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Fundamental Concepts
The last half of the twentieth century was a time in which tremendous advances in
science and technology revolutionized our entire way of life. Many new technolo-
gies were invented and developed in this time period from basic laboratory research
to widespread commercial application. Communication technology, genetic engi-
neering, personal computers, medical diagnostics and therapy, bioengineering, and
material sciences are just a few areas that were greatly affected.
Nuclear science and engineering is another technology that has been transformed
in less than fifty years from laboratory research into practical applications encoun-
tered in almost all aspects of our modern technological society. Nuclear power,
from the first experimental reactor built in 1942, has become an important source
of electrical power in many countries. Nuclear technology is widely used in medical
imaging, diagnostics and therapy. Agriculture and many other industries make wide
use of radioisotopes and other radiation sources. Finally, nuclear applications are
found in a wide range of research endeavors such as archaeology, biology, physics,
chemistry, cosmology and, of course, engineering.
The discipline of nuclear science and engineering is concerned with quantify-
ing how various types of radiation interact with matter and how these interactions
affect matter. In this book, we will describe sources of radiation, radiation inter-
actions, and the results of such interactions. As the word "nuclear" suggests, we
will address phenomena at a microscopic level, involving individual atoms and their
constituent nuclei and electrons. The radiation we are concerned with is generally
very penetrating and arises from physical processes at the atomic level.
However, before we begin our exploration of the atomic world, it is necessary to
introduce some basic fundamental atomic concepts, properties, nomenclature and
units used to quantify the phenomena we will encounter. Such is the purpose of
this introductory chapter.
Base SI units:
Physical quantity Unit name Symbol
length meter m
mass kilogram kg
time second s
electric current ampere A
thermodynamic temperature kelvin K
luminous intensity candela cd
quantity of substance mole mol
Supplementary Units:
Physical quantity Unit name Symbol
plane angle radian racl
solid angle steradian sr
Temporary Units:
Physical quantity Unit name Symbol Value in SI unit
length nautical mile 1852 m
velocity knot 1852/3600 rn s~[
length angstrom A 0.1 nm = ICT10 rn
area hectare ha 1 hm 2 = 104 m 2
pressure bar bar 0.1 MPa
pressure standard atmosphere atm 0.101325 MPa
area barn b 10~ 24 cm 2
radioactive activity curie Ci 3.7 x 10H) Bq
radiation exposure roentgen R 2.58 x 10~4 C kg"1
absorbed radiation dose gray Gy 1 J kg- 1
radiation dose equivalent sievert Sv
Source: NBS Special Publication 330, National Bureau of Standards, Washington, DC, 1977.
10 24
yotta Y Length in. 2.54 x 1CT2 ma
1021 zetta Z ft 3.048 x 10~ 1 ma
1018 exa E mile (int'l) 1.609344 X 103 m a
1015 peta P Area in 2 6.4516 x 10~4 m 2 a
1012 tera T ft 2 9.290304 X 10~2 m 2a
109 giga G acre 4.046873 X 103 m2
106 mega M square mile (int'l) 2.589988 X 106 m2
103 kilo k hectare 1 x 104 m 2
102 hecto h Volume oz (U.S. liquid) 2.957353 X 10~5 m3
101 deca da in3 1.638706 X 10~5 m3
1
lo-2 deci d gallon (U.S.) 3.785412 X 10~3 m3
io- centi c ft 3 2.831685 x 10~2 m3
10~3 milli m
Mass oz (avdp.) 2.834952 x 10~2 kg
10~6 micro M Ib 4.535924 X lO^ 1 kg
io-9 nano n
ton (short) 9.071 847 x 102 kg
10~12 pico P
io-15 femto f Force kgf 9.806650 N a
10-18 atto a lbf 4.448222 N
21
io-24 zepto z ton 8.896444 X 103 N
io- yocto y Pressure lbf/in 2 (psi) 6.894757 x 103 Pa
lb f /ft 2 4.788026 x 101 Pa
atm (standard) 1.013250 x 105 Paa
in. H 2 O (@ 4 °C) 2.49082 x 102 Pa
in. Hg (© 0 °C) 3.38639 x 103 Pa
mm Hg (@ 0 °C) 1.33322 x 102 Pa
bar 1 x 105 Paa
Energy eV 1.60219 x 10~19 J
cal 4.184 J a
Btu 1.054350 X 103 J
kWh 3.6 x 106 J a
MWd 8.64 x 1010 J a
"Exact converson factor.
Source: Standards for Metric Practice, ANSI/ASTM
E380-76, American National Standards Institute,
New York, 1976.
Grammar Comments
The speed of the electron is thus v = ^/2T/me ~ 5.93 x 105 m/s, fast by our
everyday experience but slow compared to the speed of light (c ~ 3 x 108 m/s).
together by yet other particles called gluons. Whether quarks arid gluons are them-
selves fundamental particles or are composites of even smaller entities is unknown.
Particles composed of different types of quarks are called baryons. The electron and
its other lepton kin (such as positrons, neutrinos, and muons) are still thought, by
current theory, to be indivisible entities.
However, in our study of nuclear science and engineering, we can viewr the elec-
tron, neutron and proton as fundamental indivisible particles, since the composite
nature of nucleons becomes apparent only under extreme conditions, such as those
encountered during the first minute after the creation of the universe (the "big
bang") or in high-energy particle accelerators. We will not deal with such gigantic
energies. Rather, the energy of radiation we consider is sufficient only to rearrange
or remove the electrons in an atom or the neutrons and protons in a nucleus.
