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DXAMMONIAPIPINGHANDBOOK
BruceI.Nelson,P.E.




TABLEOFCONTENTS

          Page
Background          2
SystemConfiguration         4
SystemStability         4
EvaporatorSelectionandOperation       6
 DT1vsDTMRatings        6
 SensibleHeatRatio,Roomrh%,andEvaporatorRatings    7
 OptimizingSystemTD        10
 EffectofTDonExpansionValveOperation     15
 TypesofFrostandSelectionofFinSpacing     16
CondenserSelectionandOperation       22
Subcooling          23
PipingGeneral         26
LiquidLines          27
SuctionLines          28
HotGasLines          28
EffectsofWaterinAmmoniaandItsRemoval      29
 Separation         32
 DistillationandDisposalofAmmoniumHydroxide    32
 LiquidTransfer         36
EffectsofOilonEvaporatorPerformanceandOilSeparation    37
EstimatingDXEvaporatorRefrigerantChargeInventory     40
ColmacSmartHotGasDefrost        41
CalculatingtheCostofDefrost        42
SmartHotGasSequenceofOperation       46
DefrostWaterVolumeandDrainLineSizing      47
References          50
APPENDIXADXAmmoniaP&ID       52
 Figure1SingleStage
 Figure2SingleStageEconomizedScrew
 Figure3TwoStage
 
 



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I. Background

Ammoniarefrigerationsystemshavetraditionallyemployedevaporatorssuppliedwith
liquidbyeithergravityflooding(withsurgedrums),orpumpedoverfeed(eitherwith
mechanicalpumpsordischargegasdrivenvessels).Bothofthesedesignstypicallyuse
bottomfeedcoilcircuitingwhichfeedsliquidammoniaatthelowestpointinthecoilcircuit
andcausestheammoniatoflowupwardandpercolatethroughthecoilinascending
passestotheoutletatthetopofthecircuit.Thesecoildesignsalsotypicallyuselarge
diametertubingwhichmeansrelativelylargecoilinternalvolume.Thiscombinationof
refrigerantfeed,circuiting,andtubediameter,resultsinthegreatestevaporatorcharge
inventorypossible.

Endusersofammoniarefrigerationsystemsareincreasinglyinterestedinreducingthe
chargeofammoniainevaporators(andintheoverallsystem)intheinterestofminimizing
therisktoworkersandproductsassociatedwithammonialeaks.Oneveryeffectivewayto
significantlyreduceevaporatorammoniachargeistodesignandoperatetheevaporator
usingdryexpansion(DX)circuitingandcontrols.UsingDXammoniacanreducethe
evaporatorchargebyasmuchas30to50timescomparedtobottomfeedfloodedor
pumpeddesigns.Themagnitudeofthisreductioninammoniachargemayalsomitigate
regulatoryrequirements(PSM,RMP),andpotentiallyreduceinsuranceriskandpremiums.

DXammoniahasbeenusedforsometimeinmediumandhightemperaturesystems
(suctiontemperaturesabove+20degreesF)withsomesuccess.However,inspiteofthe
chargereductionadvantagesmentionedabove,todateDXammoniahasnotbeenapplied
successfullyatfreezertemperatures.Atsuctiontemperaturesbelowabout+20F,the
followingparticularcharacteristicsofammoniaresultinextremelypoorperformanceof
evaporatorsunlessaddressedandmitigated:

1. Separationofliquidandvaporphases.Theveryhighratioofvaportoliquidspecific
volumeofammoniaatlowtemperaturescombinedwithitsveryhighlatentheatof
vaporizationcausesanunavoidableseparationofvaporandliquidphasesinside
evaporatortubes.Thisseparationofphasescausestheliquidammoniapresenttorun
alongtheverybottomofthetubesleavingthetopofthetubescompletelydry.The
resultisextremelypoorevaporatorperformanceandlowerthanexpectedsuction
temperaturesduringoperation.TosolvethisproblemColmachasdeveloped(and
patented)anenhancementtechnique,whichwhenappliedtotheinsideofevaporator
tubes,causestheliquidammoniapresenttocoattheentireinsidesurfaceofthetubes
bycapillaryaction.PerformancewithColmacenhancedtubetechnologyresultsinDX
ammoniaperformanceatlowtemperatureswhichisasgoodorbetterthan
performancewithbottomfeedpumpedammoniacircuiting.
2. Refrigerantdistributortechnology.Traditionallythedistributionofexpandedrefrigerant
tomultipleparallelevaporatorcircuitshasbeendoneusingarefrigerantdistributor
havingafixedorificeplate.Thisdesigndependsonarelativelylargepressuredrop
(approximately4045psi)acrossthefixedorificetothoroughlymixandequally
distributortheliquidandvaporphasesbeforetheyenterthedistributortubesand
evaporatorcircuits.Thisrelativelyhighpressuredropacrossthedistributorreducesthe

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pressuredropavailablefortheexpansionvalve,andconsequentlylimitshowlow
condensingpressurecanbeallowedtofallduringperiodsoflowambienttemperature.
Theveryhighlatentheatofvaporizationofammoniaresultsinlowrefrigerantmass
flowrateandconsequentlyaverysmallorificediameterforagivencoolingload(the
orificecanbeassmallas1/16diameterinsomecases).Thissmallorificesizeisprone
tofoulingandbeingblockedbyevensmallsizedebris.Otherdisadvantagesofthis
distributordesigninclude:
a. Performanceisverysensitivetoliquidtemperature(subcooling)atthe
expansionvalve.
b. Operatingrangeissmall,atmost50%to125%ofratedcapacity.
c. Theorificeanddistributortubesrestricttheflowofhotgasduringahotgas
defrostcycle.
d. Themaximumnumberofparallelevaporatorcircuitsavailableinasingle
distributorislimitedtoonly15.
ToaddresstheseshortcomingsColmachasdevelopedanew(patentpending)
refrigerantdistributortechnology,theColmacTankDistributor,havingthefollowing
characteristics:
a. RefrigerantpressuredropacrosstheTankDistributorduringoperationisvery
low,only24psi.
b. AnyoilordebrisenteringtheTankDistributoriscapturedinadropleg(whichis
integraltothedesign)beforeitcanenterthecoilandfoultubesurfaces.
c. PerformanceoftheTankDistributoriscompletelyinsensitivetoliquid
temperature(subcooling).
d. Graduatedorificesineachdistributortubeallowequaldistributionof
refrigeranttoallcircuitsoveranextremelywideoperatingrangeof0%to700%
ofratedcapacity.
e. Graduatedorificesandlargediameterdistributortubesallowfullflow(minimal
restriction)ofhotgasduringhotgasdefrost.
f. ThenumberofparallelevaporatorcircuitspossibleinasingleTankDistributor
canbeashighas48.
3. Removalofwaterfromammonia.Asdescribedelsewhere(Nelson2010),evensmall
amountsofwater(13%)intheammoniawillsignificantlypenalizeDXammonia
evaporatorperformance.Watermustbeeffectivelyremovedduringoperation,
particularlyinfreezingsystemswhichoperateatsuctionpressuresbelowone
atmosphere(inavacuum).Currently,theonlyeffectivewaytoremovewaterfrom
ammoniaisinaheateddistillationvessel(anammoniastill).Thisverynegativeeffect
ofsmallamountsofwateronevaporatorperformancehasnotbeenfullyrecognizedin
thepast,butmustbeaddressedduringthedesignoftheDXammoniasystem.Colmac
hasdevelopedaneffectiveammoniadistillationvesseldesignandinstallationstrategy
whichisdescribedwithinthisHandbook.

Colmachasdeveloped,tested,andpatented(Nelson2011)anewLowTemperatureDX
Ammoniasystemwhichcorrectlyaddressesalloftheaboveissuespeculiartoammoniaasa
refrigerantthathaveheretoforepreventeditsuseatlowsuctiontemperatures.Itisnow
possibletosuccessfullyapplyDXammoniaatsuctiontemperaturesdownto50degreesF.


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ThisPipingHandbookisintendedtoguidethereaderthroughtheprocessofsuccessfully
designingandimplementingDXAmmoniafrom+50Fto50Fandrealizingthebenefitsof:

Dramaticallyreducedammoniacharge
Simplifiedcontrols
Energyefficientdrysuctionline
Reducedlinesizes
Eliminationofammoniarecirculatorpumps

II. SystemConfiguration

ColmacDXAmmoniacanbeappliedtoanytemperaturelevelandsystemconfiguration.
P&IDdiagramsforvarioustypicalsystemsareshowninAppendixA,simplifiedforpurposes
ofclarity.Selectionandsystempipingdetails(reliefvalves,purgers,isolationvalves,vessel
designs,etc)shouldfollowindustryguidelinesasfoundintheIIARAmmoniaPiping
Handbook(IIAR2004).Thediagramsarenotintendedtopresentanexhaustiverangeof
configurationseveryindustrialrefrigerationsystemwillhaveuniquefeaturesand
requirements.Thisinformationispresentedtoillustratethegeneralsystemfeatures
particulartoasuccessfulDXAmmoniadesign.

a. Figure1SingleStageSingleTemperatureLevel
b. Figure2SingleStage(EconomizedScrew)MultipleTemperatureLevel
c. Figure3TwoStageMultipleTemperatureLevel

III. SystemStability

Withliquidoverfeedandgravityfloodedsystems,liquidreturntotherecirculatorvesselor
thesurgedrumisnormalandexpectedthroughthewetsuctionline.Therecirculatorvessel
orsurgedrumeffectivelyseparatesreturningliquidfromvaporandinsuresthatthedry
suctionlinecarriesonlyvaporbacktothecompressor.

DXsystems,ontheotherhand,aredesignedtooperatewithadrysuctionlineandareby
definitionmoresensitivetoliquidfloodback.IndustrialDXsystemsshouldincorporatea
suctionaccumulatorvesseltopreventliquidsluggingofthecompressorduringafloodback
event,however,excessivefloodbackfromevaporatorscancausehighlevelalarmingand
systemshutdownuntiltheexcessliquidinthesuctionaccumulatorcanbetransferredback
tothehighpressuresideofthesystem.Stableandsmoothoperationofthesystemandthe
evaporatorexpansionvalve(s)iscriticaltoavoidingliquidfloodback.Instabilitiesand/or
rapidchangesindischargeandsuctionpressuresduringoperationarethetypicalcauseof
unstableoperationofexpansionvalvesandshouldbeconsideredcarefullybythesystem
designerandoperator(s).

Rapidchangesinsystemdischargepressurecancausesysteminstabilitiesinanumberof
ways.Asuddenreductionindischargepressurecanresultinundesirableflashingofliquid
refrigerantinliquidlinesandwillalsobeaccompaniedbyasympathetic,albeitsmaller,
reductioninsuctionpressure.Asuddenincreaseindischargepressurewillbeaccompanied

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byasympathetic,albeitsmaller,increaseinsuctionpressure.Anincreaseinsuction
pressure,iflargeenoughandrapidenough,willsuppressboilingintheevaporatorswhich
candirectlyleadtoliquidfloodbackfromtheevaporatorstothesuctionaccumulator.

Rapidchangesindischargepressurearenormallycausedby:
a. Condenserfanscyclingonandoff,or
b. Evaporativecondenserpumpscyclingonandoff,or
c. Compressor(s)cyclingonandoff

**NOTE:Designthesystemtolimittherateofchangeincondensingtemperaturetono
morethan5degF/minute.

Rapidchangesinsystemsuctionpressurecanalsoresultinsysteminstabilityandpoor
performance.Itisasuddenincreaseinsuctionpressurethathasthehighestpotentialfor
liquidfloodbackfromDXevaporators.Thissuddenincreaseinsuctionpressureraisesthe
temperatureoftheevaporator,reducestheimposedload,andresultsinliquidrefrigerant
exitingtheevaporatorbeforetheexpansionvalvecanrespondandreducetheflowof
refrigerantenteringtheevaporatoraccordingly.

Rapidchangesinsuctionpressurearenormallycausedby:
a. Compressor(s)cyclingonandoff
b. Multipleliquidfeedsolenoidscyclingonandoff
c. Evaporatorfanscyclingonandoff
d. Evaporatorsstartingorfinishingdefrost
e. Suddenchangesinimposedloadonevaporators

**NOTE:Designthesystemtolimittherateofchangeinsuctiontemperaturetonomore
than2degF/minute.

Followingarerecommendedsystemdesignfeatureswhichwillservetomaximizesystem
pressurestabilityandminimizethepotentialforliquidfloodbackfromevaporators.

1. CondenserFans
a. UseofVFDfanspeedcontrolinsteadoffancyclingforcontrolofheadpressureis
recommended.

2. CondenserPumps
a. Itisalsorecommendedthatevaporativecondensersumpwaterpumpsbeoperated
continuouslyratherthancyclingonandoff,providedambientweatherconditions
allow.

3. CompressorCapacityControl
a. UseofVFDspeedcontrolforcapacitywherepossibleandappropriate.
b. Limitcapacityloading/unloadingsteps(on/off)tonomorethan10%oftotalsystem
capacity.

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c. Limittherateofchangeofsuctiontemperature(speedofscrewcompressorslide
valvemovement)tonogreaterthan2degF/minute.

4. EvaporatorDefrost
a. Defrosttheminimumnumberofevaporatorsatonetime.
b. Useableedlinetoequalizepressureslowlyattheendofdefrost.

5. EvaporatorFans
a. FanspeedandcoolingcapacitycanbecontrolledbyVFD,howeverthefollowing
guidelinesmustbeobservedwhenappliedtoDXevapaorators:
o Rateofchangeinfanspeedmustbegradualandlimitedtoresultinno
morethan2degF/minutechangeinsuctiontemperature.
o Minimumfanspeedmustbesettoproducenolessthan250ft/minface
velocity.
b. Iffansaregoingtobecycledon/offforcapacitycontrol,nomorethan10%ofthe
totalnumberofevaporatorfansshouldbecycledonoroffatthesametime.

