Classroom Contact Programme: Jee (Main + Advanced) : Leader & Enthusiast Course

Paper Code : 0000CT103115 006
ENGLISH
CLASSROOM CONTACT PROGRAMME
(Academic Session : 2015 - 2016)
JEE (Main + Advanced) : LEADER & ENTHUSIAST COURSE

TARGET : JEE (ADVANCED) 2016
Test Type : ALL INDIA OPEN TEST Test Pattern : JEE-Advanced
TEST DATE : 08 - 05 - 2016
Time : 3 Hours PAPER 1 Maximum Marks : 264
READ THE INSTRUCTIONS CAREFULLY
GENERAL :
1. This sealed booklet is your Question Paper. Do not break the seal till you are instructed to do so.
2. Use the Optical Response sheet (ORS) provided separately for answering the questions.
DO NOT BREAK THE SEALS WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR

3. Blank spaces are provided within this booklet for rough work.
4. Write your name and form number in the space provided on the back cover of this booklet.
5. After breaking the seal of the booklet, verify that the booklet contains 32 pages and all the 20 questions in each
subject and along with the options are legible.
QUESTION PAPER FORMAT AND MARKING SCHEME :
6. The question paper has three parts : Physics, Chemistry and Mathematics. Each part has three sections.
7. Carefully read the instructions given at the beginning of each section.
8. Section-I contains 10 multiple choice questions with one or more than one correct option.
Marking scheme : +4 for correct answer, 0 if not attempted and 2 in all other cases.
9. Section-II contains 2 match the following type questions and you will have to match entries in Column-I with the
entries in Column-II.
Marking scheme : for each entry in column-I. +2 for correct answer, 0 if not attempted and 1 in all other cases.
10. There is no questions in SECTION-III
11. Section-IV contains 8 questions. The answer to each question is a single digit integer ranging from
0 to 9 (both inclusive)
Marking scheme : +4 for correct answer and 0 in all other cases.
OPTICAL RESPONSE SHEET :
12. The ORS is machine-gradable and will be collected by the invigilator at the end of the examination.
13. Do not tamper with or mutilate the ORS.
14. Write your name, form number and sign with pen in the space provided for this purpose on the original. Do not write
any of these details anywhere else. Darken the appropriate bubble under each digit of your form number.
Please see the last page of this booklet for rest of the instructions
ALL INDIA OPEN TEST/JEE (Advanced)/08-05-2016/PAPER-1
SOME USEFUL CONSTANTS

Atomic No. H = 1, B = 5, C = 6, N = 7, O = 8, F = 9, Al = 13, P = 15, S = 16, Cl = 17, Br = 35,
Xe = 54, Ce = 58,
Atomic masses : H = 1, Li = 7, B = 11, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24,
Al = 27, P = 31, S = 32, Cl = 35.5, Ca=40, Fe = 56, Br = 80, I = 127,
Xe = 131, Ba=137, Ce = 140,
Boltzmann constant k = 1.38 1023 JK1
1
Coulomb's law constant = 9 10 9
4 0
Universal gravitational constant G = 6.67259 1011 Nm2 kg2
Speed of light in vacuum c = 3 108 ms1
StefanBoltzmann constant = 5.67 108 Wm2K4
Wien's displacement law constant b = 2.89 103 mK
Permeability of vacuum 0 = 4 107 NA2
1
Permittivity of vacuum 0 =
0 c2
Planck constant h = 6.63 1034 Js
Space for Rough Work
E-2/32 0000CT103115006
HAVE CONTROL HAVE PATIENCE HAVE CONFIDENCE 100% SUCCESS
PHYSICS
BEWARE OF NEGATIVE MARKING
PART-1 : PHYSICS
SECTIONI : (Maximum Marks : 40)
This section contains TEN questions.
Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is (are) correct.
For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
Marking scheme :
+4 If only the bubble(s) corresponding to all the correct option(s) is (are) darkened
0 If none of the bubbles is darkened
2 In all other cases
1. A particle of mass m is bound by the linear potential U kr, where k is a constant and r 0 . It is
moving in a circular orbit of radius r0 about the origin :-
3kr0
(A) Its mechanical energy is
2
(B) The speed is independent of value of radius
(C) The angular speed is independent of value of radius
kr0
(D) Its mechanical energy is
2
2. In the circuit shown, switch S1 is initially open and switch S2 is initially closed. At time t 0 , S1 is
closed and at time t 0.25 s, S2 is opened. The voltage across the inductor, VL :-
1H
S1 S2
+
10V 20
5
(A) Just after switch S1 is closed, VL = 10 V

