Advanced Pattern Cumulative Test-3 (Act-3) : Paper-2

Code
P16-16
0
ADVANCED PATTERN CUMULATIVE TEST-3 (ACT-3)
TARGET : JEE (MAIN+ADVANCED) 2017
PAPER-2 COURSE : VIJAY (01JR)
Date : 18-12-2016 Time: 3 Hours Maximum Marks : 240

Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
GENERAL %
1. The sealed booklet is your Question Paper. Do not break the seal till you are instructed to do so.
2. The question paper CODE is printed on the right hand top corner of this sheet.
3. Use the Optical Response Sheet (ORS) provided separately for answering the question.
4. Blank spaces are provided within this booklet for rough work.
5. Write your Name and Roll Number in the space provided on the below cover.
DO NOT BREAK THE SEALS WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR

6. After the open booklet, verify that the booklet contains all the 60 questions along with the options are legible.
QUESTION PAPER FORMAT AND MARKING SCHEME :

7. The question paper has three parts : Mathematics, Physics and Chemistry. Each part has three sections.
8. Each section as detailed in the following table :
Category-wise Marks for Each Question Maximum
Number of
Section Question Type Marks of the
Questions Negative
Full Marks Partial Marks Zero Marks Section
Marks
+4
0
If only the bubble 2
If none of
1 Single Correct Option 6 corresponding to the In all other 24
the bubbles
correct option is cases
is darkened
darkened
+4 +1
0
If only the bubble(s) For darkening a bubble 2
One or More Correct If none of
2 10 corresponding to all corresponding to each correct In all other 40
Option(s) the bubbles
the correct option(s) option, provided NO incorrect cases
is darkened
is(are) darkened option is darkened
+4 +1
0
Comprehension If only the bubble(s) For darkening a bubble 2
If none of
3 (One or More Correct 4 corresponding to all corresponding to each correct In all other 16
the bubbles
Option(s)) the correct option(s) option, provided NO incorrect cases
is darkened
is(are) darkened option is darkened
OPTICAL RESPONSE SHEET :

9. Darken the appropriate bubbles on the original by applying sufficient pressure.
10. The original is machine-gradable and will be collected by the invigilator at the end of the examination.
11. Do not tamper with or mutilate the ORS.
12. Write your name, roll number and the name of the examination centre and sign with pen in the space provided for this purpose on the
original. Do not write any of these details anywhere else. Darken the appropriate bubble under each digit of your roll number.
DARKENING THE BUBBLES ON THE ORS :

13. Use a BLACK BALL POINT to darken the bubbles in the upper sheet.
14. Darken the bubble COMPLETELY.
15. Darken the bubble ONLY if you are sure of the answer.
16. The correct way of darkening a bubble is as shown here :
17. There is NO way to erase or "un-darkened bubble.
18. The marking scheme given at the beginning of each section gives details of how darkened and not darkened bubbles are evaluated.
NAME OF THE CANDIDATE : ..

ROLL NO. : ..
I have read all the instructions I have verified the identity, name and roll number
and shall abide by them of the candidate.
------------------------- -------------------------
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MATHEMATICS
PART : I MATHEMATICS
MATHEMATICS
SECTION 1 : (Maximum Marks : 24)
This section contains SIX questions
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option is correct
For each question, darken the bubble corresponding to the correct option in the ORS
Marking scheme :
+4 If only the bubble corresponding to the correct option is darkened
0 If none of the bubble is darkened
2 In all other cases
1. If [ . ] denotes the greatest integer less than or equal to x and ( . ) denotes the least integer greater
than or equal to x, then domain of the function f(x) = sin1{x +[x]+(x)} is
(A) x {0} (B) x [0, 1) (C) x (1, 0] (D) x
2. Let PQ be the common tangent to circles x2 + y2 6x = 0 and x2 + y2 + 2x = 0 as shown in figure,

