (3)
Where t is parameterr found usin
ng a table, v represents tthe degrees of freedom, calculated uusing
n 3 (5 for mo
Equation ost cases, ex
xcept the Staarbucks Chaai Tea with ssoy milk, whhich was 2),, N is
the numb
ber of data points, P is th
he level of siignificance ((0.05), and is the stanndard deviatiion of
the mean
ns, calculated
d by Equatio
on 4 below:
(4)
As shown in the table, there were two different samples (on two different days) for each type of
tea (with exception of the Starbucks Chai Tea with soy milk). This was both to get a better
sample size and account for variation due to different personnel at the establishments. Three pH
measurements were taken per cup of tea in order to account for non-uniformity in the tea, and
these values were then averaged (as seen in the corresponding column in the table). The initial
temperature of the teas was also taken for reference, and the temperature at the time of pH
measurement was also recorded. A bar graph of the average pH values for each type of tea is
shown in Figure 6.
5.0
DunkinDonuts
pHValue
4.0 ArgoTea
Starbucks
3.0
SBUXw/SoyMilk
2.0
1.0
0.0
BlackTea GreenTea ChaiTea
As seen in Figure 6, the black teas were the most acidic of them all, with the Argo black tea
being the most acidic with a pH of 5.5. The Starbucks and Dunkin Donuts were both about the
same at a pH of 5.8. One interesting thing to note was both the Starbucks and Dunkin Donuts
teas came with a tea bag, whereas the Argo did not. This data would suggest that the Argo black
tea was stronger than the black tea other two establishments despite the lack of a tea bag. Perhaps
Argo had the black tea pre-brewed whereas Starbucks and Dunkin Donuts were steeped to order.
The green tea was generally more neutral than the black tea, with pH values ranging from 6.2-
6.6. Again, the green tea from Argo was the most acidic (based on the sample size), but only
marginally compared to Dunkin Donuts at 6.3. Starbucks had the most neutral green tea with a
pH of 6.6.
The chai tea had the highest amount of variation amongst the varieties tested, and this could be
attributed to the amount of (soy) milk added for each sample. For reference, the Starbucks Chai
tea was measured both with and without (soy) milk. Argo tea did not have this option. The pH of
the Starbucks chai tea without any additives was around 6.0, similar to that of black tea. This
made sense because chai tea is essentially black tea with a few added spices (and these spices
As expeccted, these curves havee the form of an expoonential decay function, and this oobeys
Newtons Law of Co
ooling [11]. The
T ideal tem
mperature lim
mits are defiined as 60C
C 8.3C [7]], and
this range was used for
f the analy
ysis of the cu
ups. Note thaat the Dunkin Donuts Sttyrofoam cupp was
The starting temperature for each of these cups was around the same (96-97C), and the room
temperature was steady around 21C (as measured by the liquid-in-glass thermometer). The
temperature at 10 minutes was also a good benchmark to compare the cups at. At this point in
time, the liquid in the Dunkin Donuts Styrofoam cup had cooled only about 10C, whereas the
liquid Dunkin Donuts paper cup had over 21C. The Argo Tea and Starbucks cups kept the
liquid at around 82C. Using a 1 minute moving average (i.e. averaging the values from the past
minute at a given point in time), it was then possible to calculate the time it took the liquid in
each cup to drop to the upper and lower limits of the ideal drinking temperature range. Then,
using the difference in these two times, the time within the ideal temperature range was
calculated (i.e. the t). As shown in the table, the Dunkin Donuts Styrofoam cup was the best at
keeping the beverage within the ideal range with a time of 43.8 minutes. The Dunkin Donuts
paper cup only kept it within this range for about 22.9 minutes and the Starbucks and Argo Tea
cups were about the same at about 30 minutes. The one minute moving average was used
because the instantaneous values for temperature would jump around (likely due to electrical
noise), so the moving average gave a more reliable estimate for each of the values. With moving
averages, there is a bit of a lag with the measurements, so there was an uncertainty of about 1
minute, conservatively.
9 Discussion
There were a few sources of error in these experiments. For example, the pH measurements for
the chai tea in particular were dependent upon the barista preparing the drink. The amount of soy
For the temperature measurements, there were also a few factors to take into consideration. One
of the major elements of this part of the experiment was the fact that it was a static measurement
in a laboratory environment. The experimental values did not take into account the decreased
volume of liquid associated with drinking as well as forced convection and radiation caused by
walking and sunlight hitting the cup (more prevalent with the darker Argo Tea cup). Again, the
goal of this experiment was to provide a baseline measurement, and to be able to evaluate the
cups under the same circumstances. The K-Type thermocouples had an accuracy of about
2.2C, and these could have had a noteworthy effect on the experiment, but as with the pH
measurements, this uncertainty would not have played a bit role in the final comparison results.
In other words, the Styrofoam cup would still clearly be the best-insulated cup of the test
samples. Other extraneous variables that would affect this experiment include the ambient
environment, namely room temperature, atmospheric pressure, and relative humidity, as these
could significantly impact the experiment.
10 Conclusions
The overall goal of this experiment was to determine the pH values of a few different varieties of
tea around Northeastern Universitys campus. It was found that chai tea with (soy) milk added
was the most neutral, specifically from Starbucks, as was the green tea, also from Starbucks. The
chai and green tea had a pH value of 7.1 and 6.6, respectively, and these were the beverages that
had a pH most similar to that of blood (7.365-7.42). The chai tea was very much dependent upon
the proportion of milk added to the tea, and this varies upon the consumers individual tastes. In
terms of the disposable cup insulation, the Dunkin Donuts Styrofoam cup kept the liquid in the
ideal consumption range for the longest amount of time (nearly 44 minutes), and this makes
11 References
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about-pH.com>.
2. "pH". Encyclopdia Britannica. Encyclopdia Britannica Online. Encyclopdia Britannica
Inc., 2015. Web. 16 Apr. 2015 <http://www.britannica.com/EBchecked/topic/454823/pH>.
3. Fig. 1 The Foundation of Health. The Natural Health Academy. < http://natural-health-
academy.com/ nutritional-supplements/hydration/>.
4. Casiday, R., & Frey, R., Blood, Sweat, and Buffers: PH Regulation During Exercise.
1999. Web. 17 April, 2015, <http://www.chemistry.wustl.edu/~edudev/LabTutorials/Buffer/
Buffer.html>
5. The Cause of Disease: pH Imbalance. Natural Health School Online.
<http://www.naturalhealthschool.com/acid-alkaline.html>.
6. Benjamin, S., The Importance of Your Bodys pH Balance.
<http://www.atlantaclassicalhomeopathy.com/pHbalance.htm>.
7. Brown, F. & Diller, K. Calculating the optimum temperature for serving hot beverages.
2008. Burns 34(5), 648654.
8. How Tea is Processed. Ineeka. 2015. <https://www.ineeka.com/how-tea-is-processed/>.
9. Myszko, A., Health Benefits of Chai Tea. San Francisco Chronicle.
<http://healthyeating.sfgate.com/health-benefits-chai-tea-9942.html>.
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Transf., 55. 53975402.
12.1 Ap
ppendix A EcoTestrr pH2 Mete
er Specifica
ations
12.3 Ap
ppendix C Amprobe
e IR608A IR
R Thermom
meter Spec
cifications
s
2.2C
1
uo 0.5C
2
u d uo2 uc2 (0.5) 2 (2.2) 2 2.256C