(B) Just before switch S2 is opened, VL = 10/eV
(C) Just after switch S2 is opened, VL = (40 50/e) V
(D) Just after switch S2 is opened, VL = (60 50/e) V
0000CT103115006 E-3/32
3. The xy plane carries a uniform surface current flowing in the x direction with a surface current density
PHYSICS
of kx = 10 A/m. The yz plane carries a uniform surface current flowing in the z direction, also with a
surface current density of kz = 10 A/m. Observe the figure below :-
z
kz
y
kx
x
(A) Magnetic field in region x > 0, z > 0; is in positive y-direction.
(B) Magnetic field in region x > 0, z < 0; is zero.
(C) Magnetic field in region x < 0, z > 0; is in negative y - direction.
(D) Magnetic field in region x < 0, z < 0; is zero
4. If Me, Mp and MH are the rest masses of electron, proton and hydrogen atom in the ground state
(with energy 13.6 eV), respectively, which of the following is exactly true ? (c is the speed of light in
free space) :-
13.6eV
(A) MH = MP + Me (B) MH = MP + Me
c2
13.6eV 13.6eV
(C) MH = MP + Me + (D) MH = MP + Me + K, where K or zero
c2 c2
E-4/32 0000CT103115006
5. A combination of two thin convex lenses of equal focal lengths, is kept separated along the optical axis by
PHYSICS
a distance of 20 cm between them. The combination behaves as a lens system of infinite focal length :-
(A) If an object is kept on the common optic axis at a distance of 10 cm from the first lens, its final
image will be formed at a distance of 10 cm from the next lens.
(B) If an object is kept on the common optic axis at a distance of 10 cm from the first lens, its final
(C) If an object is kept on the common optic axis at a distance of 30 cm from the first lens, its final
(D) If an object is kept on the common optic axis at a distance of 30 cm from the first lens, its final
6. Photons of wavelength 248 nm fall on a metal surface whose work function is 2.2 eV. Assume that
each photoelectron inside the metal lattice may come out of the surface or collide with the lattice
before coming out. In each collision with the lattice, it loses 20% of its existing energy. Which of the
following can be a kinetic energy of an ejected photoelectron?
(A) 2.8 eV (B) 2.24 eV (C) 1.8 eV (D) 1 eV
0000CT103115006 E-5/32
7. A mass m, lying on a horizontal, frictionless surface, is connected to one end of a spring of spring
PHYSICS
constant k. The other end of the spring is connected to a wall, as shown in the figure. At t = 0, the mass
is given an impulse J as shown. Taking left direction as positive. The time dependence of the
displacement, acceleration and the velocity of the mass are:
m Impulse
J k J k 3
sin t
(A) x = m (B) v = sin
m
t
mk m 2
J k k J k k
(C) a = sin t (D) a = sin t
m
m3 m3 m
8. A satellite moves around the earth in a circular orbit of radius R centered at the earth. A second
satellite of same mass moves in an elliptic orbit of semi-major axis 4R, with the earth at one of
the foci.
(A) The ratio of their time periods is 1 : 8
(B) The ratio of their time periods is 1 : 2
(C) The first satellite has a higher angular momentum about the center of the earth
(D) The first satellite has a lower mechanical energy
E-6/32 0000CT103115006
9. A hollow, conducting spherical shell of inner radius R1 and outer radius R2 encloses a charge q inside,
PHYSICS
which is located at a distance d (d<R1) from the centre of the spheres. (assume potential to be zero at
infinity) :-
kq kq
(A) The potential at the centre of the shell is
d R1
kq
(B) The potential of the shell is
R2
kq kq kq
(C) The potential outside the shell at a distance R from the center is
R d R1
kq kq kq
(D) The potential at the centre of the shell is
d R1 R 2
10. Two equal uniform rods P and Q move with the same velocity v as shown in the figure. The second rod
has an angular velocity (<6v/l ) (clockwise) about G' in addition to v.
(A) If the ends A &A' are suddenly fixed simultaneously both rods will rotate with the same angular
velocity
(B) If the ends A & A' are suddenly fixed simultaneously, the rod Q will rotate with greater angular velocity
(C) If the ends B & B' are suddenly fixed simultaneously both rods will rotate with the same angular velocity
(D) If the ends B & B' are suddenly fixed simultaneously, the rod P will rotate with greater angular velocity
0000CT103115006 E-7/32
SECTIONII : (Maximum Marks : 16)
PHYSICS
This section contains TWO questions.

Each question contains two columns, Column-I and Column-II.
Column-I has four entries (A), (B), (C) and (D)
Column-II has five entries (P), (Q), (R), (S) and (T)
Match the entries in Column-I with the entries in column-II.
One or more entries in Column-I may match with one or more entries in Column-II.
The ORS contains a 4 5 matrix whose layout will be similar to the one shown below :
(A) (P) (Q) (R) (S) (T)
(B) (P) (Q) (R) (S) (T)
(C) (P) (Q) (R) (S) (T)
(D) (P) (Q) (R) (S) (T)

For each entry in column-I, darken the bubbles of all the matching entries. For example, if entry
(A) in Column-I matches with entries (Q), (R) and (T), then darken these three bubbles in the ORS.
Similarly, for entries (B), (C) and (D).
Marking scheme :
For each entry in Column-I
+2 If only the bubble(s) corresponding to all the correct match(es) is (are) darkened
1. A monatomic ideal gas at pressure P0 & volume V0 can be made to undergo 4 different process on PV
diagram as shown. For each of the processes, match with entries in column-II. (Symbols have their
usual meanings).
2
P 1
P0 3
4
V0 V(in m3)
Column-I Column-II
(A) Process1 (P) Q + ve
(B) Process-2 (Q) U + ve
(C) Process-3 (R) W ve
(D) Process-4 (S) Temperature decreases
(T) Q ve
E-8/32 0000CT103115006
2. Match the image description in column-I with column-II. Only 2 rays are shown for convenience. (f in
PHYSICS
each case is the focal length of the respective geometrical device.)
Column-I Column-II
f/2
(A) virtual image (P)
\\\\\\
\\\\\\\\ \\\\\\\\\\\\
(B) real image (Q)
15cm
f = 10cm
=1 = 1.5
50cm
(C) erect image (R)
1m
(D) magnified image (S)
f/2
(T)
SECTIONIII : Integer Value Correct Type

No question will be asked in section III
0000CT103115006 E-9/32
SECTIONIV : (Maximum Marks : 32)
PHYSICS
This section contains EIGHT questions.

