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Tectonophysics 365 (2003) 257 282

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990 and 1100 Ma Grenvillian tectonothermal events in the northern


Oaxacan Complex, southern Mexico: roots of an orogen
L.A. Solari a,*, J.D. Keppie a, F. Ortega-Gutierrez a, K.L. Cameron b,
R. Lopez c, W.E. Hames d
a
Instituto de Geologa, Universidad Nacional Autonoma de Mexico, 04510 Mexico, D.F., Mexico
b
Earth Sciences Department, University of California, Santa Cruz, CA 95064, USA
c
Geology Department, West Valley College, Saratoga, CA 95070, USA
d
Department of Geology, Auburn University, Auburn, AL 36830, USA
Received 14 February 2002; accepted 13 June 2002

Abstract

Inliers of f 1.0 1.3 Ga rocks occur throughout Mexico and form the basement of the Oaxaquia microcontinent. In the
northern part of the largest inlier in southern Mexico, rocks of the Oaxacan Complex consist of the following structural
sequence of units (from bottom to top), which protolith ages are: (1) Huitzo unit: a 1012 F 12 Ma anorthosite mangerite
charnockite granite (AMCG) suite; (2) El Catrn unit: z 1350 Ma orthogneiss migmatized at 1106 F 6 Ma; and (3) El
Marquez unit: z 1140 Ma para- and orthogneisses. These rocks were affected by two major tectonothermal events that are
dated using U Pb isotopic analyses of zircon: (a) the 1106 F 6 Ma Olmecan event produced a migmatitic or metamorphic
differentiation banding folded by isoclinal folds; and (b) the 1004 978 F 3 Ma Zapotecan event produced at least two sets of
structures: (Z1) recumbent, isoclinal, Class 1C/3 folds with gently NW-plunging fold axes that are parallel to mineral and
stretched quartz lineations under granulite facies metamorphism; and (Z2) tight, upright, subhorizontal WNW- to NNE-trending
folds accompanied by development of brown hornblende at upper amphibolite facies metamorphic conditions. Cooling through
500 jC at 977 F 12 Ma is documented by 40Ar/39Ar analyses of hornblende. Fold mechanisms operating in the northern
Oaxacan Complex under Zapotecan granulite facies metamorphism include flexural and tangential longitudinal strain
accompanied by intense flattening and stretching parallel to the fold axes. Subsequent Phanerozoic deformation includes
thrusting and upright folding under lower-grade metamorphic conditions. The Zapotecan event is widespread throughout
Oaxaquia, and took crustal rocks to a depth of f 25 30 km by orogenic crustal thickening, and is here designated as
Zapotecan Orogeny. Modern analogues for Zapotecan granulite facies metamorphism and deformation occur in middle to lower
crustal portion of subduction and collisional orogens. Contemporaneous tectonothermal events took place throughout Oaxaquia,
and in various parts of the Genvillian orogen in Laurentia and Amazonia.
D 2003 Elsevier Science B.V. All rights reserved.

Keywords: Oaxaquia; Mexico; Grenville; U Pb geochronology; Granulite metamorphism

* Corresponding author. Tel.: +52-55-5622-4263x113; fax: +52-55-5622-4289.


E-mail address: solari@servidor.unam.mx (L.A. Solari).

0040-1951/03/$ - see front matter D 2003 Elsevier Science B.V. All rights reserved.
doi:10.1016/S0040-1951(03)00025-8
258 L.A. Solari et al. / Tectonophysics 365 (2003) 257282

1. Introduction continent continent collision events, respectively,


which occurred along the margin of Amazonia.
The Oaxacan Complex (OC) is the largest inlier
of f 1 Ga rocks in Mexico and underlies more than
10,000 km2 of southern Mexico (Fig. 1A). Other 2. Geological setting
similar smaller inliers, borehole samples and xeno-
liths in Tertiary lavas led Ortega-Gutierrez et al. The Oaxacan Complex consists of para- and
(1995) to conclude that the backbone of Mexico is orthogneisses, the latter having protolith U Pb zircon
underlain by a similar f 1.0 Ga basement, which ages ranging from z 1134 to 1150 and f 1012 Ma
they named Oaxaquia (Fig. 1A). It may continue into (Keppie et al., 2003), which were affected by granulite
the Chortis Block of Guatemala and Honduras facies metamorphism (700 750 jC and 7.2 8.2 kb,
(Donnelly et al., 1990; Manton, 1996; Nelson et Mora et al., 1986) at about 990 Ma (Keppie et al.,
al., 1997), which is inferred to have lain along the 2001, 2003). Previous structural studies of the Oax-
Pacific margin of Mexico before being sinistrally acan Complex by Kesler and Heath (1970) and Kesler
displaced in the Oligocene (Schaaf et al., 1995). As (1973) conclude that it was only affected by one phase
such, Oaxaquia and the Chortis block constitute of deformation.
major pieces that need to be considered in recon- In several other areas in Mexico, f 1.0 Ga rocks
structing f 1 Ga Rodinia. However, their inferred are also exposed (Fig. 1A): near Ciudad Victoria
location in recent reconstructions of Rodinia differs (Novillo Gneiss, Silver et al., 1994), at Molango
widely. For example, Karlstrom et al. (1999) and (Huiznopala Gneiss, Lawlor et al., 1999), and around
Burrett and Berry (2000) infer that Oaxaquia is the La Mixtequita in eastern Oaxaca State (Guichicovi
southern extension of the Laurentian Grenville Oro- Complex, Weber and Kohler, 1999; Ruz et al., 1999).
gen, and represents a connecting segment to the Published U Pb igneous protolith ages are f 1000
f 1.0 Ga orogens of eastern Australia. On the other and 1150 1200 Ma in Huiznopala (Lawlor et al.,
hand, other authors have proposed that Oaxaquia is 1999) and 1231 F 43 Ma (upper intercept) in the
an exotic terrane of either Amazonian or northeastern Guichicovi Complex (Weber and Kohler, 1999).
Laurentian provenance (Keppie, 1977; Ballard et al., Granulite facies metamorphism was also dated by
1989; Yanez et al., 1991; Keppie and Ortega-Gutier- U Pb at f 1000 Ma in Huiznopala (Lawlor et al.,
rez, 1995, 1999; Ortega-Gutierrez et al., 1999). The 1999), at f 986 Ma (Ruz et al., 1999) and 975 F 36
presence of Ordovician and Silurian fauna with Ma (Weber and Kohler, 1999) in the Guichicovi
Gondwanan affinity in rocks unconformably above Complex, and is poorly constrained between 928 F
the 1 Ga rocks in Mexico (Robinson and Pantoja- 18 Ma (K Ar on phlogopite, Denison et al., 1971)
Alor, 1968; Boucot et al., 1997) is consistent with an and 1018 F 3 Ma (U Pb on concordant zircon, Silver
Amazonian location during the lower Paleozoic. As et al., 1994) in the Novillo Gneiss.
no Neoproterozoic tectonic event has been recorded Available major, trace and REE geochemistry, as
in Oaxaquia, it is probably fair to assume that this well as Nd and common Pb isotopic data suggest that
same location also applies to its f 1 Ga position. these f 1.0 1.2 Ga igneous protoliths constitute a
Ruz et al. (1999) divided Oaxaquia into two pieces magmatic arc intruded by two series of intraplate and
along the Trans-Mexican Volcanic Belt (Fig. 1A), AMCG (anorthosite mangerite charnockite gran-
and suggested that the northern piece was continuous ite) suites (Patchett and Ruz, 1987; Ruz et al.,
with southern Laurentia, and the southern one was 1988, 1999; Lawlor et al., 1999; Weber and Kohler,
derived from Gondwana. In this paper, we document 1999; Lopez et al., 2001; Keppie et al., 2001a,b). The
that the northern Oaxacan Complex has undergone a absence of a Paleoproterozoic or Archean rocks
complex structural and metamorphic history that beneath Oaxaquia is suggested by the fact that no
involved two high-grade tectonothermal events at U Pb upper intercept ages older than f 1400 Ma
f 1100 and f 990 Ma (named Olmecan and Zapo- have been recorded and Nd model ages range
tecan, respectively). These are tentatively interpreted between f 1.3 and f 1.6 Ga (Patchett and Ruz,
as extensional and either Andean, arc continent or 1987; Lawlor et al., 1999).
L.A. Solari et al. / Tectonophysics 365 (2003) 257282
Fig. 1. (A) Oaxaquia and the main outcrops of Grenvillian-age rocks in Mexico. The box shows the location of the area studied in this work; TMVB is the Trans-Mexican Volcanic
Belt. P M fault is the Polochic Motagua system, SE of which crops out the Chortis block. (B) Geological map of the studied area, northern Oaxacan Complex. (C) Reconstructed