6. LiquidFeedSolenoids
a. Avoidcyclingmultipleliquidfeedsolenoidsallatthesametime.i.e.Liquidfeed
solenoidsshouldbecycledsequentially.

7. SuddenchangesinloadonEvaporators
a. Avoidlocatingevaporatordirectlyabovedoorways.
b. Mitigateintermittentprocessloadslocatedclosetoevaporators.

IV. EvaporatorSelectionandOperation

1. DT1vsDTMratings

Asexplainedindetailelsewhere(Nelson2012(a))evaporatormanufacturerstypically
presenttheircapacityratingsusingoneoftwodefinitionsoftemperaturedifference,
DT1orDTM.SomemanufacturerspublishratingsbasedonbothDT1andDTMand
allowthedesignertochoosethepreferreddefinition:

DT1=AirOnTemperatureEvaporatorTemperature
DTM=Average(Room)AirTemperatureEvaporatorTemperature

Figure1belowgraphicallyillustratesthesetwodefinitionsoftemperaturedifferencefor
thesameevaporatorandtheireffectonLMTD(LogMeanTemperatureDifference),and
henceratedcapacity.Inthisexample,thesameevaporatorhavinga20degF
evaporatingtemperatureratedusingDTMproduces33.3%(DTMLMTDof9.6degF
versusDT1LMTDof7.2degF)morecapacitythanthesameevaporatorratedusing
DT1!


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Inshort,byusingtheDTMratingmethodamanufacturercanshowcoolingcapacities
thataremuchhigher(30to40%higher),andsoofferalowercostevaporatorwith
muchlesssurfaceareathanthemanufacturerusingtheDT1ratingmethod.

Unfortunately,onecannotgetsomethingfornothing.Eventhoughevaporators
selectedusingDTMratingswillbecheaperinitiallybecausetheyhavelesssurfacearea,
theywillcausethesystemtorunatalowersuctionpressurewithhigheroperatingcosts
thanevaporatorsselectedusingDT1ratings.Thisdifferenceinoperatingcostbetween
DTMandDT1evaporatorshasbeencalculatedandtheincrementalreturnon
investmentshowntodramaticallyfavorselectingevaporatorsusingDT1ratings(Nelson
2012(b)).Additionally,inthesamearticletheauthorshowsthatthebasicDTM
assumptionthattheaverageairtemperaturewithintheevaporatorequalstheaverage
roomtemperatureisafundamentallyflawedandfalseassumptionbecauseofair
entrainmentandmixingintheroom.

FIGURE1
TemperatureProfilesforDT1vsDTM

(a) DT1=10F(AirOn)TempDifference(b)DTM=10F(Average)TempDifference

DT1 LMTD = 7.2 F DTM LMTD = 9.6 F

Inconclusion,ColmachighlyrecommendsthatevaporatorsbeselectedusingDT1ratings
ratherthanDTM.

2. SensibleHeatRatio,RoomRelativeHumidity(rh%),andEvaporatorRatings

Accuratepredictionoftherefrigerationload,bothsensibleandlatentcomponents,is
importanttoproperrefrigerationsystemequipmentselectionandsuccessfuloperation
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(Nelson2012(a)).Varioustypesofsensiblecoolingloadsmustbeanticipatedand
includedinthecalculation,suchas:lighting,electricmotors,forklifts,product
cooling/freezing,transmissionofheatthroughwalls,ceilings,andfloors,andcoolingof
infiltrationair.Latentcoolingloadsarepresentwhenevermoistureisaddedtotheairin
therefrigeratedspace.Sourcesofintroducedmoisturetypicallyinclude:infiltrationair,
respiringfoodproducts,surfacemoistureonproducts,packagingandotherobjects
enteringthespace,residualwaterleftonfloorsafterwashdown(processrooms),
humanrespiration,andhumidificationequipment(abovefreezing).

Roomrelativehumidity(rh%),whichistheindicationofhownearlytheairinthe
refrigeratedspaceissaturatedwithwatervapor,willbetheequilibriumcondition
resultingfromthebalanceofmoistureintroducedintothespacewiththemoisture
removedfromspacebytheevaporatorcoils(Cleland2012).

Wheneverevaporatorsurfacesoperateattemperaturesbelowthedewpointoftheair
beingcooled,watervaporintheairstreamiscondensedtoliquid(attemperatures
above32F(0C))ordepositedtoformfrost(below32F(0C)).Thecoolingeffect
associatedwiththisdehumidificationoftheairstreamistermedlatentcooling.The
sumofthesensiblecoolingloadandlatentcoolingloadistermedthetotalload.The
ratioofthesensiblecoolingloaddividedbythetotalcoolingloadiscalledtheSensible
HeatRatio(SHR)anddefinestheslopeoftheairprocesslineonapsychrometricchart.

     

    
   (1)



Refrigeratedspaceswithproductbeingtransferringinandoutthroughdoorwayswill
verytypicallyhavearelativehumidityinthe85to95%rangeduetoinfiltrationand
othersourcesofmoisture.Lowerroomrelativehumiditymaybefoundinsome
exceptionalcaseswheretrafficthroughdoorwaysisverylight,productistightly
packaged,dehumidificationequipmentisusedatdoorways,etc.Therelationship
betweenroomrelativehumidityandSHRisshowninTable1below:

TABLE1
SHRFORDT1=10degFATVARIOUSTEMPERATURESANDROOMRH%
  SensibleHeatRatio,SHR

RoomTemperature,F(C) 65%rh 75%rh 85%rh 95%rh
 45(7.2) 1.0 0.84 0.67 0.56
 32(0) 0.98 0.84 0.73 0.64

10(12.2) 0.98 0.92 0.87 0.83

0(17.8) 0.98 0.95 0.92 0.89

10(23.3) 0.99 0.97 0.95 0.93

30(34.4) 0.99 0.99 0.98 0.97

TheroomrelativehumidityandresultingSHRcanhavealargeeffectonevaporator
coolingcapacity,especiallyathigherroomtemperatures.

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Usingacomputermodeldevelopedtoaccuratelycalculatefinefficiencyandsurface
effectivenessforbothsensibleandcombinedsensibleandlatentheattransfer,a
predictionoftheincreaseinevaporatorcoilperformanceasafunctionofSHRhasbeen
made(Nelson2012(a)).ResultsofthepredictedcapacityincreaseasafunctionofSHR
foranammoniarefrigerationevaporatorcoiloperatingoverawiderangeofroom
temperatures(+45Fto30F)andhavingtypicalfinspacingsandgeometrywithDT1=
10FareshowninFigure2below.

 FIGURE2
 TotalCoolingCapacityFactorvsSHR
 1.5

CapacityFactor,Qtotal/Qsensonly

1.45

 1.4

 1.35
 1.3
 1.25
 1.2

1.15

1.1

 1.05
 1
 0.6 0.65 0.7 0.75 0.8 0.85 0.9 0.95 1
 SensibleHeatRatio,SHR

Tomakethingsabitmorecomplicated,someevaporatormanufacturersincludethe
effectofroomrh%intheirratings,othersdonot.AsshowninFigure2,thelowerthe
SHRthegreaterthetotalcoolingcapacityoftheevaporator.Amanufacturerwhoshows
theirevaporatorratingsasallsensible(SHR=1)willbemoreconservative(havemore
surfacearea)thanthemanufacturerwhoshowstheirratingsat85or95%rh.

Selectingevaporatorsusing85to95%rhratingswillresultinevaporatorshavingless
surfaceareaandlowerfirstcostcomparedtoevaporatorsselectedusingallsensible
ratings.Theriskinthisapproachisundersizingtheevaporatorsinthecasewherethe
actualoperatingroomrh%islessthantherh%usedduringtheselectionprocess.

Conclusion:Thelatentloadshouldalwaysbeestimatedandincludedinthetotal
calculatedrefrigerationload.Sizeevaporatorsforthedesigntotalcalculated
refrigerationloadattheestimatedroomrelativehumidity.Ifroomrelativehumidityis
difficulttoestimateorcannotbeestimated,thenaconservationapproachistoselect
evaporatorsbasedonalowroomrelativehumidity(i.e.65to75%rh)orusingsensible
onlyratings.

3. OptimizingSystemTD

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Theproductbeingstoredorprocessednormallydeterminestheroomairtemperature
inarefrigeratedfacility.Appropriatetemperaturesforstoringandprocessingvarious
foodsandfoodproductscanbefoundelsewhere(ASHRAE2009).

Oncetheroomtemperatureisdetermined,theevaporatortemperaturemustbe
decideduponbythedesigner.Compressorpowerandenergyconsumptionisastrong
functionofthesuctionpressureandtemperature.Thehigherthesuctionpressurethe
moreefficientlythecompressorwillrunandthelesspowerwillbeconsumed.Energy
efficiencycanbecharacterizedbyaratiotermedCoefficientofPerformance(COP),
definedas:

   
       (2)


Inthecaseofarefrigerationcompressor,


           (3)


Figure3belowshowstypicalammoniascrewcompressorCOPvsSST(SaturatedSuction
Temperature).Thefigureassumes2Stagecompressionisusedbelowasuction
temperatureof20degF.

 FIGURE3

 R717ScrewCompressorCOPvsSST
 (SCT=85DegF)
 8

 7

 6


CompressorCOP

5


4


 3


 2

 1
 50 40 30 20 10 0 10 20 30 40
 SST,DegF

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ItwouldappearfromFigure3thatasmallerTD(TD=RoomTemperatureEvaporator
Temperature)wouldalwaysbedesirablefromanenergyconsumptionstandpointsince
thesmallertheTD,thehighertheevaporator(SST)temperatureandcompressorCOP.
This,however,isnotthecase.

Heatistransferredfromtheroomviatheaircirculatedbytheevaporators.Thecooling
capacityofanevaporatorcanbecharacterizedbytheNTUeffectivenessequation.This
equationindicatesthatforaconstantcoolingcapacityandevaporatoreffectiveness(an
expressionofhowcloselytheleavingairtemperatureapproachestheevaporating
temperature),theflowrateoftheairwillbeinverselyproportionaltotheTD.

        
  (4)


Where:



 
 
Evaporatoreffectivenessis,infact,verynearlyconstantoverthetypicalnarrow
operatingrangeofarefrigerationevaporator.Theeffectivenessequationshowsthatas
TDbecomessmaller,theairflowratemustbecomelargerinthesameproportionfora
givencoolingcapacity.

Fanpowercanbecalculatedusingasimpleequationasfollows:



    
      (5)



Where:


 


Theairpressuredropthroughtheevaporatorcoil,andthereforefanpower,willbe
affectedby:
1. Thecoilfacevelocity,
2. Tubediameter,spacing,andpattern,
3. Numberofcoilrowsdeep,
4. Finspacingandpattern
5. Frostthickness


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TherelationshipsaboveindicatethatcompressorCOPwilldecreasewithincreasingTD
whileFanCOPwillincreasewithincreasingTD.Figure4showstheserelationshipsforan
exampleevaporatorcoilhaving8rowsdeepand3FPIfinspacing.

 FIGURE4

 COPvsTD
 8Row3FPI,R717,AirOnTemp=10DegF

7


6


5

4
Fan(500FPM)x10^1
COP

 Fan(750FPM)x10^1
3
Fan(1000FPM)x10^1

2 Compressor

1

0
0 5 10 15 20 25 30 35
 TD=AirOnTemp SuctionTemp,DegF




Figure4impliestherewillbesomemaximumcombinedCOPforcompressorandfans
whichwillrepresenttheoptimumoperatingTDintermsofenergyefficiency.This
combinedCOPisshownbelowinFigures5,6,and7,foratypicalammoniaevaporator
coilhavingthefollowingcharacteristics:

Tubing:7/8ODAluminum
TubePattern:2.25Staggered
Fins:ConfiguredAluminumPlateType
RowsDeep:8
FaceVelocity:500,750,and1000FPM
FinSpacing:2,3,and4FPI
AirOnTemperature:10degF
FrostThickness:0mm




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 FIGURE5

 Compressor+FanCOPvsTD
 8Row4FPI,R717,AirOnTemp=10DegF
 2.4

 2.2

2

 1.8

CombinedCOP

 1.6
 500FPM
1.4
 750FPM
 1.2 1000FPM

 1

0.8

 0.6
 0 5 10 15 20 25 30 35
 TD=AirOnTemp SuctionTemp,DegF



FIGURE6

 Compressor+FanCOPvsTD
 8Row3FPI,R717,AirOnTemp=10DegF

2.6

 2.4

 2.2

 2
CombinedCOP


 1.8 500FPM

 750FPM
1.6
 1000FPM
 1.4

 1.2

 1
 0 5 10 15 20 25 30 35
 TD=AirOnTemp SuctionTemp,DegF

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 FIGURE7

Compressor+FanCOPvsTD

8Row2FPI,R717,AirOnTemp=10DegF

 2.6

2.4

 2.2

 2
CombinedCOP


 1.8 500FPM
 750FPM
1.6
 1000FPM
 1.4

 1.2

 1
 0 5 10 15 20 25 30 35
TD=AirOnTemp SuctionTemp,DegF



ThefollowingisobservedfromFigures5through7:
a. CombinedCOPisaverystrongfunctionofcoilfacevelocity.COPat500FPMis
approximately10%higherthanCOPat750FPMand20%higherthanCOPat
1000FPM.
b. CombinedCOPincreasesasthedistancebetweenfinsisincreased.Coilswith
2FPIspacingwillhavehighercombinedCOPthancoilswith3FPI,whichwillhave
higherCOPthan4FPI.
c. Theoptimum(maximum)TDincreaseswithincreasingfacevelocity.
d. Inallcases,combinedCOPdecreasesveryrapidlybelowabout7degFTD.

