Professional Documents
Culture Documents
(Communicated by R. Kondo)
(Rec. Sept. 22, 1975; in final form Oct. 13, 1975)
ABSTRACT
We have studied the relations between particle size dis-
tribution at equal specific surface area a n d compressive
strength in Portland cement. Starting from a series of
hypotheses, we have demonstrated that the volume of hy-
drated p r o d u c t , therefore the mechanical stTength ,
increases when t h e g r k n u l o m e t r i c range decreases.
The e x p e r i m e n t a l data have demonstTated that the depth
of hydration d e p e n d s m o s t l y on t h e p a r t i c l e size, con-
trary to our hypothesis. Nevertheless, we h a v e p r o v e d
that when with the actual plants of grinding it is
possible to minimize the width of granulometric range,
the mechanical strength of Portland cements both in
Riles mortar and in concrete can be maximized.
113
114 Vol. 6, No. 1
G. F r i g i o n e , S. Marra
Introduction
Theoretical Formulation
com~ressive strength.
V e r b e c k and F o s t e r (12) and B r u n a u e r (13) d e m o n s t r a t e d t h a t
a n o r m a l P o r t l a n d c e m e n t - t y p e I ASTM- g i v e s t h e same r e a c t i o n
products at all stages of its hydration, except for the reaction
of products of gypsum which finish after the first 24 hours at
Vol. 6, No. 1 115
PARTICLE SIZE DISTRIBUTION, STRENGTH, HYDRATED CEMENT
w h i c h can be rearranged:
conditions :
m 4 ~R'-- mr4 ~ R 3 + rr~24 ~TR: VIII
m4'~R'~= m'4~TR'= + m 2 4 ~ R 2 IX
and simplifying:
,-,-,R' = ,-n, R~ + ~, R~ Z
n~ = [,,~'";÷ ~,R:] ~
[ m , R ,=+ ~ . R . = ]" X'v'I I
replaciz~ ~ and ~I i n ~ we o b t s . t n :
3rr.,,:,, ~ + ,-,-,. R:]" [~, R,~ + ,~.R: ] -- Ira, n,' + ,',',. R:]'~ < 3,',',, .,[,',r',,R, ~ + rr-,.R:]%
-- ",[~,R,~ + ,'-.,:,:]'~ + 3,',',.R.[r-,R,' + r,',. R~]'-- ~ . [ , ~ , . , ~ + ,',',.R: ] ' ~
"l;hat i s :
3m/R~R=[R: + R?--2R, R=] Jr- 3 m=R;R,[R: "~ R2 -- 2R, R=] >m,R~[RI3-'J" 2R23--3R,R2] ~"
+ r n , R2S(~[R3 -I- 2R~ -- 3R2RI2]
Experimental
:I / 1
8O 2O industrial limit and the
8 ~5 other (3.3) represents
gO to a value that might
characterize the theore-
5 tical aspect of the
4
3 problem. As we said all
2
the cements have the
n= t~5 same Blaine specific
n= 'l.cO
99 o---o n = ,~.f4 '1 surface area of 3200
n=331 cm2/g, measured on
0,5 1 2 3 45 fo ~o 3o 4o 5o foo
cement without gypsum.
d Equivalent diarnete~/~ In table I the che-
mical analysis and the
potential constitutions
FIG. 1 of the four cements are
Particle size distribution indicated.
of experimented cements.
TABLE I
n = 3.31 1 25 4.'t6i4.34
° 641°
6,.541 . o , O.281O. 621 0..74 O.33
120 Vol. 6, No. 1
G. Frigione, S. Marra
4a ~ 7iays
7d=ys
~ 3 d a ~ ~
W
I day
lit l I I I I i I I
0 ~, 5 S 7 8
(%)
0 % 4• $ ~ ? 8
(y.)
n= 2.#4 n= 3.3f
SO0
"~400
~ 7days "~ f ""'--'-~'~""~ 7days
W mi f ° ~'--"----~lday
! | ! I I ~. I I I I
4 5 6 7 8 0 ~" 5 6 ? 8
CaS04.2H20(%)added Ca504.2H~O(%) add~
FIG. 2
Influence of gypsum content on strength of Rilem mortars.
