S GD T THI TH THPT QUC GIA LN 1 NM 2017

TNH HI PHNG Mn: KHOA HC T NHIN HA HC

THPT VNH BO Thi gian lm bi: 50 pht, khng k thi gian pht

( thi c 40 cu / 4 trang)
M : 132
Cho bit nguyn t khi ca cc nguyn t :
H =1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S =32; Cl = 35,5; K = 39; Ca = 40; Cr = 52;
Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.

Cu 1: Este X mch h c cng thc phn t C5H8O2, c to bi mt axit Y v mt ancol Z. Vy Y

khng th l
A. CH3COOH. B. C2H5COOH. C. C3H5COOH. D. HCOOH.
Cu 2: Cho m gam Mg vo dung dch cha 0,12 mol FeCl3. Sau khi phn ng xy ra hon ton thu c
3,36 gam cht rn. Gi tr ca m l
A. 2,88. B. 2,16. C. 4,32. D. 5,04.
Cu 3: iu ch kim loi kim ngi ta dng phng php
A. thu luyn B. nhit luyn C. in phn dung dch D. in phn nng
chy
Cu 4: Dy no di y gm cc cht c kh nng ha tan Cu(OH) 2 to hp cht mu tan trong trong
nc
A. etilen glycol, axit axetic v GlyAlaGly B. ancol etylic, fructoz v GlyAlaLysVal
C. glixerol, glucoz v GlyAla D. ancol etylic, axit fomic v LysVal
Cu 5: Mui mononatri ca amino axit no sau y c dng lm bt ngt (m chnh)?
A. Lysin. B. Alanin. C. Axit glutamic. D. Axit amino
axetic.
Cu 6: Oxit no sau y l oxit lng tnh :
A. Cr2O3. B. CrO. C. Fe2O3. D. MgO.
Cu 7: Cho x mol Fe tc dng vi dung dch cha y mol AgNO3. dung dch sau phn ng tn ti cc
ion Fe3+, Fe2+ th gi tr ca a = y : x l
A. 3 < a < 3,5. B. 1 < a < 2. C. 0,5 < a < 1. D. 2 < a < 3.
Cu 8: t chy hon ton 1 mol cht bo X, thu c lng CO 2 v H2O hn km nhau 8 mol. Mt
khc a mol cht bo X trn tc dng ti a vi 600 ml dung dch Br2 1M. Gi tr ca a l
A. 0,15 B. 0,10 C. 0,30 D. 0,20
Cu 9: Trong cc hin tng thc hnh di y, hin tng no miu t khng chnh xc.
A. Cho mu Na vo dung dch ng FeCl3 thy c kh thot ra ng thi c kt ta mu nu .
B. Thm dung dch NH3 d vo dung dch AlCl3 thy c kt ta, sc kh CO2 d vo ng nghim cha
kt ta trn thy kt ta tan.
C. Nhng l st nh sch g vo dung dch CuSO4, l st chuyn sang mu .
D. Th mu km vo hai ng nghim u cha dung dch H2SO4. Thm vo ng nghim th nht vi
git CuSO4 thy kh thot ra ng nghim ny nhanh hn.
AlCl3 + NH3 + H2O
Cu 10: Mt loi nc cng c cha cc ion: Ca 2+, Mg2+, Cl- v SO42-. Ha cht no trong s cc cht
sau y c thm lm mm loi nc cng trn
A. K2CO3. B. NaOH C. NaCl D. KNO3
Cu 11: Kim loi Al khng phn ng vi cht no sau y trong dung dch :
A. Fe2(SO4)3 B. CuSO4 C. HCl D. MgCl2
Cu 12: Hp cht hu c X c cng thc C3H12N2O3. Khi cho 12,4 gam X tc dng vi 200 ml dung dch