The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive
For each question, darken the bubble corresponding to the correct integer in the ORS
Marking scheme :
+4 If the bubble corresponding to the answer is darkened
1. In a region of space, a time dependent magnetic field B= 0.4t Tesla points vertically upwards. Consider
a horizontal, circular loop of radius 2 cm in this region. The magnitude of the electric field (in mV/m)
induced in the loop is
2. For the arrangement given in the following figure, the coherent light sources A, B and C radiating in
phase have individual intensities of 2 mW/m2, 2 mW/m2 and 5 mW/m2, respectively at point P. The
wavelength of each of the sources is 600 nm. The resultant intensity at point P (in mW/m2) is
15mm
A
3.22mm
1m
B
2.04mm
E-10/32 0000CT103115006
3. A block of mass 2 kg is at rest on a horizontal table. The coefficient of friction between the block and
PHYSICS
the table is 0.1. A horizontal force 3 N is applied to the block. The speed of the block (in m/s) after it
has moved a distance 9 m is
4. Two L shaped wires are kept over each other as shown. The wire on the left is fixed and the wire on the
right is movable on the left wire without any friction. The whole system is in a horizontal plane. Now
we make a soap film of surface tension 0.1 N/m in between the wires such that it covers the common
quadrilateral area. If the right wire has a mass of 250 gm, what is its initial acceleration (in m/s2) on
being released ?
1.5m
2m
0000CT103115006 E-11/32
5. Lets fill an air-balloon to the same volume once with hydrogen and once with helium. In one of the
PHYSICS
case the lifting capacity is greater than the other case. By what percentage? (In the given conditions
the gas densities in kg/m3 units are: hydrogen 0.08, helium 0.16, air 1.16). The mass of the
balloons material is negligible compared to the mass of the hanging weight and the volume of the
hanging weight is negligible compared to the volume of the balloon.
6. Consider the circuit shown in Fig, made from identical resistors and voltmeters. First voltmeter shows
V1 = 10 V, and the third V3 = 2 V. What reading does the second voltmeter show (in Volts)?
V
V1 V2 V3
m
0
E-12/32 0000CT103115006
7. Suppose that we have a vernier callipers which does not expand or contract on heating. Such a device
PHYSICS
is very useful in engineering applications where the dimensions are to be found at different temperatures.
One such vernier callipers is used to measure the diameter of a rod at different temperatures as shown
in table below. What will be the vernier scale reading (division coinciding) at a temperature of 50C.
10 vernier scale divisions coincide with 9 main scale divisions and 1 main scale division = 1 mm.
Temperature T in C Main scale reading Vernier scale reading
0 2.4 cm 4th division coinciding
20 2.4 cm 8th division coinciding
8. A cylindrical vessel is divided in two parts by a fixed partition which is perfectly heat conducting. The
wall and piston are thermally insulated from surroundings. The left side contains 0.5 moles of gas with
Cv = 2R at temperature of 300 K. The right side contains 4 moles of mixture of gas with Cv = 1.75 R at
V0
same temperature of 300 K. The piston compresses slowly the right side from volume of V0 to .
4
Find the total change in internal energy of gases. If U = n 10 4 J, fill n in OMR Sheet.
25
(Take : R = S.I. unit)
3
0000CT103115006 E-13/32
PART-2 : CHEMISTRY
CHEMISTRY

Marking scheme :
1. Enthalpy change in a reaction depends on -
(A) Physical state of reactant and products (B) Allotropic from of element involved
(C) Path used by reactants to form products (D) Temperature
2. At 263K a solid compound A(H2O)8 show following equilibria (Assume 263K is sublimation point of
H2O(s) under given condition) -
A(g) + 8 H O(g) ; Kp
A(H2O)8 (s) 2 1
A(g) + 8 H O(s) ; Kp
A(H2O)8 (s) 2 2
If equilibrium partial pressures of two gases A & H2O are 0.2 bar & 0.001 bar respectively. Then correct
informations are -
(A) K 0p1 2 1025 (B) K 0p2 = 0.2
(C) Vapour pressure of ice is 0.001 bar (D) Vapour pressure of ice is 0.002 bar
3. In which of the following crystals, cations occupy tetrahedral voids ?
(A) NaCl (B) ZnS (C) Na2O (D) CaF2
4. When MnO2 is fused with KOH, a purple green coloured compound is formed. Choose correct statements
about purple green coloured compound
(A) It disproportionates in acidic medium (B) It is paramagnetic in nature
(C) Geometry is tetrahedral (D) It uses non axial d-orbital in hybridisation
E-14/32 0000CT103115006
CHEMISTRY.
5. In the following reactions. The CORRECT statements is/are :
I. FeSO4 + NO + H2O X
II. Sodium nitroprusside + Na2S Y
(A) Products X and Y both are paramagnetic
(B) In the reaction I change of oxidation state of central atom occurs while in reaction II there is no
change in oxidiation state
(C) Product (X) can also be obtained when NO2 or NO3 react with dil. H2SO4 in presence of FeSO4
(D) Hybridisation of central atom of X is sp3d2 and Y is d2sp3
6. The low-spin paramagnetic complex compounds that exhibits optical isomerism is/are
(A) [Ni(en)3]Cl2 (B) [Ru(H2O)2Br2Cl2] (C) [Cr(CN)2Br2Cl2] (D) [Pt(NH3)4Cl2]2+
7. The sets with CORRECT order of acidity is
(A) HF < HCl < HBr < HI (B) HClO > HBrO > HIO
(C) HClO4 > HClO3 > HClO2 > HClO (D) H2SO4 > H2SO3
8. Choose the correct option(s) :
HN3 , (i) LAH

CH3COH X CH3COH Y
conc. H2SO4 / (ii) PBr3
O O
(A) X is CH3CNH2 (B) Y is CH3CH2Br

O
(C) X is CH3CNHCH2CH3 (D) X is CH3NH2

O
0000CT103115006 E-15/32
CHEMISTRY
9. Compound A (C6H12O3) when treated with I2 & NaOH gives yellow precipitate. When A is treated
with Tollen's reagent no reaction occur. When A is treated with H3O & then treated with I2 & NaOH
gives yellow precipitate. Compound A can't be :
O OH
(A) CH3CCH2CH2CHOH (B) CHCH2CCH2CH3
O OCH3 OCH3
OCH3 O OCH3
(C) CH3CCH2CH (D) HCCH2CH2CH
O OCH3 OCH3
10. Correct statement(s) regarding following reaction sequence is/are :
NH2
NaNO2 CuCN Na
Q HCN R C H OH S
HCl (05)C 2 5
(P)
(A) P & S can be distinguished by dye azo test
(B) S is more basic than P
(C) R give benzophenone with PhMgBr followed by H3O
(D) Q on passing with steam produces phenol
E-16/32 0000CT103115006
CHEMISTRY.
(A) (P) (Q) (R) (S) (T)
(B) (P) (Q) (R) (S) (T)
(C) (P) (Q) (R) (S) (T)
(D) (P) (Q) (R) (S) (T)
For each entry in column-I, darken the bubbles of all the matching entries. For example, if entry (A)
in Column-I matches with entries (Q), (R) and (T), then darken these three bubbles in the ORS. Similarly,
for entries (B), (C) and (D).
Marking scheme :
1. Column-I (Compound) Column-II (Correct Characteristics)
(A) Sulphurous acid (P) dibasic acid
(B) Sodium thiosulphate (Q) Reducing agent
(C) Oleum (R) Sulphur-sulphur bond present
(D) Hydrogen Peroxide (S) +5 oxidiation state of sulphur is not present
(T) Peroxylinkage is present
0000CT103115006 E-17/32
CHEMISTRY
2. Column - I Column - II
(i) Hg(OAc) 2 / H 2O
(A) CH2 =CCH2CH2CH3 (P) Product is a racemic mixt ure of
(ii) NaBH4 / OH
Et
carboxylic acid
CH 3
(i) B2H6 (THF), (ii) H2O2 + OH
(B) CH2=CCH (iii) KMnO4
(Q) Resolvable alcohol is formed as
Et CH3 products
Reductive
(C) CH2=CCH2 CH2CH3 Ozonolysis
(R) One of the product is also obtained by
Et oxidation of 3-hexanol with KMnO4
CH3
(D) CH2=CCH Reductive (S) Product is also obtained by oxidation of
Ozonolysis
Et CH3 2-methyl-3-pentanol with KMnO4
(T) Product does not give efferrescence of

