S GD& T NGH AN K THI CHN HC SINH GII TNH LP 12

NM HC 2009 - 2010
thi chnh thc
( thi gm 02 trang)

Mn thi: HO HC - THPT BNG B

Thi gian: 180 pht (khng k thi gian giao )
Cu 1 (3,0 im).
t chy hon ton 1,60 gam mt este n chc E thu c 3,52 gam CO 2 v 1,152 gam
nc
a. Tm cng thc phn t ca E.
b. Cho 10 gam E tc dng vi NaOH va , c cn dung dch sau phn ng thu c 14
gam cht rn khan G. Cho G tc dng vi dung dch H 2SO4 long thu c G1 khng phn
nhnh. Tm cng thc cu to ca E v vit cc phng trnh phn ng.
c. X l mt ng phn ca E, X tc dng vi NaOH to ra mt ancol m khi t chy hon
ton mt th tch hi ancol ny cn 3 th tch kh O 2 o cng iu kin (nhit v p sut).
Xc nh cng thc cu to v gi tn ca X.
Cu 2 (3,0 im).
Sc kh A vo dung dch cha cht B ta c rn C mu vng v dung dch D.
Kh X c mu vng lc tc dng vi kh A to ra C v F. Nu X tc dng vi kh A trong
nc to ra Y v F, ri thm BaCl 2 vo dung dch th c kt ta trng. A tc dng vi dung dch
cht G l mui nitrat kim loi to ra kt ta H mu en. t chy H bi oxi ta c cht lng I
mu trng bc.
Xc nh A, B, C, F, G, H, I, X, Y v vit phng trnh ha hc ca cc phn ng.
Cu 3 (4,0 im.
1. Cht X c cng thc phn t C8H15O4N. T X c hai bin ha sau:
C8H15O4N dungdichNa C5H7O4NNa2 + CH4O + C2H6O
0
OH ,t

C5H7O4NNa2 C5H10O4NCl + NaCl

dungdichHCl

Bit : C5H7O4NNa2 c mch cacbon khng phn nhnh v c nhm NH 2 v tr . Xc nh

cng thc cu to c th c ca X v vit phng trnh ha hc ca cc phn ng theo hai bin ha
trn di dng cng thc cu to.
2. Hp cht A c cng thc C 9H8 c kh nng kt ta vi dung dch AgNO 3 trong NH3 v
phn ng vi brom trong CCl4 theo t l mol 1 : 2. un nng A vi dung dch KMnO 4 ti khi
ht mu tm, ri thm lng d dung dch HCl c vo hn hp sau phn ng thy c kt ta
trng l axit benzoic ng thi gii phng kh CO2 v Cl2. Xc nh cng thc cu to ca A v
vit phng trnh ha hc ca cc phn ng xy ra.
Cu 4 (3,0 im).
Cho hn hp Y gm ba kim loi K, Zn, Fe vo nc d thu c 6,72 lt kh (ktc) v cn
li cht rn B khng tan c khi lng 14,45 gam. Cho B vo 100 ml CuSO 4 3M, thu c
cht rn C c khi lng 16,00 gam. Xc nh khi lng mi kim loi trong Y?
Cu 5 (3,0 im.)
1. T kh thin nhin v cc cht v c cn thit, thit b phn ng y . Hy vit phng
trnh iu ch cc cht sau : mH2NC6H4COONa v pH2NC6H4COONa
2. Hai hp cht thm A v B l ng phn c cng thc phn t C nH2n-8O2. Hi B c khi
lng ring 5,447 gam/lt ( ktc). A c kh nng phn ng vi Na gii phng H 2 v c phn
ng trng gng. B phn ng c vi NaHCO3 gii phng kh CO2.
a) Vit cng thc cu to ca A v B.
b) Trong cc cu to ca A c cht A 1 c nhit si nh nht. Hy xc nh cng thc cu
to ng ca A1.
c) Vit cc phng trnh phn ng chuyn ha ocrezol thnh A1.
Cu 6 (4,0 im).
1.Cho 20,80 gam hn hp Fe, FeS, FeS 2, S tc dng vi dung dch HNO 3 c nng d thu
c V lt kh NO2 (l sn phm kh duy nht, o ktc) v dung dch A. Cho A tc dng vi
dung dch Ba(OH)2 d thu c 91,30 gam kt ta. Tnh V?
2. Cho m gam hn hp hai kim loi Fe, Cu (trong Fe chim 30% v khi lng) vo 50
ml dung dch HNO3 nng 63% (d = 1,38 gam/ml) un nng, khuy u hn hp ti cc
phn ng hon ton thu c rn A cn nng 0,75 m gam, dung dch B v 6,72 lt hn hp kh
NO2 v NO ( ktc). Hi c cn dung dch B th thu c bao nhiu gam mui khan ? (Gi s
trong qu trnh un nng HNO3 bay hi khng ng k)

(Cho H=1, C=12, N=14, O=16, Na=23, S=32, K =39, Fe=56, Cu=64, Zn=65, Ba =137)
- - - Ht - - -

