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ES2016
June 26-30, 2016, Charlotte, North Carolina
ES2016-59272
also mention that until recently, the research has been focusing 1
10
only on modifications and adjustment of the cycles using water- 32
ammonia mixture it but has not been conducted in direction of Absorber -
using other working fluids. Therefore he formulated properties Condenser
Pump
of three new working pairs based on organic and ionic liquids. 11 cooling
31
For absorption cycles can ionic liquids generally pair with H2 O, water / air
ammonia, hydrofluorocarbons, hydrocarbons and alcohols [29].
These cycles except for ammonia-water ones however FIGURE 2: PROCESS FLOW DIAGRAM OF THE SALT-H2 O
havent been calculated to utilize a specific heat source in waste ABSORPTION POWER CYCLE
heat recovery applications except for very recent work of the au-
thors [30, 31]. The cycles havent been studied experimentally,
of air in CT pCT is chosen with respect to manufacturers data
nor was found reference of sizing their single components. In the
from [32] and n is a number of segments for each HX discretiza-
first part of the paper will be introduced the principle of absorp-
tion. Ambient conditions were taken for relatively warm climate.
tion power cycle based on aqueous salt solution in general. After
fficiency of heat source utilization is calculated with respect to
that will be reviewed potential benefits of the proposed APC in
energy transferred from heat source fluid when cooled down to
comparison with Kalina cycle and ORCs, which are currently
ambient temperature for ACC and to wet bulb temperature for
considered for waste heat recovery applications. To see how a
CT heat rejection.
real device would be configured, what are its advantageous and
limiting features, general design aspects are then discussed, fol-
lowed by more accurate design data for 20 and 500 kWe units
TABLE 1: BOUNDARY CONDITIONS OF THE MODELS
(one with cooling by air cooled condenser, other by wet cooling
tower). In the last part before conclusion there are shown eco-
nomic aspects and brief cost estimate for the unit. TDB TW B pamb RHair Heq turb Approach
[ C] [ C] [kPa] [%] [m] [%] [ C]
25 21 100 70 15 80 5
MODELS OF THE CYCLES
Boundary Conditions and Properties Formulation pump Tmin,cond pCT RHCT,out Tmin,hs pACC f an
Heat source considered for the cycles was given as liquid [%] [ C] [Pa] [%] [ C] [Pa] [%]
water (pressurized to 8 bar) with temperatures 60-160 C, which
70 5 95 100 10 150 70
can represent fluid from geothermal or low temperature solar
sources and alternatively for later detailed design also hot air
which can represent industrial waste heat or flue gas for last bot-
toming unit. Other boundary conditions for the cycles are sum- There exist several formulations of water - salt solutions
marized in Tab. 1 for both cases of heat rejection methods, in- properties. In past were common works based on the Duhring
duced draft cooling tower (CT) and air cooled condenser (ACC). rule [33] and diagrams. Nowadays for LiBr are in use mainly two
Efficiency of pumps is chosen same for all pumps in the sys- formulations. The first one by Patek and Klomfar [34] is given
tem. Pinch point for recuperator is same as for the heat input for the entire composition range and temperature range from 0 C
HX, Tmin,hs . The difference between wet bulb temperature and to 227 C (500K), but gives only the properties on the vapour-
cold water outlet from CT is called Approach. Pressure drop liquid equilibrium curve. Second frequently used is formulation
Qeva, i
mvap, i
Nu = 0.023 Re0.8 Pra (9)
mliq, i-1 mliq, i
Qliq, i
c2
his,st + 0,st
2 zst
is,st = st (25)
c21,is c21 his,st
h1 = h1,is + 0.5 (19)
1000
0.5
w1 = c21 + u2 2 c1 u cos (1 ) = w2,is = w2 / (21)
TABLE 2: INPUT PARAMETERS IN TURBINE DESIGN
Stator vanes length without partial arch admission (theoreti- Ta gen m gear in 1 2 1
cal) l1,th is based on continuity Eqn. (22) with outflow coefficient
[ C] [-] [-] [-] [-] [-] [-] [-] [-] [ ]
1 and flow angle 1 . Ratio of theoretical and actual blade length
defines the partial arch parameter e, actual blade length is then 90 0.96 0.99 0.97 0.04 0.98 0.97 0.97 0.95 13
subject to optimization. Rotor blades are based on rule of thumb
3 mm longer than stator vanes. Mean diameter is used same for
the stator vanes and rotor blades. Continuity Eqn. (23) in relative
system is used to determine exit angle of steam from rotor blades
2 . Absolute outlet velocity is determined from velocity trian- Absorber A falling film absorber has been chosen for
gle Eqn. (24). Subsequently there are determined energy losses. primary design as it should behave most alike the theoretical
First so called primary losses are given by friction (and related counter flow absorber. Absorber design is a complex task for