CO2 with NaHCO3

E-18/32 0000CT103115006
CHEMISTRY.
Marking scheme :
1. Calculate the maximum possible concentration of Mn2+ in water that is saturated with 0.1 M H2S &
maintained at pH = 3 with HCl
Given : for H2S ; Ka = 108 ; Ka = 1012 ;
1 2
& Ksp (MnS) = 1022
If your answer in scientific notation is x 10y then fill y in OMR.
2. The ratio of wave number of the first line of lyman series in H-atom to wave number of the first line in
Balmer series of Li2+ ion is 3 : x. The value of 'x' is -
3. Acetic acid can form a dimer (CH3COOH)2 in gas phase. The dimer is held together by H-bonds. If at
27C, equilibrium constant for dimerisation is e 10 & |S| for dimerisation is 'y' cal/K, the
y
value of is
10
Given :Hydrogen-Bond enthalpy = 7.5 kcal /mol
R = 2cal / mole - K
0000CT103115006 E-19/32
4. Total number of TRUE statements about silicones/silicates ?

CHEMISTRY
(i) Silicones resist oxidation and attack by organic reagents

(ii) Silicones are lubricants at low as well as high temperature
(iii) Cross-linked silicones are formed by the hydrolysis of trichlorosilicone (RSiCl3) and subsequent
polymerisation
(iv) Both silicones and silicates compound contains SiOSi linkage.
(v) Silicones are good electrical insulator and are antifoaming agents
5. Total number of black precipitate which dissolve in yellow ammonium sulphide (YAS) as well as hot
and dil. HNO3
PbS, CuS, HgS, CdS, As2S3, As2S5, Sb2S3, Sb2S5, SnS2, Bi2S3
E-20/32 0000CT103115006
CHEMISTRY.
6. How many reactions product formed is correctly matched ?
O O
C Br C
Br2
(i) N N
+ Fe
NH2 NO2
H2SO5
or
(ii) CF3COOH
O
O=COEt

1. EtO
(iii) +
2. H3O /
N N
3. N2H4 + OEt
:
CH2COEt
O
Br
(iv) CH2=CHCMe2CO2H 1.
2. HBr + H2O 2
O CH=O
+
H3O
(v) + ClCH2CO2Et + tertiary butoxide ion X
+
H3O
(vi) O OCH3 OH + HO OH + CH3 OH
7. Number of pair of enantiomers possible for bromochlorocyclopentane if X.

Number of of pair of enantiomers possible for chlorofluorocyclobutane if Y.
Then find out the value of X + Y :
0000CT103115006 E-21/32
8. Which of the following statement are correct ?
CHEMISTRY
(i) Backelite is thermosetting polymer.
CH=O
H OH
H OH
(ii) This can be the fischer projection of D-aldoheptose HO H
H OH
H OH
CH2OH
Ph N=O
N
(iii) Reaction of N-phenyl alanine with nitrous acid affords
CO2H
Ph
(i) Br2 (CCl4)
(iv) (ii) NaNH2 (excess) Ph
(iii) H2/lindlar catalyst (Major product)
(v) The structure of conjugate acid & conjugate base of the following compound H2N OH
+
are respectively H2N OH2 & H2N O
Br
Zn
(vi) In this reaction product formed have aromatic character
Br
E-22/32 0000CT103115006
MATHEMATICS
PART-3 : MATHEMATICS
Marking scheme :
1
e e x dx is less than -
3 3
x
1.
1
2 1
(A) 2 (B) 2e (C) e 2 (D) 2e
e e
2. Let a,b,c be distinct non-zero real numbers satisfying a3 + b3 + 6abc = 8c3, then which of the following
i2
3
can be correct ? (where e and i 1 )
(A) a,c,b are in A.P (B) a,c,b are in H.P (C) a + b 2c2 = 0 (D) a + b2 2c = 0
3. Let A and B be two square matrix of order 3, then which of the following statement(s) is/are correct ?
(A) ABAT is a symmetric matrix
(B) AB BA is a skew symmetric matrix
(C) If B = |A|A1, |A| 0, then adj(AT) B is a skew symmetric matrix
(where |A| is determinant of matrix A)
(D) If B + AT = O and A is a skew symmetric matrix, then B15 is also skew symmetric matrix
0000CT103115006 E-23/32
MATHEMATICS
4. Let A,P,B are collinear points on lines y = 0, y = 2x, y = 3x respectively. If PA.PB is minimum (for a
fixed P), then -
(A) PA = PB (B) PA > PB
(C) slope of PA may lie in (,1) (D) A,B are equidistant from origin
x
1 2
2
5. Let x e x 1 sin t dt x (0,), then-
0
(A) ' exists and is continuous x (0,)

