JEE Advanced Sample Question paper for Chemistry

PAPER−1

Roll No.

JEE Advanced 2018

Sample Question Paper
CHEMISTRY
Section-1 (Maximum Marks : 21)
(i) This section contains 7 question.
(ii) Each question has 4 options (a), (b), (c), and (d). ONLY ONE of these four options
is correct.
(iii) For each question, darken the bubble corresponding to the correct option in the ORS.
(iv) For each question, marks will be awarded in one of the following categories:
Full Marks : +3 If, only the bubble corresponding to the correct option is darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : −1 In all other cases.

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 JEE Advanced Sample Question paper for Chemistry

1. Math List I with List II and select the correct answer using the code given below the lists :
En = total energy  = angular momentum
Kn = K.E. , Vn = P.E.
Tn = time period, rn = radius of nth orbit
List (I) List (II)

(a) En−y ∝ rn then y (p) 

(b)  ∝ nx then x (q) −2

(c)  (r) −4


(d) Tn ∝   t and m respectively (s) 1


Code :
(a) (b) (c) (d) (a) (b) (c) (d)
(i) s s p q (ii) r s p q
(iii) s s q p (iv) s r p q

2. The molar entropy content of 1 mole of oxygen (O2) gas at 300 K and 1 atm is 250 J mole−1.
Calculate ∆G when 1 mole of oxygen is expanded reversibly and isothermally from 300 K, 1
atm to double its volume (Take R = 8.314 J mole−1 K−1, log e = 2.303)
(a) 1.728 KJ mole−1 K−1
(b) 0
(c) −1.728 KJ mole−1 K−1
(d) 0.75 KJ mole−1K−1

3. The oxidation state of sulphur in the anions SO32−, S2O42− and S2O62−following the order:
(a) S2O62− < SO42− < SO32−
(b) S2O42− < SO32− < S2O62−
(c) SO32− < S2O42− < S2O62−
(d) S2O42− <S2O62− < SO32−

4. Which of the following statements is most likely to be incorrect ?

(a) Ti(NO3)4 is a colourless compound.
(b) [Cu(NCCH3)4]+ BF4− is a colourless compound.
(c) [Cr(NH3)6]3+ 3CI− is a coloured compound.
(d) K3[VF6] is a colourless compound.

5. Glucose and mannose are :

(a) Anomers
(b) Positional isomers
(c) Functional isomers
(d) Epimers

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 JEE Advanced Sample Question paper for Chemistry

6. Compound P(C6H10) does not have any geometrical isomer. On Ozonolysis, two products
R(C3H4O) and Q(C3H6O) are formed. R gives negative iodoform test while Q responds positively
towards I2/NaOH solution. S another isomer of P is an unsymetrical alkene and on ozonolysis
produces T(C6H10O2) which also gives a yellow precipitate with I2/NaOH solution and also gives
positive test with Tollen’s reagent. Which of the following does not represent any of the
molecules amongst P,Q,R,S & T.

(a)
(c)

(b)
(d)

7. In the equation : M + 8CN− + 2H2O + O2 → 4[M(CN)2]− + 4OH−, metal M is

(a) Ag
(b) Au
(c) Cu
(d) Hg

Section-2 (Maximum Marks : 15)

(i) This section contains 5 question of matching type.
(ii) For each question, darken the bubble corresponding to the correct option in the ORS.
(iii) For each question, marks will be awarded in one of the following categories:
Full Marks : +3 If, only the bubble corresponding to the correct option is darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : −1 In all other cases.

8. Match the species listed in column-I with the characteristic(s)/propertie(s) listed in column-II.
Column-I Column-II
(a) C2 (p) Diamagnetic
(b) N2 (q) Undergoes oxidation
(c) O22− (r) Undergoes reduction
(d) F2 (s) Bond order ≥ 2
(t) No mixing of `s` and `p` orbitals

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 JEE Advanced Sample Question paper for Chemistry

9.
Column-I Column-II
(a) NH2COONH4(s) 2NH3(g) + CO2(g); (p) High pressure and low temperature will
∆H < 0 favour formation or products.
(q) Increase in the amount of any of the
(b) CaCO3(s) CaO(s) + CO2(g);
product will definitely favour backward
∆H > 0
reaction.
(r) Increase in temperature and doubling the
(c) N2(g) + O2(g) 2NO(g);
volume of reaction vessel will cause the
∆H > 0
equilibrium to shift similar direction.
(d) 2SO2(g) + O2(g) 2SO3(g); (s) A decrease in temperature will cause
∆H < 0 decrease in value of equilibrium constant.
(t) Increase in concentration of reactant the
equilibrium is achieved will make the
equilibrium shift towards product side.