InordertomakethefinaldecisionaboutselectingtheoptimumTD,thecostofpower
aswellasinstalledcostofthecompressor(s)andevaporatorsmustbeknown(or
estimated).Thesevariablescanthenbecombinedtocalculatetheincrementalreturn
oninvestmentcomparingdifferentevaporatordesigns(facevelocityandfinspacing)in
termsoffirstcostvsoperatingcost.

Sincethesecostsarehighlyvariable,thefinalreturnoninvestmentcalculationmustbe
madeonacasebycasebasisandpresentedtotheclientinawaywhichallowsthefinal
decisiontobemadegiventheprojectfinancialconstraintsandrequirements.




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Conclusions:
1. ForhighestsystemCOP/energyefficiency,selectevaporatorsforthelowestface
velocityandwidestfinspacingfinanciallypractical.Colmacrecommendsmaximum
facevelocityof600FPMandfinspacingof3FPIorwider(lowerFPI).
2. Forcoilfacevelocitiesbetween500and750FPMadesignTDbetween10degFand
15degFisrecommended.
3. FinaloptimizedevaporatordesignandTDmustbedeterminedbasedonspecific
projectfinancialconstraintsandacceptablereturnoninvestment.

4. EffectofTDonExpansionValve(EV)Operation

Withdirectexpansion(DX)evaporatorstheflowofrefrigeranttotheevaporatoris
meteredbyanautomaticexpansionvalveinresponsetoacontrolsignalmeasuredat
theevaporatoroutlet.Thecontrolsignalisnormallytheamountofsuperheatinthe
refrigerantsuctiongas.Thetheoreticalmaximumamountofsuctiongassuperheatthat
canbegeneratedisequaltotheoperatingTD(TD=AirOnTemperatureEvaporating
Temperature).

Theamountofsuperheatrequiredforstableoperation(modulation)oftheexpansion
valvevarieswiththetypeofvalveemployed.Twobasictypesofexpansionvalvesare
currentlyavailableonthemarket,Thermostatic(TEV)andElectronic(EEV).Bothuse
superheatinthesuctiongasasthecontrolsignal.

Thermostaticexpansionvalvesmeasureandmechanicallycalculatesuperheatbymeans
ofatemperaturesensingbulbandpressureequalizingline.Thesevalvesandtheir
operationaredescribedindetailbythevalvemanufacturers.Theadvantageofthistype
ofvalveistheirlowcostandcompactness.Withthistypeofvalve,temperaturesensing
isaccomplishedbyarefrigerantfilledbulbstrappedtotheoutsideofthecoilsuction
connection.Adisadvantageofthissystemistheadditionalsuperheatrequiredto
overcomethethermalresistanceofthepipewall.Thisadditionalsuperheatforcesthe
operatingTDtobeapproximately5degFgreaterthanforanelectronicexpansionvalve
thatusesatemperaturetransducertomeasuretemperaturedirectly.

Electronicexpansionvalvesoperatebasedonasignalreceivedfromasuperheat
controllerwhichreadssuctiongastemperatureandpressurefromacombinationof
sensors.Theexpansionvalveitselfmayoperatebasedonanopen/close(pulsing)
principleoronamotorizedpositioningprinciple.Advantagesofthistypeofvalve
includemoreaccurateandresponsivesensingofsuperheatwhichallowsstable
operationatsmallerTDthanthermostatictypevalves.PIDcontrolparameterscanalso
beadjustedinthecontrollertofinetuneoperationoverawiderangeofconditions.
Theprimarydisadvantageofelectronicexpansionvalvesisthehigherfirstcost
comparedtothermostaticvalves.This,however,ischangingasvalvemanufacturersare
findinglowercostsolutionsandbeginningtooffercostcompetitiveelectronicvalvesto
themarket.


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MinimumrecommendedTDandsuperheatsettingsforbothtypesofexpansionvalves
areshowninTable2below:

TABLE2
MINIMUMRECOMMENDEDDXAMMONIATDANDSUPERHEATSETTING

ExpansionValveType MinimumRecommended RecommendedSuperheat
TD,degF Setting,degF
Thermostatic 15 12
Electronic 10 8

Note:Colmacoffersfactorysuppliedandmountedexpansionvalvesandcontrollers,
boththermostaticandelectronictype.

5. TypesofFrostandSelectionofFinSpacing

Frostcanaccumulateonevaporatorcoilfinsbyoneoftwomechanisms:

1. Bydeposition,and/or
2. Asairborneicecrystals

Designingevaporatorstoproperlyhandlethesetwotypesoffrostisdescribedinthis
section.

1. Deposition:

Wheneverthetemperatureoftheevaporatorcoilsurfaceisbelowthedewpoint
temperatureoftheroomair,moisturewillcondenseandbedepositedonthesurface
eitherasliquidwater(abovefreezing)orasfrost(belowfreezing).Thismasstransfer
process,whenrelatedtotheformationoffrostiscalleddeposition,andisdrivenbythe
differenceinwatervaporpressurebetweentheairandthesurfaceofthecoil.The
amountofheatassociatedwiththismasstransferprocessistermedlatentheatandis
quantifiedbytheSHR(seepreviousdefinition).WhenevertheSHRislessthan1.0,the
depositionoffrostwilltakeplace.Therateatwhichfrostwillbedepositedonthecoil
surfacescaneasilybecalculatedasafunctionofthetotalcoolingload,theSHR,andthe
surfaceareaoftheevaporator.

Thesurfaceeffectivenessofarefrigerationevaporatorisrelativelyhigh(usuallygreater
than80%)duetothetypicallysmallTDandlowheatfluxcomparedtoairconditioning
andprocessevaporators.Thishighsurfaceeffectivenessresultsinamoreorless
constantsurfacetemperatureanduniformdepositionoffrostovertheentiresurfaceof
theevaporator.Thisassumptionofuniformfrostdepositionismadeinthefollowing
equation:




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     (6)


Where:
 
 

 
 
 

EXAMPLE:
Anevaporatorhaving8rowsdeepandfinspacingof3FPIisoperatingwitha10degF
TD(DT1)ina+10degF/85%rhroom.Theevaporatorhasacoolingcapacityof240,000
Btu/h(20TR)andoutsidesurfaceareaof4100ft2.Whatwillbetherateoffrost
deposition?

Answer:
FromTable1theexpectedSHRatthisroomairtemperatureandrh%willbe0.87.


 



Asfrostisdepositedontheevaporatorcoilsurfacesthelocalairvelocitybetweenfins
willincreaseandresultinincreasedairpressuredropacrossthecoil.Theincreaseinair
pressuredropduetoaccumulationoffrostcanbeapproximatedbythefollowing
equation:




    
 
    (7)






Where:
 

 
 
 


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Therateofblockageofthecoilwithfrostandassociatedpressuredropwillresultina
reductioninairflowandcoolingcapacity.Thisreductionincoolingcapacitywill
ultimatelydeterminedefrostfrequencyandefficiency,andoverallsystemenergy
efficiencyandpowerconsumption.
Coolingcapacityoftheevaporatorcanbecharacterizedasfunctionsoffacevelocity,
SHR,andfrostthickness.Knowinghowcapacitychangeswiththeseparameters,
combinedwiththerelationshipsshowninequations5,6,and7above,allowsthe
constructionofasimplemodelwhichwillpredictthechangeincoilcapacityovertime.
Simplifyingassumptionsinthemodelinclude:

o Frostisdepositeduniformlyoverthesurfaceofthecoil
o Frostdensityisuniformandofafixedvalue
o Suctiontemperatureremainsconstant

Normally,refrigerationloadsarecalculatedbasedon16to18hoursofruntimeperday.
Itisnotclearwhenorwhythisruleofthumbcameintopractice.Perhapsitisacorollary
tothe2to1ruleforhotgasdefrosting.Thatis,twocoilsmustbeinoperationwhile
thethirdcoilisinhotgasdefrostinordertoprovideasufficientquantityofhotgasfor
thedefrostcycle.Perhapsitissimplyanadditionalcatchallsafetyfactor.One
industryhistorianmentionedthatthe1618runhoursrulecamefromsplitsystem
applicationswherecapacitydropsoutduringdefrostcomparedtoacentralsystem
whichwouldrebalancetheTDontheremainingevaporators(Welch2013).Itmakesthe
mostsensetotheauthorthattheruntimeadjustmenttothedesignrefrigerationload
shouldbeusedtoaccountforthedegradationincoilperformanceovertimedueto
accumulationoffrost.

Inalargerefrigerationsystemhavingaconstantrefrigerationloadandcompressor
unloadingcapability,thecompressorswillunloadtomaintainaconstantsuction
temperatureasthecoilcapacityfallsoffduetofrosting.Asthecompressorsunloadto
maintainsystemsuctionpressure,theywillrunlongertomaintainroomtemperature.
Thisimpliesthatinordertomaintainroomtemperature,defrostingshouldbeinitiated
whenevaporatorcapacityfallstoalevelequaltothedesignruntimeratio(design
runtimedividedby24).Table3belowshowsthemaximumreductioninevaporator
capacityduetofrostingthatshouldbeallowedbeforedefrostisinitiated.Notethatthis
tableobviouslydoesnotapplytoevaporatorsoperatingabovefreezing.

TABLE3
MINIMUMEVAPORATORCAPACITYTOINITIATEDEFROSTATVARIOUSDESIGN
RUNTIMES

 DesignRuntime,h/day MinimumEvaporatorCapacityat
 InitiationofDefrost
 14 58%
 16 67%
 18 75%
 20 83%

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Theevaporatorperformancemodeldescribedabovewasusedtoexaminetheeffectof
finspacingandSHRonlossofcoolingcapacityduetofrostaccumulation.SeeFigures8,
9,10,and11below.

FromTable1itisclearthatthehighestfrostload(lowestSHR)willoccurinhigh
temperature(+32F)roomswithhighrelativehumidity.Thelowestfrostloads(highest
SHR)occuratfreezertemperatures,evenwhenrelativehumidityishigh.

FIGURE8

 CapacityvsTimeforVariousFinSpacings
 7/8StaggPattern,0.65SHR
 100%
 90%

80%

70%

CoolingCapacity,%

 60%

 50% RBR(Stagg)8R2F
 40%
RBR(Stagg)8R3F

 30%
RBR(Stagg)8R4F


20%

 10%

 0%
0 0.5 1 1.5 2 2.5 3 3.5 4
 Time,h


FIGURE9

 CapacityvsTimeforVariousFinSpacings
 7/8StaggPattern,0.75SHR
 100%

 90%
 80%
 70%

CoolingCapacity,%

60%

50% RBR(Stagg)8R2F

RBR(Stagg)8R3F
 40%
RBR(Stagg)8R4F
 30%
 20%
 10%

0%
 0 1 2 3 4 5 6 7
 Time,h

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FIGURE10

 CapacityvsTimeforVariousFinSpacings
 7/8StaggPattern,0.85SHR
 100%
 90%
 80%

70%

CoolingCapacity,%

 60%

 50% RBR(Stagg)8R2F

 40%
RBR(Stagg)8R3F

 30%
RBR(Stagg)8R4F


20%

10%

 0%
0 2 4 6 8 10 12
 Time,h



FIGURE11

 CapacityvsTimeforVariousFinSpacings
 7/8StaggPattern,0.95SHR
 100%
 90%
 80%

70%

CoolingCapacity,%

 60%

 50% RBR(Stagg)8R2F

 40%
RBR(Stagg)8R3F

 30%
RBR(Stagg)8R4F


20%

10%

 0%
0 5 10 15 20 25 30 35 40
 Time,h


AnumberofobservationscanbemadewhenconsideringFigures811,Table1,and
Table3:


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1. Therateatwhichfrostaccumulatesonanevaporatorincreasesastheroom
temperatureincreasesforagivenroomrelativehumidity.i.e.Frostonan
evaporatoroperatinginaroomat+32Fand85%rhwillaccumulatemuchfaster
thanonthesameevaporatoroperatingat10Fand85%rh.Thisisduetothehigher
watervaporpressureinairathighertemperaturesandtheresultinglowerSHR.
2. Foragivenreductioninevaporatorcapacity,widerfinspacingalwaysresultsin
longeractualruntimebetweendefrosts.
3. Asdesignruntimeisincreased,thenumberofdefrostsperdayrequiredincreases.
Inthecaseofveryhighfrostload(SHRlessthan0.75)usingdesignruntimegreater
than14h/daymayresultinaninabilityoftherefrigerationsystemtomaintainroom
temperature.
4. Figures8through11canbeusedtoestimatedefrostfrequencywhenroomSHR,
designruntime,andcoilfinspacingareknown.
Example:
Anevaporatorhasbeenselectedfora+10F/85%rhroombasedondesignruntime
of16h/day.Finspacingselectedis3FPI.Estimatethedefrostfrequencyusing
Tables1and3,andFigures8through11.
FromTable1:SHR=0.87
FromTable3:CoolingCapacityatTimeofDefrost=67%
FromFigure10:Timebetweendefrosts=5.2h
Therefore,estimateddefrostfrequency=24h/day/5.2h=5defrostsperday

Conclusion:Table4belowshowssuggestedmaximumfinspacing,designruntime,and
defrostfrequencyforvariousvaluesofSHR.Thistableisintendedtobeusedasageneral
guidelineinconjunctionwithTable1.Notethatroomrelativehumidity,andtherefore
SHR,willlikelychangethroughouttheyeardependingonlocationandclimate
conditions.Thisimpliesthatoptimumdefrostfrequencymaybedifferentinsummer
monthsvswintermonths.

