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Pickling Gel CT-501 NB

SIAM PLASMA CORP.,LTD.


Chemwatch: 62-3982 Issue Date: 22/03/2016
Version No: 3.1.1.1 Print Date: 23/03/2016
Safety Data Sheet Initial Date: Not Available
S.GHS.PER.EN

SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING

Product Identifier
Product name Pickling Gel CT-501 NB
Synonyms Pickling Paste for Stainless Steels
Proper shipping name CORROSIVE LIQUID, TOXIC, N.O.S. (contains acrylamide,nitric acid and hydrofluoric acid)
Other means of
Not Available
identification

Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses Use for clean metal surface such as stainless steels.

Details of the supplier of the safety data sheet


Registered company name SIAM PLASMA CORP.,LTD.
Address 98/53 Moo 11, BUDDHAMONTHON SAI 5 Rd., RAIKHING, SAMPHRAN, NAKHONPATHOM 73210 Thailand
Telephone (66) 02-0198866
Fax (66) 02-0198874
Website www.arcmenchemical.com
Email sales@siamplasma.com

Emergency telephone number


Association / Organisation WORRAKORNPAK KHUNCHAI
Emergency telephone
(66) 02-0198866 - 101
numbers
Other emergency telephone
Not Available
numbers

SECTION 2 HAZARDS IDENTIFICATION

Classification of the substance or mixture


Metal Corrosion Category 1, Acute Toxicity (Oral) Category 3, Acute Toxicity (Dermal) Category 4, Acute Toxicity (Inhalation) Category 4, Skin
Classification Corrosion/Irritation Category 1B, Serious Eye Damage Category 1, Skin Sensitizer Category 1, Germ cell mutagenicity Category 1B, Carcinogenicity
Category 1B, Reproductive Toxicity Category 2, Specific target organ toxicity - repeated exposure Category 1, Chronic Aquatic Hazard Category 3

Label elements

GHS label elements

SIGNAL WORD DANGER

Hazard statement(s)
H290 May be corrosive to metals.
H301 Toxic if swallowed.
H312 Harmful in contact with skin.
H332 Harmful if inhaled.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H317 May cause an allergic skin reaction.
H340 May cause genetic defects.
H350 May cause cancer.

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Pickling Gel CT-501 NB

H361 Suspected of damaging fertility or the unborn child.


H372 Causes damage to organs.
H412 Harmful to aquatic life with long lasting effects.

Precautionary statement(s) Prevention


P201 Obtain special instructions before use.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P234 Keep only in original packaging.
P273 Avoid release to the environment.
P272 Contaminated work clothing should not be allowed out of the workplace.

Precautionary statement(s) Response


P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor/physician/first aider.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308+P313 IF exposed or concerned: Get medical advice/ attention.
P302+P352 IF ON SKIN: Wash with plenty of water and soap.
P363 Wash contaminated clothing before reuse.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
P390 Absorb spillage to prevent material damage.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

Precautionary statement(s) Storage


P405 Store locked up.

Precautionary statement(s) Disposal


P501 Dispose of contents/container in accordance with local regulations.