velocity loss) in turbine nozzles, in rotor blades and by outlet ki- modeling with various techniques developed, but different mod-
netic energy zst . Following that are for the stage determined els for determination of heat and mass transfer coefficients only
additional losses, namely peripheral loss, partial admission loss, seldom show agreement, number of models are valid only for
disc friction loss, windage loss, loss by variable velocity field narrow range of temperatures and concentrations and even ex-
along blade length and by outlet steam wetness st . Detailed perimental results are not well consistent [4648]. Absorber
6 35
30
5
2nd,hs [%]
1st,hs [%]
25
4 LiBr
20
LiBr LiCl
3
LiCl 15 CaCl2
2 CaCl2
ammonia-water
10 ammonia-water
max ORC simple
1 max ORC simple 5
max ORC recup
max ORC recup
0 0
60 80 100 120 140 160 60 80 100 120 140 160
Heat source temperature [C] Heat source temperature [C]
(a) Cooling tower (a) Cooling tower
8 45
7 40
35
6
30
5
2nd,hs [%]
1st,hs [%]
25
4 LiBr
20
LiBr LiCl
3
LiCl 15 CaCl2
2 CaCl2
10 ammonia-water
ammonia-water
max ORC simple
1 max ORC simple 5
max ORC recup max ORC recup
0 0
60 80 100 120 140 160 60 80 100 120 140 160
Heat source temperature [C] Heat source temperature [C]
(b) Air cooled condenser (b) Air cooled condenser
FIGURE 5: MAXIMIZED NET THERMAL (1ST LAW) FIGURE 6: MAXIMIZED NET THERMODYNAMIC
HEAT SOURCE UTILIZATION EFFICIENCY (1st,hs ) OF (2ND LAW) HEAT SOURCE UTILIZATION EFFICIENCY
THE APCS AND REFERENCE RANKINE CYCLES (2nd,hs ) OF THE APCS AND REFERENCE RANKINE
CYCLES
10
2 70%
refrigeration
cycle
1,5
1 Crystallization line
1
0,5 0 20 40 60 80 100
60 80 100 120 140 160
Heat Source Temperature [C]
Saturated solution temperature [C]
(a) Cooling tower FIGURE 8: DUHRING DIAGRAM FOR LiBr AQUEOUS SO-
4
LUTION WITH HIGHLIGHTED TYPICAL ABSORPTION
3,5 REFRIGERATION CYCLE FROM [51] AND PRESENTED
max salt APC / max ORC POWER CYCLE, BOTH WITH HIGHEST SOLUTION TEM-
3 max salt APC / ammonia APC PERATURE 90 C.
LiBr APC / max ORC
2,5
ratio [-]
1 32.8 67.1 0.451 12.54 0.333 0.375 1 32.0 79.2 6.85 16.44 0.394 0.272
2 57.6 130.0 0.451 12.54 0.531 0.375 2 49.8 130.2 6.85 16.44 0.557 0.272
3 61.2 139.1 0.451 12.54 0.558 0.375 3 61.0 162.9 6.85 16.44 0.656 0.272
4 90.0 1044.0 0.451 12.36 3.186 1.000 4 90.0 1421.0 6.85 16.26 4.335 1.000
5 90.0 2668.0 0.154 12.31 8.300 0 5 90.0 2668.0 3.39 16.20 8.173 0
6 23.5 2514.0 0.154 2.90 8.488 0 6 27.7 2495.0 3.39 3.71 8.312 0
7 90.0 203.2 0.297 12.36 0.538 0.569 7 90.0 197.2 3.46 16.26 0.569 0.539
8 42.8 107.7 0.297 12.36 0.257 0.569 8 42.0 96.2 3.46 16.26 0.271 0.539
9 42.8 107.7 0.297 2.90 0.257 0.569 9 42.0 96.2 3.46 3.71 0.271 0.539
10 56.3 928.7 0.451 2.90 3.074 0.553 10 53.5 1284.0 6.85 3.71 4.267 0.514
11 32.8 67.1 0.451 2.90 0.333 0.375 11 32.0 79.2 6.85 3.71 0.394 0.272
21 100.0 374.1 13.93 110 7.063 21 100.0 419.2 70.80 150 1.307
22 71.2 344.7 13.93 110 22 70.9 297.5 70.80 150
23 70.9 344.7 13.93 110 6.981 23 70.1 294.4 70.80 150 0.959
component/case 20 kWe unit 500 kWe unit Parameter 20kWe unit 500kWe unit units
ing steam and 13 different organic working fluids. Absorption Cooling Tower Wcooling pump 61.5 kW
power cycles have a potential of application especially for very (500 kWe unit) W f an 25.0 kW
low temperature heat sources. Below heat source temperatures
mcooling water 208.8 kg/s
of approximately 120 C is the highest efficiency of heat source
utilization (and thus power output) provided by absorption power mair 202.2 kg/s
cycles, namely first CaCl2 , then LiCl and LiBr based cycle. The
ammonia-water mixture absorption cycle (simplest Kalina cycle)
has the lowest efficiency of absorption cycles in this low temper- tion with typically high pressures gives potential for a very com-
ature domain. Relative thermodynamic benefit of absorption cy- pact turbine, however for small power output this low volumetric
cles over Rankine cycles increases as the heat source temperature flow would result in very inefficient device, not to mention cor-
goes down, reaching up to hundreds percents at source temper- rosion problems from ammonia. LiBr solution seems to provide
ature 60 C. Reason is mainly in heat rejection energy demand, a trade off between relatively moderate vacuum, high efficiency
which can go up to a level comparable with turbine output. of the cycle and volumetric flow large enough for highly efficient
All absorption cycles using salt solution operate completely turbine design. Problems might arise in designing the two-phase
in vacuum in the whole investigated range of heat source temper- heat exchangers with changing temperature along the fluid flow
atures, which will require very air tight design solution. Deepest which is planned to be in detail explored later on in experimen-
vacuum is in CaCl2 and LiCl cycles. Water-ammonia combina- tal work. Another obstacle might be corrosivity of the solution.