(B) " exists x (0,)
(C) ' is bounded
(D) There exists > 0 such that |(x)| > |'(x)| x ()
6. Consider an equation in x, 8x4 16x3 + 16x2 8x + a = 0, then the sum of all the non-real roots of the
equation can be (a R)
1
(A) 1 (B) 2 (C) (D) none of these
2
E-24/32 0000CT103115006
MATHEMATICS
n 4 n 5
x x
4
7. The values of 't' satisfying the equation lim xn1 nx 1 is -
n
t 9 t 5
x x
x 1 x 1
(A) 1 (B) 2 (C) 3 (D) 7
8. If the lines 2x y = 8, x 2y = 17 and the line L = 0 forms an isosceles triangle, then slope of
line L can be -
11 2
(A) 1 (B) (C) 1 (D)
2 11
A C 1
9. In a triangle ABC with usual notations, if tan tan , then-
2 2 3
2ac B A C 2
(A) b (B) tan tan tan
ac 2 2 2 3
B A C 4
(C) tan tan tan (D) a,b,c are in G.P.
2 2 2 3
sec 4 sec 4
10. The expression (wherever defined) can take the value -
tan 2 tan 2
(A) 4 (B) 6 (C) 8 (D) 10
0000CT103115006 E-25/32
MATHEMATICS

(A) (P) (Q) (R) (S) (T)
(B) (P) (Q) (R) (S) (T)
(C) (P) (Q) (R) (S) (T)
(D) (P) (Q) (R) (S) (T)
For each entry in column-I, darken the bubbles of all the matching entries. For example, if entry (A)
in Column-I matches with entries (Q), (R) and (T), then darken these three bubbles in the ORS. Similarly,
for entries (B), (C) and (D).
Marking scheme :
1. Column-I Column-II
4
r
(A) If tan 15
r0 5
k 3 , then the value of k is (P) 3
n 1
nr 55
(B) If r 1 r 2 r 3 3k
r 0
(where n = 10), then k is (Q) 4
(C) If the maximum area of ellipse with centre (0,0) and axis (R) 8
parallel to co-ordinate axis and tangent to it with slope 2
is normal to the circle x2 + y2 + 4x + 1 = 0 is k, then
1
k is (S)
3
(D) If the angle between asymptotes of
5x 2 2 7xy y 2 2x 1 0 is k, then tan2 k is (T) 5
E-26/32 0000CT103115006
MATHEMATICS
2. If A is a non-singular matrix of order n n, n > 2 then -
Column-I Column-II
(A) (adjA)1 (P) 2n1(adj A)
A
(B) adj(2A) (Q)
|A|
n2
(C) adj(adj A) (R) |A| A
(D) adjA1 (S) adjA
adj(adjA)
(T)
| A |n 1

0000CT103115006 E-27/32
MATHEMATICS

Marking scheme :
1 1 1 1
1. The sequence is defined as follows : a1 , a n 1 a 2n a n ,S .... , then [S] is
2 a1 1 a 2 1 a100 1
(where [.] denotes greatest integer function)
x
2. If (x) is a polynomial function such that (x) + '(x) + ''(x) + '''(x) = x3 and g x dx and
x3
g(1) = 1, then | g(e) | is (where [.] denotes greatest integer function and e is Napier's constant)
3. The number of solution of the equation x 2 2 log 2 2 x 3x 2 x is
E-28/32 0000CT103115006
MATHEMATICS
4. If the angle between two focal chords of a parabola (y 5)2 = 8(x 1) which are tangents to the circle
a
x2 + y2 = 9 is tan 1 , where a & b are relatively prime number, then (a b) is
b
1 3 12 4 16
5. Let 2 tan 1 sin 1 and sin 1 cos1 cot 1 be such that 2sin and
2 5 13 5 63
2
cos are roots of the equation x px + q = 0, then (p q) is
6. Let < an> is an infinite geometric sequence with first term 2 cotx and common ratio sin2x and < bn > is

an infinite geometric sequence with first term sin2x and common ratio sin2x. If x 0, , then the
4

minimum value of a i b j is
i 1 j1
0000CT103115006 E-29/32

MATHEMATICS
7. Let OABC be a t etrahedron whose edges are of unit lengt h. If OA a, OB b, and

p
2
OC a b a b , then (where p & q are relatively prime to each other), then the
q
q
value of is (where [.] denotes greatest integer function)
2p
3 1
3
8. The value of 1
x 1
x 2
13
dx is
1
E-30/32 0000CT103115006
0000CT103115006 E-31/32
DARKENING THE BUBBLES ON THE ORS :
15. Use a BLACK BALL POINT PEN to darken the bubbles in the upper sheet.
16. Darken the bubble COMPLETELY.
17. Darken the bubbles ONLY if you are sure of the answer.
18. The correct way of darkening a bubble is as shown here :
19. There is NO way to erase or "un-darken" a darkened bubble.
20. The marking scheme given at the beginning of each section gives details of how darkened and not darkened
bubbles are evaluated.
21. Take g = 10 m/s 2 unless otherwise stated.
NAME OF THE CANDIDATE ................................................................................................
FORM NO. .............................................
I HAVE READ ALL THE INSTRUCTIONS I have verified the identity, name and roll
number of the candidate, and that question
AND SHALL ABIDE BY THEM
paper and ORS codes are the same.
____________________________ ____________________________
Signature of the Candidate Signature of the invigilator
Corporate Office : CAREER INSTITUTE, SANKALP, CP-6, Indra Vihar, Kota (Rajasthan)-324005
+91-744-5156100 info@allen.ac.in www.allen.ac.in
E-32/32 Your Target is to secure Good Rank in JEE 2016 0000CT103115006

Paper Code : 0000CT103115 006
CLASSROOM CONTACT PROGRAMME

HINDI
(Academic Session : 2015 - 2016)
JEE (Main + Advanced) : LEADER & ENTHUSIAST COURSE

TARGET : JEE (ADVANCED) 2016
Test Type : ALL INDIA OPEN TEST Test Pattern : JEE-Advanced
TEST DATE : 08 - 05 - 2016
Time : 3 Hours PAPER 1 Maximum Marks : 264

1.
2.
(ORS)
3.
4.
5.
32
20

6.
7.
8. -I
10

: +4
0
2
9. -II
2

-I
-II

:
-I
+2
0
1
10. III
11. -IV
8
0 9 (
)

: +4
0
12.
13.
14.

