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Prof
Mak214-E
Dr.C.Ergun, Asst.Prof
Mak214-E The effects of the alloying elements
Carbon (C): decreases the ductility, formability, weldability
increases the strength and hardenability.
Manganese (Mn): increases the strength, shock resistance,
toughness, hardenability, weldebility, hot formability, no change
in ductility. In addition Mn is a strong austenite former by
reducing the eutectoid temperature below to room temperature.
Handfield steel with 1% C and 12% Mn has strong deformation
hardening ability allowing increase in strength in service (helmets,
railway equipments, rock crushers jaws, shovel dippers, etc.)
Silicone (Si): increases strength, decreases the weldability,
magnetic losses, oxide formation affinity, no change in ductility.
In addition Si has higher affinity to O than carbon therefore used as
deoxizing agent (semi-killed steels). It is also austenite former
agent leading the nucleation of austenite grain in many size yielding
finer grain size. 2
Dr.C.Ergun, Asst.Prof
Mak214-E The effects of the alloying elements
Chromium (Cr): as the Cr content increases, strength, hardenability,
corrosion resistance, high temperature strength, decreases the oxide
formation tendency. (forms a very coherent oxide layer on the surface
preventing further oxidation-- in stainless steels).
It is also strong carbide former as an essential factor behaving as a strong
second phase particle, therefore, obstructs the dislocation motion
particularly at elevated temperatures. Also nitride former and used in
nitriding steels.
Nickel (Ni): increases the strength, toughness (even at sub zero
temperatures), hardenability, no change in ductility. It is an austenite
former, therefore, widely used in austenitic stainless steels.
Molybdenum (Mo): increases the hardenability, high temperature
strength, decreases the risk for temper embritterment (~0.5 % Mo).
Since the melting point of molybdenum carbide is very high, it provides
high temperature strength which is very useful in some HSS (high speed
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steel) tools.
Dr.C.Ergun, Asst.Prof
Mak214-E The effects of the alloying elements
Dr.C.Ergun, Asst.Prof
Mak214-E The effects of the alloying elements
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Dr.C.Ergun, Asst.Prof
Mak214-E
Designation - Coding system Coding system
of Steels
1. Symbols based on the Processing method:
Carbon Reduction processes Turkish and German
Thomas Process (T)
Basic Oxygen (O)
Simens Martin (M)
Electric arc (E)
Induction Furnace (I) American
Solidification Process TS DIN
Rimmed (K) (U)
Semi killed (Si) (SY) (R)
Killed (Si + Al) (S)
American Standards
Symbols based on: Carbon and Low alloy (1040)
2. Mechanical Properties (Tensile) Stainless steel (316)
Tool steels (T1)
(construction steels) FeXX or StXX
3. Chemical Composition
a. Plain carbon (C35)
b. Low alloy (15CrMo5)
c. Free Cutting (22S20)
d. Alloy steels (X 50 CrMoW 9 11) 7
Dr.C.Ergun, Asst.Prof
Mak214-E
2. Construction Steels Fe XX (or St XX)
Minimum tensile
Constructional
Fe14 ??? strength in Kgf/mm2
Steel
8
Dr.C.Ergun, Asst.Prof
Mak214-E
3. Chemical Composition
(b) Low alloy steels
C % content
x 100 % of the highest
Alloying element content element
ordered with x MF
respect to amount
Dr.C.Ergun, Asst.Prof
Mak214-E
15 CrMo 5 1.25 % Cr
content
0.15 % C
Carbon
Semi Killed Steel 10
Dr.C.Ergun, Asst.Prof
Mak214-E
3. Chemical Composition
(c) Free cutting steels
S
C % content
x 100 Free cutting S % multiplied
Steel by 100
Alloying element
other than C and S
0.22 % C 22 S MnPb 36
22 S 20
Free
Cutting 0.22 % C
Steel 0.36 % S 0.2 % S
11
Dr.C.Ergun, Asst.Prof
Mak214-E
3. Alloy steel: If total alloying element content is higer
than 5%.
X % Alloying
Simens elements
Martin without factors
Alloying
C % Content elements
x 100 other than C
High 18 % Cr
High 9% Ni
X 50 CrMoW 9 1 1 Alloy
Alloy <1% Ti
Steel
Steel
Main Alloying 9 % Cr
0.5 % C 1% Mo X 5 CrNiTi 18 9
elements Cr,
Mo, W 1% W
Cr, Mo, Ti
0.05 % C 12
Dr.C.Ergun, Asst.Prof
American Standards
Mak214-E
Stainless Steels
Three digit designation
3xx Austenitic stainless steel 304, 316, 321, etc.
4xx Ferritic and/or Martensitic Stainless steel, 410, 430 (ferritic),
440 (martensitic), 13
Dr.C.Ergun, Asst.Prof
Tool Steels
Mak214-E
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Dr.C.Ergun, Asst.Prof
Mak214-E
Types of Steels
Constructional steels:
Profiles ( Fe37, Fe 42, Fe 50, 1010, 1020, 1040, etc.),
Sheet or plates -deep drawing quality ( low carbon, fine grain), thin plate, galvanize, plates for ship
buildings.
