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Construction and Building Materials 27 (2012) 126129

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Construction and Building Materials


journal homepage: www.elsevier.com/locate/conbuildmat

Evaluation of using waste timber railway sleepers in woodcement


composite materials
Alireza Ashori a,, Taghi Tabarsa b, Fatemeh Amosi b
a
Department of Chemical Technologies, Iranian Research Organization for Science and Technology (IROST), P.O. Box 15815-3538, Tehran, Iran
b
Department of Wood and Paper Technology, Gorgan University of Agricultural Sciences and Natural Resources (GUASNR), Gorgan, Iran

a r t i c l e i n f o a b s t r a c t

Article history: In present study, the suitability of using waste timber railway sleepers (WTRSs) as ller in woodcement
Received 18 June 2011 composites was investigated. The effects of two variable factors namely press temperatures (25 and
Received in revised form 3 August 2011 60 C) and calcium chloride contents (3%, 5% and 7% w/w cement) on some physico-mechanical proper-
Accepted 4 August 2011
ties were also investigated. The following experimental parameters were constant: wood/cement ratio
Available online 30 August 2011
(40:60), board thickness (15 mm), press pressure (40 kg/cm2), and press time (5 min). Press temperature,
calcium chloride and the interaction of both variables had signicant effects (p < 0.01) on all the studied
Keywords:
properties. Test results showed that addition of calcium chloride tends to enhance both the physical and
Timber railway sleeper
Construction material
mechanical properties of boards. All properties of the boards were improved when the calcium chloride
Woodcement composite content was increased from 3% to 7%. The results also showed that as the press temperature was
Physico-mechanical properties increased from 25 to 60 C, signicant increased in water absorption and thickness swelling occurred.
Water absorption and thickness swelling (at 2 h and 24 h) compared favorably with values reported
for cement-bonded composites produced from virgin wood particles. In general, the strength properties
of the boards were found to be a maximum when press temperature and calcium chloride were 25 C and
7%, respectively. These properties can be exploited in many applications where lightweight concretes are
required. Therefore, WTRS is technically suitable for building construction such as paneling, ceiling and
partitioning.
2011 Elsevier Ltd. All rights reserved.

1. Introduction during their service life to protect them from biological deteriora-
tion. These chemical materials contain toxic or polymeric sub-
Traditionally, wood has been an essential construction material. stances which are not easily biodegradable. Presently these
However, with the invention of reinforced concrete, its application wastes are either burnt or land lled. These approaches cause var-
has been reduced [1]. In recent years, there has been a growing ious environmental issues like air pollution, emission of green
interest in utilizing wood for making low-cost building materials house gases and occupation of useful land. The increasing charges
[25]. The primary advantages of using woody materials as llers of landll are further aggravating the problem. Moreover, these
in cement are the low density, low cost, nonabrasive nature, high methods of disposal are certainly wastage of a primary natural re-
lling levels possible, low energy consumption, and wide variety source. Therefore attempts have been made by researchers, both in
of wood species available throughout the world [6]. On the other industry and academia, to reuse these wastes as the building mate-
hand, increasing demand for forest resources in various applica- rials (i.e. woodcement composites) [1,6].
tions has led to the shortages of wood supply. Thus, there is a need Studies on the waste wood in the forms of bers, particles or
to look for innovative ways of using non-traditional forest strands suggest that these materials have the potential for use as
resources to substitute wood raw materials for wood-based indus- reinforcing agent or ller in cement composites. Kasai et al. [10]
tries. Among the possible alternatives, using recycled wood is cur- used wood particles from construction waste in Japan for making
rently at the center of attention [1,79]. Every year, a large number wood-chip concrete. They made concrete with a density range of
of old and deteriorated structures such as railways, buildings, fenc- 0.921.25 g/cm3. They found the exural strength of the product
ing poles, furniture items and bridges are being demolished. Most in the range of 47 MPa and compressive strength 58 MPa. The
of the timbers used in construction are being treated with chemical ratio between exural strength and compressive strength was
preservatives (such as chromated copper arsenate and creosote) 0.50.9, greater than that for normal concrete. This indicates the
reinforcing effect of wood particles. They further reduced the den-
Corresponding author. Tel./fax: +98 228 2276629. sity to about 0.78 g/cm3 by adding synthetic lightweight aggre-
E-mail address: ashori@irost.org (A. Ashori). gates. This resulted in comparatively lower bending and