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

Substances
See section below for composition of Mixtures

Mixtures
CAS No %[weight] Name Classification
Acute Toxicity (Oral) Category 3, Acute Toxicity (Dermal) Category 4, Acute Toxicity (Inhalation) Category 4,
Skin Corrosion/Irritation Category 2, Eye Irritation Category 2A, Skin Sensitizer Category 1, Germ cell
79-06-1 20-40 acrylamide mutagenicity Category 1B, Carcinogenicity Category 1B, Reproductive Toxicity Category 2, Specific target
organ toxicity - repeated exposure Category 1; H301, H312, H332, H315, H319, H317, H340, H350, H361,
H372
Oxidizing Liquid Category 1, Oxidizing Liquid Category 3, Metal Corrosion Category 1, Acute Toxicity
(Inhalation) Category 1, Skin Corrosion/Irritation Category 1A, Serious Eye Damage Category 1, Specific
7697-37-2 10-30 nitric acid
target organ toxicity - single exposure Category 3 (respiratory tract irritation); H271, H272, H290, H330, H314,
H318, H335
Flammable Liquid Category 2, Metal Corrosion Category 1, Acute Toxicity (Oral) Category 4, Skin
64-18-6 1-10 formic acid
Corrosion/Irritation Category 1A, Serious Eye Damage Category 1; H225, H290, H302, H314, H318
Metal Corrosion Category 1, Acute Toxicity (Oral) Category 2, Acute Toxicity (Dermal) Category 1, Acute
7664-39-3 1-5 hydrofluoric acid Toxicity (Inhalation) Category 1, Skin Corrosion/Irritation Category 1A, Serious Eye Damage Category 1; H290,
H300, H310, H330, H314, H318
p-tert-octylphenol Acute Toxicity (Oral) Category 4, Skin Corrosion/Irritation Category 2, Serious Eye Damage Category 1,
9002-93-1 1-5
ethoxylate Chronic Aquatic Hazard Category 2; H302, H315, H318, H411
Flammable Liquid Category 2, Metal Corrosion Category 1, Acute Toxicity (Oral) Category 4, Acute Toxicity
108-01-0 1-5 dimethylethanolamine (Dermal) Category 4, Acute Toxicity (Inhalation) Category 4, Skin Corrosion/Irritation Category 1A, Serious Eye
Damage Category 1; H225, H290, H302, H312, H332, H314, H318
Ingredients determined
Not Available 20-40 Not Applicable
not to be hazardous

SECTION 4 FIRST AID MEASURES

Description of first aid measures

Eye Contact

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Pickling Gel CT-501 NB

If this product comes in contact with the eyes:


Immediately hold eyelids apart and flush the eye continuously with running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids.
Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes.
Transport to hospital or doctor without delay.
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
If there is evidence of severe skin irritation or skin burns:
Avoid further contact. Immediately remove contaminated clothing, including footwear.
Flush skin under running water for 15 minutes.
Avoiding contamination of the hands, massage calcium gluconate gel into affected areas, pay particular attention to creases in skin.
Contact the Poisons Information Centre.
Skin Contact
Continue gel application for at least 15 minutes after burning sensation ceases.
If pain recurs, repeat application of calcium gluconate gel or apply every 20 minutes.
If no gel is available, continue washing for at least 15 minutes, using soap if available. If patient is conscious, give six calcium gluconate or calcium
carbonate tablets in water by mouth.
Transport to hospital, or doctor, urgently.
Inhalation of vapours or aerosols (mists, fumes) may cause lung oedema.
Corrosive substances may cause lung damage (e.g. lung oedema, fluid in the lungs).
As this reaction may be delayed up to 24 hours after exposure, affected individuals need complete rest (preferably in semi-recumbent posture) and must be
kept under medical observation even if no symptoms are (yet) manifested.
Before any such manifestation, the administration of a spray containing a dexamethasone derivative or beclomethasone derivative may be considered.
This must definitely be left to a doctor or person authorised by him/her.
(ICSC13719)
For massive exposures:
Inhalation
If dusts, vapours, aerosols, fumes or combustion products are inhaled, remove from contaminated area.
Lay patient down.
Keep warm and rested.
Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures.
Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if
necessary.
If victim is conscious, give six calcium gluconate or calcium carbonate tablets in water by mouth.
Transport to hospital, or doctor, urgently.
For advice, contact a Poisons Information Centre or a doctor at once.
Urgent hospital treatment is likely to be needed.
If swallowed do NOT induce vomiting.
If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration.
Ingestion
Observe the patient carefully.
Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.
Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
Transport to hospital or doctor without delay.

Indication of any immediate medical attention and special treatment needed


Treat symptomatically.

SECTION 5 FIREFIGHTING MEASURES

Extinguishing media
The product contains a substantial proportion of water, therefore there are no restrictions on the type of extinguishing media which may be used.

Special hazards arising from the substrate or mixture


Fire Incompatibility None known.

Advice for firefighters


Fire Fighting Alert Fire Brigade and tell them location and nature of hazard.
Fire/Explosion Hazard Non combustible.

