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l 2
(a) A > 2.0 cm (b) A = 2.0 cm l
(c) 2 (d) 2pe a
(c) A < 2.0 cm (d) A = 1.5 cm 4 p e 0 a 0
CH3 CH2Cl
58. Which of the following reagent(s) used for the conversion? (b) Boiling
+Cl2
O O
OH
CO2Et Anh. AlCl3
(c) +CH3Cl
(a) glycol/LiAlH4/H3O+ (b) glycol/NaH/H3O+
(c) LiA1H4 (d) NaBH4 CH3
59. Match List I and List II and choose the correct matching
codes
List I List II
CH2Cl
A. [Ni(CN)4]2 1. Ti4+ (d) + AgNO2
B. Chlorophyll 2. sp3; paramagnetic
C. Ziegler - Natta 3. Non-planar CH2NO2
catalyst
D. [NiCl4]2 4. Mg2+
E. Deoxyhaemoglobin 5. Planar 65. In reaction sequence
6. dsp2; diamagnetic CH2OH
Hypochlorous R
(a) A-6; B-4; C-1; D-2; E-3 CH 2 = CH 2 M |
acid CH2OH
(b) A-2; B-4; C-1; D-6; E-3
(c) A-2; B-4; C-1; D-6; E-5 molecule 'M' and reagent 'R' respectively are
(d) A-6; B-4; C-1; D-2; E-5 (a) CH3CH2Cl and NaOH
60. Decreasing order of reactivity toward nucleophilic addition (b) CH3CH2OH and H2SO4
to carbonyl group among cyclopentanone, 3-pentanone and (c) CH2Cl . CH2OH and aqueous NaHCO3
n-pentanal is (d) CH2 CH2 and heat
(a) 3-pentanone, cyclopentanone, n-pentanal
(b) n-pentanal, 3-pentanone, cyclopentanone O
(c) n-pentanal, cyclopentanone, 3-pentanone 66. Number of chiral carbons in
(d) cyclopentanone, 3-pentanone, n-pentanal b - D - (+) - glucose is
61. The linkage between the two monosaccharide units in (a) five (b) six
lactose is (c) three (d) four
(a) C1 of b-D-glucose and C4 of b-D-galactose 67. Reactivity order of halides for dehydrohalogenation is
(b) C1 of b-D-galactose and C4 of b-D-glucose (a) R F > R Cl > R Br > R I
(c) C1 of a-D-galactose and C4 of b-D-glucose (b) R I > R Br > R Cl > R F
(d) C1 of b-D-galactose and C4 of a-D-glucose (c) R I > R Cl > R Br > R F
62. Pick out the correct statements from the following and (d) R F > R I > R Br > R Cl
choose the correct answer from the codes given below: 68. The ionization constant of phenol is higher than that of
1. Hexa-1, 5-diene is a conjugated diene ethanol because :
2. Prop-1, 2-diene is conjugated diene (a) phenoxide ion is bulkier than ethoxide
3. Hexa-1, 3-diene is a conjugated diene (b) phenoxide ion is stronger base than ethoxide
4. Buta-1,3-diene is an isolated diene (c) phenoxide ion is stabilized through delocalization
5. Prop-1, 2-diene is a cumulative diene (d) phenoxide ion is less stable than ethoxide
x 2 1 (a) 4 (b) 5
2 p
84. The equation 2 cos sin x = x 2 + 2 , 0 x has
2 x 2 (c) 6 (d) 7
(a) one real solution 91. The value of cos20 + cos100 + cos140 is equal to
(b) no real solution 1 1
(c) more than one real solution (a) (b)
2 3
(d) none of these
85. If log a, log b, and log c are in A.P. and also log a log 2b, (c) 3 (d) 0
log 2b log 3c, log 3c log a are in A.P., then :
(a) a, b, c, are in H.P. 3 1
92. If a = sin -1 + sin -1
(b) a, 2b, 3c are in A.P. 2 3
(c) a, b, c are the sides of a triangle
(d) none of the above 3 1
and b = cos -1 + cos -1 , then :
86. Which of the following is correct ? 2 3
y 3 y5 x3
x 5 (a) a<b (b) a =b
(a) If y + + + .... = 2 x + + + ....
3 5 3 5 (c) a >b (d) a + b = 2p
then y = 2 x 2 - x 93. If P(n) : 3n < n!, n N, then P(n) is true
(a) for n 6 (b) for n 7
2 3
a-b 1a-b 1a -b (c) for n 3 (d) for all n.