259
structural column for the studied area. Both figures contain U Pb and Ar Ar sample locations.
260 L.A. Solari et al. / Tectonophysics 365 (2003) 257282

3. Lithologies of structural units The anorthosite gabbro Fe metadiorite is in tec-


tonic contact with the overlying dark green, weakly
Mapping of the northern Oaxacan Complex reveals foliated mafic gneiss and garnet-bearing charnockite.
that it consists of a series of thrust slices composed of The tectonic contact is characterized by a 15-m-thick
(from bottom to top) (Fig. 1B,C): (1) the Huitzo greenschist to lower amphibolite shear zone (Fig.
structural unit; (2) the El Catrn migmatite structural 1B,C) with top-to-the-SE kinematics (Solari, 2001).
unit; and (3) the El Marquez structural unit. The mafic gneisses are composed of plagioclase (An
The Huitzo structural unit is made up of a f 3-km- 25%), hypersthene, augite, hornblende, magnetite,
thick AMCG suite consisting of meta-anorthosite and garnet, zircon and minor amount of alkalic feldspar
intercalated Fe-metadiorite, metagabbro, mafic cumu- and quartz, which indicate that they also underwent
lates and garnet-bearing charnockite with protolith granulite facies metamorphism. One of the studied
ages of 1012 F 12 Ma (Keppie et al., 2003). The Fe- samples belonging to this unit contains magmatic
metadiorites and anorthosites are intimately inter- pigeonite, with hypersthene exolutions. The chemistry
leaved as a result of intense deformation that reor- of these mafic gneisses suggests that they represent
iented primary, magmatic contacts parallel to the cumulates (Keppie et al., 2003). A 200-m-thick slice
foliation. The Fe-metadiorites are dark grey in colour, of pale gray, foliated charnockite is intercalated with
and vary from massive to intensely lineated in shear these gneisses. Its contacts are parallel to the banding,
zones. Granulite facies metamorphism is indicated by and do not show any shearing. The charnockite is
mineralogy composed of plagioclase (An 30 45%), composed of perthitic feldspar, quartz, augite, hyper-
orthopyroxene, augitic clinopyroxene, brown horn- sthene, garnet, plagioclase (An 30%) and accessory
blende, rare titaniferous biotite, magnetite and ilmen- apatite and zircon, an assemblage indicative of gran-
ite, with abundant accessory apatite, and granoblastic ulite facies metamorphism.
textures, with the typical triple junctions at 120j in the The El Catrn Migmatite structural unit comprises
more massive units. Clinopyroxene is replaced by migmatitic gneisses (about 2-km thick) that lie struc-
amphibole ranging from tremolite actinolite to antho- turally above the charnockites and the mafic gneisses.
phyllite pseudomorphs, whereas magnetite and ilmen- Field relationships show that the mafic gneisses and
ite are often surrounded by coronas of garnet, which anorthosites of the Huitzo structural unit intruded these
are typical of isobaric cooling conditions (Harley, migmatites (Solari, 2001, p.26). Migmatite in the type
1989). Low-grade, late coronas of actinolite, biotite locality is represented by a stromatic to nebulitic, light
and/or epidote indicate hydration and retrograde meta- grey leucosome in a dark gray to bluish mesosome.
morphism under upper greenschist to amphibolite The leucosome consists of quartz, alkali feldspar,
facies. The metagabbros are dark green to black, and plagioclase (An 20 45%), secondary epidote, calcite
composed of augite, plagioclase, brown to green and chloritized biotite. The mesosome, in addition to
hornblende, rare biotite and relict hypersthene. Pres- those minerals characterizing the leucosome, contains
ence of this last mineral, together with textural augitic clinopyroxene, hypersthene, rare hornblende
relationships between hornblende, biotite and clino- and, in few samples, scapolite. This mineral assem-
pyroxene, suggest these metagabbros also underwent blage was produced by granulite facies metamor-
granulite metamorphism. The anorthosite is white phism, whereas secondary minerals were produced
and massive in the middle of the pluton, becoming by retrograde metamorphism. The mesosome, leuco-
more foliated towards its margins. It is made up of some and the migmatitic fabric are only preserved in
plagioclase (An 20 30%), magnetite and ilme- the middle of a low-strain window. Outside this, the
nite F K-feldspar and quartz, and secondary calcite migmatitic gneisses grade into striped gneiss, in which
and epidote. Nelsonites in the anorthosites are com- subsequent deformation is stronger and generally
posed of apatite, ilmenite and minor amounts of associated with a granulite metamorphic foliation
magnetite. In the Adirondack Highlands of the defined by augite and hypersthene. Although geo-
Laurentian Grenville Province, the nelsonites are chemical data are not available, the petrography sug-
considered to be immiscible liquids, comagmatic gests that the protolith of the migmatite was gabbroic
with the anorthosites (Darling and Florence, 1995). dioritic in composition.
L.A. Solari et al. / Tectonophysics 365 (2003) 257282 261

Intercalated paragneiss and orthogneiss of the El zircon analyses carried on metasyenite, charnockite
Marquez structural unit immediately overlie the mig- and metagabbros indicate their crystallization ages
matite (Fig. 1B,C). The contact between the two is range between f 1134 and f 1230 Ma (Keppie et
characterized by a 150-m-thick biotite- and musco- al., 2003).
vite-bearing paragneiss, mylonitized under greenschist
facies, with a top-to-the-E sense of shear (Solari,
2001). The paragneisses are represented by a variety 4. Structures and age constraints
of lithologies ranging from quartz feldspar garnet
(pyrope-almandine) gneiss, through two pyroxene The tectonic history of the three main structural
quartz feldspar gneiss, and mica graphite silliman- units of the northern Oaxacan Complex is as follows:
ite rutile gneiss to marbles and calcsilicates. Textures (i) in the f 1012 Ma Huitzo unit, two sets of structures
are generally granoblastic. The impure marbles are developed under granulite facies metamorphic condi-
generally composed of calcite with abundant acces- tions; (ii) in the El Catrn unit, two sets of structures
sory minerals such as diopside, olivine, purple fas- associated with migmatization are preserved in a strain
saite, graphite, quartz, wollastonite and phlogopite. window, and these are overprinted by two sets of struc-
The calcsilicates are composed of scapolite, micro- tures formed under granulite and amphibolite facies
cline, diopside, titanite, graphite, phlogopite and ac- metamorphic conditions, respectively; and (iii) the
cessory calcite. Although some of these marbles and z 1134 Ma El Marquez unit records four sets of
calcsilicates are foliated and concordant with the structures, the first three of which are associated with
regional banding, others cut across the structures granulite facies minerals, whereas the last set devel-
and are massive. Pinnitized cordierite and sapphirine oped under amphibolite facies conditions. On the basis
rarely occur in the northern OC paragneisses. These of age constraints (see below), the granulite upper
different parageneses and the textures indicate that the amphibolite facies structures affecting the Huitzo unit
paragneisses also underwent granulite facies meta- and their correlatives in the other units are assigned to
morphism. Based upon the abundance of sulphur- the Zapotecan tectonothermal event dated at f 978
and chlorine-rich scapolite, alkali feldspar F gypsum 1004 F 3 Ma, whereas the structures associated with
and anhydrite within this structural unit, Ortega- migmatization in the El Catrn unit are assigned to the
Gutierrez (1984) proposed that the calcsilicates were Olmecan tectonothermal event, dated at F 1100 Ma.
originally evaporites interbedded with carbonates, These names are derived from the pre-Hispanic cul-
arkoses, felsic igneous rocks (now quartzo-feldspathic tures that inhabited the Oaxacan region. Structures
gneiss), marls, alkali basalt/dolerite (now amphibolite) associated with these two tectonothermal events are
and magnesian clays (now ultramafic rocks). He overprinted by other structures developed at lower
inferred that this association was deposited in a amphibolite subgreenschist facies metamorphic con-
continental rift environment. Minor igneous bodies ditions, such as thrusts, shear zones, and upright, NW-
such as amphibolites and pegmatites, as well as major trending open folds, which are Phanerozoic in age
charnockitic, meta-syenitic and meta gabbroic bands, (Solari, 2001). This paper is limited to the Zapotecan
up to 500-m thick, intrude these paragneisses. The and Olmecan events, which are designated by Z and u
charnockites are characterized by quartz, perthitic subscripts, respectively, to constrain planar (S), and
feldspar, plagioclase (An 35%), hypersthene, augite linear (L) structures, and folds (F). In each structural
and hornblende. Metasyenite is mainly composed of unit, these events are further distinguished by the
abundant meso-perthitic feldspar, quartz, hornblende, subscripts h (Huitzo structural unit), c (El Catrn
biotite, clinopyroxene and relict hypersthene, whereas structural unit), or m (El Marquez structural unit). A
meta-gabbros are composed of augite, plagioclase, justification for the correlation between the structures
hornblende and magnetite. Zircon, Fe Ti ore and observed in each of these three structural unit and their
apatite are particularly abundant accessory minerals. assignment to Olmecan or Zapotecan will be proposed
Their parageneses indicate that these rocks were in the Summary section, but rather than introduce two
affected by granulite facies metamorphism that over- numbering schemes, the conclusions are used through-
printed the original, magmatic fabric. Previous U Pb out the paper.
262
Table 1
U Pb geochronology for the selected samples, northern Oaxacan Complex, southern Mexico
Fraction Weight U Total Pb Com. 206 206 206 207 207 207 207 206 207 207 Disc.
Pb/204Pb Pba/238U Pba/238U Pba/235U Pba/235U Pba/206Pba Pba/206Pba Pba/238U Pba/235U Pba/206Pba
(mg) (ppm) (ppm) Pb (pg) (%)
(% err.) (% err.) (% err.)
Raw datab Atomic ratiosc Age (Ma)d