SECTION 6 ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures


Drains for storage or use areas should have retention basins for pH adjustments and dilution of spills before discharge or disposal of material.
Minor Spills
Clean up all spills immediately.
Major Spills Clear area of personnel and move upwind.

Personal Protective Equipment advice is contained in Section 8 of the SDS.

SECTION 7 HANDLING AND STORAGE

Precautions for safe handling


DO NOT allow clothing wet with material to stay in contact with skin
Safe handling
Avoid all personal contact, including inhalation.
Other information Store in original containers.

Conditions for safe storage, including any incompatibilities


Lined metal can, lined metal pail/ can.
Suitable container
|P.E.

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Pickling Gel CT-501 NB

Reacts with mild steel, galvanised steel / zinc producing hydrogen gas which may form an explosive mixture with air.
Avoid any contamination of this material as it is very reactive and any contamination is potentially hazardous
Storage incompatibility
Avoid strong bases.
Avoid strong acids, acid chlorides, acid anhydrides and chloroformates.

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

Control parameters

OCCUPATIONAL EXPOSURE LIMITS (OEL)


INGREDIENT DATA
Source Ingredient Material name TWA STEL Peak Notes
Peru Occupational Exposure
acrylamide Acrilamida Not Available Not Available Not Available AQC
Limits
Peru Occupational Exposure
nitric acid cido ntrico 5.2 mg/m3 / 2 ppm 10.4 mg/m3 / 4 ppm Not Available Not Available
Limits
Peru Occupational Exposure
formic acid cido frmico 9.4 mg/m3 / 5 ppm 18.8 mg/m3 / 10 ppm Not Available Not Available
Limits
Peru Occupational Exposure
hydrofluoric acid Fluoruro de hidrgeno 1.5 mg/m3 / 1.8 ppm Not Available 2.5 mg/m3 / 3 ppm VLB
Limits

EMERGENCY LIMITS
Ingredient Material name TEEL-1 TEEL-2 TEEL-3
acrylamide Acrylamide 10 mg/m3 110 mg/m3 110 mg/m3
nitric acid Nitric acid Not Available Not Available Not Available
formic acid Formic acid Not Available Not Available Not Available
hydrofluoric acid Hydrogen fluoride; (Hydrofluoric acid) Not Available Not Available Not Available
p-tert-octylphenol ethoxylate Triton X-100; (Poly(oxyethylene)-p-tert-octylphenyl ether) 2.7 mg/m3 29 mg/m3 360 mg/m3
dimethylethanolamine Dimethylaminoethanol, 2- 0.67 ppm 7.4 ppm 72 ppm

Ingredient Original IDLH Revised IDLH


acrylamide Unknown mg/m3 / Unknown ppm 60 mg/m3
nitric acid 100 ppm 25 ppm
formic acid 30 ppm 30 [Unch] ppm
hydrofluoric acid 30 ppm 30 [Unch] ppm
p-tert-octylphenol ethoxylate Not Available Not Available
dimethylethanolamine Not Available Not Available
Ingredients determined not to
Not Available Not Available
be hazardous

Exposure controls
Appropriate engineering
Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard.
controls

Personal protection

Eye and face protection Chemical goggles.


Skin protection See Hand protection below
Wear chemical protective gloves, e.g. PVC.
When handling corrosive liquids, wear trousers or overalls outside of boots, to avoid spills entering boots.
Hands/feet protection NOTE:
The material may produce skin sensitisation in predisposed individuals.
The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from manufacturer to manufacturer.
Body protection See Other protection below
Employees working with confirmed human carcinogens should be provided with, and be required to wear, clean, full body protective clothing (smocks,
coveralls, or long-sleeved shirt and pants), shoe covers and gloves prior to entering the regulated area.
Prior to each exit from an area containing confirmed human carcinogens, employees should be required to remove and leave protective clothing and
Other protection
equipment at the point of exit and at the last exit of the day, to place used clothing and equipment in impervious containers at the point of exit for purposes of
decontamination or disposal.
Overalls.
Thermal hazards Not Available

Respiratory protection
Type ABEK-P Filter of sufficient capacity.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

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Pickling Gel CT-501 NB

Information on basic physical and chemical properties


Appearance White gel with acid odour; miscible with water.