Trang 1
 NaOH 1,5M thu c 4,48 lt ( ktc) kh Y lm xanh giy qu tm m. C cn dung dch sau phn ng
thu c cht rn c khi lng l
A. 16,2 gam. B. 17,4 gam. C. 17,2 gam. D. 13,4 gam
Cu 13: Cht no sau y trng hp to poli(metyl metacrylic) :
A. CH2=C(CH3)COOCH3 B. CH2=CHCOOCH3
C. CH3COOCH=CH2 D. CH2=C(CH3)COOC2H5
Cu 14: Cho s phn ng sau:
t0 ch HCl,t0 + Cl2 +dung d
ch KOH d +dung d
ch H2SO4 lo
ng
(NH4)2Cr2O7 X
dung d
Y Z T
Trong X, Y, Z v T u l cc hp cht khc nhau ca crom. Cht T l
A. K2Cr2O7. B. K2CrO4. C. Cr2(SO4)3. D. CrSO4.
Cu 15: Trong phng th nghim, cht rn tinh khit no sau y khng c tc dng ht m :
A. NaCl B. NaOH C. CaO D. CaCl2
Cu 16: Cho hn hp gm 0,1 mol Zn v 0,2 mol Mg vo 400ml dung dch cha ng thi Cu(NO 3)2
1M v AgNO3 1M. Sau khi phn ng xy ra hon ton, thu c cht rn X. Ha tan hon ton X trong
lng d dung dch HNO 3, thu c V lt kh NO (sn phm kh duy nht N +5, ktc). Gi tr ca V l:
A. 5,60 B. 6,72 C. 4,48 D. 2,24
Cu 17: Bng di y ghi li hin tng khi lm th nghim vi cc cht X, Y ,Z, T dng dung dch
vi dung mi nc:
Thuc th
X Y Z T
Cht
Dung dch
Khng c kt ta Ag Khng c kt ta Ag
AgNO3/NH3 un nh
Cu(OH)2 khng
Cu(OH)2, lc nh Dung dch xanh lam Dung dch xanh lam Dung dch xanh lam
tan
Mt mu nc
Mt mu nc Khng mt mu Khng mt mu
Nc brom brom v c kt
brom nc brom nc brom
ta trng
Cc cht X, Y, Z, T ln lt l
A. Phenol, Axit fomic, saccaroz, glucoz B. Anilin, glucoz, glixerol, fructoz
C. Anilin, mantoz, etanol, axit acrylic D. Phenol, glucoz, glixerol, mantoz
Cu 18: Hn hp X gm C2H5OH, HCHO, CH3COOH, HCOOCH3, CH3COOC2H3,
CH3CH(OH)COOH v CH 2OHCH(OH)CHO. t chy hon ton 13,8 gam X cn dng va 12,04
lt O2 (ktc), thu c CO 2 v 9 gam H2O. Thnh phn phn trm theo khi lng ca CH 3COOC2H3
trong X l:
A. 15,58% B. 12,46% C. 31,16% D. 24,92%
Cu 19: Tin hnh cc th nghim sau:
(a) Cho Mg vo dung dch Fe 2(SO4)3 d.
(b) Sc kh H2S vo dung dch FeCl3
(c) Cho dung dch KHSO4 vo dung dch Ba(HCO3)2
(d) Cho K d vo dung dch Ca(H2PO4)2
(e) Cho dung dch (NH4)2CO3 vo dung dch Ba(OH)2
S th nghim thu c kt ta l :
A. 3 B. 2 C. 5 D. 4
Cu 20: C 3,94g hn hp X gm bt Al v Fe 3O4( trong Al chim 41,12% v khi lng) thc hin
phn ng nhit nhm hon ton hn hp X trong chn khng thu c hn hp Y. Ha tan hon ton Y
trong dung dch cha 0,314 mol HNO 3 thu c dung dch Z ch c cc mui v 0,021mol mt kh duy
nht l NO. C cn dung dch Z, ri thu ly cht rn khan nung trong chn khng n khi lng
khng i thu c hn hp kh v hi T. Khi lng ca T gn gi tr no nht sau y?

