T=30C

COMPONEkg/d %wt kmol/d %mol

H2SO4 34,186.43 98.00% 348.56 90.00%
Water 697.68 2.00% 38.72 10.00%
TOTAL 34,884.11 100% 387.27 100%
SULFURIC ACID

ROTARY KILN

T=30C
SODIUM CHLORIDE T=460
COMPONEkg/d %wt kmol/d %mol SODIUM SULFATE
NaCl 27,159.53 99.00% 464.74 96.83% COMPONEkg/d %wt
Water 274.34 1.00% 15.22 3.17% Na2SO4 33005.99 99.00%
TOTAL 27,433.87 100% 479.97 100% Water 333.39 1.00%
TOTAL 33339.38 100%

Consumed H2SO4= 232.3711 KMOLS H2SO4 reqd= 348.5566

22790.96 kgs 34186.43
 OFF GASES W/ HCl T=460
COMPONEkg/d %wt kmol/d %mol
HCl 16,944.50 58.47% 464.74 75.40%
Water 638.63 2.20% 35.44 5.75%
H2SO4 11,395.48 39.32% 116.19 18.85%
TOTAL 28,978.60 100% 616.37 100%

kmol/d
232.37
18.50
250.87
 RECYCLED H2SO4 T=150
QUENCHER
COMPONEkg/d %wt kmol/d %mol
Water 232.56 2.00% 12.91 10.00%
H2SO4 11,395.48 98.00% 116.19 90.00%
TOTAL 11,628.04 100% 129.09 100%

OFF GASES W/ HCl T=460

COMPONEkg/d %wt kmol/d %mol
HCl 16,944.50 58.47% 464.74 75.40%
Water 638.63 2.20% 35.44 5.75%
H2SO4 11,395.48 39.32% 116.19 18.85%
TOTAL 28,978.60 100% 616.37 100%
 COOLING H2O T=30
COMPONENT kg/d kmol/d OFF GASES W/ HCl
H2O 5956.94 330.57
Condensation Temp of H2SO4 = 325
H condensation of H2SO4 = 570.96
Q condensation for H2SO4 = ###
Q(gas to liquid)=mCpdT= ###
Cp for liquid H2SO4 = 1.38
Q(senible) = 2752008
QH2SO4 = ###
GAS STREAM T=150
COMPONENT kg/d %wt kmol/d %mol QH2O = 396572.6
HCl 16,944.50 72.70% 464.74 56.82%
Water 6363.00 27.30% 353.11 43.18% QHCl = 4257038
TOTAL 23,307.50 100% 817.85 100%
QT = ###
C
kJ/kg
kJ/d
kJ/d
8kJ/kg K
kJ/d
kJ/d

kJ/d

kJ/d

kJ/d = m* 2650.09 kJ/kg

 GAS STREAM
COMPONEkg/d
T=150
%wt kmol/d %mol COOLER
HCl 16,944.50 72.70% 464.74 56.82%
Water 6,363.00 27.30% 353.11 43.18%
TOTAL 23,307.50 100.00% 817.85 100.00%
OOLER GAS STREAM
COMPONEkg/d %wt kmol/d %mol
HCl 16,944.50 72.70% 464.74 56.82%
Water 6,363.00 27.30% 353.11 43.18%
TOTAL 23,307.50 100.00% 817.85 100.00%
 COMPONEkg/d kmol/d
Water 21726.63 1205.70

COMPONE
HCl
Water
OFF GAS TOTAL
GAS ABSORBER
PRODUCT HCl
COMPONE
GAS STREAM HCl
COMPONENT kg/d %wt kmol/d %mol Water
HCl 16,944.50 72.70% 464.74 56.82% TOTAL
Water 6,363.00 27.30% 353.11 43.18%
TOTAL 23,307.50 100.00% 817.85 100.00%
 T=50
kg/d %wt kmol/d %mol
169.44 93.59% 4.6474 87.83%
11.61 6.41% 0.6440 12.17% Hs = 0.06849 kg H2O/kg HCl
181.05 100% 5.2914 100%

T=50
PRODUCT HCl %Rec= 99.00%
kg/d %wt kmol/d %mol
16,775.05 37.4% 460.09 22.80%
28078.03 62.6% 1558.16 77.20% Plant Cap=13455926.46 kg/yr
44,853.09 100% 2018.25 100% 44853.09 kg/d