SOME USEFUL CONSTANTS

Atomic No. H = 1, B = 5, C = 6, N = 7, O = 8, F = 9, Al = 13, P = 15, S = 16, Cl = 17, Br = 35,
Xe = 54, Ce = 58,
Atomic masses : H = 1, Li = 7, B = 11, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24,
Al = 27, P = 31, S = 32, Cl = 35.5, Ca=40, Fe = 56, Br = 80, I = 127,
Xe = 131, Ba=137, Ce = 140,
Boltzmann constant k = 1.38 1023 JK1
1
Coulomb's law constant = 9 10 9
4 0
Universal gravitational constant G = 6.67259 1011 Nm2 kg2
Speed of light in vacuum c = 3 108 ms1
StefanBoltzmann constant = 5.67 108 Wm2K4
Wien's displacement law constant b = 2.89 103 mK
Permeability of vacuum 0 = 4 107 NA2
1
Permittivity of vacuum 0 =
0 c2
Planck constant h = 6.63 1034 Js
H-2/32 0000CT103115006
HAVE CONTROL HAVE PATIENCE HAVE CONFIDENCE 100% SUCCESS
PHYSICS
BEWARE OF NEGATIVE MARKING

-1 :
I : (: 40)

(A), (B), (C)
(D)

:
+4
0
2
1.
m
U kr
k r 0
r0

3kr
(A) 0 (B)
2
kr
(C)
(D) 0
2
2. S
1

S2
t 0 S1
t 0.25s S2
1H
S1 S2
+
10V 20
5
(A) S1
VL = 10 V
(B) S2
VL = 10/eV
(C) S2
VL = (40 50/e) V
(D) S2
VL = (60 50/e) V

0000CT103115006 H-3/32
3.
xy
x
kx = 10 A/m
yz
PHYSICS

z
kz = 10 A/m
kz
y
kx
(A)
x > 0, z > 0
y-
(B)
x > 0, z < 0
(C)
x < 0, z > 0
y-
(D)
x < 0, z < 0
4. Me, Mp MH eV
13.6

c
13.6eV
(A) MH = MP + Me (B) MH = MP + Me
c2
13.6eV 13.6eV
(C) MH = MP + Me + (D) MH = MP + Me + K,
K
c2 c2

H-4/32 0000CT103115006
5.
20 cm
PHYSICS

(A)
10 cm

10 cm
(B)
10 cm

30 cm
(C)
30 cm

10 cm
(D)
30 cm

20 cm
6.
248 nm
2.2 eV

20%
(A) 2.8 eV (B) 2.24 eV (C) 1.8 eV (D) 1 eV
0000CT103115006 H-5/32
7.
m
k
PHYSICS

t = 0
J

m Impulse
J k J k 3
sin t
(A) x = m (B) v = sin
m
t
mk m 2
J k k J k k
(C) a = sin t (D) a = sin t
m
m3 m3 m
8.
R

4R
(A)
1 : 8
(B)
1 : 2
(C)
(D)
H-6/32 0000CT103115006
9.
R1
R2
q
PHYSICS
d (d<R1)
kq kq
(A)

d R1
kq
(B)
R2
kq kq kq
(C)
R

R d R1
kq kq kq
(D)

d R1 R 2
10.
P Q
v
v
G'
(<6v/l )

(A)
A A'
(B)
A A'
Q
(C)
B B'
(D)
B B'
P
0000CT103115006 H-7/32
II : (: 16)
PHYSICS

-I

-II
-I

(A), (B), (C) (D)
-II

(P), (Q), (R), (S) (T)
-I
-II
-I -II

4 5

:
(A) (P) (Q) (R) (S) (T)
(B) (P) (Q) (R) (S) (T)
(C) (P) (Q) (R) (S) (T)
(D) (P) (Q) (R) (S) (T)
-I
-I
(A)
(Q), (R) (T)

(B), (C) (D)
:
-I
+2
0
1
1. P0 V0
PV

2
P 1
P0 3
4
V0 V(in m3)
-I
-II
(A) -1 (P) Q + ve
(B) -2 (Q) U + ve
(C) -3 (R) W ve
(D) -4 (S)
(T) Q ve

H-8/32 0000CT103115006
2. -I
-II
2
PHYSICS

f
-I -II
f/2
(A) (P)
\\\\\\
\\\\\\\\ \\\\\\\\\\\\
(B) (Q)
15cm
f = 10cm
=1 = 1.5
50cm
(C) (R)
1m
(D) (S)
f/2
(T)
III :
III
0000CT103115006 H-9/32
IV : ( : 32)
PHYSICS

0 9

:
+4
0
1.
B= 0.4t
2 cm
(mV/m )

2.
A, B C P
2 mW/m , 2 mW/m 5 mW/m 600
2 2 2

nm
P
(mW/m2 )
P
15mm
A
3.22mm
1m
B
2.04mm
H-10/32 0000CT103115006
3.
2 kg
0.1
PHYSICS

3 N
9 m
(m/s
)
4.
L

0.1 N/m

250 gm

(m/s2 )
1.5m
2m
0000CT103115006 H-11/32
5.
PHYSICS

kg/m3
= 0.08, = 0.16,
= 1.16

6.
V1 = 10 V V3 = 2 V
V1 V2 V3
H-12/32 0000CT103115006
7.
PHYSICS

50C

10
9
1
= 1 mm
T C
0 2.4 cm
20 2.4 cm
8.

Cv = 2R 0.5
300 K
V0
Cv = 1.75 R
4
300 K
V0
4

U = n 104 J
n
25
(R = S.I. unit)
3
0000CT103115006 H-13/32

-2 :
CHEMISTRY
I : (: 40)

(A), (B), (C)
(D)

:
+4
0
2
1.
-
(A)
(B)
(C)
(D)
2. 263K
A(H2O)8
(
H2O(s)
263K
)-
A(g) + 8 H O(g) ; Kp
A(H2O)8 (s) 2 1
A(g) + 8 H O(s) ; Kp
A(H2O)8 (s) 2 2

A
H2O
0.2 bar
0.001 bar
-
(A) K 0p1 2 1025 (B) K 0p2 = 0.2
(C)
0.001 bar (D)
0.002 bar
3.
?
(A) NaCl (B) ZnS (C) Na2O (D) CaF2
4. MnO2
KOH

(A)
(B)
(C) (D)
d-

H-14/32 0000CT103115006
5.
CHEMISTRY
I. FeSO4 + NO + H2O X
II.
+ Na2S Y
(A) X
Y,
(B)
I
II

(C) FeSO4
NO2 NO3,
H2SO4
(X)