Trang 2
 A. 14,15g B. 15,35g C. 15,78g D. 14,58g
Cu 21: Hn hp X gm Mg, Al, Al2O3 v MgCO3 (trong oxi chim 25,157% v khi lng). Ha
tan ht 19,08 gam X trong dung dch cha 1,32 mol NaHSO 4 v x mol HNO3, kt thc phn ng thu
c dung dch Y ch cha cc mui trung ha c khi lng 171,36 gam v hn hp kh Z gm
CO2, N2O, H2. T khi ca Z so vi He bng 7,5. Cho dung dch NaOH d vo Y, thu c 19,72
gam kt ta. Gi tr ca x l :
A. 0,10 B. 0,18 C. 0,16 D. 0,12
Cu 22: t chy 16,8 gam bt Fe trong V lt (ktc) hn hp kh gm Cl 2 v O2, thu c hn hp
rn X gm cc oxit v mui (khng thy kh thot ra). Ha tan X trong 480 ml dung dch HCl 1M,
thu c dung dch Y. Cho dung dch AgNO 3 d vo Y, thy thot ra 0,03 mol kh NO (sn phm
kh duy nht ca N +5), ng thi thu c 132,39 gam kt ta. Gi tr ca V l.
A. 6,272 lt B. 7,168 lt C. 6,720 lt D. 5,600 lt
Cu 23: Phn ng ha hc no sau y l sai ?
A. Ba(HCO3) t0
BaO + 2CO2 + H2O B. 2FeCl2 + Cl2 2FeCl3
C. Cr + NaOH + H 2O NaCrO2 + H2 D. Al(OH)3 + NaOH NaAlO 2 + 2H2O
Cu 24: Tin hnh in phn dung dch NaCl bng in cc tr, thu c mt kh X duy nht. iu
khng nh no sau y l ng ?
A. X l kh oxi B. X l kh clo
C. X l kh hiro D. C dng mng ngn xp
Cu 25: rut non ca c th ngi nh tc dng xc tc ca cc enzim nh lipaza v dch mt, cht
bo b thy phn thnh :
A. axit bo v glixerol B. axit cacboxylic v glixerol
C. CO2 v H2O D. NH3, CO2 v H2O
Cu 25: Chn A.
Qu trnh thy phn cht bo trong c th ngi xy ra nh sau :
0
t
(RCOO)3C3H5 + NaOH 3RCOONa+ C3H5(OH)3
Cu 26: t chy hon ton 1,53 gam este X thu c 3,3 gam CO 2 v 1,35 gam H 2O. Cng thc
phn t ca X l.
A. C4H6O2 B. C5H10O2 C. C4H8O2 D. C5H8O2
Cu 27: Th nghim no sau y thu c mui st (II).
A. t chy bt st trong kh clo.
B. Cho bt st vo lng d dung dch bc nitrat.
C. Cho natri kim loi vo lng d dung dch Fe (III) clorua.
D. t chy hn hp bt gm st v lu hunh trong iu kin khng c khng kh.
Cu 28: Cho cc este sau thy phn trong mi trng kim : C6H5COOCH3, HCOOCH=CH-CH3,
CH3COOCH=CH2, C6H5OOCCH=CH2, HCOOCH=CH2,C6H5OOCCH3, HCOOC2H5, C2H5OOCCH3.
C bao nhiu este khi thy phn thu c ancol
A. 3 B. 4 C. 5 D. 6
Cu 29: Nhng mt thanh magie vo dung dch c cha 0,8 mol Fe(NO 3)3 v 0,05 mol Cu(NO3)2 . Sau
mt thi gian, ly thanh kim loi ra, ra sch, cn li thy khi lng tng 11,6 gam so vi thanh kim
loi ban u. Khi lng magie phn ng l
A. 6,96 gam B. 20,88 gam C. 25,2 gam D. 24 gam
Cu 30: Pht biu no sau y khng ng ?
A. Cc peptit m phn t ch cha t 11 n 50 gc a -aminoaxit c gi l polipeptit.
B. Cc protein u l cht rn, nhit nng chy cao v d tan trong nc.
C. Peptit mch h phn t cha hai gc a -aminoaxit c gi l ipeptit.
D. Peptit mch h phn t cha hai lin kt peptit CO-NH c gi l ipeptit.