H v tn th sinh:................................................................... S bo danh:.......................
 S GD& T NGH AN K THI CHN HC SINH GII TNH LP 12
NM HC 2009 - 2010

HNG DN V BIU IM CHM THI CHNH THC

Mn thi: HO HC - THPT BNG B
(Hng dn v biu im gm 04 trang)

Cu Ni dung im
Cu 1 3,0
a) Lp lun ra cng thc phn t ca E l C5H8O2 0,5
b) nE = nNaOH = 0,1 mol mNaOH = 4 (g) mE + mNaOH = mG 0,5
Vy E phi c cu to mch vng, cng thc cu to ca E l
CH2 CH2 C O

CH2 CH2 O 0,5

CH2 CH2 C O
0,25
+ NaOH HO - (CH2)4 - COONa
CH2 CH2 O
2HO-(CH2)4-COONa + H2SO4 2HO-(CH2)4-COOH + Na2SO4 0,25
(G1)
c) Ancol sinh ra do thy phn X l C2H5OH 0,75
Vy cng thc cu to ca X l CH2=CHCOOC2H5 (etyl acrylat) 0,25
Cu 2 3,0

A : H2S; B : FeCl3; C : S ; F : HCl ; G : Hg(NO3)2 ; H : HgS ; I : Hg ;

X : Cl2 ; Y : H2SO4 0,5
Khng cn l lun ch cn xc nh ng cc cht v vit phng trnh cho im ti a

Phng trnh ha hc ca cc phn ng :

H2S + 2FeCl3 2FeCl2 + S + 2HCl (1)
Cl2 + H2S S + 2HCl (2)
4Cl2 + H2S + 4H2O 8HCl + H2SO4 (3)
BaCl2 + H2SO4 BaSO4 + 2HCl (4) 2,5
H2S + Hg(NO3)2 HgS + 2HNO3 (5)
HgS + O2 Hg + SO2 (6)
0
t

Cc phng trnh (2), (4) mi phng trnh cho 0,25 im, ring phng trnh (1), (3), (5)
v (6) mi phng trnh cho 0,5 im
Cu 3 4,0
1 2,0
Theo iu kin bi ra th X c hai cng thc cu to sau : 0,5
CH3OOCCH2CH2CHCOOC2H5 hoc :

NH2
C2H5OOCCH2CH2CHCOOCH3

NH2
 Cc phng trnh ca phn ng :
CH3OOCCH2CH2CHCOOC2H5 + 2NaOH
0

t

0,5
NH2
NaOOCCH2CH2CHCOONa + CH3OH + C2H5OH

NH2
C2H5 OOCCH2CH2CH(NH2)COOCH3 +2NaOH
0
t

NaOOCCH2CH2CH(NH2)COONa + CH3OH + C2H5OH

NaOOCCH2CH2CH(NH2)COONa + 3HCl
0
t

0,5
HOOCCH2CH2CHCOOH + 2NaCl

NH3Cl

2 2,0
A tc dng vi dung dch AgNO3 trong NH3 suy ra A c lin kt ba u mch. A tc dng 0,25
vi Br2/CCl4 theo t l mol 1:2. Vy A c hai lin kt gc hidrocacbon mch h.
Cng thc cu to ca A l : C6H5CH2C CH 0,25
0,25
Cc phng trnh phn ng :

C6H5CH2C CH + AgNO3 + NH3 t
C6H5CH2C CAg + NH4NO3
0
0,25

C6H5CH2C CH + 2Br2 C6H5CH2CBr2CHBr2

3C6H5CH2C CH +14 KMnO4 t
3C6H5COOK +5K2CO3+KHCO3 +14MnO2 + 4H2O
0 0,25
MnO2 + 4HCl MnCl2 + Cl2 + 2H2O
0
t

0,25
C6H5COOK + HCl C6H5COOH + KCl
K2CO3 + 2HCl 2KCl + H2O + CO2
0,25
KHCO3 + HCl KCl + H2O + CO2
0,25
Cu 4 3,0
Gi a, b, c l s mol ca K, Zn, Fe c trong hn hp Y. C hai trng hp :
Trng hp 1 : a > 2b : d KOH B ch c Fe
0,25
Phng trnh phn ng : Fe + Cu2+ Fe2+ + Cu
S mol Cu2+ = 0,1.3=0,3 mol
Nu Cu2+ kt ta ht th d Fe mCu=0,3.64=19,2 (gam) > 16 (gam) loi
16 0,25
Vy Cu2+ cha kt ta ht, Fe tan ht nFe=nCu= 0,25 (mol)
64 0,25
mB=0,25.56=14 (gam) < 14,45 (gam) loi
Trng hp 2 : a < 2b : KOH ht, Zn d B ch c Zn, Fe 0,25
2K + 2H2O 2KOH + H2
a a a/2 0,25
2KOH + Zn K2ZnO2 + H2
a a/2 a a/2 0,50
a a 6,72
S mol H2 = = 0,3( mol) a=0,3
2 2 22,4
(Nu th sinh vit phng trnh Zn v dung dch KOH dng phc vn cho im ti a)
 a
mB =65(b ) +56c = 14,45 (1)
2 0,5
2+ 2+
Fe, Zn phn ng vi Cu c d Cu nn Fe, Zn ht
Zn + Cu2+ Zn2+ + Cu
Fe + Cu2+ Fe2+ + Cu
16 0,25
S mol Cu to ra = 0,25
64
a
b c 0,25 (2)
2
gii h phng trnh (1) v (2) ta c b = c = 0,2
Hn hp Y : mK=39.0,3 =11,7 (gam)
mZn=65.0,2 = 13,0 (gam)
mFe =56.0,2 = 11,2 (gam) 0,5