El Catrn migmatite, neosome, sample 67B98


(1) sng, elong, abr 0.015 78 18 22 695 0.19890 0.25 2.1821 0.32 0.07956 0.19 1169 1175 1186 F 4 1.4
(2) sng, rnd, abr 0.029 67 12 9 2473 0.17978 0.14 1.8613 0.19 0.07509 0.13 1066 1067 1071 F 3 0.5
(3) eq, abr, 11 grn 0.125 67 12 8 11,602 0.18524 0.09 1.9586 0.10 0.07668 0.04 1096 1101 1113 F 1 1.6
(4) 2 grns, irg 0.012 91 16 10 11,539 0.17607 0.10 1.8084 0.11 0.07449 0.05 1045 1048 1055 F 1 0.9
(5) eq, abr, sng 0.052 68 14 18 475 0.18387 0.24 1.9276 0.31 0.07603 0.20 1088 1091 1096 F 4 0.7
(6) pnk, sng, abr, cir 0.015 527 112 31 3135 0.19536 0.25 2.1265 0.26 0.07895 0.06 1150 1157 1171 F 2 1.8
(7) abr, sng, tip 0.020 26 5 4 1507 0.18726 0.58 1.9733 0.65 0.07643 0.28 1107 1106 1106 F 6 0.0
(8) CL, plkd, abr, sng 0.040 84 18 25 1663 0.19438 0.39 2.1044 0.42 0.07852 0.15 1145 1150 1160 F 3 1.3
(9) sng, pnk, abr, eq 0.010 262 57 21 1511 0.19633 0.19 2.1541 0.42 0.07957 0.35 1156 1166 1187 F 7 2.6

El Catrn migmatite, paleosome, sample 67A98


(10) sng, prsm, fr 0.009 688 154 31 2784 0.21850 0.25 2.5355 0.28 0.08416 0.12 1274 1282 1296 F 2 1.7
(11) 4 grns, elong, pnk, crk 0.013 524 120 22 4278 0.21689 0.51 2.5059 0.54 0.08380 0.18 1265 1274 1288 F 4 1.8
(12) lbc, abr, sng 0.013 650 138 21 5300 0.21050 0.10 2.3793 0.11 0.08198 0.04 1231 1236 1245 F 1 1.1
(13) eq, rnd, abr, sng 0.008 178 52 20 556 0.18044 0.60 1.9009 0.69 0.07640 0.34 1069 1081 1106 F 7 3.3
(14) eq, rnd, abr, sng 0.007 745 156 8 9108 0.21084 0.13 2.4214 0.13 0.08329 0.04 1233 1249 1276 F 1 3.3
(15) irg, abr, sng 0.008 818 179 10 9107 0.21567 0.09 2.4859 0.10 0.08360 0.04 1259 1268 1283 F 1 1.9
(16) irg, abr, 2 grn 0.008 649 139 8 8440 0.20859 0.09 2.3659 0.10 0.08226 0.04 1221 1232 1252 F 1 2.5

Folded pegmatite El Cuajilote, sample 6898


(17) elong, abr, sng 0.052 41 8 9 2097 0.18846 0.35 2.0025 0.38 0.07706 0.15 1113 1116 1123 F 3 0.9
(18) elong, abr, 5 grn 0.060 45 9 3 5546 0.18468 0.28 1.9584 0.31 0.07691 0.14 1092 1101 1119 F 3 2.4

Semipelitic metasediment, sample 7098


(19) eq, abr, sng 0.021 683 111 21 6611 0.16672 0.39 1.6613 0.41 0.07227 0.12 994 994 994 F 3 0.0
(20) abr, sph, multif, 2 grn 0.014 220 39 9 3859 0.18016 0.20 1.8807 0.25 0.07571 0.16 1068 1074 1087 F 3 1.8
(21) abr, sph, multif, sng 0.010 283 51 14 2364 0.18392 0.34 1.9460 0.40 0.07674 0.21 1088 1097 1114 F 4 2.3

Pre-tectonic pegmatite, sample 66B98


(22) abr, lbc, sng 0.047 96 20 38 1416 0.19083 0.11 2.0287 0.14 0.07710 0.08 1126 1125 1124 F 2 0.2
(23) abr, fr, 3 grn 0.071 92 19 11 7155 0.19425 0.16 2.0857 0.18 0.07787 0.07 1144 1144 1144 F 2 0.0
(24) abr, fr, 2 grn 0.051 106 22 11 6451 0.19582 0.34 2.1069 0.37 0.07804 0.14 1153 1151 1148 F 3 0.4
(25) abr, lbc, sng 0.035 147 31 11 18,544 0.19183 0.07 2.0566 0.08 0.07776 0.04 1131 1134 1141 F 2 0.9
(26) abr,sng, rnd to prsm 0.158 124 24 101 2143 0.17928 0.15 1.8582 0.16 0.07517 0.05 1063 1066 1073 F 2 0.9
L.A. Solari et al. / Tectonophysics 365 (2003) 257282

(27) abr, fr, sng 0.031 71 14 16 1654 0.18484 0.39 1.9535 0.43 0.07665 0.19 1093 1100 1112 F 4 1.7

Flattened axial planar pegmatite, sample 66C98


(28) lbc, flat, abr, mg 0.025 724 122 11 14,104 0.16213 0.21 1.6000 0.22 0.07157 0.07 969 970 974 F 2 0.6
(29) lbc, mg 0.112 563 96 25 15,261 0.16258 0.18 1.6065 0.19 0.07167 0.06 971 973 977 F 2 0.6
(30) stby, srp.edges, clear, 7 grn 0.086 450 81 100 2949 0.16370 0.19 1.6188 0.25 0.07172 0.16 977 978 978 F 3 0.1
(31) lbc, abr, mg 0.124 406 75 32 8535 0.16416 0.18 1.6278 0.21 0.07192 0.09 980 981 984 F 2 0.4
(32) stby, srp.edges, abr, mg 0.028 912 149 55 4566 0.15984 0.13 1.5750 0.14 0.07147 0.04 956 960 971 F 2 1.6