Physical state Liquid Relative density (Water = 1) 1.14


Partition coefficient
Odour Not Available Not Available
n-octanol / water
Auto-ignition temperature
Odour threshold Not Available Not Available
(C)
Decomposition
pH (as supplied) 0.8-1 Not Available
temperature
Melting point / freezing
Not Available Viscosity (cSt) Not Available
point (C)
Initial boiling point and
95 Molecular weight (g/mol) Not Applicable
boiling range (C)
Flash point (C) Not Applicable Taste Not Available
Evaporation rate Not Available Explosive properties Not Available
Flammability Not Applicable Oxidising properties Not Available
Surface Tension (dyn/cm or
Upper Explosive Limit (%) Not Applicable Not Available
mN/m)
Lower Explosive Limit (%) Not Applicable Volatile Component (%vol) Not Available
Vapour pressure (kPa) Not Available Gas group Not Available
Solubility in water (g/L) Miscible pH as a solution (1%) Not Available
Vapour density (Air = 1) Not Available VOC g/L Not Available

SECTION 10 STABILITY AND REACTIVITY

Reactivity See section 7


Chemical stability Contact with alkaline material liberates heat
Possibility of hazardous
See section 7
reactions
Conditions to avoid See section 7
Incompatible materials See section 7
Hazardous decomposition
See section 5
products

SECTION 11 TOXICOLOGICAL INFORMATION

Information on toxicological effects


Inhalation of vapours or aerosols (mists, fumes), generated by the material during the course of normal handling, may be harmful.
Inhaled
Corrosive acids can cause irritation of the respiratory tract, with coughing, choking and mucous membrane damage.
Toxic effects may result from the accidental ingestion of the material; animal experiments indicate that ingestion of less than 40 gram may be fatal or may
produce serious damage to the health of the individual.
Ingestion
The material can produce chemical burns within the oral cavity and gastrointestinal tract following ingestion.
Ingestion of acidic corrosives may produce burns around and in the mouth, the throat and oesophagus.
The material can produce chemical burns following direct contact with the skin.
Open cuts, abraded or irritated skin should not be exposed to this material
Skin Contact
Skin contact with acidic corrosives may result in pain and burns; these may be deep with distinct edges and may heal slowly with the formation of scar tissue.
Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects.
The material can produce chemical burns to the eye following direct contact.
Eye
If applied to the eyes, this material causes severe eye damage.
Skin contact with the material is more likely to cause a sensitisation reaction in some persons compared to the general population.
There is ample evidence that this material can be regarded as being able to cause cancer in humans based on experiments and other information.
Based on experiments and other information, there is ample evidence to presume that exposure to this material can cause genetic defects that can be inherited.
Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed.
Chronic
This material can cause serious damage if one is exposed to it for long periods.
Ample evidence from experiments exists that there is a suspicion this material directly reduces fertility.
Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-term occupational exposure.
Repeated or prolonged exposure to acids may result in the erosion of teeth, swelling and/or ulceration of mouth lining.

TOXICITY IRRITATION
Pickling Gel CT-501 NB
Not Available Not Available

TOXICITY IRRITATION
[1] Eye (rabbit): 100mg/24h - moderate
Dermal (rabbit) LD50: 1141 mg/kg

acrylamide Oral (rat) LD50: 124 mg/kgd[2] Eye (rabbit): 10mg/30s rinse-mild

Skin (rabbit): 50 mg/3d - mild


Skin (rabbit): 500 mg/24h - mild

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TOXICITY IRRITATION
[2] * DuPont
nitric acid Inhalation (rat) LC50: 0.13 mg/L/4h

Inhalation (rat) LC50: 2500 ppm/1h *t[2] Nil reported

TOXICITY IRRITATION

Inhalation (mouse) LC50: 6.2 mg/L/15M[2] Eye (rabbit): 122 mg - SEVERE


formic acid
Inhalation (rat) LC50: 15 mg/L/15mE[2] Skin (rabbit): 610 (open) - mild
[1]
Oral (rat) LD50: 730 mg/kg

