6. 5.0 liter container at 20C has 4 gases pumped in.

The total pressure of the

gases is 4.80 atm. If the pressure of the first, second and third gas is 1.2
atm, 0.490 atm, and 0.780 atm, respectively. What is the partial pressure
of the fourth gas? (Source: http://www.instruction.greenriver.edu)
6. 455 mL of oxygen gas was collected over water at a temperature 0f 85C. The total
pressure of the gases is 65.8 kPa. What is the pressure, in kPa, of the dry oxygen
gas? (Source: http://www.instruction.greenriver.edu)
7. A volatile liquid is placed in a flask whose volume is 590.0 ml and allowed to boil
until all of the liquid is gone, and only vapor fills the flask at a temperature of 100C
and 736 mm Hg pressure. If the mass of the flask before and after the experiment
was 148.375g and 149.457 g, what is the molar mass of the liquid?
(Source: http://www.oldsaybrookschools.org)
8. A sample of natural gas is collected at 25.0C in a 250.0 mL flask. If the sample
had a mass of 0.118 g at a pressure of 550.0 torr, what is the molecular weight of
the gas? (Source: http://www.oldsaybrookschools.org)
9. Calculate the mass of hydrogen gas collected over water if 156.0 mL of gas is
collected at 20.0C and 769.0 mmHg. What mass of zinc reacted?
(Source: http://www.oldsaybrookschools.org)
10. In a Diesel cycle, the compression ratio is 15. Compression begins at 0.1 Mpa,
40C. The heat added is 1.675 MJ/kg. Find (a) the maximum temperature in the
cycle, (b) work done per kg of air (c) the cycle efficiency (d) the temperature at the
end of the isentropic expansion (e) the cut-off ratio and (f) the MEP of the cycle.
(Source:http://nptel.ac.in/courses/101101001/downloads/lec20-problem
solution.pdf )
11. In an air standard Otto cycle, the compression ratio is 7 and the compression
begins at 35C and 0.1 MPa. The maximum temperature of the cycle is 1100C.
Find (a) the temperature and the pressure at various points in the cycle, (b) the
heat supplied per kg of air, (c) work done per kg of air, (d) the cycle efficiency and
(e) the MEP of the cycle.
(Source:http://nptel.ac.in/courses/101101001/downloads/lec20-problem
solution.pdf )
12. A gasoline engine receives air at 10C, 100 kPa, having a compression ratio of 9:1
by volume. The heat addition by combustion gives the highest temperature as
2500 K. use cold air properties to find the highest cycle pressure, the specific
energy added by combustion, and the mean effective pressure.
(Source:http://nptel.ac.in/courses/101101001/downloads/lec20-problem
solution.pdf )
13. A diesel engine has a compression ratio of 20:1 with an inlet of 95 kPa, 290 K, with
volume 0.5 L. The maximum cycle temperature is 1800 K. Find the maximum
pressure, the net specific work and the thermal efficiency.
(Source:http://nptel.ac.in/courses/101101001/downloads/lec20-problem
solution.pdf )
14. Otto cycle with compression ratio of 9.5. The air is at 100 kPa, 17 C, and 600 cm
prior to the compresion stroke. Temperature at the end of isentropic expansion is
800 K. Find: a) Highest temperature and pressure in the cycle, b) amount of heat
transferred, c) thermal efficiency, and d) mean effective pressure. Use constant
specific heat. (Source: http://emerald.tufts.edu/as/tampl/es7/hw/hw7soln.pdf)
15. Diesel cycle with a compresion ratio of 16 and a cutoff ratio of 2. The air is at 95
kPa and 27 C at the beginning of compression process. Find: a) temperature after
heat addition, b) thermal efficiency, and c) mean effective pressure of the process.
Use variable specific heats.
(Source: http://emerald.tufts.edu/as/tampl/es7/hw/hw7soln.pdf)
16. Stirling cycle with helium operates between temperature limits of 300 K and 2000
K and pressure limits of 150 kPa and 3 MPa. The mass of helium used in the cycle
is 0.12 kg. Find: a) thermal efficiency of the cycle; b) amount of heat transferred to
the regenerator, and c) work output per cycle.