(D) X
sp3d2
Y d2sp3
6.
(A) [Ni(en)3]Cl2 (B) [Ru(H2O)2Br2Cl2] (C) [Cr(CN)2Br2Cl2] (D) [Pt(NH3)4Cl2]2+
7.
(A) HF < HCl < HBr < HI (B) HClO > HBrO > HIO
(C) HClO4 > HClO3 > HClO2 > HClO (D) H2SO4 > H2SO3
8.
HN3 , (i) LAH

CH3COH X CH3COH Y
conc. H2SO4 / (ii) PBr3
O O
(A) X , CH3CNH2 (B) Y , CH3CH2Br

O
(C) X , CH3CNHCH2CH3 (D) X , CH3NH2

O

0000CT103115006 H-15/32

A (C6H12O3), I2
NaOH
A,
CHEMISTRY
9.

A ,H3O+
I2
NaOH

'A'
O OH
(A) CH3CCH2CH2CHOH (B) CHCH2CCH2CH3
O OCH3 OCH3
OCH3 O OCH3
(C) CH3CCH2CH (D) HCCH2CH2CH
O OCH3 OCH3
10.
NH2
NaNO2 CuCN Na
Q HCN R C H OH S
HCl (05)C 2 5
(P)
(A) P
S
(B) S P
(C) R PhMgBr
H3O
(D) Q
H-16/32 0000CT103115006
II : (: 16)
CHEMISTRY

-I

-II
-I

(A), (B), (C) (D)
-II

(P), (Q), (R), (S) (T)
-I
-II
-I -II
4
5

:
(A) (P) (Q) (R) (S) (T)
(B) (P) (Q) (R) (S) (T)
(C) (P) (Q) (R) (S) (T)
(D) (P) (Q) (R) (S) (T)

-I
-I
(A)
(Q), (R)
(T)

(B), (C) (D)

:

-I
+2
0
1
1.
-I (
)
-II
(A) (P)
(B) (Q)
(C) (R) -
(D) (S) +5
(T)
0000CT103115006 H-17/32
2.
-I
-II
CHEMISTRY
(i) Hg(OAc) 2 / H 2O
(A) CH2 =CCH2CH2CH3 (P)
(ii) NaBH4 / OH
Et
CH 3
(i) B2H6 (THF), (ii) H2O2 + OH
(B) CH2=CCH (iii) KMnO4
(Q)
Et CH3
(C) CH2=CCH2 CH2CH3 Reductive

Ozonolysis
(R)
3-
KMnO4
Et

CH3
(D) CH2=CCH Reductive (S)
2-
-3-
KMnO4
Ozonolysis
CH3
Et
(T)
NaHCO3
CO2

III :
III
H-18/32 0000CT103115006
IV : ( : 32)
CHEMISTRY

0 9

:
+4
0
1.
Mn2+
0.1 M H2S
HCl
pH = 3

: H2S ; Ka = 108 ; Ka = 1012 ;
1 2

Ksp (MnS) = 10 22

x 10y
OMR
Y
2. H-
Li2+

3 : x
'x'
-
3.
(CH3COOH)2
H-
y
27C ,
e10
|S| 'y' cal/K
10

:
-
= 7.5 kcal /mol
R = 2cal / mole - K
0000CT103115006 H-19/32
4.
CHEMISTRY
(i)
(ii)
(lubricants)
(iii)
(RSiCl3)
(iv)
SiOSi
(v)
5.
(YAS)
HNO3
PbS, CuS, HgS, CdS, As2S3, As2S5, Sb2S3, Sb2S5, SnS2, Bi2S3
H-20/32 0000CT103115006
CHEMISTRY
6.
O O
C Br C
Br2
(i) N N
+ Fe
NH2 NO2
H2SO5
or
(ii) CF3COOH
O
O=COEt

1. EtO
(iii) +
2. H3O /
N N
3. N2H4 + OEt
:
CH2COEt
O
Br
(iv) CH2=CHCMe2CO2H 1.
2. HBr + H2O 2
O CH=O
+
H3O
(v) + ClCH2CO2Et +
X
+
H3O
(vi) O OCH3 OH + HO OH + CH3 OH
7.
X

Y

X + Y
0000CT103115006 H-21/32
8.
CHEMISTRY
(i)
(thermosetting)
CH=O
H OH
H OH
(ii) HO H D-
H OH
H OH
CH2OH
Ph N=O
N
(iii) N-
CO2H
Ph
(i) Br2 (CCl4)
(iv) (ii) NaNH2 Ph
(iii) H2 /
+
(v)
H2N OH
H2N OH2

H2N O
Br
(vi) Zn

Br
H-22/32 0000CT103115006

-3 :
MATHEMATICS
I : (: 40)

(A), (B), (C)
(D)

:
+4
0
2
1
e e x dx
x3 3
1. -
1
2 1
(A) 2 (B) 2e (C) e 2 (D) 2e
e e
2.
a,b,c
a3 + b3 + 6abc = 8c3
i2
(
e 3
i 1 )
(A) a,c,b (B) a,c,b
2
(C) a + b 2c = 0 (D) a + b2 2c = 0
3.
A B,
3
(A) ABAT
(B) AB BA
(C) B = |A|A1, |A| 0
adj(AT) B
(
|A|,
A
)
(D) B + AT = O A
B15

0000CT103115006 H-23/32
MATHEMATICS
4.
y = 0, y = 2x, y = 3x
A,P,B
PA.PB ( P)
-
(A) PA = PB (B) PA > PB
(C) (,1)
PA (D) A,B
x
1 2

x e x 1 sin t dt x (0,)
2
5. -
0
(A) x (0,) '

(B) x (0,) ''
(C) '
(D) > 0
|(x)| > |'(x)| x ()
6.
x
8x 16x3 + 16x2 8x + a = 0, (a R)
4