Trang 3
Cu 31: Cho 4,48 gam hn hp etyl axetat v phenyl axetat (c t l mol 1 : 1) tc dng ht vi 800 ml
dung dch NaOH 0,1M thu c dung dch X. C cn dung dch X, thu c m gam cht rn khan. Gi
tr m l :
A. 5,6 B. 4,88 C. 3,28 D. 6,4
Cu 32: ipeptit X c cng thc : NH2CH2CONHCH(CH3)COOH. Tn gi ca X l :
A. Alanylglixyl B. Alanylglixin C. glyxylalanin D. Glyxylalanyl
Cu 33: Hn hp X nng m gam gm mantozo v tinh bt. Chia X thnh hai phn bng nhau
-Phn 1 : Ha tan trong nc d, lc ly kt ta ri cho dung dch phn ng ht vi dung dch
AgNO3/NH3 d thu c 0,03 mol Ag
-Phn 2 : un nng vi dung dch H 2SO4 long thc hin phn ng thy phn. Hn hp sau phn
ng c trung ha bi dung dch NaOH sau cho ton b sn phm thu c tc dng ht vi
AgNO3/NH3 d thu c 0,192 mol Ag. Bit hiu sut phn ng thy phn t 60%. Gi tr ca m l :
A. 45,9 g B. 35,553 g C. 49,14 g D. 52,38 g
Cu 34: Vt liu polime no sau y c cha nguyn t nit?
A. Nha poli(vinyl clorua). B. T visco.
C. T nilon-6,6. D. Cao su buna.
Cu 35: Kim loi Cu khng tan trong dung dch
A. H2SO4 c nng. B. HNO3 c nng. C. HNO3 long. D. H2SO4 long.
Cu 36: Cho glucoz ln men thnh ancol etylic. Ton b kh CO 2 sinh ra trong qu trnh ny c hp
th ht vo dung dch Ca(OH)2 d to ra 50 gam kt ta, bit hiu sut qu trnh ln men t 80%. Khi
lng glucoz cn dng l
A. 33,70 gam. B. 56,25 gam. C. 20,00 gam. D. 90,00 gam.
Cu 37: Kim loi c con ngi dng ph bin ch to trang sc, c tc dng bo v sc kho l
A. st. B. st ty. C. bc. D. ng.
Cu 38: Mt mu kh thi c sc vo dung dch CuSO 4, thy xut hin kt ta mu en. Hin tng
ny do trong kh thi c ?
A. NO2. B. H2S. C. CO2. D. SO2.
Cu 39: un nng 100 gam dung dch glucoz 18% vi lng d dung dch AgNO3 trong NH3, n
khi phn ng xy ra hon ton thu c m gam Ag. Gi tr ca m l:
A. 16,2 gam. B. 32,4 gam. C. 21,6 gam. D. 10,8 gam.
Cu 40: un nng este CH3OOCCH=CH2 vi mt lng va dung dch NaOH, sn phm thu c
l:
A. CH2=CHCOONa v CH3OH. B. CH3COONa v CH2=CHOH.
C. CH3COONa v CH3CHO. D. C2H5COONa v CH3OH.

----------HT----------

Trang 4
 PHN TCH - HNG DN GII
THI TH THPT VNH BO LN 1

Cu 1: Chn B.
Vy X khng th l C2H5COOCH=CH2 v :
0
C2H5COOCH=CH2 + NaOH
t
C2H5COONa + CH3CHO
Cu 2: Chn A.
3,36 2n + n
- Rn ch cha Fe, c nFe =
BT:e
= 0,06 nMg = Fe FeCl3 = 0,12 mMg = 2,88(g)
56 2
Cu 3: Chn D.
Cu 4: Chn A.
2C2H4(OH)2 + Cu(OH)2 [C2H4(OH)O]2Cu(xanh lam) + H2O
2CH3COOH + Cu(OH)2 (CH3COO)2Cu(xanh lam) + 2H2O
GlyAlaGly to phc mu tm xanh vi Cu(OH) 2.
Cu 5: Chn C.
Bt ngt (m chnh) l mui mononatri ca axit glutamic (hay mononatri glutamat)
HOOC - CH2 - CH2CH(NH2 )COOH HOOC - CH2 - CH2CH(NH2)COONa
axit glutamic mononatri glutamat