TABLE4
SUGGESTEDFINSPACING,RUNTIME,ANDDEFROSTFREQUENCYVSSHR
 SHR SuggestedMaximum RecommendedMaximum SuggestedDefrostFrequency,
 FinSpacing,FPI DesignRuntime,h/day No.Defrosts/day
 0.65 2 14 9
 0.75 3 16 8

0.85 4 16 6

0.95 4 18 2


Theabovediscussionandrecommendationsarebasedonfrostaccumulationby
depositionanddonotincludetheeffectsofairborneicecrystalsonfinspacingand
defrostfrequency.Theeffectsofairborneicecrystalsarediscussedinthefollowing
section.

2. AirBorneIceCrystals:


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Thistypeoffrostisformedquitedifferentlyfromthefrostformedbydepositionas
explainedabove.Itaccumulatesonevaporatorsurfacesbyadifferentmechanism,and
ismoredifficulttoquantifyandpredict.

Airborneicecrystalsasatypeoffrostthatcanbedepositedoncoilsurfaceshasbeen
recognizedanddiscussedforsometime(Cleland2002,Stoecker1988).Theseice
particulatesformwheninfiltrationairmixeswithrefrigeratedairtoproducea
supersaturatedcondition.Onapsychrometricchart,asupersaturatedconditionis
indicatedwhenthemixedairconditionfallstotheleftofthesaturation(100%rh)line
(thinkoffogthathasfrozeninmidair).

Ratherthanaccumulaterelativelyuniformlyovertheentirecoilsurfaceasisthecase
withfrostformedbydeposition,airborneicecrystalsaccumulateontheleadingedges
ofthecoilfinsandhavetheprimaryeffectofrestrictingairflow.Thistypeoffrostis
moredifficulttopredictsinceitsformationdependsonnotonlytheconditionoftheair
outsidetherefrigeratedspace,butalsoontheconditionofdoorwaysandhowtheyare
operated.

Whenevaporatorsarelocateddirectlyabovedoorwayswhereairborneicecrystalsare
formedthistypeoffrostcanaccumulateveryquicklyandhaveseriousconsequencesin
termsofdegradedperformanceandinabilitytodefrosteffectivelyduetoexcessive
accumulationofhoarfrostandice.Inoneparticularcaseobservedbytheauthor,two
identicalevaporatorswereinstalledinthesamerefrigeratedspace(a10degFfreezer)
alongthesamewall,onedirectlyoverthedoorwayandthesecondoffsetbetween
doorways.Theevaporatordirectlyoverthedoorwayhadchronicproblemswithrapid,
heavyaccumulationoffrost,andwithdefrostissuesrelatedtoaccumulationoficeon
theunitcabinetandinthedrainpan.Theevaporatorlocatedonly20feetawaybetween
doorways,operatedwithoutaccumulatingiceonthecabinetandorinthepanand
defrostednormallyandeffectively.Itisthereforerecommendedthatevaporatorsnotbe
locateddirectlyabovedoorwayswheneverpossible.

Ifitisknownthattheevaporatorwillbeexposedtothistypeoffrost,variablefin
spacingisrecommended.Thatis,afinspacingarrangementwhichhasfinsonthefirst
onetotworowsontheairenteringsideofthecoilspacedwiderthanintheremaining
rows.Typicalarrangementsare1/2fpi(finsperinch),1.5/3fpi,and2/4fpi.

V. CondenserSelectionandOperation

Anumberofdifferenttypesofcondensersareavailableforusewithammonia.

WaterCooled
AirCooled
Evaporative
Hybrid(Adiabatic)AirEvaporative


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Incertaincasesthetypeofcompressionequipment(screwvsreciprocating)selectedand
theexpectedmaximumambienttemperaturewilldeterminewhetherornotaircooled
condensingwillbepossible.Inothercasestheavailability(orunavailability)ofwatermay
requiretheuseofaircooledcondensing.ThegoodnewsisthatDXammoniaiscompatible
withalltypesofcondensingsystems!

Properselectionandoperationofammoniacondensingequipmentisoutlinedinthe
condensermanufacturersliterature.

Itisrecommendedthatthesystemdesignercarefullyconsiderthefollowingpointswhen
selecting/designingcondensingequipment:
Energyefficiency
Partloadoperation
Lowambientoperation
Internalvolumeandammoniacharge
Gasinletandliquidoutletpiping
Purgingofnoncondensiblegases
VFDcondenserfancontrol(highlyrecommended)

VI. Subcooling

Refrigerantliquidleavingthecondenseristypicallyatornearsaturationtemperatureand
pressure.Iftheliquidhasnotbeensubcooledbeforeitenterstheliquidline,anydropin
pressure,and/oranyheatinput,willcausetheliquidtoboilandflashgaswillbeformed.
Becauseoftheverylargevolumeoccupiedbyvaporcomparedtoliquid,theflashgas
increasestherefrigerantvelocityandcausesanexcessivepressuredropintheliquidline,
Thisreducesthecapacityandinterfereswiththeoperationoftheexpansionvalve,and
consequentlywillreducesystemcapacity.Adequatesubcoolingoftheliquidwillpreventthe
formationofflashgasinliquidlines.

Subcoolingtheliquidafteritleavesthereceiveristhereforeanecessityforpropersystem
operation.Notethatanysubcoolingdonewithinthecondenserorbetweenthecondenser
andthereceiverwillbeeliminatedinthereceiverduetotheequalizerline.Theamountof
subcoolingrequiredcorrespondstotheliquidlinepressuredropandheatgain.Thepressure
dropisthesumof1)thelossinpressureduetoelevationgainintheliquidline,2)liquidline
pressuredropduetofriction,and3)pressuredropthroughserviceandcontrolvalves.

Table5showsthepressuredropinliquidlinesproducedbyelevationgainbetweenthe
receiverandevaporatorswithammonia.








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TABLE5

PressureDropinAmmoniaLiquidLinesDuetoElevationGain

ElevationGain PressureDrop
 ft m psi kPa
 1 0.3 0.3 1.9
 5 1.5 1.4 9.3
 10 3.0 2.7 18.7
 15 4.6 4.1 28.0
 20 6.1 5.4 37.3
25 7.6 6.8 46.7

30 9.1 8.1 56.0
 35 10.7 9.5 65.4
 40 12.2 10.8 74.7
 45 13.7 12.2 84.0
 50 15.2 13.5 93.4

Oncethetotalliquidlinepressuredrop(thesumofelevationpressuredropplusfrictional
pressuredroppluspressuredropthroughvalves)iscalculated,therequiredamountof
subcoolingtopreventflashgasinthelinecanbedeterminedfromTable6.Notethatthe
amountofsubcoolingrequiredforagivenpressuredropincreasesascondensing
temperaturedecreases.

TABLE6

 TotalLiquidLine RequiredAmountofSubcooling(Ammonia)
 PressureDrop 120F(49C)SCT 95F(35C)SCT 65F(18C)SCT
 psi kPa degF degC degF degC degF degC
 1 6.9 0.2 0.1 0.3 0.2 0.5 0.3
 4 27.6 1.0 0.5 1.3 0.7 1.9 1.0
 6 41.4 1.4 0.8 1.9 1.1 2.8 1.6
 8 55.2 1.9 1.1 2.6 1.4 3.8 2.1
 10 68.9 2.4 1.3 3.2 1.8 4.7 2.6
 12 82.7 2.9 1.6 3.8 2.1 5.6 3.1
 14 96.5 3.4 1.9 4.5 2.5 6.6 3.7

16 110.3 3.8 2.1 5.1 2.8 7.5 4.2

18 124.1 4.3 2.4 5.8 3.2 8.5 4.7

 20 137.9 4.8 2.7 6.4 3.6 9.4 5.2
 25 172.4 6.0 3.3 8.0 4.4 11.8 6.5
 30 206.8 7.2 4.0 9.6 5.3 14.1 7.8
 35 241.3 8.4 4.7 11.2 6.2 16.5 9.2
 40 275.8 9.6 5.3 12.8 7.1 18.8 10.5
 45 310.3 10.8 6.0 14.4 8.0 21.2 11.8
 50 344.7 12.0 6.7 16.0 8.9 23.5 13.1

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AcommonlyusedmethodofsubcoolingliquidrefrigerantistermedMechanicalSubcooling.This
istheCOLMACRECOMMENDEDmethodofliquidsubcoolingandreferstousingaportionof
liquidrefrigerantfromtheuncooledliquidlinetoevaporateandcooltheremainingliquid.A
heatexchanger(typicallyaplatetypeexchanger)isinstalledintheliquidlineinsuchawayasto
cooltheliquidrefrigerantononesideoftheexchangerbyevaporatingarelativelysmallamount
oftherefrigerantontheothersideoftheexchanger.Theevaporatingsiderefrigerantis
meteredbyaTXVormotorizedvalveinresponsetoliquidlinetemperatureandtheevaporated
refrigerantthenreturnedtothesuctionline.Thismethodofsubcoolingproducespredictable
resultsunderallconditions,andisrequiredtoinsureproperoperationofColmacDXAmmonia
evaporatorcontrols.Withmechanicalsubcoolingthereisnonetlossofrefrigeratingeffector
systemenergyefficiency.

Alternatemethodsforsubcoolingrefrigerantliquidcanbeapplied,buthavevariousdrawbacks:

AmbientSubcooling.Thisinvolvesusingaseparatecircuitwithinthecondensertoroute
liquidrefrigerantfromthereceivertothesystemcausingtherefrigeranttoapproachthe
ambientairtemperature.Thisisarelativelysimpledesign,howevertheamountof
subcoolingwillbelimitedtothecondenserTD.Thismaynotbeasufficientamountof
subcoolingtoavoidformationofflashgasduringcertaintimesoftheyear.Therefore,this
methodofsubcoolingisNOTrecommended.

LiquidPumping.Herealiquidpumpisinstalledattheexitofthereceivertopressurizethe
liquidlinesufficientlytoovercomethetotalpressuredropduetofrictionandelevationgain.
Whileeffectiveateliminatingflashgasregardlessofoperatingconditions,thismethodadds
complexityandwillcausetheliquidlinetooperateatapressurewhichishigherthan
condensingpressure.Aswithambientsubcooling,thismethodisNOTrecommended.

NOTE:ReferringtoFigures13,liquidtemperatureleavingthemechanicalsubcoolerisshownas
40degF.Thisliquidtemperatureisconservativeandshouldpreventtheformationofflashgas
inliquidlinesinmostifnotallcases.

SubcoolerPiping:

Figure12belowillustratestypicalmechanicalsubcoolerheatexchangerpiping.











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FIGURE12

SUBCOOLER KIT

SUCTION
 HOT LIQUID IN


 N.C.

SUBCOOLED LIQUID OUT

 TEMPERATURE
TRANSDUCER

T

 TEMPERATURE
CONTROLLER


SOLENOID VALVE GLOBE VALVE PRV VALVE


ANGLE VALVE STRAINER T TEMPERATURE GAUGE


Toinsureeffectiveliquidsubcooling,besuretoobservethefollowingrules:
1. Sizepipingandvalvesforthemaximumrefrigerantflowconditionanticipated,i.e.
lowestheadpressure/highestsuctionpressure.Thisconditiontypicallyoccursduring
wintermonths.
2. Alwaysinsulateliquidlinestopreventheatgainandlossofsubcooling.
3. Locatesubcoolerheatexchangerdownstreamofthereceiverattheentrancetothe
liquidline,NOTbetweenthecondenserandreceiver.SeeP&IDexamplesabove.
4. Usegoodpipingpractice,ascanbefoundintheIIARAmmoniaRefrigerationPiping
Handbook(IIAR2004).

MechanicalSubcoolerSelection:

ColmacofferspreengineeredMechanicalSubcoolerswhicharefactorypipedandpackaged
inafreestandingframe,andincludethefollowingcomponents:
Stainlesssteelplatetypesubcoolingheatexchanger
Electronicexpansionvalveandtemperaturecontroller
Service(isolation)valves
Pressurereducingvalveforcontrolledleavingliquidlinepressure
ULlistedandwiredcontrolpanel

SeeseparateEngineeringBulletinforsubcoolerselectionandspecificationdetails.

VII. PipingGeneral

1. Cleanliness.Thesmallinternalpassagesfoundinexpansionvalves(andothercontrol
valves)inDXammoniasystemsareparticularlysensitivetofoulingandpluggingwith

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relativelysmallamountsofdirtanddebris.Forthisreason,particularcareneedstobe
takenduringtheinstallationofsystempipingtoinsurecleanlinessandtominimizethe
introductionofweldscaleanddust,andothertypesofdirtanddebris.

2. EvacuationPriortoChargingtheSystemwithAmmonia.BecausetheperformanceofDX
ammoniaevaporatorsisdramaticallyaffectedbyevensmallamountsofwater,itisvery
importanttofollowgoodpressuretestingandevacuationprocedurespriortocharging
thesystemwithammonia.Recommendedevacuationprocedurecanbefoundinthe
separateColmacEngineeringBulletinonthistopic.

VIII. LiquidLines

Industryacceptedmethodsandpracticeforpropersizingandarrangementofliquidlines
canbefoundintheIIARAmmoniaRefrigerationPipingHandbook(IIAR2004).Additionally,
followtheguidelinesexplainedbelow.