1
(A) 1 (B) 2 (C) (D)
2

H-24/32 0000CT103115006
MATHEMATICS
n 4 n 5
x x
7. lim x 1 x 1 4
t
-
n n n
5
t 9 t
x x
x 1 x 1
(A) 1 (B) 2 (C) 3 (D) 7
8.
2x y = 8, x 2y = 17
L = 0
L
-
11 2
(A) 1 (B) (C) 1 (D)
2 11
A C 1
9.
ABC
tan tan
-
2 2 3
2ac B A C 2
(A) b (B) tan tan tan
ac 2 2 2 3
B A C 4
(C) tan tan tan (D) a,b,c
2 2 2 3
sec 4 sec 4
10. (
)
-
tan 2 tan 2
(A) 4 (B) 6 (C) 8 (D) 10

0000CT103115006 H-25/32
II : (: 16)
MATHEMATICS

-I

-II
-I

(A), (B), (C) (D)
-II

(P), (Q), (R), (S) (T)
-I
-II
-I -II

4 5

:
(A) (P) (Q) (R) (S) (T)
(B) (P) (Q) (R) (S) (T)
(C) (P) (Q) (R) (S) (T)
(D) (P) (Q) (R) (S) (T)
-I

-I
(A)
(Q), (R)
(T)

(B), (C) (D)
:
-I
+2
0
1
1. -I
-II
4
r
(A) tan k 3
k (P) 3
r0 15 5
n 1
nr 55
(B) (n = 10)
k (Q) 4
r 0 r 1 r 2 r 3 3k

(C)
(0,0) (R) 8

2
x2 + y2 + 4x + 1 = 0
k

k
1
(D) 5x 2 2 7xy y 2 2x 1 0 (S)
3

k
tan2k (T) 5
H-26/32 0000CT103115006
A,
n n, n > 2 -
MATHEMATICS
2.
-I
-II
1 n1
(A) (adjA) (P) 2 (adj A)
A
(B) adj(2A) (Q)
|A|
(C) adj(adj A) (R) |A|n2A
1
(D) adjA (S) adjA
adj(adjA)
(T)
| A |n 1

III :
III
0000CT103115006 H-27/32
IV : ( : 32)
MATHEMATICS

0 9

:
+4
0
1 1 1 1
1. a1 , a n 1 a 2n a n ,S ....
[S]
2 a1 1 a 2 1 a100 1
([.]
)
x
2. (x)
(x) + '(x) + ''(x) + '''(x) = x3 g x dx
x3
g(1) = 1
| g(e) |
(
[.],
e,
)
3. x 2 2 log 2 2 x 3x 2 x

H-28/32 0000CT103115006
MATHEMATICS
a
4. (y 5)2 = 8(x 1)
x2 + y2 = 9
tan 1
b

a
b
(a b)
1 3 12 4 16
5.
2 tan 1 sin 1
sin 1 cos1 cot 1
2sin
cos
2 5 13 5 63
x2 px + q = 0
(p q)
6.
< an >
2 cotx
sin2x
< bn >

sin2x
sin2x
x 0,
i b j
a
4 i 1 j1
0000CT103115006 H-29/32

MATHEMATICS
7. OABC OA
a, OB
b
p
OC a b a b
(p q )
2
q
q
2p
(
[.]
)

3 1

dx
3
8. 1
1 x 1 x 2
1 3
H-30/32 0000CT103115006

0000CT103115006 H-31/32
15.

16.

17.

18.

:
19.

20.

21. g = 10 m/s2
................................................................................................
.............................................
____________________________ ____________________________
Corporate Office : CAREER INSTITUTE, SANKALP, CP-6, Indra Vihar, Kota (Rajasthan)-324005
+91-744-5156100 info@allen.ac.in www.allen.ac.in
H-32/32 Your Target is to secure Good Rank in JEE 2016 0000CT103115006

Classroom Contact Programme: Jee (Main + Advanced) : Leader & Enthusiast Course

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Paper Code : 0000CT103115 006

JEE (Main + Advanced) : LEADER & ENTHUSIAST COURSE

READ THE INSTRUCTIONS CAREFULLY

DO NOT BREAK THE SEALS WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR

QUESTION PAPER FORMAT AND MARKING SCHEME :

7. Carefully read the instructions given at the beginning of each section.

10. There is no questions in SECTION-III

Marking scheme : +4 for correct answer and 0 in all other cases.

OPTICAL RESPONSE SHEET :

13. Do not tamper with or mutilate the ORS.

SOME USEFUL CONSTANTS

Space for Rough Work

(A) Just after switch S1 is closed, VL = 10 V

Space for Rough Work

This section contains TWO questions.

(B) (P) (Q) (R) (S) (T)

(C) (P) (Q) (R) (S) (T)

(D) (P) (Q) (R) (S) (T)

(D) magnified image (S)

Space for Rough Work

SECTIONIII : Integer Value Correct Type

This section contains EIGHT questions.

Space for Rough Work

Space for Rough Work

Space for Rough Work

Space for Rough Work

SECTIONI : (Maximum Marks : 40)

(A) K 0p1 2 1025 (B) K 0p2 = 0.2

HN3 , (i) LAH

(A) X is CH3CNH2 (B) Y is CH3CH2Br

(C) X is CH3CNHCH2CH3 (D) X is CH3NH2

Space for Rough Work

10. Correct statement(s) regarding following reaction sequence is/are :

(A) P & S can be distinguished by dye azo test

(B) S is more basic than P

(C) R give benzophenone with PhMgBr followed by H3O

(D) Q on passing with steam produces phenol

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(T) Product does not give efferrescence of

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SECTIONIII : Integer Value Correct Type

4. Total number of TRUE statements about silicones/silicates ?

(i) Silicones resist oxidation and attack by organic reagents

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7. Number of pair of enantiomers possible for bromochlorocyclopentane if X.

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(i) Backelite is thermosetting polymer.

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(A) ' exists and is continuous x (0,)

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SECTIONII : (Maximum Marks : 16)

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SECTIONIII : Integer Value Correct Type

SECTIONIV : (Maximum Marks : 32)

3. The number of solution of the equation x 2 2 log 2 2 x 3x 2 x is

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7. Let OABC be a t etrahedron whose edges are of unit lengt h. If OA a, OB b, and

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DARKENING THE BUBBLES ON THE ORS :

16. Darken the bubble COMPLETELY.

18. The correct way of darkening a bubble is as shown here :