TOXICITY IRRITATION

hydrofluoric acid Inhalation (rat) LC50: 1.1 mg/L/60M[2] Eye (human): 50 mg - SEVERE

Inhalation (rat) LC50: 1276 ppm/1h[2]

TOXICITY IRRITATION
p-tert-octylphenol
Oral (rat) LD50: 1800 mg/kgd[2] Eye (rabbit): 1 mg - moderate
ethoxylate
Skin (human): 2 mg/3d -I - mild

TOXICITY IRRITATION

Dermal (rabbit) LD50: 1664.3 mg/kg [1] Eye (rabbit):0.75 mg(open)-SEVERE


dimethylethanolamine
Inhalation (rat) LC50: 1641 ppm/4hE[2] Skin (rabbit): 445 mg(open)-mild

Oral (rat) LD50: 1210.4 mg/kg [1]

Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise specified data
extracted from RTECS - Register of Toxic Effect of chemical Substances

The following information refers to contact allergens as a group and may not be specific to this product.
The material may produce moderate eye irritation leading to inflammation.
The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of vesicles,
scaling and thickening of the skin.
ACRYLAMIDE
WARNING: This substance has been classified by the IARC as Group 2A: Probably Carcinogenic to Humans.
Tenth Annual Report on Carcinogens: Substance anticipated to be Carcinogen
[National Toxicology Program: U.S. Dep.

Asthma-like symptoms may continue for months or even years after exposure to the material ceases.
for acid mists, aerosols, vapours
Data from assays for genotoxic activity in vitro suggest that eukaryotic cells are susceptible to genetic damage when the pH falls to about 6.5.
NITRIC ACID The material may produce severe irritation to the eye causing pronounced inflammation.
The material may produce respiratory tract irritation, and result in damage to the lung including reduced lung function.
The material may cause severe skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of
vesicles, scaling and thickening of the skin.
Oral (?) LD50: 50-500 mg/kg * [Various Manufacturers]

Asthma-like symptoms may continue for months or even years after exposure to the material ceases.
No significant acute toxicological data identified in literature search.
for acid mists, aerosols, vapours
FORMIC ACID
Data from assays for genotoxic activity in vitro suggest that eukaryotic cells are susceptible to genetic damage when the pH falls to about 6.5.
The material may produce severe irritation to the eye causing pronounced inflammation.
The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of vesicles,
scaling and thickening of the skin.
No significant acute toxicological data identified in literature search.
The material may produce severe irritation to the eye causing pronounced inflammation.
HYDROFLUORIC ACID
Asthma-like symptoms may continue for months or even years after exposure to the material ceases.
The material may produce respiratory tract irritation, and result in damage to the lung including reduced lung function.
(liver and kidney damage) [Manufacturer] for hydrogen fluoride (as vapour)
Octoxynols:
Octoxynols of various chain lengths as well as octoxynol salts and organic acids function in cosmetics either as surfactants-emulsifying agents, surfactants-
cleansing agents, surfactant-solubilizing agents, or surfactants-hydrotropes in a wide variety of cosmetic products at concentrations ranging from 0.0008% to
P-TERT-OCTYLPHENOL
25%, with most less than 5.0%.
ETHOXYLATE
Human beings have regular contact with alcohol ethoxylates through a variety of industrial and consumer products such as soaps, detergents, and other
cleaning products .
Both laboratory and animal testing has shown that there is no evidence for alcohol ethoxylates (AEs) causing genetic damage, mutations or cancer.

Asthma-like symptoms may continue for months or even years after exposure to the material ceases.
While it is difficult to generalise about the full range of potential health effects posed by exposure to the many different amine compounds, characterised by
those used in the manufacture of polyurethane and polyisocyanurate foams, it is agreed that overexposure to the majority of these materials may cause adverse
health effects.
DIMETHYLETHANOLAMINE
Lower doses of dimethylethanolamine (DMAE) produce a gradual increase in muscle tone and perhaps an increased frequency of convulsions in susceptible
individuals.
The material may produce severe irritation to the eye causing pronounced inflammation.
The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of vesicles,
scaling and thickening of the skin.