Late tectonic pegmatite, sample 66D98


(33) abr, sng, stubby to rnd 0.082 288 50 19 12,196 0.16339 0.17 1.6145 0.17 0.07167 0.04 976 976 976 F 1 0.0
(34) abr, sng, stubby to rnd 0.045 937 168 22 19,279 0.16263 0.18 1.6081 0.19 0.07171 0.05 971 973 978 F 1 0.7
(35) abr, sng, elg 0.032 498 88 29 5530 0.16349 0.60 1.6164 0.62 0.07171 0.16 976 977 978 F 3 0.2
(36) abr, sng, elg 0.032 365 65 37 3202 0.16403 0.25 1.6222 0.26 0.07173 0.07 979 979 978 F 2 0.1

El Tecolote pegmatite, sample 6998


(37) fr, abr 0.188 123 20 23 9933 0.16241 0.20 1.6032 0.23 0.07159 0.12 970 971 975 F 1 0.5
(38) fr, abr 0.019 159 28 4 14,039 0.16434 0.44 1.6256 0.44 0.07174 0.04 980 980 979 F 3 0.1
L.A. Solari et al. / Tectonophysics 365 (2003) 257282 263

Table 2
40
Ar 39Ar geochronology for sample OC 9901, northern Oaxacan Complex, southern Mexico
39
Analysis Ar/40Ar 36
Ar/40Ar 38
Ar/40Ar 37
Ar/40Ar K/Ca K/Cl Ca/Cl %40Ar* Agesa
(  10 2) (  10 5) (  10 4)
1 1.48 F 0.0093 2.00 F 1.06 2.31 F 0.0630 0.0401 F 0.0003 0.192 6.8 35.5 99.4 1021.9 F 6.4
2 1.56 F 0.0094 1.60 F 0.984 2.06 F 0.0672 0.0403 F 0.0002 0.201 8.1 40 99.5 981.3 F 5.9
3 1.60 F 0.0110 2.00 F 0.776 2.12 F 0.0605 0.0402 F 0.0003 0.208 8.1 38.8 99.4 959.3 F 6.6 Mean Age:
977 F 12 Ma
4 1.64 F 0.0136 1.07 F 30.47 2.89 F 0.204 0.0429 F 0.0003 0.199 6 30.4 100.3 948.2 F 7.8
5 1.58 F 0.0137 0.35 F 0.367 2.38 F 0.0588 0.0410 F 0.0003 0.201 7.1 35.2 99.9 973.2 F 8.5 Regression:
987 F 6
6 1.53 F 0.0117 1.54 F 0.775 2.20 F 0.0508 0.0403 F 0.0002 0.198 7.4 37.5 99.5 995.4 F 7.6 Initial 40/36:
36 F 28
7 1.55 F 0.0123 2.82 F 1.22 2.25 F 0.0715 0.0407 F 0.0003 0.198 7.3 36.9 99.2 982 F 7.8
8 1.56 F 0.0176 0.82 F 7.44 2.97 F 0.138 0.0413 F 0.0003 0.196 5.6 28.4 100.2 987.1 F 11.2
9 1.63 F 0.0172 1.91 F 1.67 2.54 F 0.0970 0.0400 F 0.0005 0.212 6.8 32.2 99.4 946.2 F 10
10 1.56 F 0.0158 1.65 F 0.952 2.32 F 0.0561 0.0407 F 0.0003 0.2 7.2 36 99.5 978.4 F 9.9
Mean age calculated with all data (n = 10), as the mean of air-corrected data, with error expressed as the standard error of the mean.
Regression result is based on the methods of York (1969).
All uncertainties are 2r. The uncertainty in the statistical ages include uncertainties arising from the J-value (0.01132 F 0.00006), which
corresponds to an additional 0.5%.
%40Ar*: percentage of radiogenic 40Ar from total 40Ar.
a
Ages are calculated for each analysis on the basis of analytical precision only.

Several samples were collected for zircon U Pb isotopic analysis (Fig. 1b,c). Zircon separation,
isotopic analysis to bracket the age of the observed chemistry and mass spectrometry were performed at
tectonothermal events: two samples of migmatite University of California, Santa Cruz (UCSC) follow-
(67A98 paleosome and 67B98 neosome) of the El ing the analytical procedures described in Lopez et
Catrn unit, three pegmatites from one locality in the al. (2001). Isotopic ratios were reduced, and the
El Marquez unit (66B98, 66C98, 66D98 that are errors assessed, using the program PbDat (Ludwig,
early, middle and late with respect to the local 1991) (Table 1) and the concordia diagrams plotted
fabrics), a pegmatite in the El Catrn unit that is using Isoplot for Excel v. 2.49 (Ludwig, 2001). The
40
folded and sheared together with its host rock (6898), Ar/39Ar laser fusion analyses of hand-picked horn-
a late-tectonic, high-grade pegmatite as well as a blende crystals (Table 2) were performed at the
metasediment (7098), both belonging to El Marquez Massachusetts Institute of Technology using the
unit (6998), and finally a hornblende-bearing meta- methodology outlined in Hames and Bowring
gabbro (OC9901) in the Huitzo unit for 40Ar/39Ar (1994).

Notes to Table 1:
abr = abraded; grn = grains; rnd = round; sng = single; prsm = prismatic; cir = circular; pnk = pink; fr = fragment; crk = with cracks; irg = irregular
elg = elongate; sph = spherical; multif = multifaceted; brk xls = broken crystals; CL = imaged by cathodoluminescence; plkd = plucked off from
the CL mount; mg = multigrain; eq = equant.
a
Denotes radiogenic Pb. Zircon sample dissolution and ion exchange chemistry modified after Krogh (1973) and Mattinson (1987) in
Parrish (1987)-type microcapsules.
b
Observed isotopic ratios are corrected for mass fractionation of 1x for both 208Pb and 205Pb spiked fractions. Fractions spiked with the
mixed 235U/205Pb tracer are also corrected for spike and blank relative contributions. Uncertainties in the 206Pb/204Pb ratio vary from 0.1% to
2.4%.
c
Decay constants used: 238U=1.5512510 10; 235U=9.4848510 10; 238U/235U=137.88. Estimated uncertainties of the U/Pb ratio are
F0.4 based on replicate analyses of a single zircon standard fraction (see Lopez et al., 2001).
d 207
Pb*/206Pb* age uncertainties are 2r and from the data reduction program PBDAT of K. Ludwig (1991). Total processing Pb blank
amount varied between 2 and 30 pg, generally averaging <10 pg. Initial Pb composition are from isotopic analysis of feldspar separates or from
the two-stage Pb evolution curve of Stacey and Kramers (1975). Isotopic data were measured on a VG 54-30 sector multicollector mass
spectrometer with a pulse counting Daly detector at UC Santa Cruz.
264 L.A. Solari et al. / Tectonophysics 365 (2003) 257282

4.1. Analysis of Zapotecan structures in the Huitzo banding defined by thin ilmenite and apatite bands
unit (magmatic bands, S0, and Z1h) may be observed, and was probably produced by
liquid immiscibility and is therefore magmatic in
4.1.1. S0 and Z1h origin. This S0 banding is deformed by close to
The anorthosite of the Huitzo unit is weakly isoclinal, FZ1h intrafolial folds that plunge gently to
foliated-massive in the middle of the body where a moderately towards NW (Fig. 2). They are generally

Fig. 2. Stereoplots obtained for foliations, mineral and stretching lineations and fold axes in the studied area, divided for each structural unit
discussed in the text.
L.A. Solari et al. / Tectonophysics 365 (2003) 257282 265

less than 20 cm in amplitude and plot in the Class 3 oped axial plane foliation defined by rare ortho- and
field, close to Class 2 (Fig. 3a), which suggests they clinopyroxenes, as well as hornblende is parallel to
formed by a buckling mechanism, possibly a combi- the FZ1h axial planes in the FZ1h hinges. In the
nation of flexural and tangential longitudinal strain margins of the body, the S0 banding is transposed
that was accompanied by flattening. A poorly devel- into the SZ1h foliation represented by dimensionally