Heat treatable steels (for combination of strength and ductility)
Carbon steels
Low Alloy steels (alloyed less than 5%)
Carburizing steels (low carbon steels for case hardening)
Nitriding steels (alloyed with nitride formers such as Al and Cr)
Free cutting steels: (To be easiliy cut by tools: high machinability, high S content)
Spring steels (0.5-0.6 C and good hardenability and elastic properties)
Bolt steels (Good cold formability for thread rolling)
High temperature steels: For boilers and pipes
Sub zero steels (shows no DBTT, generally austenitic steels)
Valve steels (high strength, good toughness and ductility)
Stainless steel (Ferritic, Martensitic, Austenitic, Precipitation Hardening)
Tools steels (Hot work and Cold work Tool steel, High speed steels)
Ball bearing steels
Electrical steels Extra low C with Si up to 3%.
Non-magnetizable steels -austenitic steels
High strength low alloy steels (HSLA) micro alloyed with V or Nb etc. Common in automotive industry.
Dual phase steels (contains martensite in ferrite matrix, obtained with inter-critical range annealing and
quenching, widely demanded for transport vehicles)
Maraging steels ( ultra high strength as a result of martensitic transformation and following aging
treatment)
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Cast steels:
Dr.C.Ergun, Asst.Prof
Mak214-E
Designation - Coding system Coding system
of Steels
1. Symbols based on the Processing method:
Carbon Reduction processes Turkish and German
Thomas Process (T)
Basic Oxygen (O)
Simens Martin (M)
Electric arc (E)
Induction Furnace (I) American
Solidification Process TS DIN
Rimmed (K) (U)
Semi killed (Si) (SY) (R)
Killed (Si + Al) (S)
American Standards
Symbols based on: Carbon and Low alloy (1040)
2. Mechanical Properties (Tensile) Stainless steel (316)
Tool steels (T1)
(construction steels) FeXX or StXX
3. Chemical Composition
a. Plain carbon (C35)
b. Low alloy (15CrMo5)
c. Free Cutting (22S20)
d. Alloy steels (X 50 CrMoW 9 11) 16
Dr.C.Ergun, Asst.Prof
Mak214-E
2. Construction Steels Fe XX (or St XX)
Minimum tensile
Constructional
Fe14 ??? strength in Kgf/mm2
Steel
17
Dr.C.Ergun, Asst.Prof
Mak214-E
3. Chemical Composition
(b) Low alloy steels
C % content
x 100 % of the highest
Alloying element content element
ordered with x MF
respect to amount
18
Dr.C.Ergun, Asst.Prof
Mak214-E
15 CrMo 5 1.25 % Cr
content
0.15 % C
Carbon
Semi Killed Steel 19
Dr.C.Ergun, Asst.Prof
Mak214-E
3. Chemical Composition
(c) Free cutting steels
S
C % content
x 100 Free cutting S % multiplied
Steel by 100
Alloying element
other than C and S
0.22 % C 22 S MnPb 36
22 S 20
Free
Cutting 0.22 % C
Steel 0.36 % S 0.2 % S
20
Dr.C.Ergun, Asst.Prof
Mak214-E
3. Alloy steel: If total alloying element content is higer
than 5%.
X % Alloying
Simens elements
Martin without factors
Alloying
C % Content elements
x 100 other than C
High 18 % Cr
High 9% Ni
X 50 CrMoW 9 1 1 Alloy
Alloy <1% Ti
Steel
Steel
Main Alloying 9 % Cr
0.5 % C 1% Mo X 5 CrNiTi 18 9
elements Cr,
Mo, W 1% W
Cr, Mo, Ti
0.05 % C 21
Dr.C.Ergun, Asst.Prof
American Standards
Mak214-E
Stainless Steels
Three digit designation
3xx Austenitic stainless steel 304, 316, 321, etc.
4xx Ferritic and/or Martensitic Stainless steel, 410, 430 (ferritic),
440 (martensitic), 22
Dr.C.Ergun, Asst.Prof
Tool Steels
Mak214-E
23
Dr.C.Ergun, Asst.Prof
Mak214-E
Types of Steels
1. Constructional steels
2. Heat treatable steels
3. Carburizing steels
4. Nitriding steels
5. Free cutting steels
6. Spring steels
7. Bolt steels
8. High temperature steels
9. Sub-zero steels
10. Valve steels
11. Stainless steels
12. Tool steels
13. Bolt steels
14. Electrical steels
15. Non-magnetizable steels
16. HSLA steels
17. Dual phase steels
18. Maraging steels
19. Cast steels
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Dr.C.Ergun, Asst.Prof
Mak214-E
Coding systems of Steels
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Dr.C.Ergun, Asst.Prof
Mak214-E
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Dr.C.Ergun, Asst.Prof
Mak214-E
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Dr.C.Ergun, Asst.Prof
Mak214-E
Why subzero?