(b) + + + ..... = log ab
a 2 a 3 a
94. If a,b, g are the altitudes of a triangle, then a -1 + b -1 + g -1 =
1 2 2 3 3 4 x
(c) x + x + x + .. = + log(1 - x) (a) D/s (b) s/D
2 3 4 1- x
(c) sD (d) s / D2
(d) log 4 2 - log 8 2 + log16 2 - ..... = - log 2
95. The position of points O (0, 0) and P (2, 2) in the region of
87. Findout incorrect sum in the following :
graph of inequation 2x 3y < 5, will be
1+ a 1+ a + a 2 ea - e (a) O inside and P outside
(a) 1+ + + ..... = (b) O and P both inside
2! 3! a -1
(c) O and P both outside
19 35 57 85 (d) O outside and P inside
(b) 9+ + + + + .... = 12e - 5
2 ! 3! 4 ! 5 !
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8
104. Let f(x) be continuous at x = 0 and f(0) = 4.
16 1
96. If sin a = , then the value of 2f ( x) - 3f (2x ) + f (4x )
5 Then value of = lim is
h 0 x2
1 1 2 4 (a) 12 (b) 10
2
+ 2
+ + is equal to
cos a 1 + sin a 1 + sin a 1 + sin8 a
4
(c) 6 (d) 4
(a) 2 (b) 4 2 3 n dy
105. If y = e x e x e x ...e x ..., for 0 < x < 1, then at
(c) 6 (d) 8 dx
97. The equation of the pair of straight lines parallel to the y-
1
axis and which are tangents to the circle x= is
2
x 2 + y 2 - 6x - 4 y - 12 = 0 is (a) e (b) 4e
(c) 2e (d) 3e
(a) x 2 - 4 y - 21 = 0 (b) x 2 - 5x + 6 = 0 106. Let f(x) = xn, n being a non-negative integer. The value of n
for which equality
(c) x 2 - 6 x - 16 = 0 (d) None of these f (a + b) = f(a) + f (b) is valid for all a, b > 0 is :
98. If a and c are positive real numbers and the ellipse (a) 5 (b) 1
(c) 2 (d) 4
x2 y2
+ = 1 has four distinct points in common with the kx
4c 2 c2 107. The angle at which the curve y = ke intersects the
y-axis is :
circle x2 + y2 = 9a2 , then
(a) tan1(k2) (b) cot1(k2)
(a) 9ac 9a2 2c2 < 0 (b) 6ac + 9a2 2c2 < 0
2 2
(c) 9ac 9a 2c > 0 (d) 6ac + 9a2 2c2 > 0 1
99. If the eccentricity of the hyperbola (c) sin -1 (d) sec -1 1 + k 4
4
1+ k
x 2 - y 2 cos ec 2 a
= 25 is 5 times the eccentricity of the
108. The maximum value of the function
2 2 2
ellipse x cos ec a + y = 5 , then a is equal to : a2 b2
y= + , a > 0, b > 0 in (0, a) is :
x a-x
3
(a) tan -1 2 (b) sin -1 1
4 (a) a + b (b)
a+b
2 2
(c) tan -1 (d) sin -1 1 1
5 5 (c) (a + b ) 2 (d) (a + b )
a a2
100. If a point P(x, y) moves along ellipse and if C is the centre of 109. The set of all points, where the function
the ellipse then the sum of maximum and minimum values of
CP is x
f (x) =
(a) 25 (b) 9 (1+ | x |) is differentiable, is
(c) 4 (d) 5 (a) (, ) (b) (0, )
101. Four distinct points (2k, 3k), (1, 0), (0, 1) and (0, 0) lie on (c) (, 0) (0,) (d) None of these
circle for 110. For (2n + 1) observations x1, x1, x2, x2, .........xn, xn and
0 where xs are all distinct. Let S.D. and M.D. denote the
(a) all integral values of k (b) 0 < k < 1
standard deviation and median respectively.Then which of
(c) k < 0 (d) For one value of k
the following is always true?
102. The condition that the straight line cx - by + b 2 = 0 may (a) S.D < M.D.
(b) S.D.> M.D.
touch the circle x 2 + y 2 = ax + by (c) S.D. = M.D.
(d) Nothing can be said in general about the relationship
(a) abc = 1 (b) a = c
of S.D. and M.D.