Cu 6: Chn A.
Cu 7: Chn D.
- dung dch thu c tn ti cc ion Fe2+ v Fe3+ th
y
2nFe < nAgNO3 < 3nFe 2x < y < 3x 2 < < 3 2 < a < 3
x
Cu 8: Chn B.
quan h
- t X th
CO2 vH 2O
nX (kX - 1) = nCO2 - nH2O kX - 1= 8 kX = 9 = 3p C-O + 6p C-C
nBr2
- Cho a mol X tc dng vi Br2 th : a = = 0,1mol
6
Cu 9: Chn B.
Cu 10: Chn A.
Ca2+ + CO32- CaCO3 Mg2+ + CO32- MgCO3
Cu 11: Chn D.
A. 2Al + 3Fe 2 (SO 4 ) 3 Al 2 (SO 4 ) 3 + 6FeSO 4 . Nu Al d th 2Al + 3FeSO 4 Al 2 (SO 4 ) 3 + 3Fe
B. 2Al + 3Cu SO 4
Al 2 (SO 4 ) 3 + 3Cu
C. 2Al + 6HCl 2AlCl 3 + 3H 2
D. Al + MgCl2 khng xy ra phn ng
Cu 12: Chn B.
(CH3NH3)2CO3+ 2NaOH
Na2CO3+ 2CH3NH2 + H 2O
0,1mol 0,3mol 0,1mol 0,2mol

CnNaOH(d) = 0,1 mrn = 40nNaOH(d) + 106nNa2CO3 = 14,6(g)

Cu 13: Chn A.

Trang 5
 COOCH3

n CH2 C COOCH3 to, p, xt

CH2 C
n
CH3 CH3

Cu 14: Chn A.
0
t
(NH 4)2Cr2O7 Cr2O3(X) + N 2 + H2O
0
t
Cr2O3(X) + HCl CrCl 3(Y ) + H2O
CrCl 3(Y ) + Cl 2 + KOH K 2CrO4(Z) + KCl + H2O
K 2CrO4(Z) + H2SO4 K 2SO4 + K 2Cr2O7(T) + H2O
Cu 15: Chn A.
- Trong phng th nghim ta hay gp c ha cht c tc dng ht m nh: H2SO4 c, dung dch kim v
cc cht khan CuSO4, CaCl2, CaO, P2O5. Vy NaCl khng khng c tc dng ht m.
Cu 16: Chn C.
- Hng t duy 1 :
0,1mol 0,2mol 1,2mol 0,4mol
} 6 40,4mol
0,1mol 0,2mol
} 7 48 640,4m
7 4ol
8 } } } }
- Qu trnh: 1Zn , Mg + Cu(NO3)2 ,AgNO3 Zn2+ ,Mg2+ ,Cu2+ ,NO3- + Ag ,Cu
4 2 4 3 1 4 44 2 4 4 43 1 4 4 4 4 2 4 4 4 43 14 2 43
h
n h
p kl dd ddsau ph
nng(T) r
nX