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Acute Toxicity Carcinogenicity


Skin Irritation/Corrosion Reproductivity
Serious Eye
STOT - Single Exposure
Damage/Irritation
Respiratory or Skin
STOT - Repeated Exposure
sensitisation
Mutagenicity Aspiration Hazard
Legend: Data available but does not fill the criteria for classification
Data required to make classification available
Data Not Available to make classification

SECTION 12 ECOLOGICAL INFORMATION

Toxicity
Ingredient Endpoint Test Duration (hr) Species Value Source
acrylamide NOEC 672 Crustacea =0.06mg/L 1
acrylamide BCF 72 Fish 0.71mg/L 4
acrylamide EC50 48 Crustacea 0.43mg/L 4
acrylamide LC50 96 Fish 100mg/L 4
acrylamide EC50 96 Fish 85mg/L 5
nitric acid NOEC 2160 Fish 97.8mg/L 2
nitric acid EC50 48 Crustacea 490mg/L 2
nitric acid EC50 96 Crustacea 39mg/L 2
formic acid EC50 48 Crustacea =34.2mg/L 1
formic acid EC20 96 Algae or other aquatic plants =12.6mg/L 1
formic acid EC50 96 Algae or other aquatic plants =25mg/L 1
formic acid LC50 96 Fish 46mg/L 1
formic acid NOEC 96 Fish 22mg/L 1
hydrofluoric acid LC50 96 Fish 51mg/L 2
hydrofluoric acid EC50 48 Crustacea 97mg/L 2
hydrofluoric acid EC50 96 Crustacea 10.5mg/L 2
hydrofluoric acid NOEC 504 Crustacea 3.7mg/L 2
hydrofluoric acid EC50 96 Algae or other aquatic plants 43mg/L 2
p-tert-octylphenol
EC50 384 Crustacea 0.089mg/L 3
ethoxylate
p-tert-octylphenol
EC50 96 Algae or other aquatic plants 0.366mg/L 3
ethoxylate
p-tert-octylphenol
LC50 96 Fish 0.347mg/L 3
ethoxylate
p-tert-octylphenol
BCFD 336 Algae or other aquatic plants 0.1mg/L 4
ethoxylate
dimethylethanolamine EC50 48 Crustacea =98.37mg/L 1
dimethylethanolamine EC20 72 Algae or other aquatic plants 18mg/L 1
dimethylethanolamine EC50 72 Algae or other aquatic plants 35mg/L 1
dimethylethanolamine LC50 96 Fish 88-131mg/L 1
dimethylethanolamine NOEC 96 Fish 100mg/L 2
Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 3. EPIWIN Suite V3.12 -
Legend: Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) -
Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data

Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Do NOT allow product to come in contact with surface waters or to intertidal areas below the mean high water mark.
Prevent, by any means available, spillage from entering drains or water courses.
DO NOT discharge into sewer or waterways.

Persistence and degradability


Ingredient Persistence: Water/Soil Persistence: Air
acrylamide LOW LOW
formic acid LOW (Half-life = 14 days) LOW (Half-life = 55.46 days)
p-tert-octylphenol ethoxylate HIGH HIGH
dimethylethanolamine LOW LOW

Bioaccumulative potential
Ingredient Bioaccumulation
acrylamide LOW (BCF = 1.65)

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Pickling Gel CT-501 NB

formic acid LOW (BCF = 0.22)


p-tert-octylphenol ethoxylate HIGH (LogKOW = 4.863)
dimethylethanolamine LOW (LogKOW = -0.9351)

Mobility in soil
Ingredient Mobility
acrylamide LOW (KOC = 10.46)
formic acid HIGH (KOC = 1)
p-tert-octylphenol ethoxylate LOW (KOC = 699.2)
dimethylethanolamine HIGH (KOC = 1.602)

SECTION 13 DISPOSAL CONSIDERATIONS

Waste treatment methods


Containers may still present a chemical hazard/ danger when empty.
Product / Packaging
DO NOT allow wash water from cleaning or process equipment to enter drains.
disposal
Recycle wherever possible.