10. Match the following :

Column-I Column-II
(a) If the activation energy is 65 kJ then how much time faster a (p) 0
reaction proceed at 25°C than at 0°C.
(b) Rate constant of a first-order reaction is 0.0693 min−1. If we start (q) 11
with 20 mol L−1, it is reduced to 2.5 mol L−1 in how many minutes.
(c) Half-lives of first-order and zeroth order reactions are same. Ratio of (r) 30
rates at the start of reaction is how many times of 0.693 ? (If initial
concentration are same for both zero and first order reactions.)
(d) The half-life periods are given, (s) 1/4
[A]0 (M) 0.0677 0.136 0.272
t1/2 (sec) 240 480 960
order of the reaction is
(t) 2

11. Match column I with column II and select the correct answer using the codes given below the
lists :
Column-I Column-II
(I) Cyanide process (p) Ultra pure Ge
(II) Froth floatation process. (q) Pine oil
(III) Electrolytic reduction. (r) Extraction of Al
(IV) Zone refining (s) Extraction of Au
(a) I−(r), II−(p), III−(s), IV−(q)
(b) I−(s), II−(q), III−(r), IV−(p)
(c) I−(r), II−(q), III−(s), IV−(p)
(d) I−(s), II−(p), III−(r), IV−(q)

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 JEE Advanced Sample Question paper for Chemistry

12. Match the order given in column (I) with the property(ies) in column (II).
Column-I Column-II
(a) Rb2CO3 > K2CO3 > Na2CO3 (p) Solubility of salts in water
(b) SrSO4 > CaSO4 > MgSO4 (q) Thermal stability of salts
(c) Rb > K > Na (r) Softness of metals
(d) Be > Mg > Ca (s) Hydration energy of metals
(t) Ionization energy of metals

Section-3 (Maximum Marks : 18)

(i) This section contains 6 question.
(ii) The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both
inclusive.
(iii) For each question, darken the bubble corresponding to the correct integer in the ORS.
(iv) For each question, marks will be awarded in one of the following categories:
Full Marks : +3 If, only the bubble corresponding to the correct option is darkened.
Zero Marks : 0 In all other cases.

13. 29.2% (w/w) HCl stock solution has a density of 1.25 g mL−1. The molecular weight of HCl is
36.5 g mol−1. Find the Volume(V) (mL) of stock solution required to prepare a 500 mL
solution of 0.4 M HCl. Report your answer as V/5

14. How many of the following liberate coloured vapour/gas with concentrated H2SO4?
KCl(s) + K2Cr2O7(s), Kl(s), KBr(s), KCl(s)
KBr(s) + MnO2(s), KNO3, KCl(s) + MnO2, K2SO3

15. How many isomers of the complex, Pt(NH3)2 (SCN)2 are possible?

16. For given simultaneous reaction :

X(s) ⇌ A(g) + B(s) + C(g) KP  = 500 atm
Y(s) ⇌ D(g) + A(g) + E(s) KP  = 2000 atm
If total pressure = x, then write your answer after dividing by 25.

17. Sum of antibonding π electrons (π* electrons) in species O2, O2− and O22− are.

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 JEE Advanced Sample Question paper for Chemistry

18. An element undergoes a reaction as shown :

X + e− → X− Energy released = 30.876 eV
The energy released, is used to dissociate 8 g of H2 molecules equally into H+, where H*, is in
an excited state, in which the electron travels a path length equal to four times its debroglie
wavelength.
(a) Determine the least amount (moles) of `X` that would be required.
Given : I.E. of H = 13.6 eV/atom
Bond energy of H2 = 4.526 eV/molecule.
(b) Why is the amount of X calculated in the above question `least`?