BTDT
nNO - - 2nMg2+ + 2nZn2+ BT:Cu
nCu2+ (T) = 3
= 0,3mol
nCu(X) = nCu(NO3)2 - nCu2+ (T) = 0,1mol
(T) 2
BT:e
- Khi cho X tc dng vi HNO 3 th 2n Cu + n Ag = 3n NO n NO = 0, 2 mol VNO = 4, 48(l)
- Hng t duy 2: p dung bo ton e cho ton qu trnh phn ng
BT:e 2n Mg + 2n Zn
n NO = = 0, 2 VNO = 4, 48(l)
3
Cu 17: Chn B.
Thuc th
Anilin Glucoz Glixerol Fructoz
Cht
Dung dch
Khng c kt ta Ag Khng c kt ta Ag
AgNO3/NH3 un nh
Cu(OH)2 khng
Cu(OH)2, lc nh Dung dch xanh lam Dung dch xanh lam Dung dch xanh lam
tan
Mt mu nc
Mt mu nc Khng mt mu Khng mt mu
Nc brom brom v c kt
brom nc brom nc brom
ta trng
Cu 18: Chn A.
HCHO
2 3 ,CH
1 43COOH,
4 44 2HCOOCH
4 4 4 433 , HOCH CH ( OH ) CHO, CH CH ( OH ) COOH C n H 2n O n
- Quy i: 1CH O
1 4 4 24 4 4 4 4 4 2 4 43 4 4 4 4 4 4 3
2 C 2 H 4O 2 C 3H 6 O 3
(Lu : ta cng c th quy i C n H 2n O n thnh CH2O, v bn cht bi ton khng thay i).
6 4 44x7mol4 4 48 6 4 4 4 4y7mol4 4 4 4 8 6 4z7mol48
- Qu trnh: (C 2 H 5OH)C 2 H 6O , (CH 3COOC 2H 3 )C 4H 6O 2 , C n H 2n O n O
{2 CO 2 + H
{2O
14 4 4 4 4 4 4 4 4 44 2 4 4 4 4 4 4 4 4 4 4 43
13,8(g) X 0,5375 mol 0,5 mol

BTKL m X - 32n O 2 - 18n H 2O quan h

n CO 2 = = 0,5 mol
CO
y - x = nCO2 - nH2O y = x .
44 2 vH2O

Trang 6
 BT: C
2n C2H 6O + 4n C 4H 6O 2 + nn Cn H 2nO n = n CO 2 2x + 4x + nz = 0,5
y = 0,025 %m C4H 6O 2 = 15,58
m X = 46n C 2H6O + 86n C4H 6O 2 + 30n.n C n H 2n O n = m X 46x + 86x + 30nz = 13,8
Cu 19: Chn A.
(a) Mg + Fe 2 (SO 4 )3 MgSO 4 + 2FeSO 4
(b) H2S + FeCl3 FeCl2 + S + HCl
(c) KHSO4 + Ba(HCO3)2 K2SO4 + BaSO4 + CO2 + H2O
(d) K + H2O + Ca(H2PO4)2 Ca3(PO4)2 + K3PO4 + H2
(e) (NH4)2CO3 + Ba(OH)2 BaCO3 + NH3 + H2O
Vy c c 4 phn ng to kt ta l (b), (c), (d) v (e) khng sinh ra n cht.
Cu 20: Chn B.
0,01mol 0,06mol 0,015mol 0,03mol
6 78 }
Al, Al2O3 HNO3 3+ 2+
Al , Fe , Fe
3+ 67 8 678 N O, NO2
t0 t0
Fe
- Qu trnh: 1 44O , Al
3 42 4 43 Z + Fe 2 O3 , Al2O3 + T 2
Fe, Fe x O y - 1 44 2 4 43 O2 , H 2O
X NH 4 , NO3 5,46(g)

BT:O n H + - 2n O(X) - 4n NO
n O(X) = 4n Fe3O 4 = 0, 04 . Xt dung dch Z c n + = = 0, 015
NH 4 10
BT:N BT:Fe
n NO - = n HNO3 - n NH + - n NO = 0, 278 v nFe2+ + nFe3+ = 3nFe3O4 = 2nFe2O3 = 0,03
3 4
BT:Al
n Al = n Al3+ = 2n A l 2 O3 = 0,06 m Z = 56(n Fe 2+ + n Fe3+ ) + 24n Al3+ + 18n NH 4+ + 62n NO3- = 20,806(g)
BTKL
- Khi nung Z th mT = m Z - 160n Fe2O3 - 102n Al2O3 = 15,346 (g)
Cu 21: Chn C.
0,25157.19,08
- Theo bi ta c : nO(trong X) = = 0,3mol
16
- Khi cho dung dch tc dng vi NaOH d ta c : nMg2+ = nMg(OH)2 = 0,34mol
BTDT
3nAl3+ + nNH4+ = 2nSO42- - nNa+ - 2nMg2+ = 0,64
nAl = 0,2mol
- Xt dung dch Y c
27nAl + 18nNH4+ = mY - 96nSO42- - 23nNa+ - 24nMg2+ = 6,12 nNH4+ = 0,04mol