1. Designmassflowrate.Liquidlinesmustbesizedappropriatelyforthetypeofline
(condensertoreceiver,receivertoexpansionvalve,etc.)andtheexpectedmaximum
massflowratecondition.Themaximummassflowrateconditionwilloccurwhen
dischargepressureisatitsminimum,suctionpressureisatitsmaximum,and
compressorsarerunningfullyloaded.Typicallythiswouldoccurwithfloatinghead
pressuresystemsduringwintermonths.Designingliquidlinesforthehottestdayofthe
year(commonlytakenasthedesignpoint)willlikelyleadtoundersizedliquidlines
andhigherthanexpectedpressuredropwiththepotentialofformingflashgasinthe
liquidline.
2. Insulation.Insulationofliquidlinesdownstreamoftheliquidsubcoolerbecomes
criticallyimportantinDXammoniasystemstoavoidheatgainandthepotentialfor
developingflashgasintheliquidlineupstreamoftheexpansionvalves.Usegood
qualityinsulationsystemswithadequateinsulationvalueandprotectionagainst
physicalandweatherdamage.
3. TypeofExpansionValve.ThreetypesofexpansionvalvesarecommonlyusedinDX
systems:1)Thermostatic,2)Motorized,and3)PulsewidthModulating.Thermostatic
andmotorizedvalvesmodulateinresponsetotheimposedloadonthecoilandsoliquid
linesshouldbesizedforthemaximumexpecteddesignmassflowrate(seeparagraph
V.1.above).Pulsewidthmodulating(PWM)expansionvalves,ontheotherhand,
alternatebetweenwideopenandfullyclosedataratewhichcorrespondstotheduty
calledforbytheelectroniccontroller.Becausethemassflowrateofrefrigerantwillbe
determinedbythewideopencapacityofthePWMvalve,thelocalliquidlinefromthe
liquidsupplymaintotheindividualevaporatormustbesizedtohandlethemaximum
capacityofthevalve.WhenPWMvalvesareused,theliquidsupplymainlinemustbe
sizedtohandlethiswideopencapacitybyusingadiversityfactorbasedonthe
numberofevaporatorsexpectedtobeoperatingatthesametimedividedbythetotal
numberofevaporators.
4. PressureRegulatingValve.AsshowninFigures13,theliquidlinepressureleavingthe
subcoolerassemblyismaintainedat75psigbyapressureregulatingvalve.When
defrosthotgaspressureisregulatedtomaintain90psig(alsoshowninFigures13)this

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pressuredifferentialallowsdefrostcondensateleavingtheevaporatorsduringdefrost
tobefeddirectlybackintotheliquidlineandsenttootheroperatingevaporators.
5. Pipematerialspecifications.RefertotheIIARAmmoniaRefrigerationPipingHandbook
(IIAR2004)andANSI/IIARStandard22008(IIAR2008)fordetailedpipematerial
specificationrequirementsforammonialiquidpiping.

IX. SuctionLines

Unlikepumpedammoniasystems,nowetsuctionlinesareneededforDXammonia.
Althoughtheyshouldbepitchedandtrappedtoaccommodatetheoccasionalpresenceof
liquid,suctionlinepressuredropshouldbecalculatedtoreflectdryoperation.Refertothe
IIARAmmoniaRefrigerationPipingHandbook(IIAR2004)forpropersizingandarrangement
ofdrysuctionlines.Additionally,followtheguidelinesexplainedbelow.

1. Designmassflowrate.Aswithliquidlines,drysuctionlinesshouldbesizedforthe
expectedmaximummassflowratecondition.Again,themaximummassflowrate
conditionwilloccurwhendischargepressureisatitsminimum,suctionpressureisatits
maximum,andcompressorsarerunningfullyloaded.
2. Trappedverticalrisers.Suctionlineswithverticalupflow(suctionrisers)mustbe
installedwithaptrapatthebottom(entrance)oftheriseranddischargeintothetopof
theoverheadsuctionmainpipe.Whenvaryingloadsontheevaporatorareexpected,a
doubleriserdesignshouldbeused.RefertotheIIARAmmoniaRefrigerationPiping
Handbook(IIAR2004)forexamplesofdoublesuctionriserdesigns.
3. Pitchedsuctionlines.Suctionlinesmustbepitchedaminimumof1/8perfoottoward
thesuctionaccumulatortofacilitategooddrainageofanyliquidrefrigerantand/oroil
thatentersthesuctionline.
4. Pipematerialspecifications.Particularattentionmustbepaidtocarbonsteelpipe
materialspecificationsinlowtemperature(suctiontemperaturesbelow20degF),
whichmayrequireimpacttesting.RefertotheIIARAmmoniaRefrigerationPiping
Handbook(IIAR2004)andANSI/IIARStandard2(IIAR2008)fordetailedpipematerial
specificationsandrequirements.

X. HotGasLines

Industryacceptedmethodsandpracticeforpropersizingandarrangementofhotgaslines
canbefoundintheIIARAmmoniaRefrigerationPipingHandbook(IIAR2004).Additionally,
followtheguidelinesexplainedbelow.

1. Designmassflowrate.Hotgas(defrost)linesshouldbesizedforthemassflowrate
correspondingtothemaximumnumberandsizeofevaporatorsexpectedtodefrostat
thesametime.Conventionalwisdommaintainsthateachindividualevaporatorrequires
aflowofhotgasequalto2xtimestheflowrequiredduringcooling,andsothiswould
limitthenumberofevaporatorsbeingdefrostedatthesametimetoamaximumof1/3
thetotalnumberofevaporatorsinthefacility(thetwotoonerule).However,
evaporatorsequippedwithColmacSmartHotGascontrolscaneffectivelydefrostan
evaporatorwithhotgasflowingtotheevaporatorforonly8to10minutes.Withan

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effectivebuildingmanagementcontrolsystem,anddependingonthefrostloadand
frequencyofdefrosting,itispossibletolimittheamountofdefrosthotgasflowingat
anygiventimetoonlythatrequiredforthelargestsingleevaporatorinthefacility.This
approachobviouslyhasthepotentialtoreducethehotgaslineandPRVsizeandcost.
Expectedmassflowrateofhotgasfordefrostofagivensizedevaporatorcanbe
calculatedusingthemethoddescribedbelowintheHotGasDefrostsection.
2. Insulation.Insulationofhotgaslinesiscriticallyimportanttoinsurefastdefrosting.Use
goodqualityinsulationsystemswithadequateinsulationvalueandprotectionagainst
physicalandweatherdamage.
3. PressureRegulatingValve.AsshowninFigures13,thehotgaslinecomingfromthe
compressordischargelineismaintainedat90psigbyapressureregulatingvalve.When
defrosthotgaspressureisregulatedtomaintain90psigandtheliquidlineis
maintainedat75psig(alsoshowninFigures13)thispressuredifferentialallowsdefrost
condensateleavingtheevaporatorsduringdefrosttobefeddirectlybackintotheliquid
lineandsenttootheroperatingevaporators.Maintainingthehotgaslinepressureat
thereduced90psigalsominimizesheatlosstothesurroundingambient.
4. Pitchedhotgaslinesanddriplegs.Hotgaslinesmustbepitchedaminimumof1/8per
foottowardtheevaporatorstofacilitategooddrainageofanycondensedrefrigerant
(condensate)todriplegsinstalledaheadoftheevaporatorcontrolvalvegroup(s).
5. Liquiddrainers.Ashotgasfordefrosttravelsfromtheengineroomtotheevaporators
someofitsenergywillbereleasedtoheatupthepipingitself,andsomereleaseddue
toheatlossthroughinsulation.Condensatewillthereforeforminthehotgaspiping
whichmustthenbeeffectivelytrappedanddrainedbeforeitreachestheevaporators.
Unlessitiseffectivelyremoved,accumulatingcondensedliquidupstreamofhotgas
solenoidvalveswillcausecavitationontheseatsofthesolenoidvalveswhenthevalve
isclosed(Jensen2013).Condensatewillcollectindriplegs(describedabove)andmust
bereturnedtoeitheranearbysuctionline,oracondensatereturnline.Usealiquid
draineroranappropriatelysizedsteamtraptoallowonlyliquidtoleavethedripleg.
Usingliquiddrainersalsoeffectivelykeepshotgaslinescontinuallyheatedandreadyto
supplyfullflowofhotgastoevaporatorsimmediatelyondemandfordefrosting.
6. Pipematerialspecifications.RefertotheIIARAmmoniaRefrigerationPipingHandbook
(IIAR2004)andANSI/IIARStandard22008(IIAR2008)fordetailedpipematerial
specificationrequirementsforammoniahotgaspiping.

XI. EffectsofWaterinAmmoniaandItsRemoval

Asexplainedindetailelsewhere(Nelson2010),thepresenceofevensmallamountsof
waterinammoniahasasignificantnegativeeffectonDXevaporatorperformance.
Unfortunately,waterisdifficulttoentirelykeepoutofindustrialammoniarefrigeration
systemsforanumberofreasons:Residualwaterinpressurevesselsleftfromhydrotesting,
incompleteevacuationofthesystempriortostartup,leaksinpartsofthesystemwhich
normallyoperateinavacuum,etc.

Thisresidualwatergoesintosolutionwiththeammoniaandincreasesandtheboilingpoint
(bubblepoint)temperature.Ataconcentrationof20%(bymass)waterinammonia,the

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boilingpointrisestoapproximately10degFabovetheboilingpointofpureammoniaatthe
samepressure.SeeFigure13below.

Astheammoniawaterliquidenterstheevaporatorcircuititbeginstoboil.Becauseofthe
largedifferenceinvaporpressuresofammoniaandwater,onlyammoniavaporis
generatedduringtheevaporationprocess,leavingthewaterbehindintheremainingliquid.
Sotheevaporationprocessresultsinanincreaseinwaterconcentrationanda
correspondingincreaseintheboilingpointoftherefrigerantasitpassesthroughthecoil
circuit.Inthecaseofanevaporatoroperatingwitha10degFTD,therefrigerantwillstop
boilingoncethewaterconcentrationreachesabout20%sincetheboilingpointwillhave
risenby10degF.Thiscessationofboilingwilloccuratsomepointalongthelengthofthe
evaporatorcircuit,thepointatwhichboilingstopsdependingontheinitialconcentrationof
waterandsuctionpressure.Atthepointwheretheincreaseinthewaterconcentrationhas
causedanincreaseintheboilingpointequaltothecoilTD,liquidrefrigerantwillexitthe
evaporatorandenterthesuctionline.

Figure13belowshowstheincreaseinboilingpoint(bubblepoint)forvariousinitialwater
concentrationinammoniaatvariouspressures.

FIGURE13

 IncreaseinBubblePointTemperaturevsComposition
 AmmoniaWater
40


35
 48.2 psia(3.3bar)
30.4psia(2.1bar)

IncreaseinBubblePointTemperature,F

30 18.3psia(1.3bar)
 10.4psia(0.7bar)

 25

 20


 15


 10


5


0
 0 0.1 0.2 0.3 0.4 0.5

 Composition(MassFractionWater)



Anexampleoftheincreaseinbubblepointtemperatureoverthecircuitlengthofan
evaporator,representedbythechangeinvaporquality,isshowninFigure14belowforan
initialwaterconcentrationinammoniaof3%atapressureof10.4psia(40degFSST).In

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thisexamplethebubblepoint(Tbub)hasincreasedby10degFatavaporqualityofapprox.
0.89.
FIGURE14

 Incr in Bubble Point vs NH3 Vap Quality, 3.00% Water in NH3,
Tsat = -40.0F

 50

 45

40

 35

Increase in Tbub, F

30

 25

 20

 15

 10

5

 0
0 0.2 0.4 0.6 0.8 1

NH3 Vapor Mass Fraction (Quality)


Thisincreaseinbubblepointsignificantlyreducesthemeantemperaturedifferenceand
thereforethecoolingcapacityoftheevaporatorisreducedasillustratedinFigure15.

FIGURE15


















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Inadditiontotheperformancepenaltyseenwhenrelativelysmallamountsofwaterare
presentintheammonia,thisalsomeansthatthemassfraction(10.89)=0.11,or11%of
themassofrefrigerantexitingtheevaporatorasliquidwillhavetobecaptureddownstream
inthesuctionaccumulator.

Knowingthatammoniawaterliquidofapproximately20%waterconcentrationwill
unavoidablyleavetheevaporatorswheneverevensmallamountsofwaterarepresentin
theammoniaisimportantforthedesignertounderstand.Thesuctionaccumulatormust
thereforebeproperlydesignedtoperformthefollowingfunctions:

i. Separateliquidandvaporrefrigerantandallowonlyvaportoreturntothe
compressor,
ii. Captureanddistill(byheating)ammoniawaterliquidtoaconcentrationthat
cansafelyberemovedfromthesystemfordisposal.
iii. Transferexcesstrappedliquidtothehighpressurereceiver,orintothereduced
pressureliquidline.

1. Separation

Liquidvaporseparationinsuctionaccumulatorvesselsiswellunderstoodanddesign
methodswelldocumented.Refertorecognizedpublishedsizinganddesignmethods
(Stoecker1988,Wiencke2002).

Colmacoffersarangeofpreengineeredfactoryassembledsuctionaccumulator
packagesspecificallysuitedtooperationwithDXammonia.SeeseparateEngineering
Bulletinforselectionandspecificationdetails.

2. DistillationandDisposalofAmmoniaWaterSolution(AmmoniumHydroxide)

Distillation:

AmmoniaishighlysolubleinwaterduetothepolarityofNH3moleculesandtheir
abilitytoformverystronghydrogenbonds(Nelson2010).Thishighsolubilitymakes
ammoniawateragoodworkingfluidpairinabsorptionrefrigerationmachines,taking
advantageofthelargevaporpressuredifferencesbetweentheammoniavaporand
weaksolution.However,thissamebehaviormakeswaterremovalfromammonia
refrigerationsystemssomewhatchallenging.