Which elements
are improtant?
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Dr.C.Ergun, Asst.Prof
Mak214-E
Which elements
should be dominant?
Which elements
should be dominant?
How can a PH SS be
strenghtened?
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Dr.C.Ergun, Asst.Prof
Mak214-E
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Dr.C.Ergun, Asst.Prof
Mak214-E
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Dr.C.Ergun, Asst.Prof
Mak214-E
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Dr.C.Ergun, Asst.Prof
Mak214-E
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Dr.C.Ergun, Asst.Prof
Mak214-E
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Dr.C.Ergun, Asst.Prof
Mak214-E
Heat treatments!!!!
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Dr.C.Ergun, Asst.Prof
37
Dr.C.Ergun, Asst.Prof
Mak214-E
A Basic Heat Treatment Cycle
800
Treatment
Important Process Temperature
Temperature (C, F, K, etc.)
Parameters 600
Heating rate
Holding time
Holding temperature 400
Holding time
Cooling rate 200
Cooling rate
0
Heating rate 0 1 2 3
Time (day, hr, min, sec, etc.)
TTT
(Time temperature transformation)
Diagrams
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Dr.C.Ergun, Asst.Prof
Mak214-E TTT diagrams
Fs: Ferrite start temp.
Ps: Pearlite start temp.
Pf: Pearlite finish temp.
Bs: Bainite start temp.
Bf: Bainite finish temp.
Ms: Martensite start temp.
Mf: Martensite finish temp.
Phase areas
Coarse Pearlite
Fine Pearlite
Upper Bainite
Lower Bainite
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Dr.C.Ergun, Asst.Prof
Mak214-E
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Dr.C.Ergun, Asst.Prof
Mak214-E
TTT diagrams: Isothermal heat treatment curves.
Hypoeutoctoid Steel
Wing for ferrite start
temperatures.
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Dr.C.Ergun, Asst.Prof
Mak214-E
TTT diagrams: Isothermal heat treatment curves.
Fe3C
Hypereutoctoid Steel Wing for cementite
start temperatures.
+ Fe3C
Dr.C.Ergun, Asst.Prof
Mak214-E
Phase transformation
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Dr.C.Ergun, Asst.Prof
Mak214-E
TTT Curves
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Dr.C.Ergun, Asst.Prof
Mak214-E
Kritik souma hz
Scaklk (oC)
Perlit +
Martenzit nce perlit Kaba perlit
Martenzit
Zaman (s)
The cooling rate that just misses the nose is called the critical cooling rate (CCR).
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If we cool at the critical rate, or faster, the steel will transform to 100% martensite.
Dr.C.Ergun, Asst.Prof
Mak214-E
Isothermal cooling
Because C-curves are determined by quenchholdquench
sequences they can, strictly speaking, only be used to predict the
microstructures that would be produced in a steel subjected to a
quenchholdquench heat treatment. But the curves do give a pretty
good indication of the structures to expect in a steel that has been
cooled continuously.
Continues cooling
For really accurate predictions, however, continuous cooling
diagrams are available (see the literature of the major steel
manufacturers).
47
Dr.C.Ergun, Asst.Prof
Mak214-E
Continuous Cooling curves (CCC) vs. Isothermal Cooling curves
TTT Diagrams
zet
Yava
Mechanical Prop vs.
Austenite Souma
Peartlite (+Fe3C) Microstructure
Yaynmal
Ferrite
Hardness
Coarse Pearlite
zotermal
Dnm Fine Pearlite
Austenite Bainite (+Fe3C)
Yaynmal Upper Bainite
Lower Bainite
ok hzl Martensite
Souma
Austenite Martensite (single)
Yaynmasz
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Dr.C.Ergun, Asst.Prof
Mak214-E
Dr.C.Ergun, Asst.Prof
Mak214-E
Hardenability Curves and
Jominy Tests
Jominy test - The test used to evaluate
hardenability. An austenitized steel bar is
quenched at one end only, thus producing a
range of cooling rates along the bar.
Hardenability curves - Graphs showing the
effect of the cooling rate on the hardness of as-
quenched steel.
Jominy distance - The distance from the
quenched end of a Jominy bar. The Jominy
distance is related to the cooling rate.
Dr.C.Ergun, Asst.Prof
Mak214-E
A Practical Result of Cooling Rate:
Weldability of Steel
Figure 12.29 The
development of the
heat-affected zone
in a weld: (a) the
structure at the
maximum
temperature, (b) the
structure after
cooling in a steel of
low hardenability,
and (c) the
structure after
cooling in a steel of
high hardenability. 54
Example 12.8
Dr.C.Ergun, Asst.Prof
Mak214-E
4340
Structures of Heat-
Affected Zones
Compare the structures in
the heat-affected zones
of welds in 1080 and
4340 steels if the cooling
rate in the heat-affected
zone is 5oC/s.
1080
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Dr.C.Ergun, Asst.Prof
Mak214-E
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Dr.C.Ergun, Asst.Prof