Safety Data Sheet in accordance with Regulation (EC) No

1907/2006
Arkofix ELF liq c Page 1

Substance key: 000000312612 Revision Date: 04.06.2009

Version : 3 - / EU Date of printing : 14.09.2009

1. Identification of the substance/preparation and of the company/undertaking

Trade name
Arkofix ELF liq c
Material number: 230161
Use of the substance/preparation.
Industry sector : Textile processing industry
Type of use : Textile finishing
Identification of the company
Clariant Production (France)

Usine de Lamotte
60350 Trosly Breuil
Telephone no. : +33 3 44 85 40 00
Information about the substance/preparation
Product Safety Dpt.
tel.: +33 1 46 96 97 82
e-mail: France.ProductSafety@clariant.com
Emergency telephone number : +33 1 45 42 59 59 (24 h)

2. Hazards identification
Does not require a hazard warning label, but the normal safety precautions for handling
chemicals must be observed.

3. Composition/information on ingredients
Chemical characterization
N-Methyloldihydroxyethylenurea modified aqueous medium

Hazardous ingredients
Methanol
Concentration : <= 3 %
CAS number : 67-56-1
EINECS number : 200-659-6
Hazard symbols F T
R phrases 11 23/24/25 39/23/24/25
Diethylene glycol
Concentration : <= 25 %
CAS number : 111-46-6
EINECS number : 203-872-2
Hazard symbols Xn
R phrases 22
The text of the R-phrases is shown in section 16.

4. First aid measures

Safety Data Sheet in accordance with Regulation (EC) No
1907/2006
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Substance key: 000000312612 Revision Date: 04.06.2009

Version : 3 - / EU Date of printing : 14.09.2009

General information
Remove soiled or soaked clothing immediately
After inhalation
When inhaled remove to fresh air and seek medical aid.
After contact with skin
In case of contact with skin wash off immediately with plenty of water
After contact with eyes
In case of contact with eyes rinse thoroughly with plenty of water and seek medical advice
After ingestion
Call in a physician immediately and show him the Safety Data Sheet.

5. Fire-fighting measures
Suitable extinguishing media
Product itself is non-combustible; Fire extinguishing method of surrounding areas must be
discussed.
Special hazards from the substance itself, its combustion products or from its vapours
In the event of fire the following can be released:
Carbon dioxide (CO2)
Carbon monoxide (CO)
Special protective equipment for firefighting
Use self-contained breathing apparatus
Wear full protective suit.
Further information
Fire residues must be disposed of in a proper manner

6. Accidental release measures

Personal precautions
Ensure adequate ventilation.
Environmental precautions
Do not allow to enter drains or waterways
Methods for cleaning up/taking up
Cover with absorbent material (eg sand, peat, earth) and then pick it up.
Dispose of contaminated material as prescribed

7. Handling and storage

Safety Data Sheet in accordance with Regulation (EC) No
1907/2006
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Substance key: 000000312612 Revision Date: 04.06.2009

Version : 3 - / EU Date of printing : 14.09.2009

Advice on safe handling

It cannot be ruled out, that traces of following substances are present.
Formaldehyde
Ensure adequate ventilation.
Local exhaust ventilation.
It cannot be ruled out, that traces of following substances are present.
Methanol
Formaldehyde
Ensure adequate ventilation.
Local exhaust ventilation.
Advice on protection against fire and explosion
Observe the general rules of industrial fire protection
Requirements for storage rooms and vessels
Keep only in the original container
Further information on storage conditions
Keep container tightly closed in a cool, well-ventilated place
Storage temperature should not exceed 40 C
- sensitive to frost - In case of the product becoming opaque, thickening or being frozen due
to the effects of cold, allow to thaw slowly at room temperature. Stir briefly before use.
Storage stability
Storage period up to 12 months

