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ACADEMIC SESSION:2014-15
SUBJECT : CHEMISTRY
Time : 2 Hrs. Maximum Marks : 60
1. Blank papers, clip boards, log tables, slide rule, calculators, mobile or any other electronic
2. Write your Name in the space provided in the bottom of this booklet.
3. Each correct answer carries ‘+ 1’ mark and each wrong answer ‘–0.25’ marks.
4. In case of any dispute, the answer filled in the OMR sheet available with the institute shall be
final.
5. After completion submit the Question Paper back along with the Answer Sheet.
7. The number of electrons required to deposit 1 g atom of AI (at. wt. = 27) from a solution of AICI3 are:
(A) 1 N (B) 2 N (C) 3 N (D) 4 N
8. The number of coulombs required for the deposition of 107.87 g of silver is:
(A) 96500 (B) 48205 (C) 19300 (D) 10000
PCCP-FTP_CHEMISTRY_PAGE # 2
11. A gas behaves most like an ideal gas under conditions of :
(A) High pressure and low temperature (B) High temperature and high pressure
(C) Low pressure and high temperature (D) Low pressure and low temperature
14. For 1 mole of gas, the average kinetic energy is given as E. The urms of gas is :
1/ 2 1/ 2 1/ 2 1/ 2
2E 3E 2E 3E
(A) (B) (C) (D)
M M 3M 2M
15. Which of the following elements constitutes a major impurity in pig iron ?
(A) Carbon (B) Oxygen (C) Sulphur (D) Silicon
17. The equivalent weight of a divalent metal is 31.82. The weight of a single atom is :
(A) 32.77×6.02×1023 (B) 63.64×6.02×1023 (C) 63.64 (D) 63.64/6.02×1023
18. 0.5 g of a metal combined with 0.2 g of oxygen to form :
(A) 40 (B) 20 (C) 14 (D) 10
19. 2 moles of ethyl alcohol are present with 6 mole of water. The mole fraction of alcohol is :
(A) 0.5 (B) 0.75 (C) 0.15 (D) 0.25
20. Volume of 0.1 M NaOH needed for the neutralisation of 20 mL of 0.05 M oxalic acid is :
(A) 10 mL (B) 15 mL (C) 20 mL (D) 30 mL
21. In alkaline conditions KMnO4 reacts as, 2KMnO 4 2KOH 2K 2MnO 4 H2O O . There, its equiva-
lent weight is :
(A) 31.6 (B) 52.7 (C) 79.0 (D) 158.0
22. How many g of KCl would have to be dissovled in 60 g H2O to give 20% by weight of solution ? :
(A) 15 g (B) 1.5 g (C) 11.5 g (D) 31.5 g
PCCP-FTP_CHEMISTRY_PAGE # 3
23. Equal volumes of 0.1 M AgNO3 and 0.2 M NaCl are mixed. The concentration of NO3– ions in the mixture
will be :
(A) 0.1 M (B) 0.05 M (C) 0.2 M (D) 0.15 M
24. A certain radioactive isotope has a half life of 50 day. Fraction of the material left behind after 100 day will
be:
(A) 50% (B) 75% (C) 12.5% (D) 25%
25 The ore which is concentrated by wetting process is :
(A) an oxide ore (B) a sulphate ore (C) a carbonate ore (D) a sulphide ore
228 212
26. The number of - and -particles emitted in the unclear reaction 90 Th 83 Bi are:
(A) 4 and 1 (B) 3 and 7 (C) 8 and 1 (D) 4 and 7
27. In a nuclear fission caused by the impact of a single neutron, two neutrons are produced in one step. The
number of neutrons produced in nth step will be:
(A) 2n (B) n2 (C) 2n2 (D) 2n
28. Consider the following sequence of tests,
Mn+ + HCI white precipitate
water soluble
The metal ion (Mn+) would be:
(A) Hg2+ (B) Ag+ (C) Pb2+ (D) Sn2+
29. Mass number of a nuclide is 216. Its approximate radius in fermi units is:
