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Thin layer drying characteristics of thyme leaves (Anethum sowa L.) under fluidized (air
velocity 2.8 m/s), semi fluidized (air velocity 2.1 m/s) and fixed bed (air velocity 1.2 m/s)
drying conditions were studied at various air temperatures (40, 50, 60 and 70°C). The
effective moisture diffusivity of thyme leaves occurred during 2 periods in the drying
-10 2
process. Results show that the effective moisture diffusivity was 0.243-6.08×10 (m /s)
-11 2
for the first period and 0.311-12.17 ×10 (m /s) for the second period. The values of
activation energy for thyme leaves drying in the first period ranged from 62.71 to 99.52
and from 67.96 to 104.77 (kJ/mol) in the second period. Also the energy consumption
and the required specific energy for drying were in the range of 5.37 and 16.90 kW.h and
358.03 and 1126.83 (kW h/kg), respectively.
keywords: Energy Consumption, Activation Energy, Effective Moisture Diffusion, Thyme leaves
Introduction
Some of the medicinal properties of thyme (Thymus vulgaris) are widening of pulmonary arteries and
reducing coughs, anti-bacterial effect, anti-spasm of digestion tract (nausea), and also thinning of phlegm.
Currently, in most countries medicinal plants are becoming more popular due to complications caused by
synthetic drugs, high costs of synthetic drugs production, and exclusive treatment of certain diseases (e.g.,
leprosy, Aleppo boil, etc.) using medicinal plants (Ahmadi Chenarbon et al., 2011).
Drying action by which water activity due to a food remove almost all the water in which there will stop.
The main purpose of drying is increasing the storage period, weight, volume of material (for packing and
transportation) and preventing biological activities such as microbial and enzyme (Koyuncu et al., 2007).
During storage of agricultural products depend on two physical factors of temperature and moisture. With
decreasing temperature or humidity or both can be significantly increased during this period. Factors affecting
the time and energy consumption during the drying process are: 1-physical properties of product 2- The
geometric shape 3-Relative humidity 4- Temperature (Air Products) 5- Equilibrium moisture content 6-Initial
moisture content of the product 7- Original compositions. Each of the above mentioned factors have a direct
effect on the speed, and rate energy consumption during the drying process (Aghbashlo et al., 2008).
Hot airflow drying could be performed on three different types of drying beds, namely fixed, semi-fluidized,
and fluidized. Fluidization is defined as suspending the vegetable bed (thyme leaves) in air flow. With the
gradual increase in air flowing through a bed of vegetable, fixed bed, minimum fluidized bed (semi fluidized
bed), bubbling fluidized bed and transportation will be created, respectively (Chayjan et al., 2011).
The advantages of fluidized bed drying are the uniform final moisture content of products, high
temperatures for drying, high drying capacity due to better transfer of mass and heat, smaller drying chamber,
lower costs, lower energy consumption, and higher product quality (Soponronnarit, 1999).
Studies on effective moisture diffusivity and activation energy in thin layer drying of vegetables and fruits
include: a constant rate and a falling rate phase. Furthermore, the major part of the drying process occurs at
the falling rate phase. Two well-defined falling rate periods are observed in the drying of some agriculture
products. Each falling rate period corresponds to an approximately constant slope from which the effective
Intl. J. Agron. Plant. Prod. Vol., 4 (9), 2404-2412, 2013
diffusion coefficients are calculated. The drying rates have more than one falling rate period that are reported
for apple (Velic et al., 2004), Jujube fruit (Motevali et al., 2012) and Iranian pistachios (Kouchakzadeh, 2010).
Although considerable data exists in the literature regarding the energy consumption for drying of various
agricultural commodities such as mulberry (Akbulut and Durmus, 2010), garlic cloves (Sharma et al., 2006),
pistachios (Midilli et al., 2003), longan (Tippayawong et al., 2008), pomegranate arils (Motevali et al., 2011),
nettle leaves (Alibas, 2007), berberis fruit (Aghbashlo et al., 2008), azarole (Koyuncu et al., 2007), carrot
slices (Aghabashlo et al., 2009), red pepper (Akpinar et al., 2004), coroba slices (Corzo et al., 2008), potato
(Akpinar et al., 2005), and carrot cubes (Nazghelichi et al., 2010) little information is available on the energy
consumption and specific energy consumption in different bed drying of agriculture products.
