UBND HUYN PH LNG K THI CHN HC SINH GII LP 9

NM HC 2016 - 2017
PHNG GIO DC V O TO
Mn: Ha hc

Thi gian lm bi: 150 pht (khng k thi gian giao )

Cu 1(2): a. Hon thnh s chuyn ha vit phng trnh ha hc minh ha,

ghi r iu kin nu c.
B D
A C E 3
F

3
Z
P Q R 3
X Y

b. Nu th d 2 mui (to bi 2 kim loi khc nhau v 2 gc axit khc nhau) va

c kh nng phn ng vi axit va c kh nng phn ng vi kim. Vit PTHH
minh ha.

Cu 2(2): a. Nhn bit cc dung dch sau ch bng qu tm: Na2SO4, NaOH,
BaCl2, HCl, AgNO3 MgCl2 . Vit tt c cc PTHH xy ra.

b. Nu phng php tch hn hp sau thnh cc cht nguyn cht. Hn hp 3 kh

: CO2, SO2 , CO.

Cu 3(2): Ha tan hon ton mt lng oxit kim loi ha tr II vo mt lng

va dung dch H2SO4 a% to thnh dung dch mui sunphat c nng b%.

a. Xc nh khi lng mol ca kim loi theo a v b.

b. Cho a% = 10% v b% = 11,76%. Hy xc nh oxit kim loi.

Cu 4(2): t hon ton m gam cht A cn dng ht 5,824 lit oxi (ktc). Sn
phm c CO2 v H2O c chia i. Phn 1 cho i qua P2O5 thy lng P2O5 tng
1,8 gam. Phn 2 cho i qua dung dch CaO thy lng CaO tng 5,32 gam. Tm
m v cng thc n gin ca A. Tm cng thc phn t ca A bit A th kh (
iu kin thng) c s C 4.

Cu 5(2): Hn hp X gm Na, Ba, Na2O, BaO. Ha tan hon ton 21,9 gam X
vo nc , thu c 1,12 lit H2 (ktc) v dung dch Y, trong c 20,52 gam
Ba(OH)2 v m gam NaOH. Tnh m ?

--------------------------Ht----------------------

H v tn th sinh: S bo danh: ..
 HNG DN CHM MN HA HC LP 9
NM HC 2016 - 2017
Cu 1(2) Mi phng trnh ng c 0,2

a. S bin ha c th l:

CaO Ca(OH)2 CaCl2 3

CO2 K2CO3 KHCO3 3

Cc phng trnh phn ng:

CaCO3 CaO + CO2

0
t

CaO + CO2 Ca(OH)2

Ca(OH)2 + 2HCl CaCl2 + 2H2O

CaCl2 + Na2CO3 CaCO3 + 2NaCl
CO2 + 2KOH K2CO3 + H2O
K2CO3 + CO2 + H2O 2 KHCO3
2KHCO3 + Ca(OH)2 CaCO3 + K2CO3 + 2H2O

Ghi ch: c th i v tr gia K2CO3 v KHCO3 khi :

CO2 + KOH KHCO3
KOH + KHCO3 K2CO3 + H2O
b, NaHCO3 + HCl NaCl + H2O + CO2

NaHCO3 + NaOH Na2CO3 + H2O

KHSO3 + HCl KCl + H2O + SO2

2KHSO3 + 2NaOH K2SO3+ Na2SO3 + 2 H2O

Cu 2( 2): Mi ng c 1

a.Dung dch HCl lm qu tm chuyn sang mu .

Dung dch NaOH lm qu tm xanh (nhm A)
4 dung dch Na2SO4, BaCl2, MgCl2 , AgNO3 khng i mu qu tm ( nhm B)
- Dng HCl nhn ra AgNO3 nhm B kt ta trng,
- AgNO3 + HCl AgCl + HNO3
Dng NaOH nhn ra MgCl2 nhm B c kt ta trng
2NaOH + MgCl2 Mg(OH)2 + 2NaCl
- Dng AgNO3 nhn ra BaCl2 nhm B kt ta
2AgNO3 + BaCl2 2AgCl + Ba(NO3)2
Cn li l Na2SO4 (B).
b. Cho hn hp i qua nc Br2 v thu kh CO, CO2 khng phn ng
SO2 + 2H2O + Br2 H2SO4 + 2HBr
C c dung dch v cho lu hunh vo H2SO4 c, nng
2H2SO4 + S 3SO2 + 2H2O
Hn hp CO2, CO i qua dung dch kim v thu ly CO khng phn ng:
CO2 + 2KOH K2CO3 + H2O
Thm H2SO4 iu ch CO2 :
H2SO4 + K2CO3 K2SO4 + CO2 + H2O
Cu 3( 2)

MO + H2SO4 MSO4 + H2O

(M + 16)g 98g (M + 96)g

Tnh khi lng dd H2SO4 cn dng:

Mun c a (g) H2SO4 phi ly 100g dd
9800
98g H2SO4 x (g) dd x= .
a
( M 96).100
Theo cng thc tnh C% ta c: C% = =b
( M 16) 9800 / a
 16ab 100.(98b 96a)
Rt ra: M=
a(100 b)
b) p s : M = 24 Mg ; Oxit l MgO.
Cu 4(2):
P2O5 hp th H2O theo phng trnh
P2O5 + 3H2O 2H3PO4
Cn CaO hp th c CO2 v H2O:
CaO + H2O Ca(OH)2
CaO + CO2 CaCO3

mH O = 1,8.2 = 3,6 gam cn

2

mCO 2 = (5,32 1,8) .2 = 3,52. 2 =7,04 gam

nO phn ng = 5,824
2
22, 4
= 0,26mol nO = 0,52 mol

t mH2O = 3,6 gam nH O = 0,2mol

2 nH = 0,4 mol; nO= 0,2 mol
mCO =7,04 gam nCO
2 2 =0,16 nC = 0,16 mol; nO = 0,32 mol
noxi trong A = noxi trong CO + noxi trong H O noxi phn ng.
2 2

= 0,32 + 0,2 - 0,52 = 0

Vy hp cht A khng c oxi . t cng thc ca A l CxHy (x, y nguyn
dng).

Lp t l x: y = nC : nH = 0,16 : 0,4 = 2:5

Cng thc n gin ca A l (C2H5)n
m s nguyn t C 4 vy cng thc ca A l C4H10.
Cu 5(2):
PTHH:
2Na + 2H2O 2NaOH + H2
Ba + 2H2O Ba(OH)2 + H2
BaO + H2O Ba(OH)2
Na2O + H2O 2NaOH
Nu t n th PTHH c 4 n v 3 d kin nn ta gii da vo nh lut bo ton
khi lng v bo ton nguyn t
X + H2O Y Ba(OH) 2 , NaOH + H2
21,9g xmol 20,52g(0,12 mol ) mg(amol) 0,05 mol
- Bo ton H ta c:
2.x = 2.0,12 + a + 2.0,05 (1)
- Bo ton khi lng:
21,9 + 18.x = 20,52 + 40.a + 0,05 .2 (2)
T 1v 2 ta c: x = 0,24 ; a = 0,14
Vy m= 0,14 . 40 = 5,6( gam)
Ch : hoc sinh c cch gii khc vn cho im ti a.