(A) 6.0 (B) 7.0 (C) 8.0 (D) 7.8
30. When KMnO4 acts as an oxidising agent and ultimately forms MnO42–, MnO2, Mn2O3 and Mn2+, then the
number of electrons transferred in each case respectively
(A) 4, 3, 1, 5 (B) 1, 5, 3, 7 (C) 1, 3, 4, 5 (D) 3, 5, 7, 1
31. The colour of K2Cr2O7 changes from red-orange to lemon-yellow on treatmetn with KOH (aq) because of:
(A) Reduction of Cr (VI) to Cr (III)
(B) Formation of chromium hydroxide
(C) Conversion of dichromate into chromate ion
(D) Oxidation of potassium hydroxide to potassium peroxide
(A) NaBr + HCI NaCI + HBr (B) HBr + AgNO3 AgBr + HNO3
33. The compound that can work both as an oxidising and reducing agent is:
(A) KMnO4 (B) H2O2 (C) Fe2(SO4)3 (D) K2Cr2O7
PCCP-FTP_CHEMISTRY_PAGE # 4
34. For the redox reaction, MnO4– + C2O42– + H+ Mn2+ + CO2 + H2O The correct coefficients of the
reactants for the balanced reaction are:
MnO4– C2O42– H+
(A) 2 5 16
(B) 16 5 2
(C) 5 16 2
(D) 2 16 5
35. How many mole of electrons are involved in the reduction of one mole of MnO4 ion in alkaline medium to
MnO3– ?
(A) 2 (B) 1 (C) 3 (D) 4
h h h
(A) (B) Zero (C) (D) 2 . 2 .
4 2
39. Assuming the velocity be same, which sub-atomic particle possesses smallest de Broglie wavelength :
(A) An electron. (B) A proton. (C) An -particle. (D) All have same .
40. Three most occuring elements into the earth crust are :
(A) O, Si, Al (B) Si, O, Fe (C) Fe, Ca, Al (D) Si, O, N
PCCP-FTP_CHEMISTRY_PAGE # 5
43. The mass of an electron is m, its charge e and it is accelerated from rest through a potential difference
V. The kinetic energy of the electron in joules will be :
(A) V (B) eV (C) MeV (D) None of these.
46. The temperature at which vapour pressure of a solvent in its liquid and solid phase becomes same is
called:
(A) B.p. (B) F.p. (C) Krafft point (D) None of these
48. The relative lowering of vapour pressure is equal to the mole fraction of the non-volatile solute. This
statement was given by:
(A) Raoult (B) Henry (C) Joule (D) Dalton
PCCP-FTP_CHEMISTRY_PAGE # 6
53. The element having very high ionization enthalpy but zero electron gain enthalpy is :
(A) H (B) F (C) He (D) Be
54. An element has successive ionization enthalpies as 940 (first), 2080, 3090, 4140, 7030, 7870, 16000 and
19500 kJmol–1. To which group of the periodic table does this element belong?
(A) 14 (B) 15 (C) 16 (D) 17
58. Formation of Ni(CO)4 and subsequent its decompostion into Ni and CO makes basis of Mond’s process:
T1 T2
Ni + 4CO Ni(CO)4
Ni + 4CO , T1 and T2 are :
(A) 100ºC, 50ºC (B) 50ºC, 100ºC (C) 50ºC, 230ºC (D) 230ºC, 50ºC
60. Dimethyl glyoxime forms a square planar complex with Ni2+ . This complex should be :
(A) diamagnetic (B) paramagnetic having 1 unpaired electron
(C) paramagnetic having 2 unpaired electrons (D) ferromagnetic
ANSWER KEY
Ques. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans. B C A B A B C A D B C C A A A
Ques. 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Ans. C D B D C D A B D D A D C D C
Ques. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
Ans. C D B A A A A B C A C C B A B
Ques. 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Ans. B A A B B B D C C C B A C D A
PCCP-FTP_CHEMISTRY_PAGE # 7