Although there is ample information about the drying of medicinal plants using fixed bed drying, very little
information is available on drying of thyme with semi-fluidized and fluidized beds. Also, very little information
is available on using dynamic neural networks for the convective drying of thyme leaves using fixed, semi-
fluidized and fluidized bed conditions.
Therefore, the objectives of this study were as follows:
1- Amount of energy used and specific energy consumption during drying of thyme leaves
2- Determining the effective moisture diffusivity (in two phases) and activation energy (in two phases) for
thyme leaves.
Freshly harvested thyme leaves were purchased from a local farm in Karaj, Alborz province, and samples
o
were stored in a refrigerator at +4 °C. The mean ambient temperature was 28±2 C and the relative humidity
of air was measured as 26±3 % during the experiments. Initial moisture content of fruits was obtained using
the gravimetric method and was determined to be 73.7 % wet basis.
A dryer capable of providing different bed conditions (fixed, semi-fluidized, and fluidized) was used for the
experiments. A centrifugal blower (fan) driven by a 1HP three-phase electromotor was employed to provide
the desired air flow rate. The rotary speed of the electromotor was controlled within zero to its nominal speed
range by an inverter (PSMC-DC, Parto Sanat, Iran) capable of controlling the rotary speed with a 0.1
precision. In order to supply the thermal energy required for the drying process, two thermal elements (2 and
3 kW) were put to use. A type K thermostat (K type, Pooyesh, ±0.1˚C) controlled the input (inlet) air
temperature within the 0 to 100˚C range. Temperature measurements were performed using a sensor (LM35,
National Semiconductor, ±0.1˚C) at both inlet and outlet of the drying apparatu s. Accordingly, the input and
output air’s relative humidity measurements were carried out using HIH-3610, Honeywell, USA, ±2%RH
sensors.
Air parameters were adjusted by measuring temperature and velocity using a thermometer (Lutron, TM-
925, Taiwan) and an anemometer (Anemometer, Lutron-YK, 80AM, Taiwan), respectively. A pressure gauge
(PVR 0606A81, Italy, ±0.1 Pa) and differential digital manometer (Testo 505-P1) was used for recording
fluidization characteristics of bed materials (air velocity against pressure drop) and measuring the inner
pressure of the dryer chamber. Dried samples were weighed using an electronic balance with an accuracy of
±0.01 g, (AND GF-600, Japan).
The maximum value of the static pressure drop versus a specific air velocity in fluidization systems is
defined as the minimum fluidization point or semi fluidized bed (Kunii and Levenspiel, 1991). After
determining the air velocity for semi-fluidized conditions to be about 2.1 m/s, one point below it (in fixed bed
domain) was selected for fixed bed condition with air velocity of 1.2 m/s and one point above the fixed bed
condition as a fluidized bed condition with air velocity of 2.8 m/s. Then the drying experiments were
conducted (Fig. 1). (Chayjan et al., 2012a and b).
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Intl. J. Agron. Plant. Prod. Vol., 4 (9), 2404-2412, 2013
Fig.1. Fluidization curve of thyme leaves and selected points for modeling: A) fix bed (1.2 m/s), B) semi-
fluidized bed (2.1 m/s), and C) fluidized bed (2.8 m/s)
8 D t
ln( MR ) ln( ) ( 2 eff2 ) (4)
2
4L
Plotting equation (3) against time yields a straight line with slope of K1. By plotting the experimental data
in terms of ln(MR) against time (s), effective diffusivity coefficient is determined.
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Intl. J. Agron. Plant. Prod. Vol., 4 (9), 2404-2412, 2013
2 Deff
2
k1 (5)
4L
Using Arrhenius equation, the relationship between temperature and effective diffusivity is shown in the
following equation by which activation energy can be calculated.