Fig. 3. (a d) tVvs. a diagrams for studied folds associated with different phases of deformation, according to Ramsay (1967). tVis defined as the
ratio between the value ta (thickness between the tangents to two folded surfaces at an angle a p 0), and t0 (thickness between the tangents to
two folded surfaces at the angle a = 0, generally in the hinge zone). a is the angle of dip of the tangents. See Ramsay (1967, p. 358 372), for
further explanations on the dip-isogons classification of folds.
266 L.A. Solari et al. / Tectonophysics 365 (2003) 257282

oriented orthopyroxene, clinopyroxene (augite), preserved, which are progressively transformed in


brown hornblende F titaniferous biotite, in the mafic granulite facies, striped gneisses toward the mar-
gneiss and metagabbro. Orthopyroxene constitutes a gins. Subsequent intense reequilibration under green-
relict phase, surrounded by brown hornblende coro- schist facies conditions affected the entire migmatitic
nas. The gently to moderately NW plunging LZ1h unit. The first recognizable structure in the El Catrn
lineation is defined by oriented hornblende that is unit is represented by the stromatic to nebulitic,
generally parallel to the long axes of quartz ribbons, centimetric banding of mesosome and leucosome,
which have aspect ratios of up to 15:1. This mineral Su1c (Fig. 4a,b). We interpret the thin Su1c banding
association orthopyroxene clinopyroxene brown as the product of metamorphic differentiation and
hornblende indicates that these fabrics formed under migmatization that overprinted an original, banded
granulite facies conditions. Some of the gabbros show magmatic feature. The gently NNW plunging nor-
retrogression at upper amphibolite conditions. Alman- mal to the great circle distribution of the Su1c
dine garnet, when present, shows poikilitic textures foliation poles in the stereonet of Fig. 2 is coinci-
and is in textural equilibrium with both pyroxenes and dent with the axes of Fu2c folds and Phanerozoic
hornblende. SZ1h poles are distributed along a great fold axes.
circle whose gently NNW-plunging pole is approxi-
mately parallel to both the FZ1h fold axes, the NW 4.2.2. h2c
plunging LZ1h lineations and the Phanerozoic fold axes The Su1c banding in El Catrn unit is deformed by
(Fig. 2). isoclinal, ghostly looking, gently moderately N-dip-
ping folds (Fu2c) (Fig. 4a,b). These < 15-cm-ampli-
4.1.2. Age constraints on the Zapotecan structures in tude folds have gently N plunging hinges that are
the Huitzo unit parallel to a lineation (stereonet in Fig. 2), which is
Ten 40Ar/39Ar laser fusion analyses were per- constituted by moderately NNW-plunging stretched
formed on hornblende separated from a 100-m-thick quartz ribbons with elongation of up to 8:1. This
gabbro (sample OC9901) interleaved with the anor- lineation probably reflects composite finite strain
thosites within the Huitzo unit (Fig. 1b,c). The horn- accumulated during the Olmecan deformation and
blende is in stable contact with augite, plagioclase and the Z1c event.
biotite. The analyses are characterized by very high
radiogenic yields (about 99.5% or higher) and there is 4.2.3. Z1c
no evidence of extraneous, nonatmospheric argon. FZ1c folds deform both Su1c migmatitic banding
Regression of all the data yields an age of 987 F 6 and Fu2c folds (Fig. 4a). FZ1c folds are up to 20 cm in
Ma, whereas air-corrected data give a mean age of size, open to close, gently to moderately N NNE
977 F 12 Ma (Table 2). The latter is viewed as plunging, with moderately to gently NE-dipping axial
preferable because there is no clear evidence of an planes (Fig. 2). Clinopyroxene and orthopyroxene
extraneous argon component. This age is interpreted crystals in the limbs of these folds are aligned
to date cooling through the argon blocking of f 500 parallel to the FZ1c axial plane, indicating that they
jC temperature in hornblende (Harrison, 1981), and formed under granulite facies conditions but no axial
provides a younger limit on the granulite facies meta- plane foliation was observed in the hinges of these
morphism. folds.

4.2. Analysis of Olmecan (h1c and h2c) and Zapo- 4.2.4. Z2c
tecan (Z1c and Z2c) structures in the El Catrn unit A SZ2c foliation, which is oblique to the migma-
titic banding (Su1c) and to the FZ1c axial trace, is
4.2.1. h1c microscopically defined by green hornblende that
The oldest structures in the El Catrn unit were coexists with quartz and plagioclase (Fig. 4b). It is
only discerned in a strain window (about 500-m parallel to the axial planes of V 40-cm amplitude,
wide) located at the type locality along the Federal gently W-plunging, gently NW-dipping, open to iso-
Road 190 (Fig. 1b). Here, migmatitic structures are clinal, FZ2c folds (Fig. 4b and stereonet of Fig. 2).
L.A. Solari et al. / Tectonophysics 365 (2003) 257282 267

Fig. 4. (a) Picture illustrating the classic aspect of El Catrn migmatite in the type locality. Two phases of high-grade folding, marked by long
(Fu2c) and short (FZ1c) white arrows, affect the Su1c migmatitic banding. (b) Z-shaped, close to recumbent, amphibolite facies FZ2c fold in El
Catrn migmatite. White lines underline the SZ2c foliation in the outcrop.

The presence of axial planar green hornblende, not 4.2.5. Age constraints on structures in the El Catrn
associated with pyroxenes, suggests that FZ2c folds unit
formed under amphibolite facies metamorphic con- A total of 16 analyses were performed by U Pb
ditions. geochronology, seven on single or few zircon grains
268 L.A. Solari et al. / Tectonophysics 365 (2003) 257282

separated from the paleosome (67A98), and nine from cepts at 1116 + 50/ 27 and 937 F 100 Ma. The upper
the neosome (67B98) (Table 1). All but one yielded intercepts in (i) and (ii) of 1358 F 43 and 1399 F 58
slightly discordant results, a reflection of the internal Ma, respectively, are inferred to provide a minimum
complexity of these zircons (Fig. 5, images a, b and age for the protolith. On the other hand, the lower
c). The only concordant point yielded an age of intercepts in (i) and (iii) of 1048 F 31 and 937 F 100
1106 F 6 Ma (analysis 7 in Table 1), and was obtained Ma, respectively, may provide a rough estimate of the
from a single, abraded tip broken off from a prismatic, age of the granulite metamorphism in the El Catrn
euhedral zircon from the neosome. Its internal cath- unit.
odoluminescence image (image d in Fig. 5) shows a In the upper part of the El Catrn unit, a pegmatite
thin, oscillatory zoning, which suggests magmatic (6898) folded by a FZ1c fold (Fig. 1b) is composed of
growth. We interpret this concordant age of 1106 F 6 quartz, plagioclase (An 20%) and alkalic feldspar, with
Ma as the best estimate of the time of migmatization. A accessory zircon, apatite and secondary epidote and
high luminescent overgrowth (possibly metamorphic chlorite. Zircons separated from this pegmatite are
in origin) was removed by abrasion, performed after elongated, clear, light pink coloured. Cathodolumines-
the zircon was plucked off from the CL mount. Several cence images reveal internal homogeneity and thin,
chords may be drawn: (i) through all the data, yielding low luminescent overgrowths in the elongate zircons
intercepts of 1358 F 43 and 1048 F 31 Ma, with an (image e in Fig. 5), and thin, oscillatory zoning in the
MSWD of 10.6; (ii) through the concordant point at stubby to elongate zircons, which suggests magmatic
1106 Ma and the older data, yielding intercepts of crystallization. A chord through two slightly discordant
1399 F 58 and 1092 F 38 Ma, with an MSWD of 7.3 analyses (Table 1) yields an upper intercept at 1126 +
(shown in Fig. 6a); and (iii) through the concordant 11/ 6 Ma (Fig. 6b), which is tentatively interpreted as
point at 1106 Ma and the younger data, yielding inter- a minimum crystallization age for this pegmatite.