then find the area of the shaded region PQR.
11 11
(A) 3 3 (B) 4 3 (C) 4 3 (D) 3 3
3 6 3 6
Space for Rough Work
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P2JRACT3181216C0-1
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MATHEMATICS
x cos 1
3. (x2 2x cos 1)3 / 2 dx is
MATHEMATICS
1
(A) x cos 1 C (B) C
x 2x cos 1
2
x
(C) C (D) x 2 2x cos 1 C
x 2x cos 1
2
4. Six X's are to be placed in boxes of the figure such that each row contains at least one 'X'. In how
many different ways can this be done ?
(A) 28 (B) 27 (C) 26 (D) 29
dy x(x 2 3y 2 )
5. The solution of the differential equation, 0 is
dx y(y 2 3x 2 )
(A) x4 + y4 + x2y2 = c (B) x4 + y4 + 3x2y2 = c
(C) x4 + y4 + 6x2y2 = c (D) x4 + y4 + 9x2y2 = c
6. Two tangents are drawn from any point P on a given line L = 0 to a given circle S = 0. If these
tangents touch the circle at points A and B, then locus of the circumcentre the PAB will be
(A) A pair of straight lines (B) A circle touching the given line L= 0.
(C) A circle touching the given circle S= 0. (D) A line parallel the given line L= 0.
P2JRACT3181216C0-2
MATHEMATICS
MATHEMATICS
This section contains TEN questions
Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is(are) correct
For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
For each question, marks will be awarded in one of the following categories :
Full Marks : +4 If only the bubble(s) corresponding to all the correct option(s) is(are)
darkened.
Partial Marks : +1 For darkening a bubble corresponding to each correct option, provided
NO incorrect option is darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : 2 In all other cases.
For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three
will result in +4 marks ; darkening only (A) and (D) will result in +2 marks and darkening (A) and
(B) will result in 2 marks, as a wrong option is also darkened.
7. If quadratic equation f(x) = x2 + ax + 1 = 0 has two positive distinct roots, then

(A) f(1) > 0 (B) f(1) < 0 (C) f(0) f(0) = 2 (D) f(0) < 2
8. Which of the following are True? (where [ . ] denotes greatest integer function)
7 7
(A) If f(x) = [x], g(x) = |x 1|, then the value of fog + gof is equal to 5
4 4
(B) The number of solution of equation |[x] 1| = x2 is 2.
(C) If f2(x) = x2, then number of different possible continuous functions f(x) is 4
(D) If a polynomial function is invertible, then its inverse function is always differentiable
P2JRACT3181216C0-3
MATHEMATICS

9. If tan1 (x2 + 3 |x| 4) + cot1(4 + sin1 sin14) = , then the value of sin1 (sin2x) can be equal to
MATHEMATICS
2
(A) 6 2 (B) 2 6 (C) 3 (D) 3
10. Consider a family of circles passing through two fixed points A(3, 7) and B(6, 5). If the common
chords of the circle x2 + y2 4x 6y 3 = 0 and the members of the family of circles pass
through a fixed point (a, b), then
(A) a + 3b = 25 (B) 3b a = 21 (C) 3a + b = 25 (D) 3a b = 21
11. There are 12 points in a plane of which 5 are collinear. Except these five points no three are collinear, then
(A) the number of quadrilaterals one can form using these points is 420
(B) the number of triangles one can form using these points is 210
(C) the number of lines one can form using these points is 57
(D) the number of lines one can form using these points is 56
P2JRACT3181216C0-4
MATHEMATICS
12. For a Function f : A B such that n(A) a, n(B) b (a,bN) then which of the following
MATHEMATICS
statements must be CORRECT ?
(A) If function is one - one, onto, then a > b
(B) If function is one - one, into, then a < b
(C) If function is many - one, onto, then a > b
(D) If function is many - one, into, then a < b
13. If 3 x 5 y (75)z then z =
y x2 y2
(A) (B)
2 log5 3 2x y
x xy
(C) (D)
2log3 5 1 2x y
2[x]
14. If f(x) = cos1 sgn , where sgn ( ) denotes the signum function and [ . ] denotes the
3x [x]
greatest integer function, then which of the following is/are CORRECT ?
(A) lim f(x) = 0 (B) lim f(x) = 0
x 1 x 1
(C) f(x) is derivable at x = 1 (D) f(x) is derivable at x = 1
P2JRACT3181216C0-5
MATHEMATICS
15. A normal is drawn at a point P(x, y) of a curve. It meets the x-axis and y-axis at points A and B
MATHEMATICS
2 3
respectively such that + = 1, O being origin. Equation of such curve passing through
OA OB
point (1, 1) can be
2 2 2 2
(A) x + y 4x 6y + 8 = 0 (B) x + y 2x 3y + 3 = 0
2 2 2 2
(C) 2x + 2y x y 2 = 0 (D) x + y 4x + 6y 4 = 0
16. A straight line through the point A ( 2, 3) cuts the line x + 3y = 9 and x + y + 1 = 0 at B and C
respectively. If AB. AC = 20 then equation of the possible line is
(A) x y = 1 (B) x y + 1 = 0
(C) 3x y + 3 = 0 (D) 3x y = 3
P2JRACT3181216C0-6
MATHEMATICS
MATHEMATICS
This section contains TWO paragraphs
Based on each paragraph, there will be TWO questions.
darkened.
Paragraph for Question Nos. 17 to 18
16 players P1, P2, P3,.......P16 take part in a tennis tournament. Lower suffix player is better than
any higher suffix player. These players are to be divided into 4 groups each comprising of 4
players and the best from each group is selected for semifinals.
17. Number of ways in which they can be divided into 4 equal groups if the players P1, P2, P3 and P4
are in different groups, is :
(11)! (12)! (12)! (11)!
(A) (B) (C) (D)
216 (3!)4 (3!)4 (4!) (3!)4
18. Number of ways in which these 16 players can be divided into four equal groups, such that when
12!
the best player is selected from each group, P6 is one among them, is (k) . The value of k is :
(4!)3
(A) 36 (B) 24 (C) 18 (D) 20
P2JRACT3181216C0-7
MATHEMATICS
MATHEMATICS
1
ex
Let A =
0
x 1
dx then answer the following questions in terms of A.
1
x 2ex
19.
0
x 1
dx equals
(A) A e (B) e 2 + A (C) 2 + A (D) 2 e + A
1 2
x x
20.
0
x 1 e dx equals

