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CHEMICAL KINETICS

By: Er. Vineet Loomba


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Rate of a reaction
1. The rate at which a substance reacts depends on its
(a) Atomic weight (b) Equivalent weight
(c) Molecular weight (d) Active mass
2. The rate law for the reaction
(a) Rate K[ A][B] (b) Rate K[ A][2B]
RCl NaOH (aq) ROH NaCl is given by Rate
K1 [RCl ] . The rate of the reaction will be [C][D]2
[IIT 1988] (c) Rate K[ A][B]2 (d) Rate K
[ A][B]2
(a) Doubled on doubling the concentration of sodium
hydroxide 9. In the reaction 2N2O5 4 NO2 O2 , initial pressure
(b) Halved on reducing the concentration of alkyl is 500 atm and rate constant K is
halide to one half
3.38 105 sec 1 . After 10 minutes the final
(c) Decreased on increasing the temperature of the
pressure of N 2O5 is
reaction
(d) Unaffected by increasing the temperature of the (a) 490 atm (b) 250 atm
reaction (c) 480 atm (d) 420 atm
3. The rate of a gaseous reaction is given by the 10. The rate law for the reaction
expression K [ A][B] . If the volume of the reaction [H ]
Sucrose + Water Glucose + Fructose is
vessel is suddenly reduced to 1/4th of the initial
given by
volume, the reaction rate relating to original rate will
be [Roorkee 1992] (a) Rate K [sucrose] [water]
(a) 1/10 (b) 1/8 (b) Rate K [sucrose] [water] 0
(c) 8 (d) 16 (c) Rate K [sucrose] 0 [water]
4. For a given reaction 3 A B C D the rate of (d) Rate K [sucrose] 1 / 2 [water] 1 / 2
reaction can be represented by [DCE 2000] d[ A]
1 d[ A] d[B] d[C] d[D] 11. A 2B C D . If 5 10 4 mol l 1s 1 , then
(a) dt
3 dt dt dt dt
d[B]
1 d[ A] d[C] m n is
(b) K[ A] [B] dt
3 dt dt
1 d[ A] d[C] (a) 2.5 104 mol l 1s 1 (b) 5.0 104 mol l 1s 1
(c) K[ A]n [B]m
3 dt dt
(c) 2.5 10 3mol l 1s 1 (d) 1.0 103 mol l 1s 1
(d) None of these
5. The rate of a chemical reaction depends upon 12. The data for the reaction A B C is
(a) Time (b) Pressure Exp. [A]0 [B]0 Initial rate
(c) Concentration (d) All of these
(1) 0.012 0.035 0.10
6. The rate of a reaction is doubled for every 10 o rise in
temperature. The increase in reaction rate as a result (2) 0.024 0.070 0.80
of temperature rise from 10 o to 100o is (3) 0.024 0.035 0.10
(a) 112 (b) 512 (4) 0.012 0.070 0.80
(c) 400 (d) 614
The rate law corresponds to the above data is
Rate law and Rate constant (a) Rate k [B]3 (b) Rate k [B]4
7. Which of these does not influence the rate of reaction (c) Rate k [ A][B]3 (d) Rate k [ A]2 [B]2
(a) Nature of the reactants
13. The experimental data for the reaction
(b) Concentration of the reactants
2 A B2 2 AB is
(c) Temperature of the reaction
(d) Molecularity of the reaction
8. The rate law for reaction A 2B C 2D will be Exp. [A]0 [B]0 Rate (mole s 1 )
(b) A plot of log [ X] versus time is linear for a first 36. A rise in temperature increases the velocity of a
order reaction X P reaction. It is because it results in
(c) A plot of log P versus 1 / T is linear at constant (a) An increased number of molecular collisions
volume (b) An increased momentum of colliding molecules
(d) A plot of P versus 1 / V is linear at constant (c) An increase in the activation energy
temperature (d) A decrease in the activation energy
37. The number of collisions depend upon
Collision theory, Energy of (a) Pressure (b) Concentration
(c) Temperature (d) All the above
activation 38. If E f and Er are the activation energies of forward
and Arrhenius equation and reverse reactions and the reaction is known to be
exothermic, then
(a) E f Er
31. A large increase in the rate of a reaction for a rise in
temperature is due to (b) E f Er
(a) The decrease in the number of collisions
(c) E f Er
(b) The increase in the number of activated
molecules (d) No relation can be given between E f and Er as
(c) The shortening of the mean free path data are not sufficient
(d) The lowering of the activation energy 39. According to Arrhenius theory, the activation energy
32. Which of the following statements is not true is
according to collision theory of reaction rates (a) The energy it should possess so that it can enter
(a) Collision of molecules is a precondition for any into an effective collision
reaction to occur (b) The energy which the molecule should possess in
(b) All collisions result in the formation of the order to undergo reaction
products (c) The energy it has to acquire further so that it can
(c) Only activated collisions result in the formation of enter into a effective collison
the products (d) The energy gained by the molecules on colliding
(d) Molecules which have acquired the energy of with another molecule
activation can collide effectively 40. The energy of activation is
33. According to the collision theory of chemical reactions (a) The energy associated with the activated
(a) A chemical reaction occurs with every molecular molecules
collision (b) Threshold energy energy of normal molecules
(b) Rate is directly proportional to the number of (c) Threshold energy + energy of normal molecules
collisions per second (d) Energy of products energy of reactants
(c) Reactions in the gas phase are always of zero 41. On increasing the temperature, the rate of the
order reaction increases because of [
(d) Reaction rates are of the order of molecular (a) Decrease in the number of collisions
speeds (b) Decrease in the energy of activation
34. According to the collision theory of reaction rates, (c) Decrease in the number of activated molecules
rate of reaction increases with temperature due to (d) Increase in the number of effective collisions
(a) Greater number of collisions 42. Energy of activation of a reactant is reduced by
(b) Greater velocity of the reacting molecules (a) Increased temperature
(c) Greater number of molecules have activation (b) Reduced temperature
energy (c) Reduced pressure
(d) None of the above (d) Increased pressure
35. The reaction rate at a given temperature becomes 43. The minimum energy a molecule should possess in
slower, then order to enter into a fruitful collision is known as
(a) Reaction energy (b) Collision energy
(a) The free energy of activation is higher
(c) Activation energy (d) Threshold energy
(b) The free energy of activation is lower
44. Activation energy is
(c) The entropy changes (a) The amount of energy to be added to the actual
(d) The initial concentration of the reactants remains energy of a molecule so that the threshold energy
constant is reached
60. Temperature dependent equation can be written as
(b) H 2 OH