- Quy i hn hp rn X thnh Mg, Al, O v C. Xt hn hp rn X ta c
BT:C mX - 24nMg - 27nAl - 16nO
nMgCO3 = nC = = 0,06mol
12
- Quay li hn hp rn X vi Al, Al2O3, Mg v MgCO3 c : nMg = nMg2+ - nMgCO3 = 0,28mol
BT:O nO(trongX ) - 3nMgCO3
nAl2O3 = = 0,04mol nAl = nAl3+ - 2nAl 2O3 = 0,12mol
3
nCO2 + nN2O 2y
- Xt hn hp kh Z ta c : = nN2O = 2y - nCO2 = 2y - 0,06 nH2 = ymol
nH2 y
- Xt ton b qu trnh phn ng ca X vi dung dch cha 1,32 mol NaHSO 4 v x mol HNO3 c:
BT:H
nNaHSO4 + nHNO3 - 4nNH 4+ - 2nH 2
nH2O = = 0,5x - y + 0,58
2
BTKL
m+ 63nHNO3 + 120nNaHSO4 = mY + mZ + 18nH2O
19,08+ 63x + 120.1,32 = 171,36 + 90y + 18(0,5x - y + 0,58) 54x- 72y = 4,32(1)
BT:N
2nN2O + nNH4+ = nHNO3 2(2y- 0,06) + 0,04 = x x- 4y = -0,08(2)
- Gii h (1) v (2) ta c : x = 0,16 v y =0,06
Cu 22: Chn C.
- Gi x l s mol Cl 2. Khi cho hn hp X tc dng vi HCl th :

Trang 7
 nH+ nHCl - nH+ (d)
nO2 = = = 0,09mol (vi nH+ (d) = 4nNO = 0,24mol )
4 4
- Khi cho dung dch X tc dng vi AgNO 3 c: nAgCl = nCl - = 2nCl 2 + nHCl = 2x + 0,48

143,5nAgCl + 108nAg = m 143,5(2x + 0,48) + 108y = 132,39

x = 0,03
BT:e
nAg + 3nNO + 2nCl2 + 4nO2 = 3nFe 2x + y = 0,45 y = 0,21

Vy VCl2,O2 = (0,21+ 0,09).22,4 = 6,72(l)

Cu 23: Chn C.
- Cr khng tc dng c vi dung dch NaOH long.
Cu 24: Chn C.
- Khi in phn dung dch NaCl khng c mn ngn th:
pdd
2NaCl + 2H2O 2NaOH + H2 + Cl2 Cl2 + 2NaOH NaCl + NaClO + H2O
Vy kh thu c duy nht l H 2.
Cu 26: Chn B.
1,53 n =5
- Khi t chy X nhn thy: n CO 2 = n H 2O = 0, 075 mol M X = n X l C5H10O2
0, 075
Cu 27: Chn B.
o
t
A. 2Fe + 3Cl 2 2FeCl3
B. Fe + 3AgNO3 (d) Fe(NO3)3 + 3Ag
C. 6Na + 3H2O + 2FeCl 3
2Fe(OH)3 + 6NaCl + 3H2
o
D. Fe + S t
FeS
Cu 28: Chn A.
C este khi thy phn thu c ancol l C 6H5COOCH3, HCOOC2H5 v C2H5OOCCH3.
Cc este cn li khi thy phn thu c :
0
HCOOCH=CH-CH3 + NaOH
t
HCOONa + CH3CH2CHO
0
CH3COOCH=CH2 + NaOH
t
CH3COONa + CH3CHO
0
C6H5OOCCH=CH2 + 2NaOH
t
CH2=CH-COONa + C6H5ONa + H2O
0
HCOOCH=CH2 + NaOH
t
HCOONa + CH3CHO
0
C6H5OOCCH3 + 2NaOH t
CH3COONa + C6H5ONa + H2O
Cu 29: Chn C.
- Dung dch thu c sau phn ng gm Mg 2+, Fe2+, Cu2+ v NO3-.
- p dng phng php tng gim khi lng v bo ton e ta c :
n
mthanh KL tng = nFe(NO3)2(p).DM Fe-Mg + nCu(NO3)2 .DM Cu-Mg - Fe(NO3)3 .24
2
11,6 = 32nFe(NO3)2(p) + 40.0,05- 0,4.24 nFe(NO3)2(p) = 0,6mol
BT:e nFe(NO3)3 + 2nCu(NO3)2 + 2nFe(NO3)3(p) 0,8+ 2.0,05+ 2.0,6
nMg(p) = = = 1,05mol
2 2
- Vy mMg(p) = 1,05.24 = 25,2(g)
Cu 30: Chn C.
A. Sai, peptit c chia thnh hai loi :
* Oligopeptit gm cc peptit gm cc peptit c t 2 10 gc aminoaxit.
* Polipeptit gm cc peptit c t 11 n 50 gc aminoaxit. Polipeptit ca protein.
B. Sai, Protein c chia lm 2 loi : dng protein hnh si v protein hnh cu