e e e e
(A) A (B) +1A (C) A (D) A 1 +
2 2 2 2
P2JRACT3181216C0-8
PHYSICS
PART - II : PHYSICS
PHYSICS
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option is
correct
Marking scheme :
21. A person throws a ball in vertical plane such that velocity of ball along horizontal is vx and along
vertical is vy. Coefficient of friction between man and ground is . Necessary condition so that man
always remains at rest will be (Note : The process is done in time t 0)
(A) vx > vy (B) v x v y (C) v y v x (D) v x v y

22. Two particles of masses m and 2m has initial velocity u1 2i 3j m/s and u2 4i 3j m/s

respectively. These particles have constant acceleration a1 4i 3j (m/s2) and a2 4i 2j (m/s2)
respectively. Path of the centre of mass of this two particle system will be :
(A) Straight line (B) Circular (C) Parabolic (D) Elliptical
23. A uniform disc of mass m and radius R is released gently on a horizontal rough surface. Such that
centre of the disc has velocity V0 towards right and angular velocity 0 (anti clockwise) as shown.

Disc will certainly come back to its initial position if
(A) 0R > 2V0 (B) 0R = 2V0 (C) 0R < 2V0 (D) It is impossible
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P2JRACT3181216C0-9
PHYSICS
24. A parallel plate capacitor of capacitance C is charged to a potential V and then disconnected with
PHYSICS
the battery. If separation between the plates is decreased by 50% and the space between the
plates is filled with a dielectric slab of dielectric constant K = 10. Then
(A) P.d. between the plates increases by 95%
(B) P.d. between the plates decreases by 50%
(C) P.d. between the plates increases by 50%.
(D) P.d. between the plates decreases by 95%
25. A small ball thrown at an initial velocity v0 at an angle to the horizontal strikes elastically with a
smooth vertical wall moving towards it at a horizontal velocity and returns to the point from which
it was thrown. Determine the time t from the beginning of motion to the moment of impact with
vertical wall. Neglect friction losses.
0 sin ( 0 cos 2 )
(A) t
g(v 0 cos )
0 sin ( 0 cos 2 )
(B) t
g(v 0 cos )
0 sin ( 0 cos 2 )
(C) t
g(v 0 cos )
0 cos ( 0 sin 2 )
(D) t
g(v 0 sin )
P2JRACT3181216C0-10
PHYSICS

26. A dipole of dipole moment p p i is kept at the centre of a circle of radius r as shown in the figure.
PHYSICS
The radius of the circle is very large in comparison to the distance between the two charges of the
dipole. A & B are two points on the axis and C & D are two points on the equitorial line of the
dipole. If VA, VB, VC and VD are potentials at A, B, C and D respectively then, which of the following
is correct?
B A
p
2kp kp
(A) VA - VB=0, VA - VD = (B) VA - VB=0, VA - VD =
r2 r2
2kp kp 2kp 2kp