Ea
Deff D0 exp( ) (6)
Rg Tabs
2
where D0 indicates Arrhenius coefficient (m /s), Ea activation energy (kJ/mol), Tabs absolute temperature (k)
and Rg universal gas constant.
The temperature used in equation 6 is the heat surround contained in the dryer environment, so the
assumption of constancy of temperature should be considered in both the effective diffusivity and activation
energy. Equation 6 can become linear by applying logarithm on both sides of equation.
Ea 1
LnDeff LnD0 . (7)
Rg Tabs
Activation energy Ea can be determined by plotting the lnDeff diagram against 1/Tabc and the slope of this
line equals K2 and the abscissa is lnD0.
E a
K 2 (8)
Rg
Figure 2 shows changes in ln(MR) with time (s). Generally, the drying process of agricultural produce occurs
in two different rates (fixed and falling rate). This might be due to the capillary and cellular structure properties
of thyme which affect the evaporation rate throughout the drying process.
40 °C 40 °C 50 °C 50 °C 60 °C 60 °C 70 °C 70 °C 40 °C 40 °C 50 °C 50 °C 60 °C 60 °C 70 °C 70 °C
Fig. 2. Plot of ln(MR) versus time (s) at air velocity of (A) fluidized, (B) semi fluidized and(C) fix beds.
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Intl. J. Agron. Plant. Prod. Vol., 4 (9), 2404-2412, 2013
Considering the variation trend of the ln(MR) curve against time (s), a single straight line could not be
used in predicting the slope of curves. In such processes, two or three lines should be used to obtain the
slope gradient of a curve (Velic et al., 2004; Motevali et al., 2012). Values of the effective moisture diffusion
coefficient for drying of thyme in the first falling rate and the second falling rate periods are presented in
figures 3A and 3B, respectively.
4.00E-10 1.60E-10
B
3.20E-10 1.20E-10
A
2.40E-10
Def f Def f 8.00E-11
1.60E-10
4.00E-11
8.00E-11
0.00E+00
2.
0.00E+00
2.
8
Velocity (m/s)
8
Velocity (m/s)
2
2
40
40
50
1.
50
60
1.
2
60
Fig 3. Effective moisture diffusivity of thyme leaves in the A) first falling rate and B) second falling rate periods
As shown, the effective moisture diffusion coefficient in the first falling rate period is higher than that in
the second falling rate period which might be due to higher evaporation rate during the first period compared
with the second period. This would lead to a steeper curve slope for the first period than the second. Similar
results were reported for the drying of jujube (Motevali et al., 2012) and pistachio (Kouchakzadeh, 2010).
Also, the results showed that increasing temperature and airflow rate would increase the effective
-10 -10 2
moisture diffusion rate so that the highest infiltration rates of 6.085×10 and 1.22×10 m /s could be
achieved at 70 ˚C in the fluidized bed for the first and second periods, respectively. While the l owest infiltration
-11 -12 2
rates of 2.43×10 and 3.11×10 m /s were obtained at fixed bed for the first and second periods,
respectively.
Using multiple regression analysis, relationships were established between the effective moisture diffusion
in the first and second periods, air velocity and air temperature for the convection dryer (Fig. 4 and 5). The
2
equations and their respective coefficients of determination (R ) are given below the figures (Eq.12 and Eq.
13).
Fig 4. Interaction effect of temperature and air velocity (bed types) on the effective moisture diffusion for the
first falling rate period in drying of thyme leaves
2
R =0.974 (12)
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Intl. J. Agron. Plant. Prod. Vol., 4 (9), 2404-2412, 2013
Fig 5. Interaction effect of temperature and air velocity (bed types) on the effective moisture diffusion for the
second falling rate period in drying of thyme leaves.