However, atoms of the same element may have different numbers of neutrons in
the nucleus. Atoms of the same element, but with different numbers of neutrons,
are called isotopes. The symbol used to denote a particular isotope is
where X is the chemical symbol and A = Z + TV, which is called the mass number.
For example, two uranium isotopes, which will be discussed extensively later, are
2
g|U and 2 g2U. The use of both Z and X is redundant because one specifies the
other. Consequently, the subscript Z is often omitted, so that we may write, for
example, simply 235U and 238U.1
1
To avoid superscripts, which were hard to make on old-fashioned typewriters, the simpler form
U-235 and U-238 was often employed. However, with modern word processing, this form should
no longer be used.
where the summation is over all the isotopic species comprising the element. Ele-
mental atomic weights are listed in Appendix Tables A. 2 and A. 3.
Example 1.1: What is the atomic weight of boron? From Table A.4 we find
that naturally occurring boron consists of two stable isotopes 10B and n B with
isotopic abundances of 19.1 and 80.1 atom-percent, respectively. From Appendix
B the atomic weight of 10B and U B are found to be 10.012937 and 11.009306,
respectively. Then from Eq. (1.2) we find
AB = (7io-4io +7n./4ii)/100
Example 1.3: Estimate the mass on an atom of 238 U. From Eq. (1.3) we find
238 (g/mol)
= 3.952 x 10 g/atom.
6.022 x 1023 atoms/mol
To find the atom density Ni of isotope i of an element with atom density N simply
multiply N by the fractional isotopic abundance 7^/100 for the isotope, i.e., Ni —
Example 1.4: What is the hydrogen atom density in water? The molecular
weight of water AH Q = 1An + 2Ao — 2A# + AO = 18. The molecular density
of EbO is thus
/- -,
t • (1.6)
nAx + mAy
Finally, as a general rule of thumb, it should be remembered that atom densities
in solids and liquids are usually between 1021 and 1023 /cm~ 3 . Gases at standard
temperature and pressure are typically less by a factor of 1000.
Since the atomic radius of about 2 x 10~8 cm is 105 times greater than the
nuclear radius, the nucleus occupies only about 10~15 of the volume of a atom. If
an atom were to be scaled to the size of a large concert hall, then the nucleus would
be the size of a very small gnat!
Nuclear Density
Since the mass of a nucleon (neutron or proton) is much greater than the mass of
electrons in an atom (mn = 1837 m e ), the mass density of a nucleus is
m
nucleus A/Na 14 , 3
^nucleus = T7- = ~, \ r> ~ 2A X 1U
S/ cm '
^nucleus
This is the density of the earth if it were compressed to a ball 200 m in diameter.
These two sites have links to the some of the major nuclear and atomic data repos-
itories in the world.
http://www.nndc.bnl.gov/wallet/yellows.htm
http://www.nndc.bnl.gov/usndp/usndp-subject.html
The following sites have links to many sources of fundamental nuclear and atomic
data.
http://www.nndc.bnl.gov/
http://physics.nist.gov/cuu/index.htm
http://isotopes.Ibl.gov/isotopes/toi.html
http://wwwndc.tokai.jaeri.go.jp/index.html
http://wwwndc.tokai.j aeri.go.jp/nucldata/index.html
http://www.fysik.lu.se/nucleardata/toi_.htm
http://atom.kaeri.re.kr/
http://physics.nist.gov/
http://www.nist.gov/
http://www.energy.gov/
http://www.nrc.gov/
http://www.doe.gov/
http://www.epa.gov/oar/
http://www.nrpb.org.uk/
http://www-rsicc.ornl.gov/rsic.html
http://www.iaea.org/worldatom/
http://www.nea.fr/
PROBLEMS
1. Both the hertz and the curie have dimensions of s"1. Explain the difference
between these two units.
2. Explain the SI errors (if any) in and give the correct equivalent units for the
following units: (a) m-grams/pL, (b) megaohms/nm, (c) N-m/s/s, (d) gram
cm/(s~ 1 /mL). and (e) Bq/milli-Curie.
3. In vacuum, how far does light move in 1 ps?
4. In a medical test for a certain molecule, the concentration in the blood is
reported as 123 mcg/dL. What is the concentration in proper SI notation?
5. How many neutrons and protons are there in each of the following riuclides:
(a) 10B. (b) 24 Na, (c) 59Co, (d) 208 Pb. and (e) 235U?
6. What are the molecular weights of (a) H2 gas, (b) H 2 O, and (c) HDO?
7. What is the mass in kg of a molecule of uranyl sulfate UC^SCV/
8. Show by argument that the reciprocal of Avogadro's constant is the gram
equivalent of 1 atomic mass unit.
9. How many atoms of 234 U are there in 1 kg of natural uranium?
10. How many atoms of deuterium are there in 2 kg of water?
11. Estimate the number of atoms in a 3000 pound automobile. State any assump-
tions you make.
12. Dry air at normal temperature and pressure has a mass density of 0.0012 g/cm 3
with a mass fraction of oxygen of 0.23. WThat is the atom density (atom/cm 3 )
of 180?