(C) VA - VB= 2
, VA - VD = 2
(D) VA - VB= 2
, VA - VD =
r r r r2
P2JRACT3181216C0-11
PHYSICS
PHYSICS
darkened.
27. In each of three figures shown, two blocks are connected by a light spring and the system is
placed on smooth horizontal surface. A constant horizontal force of magnitude F is applied to left
block as shown. Assuming spring constant in all three cases to be same, which of the following
statements is/are true.
1 2 3
F F F
2m 2m 3m m m 3m
fig.-1 fig.-2 fig.-3

(A) maximum compression in spring 1 is greater than that in spring 2.
(B) maximum compression in spring 3 is greater than that in spring 1.
(C) maximum compression in spring 3 is greater than that in spring 2.
(D) maximum compression in all springs is equal.
P2JRACT3181216C0-12
PHYSICS
28. A ladder AB is supported by a smooth vertical wall and rough horizontal floor as shown. A boy
PHYSICS
starts moving from A to B slowly. The ladder remains at rest, then pick up the correct statement(s):
B
smooth
wall
A
///////////////////////////////
rough floor
(A) Magnitude of normal reaction by wall on ladder will increase.
(B) Magnitude of normal reaction by wall on ladder will decrease.
(C) Magnitude of normal reaction by floor on ladder will remain unchanged.
(D) Magnitude of friction force by floor on ladder at will increase.
29. A cylinder of mass M and radius R is resting on two corner edges A and B as shown in figure. The
normal reaction at the edges A and B are : (Neglect friction)
Mg 2 3Mg
(A) NA = 2NB (B) NB = 3NA (C) NA = (D) NB =
2 5
P2JRACT3181216C0-13
PHYSICS
30. Tension in a uniform string of length L varies with length uniformly. At one end A tension is T0 and
PHYSICS
at other end B it is 16 T0. If mass per unit length of string is . Choose the correct option(s).
2
(A) Time taken by a pulse to move from end A to end B is L
5 T0
2 L
(B) Time taken by a pulse to move from end A to end B is
15 T0
15 1
15T0
(C) Tension in the string as function of distance x from end A is T = T0 + x
L
16T0
(D) Tension in the string as function of distance x from end A is T = T0 + x
L
31. A person, standing on the roof of a 40 m high tower, throws a ball vertically upwards with speed
10 m/s. Two seconds later, he throws another ball again in vertical direction. (use g = 10 m/s2)
Both the balls hit the ground simultaneously.
(A) The first stone hits the ground after 4 seconds.
(B) The second ball was projected vertically downwards with speed 5 m/s.
(C) The distance travelled by the first ball is 10 m greater than the distance travelled by the second
ball.
(D) Both balls hit the ground with same velocities.
32. In the given circuit, in steady state we may say : (capacitors are initially uncharged)
(A) potential drop across the capacitor c1 is 4v (B) potential drop across 10 resistance 10 v
(C) charge on C1 and C2 is 20 C (D) ratio of charge on C1 and C2 is 1
P2JRACT3181216C0-14
PHYSICS
33. In the given circuit potential of the point A is 9V higher than potential of the point B. Choose
PHYSICS
correct alternative(s)
(A) Value of resistance R is 1

(B) Value of resistance R is 7
(C) magnitude of potential difference between B and D is 30 V.
(D) magnitude of potential difference between B and C is 15 V.
34. A block of mass 'm' rests on a fixed incline plane of inclination '' with horizontal. Assume friction is
large enough to make the block stationary. Then choose correct alternative(s).
(A) Maximum value of horizontal component of friction is mg
(B) Angle at which horizontal component of friction is maximum is /4
(C) Maximum value of horizontal component of friction is mg/2
(D) Angle at which horizontal component of friction is maximum is /3
35. A bob of mass m connected to the end of an inextensible string of length , is released from
position shown in figure. If impacts of bob with smooth floor is perfectly inelastic. Choose the
correct option(s).
/2
Floor