Asmentionedabove,ammoniawatersolutionconcentratedtoapproximately20%
waterwillreturnfromevaporatorsviathesuctionlinetobetrappedinthesuction
accumulator.Thisaqueousammoniasolution,calledAmmoniumHydroxide,ata
concentrationof80%ammonia(20%water)wouldbeverydifficulttosafelyremove
fromthesystemfordisposal.Furtherdistillationofthesolutionisneededtobringthe
ammoniaconcentrationinthesolutiondowntothepracticalminimumbeforeitis
removed.

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TheonlypracticalwaytodistilltheAmmoniumHydroxideisbyheatinginaseparate
distillationvessel,calledastill.AmmoniumHydroxidetrappedinthesuction
accumulatordrainsbygravityintothestillwhereitisheatedtoatemperature
correspondingtothepointonaPhaseEquilibriumdiagramwheretheslopeofthedew
pointlinechangesrapidlyfromnearlyverticaltomorenearlyflat.Thispointisshownon
Figure16asPointA.Belowthistemperature(between100and120degF),nearlypure
ammoniavaporwillleavethestillandtravelthroughtheventlinebacktothesuction
accumulatorwhereitwillthenbetakenbacktothecompressor.Abovethis
temperature,watervaporwillbegintoleavetheAmmoniumHydroxidesolutionand
exitthestillventlinewhereitwillgobackintosolutionwithanyammonialiquid
presentinthesuctionaccumulator.Basedonthis,theheatingelementinthestillmust
becontrolledtobringthesolutiontemperatureuptoamaximumof100to120degF,
atwhichpointitisreadytoberemovedsafelytoastoragecontainerforfurther
processingand/ordisposal.

FIGURE16
























Figure16alsoshowsthatthemaximumwaterconcentrationintheAmmonium
Hydroxidesolutionheatedto100degFvarieswithsuctionpressure.Themaximum
waterconcentrationspossibleareshownasPointsB,C,D,andE,inFigure16,andare
listedinTable7below.Itisapparentfromthefigureandthetablethatthestillisableto
achievehigherwaterconcentrationsatlowersuctionpressures.

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TABLE7
AMMONIAWATERCONCENTRATIONS@100degFvsSUCTIONPRESSURE
SuctionPressure,psia WaterConcentration, AmmoniaConcentration,
(SaturationTemp,F) %bymass %bymass
48.2(+20F) 57.5 42.5
30.4(0F) 65.0 35.0
18.3(20F) 72.5 27.5
10.4(40F) 80.0 20.0

Usingtheaboveinformation,anestimatecannowbemadeofthevolumeof
AmmoniumHydroxidesolutionthatwillbegeneratedbythestillforagivensystem
ammoniachargehavingagiveninitialwatercontent.Table8belowshowsthe
expectedvolumeofAmmoniumHydroxidesolutionperpoundofinitialammonia
chargethatwillhavetoberemovedbythestill(anddisposedof)inorderto
completelyremovethewaterfromrefrigerationsystem.

TABLE8
EXPECTEDVOLUMEOFDISTILLEDSOLUTIONAMMONIUMHYDROXIDE@100F
(GALLONSperPOUNDINITIALAMMONIACHARGE)

 InitialWater SaturatedSuctionPressure,psia(SaturatedTemp,F)
 Content,% 48.2(+20F) 30.4(0F) 18.3(20F) 10.4(40F)
 0 0.00000 0.00000 0.00000 0.00000
 1 0.00246 0.00211 0.00183 0.00161
 3 0.00738 0.00633 0.00550 0.00484

5 0.01230 0.01055 0.00917 0.00807

10 0.02460 0.02109 0.01835 0.01614

 20 0.04920 0.04218 0.03669 0.03229 

EXAMPLE:
Asystemhasaninitialammoniachargeof5,000lbswith3%watercontent.Thestill
isinstalledonthe20degFsuctionaccumulator.Whatwillbethetotalvolumeof
distilledAmmoniumHydroxidesolutiondrainedfromthestill?

Answer:
FinalDistilledSolutionAmmoniaConcentrationforDisposal(fromTable7):27.5%
ExpectedVolumeofDistilledSolutionperPound(fromTable4):0.0055gal/lbs

TotalExpectedVolumeof27.5%AmmoniumHydroxideforDisposal:
5,000lbsx0.0055gal/lbs=27.5gallons

StorageandDisposal:


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AmmoniumHydroxideislistedasahazardoussubstanceunderCWA(40CFR
1164.40CFR117.3ReportableQuantityCategoryC.1000lbs/454kg).Assuch,itis
importanttocomplywithalllocalandnationalregulationsforsafehandlingand
disposalofthesolutionremovedfromthesystemstill(Smith2010).

ItisinterestingtonotethatsuitablydilutedAmmoniumHydroxidemaybedisposed
ofonagriculturallandasfertilizer.However,thematerialshouldbekeptfrom
enteringstreamsandlakesasitisharmfultoaquaticlifeandcancause
environmentaldamage.

AmmoniumHydroxidewillreactexothermically(heatisgenerated)withacids,and
soneutralizingofthesolutionbyunqualifiedpersonnelisnotrecommended.

ItisimportanttopreventcontactoftheAmmoniumHydroxidesolutionwith
chemicalssuchasmercury,chlorine,iodine,bromine,silveroxide,and
hypochlorites,astheycanformexplosivecompounds.Contactwithchlorineforms
chloraminegaswhichisaprimaryskinirritantandsensitizer.

Figure16incombinationwithTable7canbeusedtopredictthetemperatureabove
whichammoniavaporwillbegeneratedwhenthedistilledsolutionisstoredinan
opencontainer.Thisvaporneutraltemperatureisfoundusingtheammonia
concentrationsshowninTable7forvarioussuctionpressures,intersectingalineof
constantbubblepointtemperature(Tbub)atatmosphericpressure(14.7psia)on
Figure16.Table9belowshowstheambient(storage)temperaturesbelowwhich
ammoniavaporwillnotbegeneratedfromtheAmmoniumHydroxidesolution
dischargedfromthestill.

TABLE9
RECOMMENDEDMAXIMUMAMMONIUMHYDROXIDESTORAGETEMPERATURES
SuctionPressure,psia AmmoniaConcentration, StorageTemperature,
(SuctionTemp,F) %bymass DegF
48.2(+20F) 42.5 42
30.4(0F) 35.0 64
18.3(20F) 27.5 90
10.4(40F) 20.0 108

AmmoniumHydroxidesolutionhasacorrosivereactionwiththefollowingmaterials
whichshouldnotbeusedtostorethedistilledAmmoniumHydroxidesolution
(LaRocheIndustries1987):
x Galvanized(zinccoated)surfaces
x Copper
x Brassandbronzealloys
x Certaintypesofelastomers

ThedistilledAmmoniumHydroxidesolutioncanbesafelystoredincontainersmade
ofthefollowingmaterials:
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x Carbonsteel
x Stainlesssteel
x Aluminum
x CastIron

Generallyspeaking,aluminumalloysarenotrecommendedforexposuretoaqueous
solutionshavingapHgreaterthan9.0duetoacceleratedcorrosionandmetalloss.
AmmoniumHydroxidehowever,eveninhighconcentrations,isanexceptiontothis
rule.(Davis1999).

Inconclusion,AmmoniumHydroxidesolutioncollectedfromthestillshouldbestored
inanappropriatelyconstructedcontainerlocatedinacoolspaceoutofdirect
sunlight.Itisrecommendedthatthedistilledsolutionbedisposedofusingalocal
qualifiedwastedisposalvendor.

MoredetailedhandlingandsafetyinformationcanbefoundonMSDSsheets
publishedbysuppliersofAmmoniumHydroxide(TannerIndustries2000,LaRoche
Industries1998).

3. LiquidTransfer

Theanticipatedvolumeofammoniawaterliquidleavingtheevaporator(s)basedon
anaverage20%waterconcentrationattheevaporatorexithasbeencalculatedand
showninTable10below.Multiplythevalueshowninthetablebythetotalcapacity
ofthesystemintons(TR)todeterminethevolumeofammoniawaterliquid
returningtothesuctionaccumulator.

TABLE10
VolumeofAmmoniaWaterLiquidLeavingDXEvaporators

InitialWaterContentin VolumetricFlowrateofAmmoniaWater
Ammonia,% (20%waterconcentration)LeavingDX
Evaporators,ft3/h/TR
0.5 0.01
1.0 0.02
3.0 0.07
5.0 0.12
10.0 0.24

Example:
Ithasbeendeterminedthattheammoniachargeina500ton(TR)ammoniasystem
hasawatercontentof3%.Iftheevaporatorsareoperatedasdirectexpansion(DX),
howmuchammoniawaterliquidisexpectedtoreturnfromtheevaporatorstothe
suctionaccumulator?
Answer:
500TRx0.07ft3/h/TR=35ft3/h=4.4gal/min
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Thisvolumeofliquidreturningtothesuctionaccumulatorduetowaterinthe
ammonia(atleastinitially)mustbeaddedtothevolumeofliquidrefrigerant
floodbacknormallyconsideredwhendesigningthesuctionaccumulatortransfer
vessel.

AliquidtransfervesselisincorporatedintotheColmacPreEngineeredSuction
AccumulatorSkidpackage(seeseparateEngineeringBulletin).Thetransfervesselis
designedtohandleupto5%initialwatercontentinthesystemammoniacharge.
NotethatIndustrialRefrigerationgradeanhydrousammoniaiscertifiedtobe
99.95%pureammonia.

XII. EffectsofOilonEvaporatorPerformanceandOilSeparation

ImmisciblelubricantsarerecommendedovermisciblelubricantsforlargeindustrialDX
ammoniarefrigerationsystemsforanumberofreasons:
o Lowercost
o Easeofseparation
o Relativeinsensitivitytocontaminants(water,dirt)

Therefore,immiscibleoilispreferredovermiscible,however,DXevaporator
performanceisseverelypenalizedifimmiscibleoilisallowedtoreachevaporatorsand
coatinternaltubesurfaces.Evenathinlayerofoildepositedonevaporatortubeswill
resultinarelativelylargefoulingfactorasshowninFigure17below.

FIGURE17

 InsideFoulingFactorvsOilFilmThickness
 0.006


 0.005
InsideFoulingFactor,ft2Rh/Btu


 0.004


 0.003


 0.002


 0.001


 0
0 0.001 0.002 0.003 0.004 0.005
 OilFilmThickness,inches


InatypicalDXammoniaevaporator,thisfoulingfactorcausesasignificantreductionin
coolingcapacityasisshownbelowinFigure18.

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FIGURE18

 CapacityReductionvsOilFilmThickness
 AmmoniaEvaporator,15FSST,5FAirOn
 1


 0.95


CapacityReductionRatio

 0.9


 0.85


0.8


 0.75
 0 0.0005 0.001 0.0015 0.002 0.0025 0.003 0.0035 0.004
OilFilmThickness,inches



ItisapparentfromFigures17and18abovethatitishighlydesirablefromanenergy
efficiencystandpointtopreventcompressorlubricatingoilfromreachingtheevaporators.
Toachievethis,thefollowingshouldbecarefullyconsideredandspecifiedinthesystem
design:

a. Typeofcompressorlubricatingoil
b. Compressoroilseparatordesignandefficiency
c. Oilcaptureinthesystemreceiverandaccumulator(s)
d. Oilcaptureattheevaporator

TypeofOil:

Dependingonthetypeofcompressorused(reciprocatingorrotaryscrew),varyingamounts
oflubricatingoilwillunavoidablybedischargedwiththeammoniavapor.Oilwillleavethe
compressorbothinliquiddropletformandasoilvapor.Theliquiddropletscanbecaptured
mechanicallyintheoilseparatorvesselbycontrollingvelocityandbyincorporating
coalescingelements.Theoilwhichiscombinedwiththeammoniainvaporformismore
difficulttocapture.Generallyspeaking,asvolatilityandsolubilityoftheoilincrease,
separationbecomesmoredifficult.Theamountofoilwhichisnotcapturedintheseparator
andreturnedtothecompressorisreferredtoasoilcarryover.


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T: +1.509.684.2595 | F: +1.509.684.8331
www.colmaccoil.com

Alllubricatingoilsusedintheammoniarefrigerationindustryareblendsofabasefluid(s)
withadditives(Wierbosch2010).Thebasefluidcontrolsvolatilityandsolubiltyoftheoil.
Today,commonlyusedbasefluidsinclude:
Napthenic
SolventRefinedParaffinic
AlkylBenzene
2StageHydrocracked
PAO/AB

Thearomaticcontentofthebasefluidhasalargeeffectonvaporpressure(volatility)and
solubility.Thehigherthevaporpressureoftheoil,themoreoilvaporwillleavethe
compressorwiththeammoniainthedischargegas(Briley1984).Sincethisoilvaporis
difficulttocaptureintheseparator,itisdesirabletoselectanoilwhichhasthelowestvapor
pressurepossible.AlkylBenzeneandNaphthenicbaseshavethehighestaromaticcontent,
vaporpressure,andsolubility.2StageHydrocrackedbaseshavelowestaromaticcontent,
vaporpressure,andthelowestsolubility.

Itisthereforerecommendedthatammoniarefrigerationoilhavinga2StageHydrocracked
basefluidbeusedintheDXammoniacompressionsystemdesign.2StageHydrocracked
mineraloilmanufacturedbyCPI(CPI100868)isrecommendedforapplicationin
reciprocatingandscrewtypeammoniacompressorsfortemperaturesabove40.

Anotherfactoraffectingoilvaporpressureistheoiltemperature.Thehighertheoil
temperature,thehigherthevaporpressure.Reducingthedischargegas(andoilvapor)
temperaturebeforeitenterstheseparatorwillthereforereduceoveralloilcarryoverand
increasetheefficiencyoftheseparator.Forexample,desuperheatingthedischargegas
from80degCto35degCreducestheoilvaporpressure,andthereforecarryoverofoil
vapor,byapproximately85%(Wiencke2012).