(c) b = ac (d) None of these
dx
d4y 111. If 2
= A log | x + 1 | + C for x < -1
103. If y = ex cos x and y4 + ky = 0, where y4 = 4 , then k = x + 2x + 1
dx
the A is
(a) 4 (b) 4 (a) 0 (b) 1
(c) 2 (d) 2 (c) 1 (d) None of these
p
(a) 3 6 (b) 2 6
1 3 p
(a) + (b) 1 - +
2 6 2 6 (c) 6 (d) 12
123. Given two independent events, if the probability that exactly
1 p 3 p
(c) - - (d) -1-
26
2 6 2 6
one of them occurs is and the probability that none of
116. The solution to the differential equation 49
dy 15
= e 3x - 2 y + x 2 e - 2 y is them occurs is , then the probability of more probable of
dx 49
the two events is :
(a) e 2 y = e3x + x 3 + C (b) 3e 2 y = 2 (e 3x + x 3 ) + c (a) 4/7 (b) 6/7
(c) 3/7 (d) 5/7
e 3x + 2 y = x 3 + c
(c) (d) none of these.
117. The solution of the differential equation 124. Let u , v and w be vectors such that u + v + w = 0 .
( xy 2 + x )dx + ( yx 2 + y)dy= 0 is If
2 2 | u |= 3, | v |= 4 and | w |= 5 , then
(a) ( x 2 + 1)(y 2 + 1) = c (b) ex + ey =c
u . v + v . w + w . u is
(c) ( y 2 + 1) = c ( x 2 + 1) (d) none of these.
(a) 47 (b) 25
118. If a = i + 2 j + 3k , b = 2i + 3 j + k , c = 3i + j + 2 k and (c) 0 (d) 25
125. A rectangular parallelopiped is formed by drawing planes
a a + b b + g c= - 3( i - k ) , then the number triple through the points (1, 2, 5) and (1, 1, 1) and parallel to the
coordinate planes. The length of the diagonal of the
(a, b, g ) is
parallelopiped is
(a) (2, 1, 1) (b) (2, 1, 1) (a) 2 (b) 3
(c) (2, 1, 1) (d) (2, 1, 1) (c) 6 (d) 7
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Section IV - English Proficiency & Logical that does not bolong to the group.
(a) bonafide (b) genuine
Reasoning (c) credential (d) authentic
English Proficiency 133. Directions: In the following question, a part of the sentence
is italicized. Below are given alternatives to the italicized
126. Choose the correct synonym for the given word. part which may improve the sentence. Choose the correct
NAIVE alternative
(a) popular (b) unsophisticated From where did he obtain the money is a mystery.
(c) knowledge (d) wise (a) Where from did he obtain the money
127. Choose the correct antonym for the given word. (b) Where did he obtain the money from
(c) Where he obtained the money from
CALLOW
(d) No improvement
(a) experienced (b) naive
134. Directions: In the following question, you are given
(c) informal (d) follish oneblank. The question is followed by four choices, only
128. Directions: Choose the option which contains a pair of one of which fits the blank appropriately. That correct choice
words related to each other in the same way as the pair is your answer.
given in capital letters. The petition before the court prayed for ....... the
EULOGY : SPEECH appointment orders issued by the management.
(a) euphoria : feelings (a) removing (b) granting
(b) eureka : discovery (c) posting (d) quashing
(c) euthanasia : painless 135. Directions: In the following sentence, choose the most
(d) eucalyptus : wood appropriate verb.
129. Directions: In the following questions, each sentence has Everything he told me, I ...... before.
four underlined words or phrases marked A, B, C and D. (a) had heard (b) heard
Choose the word or phrase that must be changed for the (c) have heard (d) hear
sentence to be correct. 136. Directions: Below question has an idiomatic expression
followed by four options. Choose the one closest to its
On second thoughts the employee has withdraws meaning.
A B To fight to the bitter end
his resignation from his job a week ago. No error (a) To fight with poison-tipped arrows
C
(b) To fight to the last point of enemy position
D
(c) To die fighting
(a) A (b) B (d) To carry on a contest regardless of consequences
(c) C (d) D 137. In the question below are given two sentences numbered I
130. Directions: Arrange the sentences, P, Q, R and S to form a and II. In these sentences, two homonyms are given in italics
logical sequence between sentences 1 and 6. type, which may be either mis-spelt or inappropriate in the
1. There was once a Persian king called Shahryar who context of the sentences. Read both the sentences carefully
had a beautiful wife. and decide on their correctness on the basis of the italicized
P: When the king discovered this he killed her. words.
Q: He gave orders that he was to be provided with a new I. An ordnance declaring presidents rule in the state
wife every day. has been issued today.
II. The ordinance depot is situated far away form this
R: He loved her very much, but she was wicked woman. city.