(A) The maximum height reached by the bob during subsequent motion is .
32
(B) Maximum height reached by the bob during subsequent motion is zero.
(C) Energy loss from the time duration bob is released to the time it reaches at its maximum height
3mg
during subsequent motion is .
8Space for Rough Work
(D) Energy loss from the time duration bob is released to the time it reaches at its maximum height
15mg
during subsequent motion is .
32
P2JRACT3181216C0-15
PHYSICS
36. A transverse sinusoidal wave of amplitude 2 mm is setup in a long uniform string. Snapshot of
PHYSICS
string from x = 0 to x = meter is taken at t = 0, which is shown. Velocity of point P is in
y direction. Magnitude of relative velocity of P with respect to Q is 2 cm/s. Choose the correct
options: wave equation is
(A) Displacement of particle at position P from its mean position as function of time is given by
Y= (2103) sin5t (m)

(B) wave equation is Y = (2 103) sin (5t + 2x + ) (m)
6
5
(C) wave equation is Y = (2 103) sin (5t + 2x + ) (m)
6

(D) wave equation is Y = (2 103) sin (5t 2x + ) (m)
6
P2JRACT3181216C0-16
PHYSICS
PHYSICS
darkened.
Paragraph for Questions 37 and 38

A point object is located at a distance 100 cm from the screen. A lens of focal length 23 cm
mounted on a movable frictionless stand is kept between the object and screen. The stand is
attached to massless spring of natural length 50 cm and spring constant 800 N/m as shown in the
figure. Mass of the stand with lens is 2 kg. Initially spring is in its natural length. Now a sharp
impulse J is given to the stand. Answer the following questions.

37. It is observed that a real image of the object S is formed on the screen after a fixed time gap
(four times in an oscillation). This time gap is :

(A) sec (B) sec (C) sec (D) sec
10 20 30 40
38. Choose the correct option(s):

(A) Impulse J imparted to the stand is 8 kg m/sec
(B) Impulse J imparted to the stand is 6 kg m/sec
(C) Difference between extreme positions of lens is 40 cm
(D) Difference between extreme positions of lens is 60 cm
P2JRACT3181216C0-17
PHYSICS
Paragraph for Questions 39 and 40
PHYSICS
A block A of mass m is given a velocity v0 towards another block B of same mass. B is attached to
an ideal spring of spring constant K. A makes a head on perfectly inelastic collision with B.
K v0
B A
m m
Smooth
Answer the following two questions:
39. Let the collision takes place at time t = 0, choose the time instant(s), when the spring is in its
natural length:
2m 2m m m
(A) (B) 2 (C) ( 2 +1) (D) 2
K K K K
40. Choose the correct option(s)
1 mv 02
(A) Maximum elongation in the spring during subsequent motion is .
2 K
mv 02
(B) Maximum elongation in the spring during subsequent motion is .
2K
v0
(C) Final velocity of block A is
2
v0
(D) Final velocity of block A is
4
P2JRACT3181216C0-18
CHEMISTRY
PART : III CHEMISTRY
Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,
CHEMISTRY
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75,
Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]

Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option is
correct
Marking scheme :
41. 0.2 mol A xBy

0.5 mol A 2 0.4 mol B3. From this data the molecular formula of AB
(A) AB2 (B) A2B3
(C) A4B5 (D) A5B6
42. Which of the following reaction is not an ion-exchange reaction ?

(A) Pb(NO3)2 + 2KI PbI2 + 2KNO3 (B) KNO2 + AgF AgNO2 + KF
(C) 2AgF + MgCl2 MgF2 + 2AgCl (D) CaSO3 (ppt) + SO2 + H2O Ca(HSO3)2
P2JRACT3181216C0-19
CHEMISTRY
43. For metal olefin complexes (i) [PtCl3 (C2H 4 )] and (ii) [PtCl3 (C2F4 )]- , the correct statement is/are
CHEMISTRY
that :
(A) carbon-carbon bond length is same both in (i) and (ii).
(B) carbon-carbon bond length in (i) is smaller than in (ii).
(C) carbon-carbon bond length in (i) is larger than in (ii).
(D) chelation takes place in both the complexes.
44. For reaction : NH3(liq.) + Na