Fig. 5. Cathodoluminescence images for some of the dated zircons. The white bar close to each image represents 100-Am scale. (a d) Zircons
from the El Catrn migmatite 6798; (e g) zircons from the pegmatite 6898; (h) zircon from the pegmatite 66D98.
L.A. Solari et al. / Tectonophysics 365 (2003) 257282 269

Fig. 6. U Pb concordia plots. (a) El Catrn migmatite, 67A98 and 67B98; (b) El Cuajilote folded pegmatite, 6898; (c) semipelitic metasediment,
7098; (d) pre-tectonic pegmatite, 66B98; (e) flattened, axial planar pegmatite, 66C98; (f) Late tectonic pegmatite, 66D98; (g) El Tecolote
pegmatite, 6998. Errors are quoted at F 2r.
270 L.A. Solari et al. / Tectonophysics 365 (2003) 257282

4.3. Analysis of Olmecan (h1m and h2m) and longitudinal strain mechanisms, with superposed flat-
Zapotecan (Z1m and Z2m) structures in the El tening. There is no a well-developed axial plane
Marquez unit foliation and pyroxene and hornblende are stable in
the fold hinges.
4.3.1. h1m
The V 5 mm Su1m banding consists of alternating 4.3.3. Z1m
leucocratic and mafic horizons that could have formed Gently NNW plunging, gently N dipping, FZ1m
by metamorphic differentiation that may, or may not, close folds up to V 10 m are common in paragneisses
have enhanced an original fabric in the rocks. In the (stereonet in Fig. 2). They range from Class 1C to 3,
orthogneisses, the leucocratic bands are made up of close to Class 2 (Fig. 3c). This can be interpreted as a
various proportions of quartz, plagioclase, potassic combination of flexural and tangential longitudinal
feldspar and, sometimes, almandine garnet. The mafic strain mechanism, affected by flattening perpendicular
horizons are composed of orthopyroxene, clinopyrox- to the axial plane. At one location, a gently folded
ene, hornblende, biotite, plagioclase and opaque min- pegmatite cuts across both limbs of a nearly isoclinal
erals. In the paragneisses, the leucocratic bands also fold and allows the strain to be partitioned into pre-
contain sillimanite, rutile and graphite. The foliation, and post-intrusion components (Fig. 7). The pegma-
Su1m, is defined by planar distribution of aligned tite contains flattened discs of quartz, whereas the host
hornblende and/or titaniferous biotite, and stretched gneisses contain high-stretched quartz. The flattening
quartz, whereas in the meta-syenite and charnockite, it component can be estimated using the methods pro-
is defined by aligned orthopyroxene, clinopyroxene posed by Lisle (1992) or Weger (1993). An oriented
and hornblende aggregates, which are parallel to sample of this pegmatite was cut perpendicular to the
stretched quartz ribbons. Only one mineral lineation fold axis, polished to expose the SZ1m surface, then
was observed in the foliation and because the rocks photographed and finally restored to allow the flat-
have been deformed several times at high grade tened quartz to recover a quasi-equidimensional shape.
during the Olmecan and Zapotecan events, it is Both methods give a two-dimensional ratio of 1:3.3,
inferred that the lineation is the finite result of several which corresponds to the strain component due to
increments of strain. This composite, NW to N flattening superimposed on FZ1m folding. Quartz
plunging Lu1 2m Z1m mineral lineation in the orthog- plagioclase garnet F orthopyroxene association
neisses is defined by the long axes of pyroxene, mica observed along the axial plane of one of these folds,
and hornblende, and in the paragneisses by mica and as well as the paragenesis garnet sillimanite rutile
orthopyroxene is parallel to a stretched quartz line- quartz, suggest FZ1m folds formed under granulite
ation. The Su1m foliation poles are generally distrib- facies metamorphism.
uted along a great circle, whose axis is parallel to the
Fu2m isoclinal folds axes, the FZ1m fold axes and 4.3.4. Z2m
Phanerozoic fold axes (Fig. 2). These structures consist of gently N-plunging,
steeply inclined FZ2m folds (Fig. 2). They show a
4.3.2. h2m well-developed axial plane foliation in the hinge zone
The Su1m foliation and banding is deformed by defined by hornblende crystals that crosscut the Su1m
close to isoclinal, gently to moderately NNW to N banding (Fig. 8a). The outer arc of one of these folds
plunging, gently NNW dipping, S and Z asymmetric is intruded along its axial plane by a pegmatite
folds (Fig. 2). The folds are common in paragneisses, (sample 66C98) that displays flattened quartz in the
and only a few were observed in the orthogneisses. margins, whereas its centre is not foliated (Fig. 9b).
Rootless fold hinges in quartz-feldspar veins were The shape of the outer arc of the fold changes from
also observed in mica-rich bands. The Fu2m folds are Class 1A to 1C with the increasing of curvature,
Class 1B 1C in the charnockites, 1C in mafic whereas the inner arc of this fold is Class 3 close to
horizons and 1C close to 2 in metasediments (exam- 2 (Fig. 3d). These data suggest a tangential longitu-
ples in Fig. 3b). These data may be interpreted in dinal strain mechanism, where the outer arc of the fold
terms of a combination of flexural and tangential hinge was stretched parallel to the banding facilitating
L.A. Solari et al. / Tectonophysics 365 (2003) 257282 271

Fig. 7. Granulite facies, mesoscale recumbent FZ1m fold, which limbs are cut across by a 15-cm-thick pegmatite, unfolded but affected by
flattening perpendicular to the fold axis. The estimated flattening corresponds to an S1/S2 ratio of f 3.3:1. White lines in the detail (b) marks
the axial plane foliation in both pegmatite and folded host rock. Scale in picture (b) is 5-cm large. See text for further explanations.
272 L.A. Solari et al. / Tectonophysics 365 (2003) 257282

Fig. 8. (a) Photomicrograph taken in an oriented thin section, showing the SZ2m hornblende retrogression foliation, cutting across the previous
hornblende (Hbl1, basal sections) + augite (Cpx) + plagioclase (Pl) banding of the hosting folded metagabbros. The dark, new hornblende (Hbl2)
grows in the SZ2m planes, roughly oriented NW SE in the picture. The black arrows indicate the triple joints in the plagioclase matrix. Parallel
polars. The long side of the picture corresponds to 2.5 mm. (b) Photomicrograph of the flattened quartz in the margins of the pegmatite 66C98,
which shows microstructures such as subgrains with domino-like shape and 90j angles, with undulose extinction and internal, oblique
deformation lamellae (white arrows). The flattened quartz grains make an angle of f 10j with respect of the pegmatite margins. Crossed
polars. The long side of the picture corresponds to a 2.5-mm field.
L.A. Solari et al. / Tectonophysics 365 (2003) 257282 273

Fig. 9. (a) Picture of the outcrop at km 199.2 of the Highway Mexico City-Oaxaca, where the samples 66A98, 66B98, 66C98 and 66D98 were
collected. Each sample, together with the U Pb interpreted age, is indicated. Sample 66A98 is dated and discussed in Keppie et al. (2003). (b)
Schematic of the 66C98 pegmatite field relationships with respect to the hosting FZ2m fold. See text for further explanations.