0950-0618/$ - see front matter 2011 Elsevier Ltd. All rights reserved.
doi:10.1016/j.conbuildmat.2011.08.016
A. Ashori et al. / Construction and Building Materials 27 (2012) 126129 127

compressive strength values at 2.05 and 2.2 MPa, respectively. In Table 2


another study by Wolfe and Gjinolli [11] on the use of southern Mixing ratios of raw materials and their abbreviations.

pine wood particles derived from construction waste, it was found Code Press temp. (C) CaCl2 (%) Cement (%) WTRS (%) Replications
that the toughness index, which is used to compare the energy A1B1 25 3 60 40 3
absorption capacity during failure of a material, was greater than A1B2 25 5 60 40 3
whereas the average value of toughness index for other ber rein- A1B3 25 7 60 40 3
forced concrete products is 5. Therefore, they achieved a better A2B1 60 3 60 40 3
A2B2 60 5 60 40 3
toughness index. A2B3 60 7 60 40 3
A number of studies have reported the effects of virgin or waste C1 25 0 100 0 3
wood particles on the properties of cement composites [9,1215]. C2 60 0 100 0 3
However, no published reports are available that evaluate effects of
waste timber railway sleepers (WTRSs) on the strength and sorp-
tion properties of cement-bonded composites. In addition, reutili- 2.3.1. Physical properties
zation of WTRS has advantages for economy and environment. Physical properties in terms of apparent density (AD), water absorption (WA)
The main objective of present work is to evaluate the suitability and thickness swelling (TS) were evaluated. The specimens for WA and TS
(50  50 mm2) were completely submerged horizontally under distilled water
of using WTRS as reinforcing agent in the cement composites. Fur-
maintained at 25 C for 2 h and 24 h. After soaking, the samples were drained on
ther, the effects of two variable factors namely press temperatures paper towels for 10 min to remove excess water. The WA and TS were calculated
and calcium chloride contents on the selected physical and from the increase in weight and thickness of the specimen during submersion,
mechanical properties were investigated. respectively. At least three specimens of every board were tested to obtain a reliable
average and standard deviations.

2. Experimental procedures
2.3.2. Mechanical properties
Conditioned boards were sawn into test samples for modulus of rupture (MOR)
2.1. Materials
modulus of elasticity (MOE) and internal bonding (IB) strength. Three-point exural
testing was carried out using an Instron Universal Testing Machine, with a span of
The woody material used in this work was WTRS which was collected from a
180 mm and crosshead, bearer diameter of 25 mm and loading speed of 5 mm/min.
local railway station, Karaj, Iran. They have been preserved by pressure treatment
with an EPA-registered pesticide containing creosote to protect them from insect
attack and decay. The WTRSs were initially chipped using a laboratory-scale drum 2.4. Statistical analysis
chipper (Pallmann PHT). The chips were then reduced into smaller pieces using a
laboratory-scale ring aker (Pallmann PZB). Dried particles with 5% moisture con- The experimental design consisted of two treatments press temperature and
tent were screened to eliminate oversized particles. The weight distributions of percentage concentration of CaCl2 and three replications per treatment. Data for
wood particles are presented in Table 1. each treatment were statistically studied by analysis of variance (ANOVA). When
The binding agent employed was commercial grade of Portland cement (type II). the ANOVA indicated a signicant difference among factors and levels, a comparison
Calcium chloride (CaCl2) was used as cement setting accelerator. It was an analyt- of the means was done employing Duncans multiple range test to identify the
ical grade from Merk Co, Germany. groups that were signicantly different from others groups at 99% condence level.