8. Exposure controls / personal protection

Occupational exposure controls
Exposure limit values
Methanol
CAS number : 67-56-1
Directive on indicative exposure limits (amended)
EU OEL - Directive on indicative exposure limits
Revision : 07/02/2006
Time-weighted average (8 hrs)
Values: 260 mg/m3 200 ppm
Methanol
CAS number : 67-56-1
Directive on indicative exposure limits (amended)
EU OEL - Directive on indicative exposure limits
Revision : 07/02/2006
Notations
Skin
Methanol
CAS number : 67-56-1
Directive on indicative exposure limits (amended)
EU OEL - Directive on indicative exposure limits
Revision : 29/05/1991
Threshold Limit Values
Values: 260 mg/m3 200 ppm
Safety Data Sheet in accordance with Regulation (EC) No
1907/2006
Arkofix ELF liq c
Substance key: 000000312612
Version : 3 - / EU
Hygiene measures
Wash hands before breaks and after work.
Respiratory protection :
Hand protection :
Eye protection :
Body protection :
9. Physical and chemical properties
Form :
Colour :
Odour :
Solidifying temperature :
Boiling point :
Flash point :
Ignition temperature :
Self-ignition temperature :
Flammability
Lower explosion limit :
Upper explosion limit :
Vapour pressure :
Density :
Bulk density :
Solubility in water :
pH value :
Octanol/water partition
coefficient (log Pow) :
Viscosity (dynamic) :
Page 4
Revision Date: 04.06.2009
Date of printing : 14.09.2009
Use respiratory protection in case of insufficient exhaust
ventilation or prolonged exposure
Filter A (organic gases and vapours) to standard DIN EN 141
Nitrile rubber gloves.
These types of protective gloves are offered by various
manufacturers. Please note the manufacturers detailed
statements, especially about the minimum thickness and the
minimum breakthrough time. Consider also the particular
working conditions under which the gloves are being used.
safety glasses
see respiratory protection
protective clothing
Liquid
colourless to slightly yellow
slightly perceptible
< -40 C
approx. 104 C
Method : NFT 60103 (closed cup)
No flash point - Measure made up to the boiling point.
not tested.
Not applicable
not tested.
not tested.
not tested.
approx. 1,22 g/cm3 (20 C)
Not applicable
miscible in all proportions
4-5
Determined in the undiluted form
Not determined
< 200 mPa.s (23 C)
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1907/2006
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Substance key: 000000312612 Revision Date: 04.06.2009

Version : 3 - / EU Date of printing : 14.09.2009

10. Stability and reactivity

Thermal decomposition : not tested.
Hazardous decomposition products
Carbon monoxide and carbon dioxide

11. Toxicological information

Acute oral toxicity : LD50 > 2.000 mg/kg (rat)
Source : Analogy
Test conducted with a similar formulation.

Irritant effect on skin : non-irritant (rabbit)

Source : Analogy
Test conducted with a similar formulation.
Irritant effect on eyes : non-irritant (rabbit eye)
Source : Analogy
Test conducted with a similar formulation.
Sensitization : non-sensitizing (Guinea pig)
Method : OECD 406 - EEC 92/69, B.6
Source : Analogy
Test was carried out with a comparable product

12. Ecological information

Biodegradability : not tested.

Fish toxicity : LC50 > 500 mg/l (Brachydanio rerio)

Source : Analogy
Test conducted with a similar formulation.

Daphnia toxicity : not tested.

Algae toxicity : not tested.

Bacteria toxicity : EC50 > 1.000 mg/l (activated sludge)

Source : Analogy
Test conducted with a similar formulation.

Chemical oxygen demand 752.000 mg/g

(COD) :

Biochemical oxygen demand 81.800 mg/l

(BOD5) : 5d
Safety Data Sheet in accordance with Regulation (EC) No
1907/2006
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Substance key: 000000312612 Revision Date: 04.06.2009

Version : 3 - / EU Date of printing : 14.09.2009

Remarks
The ecotoxicity of the product has not been tested. The information given is based on
products of similar structure or composition.
Product does not contain any organic bound Halogens which could lead to AOX-values.

13. Disposal considerations

Product
Disposal in an incineration plant in accordance with the regulations of the local
authorities.
Uncleaned packaging
Packaging that cannot be cleaned should be disposed of as product waste

14. Transport information

ADR not restricted

ADNR not restricted
RID not restricted
IATA not restricted
IMDG not restricted

15. Regulatory information

Labelling in accordance with EC-Directives
hazard warning labelling not compulsory
The product does not require a hazard warning label in accordance with EC directives/the
relevant national laws.
Chemical Safety Assessment
No Chemical Safety Assessment (CSA) is yet available for the substance, or for the
component substances, contained in this product.
Special labelling for certain preparations
Safety Data Sheet available for professional user on request.
Safety Data Sheet in accordance with Regulation (EC) No
1907/2006
Arkofix ELF liq c Page 7

Substance key: 000000312612 Revision Date: 04.06.2009

Version : 3 - / EU Date of printing : 14.09.2009

16. Other information

See product leaflet
Text of the R-phrases assigned to the ingredients/components mentioned in
section 3 :
11 Highly flammable.
22 Harmful if swallowed.
23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in
contact with skin and if swallowed.

Decimal notation: "Thousands" places are identified with a dot (example: 2.000 mg/kg
means "two thousand mg/kg"). Decimal places are identified with a comma (example: 1,35
g/cm3).

The data are based on the current state of our knowledge, and are intended to describe the
product with regard to the requirements of safety. The data should not be taken to imply
any guarantee of a particular or general specification. It is the responsibility of the user of
the product to ensure to his satisfaction that the product is suitable for the intended purpose
and method of use. We do not accept responsibility for any harm caused by the use of this
information. In all cases, our general conditions of sale apply.