intrusion of the pegmatite. It is inferred that continued extinction and (c) internal, oblique deformation lamel-
deformation led to flattening of the quartz in the lae (Fig. 8b). The hornblende parallel to the axial
margins of the pegmatite, which shows ductile micro- plane foliation and adjacent to the pegmatite suggest
structures such as (a) formation of subgrains with that the fold formed under amphibolite facies con-
domino-like shape and 90j angles, (b) undulose ditions, and that fluids necessary to hydrate the
274 L.A. Solari et al. / Tectonophysics 365 (2003) 257282

clinopyroxene, stable far from the pegmatite intrusive of 1126 + 11/ 6 Ma calculated on the pegmatite
contacts, were probably provided by the pegmatite. 6898 in the El Catrn structural unit, suggesting that
they may be related intrusions.
4.3.5. Age constraints on structures in the El Marquez The pegmatite 66C98 intruding the outer arc of the
unit FZ2m fold described above (Fig. 9b) is made up of
A sample of metasediment in the El Marquez-type quartz, pink perthitic feldspar, plagioclase (An 25%),
locality (sample 7098) was analysed to constrain its rare hornblende, magnetite and ilmenite. Zircons from
protolith and granulite metamorphism age. The this pegmatite vary from pink to red, stubby to broken,
selected sample has a semipelitic composition, being clear, with rounded tips and no visible cores. Five
made up of quartz, plagioclase, graphite, biotite, relict analyses were performed on unabraded/abraded multi-
pyroxene, opaque minerals, and accessory zircon and grain fractions and yielded concordant to slightly
apatite. Three analyses were performed on selected discordant ages with 207Pb/206Pb between 971 and
grains. Analysis 19 on an equant and abraded single 984 Ma (Table 1). Analysis 30 was performed on
crystal yielded a concordant age of 994 F 3 Ma (Table seven unabraded stubby grains with sharp edges
1), which is interpreted as recording the granulite between the facets, and yielded a concordant age of
facies metamorphism. Analyses 20 and 21 yielded 978 F 3 Ma, which is inferred to represent the time
discordant data (Table 1). A chord drawn through all of intrusion. Because this pegmatite intrudes the
three analyses in the concordia diagram of Fig. 6c stretched, outer arc of a FZ2m fold and is itself ductilely
yields a lower intercept of 996 + 18/ 22 Ma and an deformed during the last increment of flattening, we
upper intercept of 1300 + 69/ 61 Ma, which is interpret the concordant age of 978 F 3 Ma as provid-
possibly a mixing of detrital zircons and the f 1106 ing the best estimate of the age of the FZ2m folding
Ma Olmecan event. event formed under amphibolite facies conditions.
In order to bracket the structural fabrics in the El An undeformed, massive, 50-cm-thick pegmatite
Marquez unit, several samples (66B98, 66C98, (66D98) that cuts across the foliation in the metagab-
66D98) were collected from early-, middle- and late- bro host rock and the foliated 66B98 pegmatite (Fig.
stage pegmatites cutting a metagabbro on the Federal 9a) was sampled for U/Pb geochronology. It consists
Highway at 199.2 km (Fig. 9a). Zircons in the of quartz, pink perthitic feldspar, microcline, plagio-
metagabbro yielded discordant analyses that fall on clase (An 25%), magnetite, retrogressed hornblende,
a chord between 1257 F 71 and 1021 F 39 Ma, which and apatite and zircon as accessory minerals. Four,
are interpreted as the minimum protolith age and as a abraded, single zircons were analysed for U Pb
rough estimate of the age of granulite facies meta- isotopes and yielded concordant to slightly discordant
morphism, respectively (Keppie et al., 2003). Sample data (Table 1), with the weighted mean giving an age
66B98 is a 2-m-thick, foliated pegmatite that is nearly of 977 F 2 Ma (Fig. 6f). Analyses 33 and 34 in Table
concordant with the foliation in the surrounding 1 were performed on stubby to rounded grains. A
metagabbro. It is composed of quartz, alkalic feldspar, similar, stubby zircon was imaged by cathodolumi-
plagioclase, hornblende, magnetite and apatite. U Pb nescence (image h in Fig. 5) and its internal morphol-
analyses yielded one concordant result with an age of ogy is characterized by thin concentric oscillatory
1144 F 2 Ma on an abraded three-grain fraction inter- zoning, suggesting a magmatic origin.
preted as a minimum for the time of intrusion (Table A 2-m-thick pegmatite (6998) intrudes quartz
1, analysis 23), and several 0.4% to + 1.7% dis- feldspar garnet paragneisses and cuts across the
cordant points. All of these analyses fall on a chord Su1m foliation. Thin pegmatitic dikes emanating from
with a MSWD of 5.9, with upper and lower intercepts the main body contain a C S fabric of stretched
of 1144 F 36 and 925 F 200 Ma; the latter is within quartz with top to SE sense of shearing, which are
error of the time of granulite facies metamorphism. inferred to have formed at lower amphibolite upper
The 1144 F 2 Ma age is similar to the 1131 F 10 Ma greenschist facies metamorphic conditions (Passchier
upper intercept U/Pb age determined for the meta- and Trouw, 1996). This pegmatite is composed of
syenite in the El Marquez unit (Keppie et al., 2003). It bluish quartz, plagioclase, perthitic feldspar and very
is also within error of the minimum crystallization age large zircons, up to 2 cm in size. The intense blue
L.A. Solari et al. / Tectonophysics 365 (2003) 257282
Fig. 10. Summary of the tectonic events recognized in the three tectonic units of the northern Oaxacan Complex, and discussed in the text. The intrusive events reported by Keppie et
al. (2003) are shown in italic.

275
276 L.A. Solari et al. / Tectonophysics 365 (2003) 257282

colour in the quartz is probably due to microscopic events, and makes identification of the Zapotecan
inclusions of Ti Fe oxides, such as rutile or ilmenite. structures relatively clear. Thus, we correlate the
This scattering phenomenon has been described else- Zapotecan structures in the Huitzo unit (Z1h: NW-
where in high-grade gneiss terrains (e.g., Herz and plunging lineation, a generally NW-dipping foliation,
Force, 1984), and it is inferred to be due to a high- and NW-plunging, northerly inclined folds) with sim-
grade ilmenite exolution. Thus, although the pegmatite ilarly oriented structures in the El Catrn (Z1c) and El
was probably intruded under granulite facies condi- Marquez units (Z1m) (Figs. 2 and 10). This is con-
tion, it was deformed at a much lower grade of meta- sistent with their formation under granulite facies
morphism. Zircons occur as big, dark purple euhedral metamorphic conditions. The structures formed under
prismatic crystals. One large zircon was broken into upper amphibolite facies metamorphic conditions in
fragments, which were intensely abraded, and then two the El Catrn (Z2c) and El Marquez (Z2m) units have
of them were chosen for U Pb geochronology. The distinctly different orientations from the Z1 structures:
first yielded a 0.5% discordant data with 207Pb/206Pb W-plunging nearly recumbent folds in the El Catrn
age of 975 F 1 Ma (Table 1, analysis 37). The second unit, and NNE-plunging, upright folds in the El
fragment yielded an almost concordant age ( 0.1% Marquez unit (Figs. 2 and 10).
reverse discordance) at 979 F 3 Ma (Table 1, analysis This leaves two earlier sets of structures in the El
38), which is interpreted as the time of pegmatite Catrn and El Marquez units, which are assigned to
crystallization. If the blue quartz formed under gran- the Olmecan tectonothermal event. Thus, the mig-
ulite facies conditions, then the 979 F 3 Ma age matization in the El Catrn unit (u1c) may be broadly
records the last stage of this grade of metamorphism. synchronous with metamorphic differentiation in the
El Marquez unit that produced the banding (u1m)
4.4. Summary (Figs. 2 and 10). This allows the similarly oriented
isoclinal folds (u2) in these two units to be corre-
Using these data together with that in Keppie et al. lated (Figs. 2 and 10). The metamorphic assemb-
(2003), all the Zapotecan granulite and upper amphib- lages formed during the Olmecan event were
olite fabrics are bracketed between the 1012 F 12 Ma overprinted by the Zapotecan granulite facies meta-
protolith age in the Huitzo unit and the 977 F 2 Ma morphism.
age of the post-tectonic pegmatite (66D98). Granulite
facies metamorphic ages range between the concord-
ant 1004 F 3 Ma age in charnockite of the Huitzo unit 5. Discussion
(Keppie et al., 2003) and the concordant 979 F 3 Ma
age on the post-tectonic, blue quartz pegmatite Data presented here indicate that two main tecto-
(6998). Using all the data, the transition from gran- nothermal events occurred in the northern Oaxacan
ulite to amphibolite facies conditions took place Complex of southern Mexico: 1106 F 6 Ma Olmecan
between 981 and 976 Ma: the overlap between event and f 1004 978 F 3 Ma Zapotecan event.
979 F 3 Ma (sample 6998: pegmatite intruded during The significance of the Olmecan migmatization and
granulite facies metamorphism) and 978 F 3 Ma deformation is uncertain, and it has yet to be recorded
(sample 66C98: pegmatite intruded during upper elsewhere in the f 1.1 Ga rocks of Mexico. The
amphibolite facies of metamorphism), respectively. Olmecan event is approximately contemporaneous
Following the Zapotecan tectonothermal event, cool- with a rift-related granite dated at 1117 F 4 Ma in
ing through f 500 jC occurred quickly, as indicated the southern Oaxacan Complex, and follows rift-
by the 977 F 12 Ma age on the hornblende. related magmatism at f 1140 Ma (Keppie et al.,
2001, 2003). Thus, it is possible that the Olmecan
4.5. Correlation of structures in the three units event is related to rifting, in which case it may be
extensional rather than compressional. Assuming a rift
Intrusion of the AMCG units at f 1012 Ma of the model, partial melting could have been triggered by a
Huitzo unit clearly separates the f 1100 Ma Olme- rise in the isotherms caused by rifting. Clearly, more
can and f 1004 980 Ma Zapotecan tectonothermal data are required, such as kinematic data and more
L.A. Solari et al. / Tectonophysics 365 (2003) 257282 277