Cu 5 3,0
1 1,25
CH4 + Cl2
as
CH3Cl + HCl
C6H6 + CH3Cl AlCl C6H5CH3 + HCl
0
,t
3

+ iu ch pH2NC6H4COONa
C6H5CH3 + HNO3(c) HSO p-O2N-C6H4CH3 + H2O
0
,t
2 4

5 p-O2N-C6H4CH3 + 6KMnO4 +9 H2SO4 t

5 p-O2N-C6H4COOH +6MnSO4 + 3K2SO4 +
0
0,75
14H2O
p-O2N-C6H4COOH + 6H FeHCl p-H2N-C6H4COOH + 2H2O
p-H2N-C6H4COOH + NaOH p-H2N-C6H4COONa + H2O

+ iu ch mH2NC6H4COONa
5C6H5CH3 + 6KMnO4 +9 H2SO4 5C6H5COOH +6MnSO4 + 3K2SO4 + 14H2O
0
t

C6H5COOH + HNO3(c) HSO m-O2N-C6H4COOH + H2O 0,5

0
,t 2 4

m-O2N-C6H4COOH + 6H p-H2N-C6H4COOH + 2H2O

FeHCl

m-H2N-C6H4COOH + NaOH p-H2N-C6H4COONa + H2O

(iu ch c mi cht cho 0,5 im. Lm cch khc nhng ng cho im ti a)
2 1,75
a) MB =5,447.22,4 = 122 (gam) 14n + 24 = 122 n = 7. Vy cng thc phn t ca A v
0,25
B l C7H6O2
A + Na H2
0,25
A + AgNO3/NH3 A tp chc c 1 nhm OH v 1 nhm CHO
A c ba cng thc cu to :
CHO CHO CHO

OH 0,25

OH
OH
B + NaHCO3 CO2 Vy B c cng thc cu to :
COOH
0,25
 b)
CHO

OH 0,25
A1 l
v A1 c lin kt H ni phn t, nn nhit si thp hn so vi 2 ng phn cn li
a) Phng trnh chuyn ha o-cresol thnh A1
o-HO-C6H4-CH3 + Cl2 as,1:1
o-HO-C6H4-CH2Cl + HCl
o-HO-C6H5-CH2Cl + 2NaOH o-NaO-C6H5-CH2OH + 2NaCl +H2O 0,5
0
t

o-NaO-C6H5-CH2OH + CuO o-NaO-C6H5-CHO + H2O + Cu

0
t

o-NaO-C6H5-CHO + HCl o-HO-C6H5-CHO + NaCl

0
t

Cu 6 4,0
1 2,0
Do sn phm cui cng khi cho hn hp tc dng vi HNO3 c nng c Fe3+, SO42- nn c
th coi hn hp ban u l Fe v S. Gi x v y l s mol ca Fe v S, s mol ca NO2 l a
Fe Fe+3 + 3e
x x 3x
+6 0,5
S S + 6e
y y 6y
+5 +4
N + e N
a a a
A tc dng vi Ba(OH)2
Fe3+ + 3OH- Fe(OH)3 0,5
Ba2+ + SO42- BaSO4
56x +32 y =20,8 x =0,2
Ta c h phng trnh Gii ra 0,5
107x +233y =91,3 y =0,3
Theo nh lut bo ton electron : 3x + 6y = a = 3.0,2 + 6.0,3 = 2,4
0,5
V = 2,4.22,4 = 53,76 (lt)
Khi lng Fe = 0,3m (g); khi lng rn A = 0,75 m(g). Suy ra lng Fe phn ng = 0,25
m Fe d ; Cu cha phn ng. Dung dch B cha Fe(NO3)2 , khng c Fe(NO3)3 v 0,5
Cu(NO3)2
nhn hpkh = 6,72/22,4= 0,3 mol
50.1,38.63 0,5
S mol HNO3 = 0,69 (mol)
100.63
2
Fe Fe+2 + 2e
NO3- + 3e NO
NO3- +e NO2
S mol NO3- to mui = 0,69 0,3 = 0,39 (mol) 1,0
1
Khi lng Fe(NO3)2 = .0,39(56 62.2) 35,1( g ) (gam)
2
Ghi ch : - Th sinh lm cch khc nhng ng vn cho im ti a,
- Phng trnh ha hc ghi thiu iu kin tr i s im.