warm
P + Q
Incorrect statement is :
(A) Hydrolysis of 'P' produces NH3 gas.
(B) Gas 'Q' reacts with heated alkali metals.
(C) Anionic part of 'P' is weaker base than NH3.
(D) Gas Q is also produced, when Li metal is heated with NH3 gas.
P2JRACT3181216C0-20
CHEMISTRY
CH3
CHEMISTRY
H
CH2
45. Product
(2eq)
Major product is :
(A) Ph
(B)
Ph
Ph
(C) (D)
Ph
46. Ph C C CH2 CH3 A, A is :
(A) (B)
(C) (D)
P2JRACT3181216C0-21
CHEMISTRY
CHEMISTRY
darkened.
P2JRACT3181216C0-22
CHEMISTRY
47. Consider the following structures (M : central metal).
Cl Cl
CHEMISTRY
H3N Cl
M M M en M en
H3N NH3
NH3 Cl
(IV)
(III)
en
en Cl en
en Cl Cl
Cl M
M M
M Cl Cl
Cl Cl en
en en en
(V) (VI) (VII) (VIII)
Choose the correct statement(s) :
(A) I and II are geometrical isomers (B) VI and VIII are identical structure
(C) IV and VIII are geometrical isomers (D) V and VII are optical isomers.
48. Which of the following gas/gases show Z 1 at all temperatures ?

(A) H2 (B) He
(C) CH4 (D) None of these
49. The incorrect statement(s) is/are -

(A) For coagulation of As2S3 sol, +ve ions are effective.
2+ +
(B) For coagulation of aluminium hydroxide sol Ba ions are more effective than Na
(C) Cellulose solution is an example of multimolecular colloid system
(D) Colloidal sol of metals such as gold, silver etc are prepared by Bredig's arc method.
P2JRACT3181216C0-23
CHEMISTRY
50. The wave functions of 3s and 3pz orbitals are given by
3/2
1/2
z 4zr 4 z2r 2 zr /3a
CHEMISTRY
1 1
3s 6 e 0
9 3 4 a0 a0 9 a02

1/2 3/2
1 3 z 2zr 2zr zr /3a0
3p 4 e cos
9 3 4 a0 3a0 3a0
From these we can conclude :

(A) Number of nodal surface for 3pz & 3s orbitals is equal.
(B) The angular nodal surface of 3pz orbital has the equation = /2.
(C) The radial nodal surfaces of 3s orbital and 3pz orbital are at equal distance from the nucleus.
(D) 3s electron have greater penetrating power into the nucleus in comparison to 3p electrons.
51. Which of the following is/are correct ?
(A) A B gives bonding molecular orbital.
+
(B) is bonding molecular orbital.
(C) The probability density of finding the electrons in bonding molecular orbital equal to
A2 B2 2 A B .
(D) Electron density increases between the nuclei of bonding M.O.
P2JRACT3181216C0-24
CHEMISTRY
52. Aniline, C6H5NH2 react with water according to the equation
C6H5NH2 aq H2O C6H5NH3 aq OH aq

CHEMISTRY
In a 0.180 M aqueous aniline solution the OH 8.80 10 6 M
The value of the base ionization constant Kb for C6H5NH2(aq) and the percent ionization of
C6H5NH2 in this solution are :
(A) 4.3 10 10 (B) 3.1 10 10
(C) 4.9 10 3 % (D) 2.4 10 3 %
53. Observe the following reaction I and II k1 k1, k2 k2 are rate constants. Select the correct
option(s).
(I) CH3 I
(II) CH3 CH CH3

|
I
(A) k1 > k1 (B) k1 > k2
(C) k2 > k2 (D) k2 > k1
P2JRACT3181216C0-25
CHEMISTRY
54. Which can not be the major product formed upon addition of 1 mole of HBr in the following
reactions is :
CHEMISTRY
HBr(1 mole)
Major product ?
(A) (B)
(C) (D)
55. Choose the correct option for major product :