conventional U Pb and SHRIMP dating, to better ( f 928 1018 Ma, Denison et al., 1971; Silver et al.,
define the nature and significance of the Olmecan 1994). Although a contemporaneous event has not
event. been recorded in Texas (Mosher, 1998 and references
The Zapotecan tectonothermal event in the north- therein) or in most of the Grenville Province, the
ern Oaxacan Complex is recorded by widespread Zapotecan event is contemporaneous with the 980
polyphase deformation and associated granulite facies 1000 Ma Rigolet event, which is restricted to amphib-
metamorphism. A contemporaneous tectonothermal olite greenschist facies reactivation along the Gren-
event has also been recorded in all the other Mexican ville Front (Scharer et al., 1986; Krogh, 1994;
inliers that form Oaxaquia, such as in the Guichicovi Corrigan et al., 2000). Several Grenvillian massifs in
Complex ( f 986 Ma, Ruz et al., 1999; Weber and the southern Appalachians also record a f 990 1010
Kohler, 1999), in the Huiznopala Gneiss ( f 1000 Ma tectonothermal event (references in Sinha et al.,
Ma, Lawlor et al., 1999), and in the Novillo Gneiss 1996). Aleinikoff et al. (1996) reported a granulite

Fig. 11. 1 Ga Rodinia reconstruction (modified from Keppie et al., 2003) showing 990 1000 Ma tectonothermal events in the Grenville-aged
orogens (dark, diagonal pattern). Bold numbers 1 to 3 indicate the possible locations of Oaxaquia (OX) and Chortis Block (CH), as discussed by
Keppie et al. (2003). Abbreviations: SM = Santa Marta Massif; AA = Arequipa Antofalla Massif; R = Rockall Plateau (Goochland and Carolina
terranes); SN = Sveco Norwegian Orogen; CM = Coats Land/Maudheim/Grunehogna terrane; SO = Sunsas Orogen; WA BR = West
Avalonia Blair River; SF = Sao Francisco Craton.
278 L.A. Solari et al. / Tectonophysics 365 (2003) 257282

Fig. 12. Schematic cartoon illustrating the evolution of Oaxaquia during the Zapotecan orogeny ( f 990 Ma). (a) Andean-type orogen, in which
retro-arc thrusting places the Avalonian magmatic arc over the Oaxaquia backarc where rift-related AMCG magmatism occurred at f 1012 Ma:
the Andes would be the modern analogue; (b) arc continent collision model, where the overriding Avalonian arc collides with Oaxaquia, the
passive margin of the Amazonian craton: Australia Papua New Guinea would be the modern analogue; (c) continent continent collision
model, in which a continent (Laurentia?) overrides the passive margin of Amazonia constituted by Oaxaquia: the Alps can be viewed as modern
analogue.
L.A. Solari et al. / Tectonophysics 365 (2003) 257282 279

facies metamorphism at f 1011 Ma of the f 1045 cannot be used to discriminate between them. Syn-
Ma Montpellier anorthosite in the Goochland terrane chroneity of granulite facies metamorphism and defor-
of the southern Appalachians. Similarly, the upper mation may also be overcome by overriding a plume
amphibolite facies metamorphism at f 996 Ma in the as occurred in the Laramide orogeny; however, here;
Blair River Complex of the northern Appalachians is it is associated with widespread magmatism (Murphy
synchronous with the Zapotecan event (Miller et al., et al., 1998), a feature apparently absent in Oaxaquia
1996; Miller and Barr, 2000), as well as the 980 960 during the Zapotecan. On the other hand, is it possible
Ma Sveconorwegian Orogeny of southwestern Baltica that intrusion of the f 1012 Ma AMCG suite pro-
(Soderlund et al., 2002). Restrepo-Pace (personal vided a sufficiently large initial temperature increment
communication, 2000) reported a tectonothermal that survived into the Zapotecan deformation episode?
event at 981 F 85 Ma in the Colombian massifs of Even with a positive response to this question, one
the Andes. Wasteneys et al. (1995) reported a 970 F 23 cannot discriminate between the various tectonic set-
Ma, granulite facies metamorphism and deformation in tings.
the Mollendo Domain of the Arequipa Massif of Peru. Thus, all three tectonic settings envisaged for the
Although Litherland et al. (1986) reported a f 990 Zapotecan are possible: (1) continent continent colli-
Ma tectonothermal event in the Sunsas Orogen of sion between two land masses that could be Laurentia
Bolivia, recent U Pb data suggests that it is consid- and Amazonia (Fig. 12a); (2) arc continent collision
erably older (Tassinari et al., 2000). Thus, the distri- between the Avalonia Carolinia juvenile arc and
bution of granulite facies metamorphism during the Oaxaquia (Fig. 12b); or (3) an Andean-type orogen
f 1 Ga tectonothermal event appears to be restricted adjacent to the northern margin of Amazon craton
to the central parts of the Grenville Orogen in a Rodi- (Fig. 12c).
nia reconstruction (Fig. 11).
The Zapotecan granulite facies tectonothermal
event that occurred at depths of f 30 km probably Acknowledgements
formed in the roots of an orogen produced during
subduction and/or collision (Jamieson et al., 1998). We gratefully acknowledge funding for various
We consider three models (Fig. 12): (1) fold-and- aspects of this project from CONACyT grants (0225P-
thrust belt associated either with A-subduction (e.g. T9506 and 25705-T), PAPIIT-UNAM grants
the Andes: Ramos and Aleman, 2000), or with shal- (IN116999 and IN107999) to JDK and FOG, a UC-
lowing of the subduction zone, subduction of young MEXUS grant to KLC and FOG, NSF grant
oceanic lithosphere, and overriding of plumes (e.g. EAR9909459 to KLC and UNAM-PAEP student grant
Laramide Orogeny: Murphy et al., 1998); (2) arc to LAS. We would also like to thank Pete Holden for
continent collision (e.g. Papua/New Guinea and Aus- assistance with isotopic analyses at UCSC, and Kip
tralia: van Staal et al., 1998); and (3) continent Hodges for access to the MIT 40Ar/39Ar facility. Care-
continent collision (e.g. Alps: Stampfli et al., 1998). ful reviews of I. Fitzsimons, E. Johnson and P. Schaaf
Although polyphase deformation is present in all these greatly improved the clarity of the manuscript, and
tectonic settings, a contemporaneous association with helped to clarify some points. This work is a
granulite facies metamorphism is perhaps more diag- contribution to the IGCP # 453 (Modern and Ancient
nostic. England and Richardson (1977) and Jamieson Orogens).
et al. (1998) have shown that >25 40 million years is
required to reequilibrate the isotherms following crus-
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