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Problem Statement
Acetone is a clear, colorless, low-boiling, flammable and volatile liquid characterized by rapid
evaporation and a faintly aromatic, sweetish odor. It readily mixes with most organic solvents and
mixes completely with water.
Roughly 75% of the available acetone is used to produce other chemicals, and 12% is used as a
solvent. Applications range from surface coatings, films and adhesives to cleaning fluids and
pharmaceutical applications.
Acetone is a highly flammable material in both the liquid and vapor forms, has a relatively high
vapor pressure, and should be handled only with adequate ventilation and in areas where ignition
sources have been removed (e.g. matches and unprotected light switches). The flash point for
acetone is -4ºF /-20ºC.
There is about 7% increment in the requirement of the acetone worldwide. With this increasing
demand the requirement of the acetone in some upcoming years is:
2011 7.2
2012 7.9
2013 8.4
2014 9.0
2015 9.63
2016 10.3
2017 11.02
1.5 Capacity:
The capacity of the desired plant to produce acetone is 45000 tons per year. The capacity data of
some previous years is:
This process converts two relatively cheap starting materials, benzene and propylene, into two
more valuable ones, phenol and acetone. Other reactants required are oxygen from air and small
amounts of a radical initiator. Cumene process is a process of producing phenol (C6H5-OH) and
acetone (CH3-CO-CH3) from benzene (C6H6) and propene (C3H6).
The term stems from isopropyl benzene or cumene (C6H5-CH(CH3)2), the intermediate
material during the process.
Acetone can also be produced by the direct oxidation of propylene using air. In this process
the catalysis consists of a solution of copper chloride containing small quantities of palladium
chloride. The reaction takes place under a moderate pressure and at 100°C. It is exothermic
by 61 kcal/mole of acetone produced. The overall reaction is as follows:
In this process, an aqueous solution of isopropyl alcohol is fed into the reactor, where the stream
is vaporized and reacted over a solid catalyst. The reactions occurring within the reactor are as
follows:
𝐶𝑢/𝐶
𝐶𝐻3 − 𝐶𝐻𝑂𝐻 − 𝐶𝐻3 → 𝐶𝐻3 − 𝐶𝑂 − 𝐶𝐻3 + 𝐻2
The primary advantage of this process is that the acetone produced is free from trace aromatic
compounds, particularly benzene. For this reason, acetone produced from IPA is favored by the
pharmaceutical industry.
Major disadvantage of the production of acetone from cumene process is that some amount
of reactant benzene is present along with desired product which is toxic.
The disadvantage of production of acetone from propylene oxidation process is that
propylene required for the process should be 99 % pure.
The reaction occurs in vapor phase at a temperature of 350 °C and a pressure of 1.8 – 2 bars in the
presence of catalyst.
𝐶𝑎𝑡𝑎𝑙𝑦𝑠𝑡
𝐶𝐻3 − 𝐶𝐻𝑂𝐻 − 𝐶𝐻3 (𝑣) → 𝐶𝐻3 − 𝐶𝑂 − 𝐶𝐻3 (𝑣) + 𝐻2 (𝑔) ∆𝐻 = +62.9𝐾𝐽/𝑚𝑜𝑙
At a temperature lower than 325 °C the following reaction is more expected to occur, and ether
(di-isopropyl ether) is obtained as the product instead of acetone.
At the higher temperature (>350 °C), dehydration reaction is expected to be significant and
propylene is formed.
So the suitable temperature conditions for the reaction is between 325 °C to 350 °C
Trial and error experimentation and scientific analysis provide guidance for the selection of the
catalyst. There are some categories of the catalyst which are suitable for some purpose. For
example platinum, copper and related metals elements such as palladium are known to catalyze
hydrocarbon oxidation and dehydrogenation. Since our desired reaction is the dehydrogenation
reaction of hydrocarbon (isopropyl alcohol), so the catalyst used for the process belong to this
category.
One of the factors considered in the selection of catalyst is their turn over frequency (TOF).
4.3.1 Turn over frequency: Turn over frequency of the catalyst is defined as the amount of reactant
converted into product by the catalyst in the unit time. For most relevant industrial applications,
the turnover frequency is in the range of 10−2 - 102 s−1
The turnover frequency of cu chromites catalyst is 0.026 per second
The TOF of carbon supported copper is 0.052 per second double than that of the cu
chromites catalyst.
Platinum (with a turnover frequency of 0.66 per second) metal has the high TOF for this
process but it is expensive.
So the suitable catalyst for this process is carbon supported copper.
Molecular 18 58 60 2
Weight(kg/kmol)
7. Flow sheet:
7.1.1 Feed drum: Feed drum is a kind of tank used for the mixing of the recycle stream and feed
stream. Recycle stream concentration is assumed to be same with the feed stream. Feed stream is
7.1.2 Vaporizer: In the vaporizer molten salt is used for heating. The temperature at the entrance
of the unit is the temperature of the mixture leaving the feed drum, which is 32.890 °C. And the
leaving temperature is the bubble point temperature of the mixture, which is 109.50 °C. The
pressure is 2 bars, and assumed to be constant.
7.1.3 Heater: Since the temperature leaving the vaporizer is not enough for the reaction to carry
out. Due to which a pre-heater is used to maintain the temperature of the feed stream to the reaction
temperature of 350 °C which is the reaction temperature. The unit is working at 2 bars, and
assumed to be constant. The entrance and leaving temperatures are 109.50°C and 350 °C.
7.1.4 Reactor: The reactor is the starting point for the calculations. The temperature values for the
entering and leaving streams is 350 °C, (i-e the process is isothermal). The reaction takes place
inside is endothermic, for this reason the reactor has to be heated. For heating, molten salt is used
from the furnace.