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 Protein hnh cu gm : abumin (long trng trng g), hemoglobin (mu)
Protein hnh si gm : keratin (tc, mng, sng), fibroin (t tm, mng nhn)
- Tnh tan : Protein hnh si hon ton khng tan trong nc, ngc li cc protein hnh cu tan trong
nc to thnh dung dch keo.
C. ng, nu peptit c n mc xch th s c (n 1) lin kt peptit nn ipeptit s c 1 lin kt peptit.
D. Sai, peptit mch h phn t cha hai lin kt peptit CO-NH c gi l tripeptit.
Cu 31: Chn D.
- Theo bi ta c : nCH3COOC2H5 = nCH3COOC6H5 = 0,02mol
- Khi cho 4,48 gam hn hp trn tc dng vi 0,08 mol NaOH th : nH2O = nCH3COOC6H5 = 0,02mol
BTKL
mrn = mhn hp + 40nNaOH - 18nH2O = 6,4(g)
Cu 32: Chn D.
Cu 33: Chn C.
nAg
- Xt phn 1 ta c : nmantz= = 0,015mol
2
- Xt phn 2 ta c :
nAg = (4nmantz+ 2ntinh bt).H + 2nmantz(d) (4.0,015+ 2x).0,6+ 0,015.0,4.2 = 0,192 x = 0,12
Vy m = 2(342nmantz+ 162ntinh bt) = 49,14(g)
Cu 34: Chn C.
Cu 35: Chn D.
Cu 36: Chn B.
- Sc CO2 vo dung dch Ca(OH) 2 d th : nCO2 = nCaCO3 = 0,5mol
n
nC6H12O6 = CO2 = 0,3125mol mC6H12O6 = 56,25(g)
2H%
Cu 37: Chn C.
- Trong cc loi hng trang sc th bc c bit n ph bin nht vi hai chc nng chnh l: lm p
v trnh gi.
- i vi tr nh th bc c xem nh l ba h mnh. Chnh v vy, hu nh b no cng c eo cho
mt chic lc bc nh xinh trnh gi v theo di sc kho cho b.
- Trang sc bc d kiu no v u cng u c li cho sc kho.
- Ngoi kh nng trnh gi v co gi, bc cn c tc dng lu thng khp v ng tim mch.
Cu 38: Chn B.
- Phn ng: CuSO4 + H2S CuS den + H2SO4
Cu 39: Chn C.
m .C%
- Ta c: mAg = 108.nAg = 108.2. dd C6H12O6 .h% = 21,6(g)
180
Cu 40: Chn A.
- Phn ng: CH3OOCCH=CH2 + NaOH CH2=CHCOONa + CH3OH

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