OilSeparator;

ForsuccessfulDXammoniasystemoperation,anoilseparatorwithcoalescingelements
capableofguaranteeing57ppmcarryovershouldbespecifiedandinstalled.

Forreasonsmentionedabove,itisalsorecommendedthatthedischargegasbe
desuperheatedasmuchaspracticalpriortoenteringtheoilseparator.

NOTE:MeshPadoilseparatorsasfoundonolderscrewcompressorpackagesand
reciprocatingcompressorswillnothavetherequiredseparationefficiencyandarenot
recommended!

OilCaptureattheEvaporator:

Evenwhen2StageHydrocrackedoilisusedwithahighlyefficientoilseparator,itispossible
forsomeverysmallamountofoiltoreachtheentrancetotheevaporators.


Page39of52
ENG00019544REV02013ColmacCoilManufacturingInc.
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www.colmaccoil.com

Toseparateandcapturethisoilbeforeitreachestheevaporator,Colmachasdesigneda
proprietaryDXammoniadistributor.TheColmacTankDistributor(patentpending)
incorporatesadroplegintothebodyofthedistributortankwhichservestocollectoiland
debriswhereitcanbeperiodicallydrainedandremovedfromthesystemattheevaporator.

Figure19belowshowsacrosssectionoftheColmacTankDistributorwithitsintegraldrop
legfeatureforcapturingandremovingoil.

FIGURE19
COLMACTANKDISTRIBUTOR(CROSSSECTION)




















OilCapturefromtheSystem:

Colmacpreengineeredsuctionaccumulatorandintercoolervesselskidpackagesincludean
integraloilpotforcollectionandperiodicremovalofoil.

Itisalsorecommendedthathighpressurereceiversbedesignedwithanoilsumpanddip
tubeforcollectionandperiodicremovalofoil.

XIII. EstimatingDXEvaporatorRefrigerantChargeInventory

Inordertoproperlysizethevolumeofthesystemvessels(highpressurereceiverand
lowpressureaccumulator),anestimateoftherefrigerantchargeheldinthe
evaporatorsmustbemade.Designersnormallycalculatetheevaporatorchargeasa
percentageoftheevaporatorinternalvolumetimestheliquiddensityofammonia.


Page40of52
ENG00019544REV02013ColmacCoilManufacturingInc.
P.O. Box 571 | Colville, WA 99114 | USA
T: +1.509.684.2595 | F: +1.509.684.8331
www.colmaccoil.com

OneofthemainadvantagesofDXoperationisthesignificantlyreducedevaporator
ammoniachargecomparedtopumpedammonia.Manysystemdesignersestimate
evaporatorchargeforbottomfeedpumpedammoniaevaporatorstobeasmuchas
80%oftheinternalvolumetimestheliquiddensitytoaccountforlowloadandidle
conditions.DXammoniaevaporatorchargecanbeestimatedusingtwophasevoid
fractionequations.Table11belowshowsDXammoniaevaporatorchargeasa
percentageofinternalvolume.

TABLE11
COLMACDXAMMONIACHARGEINVENTORY
SuctionPressure,psia ColmacDXAmmonia
(SaturationTemp,F) EvaporatorChargeInventory,
lbs/ft3ofInternalVolume
48.2(+20F) 1.01
30.4(0F) 0.83
18.3(20F) 0.63
10.4(40F) 0.52

Thissignificantlyreducedsystemchargenotonlyreducestherequiredsizeofthe
receiver(and/orothersystemvessels),italsogreatlyreducespumpouttimeforthe
evaporatorspriortodefrosting.Thisservestoshortentotaldefrosttimeandincrease
theeffectivenessofhotgasdefrosting,reducingenergyconsumptionandoperating
costs.

EXAMPLE:
AColmacDXammoniaevaporatoroperatingatasuctiontemperatureof20degFhas
aninternalvolumeof12ft3.WhatistheexpectedDXammoniaoperatingcharge?What
wouldtheoperatingchargebeforpumpedammoniaoperationusingthe80%rule?

Answer:
ColmacDXammoniacharge=12ft3x0.63=7.6lbs
Pumpedammoniacharge=12ft3x0.8x42.2lbs/ft3=405lbs

XIV. ColmacSmartHotGasDefrost

Theenergyefficiencyofhotgasdefrostingevaporatorsdependsonthefollowing
(Nelson2011(1)):

1. Minimizingconvectiveheatloss.
Uselowestpracticaldefrostregulatorsetting.75to90psig(50to60F)
shouldbeadequate.Note:Ifhigherpressuresareneeded,lookfor
problemselsewhere.
2. Shortendefrostduration.
UsetopfeedorDX(directexpansion)evaporatorfeedtoreducetime
requiredforpumpout.
Openthehotgassolenoidonlylongenoughtoclearcoil(68minutes).

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Installaseparatehotgassolenoidanddefrostregulatorforpreand
postheatingofthepanloop.Alternately,installelectricresistance
drainpanheating.
3. Reducethenumberofdefrostsperday.
Reducethenumberofdefrostsperdaytomatchthefrostload.
Chooseevaporatorswithwidefinspacing(3fpiinsteadof4fpi)to
maximizefrostcarryingcapacity.
Mitigateinfiltrationofhumidairintotherefrigeratedspaceby:
x Properdesignandoperationofdoorways,and
x Keeploadingdocksatthelowestpracticaldewpoint
temperature.

CalculatingtheCostofDefrost

Asmentionedabovedefrostefficiencycanbesignificantlyimprovedbyreducingthe
amountofenergylosttotheroombyconvectionduringdefrost.Theoperatingcost
savingsduetoareductionindefrostdurationhasbeencalculatedandpresentedbelow
basedon:

1. Reducingdefrostdurationfrom30minutesto10minutes,and
2. Increasingfrostthicknessfrom1mmto2mm(reducingthenumberofdefrosts
perdaybyhalf).

Thecalculationsassume:

Evaporatorcapacity:100TR
Compressorruntime:16h/day
CostofElectricity:$0.10/kWh

Table12showscalculatedcostsavingsforfourdifferentroomtemperatures.













Page42of52
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TABLE12
CALCULATEDCOSTSAVINGS($/y/100TR)FOROPTIMIZEDVSCONVENTIONALDEFROST

 Room Temp, C (F)
 0 (+32) -18 (0) -23 (-10) -34 (-30)
 SHR 0.66 0.89 0.93 0.97
System COP: 3.2 2.5 2.2 2

Frost Removed, kg/day: 2,778 899 572 245
 Frost Removed, kg/y: 1,014,096 328,090 208,784 89,479
 I. Baseline (30 min, 1 mm)
 Defrost Efficiency, % 32% 18% 17% 14%
 Defrost Convective Losses, %: 46% 61% 63% 65%
 Defrost Convective Losses, kWh/y: 1,012,438 753,334 545,922 283,071
 Baseline Cost of Defrost (Convective), $/y: $31,639 $30,133 $24,815 $14,154
II. Optimized (10 min, 2 mm)

Defrost Efficiency, % 61% 46% 43% 40%
 Defrost Convective Losses, %: 15% 26% 27% 30%
 Defrost Convective Losses, kWh/y: 168,740 125,556 90,987 47,178
 Optimized Cost of Defrost (Convective), $/y: $5,273 $5,022 $4,136 $2,359
SmartHotGasDefrostPiping
Savings
 Optimized vs Baseline, $/y: $26,366 $25,111 $20,679
 $11,795

Conventionalammoniaevaporatorsaretypicallyarrangedforbottomfeedwiththehot
gaspanlooppipedinserieswiththecoil.TheColmacSmartHotGasDefrostsystem
(Nelson2011(2))resultsinthehighestpossibledefrostefficiencyandlowestoperating
costbyutilizingtopfeedDXcircuitingwiththehotgaspanlooppipedseparatelyfrom
thecoil.Thisresultsin:

Pumpoutperiodshortenedto5minutes
Defrostduration(timecoilhotgassolenoidisopen)ofonly68minutes

ColmacSmartHotGasDefrostcontrolvalvegroupsareshowninFigures20and21
below.















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P.O. Box 571 | Colville, WA 99114 | USA
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www.colmaccoil.com


FIGURE20
COLMACDXSMARTHOTGASDEFROSTCONTROLVALVEGROUP
HIGHPRESSURELIQUID(HPL)FEED






















 DC







GLOBE VALVE ANGLE VALVE

 SOLENOID VALVE ELECTRONIC EXPANSION VALVE

 STRAINER HAND EXPANSION VALVE

 SUCTION STOP VALVE CHECK VALVE


TANK DISTRIBUTOR AUTO VENT


SIGHT GLASS




Page44of52
ENG00019544REV02013ColmacCoilManufacturingInc.
P.O. Box 571 | Colville, WA 99114 | USA
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www.colmaccoil.com


FIGURE21
COLMACDXSMARTHOTGASDEFROSTCONTROLVALVEGROUP
INTERMEDIATEPRESSURELIQUID(FROMINTERCOOLER)FEED























 DC








GLOBE VALVE ANGLE VALVE CHECK VALVE


SOLENOID VALVE ELECTRONIC EXPANSION VALVE SIGHT GLASS


STRAINER HAND EXPANSION VALVE PRV VALVE


SUCTION STOP VALVE TANK DISTRIBUTOR





Page45of52
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P.O. Box 571 | Colville, WA 99114 | USA
T: +1.509.684.2595 | F: +1.509.684.8331
www.colmaccoil.com


Withaconventionalbottomfeedandhotgasdefrostpipingarrangement,hotgasisfirst
sentthroughthedrainpanloopandtheninseriesthroughthecoilblock.Thiscommonly
usedarrangementiseffectiveandsimple,however,itrequiresthatthehotgassolenoid
remainsopentokeepthedrainpanheatedlongenoughforallwatertocompletely
drainandexitthroughthedrainpiping.Convectiveheatlosstotheroomcontinuesafter
thecoilisclearoffrostwhilethepanisdraining.

Amoreefficientarrangementistocontrolhotgastothecoilblockandtothedrainpan
loopseparatelythroughtwoseparatelytimedhotgassolenoidvalves.Thisarrangement
shortenstheamountoftimehotgasisflowingthroughthecoilblock,minimizingthe
convectiveheatlossandmaximizingdefrostefficiency.

AproperlysizedcontrolvalvegroupfortheColmacSmartHotGasDefrostpiping
arrangementislessexpensivethanaconventionalbottomfeedhotgasdefrostpiping
arrangementwithdefrostregulator.

ColmacDXSmartHotGasDefrostSequenceofOperation

1. Defrostisinitiated.
2. LiquidLineSolenoid(LLS)closes
3. Briefpumpoutperiod(5minutes)
4. Fan(s)stop
5. Panloopsolenoidenergizedfortimedpanpreheat(23minutes)
6. Coilhotgassolenoidandpilotsolenoid(closessuctionstopvalve)open
7. Timeddefrost(68minutes)
8. Coilhotgassolenoidcloses
9. Aftercoilpressureisequalizedtosuctionpressure(35minutes),SuctionStop
Valveopens
10. OpenLLS
11. Panloopsolenoiddeenergized
12. After5minutecooldowndelayfansrestart

DiversityandDefrostTiming

Aswithallhotgasdefrostsystems,thetwotoonerulemustbeobservedinthe
executionofdefrosts.Thatis,aminimumoftwoevaporatorsinthesametemperature
zonemustberunning(liquidlinesolenoidsopen)atthesametimeoneevaporatoris
defrosting.Thisstrategyisneededtoprovideenoughloadtobalanceevaporatingto
condensing(defrosting)capacityintherefrigerationsystem.

HotGasFlowrateandValveSelection

Colmacprovidestoitsrepresentativesandselectedcustomersacalculationtoolfor
estimatinghotgasflowrategivenoperatingtemperaturesandevaporatordimensional
data.

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www.colmaccoil.com


ThecompleteColmacDXSmartHotGasDefrostevaporatorcontrolvalveisalsooffered
fromColmacasakitorfactorymountedontheevaporator.

XV. DefrostWaterVolumeandDrainLineSizing

Followingisasimplemethodtocalculatetheamountofmoistureremovedbytheair
coolersfromairintherefrigeratedspacesinordertodetermine:

A) Totalseweragerequirementsforthefacility,and
B) Properdrainpipingsizestohandlepeakflowratesduringdefrost.

Thissectionwillpresenttwosimplecalculationmethodsfordeterminingthese
importantdesignparameters(Nelson2008).

DeterminingTotalVolumeofMoistureRemoved:

Inordertoestimatethevolumeofwatergeneratedfromdefrosting(orwetfin)air
coolers,thehoursperdaythecooler(s)operatealongwiththeSensibleHeatRatio
(SHR)mustbeknown.Assumingaroomrelativehumidityof90%,theSHRforanair
cooleroperatingatvarioustemperatureswillbeasshowninTable13below:

Table13
SHRfor90%rhAiratVariousTemperatures

RoomTemp,F AirSHR
45 0.59
32 0.70
10 0.85
10 0.93
30 0.98

Theamountofmoistureaccumulatedonthesurfacesoftheaircooler(s)thatwillbedrained
ascondensedwaterinhightemproomsorasmeltedfrostinmediumandlowtemprooms,
canbeestimatedusingthefollowingformula:

 Gal / day 1.35t 1  SHR Q     (8)

where:
t=OperatingTime,hours/day
SHR=AirSensibleHeatRatio
Q=SystemCoolingCapacity,tons(note:1ton=12,000Btuh)
1.35(constant)=12,000Btuh/ton/(8.33lbs/galx1,068Btu/lbs)
8.33lbs/gal=liquiddensityofwater
1,068Btu/lbs=latentheatofvaporizationofwater

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Example1:
 RoomTemp:45F
 OperatingTime:12hours/day
 RoomSHR(fromTable1):0.59
 SystemCoolingCapacity:50tons
 CondensedWaterVolume=1.35x12x(1.59)x50=332gal/day

Example2:
 RoomTemp:10F
 OperatingTime:16hours/day
 RoomSHR(fromTable1):0.93
 SystemCoolingCapacity:100tons
 DefrostWaterVolume=1.35x16x(10.93)x100=151gal/day

DeterminingPeakDefrostWaterFlowrate

Todeterminethepeakdefrostwaterflowrateleavingafrostedcoilsurface,firstcalculate
thevolumeofwateryieldedbyacoolingcoilduringdefrostusingthefollowingequation:


1

 t fin

 S fin
    Vdef  u Asurf
 0.0937  u   u H   (9)
2




     :
where        

 Vdef
 Asurf

 S fin
 t fin

 H

Note:Thisequationassumesfrosthasaveragedensityof150kg/m3(Besant1999),approx.
1/6ththatofliquidwater.