SECTION 14 TRANSPORT INFORMATION

Labels Required

Marine Pollutant NO

Land transport (UN)


UN number 2922
Packing group III
UN proper shipping name CORROSIVE LIQUID, TOXIC, N.O.S. (contains acrylamide,nitric acid and hydrofluoric acid)
Environmental hazard Not Applicable

Class 8
Transport hazard class(es)
Subrisk 6.1

Special provisions 223; 274


Special precautions for user
Limited quantity 5L

Air transport (ICAO-IATA / DGR)


UN number 2922
Packing group III
UN proper shipping name Corrosive liquid, toxic, n.o.s. * (contains acrylamide,nitric acid and hydrofluoric acid)
Environmental hazard Not Applicable

ICAO/IATA Class 8
Transport hazard class(es) ICAO / IATA Subrisk 6.1
ERG Code 8P

Special provisions A3A803


Cargo Only Packing Instructions 856
Cargo Only Maximum Qty / Pack 60 L
Special precautions for user Passenger and Cargo Packing Instructions 852
Passenger and Cargo Maximum Qty / Pack 5L
Passenger and Cargo Limited Quantity Packing Instructions Y841
Passenger and Cargo Limited Maximum Qty / Pack 1L

Sea transport (IMDG-Code / GGVSee)


UN number 2922
Packing group III
UN proper shipping name CORROSIVE LIQUID, TOXIC, N.O.S. (contains acrylamide,nitric acid and hydrofluoric acid)
Environmental hazard Not Applicable

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Chemwatch: 62-3982 Page 9 of 9 Issue Date: 22/03/2016
Version No: 3.1.1.1 Print Date: 23/03/2016
Pickling Gel CT-501 NB

IMDG Class 8
Transport hazard class(es)
IMDG Subrisk 6.1

EMS Number F-A, S-B


Special precautions for user Special provisions 223 274
Limited Quantities 5L

Transport in bulk according to Annex II of MARPOL and the IBC code


Not Applicable

SECTION 15 REGULATORY INFORMATION

Safety, health and environmental regulations / legislation specific for the substance or mixture

ACRYLAMIDE(79-06-1) IS FOUND ON THE FOLLOWING REGULATORY LISTS


International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Peru Occupational Exposure Limits
Monographs

NITRIC ACID(7697-37-2) IS FOUND ON THE FOLLOWING REGULATORY LISTS


International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Peru Occupational Exposure Limits
Monographs
International Air Transport Association (IATA) Dangerous Goods Regulations - Prohibited List
Passenger and Cargo Aircraft

FORMIC ACID(64-18-6) IS FOUND ON THE FOLLOWING REGULATORY LISTS


International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Peru Occupational Exposure Limits
Monographs

HYDROFLUORIC ACID(7664-39-3) IS FOUND ON THE FOLLOWING REGULATORY LISTS


International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Peru Occupational Exposure Limits
Monographs

P-TERT-OCTYLPHENOL ETHOXYLATE(9002-93-1) IS FOUND ON THE FOLLOWING REGULATORY LISTS


Not Applicable

DIMETHYLETHANOLAMINE(108-01-0) IS FOUND ON THE FOLLOWING REGULATORY LISTS


Not Applicable

National Inventory Status


Australia - AICS Y
Canada - DSL Y
Canada - NDSL N (acrylamide; p-tert-octylphenol ethoxylate; formic acid; hydrofluoric acid; nitric acid; dimethylethanolamine)
China - IECSC Y
Europe - EINEC / ELINCS /
N (p-tert-octylphenol ethoxylate)
NLP
Japan - ENCS Y
Korea - KECI Y
New Zealand - NZIoC Y
Philippines - PICCS Y
USA - TSCA Y
Y = All ingredients are on the inventory
Legend:
N = Not determined or one or more ingredients are not on the inventory and are not exempt from listing(see specific ingredients in brackets)

SECTION 16 OTHER INFORMATION

Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using
available literature references.

The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment.

This document is copyright.

end of SDS