2.2. Preparation of boards 3. Results and discussion


All the boards were made with 40:60 weight ratio for wood/cement, and a 1:0.6
weight ratio for cement/water (the amount of water in the wood particles was in-
The results of the physical and mechanical tests, with statistical
cluded). The wood/cement ratio was selected based on commercially produced analysis, are shown in Tables 35 for all the fabricated materials.
woodcement composites. Two process variables considered in this study include
CaCl2 contents (3%, 5% and 7% w/w cement) and press temperature levels (25 and
3.1. Physical properties
60 C). Control samples contained neat cement and water. Board thickness
(15 mm), press pressure (40 kg/cm2) and press time (5 min) were kept constant
in all experiments. Table 2 presents the formulations and abbreviations of the The woodcement composites with low board density (61 g/
boards produced. cm3) would be preferred for applications that require boards of
The wood particles for each board were rst sprayed evenly with the dilute light weight such as ceiling and roong for easy installation. In
aqueous solution of CaCl2. Consequently, the cement and WTRS were uniformly
blended and then immediately transferred into a mould of 450 mm 
addition, the composites with low cement/wood ratio would be
450 mm  15 mm. The mixture was evenly distributed and attened using a woo- more economical because a small quantity of cement is required
den block, the mould removed and a piece of plywood placed on top of the mat. with a large quantity of particles used in this study (WTRS) during
The resulting assemblage was pre-pressed to reduce its height while the mat for CBB production. It must be noted that cement is more expensive to
the next board was mixed. This stack of mats was placed between two steel plates
procure than WTRS. According to Adhikary et al. [16] the water
and pressed. The pressed mats were kept under compression for 24 h by bolting
the two steel plates together using four 15 mm thick bolts. After 24 h, the boards absorption and swelling rate increased linearly with the decreasing
were declamped, stacked vertically and conditioned for 28 days at 35 1 C and of the composite board density.
90 5% RH to allow the cement to cure and gain strength. The specimens were con- In general, the characteristics that make woodcement compos-
ditioned in a controlled room for 28 days at 25 C and 65% RH. ites desirable to construction applications are low water absorp-
tion and good dimensional stability. On the other hand, water
2.3. Test procedure absorption can affect on the mechanical properties. As Tables 3
and 4 present, a signicant difference in water absorption was ob-
Mechanical and physical properties were determined following ISO 8335:1987.
It is a procedure for boards of Portland or equivalent cement reinforced with wood served for the 8 types of boards after 2 h and 24 h of immersion.
particles. A1B1, A1B2 and A1B3 boards showed intermediate values of water
absorption which increased with immersion time. A1B3 board
Table 1
showed the lowest values of water absorption among the studied
Distribution of wood particles.
boards. However, water absorption of woodcement composite
Size (mm) Percentage boards was signicantly higher than control samples (C1 and C2).
<0.4 3.2 This could be attributed to their lower bulk density and hence
0.41 3.4 higher porosity already alluded to (Table 3). Asasutjarit et al. [17]
12 8.4
reported that the low density woodcement boards have more
34, >4 82.1
void spaces than dense ones so that more water can be absorbed.
128 A. Ashori et al. / Construction and Building Materials 27 (2012) 126129

Table 3
Mean values of physical and mechanical properties of woodcement composites.

Code D (g/cm3) MOR (MPa) MOE (MPa) IB (MPa) WA (%) TS (%)


2h 24 h 2h 24 h
A1B1 0.98 (0.06) 8.3 (1.1) 2166 (102) 0.36 (0.06) 14.6 (1.8) 16.5 (1.2) 1.34 (0.8) 1.78 (0.93)
A1B2 1.00 (0.04) 9.5 (0.8) 2189 (87) 0.40 (0.09) 15.1 (1.6) 15.8 (2.5) 1.09 (0.12) 1.61 (0.47)
A1B3 1.02 (0.06) 10.1 (0.9) 2206 (152) 0.43 (0.05) 11.0 (1.8) 15.4 (1.2) 0.98 (0.91) 1.51 (0.82)
A2B1 0.94 (0.11) 1.9 (0.4) 1034 (92) 0.09 (0.02) 26.1 (2.3) 39.8 (2.7) 6.16 (1.14) 15.25 (1.35)
A2B2 0.96 (0.10) 2.1 (0.7) 1271 (120) 0.12 (0.04) 25.9 (2.7) 39.4 (4.1) 5.95 (2.01) 15.11 (2.06)
A2B3 0.98 (0.8) 2.8 (0.6) 1542 (84) 0.14 (0.07) 25.6 (2.4) 39.1 (2.8) 5.80 (1.97) 15.01 (1.69)
C1 1.13 (0.09) 15.4 (1.0) 2261 (186) 0.51 (0.10) 15.6 (1.9) 29.2 (2.1) 1.33 (1.01) 10.73 (2.03)
C2 1.17 (0.11) 14.6 (1.2) 2247 (191) 0.50 (0.08) 15.2 (1.4) 28.9 (1.4) 1.53 (0.98) 11.21 (1.27)

Note: Standard deviations are in parenthesis.

Table 4
Analysis of variances on the effects of press temperature (A) and CaCl2 (B) and their interaction (AB) on the physical properties.