Example1:
 TotalSurfaceArea=4,500sqft
 FinSpacing=4finsperinch
 FinThickness=0.012inches
 FractionofFrostBlockage=0.5
 VolumeofDefrostWater=0.0937x4,500x(1/40.012)/2x0.5=25gallons

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www.colmaccoil.com


Inordertothendeterminethepeakflowrate,anestimateofthelengthofdefrosttime
mustbemade.Forhotgasdefrosting,themajorityofdefrostwaterflowstothedrainina
relativelyshortperiodoftime.Toestimatepeakflowrateofdefrostwateranestimated
durationofdefrostof5minutescanreasonablybemade(Stoecker1983).

Tocalculatepeakflowrate,simplydividethevolumeofdefrostwaterbytheestimated
durationofdefrost.Fortheexample:

Estimatedpeakdefrostflowrate=25gal/5min=5gpm

Drainlinescannowbesizedbasedonthecalculatedpeakdefrostflowrate.Themaximum
peakflowrateforafacilitywillbethecombinedflowratesforthemaximumnumberof
coolingcoilsexpectedtodefrostsimultaneously.

Colmacprovidestoitsrepresentativesandselectedcustomersacalculationtoolfor
estimatingdefrostflowrategivenoperatingtemperaturesandevaporatordimensional
data.

SizingSlopingDrainLines

TheAmericanSocietyofPlumbingEngineers(ASPE)publishessizingmethodsforvertical
andslopingdrains(ASPE1999).ThefollowingtableistakenfromtheASPEDataBook
Volume2,page8.

Table14
ApproximateDischargeRatesandVelocitiesinSlopingDrains,n=0.015*

ActualInsideDiameter FullFlowDischargeRateandVelocity
ofPipe,inches Basedoninch/ftSlope
Discharge,gpm Velocity,fps
13/8 3.13 1.34
1 3.91 1.42
15/8 4.81 1.50
2 8.42 1.72
2 15.3 1.99
3 24.8 2.25
4 53.4 2.73
5 96.6 3.16
6 157 3.57
8 340 4.34
10 616 5.04
12 999 5.67

*n=Manningcoefficient,whichvarieswiththeroughnessofthepipe.

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Horizontaldrainlinesmustbepitchedatleastperfoottoinsurepositivedrainage.

Drainlinesrunningthroughfreezingspacesshouldbeactivelyheatedwithheattracecable
andthenwellinsulated.

Drainlinesshouldalsohaveptrapsinstalledjustoutsidetherefrigeratedspacetoprevent
backflowofwarmhumidambientairthroughthedrainlineintotherefrigeratedspace.


XVI. References

Briley,G.C.1984.Lubricant(Oil)Separation.InternationalInstituteofAmmonia
Refrigeration,Alexandria,VA.ProceedingsoftheIIAR1984AnnualMeeting,pp107F131F.

ClelandD.J.,OHaganA.N.2002.PerformanceofanAirCoolingCoilUnderFrosting
Conditions.AmericanSocietyofHeating,RefrigeratingandAirConditioningEngineers.
ASHRAETransactions2002V.109,Pt.1

Cleland,D.J.2012.TheEffectofWaterVapouronFoodRefrigerationSystems.The
InstituteofRefrigeration.London,UK.Proc.Inst.R.201112.5.

Davis,J.R.,1999,CorrosionofAluminumandAluminumAlloys,ASMInternaional,
MaterialsPark,OH.Chap2,pp38.

IIAR2004,AmmoniaRefrigerationPipingHandbook.InternationalInstituteofAmmonia
Refrigeration.Alexandria,VA.

IIAR2008,ANSI/IIAR22008Equipment,Design,andInstallationofClosedCircuitAmmonia
MechanicalRefrigeratingSystems,InternationalInstituteofAmmoniaRefrigeration.
Alexandria,VA.

Jensen,S.2013.Personalcorrespondence.

LaRocheIndustries,1987,AquaAmmoniaInformationManual,LaRocheIndustriesInc.
Concord,NC.

LaRocheIndustries,1998,MaterialSafetyDataSheet#4003(AmmoniumHydroxide),
LaRocheIndustriesInc.Concord,NC.

Nelson,B.I.,2008,DeterminingDefrostWaterVolume.TechnicalBulletin.ColmacCoil
Manufacturing,Inc.Colville,WA.

Nelson,B.I.,2010,ThermodynamicEffectsofWaterinAmmoniaonEvaporator
Performance,InternationalInstituteofAmmoniaRefrigeration,Alexandria,VA.
ProceedingsoftheIIAR2010AnnualMeeting,pp201236.


Page50of52
ENG00019544REV02013ColmacCoilManufacturingInc.
P.O. Box 571 | Colville, WA 99114 | USA
T: +1.509.684.2595 | F: +1.509.684.8331
www.colmaccoil.com

Nelson,B.I.,2011,U.S.Patent7,958,738,DirectExpansionAmmoniaRefrigerationSystem
andaMethodofDirectExpansionAmmoniaRefrigeration.

Nelson,B.I.,2011(1),OptimizingHotGasDefrost.TechnicalBulletin.ColmacCoil
Manufacturing,Inc.Colville,WA.

Nelson,B.I.,2011(2),ColmacIntroducesDXAmmoniawithSmartHotGasSHGDefrost.
TechnicalBulletin.ColmacCoilManufacturing,Inc.Colville,WA.

Nelson,B.I.,2012(a),ComparingAirCoolerRatingsPart1:NotAllRatingMethodsare
CreatedEqual.TechnicalBulletin.ColmacCoilManufacturing,Inc.Colville,WA.

Nelson,B.I.,2012(b),ComparingAirCoolerRatingsPart2:WhyDTMRatingsCostYou
Money.TechnicalBulletin.ColmacCoilManufacturing,Inc.Colville,WA.

Smith,E.2010,TechnicalNote.InternationalInstituteofAmmoniaRefrigeration(IIAR).
Alexandria,VA.CondenserMagazineAugust2010.

Stoecker,W.F.1988,IndustrialRefrigerationHandbook,BusinessNewsPublishing
Company,Michigan.

TannerIndustries,2000,MaterialSafetyDataSheet(AmmoniumHydroxide),Tanner
Industries,Inc.Southampton,PA.

Welch,J.2013.Personalcorrespondence.

Wiencke,B.2002,SizingandDesignofGravityLiquidSeparatorsinIndustrial
Refrigeration,InternationalInstituteofAmmoniaRefrigeration,Alexandria,VA.
ProceedingsoftheIIAR2002AnnualMeeting,pp63133.

Wiencke,B.2012.Personalcorrespondence.

Wierbosch,M.andSandler,M.2010,BaseFluidEffectonPerformanceinanAmmonia
RefrigerationSystem.RMSupportBV.Henglelo,NL.













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XVII. APPENDIXA

ThreeP&IDdiagramsareshownrepresenting:

Figure1SingleStageSingleTemperatureLevel
Figure2SingleStage(EconomizedScrew)MultipleTemperatureLevel
Figure3TwoStageMultipleTemperatureLevel



































Page52of52
ENG00019544REV02013ColmacCoilManufacturingInc.
FIGURE1
COLMACDXAMMONIA
SINGLESTAGESINGLETEMPERATURELEVEL

 EXPANSION
TANK

 EVAPORATIVE
90 psig CONDENSER
 60F

e  GLYCOL OIL
COOLING LOOP

LP

SH HLCO  COMPRESSOR

SUCTION DRY  LEVEL HIGH PRESSURE


TRAP OPERATION RANGE RECEIVER
 MOTOR
OPTIONAL
DX EVAPORATOR BPRV 
AIR DEFROST


 COALESCING OIL
SEPARATOR SUBCOOLER
OIL POT 
e T
HTR
110F

WATER STILL TRANSFER N.C.
 GLYCOL
OIL COOLER
 75 psig
SH e
 (50.3F SAT)
P
 SUBCOOLER SUCTION T
SUBCOOLED
 to 40F
DX EVAPORATOR
HOT GAS COIL ONLY  SUBCOOLED REDUCED PRESSURE LIQUID


e 
SOLENOID VALVE ELECTRONIC EXPANSION VALVE PRV VALVE W/ ELECTRIC SHUT OFF

DRAIN VALVE  VALVE
3-WAY HAND EXPANSION VALVE

RELIEF VALVE GLOBE VALVE ANGLE VALVE

AUTO VENT  VALVE
CHECK STRAINER

PUMP

TANK DISTRIBUTOR DOUBLE ACTING RELIEF VALVE

P PRESSURE GAUGE REFLEX LEVEL EYE LP LEVEL PROBE

SH SUPERHEAT TRANSDUCER T

TEMPERATURE TRANSDUCER




Copyright2013ColmacCoilManufacturingInc.
FIGURE2
COLMACDXAMMONIA
SINGLESTAGE(ECONOMIZEDSCREW)MULTIPLETEMPERATURELEVEL EXPANSION
TANK

EVAPORATIVE
 90 psig CONDENSER
60F

GLYCOL OIL
e
70 psig  COOLING LOOP
(47F)

LP 
SH 
HLCO
P LEVEL
ECONOMIZER

FLASH COOLER/
RANGE
RECEIVER

HOT GAS PAN LOOP 
SUBCOOLER

DX EVAPORATOR

SMART HOT GAS COIL & PAN
MEDIUM TEMPERATURE  N.C.

OIL POT 
SUBCOOLER
75 psig
e
 (50.3F SAT)

N.C.  T

 SUBCOOLED
SUBCOOLED to 40F
e
by 10F  ECONOMIZER
T


e

SUCTION

LP

SH 
HLCO
P
DRY SUCTION

OPERATION TRAP
 MOTOR

HOT GAS PAN LOOP



 COMPRESSOR
DX EVAPORATOR
SMART HOT GAS COIL & PAN 
LOW TEMPERATURE COALESCING OIL
OIL POT  SEPARATOR
T
HTR
110F
WATER STILL TRANSFER
 GLYCOL
OIL COOLER

e

SOLENOID VALVE 
ELECTRONIC EXPANSION VALVE PRV VALVE W/ ELECTRIC SHUT OFF

DRAIN VALVE 3-WAY VALVE


 HAND EXPANSION VALVE

RELIEF VALVE GLOBE VALVE ANGLE VALVE

LIQUID DRAINER CHECK VALVE STRAINER

PUMP 
TANK DISTRIBUTOR DOUBLE ACTING RELIEF VALVE

AUTO VENT

PIPE CAP (CLEANOUT) LP LEVEL PROBE
Copyright2013ColmacCoilManufacturingInc.
P PRESSURE GAUGE REFLEX LEVEL EYE T TEMPERATURE TRANSDUCER

SH SUPERHEAT TRANSDUCER PRV VALVE


FIGURE3
COLMACDXAMMONIA EXPANSION
TWOSTAGEMULTIPLETEMPERATURELEVEL TANK

 EVAPORATIVE
90 psig CONDENSER
 60F

 GLYCOL OIL
70 psig
e COOLING LOOP
(47F) 

LP
SH

P
HLCO  LEVEL
INTERCOOLER/
ECONOMIZER RANGE
RECEIVER

 HIGH STAGE
HOT GAS PAN LOOP SUBCOOLER COMPRESSOR

DX EVAPORATOR
SMART HOT GAS COIL & PAN
 MOTOR
MEDIUM TEMPERATURE N.C.

OIL POT
SUBCOOLER  75 psig
e (50.3F SAT)

T COALESCING OIL
N.C.  SEPARATOR
SUBCOOLED
 to 40F
e SUBCOOLED
by 10F
 GLYCOL
OIL COOLER
T 

e 

LP

SH BOOSTER
HLCO  COMPRESSOR
P
DRY SUCTION
OPERATION TRAP 
MOTOR

HOT GAS PAN LOOP

DX EVAPORATOR 
SMART HOT GAS COIL & PAN
LOW TEMPERATURE  COALESCING OIL
OIL POT SEPARATOR
T 
HTR
WATER STILL 
110F
TRANSFER GLYCOL
 OIL COOLER


e 
SOLENOID VALVE ELECTRONIC EXPANSION VALVE PRV VALVE W/ ELECTRIC SHUT OFF

DRAIN VALVE 3-WAY VALVE  HAND EXPANSION VALVE

RELIEF VALVE GLOBE VALVE ANGLE VALVE

LIQUID DRAINER CHECK VALVE


 STRAINER

PUMP TANK DISTRIBUTOR DOUBLE ACTING RELIEF VALVE

AUTO VENT PIPE CAP (CLEANOUT) LP LEVEL PROBE Copyright2013ColmacCoilManufacturingInc.
P PRESSURE GAUGE REFLEX LEVEL EYE T TEMPERATURE TRANSDUCER

SH SUPERHEAT TRANSDUCER PRV VALVE

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