(Source: http://emerald.tufts.edu/as/tampl/es7/hw/hw7soln.pdf)
17. Brayton cycle with air; pressure ratio is 12. Air enters the compressor at 300 K and
enters the turbine at 1000 K. Net power output is 90 MW. Find: The required mass
flow rate for turbine and compressor isentropic efficiencies of a) 100 percent, and
b) 80 percent. Use constant specific heats.
(Source: http://emerald.tufts.edu/as/tampl/es7/hw/hw7soln.pdf)
18. Brayton cycle with air, with power output of 15 MW. The temperature limits are 310
K and 900 K, and the pressure ratio is 8. The compressor and turbine have
isentropic efficiencies of 80 percent and 86 percent, respectively. Find: The
required mass flow rate for turbine using variable specific heat.
(Source: http://emerald.tufts.edu/as/tampl/es7/hw/hw7soln.pdf)
19. Regenerative gas-turbine engine. Air enters the compressor at 300 K and 100 kPa,
and leaves the compressor at 800 kPa and 580 K. The regenerator effectiveness
is 72 percent, and the air enters the turbine at 1200 K. The turbine has an efficiency
of 86 percent. Find: a) Amount of heat transfer in the regenerator, and b) thermal
efficiency of the cycle. Use variable specific heats.
(Source: http://emerald.tufts.edu/as/tampl/es7/hw/hw7soln.pdf)
20. A solution of hydrochloric acid was formed by dissolving 1.52 g of hydrogen
chloride gas in enough water to make 24.1 mL of solution. What is the
concentration in percent (m/v) of the solution? (Source: http://www.dpcdsb.org)
21. At 25C, a saturated solution of carbon dioxide gas in water has a concentration of
0.145% (m/v). What mass of carbon dioxide is present in 250 mL of the solution?
(Source: http://www.dpcdsb.org)
22. Ringers solution contains three dissolved salts in the same proportions as they
are found in blood. The salts and their concentrations (m/v) are as follows: 0.86%
NaCl, 0.03% KCl, and 0.033% CaCl2. Suppose that a patient needs to receive 350
mL of Ringers solution by an intravenous drip. What mass of each salt does the
pharmacist need to make the solution? (Source: http://www.dpcdsb.org)
23. If 55 g of potassium hydroxide are dissolved in 100 g of water, what is the
concentration of the solution expressed as mass/mass percent?
(Source: http://www.dpcdsb.org)
24. Steel is an alloy of iron and about 1.7% carbon. It also contains small amounts of
other materials, such as manganese and phosphorus. What mass of carbon is
needed to make a 5.0 kg sample of steel? (Source: http://www.dpcdsb.org)
25. Stainless steel is a variety of steel that resists corrosion. Your cutlery at home may
be made of this material. Stainless steel must contain at least 10.5% chromium.
What mass of chromium is needed to make a stainless steel fork with a mass of
60.5 g? (Source: http://www.dpcdsb.org)
26. 18-carat white gold is an alloy. It contains 75% gold, 12.5% silver, and 12.5%
copper. A piece of jewelry, made of 18-carat white gold, has a mass of 20g. How
much pure gold does it contain? (Source: http://www.dpcdsb.org)
27. 60 mL of ethanol is diluted with water to a final volume of 400 mL. What is the
percent by volume of ethanol in the solution? (Source: http://www.dpcdsb.org)
28. Milk fat is present in milk. Whole milk usually contains about 5.0% milk fat by
volume. If you drink a glass of milk with a volume of 250 mL, what volume of milk
fat have you consumed? (Source: http://www.dpcdsb.org)
29. Vinegar is sold as a 5% (v/v) solution of acetic acid in water. How much water
should be added to 15 mL of pure acetic acid (a liquid at room temperature) to
make a 5%(v/v) solution of acetic acid. Note: Assume that when water and acetic
acid are mixed, the total volume of the solution is the sum of the volumes of each.
(Source: http://www.dpcdsb.org)