Source of variations df WA 2-h WA 24-h TS 2-h TS 24-h


SS MS F SS MS F SS MS F SS MS F
A 1 791.092 791.092 518.81 2492.88 2492.88 7866.48 105.17 105.17 3312.31 815.54 815.54 62.97
B 2 12.62 6.31 4.14 2.416 1.208 3.81 0.405 0.202 6.37 0.284 0.142 3.09
AB 2 7.55 3.78 2.484ns 0.156 0.078 0.25ns 0.001 0.0006 0.02 ns 0.014 0.007 0.15ns
Error 12 18.29 1.53 3.169 0.317 0.317 0.0317 0.460 0.046
Total 17 829.56 2499.42 106.68 819.18

df = degree of freedom; MS = mean of squares; SS = sum of squares; F = F value; = signicant difference at the 1% level (p 6 0.01%); and ns = not signicant.

Table 5
Analysis of variances on the effects of press temperature (A) and CaCl2 (B) and their interaction (AB) on the density and mechanical properties.

Source of variations df MOR MOE IB AD


SS MS F SS MS F SS MS F SS MS F
A 1 222.18 222.18 877.52 3685612.5 3685612.5 5403.3 0.35 0.35 453.56 0.0845 0.0845 93089
B 2 6.1 3.05 13.05 225,424 112,712 165.2 0.0103 0.0051 6.71 0.0044 0.0022 24.63
AB 2 0.907 0.453 1.94ns 164,668 82,334 12.74ns 0.0002 0.0001 0.14 ns 0.00003 0.000016 0.19ns
Error 10 3.04 0.252 6821 682.1 1.07 8.94 5.93 9.94
Total 17 232.23 4084482.5 1.45 6.02

df = degree of freedom; MS = mean of squares; SS = sum of squares; F = F value; = signicant difference at the 1% level (p 6 0.01%); and ns = not signicant.

In other words, increasing board density decreases the void and the WTRS with cement was improved considerably. The strength
improves thickness swelling and water absorption characteristics. properties of the boards were found to be a maximum when press
It is interesting to mention that the increase in void content is also temperature and CaCl2 were 25 C and 7%, respectively.
due to the inadequate compaction of the unworkable mixes. As mentioned earlier, wood used in construction is typically
After addition of 7% CaCl2 to woodcement composites, a reduc- treated with chemical preservatives to make it resistant against
tion ratio of 25% and 8% in water absorption after 2 h and 24 h of microbial degradation and biological deterioration. Among the
water soaking, respectively, was observed. In addition, it was ob- chemical preservatives, creosote or coal tar creosote is the most
served that CaCl2 treated composites generally absorbed less water widely used wood preservative, particularly for timber railway
at 2 h and 24 h, respectively. This is most probably due to changes in sleeper in the world. The possible reason for strength reduction
the ber structure that rendered them stiffer and tougher by the cre- with increasing press temperature, should be related to the diffu-
ation of high cement-to-cement bonds and cementwood bonds. sion of creosote to the surface of wood particles. This could reduce
These results are comparable with those obtained by Ashori et al. adhesion at the interface, which causes inferior interfacial bonding
[6] and Tabarsa and Ashori [18] who proposed the addition of CaCl2, strength as compared to the control (C1 and C2) samples.
35%, could improved the water absorption and thickness swelling.

3.2. Mechanical properties 4. Conclusions

The average values and statistical analysis of the mechanical Based on the results of this work the following conclusions can
properties in terms of MOR, MOE and IB are presented in Tables be drawn.
3 and 5, respectively. Mechanical properties generally decreased
with increase in press temperature (60 C) and increased with in- 1. During the process of using recycled wood wastes for further
crease in CaCl2 content. Further, ANOVA test showed that the reutilization, some problems should be taken into consider-
strength properties of the boards were signicantly inuenced by ation such as chemical preservatives.
the press temperature and CaCl2 contents and their interaction (Ta- 2. Statistical analysis of the test results conrmed that the
ble 5). All boards made with 25 C had the highest values among physical and mechanical properties of the woodcement
the other types of specimens. In addition, all mechanical properties composites showed evidence of signicant difference
of the boards were improved when the CaCl2 was increased from between the means of the two treatments (press tempera-
3% to 7%. This may be due to the fact that the compatibility of ture and CaCl2 contents) and their interaction tested.
A. Ashori et al. / Construction and Building Materials 27 (2012) 126129 129

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