2
R =0.925 (13)
Presents the values for the activation energy during the first and second periods. According to table 1,
increasing the airflow rate and shifting the product bed from fixed to floating during the drying process would
lead to increased activation energy for both periods. Aerodynamic effects could be the cause of this
phenomenon, considering the change in the product bed from fixed to floating during the drying process.
Similar results were reported by other authors for the drying of pomegranate seed (Chayjan et al., 2012c)
and garlic slices (Chayjan et al., 2012b).
Table1. Activation energy and related correlation coefficient at different bed drying for thin-layer drying of dill
leaves.
Type of Bed
Semi
Fix Fluid
Variables Fluid
Energy Consumption
Fig. 6 shows the amount of energy needed by the heaters to dry thyme leaves at different air velocity
and temperature. It is observed from the figure that with increasing air velocity at constant temperature,
energy consumption increased. Also, energy consumption decreased as temperature increased at constant
air velocity. With increasing temperature, the drying time is reduced due to increased thermal gradients inside
the material and as a result increased product drying rate. The minimum and maximum values of energy
consumption for drying of thyme leaves were found to be 5.37 and 16.90 kW.h, at 70°C and 1.2 m/s, and
40°C and 2.8 m/s, respectively.
The specific energy for thyme leaves drying in the convection dryer, decreased with increasing
temperature (at constant air velocity) while it increased with air velocity (at constant temperature). The
minimum and maximum values of specific energy consumption for drying of thyme leaves were found to be
358.03 and 1126.83 kW.h/kg, at 70°C and 1.2 m/s, and 40°C and 2.8 m/s, respectively (Fig. 7).
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Intl. J. Agron. Plant. Prod. Vol., 4 (9), 2404-2412, 2013
18
Energy Consumption (kW.h)
15
12
0
40
50
60
70
40
50
60
70
40
50
60
70
°C
°C
°C
°C
°C
°C
°C m/s
°C
°C
°C
°C
°C
,1
,1
,1
,1
,2
,2
,2
,2
,2
,2
,2
,2
.2
.2
.2
.2
.1
.1
.1
.1
.8
.8
.8
.8
m
m
/s
/s
/s
/s
/s
/s
/s
/s
/s
/s
/s
Fig 6. Energy consumption for thin-layer drying of thyme leaves at different levels of air temperature and
velocity
Specific Energy Consumption (kWh/kg)
1200
900
600
300
0
40
50
60
70
40
50
60
70
40
50
60
70
°C
°C
°C
°C
°C
°C
°C
°C
°C
°C
°C
°C
,1
,1
,1
,1
,2
,2
,2
,2
,2
,2
,2
,2
.2
.2
.2
.2
.1
.1
.1
.1
.8
.8
.8
.8
m
m
/s
/s
/s
/s
/s
/s
/s
/s
/s
/s
/s
/s
Fig7. Specific energy consumption for thin-layer drying of Thyme leaves at different levels of air temperature
and velocity
Conclusion
The drying behavior of thyme leaves under three different drying conditions (fixed, semi-fluidized, and
fluidized beds) and four temperature levels (40, 50, 60, and 70˚C) was studied and the following findings are
deduced:
1- It was observed that energy consumption diminished when temperature increased at each air velocity,
while it increased with increasing hot air velocity. It can be concluded that 70 ºC air temperature and velocity
of 2.1 m/s are the optimum parameters for reduction of energy consumption.
2- The amount of required specific energy was decreased by increasing temperature and was increased
by increasing air rate.
3- The effective moisture diffusion rate for thyme was obtained in two periods. Also, the highest and lowest
infiltration rates and activation energy were obtained in fluidized and fixed beds, respectively.
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Intl. J. Agron. Plant. Prod. Vol., 4 (9), 2404-2412, 2013
Acknowledgment
This paper is a result of one of the research projects that has been approved by Islamic Azad University,
Shahr-e-Qods, Iran. This research project has been supported financially by Department of Research of
Islamic Azad University, Shahr-e-Qods Branch, in 2013. This is an opportunity for the authors to extend their
sincere appreciations to Department of Research of the Islamic Azad University, Shahr-e-Qods Branch.
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