18
OH

(A)
BH3 THF
18
(B)
H3 O
OH
H2 O2 / O H
O
NBS / h
(C) Br (D) CH3CCH CH3CCHBr2
HOBr
P2JRACT3181216C0-26
CHEMISTRY
56. Which of the following is/are meso compound :
CHEMISTRY
(A)
(B)
(C)
(D)
P2JRACT3181216C0-27
CHEMISTRY
CHEMISTRY
darkened.
The reaction A(g) B(g) + 2C(g) is a first order reaction with rate constant 2.772 10
3 1
sec .
Reaction is started with only 0.1 mol of A in a container with volume 2 litre and is allowed to take
1 1
place at constant volume and at constant temperature 300 K. [R = 0.082 litre atm mol K ]
(log 2 = 0.30)
P2JRACT3181216C0-28
CHEMISTRY
57. Concentration of A after 250 sec will be :
(A) 0.125 M (B) 0.0125 M
CHEMISTRY
(C) 0.05 M (D) 0.025 M
58. Select the correct statement(s) :
(A) Concentration of C after 250 sec will be 0.05 M
(B) Concentration of C after 250 sec will be 0.1 M
(C) Partial pressure of C after 250 sec will be 2.46 atm
(D) Partial pressure of C after 250 sec will be 1.23 atm
Grignard reagents are -bonded organometallic compounds. There exists covalent bond
between carbon and Magnesium atoms. Grignard reagent finds applications in the Synthesis of
variety of compounds. Grignard reagent reacts as carbanion and the reaction of carbanion
with the proton of an acid is acid base reaction. Cabonyl compounds (including ester) on
interaction with Grignard reagent generates alkoxide ion and thus can be converted into
alcohols. Grignard reagent reacts with almost all functional groups. Notable exceptions are
tertiary amines aliphatic and aromatic C=C bonds.
P2JRACT3181216C0-29
CHEMISTRY
59. Which of the following combination of reactants can be used to prepare the following given
compound?
CHEMISTRY
OH
CH3 CH3
Ph
(1)CH3 MgBr excess (1)PhMgBr excess
(A) PhCOCH3 (B) PhCCH3
(2)H2O,H (2)H2O,H
O O
Ph
(1)PhMgBr excess (1)CH3 MgBr excess
(C) CH3CCl (D) CH3CO
(2)H O,H 2

(2)H2O,H
O O
60. Which of the following compounds gives benzene as a major product on reaction with PhMgBr
(1eq.).
O
(A) (B) CH3CCH

O
O
(C) (D)
P2JRACT3181216C0-30

Advanced Pattern Cumulative Test-3 (Act-3) : Paper-2

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Date : 18-12-2016 Time: 3 Hours Maximum Marks : 240

DO NOT BREAK THE SEALS WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR

QUESTION PAPER FORMAT AND MARKING SCHEME :

OPTICAL RESPONSE SHEET :

DARKENING THE BUBBLES ON THE ORS :

NAME OF THE CANDIDATE : ..

Resonance Eduventures Ltd.

2. Let PQ be the common tangent to circles x2 + y2 6x = 0 and x2 + y2 + 2x = 0 as shown in figure,

Space for Rough Work

(A) 28 (B) 27 (C) 26 (D) 29

Space for Rough Work

SECTION 2 : (Maximum Marks : 40)

7. If quadratic equation f(x) = x2 + ax + 1 = 0 has two positive distinct roots, then

Space for Rough Work

(A) 6 2 (B) 2 6 (C) 3 (D) 3

through a fixed point (a, b), then

(A) a + 3b = 25 (B) 3b a = 21 (C) 3a + b = 25 (D) 3a b = 21

Space for Rough Work

13. If 3 x 5 y (75)z then z =

(C) f(x) is derivable at x = 1 (D) f(x) is derivable at x = 1

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point (1, 1) can be

respectively. If AB. AC = 20 then equation of the possible line is

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SECTION 3 : (Maximum Marks : 16)

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(A) A e (B) e 2 + A (C) 2 + A (D) 2 e + A

Space for Rough Work

Space for Rough Work

Space for Rough Work

Space for Rough Work

2kp kp 2kp 2kp

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Space for Rough Work

SECTION 2 : (Maximum Marks : 40)

fig.-1 fig.-2 fig.-3

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Space for Rough Work

Space for Rough Work

(A) Value of resistance R is 1

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options: wave equation is

Y= (2103) sin5t (m)

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SECTION 3 : (Maximum Marks : 16)

Paragraph for Questions 37 and 38

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38. Choose the correct option(s):

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Answer the following two questions:

40. Choose the correct option(s)

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SECTION 1 : (Maximum Marks : 24)

This section contains SIX questions

41. 0.2 mol A xBy

(C) A4B5 (D) A5B6

42. Which of the following reaction is not an ion-exchange reaction ?

Space for Rough Work

(A) carbon-carbon bond length is same both in (i) and (ii).

(B) carbon-carbon bond length in (i) is smaller than in (ii).

(C) carbon-carbon bond length in (i) is larger than in (ii).

(D) chelation takes place in both the complexes.