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NM HC 2009 - 2010
thi chnh thc
( thi gm 02 trang)
(Cho H=1, C=12, N=14, O=16, Na=23, S=32, K =39, Fe=56, Cu=64, Zn=65, Ba =137)
- - - Ht - - -
H v tn th sinh:................................................................... S bo danh:.......................
S GD& T NGH AN K THI CHN HC SINH GII TNH LP 12
NM HC 2009 - 2010
Cu Ni dung im
Cu 1 3,0
a) Lp lun ra cng thc phn t ca E l C5H8O2 0,5
b) nE = nNaOH = 0,1 mol mNaOH = 4 (g) mE + mNaOH = mG 0,5
Vy E phi c cu to mch vng, cng thc cu to ca E l
CH2 CH2 C O
Cc phng trnh (2), (4) mi phng trnh cho 0,25 im, ring phng trnh (1), (3), (5)
v (6) mi phng trnh cho 0,5 im
Cu 3 4,0
1 2,0
Theo iu kin bi ra th X c hai cng thc cu to sau : 0,5
CH3OOCCH2CH2CHCOOC2H5 hoc :
NH2
C2H5OOCCH2CH2CHCOOCH3
NH2
Cc phng trnh ca phn ng :
CH3OOCCH2CH2CHCOOC2H5 + 2NaOH
0
t
0,5
NH2
NaOOCCH2CH2CHCOONa + CH3OH + C2H5OH
NH2
C2H5 OOCCH2CH2CH(NH2)COOCH3 +2NaOH
0
t
0,5
HOOCCH2CH2CHCOOH + 2NaCl
NH3Cl
2 2,0
A tc dng vi dung dch AgNO3 trong NH3 suy ra A c lin kt ba u mch. A tc dng 0,25
vi Br2/CCl4 theo t l mol 1:2. Vy A c hai lin kt gc hidrocacbon mch h.
Cng thc cu to ca A l : C6H5CH2C CH 0,25
0,25
Cc phng trnh phn ng :
C6H5CH2C CH + AgNO3 + NH3 t
C6H5CH2C CAg + NH4NO3
0
0,25
C6H5CH2C CH + 2Br2 C6H5CH2CBr2CHBr2
3C6H5CH2C CH +14 KMnO4 t
3C6H5COOK +5K2CO3+KHCO3 +14MnO2 + 4H2O
0 0,25
MnO2 + 4HCl MnCl2 + Cl2 + 2H2O
0
t
0,25
C6H5COOK + HCl C6H5COOH + KCl
K2CO3 + 2HCl 2KCl + H2O + CO2
0,25
KHCO3 + HCl KCl + H2O + CO2
0,25
Cu 4 3,0
Gi a, b, c l s mol ca K, Zn, Fe c trong hn hp Y. C hai trng hp :
Trng hp 1 : a > 2b : d KOH B ch c Fe
0,25
Phng trnh phn ng : Fe + Cu2+ Fe2+ + Cu
S mol Cu2+ = 0,1.3=0,3 mol
Nu Cu2+ kt ta ht th d Fe mCu=0,3.64=19,2 (gam) > 16 (gam) loi
16 0,25
Vy Cu2+ cha kt ta ht, Fe tan ht nFe=nCu= 0,25 (mol)
64 0,25
mB=0,25.56=14 (gam) < 14,45 (gam) loi
Trng hp 2 : a < 2b : KOH ht, Zn d B ch c Zn, Fe 0,25
2K + 2H2O 2KOH + H2
a a a/2 0,25
2KOH + Zn K2ZnO2 + H2
a a/2 a a/2 0,50
a a 6,72
S mol H2 = = 0,3( mol) a=0,3
2 2 22,4
(Nu th sinh vit phng trnh Zn v dung dch KOH dng phc vn cho im ti a)
a
mB =65(b ) +56c = 14,45 (1)
2 0,5
2+ 2+
Fe, Zn phn ng vi Cu c d Cu nn Fe, Zn ht
Zn + Cu2+ Zn2+ + Cu
Fe + Cu2+ Fe2+ + Cu
16 0,25
S mol Cu to ra = 0,25
64
a
b c 0,25 (2)
2
gii h phng trnh (1) v (2) ta c b = c = 0,2
Hn hp Y : mK=39.0,3 =11,7 (gam)
mZn=65.0,2 = 13,0 (gam)
mFe =56.0,2 = 11,2 (gam) 0,5
Cu 5 3,0
1 1,25
CH4 + Cl2
as
CH3Cl + HCl
C6H6 + CH3Cl AlCl C6H5CH3 + HCl
0
,t
3
+ iu ch pH2NC6H4COONa
C6H5CH3 + HNO3(c) HSO p-O2N-C6H4CH3 + H2O
0
,t
2 4
+ iu ch mH2NC6H4COONa
5C6H5CH3 + 6KMnO4 +9 H2SO4 5C6H5COOH +6MnSO4 + 3K2SO4 + 14H2O
0
t
OH 0,25
OH
OH
B + NaHCO3 CO2 Vy B c cng thc cu to :
COOH
0,25
b)
CHO
OH 0,25
A1 l
v A1 c lin kt H ni phn t, nn nhit si thp hn so vi 2 ng phn cn li
a) Phng trnh chuyn ha o-cresol thnh A1
o-HO-C6H4-CH3 + Cl2 as,1:1
o-HO-C6H4-CH2Cl + HCl
o-HO-C6H5-CH2Cl + 2NaOH o-NaO-C6H5-CH2OH + 2NaCl +H2O 0,5
0
t
Cu 6 4,0
1 2,0
Do sn phm cui cng khi cho hn hp tc dng vi HNO3 c nng c Fe3+, SO42- nn c
th coi hn hp ban u l Fe v S. Gi x v y l s mol ca Fe v S, s mol ca NO2 l a
Fe Fe+3 + 3e
x x 3x
+6 0,5
S S + 6e
y y 6y
+5 +4
N + e N
a a a
A tc dng vi Ba(OH)2
Fe3+ + 3OH- Fe(OH)3 0,5
Ba2+ + SO42- BaSO4
56x +32 y =20,8 x =0,2
Ta c h phng trnh Gii ra 0,5
107x +233y =91,3 y =0,3
Theo nh lut bo ton electron : 3x + 6y = a = 3.0,2 + 6.0,3 = 2,4
0,5
V = 2,4.22,4 = 53,76 (lt)
Khi lng Fe = 0,3m (g); khi lng rn A = 0,75 m(g). Suy ra lng Fe phn ng = 0,25
m Fe d ; Cu cha phn ng. Dung dch B cha Fe(NO3)2 , khng c Fe(NO3)3 v 0,5
Cu(NO3)2
nhn hpkh = 6,72/22,4= 0,3 mol
50.1,38.63 0,5
S mol HNO3 = 0,69 (mol)
100.63
2
Fe Fe+2 + 2e
NO3- + 3e NO
NO3- +e NO2
S mol NO3- to mui = 0,69 0,3 = 0,39 (mol) 1,0
1
Khi lng Fe(NO3)2 = .0,39(56 62.2) 35,1( g ) (gam)
2
Ghi ch : - Th sinh lm cch khc nhng ng vn cho im ti a,
- Phng trnh ha hc ghi thiu iu kin tr i s im.