Kimia

Aska Zakiya
Fisik 21100116120022
Teknik Geologi UNDIP

1. Calculate the effect of an increase in pressure of 1.00 bar on the liquid and solid phases of
carbon dioxide (of molar mass 44.0 g/mol) in equilibrium with densities 2.35 g/cm3, and
2.5 x 103 g/cm3, respectively.

Method
We know that the change in chemical potential of an incompressible substance when the
pressure is changed by p is = Vmp. Therefore, to answer the question, we need to
know the molar volumes of that phase. These values are obtained from the mass density,
, and the molar mass, M, by using Vm = M/. Therefore, we use the expression =
Mp/.

Answer
Pressure = 1 bar = 1 x 105 Pa
Molar mass = 44.0 g/mol = 4.4 x 10-2 kg/mol
Densities = 2.35 x 103kg/m3 (liquid), 2.5 x 103 kg/m3
Mp
=

Mp Mp
(l) = (s) =

(4.4 x 102 kg/mol) x (1 x 105 Pa) (4.4 x 102 kg/mol) x (1 x 105 Pa)
= =
2.35 x 103 kg/m3 2.5 x 103 kg/m3

= + 1.87 J/mol (Liquid) = + 1.76 J/mol (Solid)

We can concluse that numerical results as follows: the chemical potential of Carbon
dioxide in the liquid phase and in the solid phase, we can find if liquid phase rises more
sharply than that of the solid. So, it needs small chemical potential to be the dry ice than
to be in liquid phase.

2. Calculate the effect of an increase in pressure of 100 bar on the vapor pressure of benzene
at 25C, which has density 0.879 g/cm3.

Method
We know that the change in chemical condition (2) when the vapor pressure is increase
by p = p*eVm(l)P/RT. Therefore, to answer this question, we need to know Molar Volume
of Benzene, by Vm = M/. These values are obtained the gas constant, and the
temperature. Therefore, we use the expression p = p*eVm(l)P/RT.

1
askazakiya@ymail.com
Teknik Geologi Undip(20022)
 Answer
p = p*eVm(l)P/RT
Pressure = 1 x 107 Pa
Densities = 0.879 g/cm3 = 8.79 x 102 kg/m3
Molar Volume = 7.811 x 10-2 kg/mol (find in other reference)
R = 8.314 J/Kmol
T = 25 C = 298 K

Vm =

7.811 x 102 kg/mol

=
8.79 x 102 kg/m3

= 0.00888 x 10-2 ml

= 8.88 x 10-5 L

Vm(l)P ( 8.88 x 105 L)x(1 x 107 Pa)

=
RT (8.314 J/Kmol)x(298 K)

= 0.0035 x 102

= 0.35

p = p*eVm(l)P/RT

= p*e0.35

= p*1.43105998278
1.43
= p*1.43
= 1

= (1.43-1) x 100%

= 0.43 x 100%

= 43% this is the increasing pressure of Benzena.

We can concluse that numerical results as follows: When pressure is applied to a condensed
phase, its vapour pressure rises.

2
askazakiya@ymail.com
Teknik Geologi Undip(20022)