S: He decided that all women were wicked and that he (a) if only sentence I is correct;
would punish them. (b) if only sentence II is correct;
6: After one days marriage he would cut off her head and (c) if both the sentences I and II are correct;
marry again. (d) if I as well as II are incorrect, but both could be made
(a) PQRS (b) QSPR correct by interchanging the italicised words;
(c) RPSQ (d) SPRQ Directions for Q.138 to 140. Read the following passage carefully
131. Directions : In the following question, a sentence has been and answer the questions given below in the passage. Certain
given in Active (or Passive) Voice. Out of the four words/phrases in the passage are given in bold to locate them
alternatives suggested select the one which best expresses while answering some of the questions.
the same sentence in Passive (or Active) voice. In this life, there are no gains without pains. Life indeed would be
The Romans expected to conquer Carthage. dull if there were no difficulties. Games lose their zest if there is no
(a) Carthage was expected to be conquered by the Romans. real struggle and if the result is a foregone conclusion. Both the
(b) The Romans were expected to conquer Carthage. winner and the loser enjoy a game most its closely contested to
(c) It was expected by the Romans that they would conquer the last. No victory is a real triumph unless the foe is worthy of the
Carthage. steel. Whether we like it or not. Life is one continuous competitive
(d) The Romans expected to have conquered Carthage. examination.
132. Directions : The question has four items. Select the item 138. Which of the following represents the central idea of the
(c) (d)
(a) (b)
X Y Z
(c) (d)
149. In the following question, select the answer figure that will (a)
fit in the blank space in the question figure, maintaining the
pattern in the proper sequence.
(b)
(c)
(d)
ADDITIONAL QUESTION
1. Electrons are accelerated through a potential difference V (a) NH4NO3, N2O, H2O (b) NH4NO2, NO, H2O
and protons are accelerated through a potential difference 4 (c) CaO, H2O, CaCl2 (d) Ba(NO3)2, H2O, NO2
V. The de-Broglie wavelengths are le and lp for electrons 7. In the following equilibrium reaction
B + C,
2A
le
and protons respectively. The ratio of is given by : the equilibrium concentrations of A, B and C are 1 103 M,
lp 2 103 M and 3 103 M respectively at 300 K. The value
(given me is mass of electron and mp is mass of proton). of Kc for this equilibrium at the same temperature is
le mp le me 1
(a) = (b) = (a) (b) 6
lp me lp mp 6
1
le 1 me le mp (c) (d) 36
(c) = (d) =2 36
l p 2 mp lp me 8. An organic compound A containing nitrogen, on acid
2. The surface charge density of a thin charged disc of radius catalysed hydrolysis produces a water soluble organic
compound B and a gaseous compound C. When methyl
R is s. The value of the electric field at the centre of the disc
s magnesium bromide is slowly added to A in 1 : 1 ratio and
is . With respect to the field at the centre, the electric hydrolysed, it produces a compound which can be obtained
2 0
by dry distillation of the calcium salt of B. The compound A
field along the axis at a distance R from the centre of the disc : is
(a) reduces by 70.7% (b) reduces by 29.3% (a) N-methylmethanamide
(c) reduces by 9.7% (d) reduces by 14.6% (b) N-ethylmethanamide
3. A tennis ball (treated as hollow spherical shell) starting from (c) acetonitrile
O rolls down a hill. At point A the ball becomes air borne (d) N, N-dimethylmethanamide
leaving at an angle of 30 with the horizontal. The ball strikes 9. For integers m and n, both greater than 1, consider the
the ground at B. What is the value of the distance AB ? following three statements :
(Moment of inertia of a spherical shell of mass m and radius P : m divides n
2 Q : m divides n2
R about its diameter = mR 2 ) R : m is prime,
3
(a) 1.87 m (b) 2.08 m then
(c) 1.57 m (d) 1.77 m (a) QR P (b) PQ R
4. Six equal resistances are connected between points P, Q
and R as shown in figure. Then net resistance will be maximum (c) QR (d) Q P
r r
between : 10. If a and b are non-collinear vectors, then the value of a for
P r r r r r r
which the vectors u = (a - 2)a + b and v = (2 + 3a)a - 3b
are collinear is :
r 3 2
r (a) (b)
r 2 3
r
r 3 2
(c) (d)
2 3
Q R
r 11. If the complex numbers sin x + i cos 2x and cos x i sin 2x are
(a) P and R (b) P and Q conjugate to each other, then x is equal to :
(c) Q and R (d) Any two points 1
(a) np (b) n + p
5. How many molecules of CO2 are formed when one milligram 2
(c) 0 (d) None of these
of 100% pure CaCO3 is treated with excess hydrochloric
12. The term independent of x in expansion of
acid?
(a) 6.023 1023 (b) 6.023 1021 x +1 x -1
10