Vol. 6, No. 1 121
PARTICLE SIZE DISTRIBUTION, STRENGTH, HYDRATEDCEMENT
We prepared pastes for every sample with two W/C ratios and
put them into test tubes at 20 ± I oC for a curing period. At
fixed periods, the hardened paste was ground and tested to D-dr~
ing according Copeland and Hayes (25) for the determination of
nonevaporable water, Wn/C.
The hydration rates were also confirmed by heat of hydra-
tion measures, H, determined according ASTM C 186-68 but at
room temperature of 2 0 ± I oC.
The two fixed W/C ratios were:
W/C = 0.40, corresponding to the ratio established by ASTM for
the determination of hydration heat.
W/C = 0.80, corresponding to a very high fluidity paste. To
avoid bleeding and, therefore, the change of ratio, as
soon as the paste was made it was poured into test tubes
which, well closed, were set in a continuous motion, in a
radial position, attached to a vertical disc rotating at a
slow velocity until the cement had completed its setting
(26).
We had not considered the values of W./C and of H determi-
ned at ~ges of I and 2 days for pastes at high W/C ratio, be-
cause these values have a high dispersion.
In figg. 3 and 4 the plotting values of nonevaporable
water and of hydration heat, versus n, demonstrate that the
w/c-
~
2B days
~4 days
7 days
- f4 d,,ys days
~" ~ 3days
04
I
f.rs t.~ 2 f.~ 1~..~t 0 t,15 t.50 2 ~.~ 5 3J!
Ig~-n IQcx-n
FIG. 3
The nonevaporable water as a function of n.
122 Vol. 6, No. l
G. Frigione, S. Marra
8 o t day
t~
fn
I I I I
.%31 o U5 I,~ Z Z,14 3 ]31
[q~= n i'qo~= n
FIG. 4
The hydration heat as a function of n.
TABLE II
7d. 3d.
I-..-
, I J I i
f.tS tSO t t.~ 3 3.ZJ 0 J,~5 C50 2 ~,f,~ 3 S, Sf
[ga= n tga = n
FIG. 6
The d e p t h s of water penetration as a function of n.
MechQnical stTeng~hs on R i l e m m o r t a r
,, | , , , H
FIG. 7
Mechanical stremg~hs on Rilem
mortar as a function of n.
J.Jl t ~ | I.~ ,.t SM
M_echanical.strengths on c o n c r e t e
M
28days 28 dove,
° N clays t~.days
* 7 days 7 days
. 3 days 3 da~
. ~ rJays
2 ~ys
v
1 day
,~ f day
I h I i
3 u~ f,fg f.S4p f t, f4 3 Uf
tg~= n
FIG. 8 PIG. 9
Hechanical strengths on con- Hechanlcal strengths on con-
crete as a function of n, crete as a function of n,
(W/C = 0 . 4 2 ) , (w/c = o . 8 2 ) .
FI~. 10
Mechem&cal s t r e r ~ t h s on c o n c r e t e
as a function of Wo/W..
Z~
I I I I
!
Wc/Wn
Conclusion
References
(Communicated by R. Kondo)
(Rec. Sept. 22, 1975; in final form Oct. 13, 1975)
ABSTRACT
We have studied the relations between particle size dis-
tribution at equal specific surface area a n d compressive
strength in Portland cement. Starting from a series of
hypotheses, we have demonstrated that the volume of hy-
drated p r o d u c t , therefore the mechanical stTength ,
increases when t h e g r k n u l o m e t r i c range decreases.
The e x p e r i m e n t a l data have demonstTated that the depth
of hydration d e p e n d s m o s t l y on t h e p a r t i c l e size, con-
trary to our hypothesis. Nevertheless, we h a v e p r o v e d
that when with the actual plants of grinding it is
possible to minimize the width of granulometric range,
the mechanical strength of Portland cements both in
Riles mortar and in concrete can be maximized.
113