(a) OH H
Ea / RT
(a) ln k ln A e
(c) H 2 O2 (d) H 2O H 2 O2
Ea / RT
(b) ln k ln A e 63. The law of photochemical equivalence was given by
RT / Ea
(c) ln k ln A e (a) Drapper (b) Grauths
(d) All of these (c) Einstein (d) Labbert
64. If I is the intensity of absorbed light and C is the
Photochemical reactions concentration of AB for the photochemical process
AB hv AB*, the rate of formation of AB* is

61. The formation of starch in plants results from directly proportional to [IIT Screening 2001]
(a) Photosynthesis (b) Photolysis (a) C (b) I
(c) Flash photolysis (d) None of the above (c) I 2 (d) C.I
62. The photolysis of water gives the substance

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ANSWER KEY

1a 2b 3a 4a 5b 6c 7d 8c 9a 10b 11a 12a

13a 14c 15c 16d 17c 18b 19c 20b 21a 22c 23c 24b

25d 26a 27b 28a 29c 30abd 31b 32b 33b 34c 35a 36d

37d 38b 39c 40b 41d 42a 43d 44a 45b 46d 47b 48b

49a 50ab 51c 52b 53b 54c 55b 56d 57c 58c 59a 60a

61a 62a 63c 64b

Er. Vineet Loomba


IITIAN | IIT-JEE MENTOR

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