7.1.5 Cooler: The entrance temperature of the cooler is 350 °C and leaving temperature is 94.70
°C. (Temperature is calculated by using energy balance). For cooling purpose water is used. By
using refrigerant better results may be obtained. But since it costs too much, due to which it isn’t
chosen as the cooling material. From the temperature values it’s easily seen that the load is on the
cooler not on the condenser, for this process. But in reality the unit cannot cool that much, and the
load is mostly on the condenser. In this process, the mixture cooled down to its dew point. The
pressure is 1.5 bars, and assumed to be constant.
7.1.6 Condenser: The temperature of the entering stream is the dew point and the leaving
temperature is the bubble point of the mixture. In the condenser water is used as cooling material.
7.1.7 Flash unit: Flash unit is operating isothermally, for this reason temperature is not changed.
It is 81 °C in the entrance and exit. From trial and error method, (V / F) value is found to be 0.2.
The entrance temperature of the unit is the bubble point of the mixture, but if it is its dew point the
(V/F) value should be much higher. In the flash unit the hydrogen is flashed out from the mixture
of isopropyl alcohol, water and acetone. Along with hydrogen some amount of acetone and
isopropyl alcohol is also flashed out. In order to recover these, a scrubber unit is used.
7.1.8 Scrubber: Scrubber operated adiabatically. Water entering the unit is at atmospheric
temperature (i-e 25 °C). The temperature of the off gas, including hydrogen and a very little amount
7.1.9 Acetone distillation column: The acetone column is used to separate the acetone from the
mixture. The entrance temperature is 45 °C. The leaving temperatures for the top and bottom
product are 102.3 °C and 105 °C, respectively, which are the bubble and dew points. Top product
of the unit includes acetone (99wt% of acetone which is desired). From the bottom isopropyl
alcohol, water and a very little amount of, 0.1 %, acetone is discharged.
7.1.10 Isopropyl alcohol column: In this distillation column, isopropyl alcohol and water are
separated. The entrance temperature is 105 °C. The leaving temperatures of the top and bottom
products are both111.50 °C. The top product is recycled to the feed drum. For this reason it’s
assumed to have the same concentration with the feed stream. The bottom product is pure water
and it’s thrown away. Since its temperature is very high it cannot be recycled to the scrubber. But
if a cooler is used, a recycle can be used.
Selection of the reactor type for a given process is subjected to a number of considerations
d) Catalyst use consideration such as requirement for solid catalyst particle and contact with
fluid reactants and products.
For conversion up to 90%, the performance of five or more CSTRs connected in series
approaches to that of PFR.
Batch reactors are best suited for small scale production, very slow reactions or those
requiring intensive monitoring and control. For large operations CSTR or PER is used
CSTRs are used for slow liquid phase and slurry reactions. For gas phase reactions PER is
more preferable.
For endothermic reactions the plug flow reactor is used. For exothermic reaction that has a
large temperature raise during the reaction, recycle reactors are the best choice.
𝐶𝑝 𝐶
For small ⁄−∆𝐻 mixed flow reactor is used. For large 𝑝⁄−∆𝐻 plug flow reactor is
𝑟 𝑟
best choice.
Since our reaction is the gaseous phase and endothermic reaction so the choice is the plug flow
reactor.
Use of the catalyst requires modifications to basic reactor design to fixed bed reactors, moving bed
reactors or fluidized bed reactors.
8.2.1 Fixed bed reactors: These are used in the heterogeneous catalyst reactions and pressure drop
across the bed is small. The design of the fixed bed reactor is very easy as compared to the moving
8.2.2 Fluidized bed reactors: These are the reactors with a gas phase working fluid that requires
gas flow around and across the fine particles at a rate sufficient to fluidize the particles suspended
within the reactor. Since the catalyst bed has to be fluidized so the energy requirement in these
reactors is large. Pressure drop is also large as compared to the fixed bed reactors because the
pressure is dissipated to fluidize the bed. The volume of the reactor required is also large as
compared to fixed bed reactor, because the void spaces between the fluidized beds occupy the
more volume.
8.2.3 Moving bed reactor: These units are fluid reactors used where the fluid contain solid particles
that can be separated from the suspension fluid. Mostly suitable for liquid phase reactions or where
the slurry travels through the reactor. Moving bed reactors are not preferred for the gas phase
reactions. In these reactors the pressure drop is the greater among all.
From above points we see that the suitable reactor for our process is fixed bed plug flow reactor,
with the reaction occurring in the tubes and the heat exchanging material flowing outside the tubes.
a) Collect together all the kinetic and thermodynamic data on the desired reaction and the side
reactions (if present). The kinetic data required for reactor design will normally be obtained
from laboratory or pilot plant studies. Values will be needed for the rate of reaction over a
range of operating conditions: pressure, temperature, and flow-rate and catalyst
concentration.
b) Collect the physical property data required for the design.
c) Identify the predominant rate-controlling mechanism: kinetic, mass or heat transfer.
d) Choose a suitable reactor type, based on experience with similar reactions, or from the
laboratory and pilot plant work.
e) Make an initial selection of the reactor conditions to give the desired conversion and yield.
f) Size the reactor and estimate its performance. Exact analytical solutions of the design
relationships are rarely possible; semi empirical methods based on the analysis of idealized
reactors will normally have to be used.
g) Select suitable materials of construction.
h) Make a preliminary mechanical design for the reactor: the vessel design, heat-transfer
surfaces, internals and general arrangement.
i) Cost the proposed design, capital and operating, and repeat steps 4 to 8, as necessary, to
optimize the design.
i. Chemical factors:
The design must provide sufficient residence time for the desired reaction to proceed to the
required degree of conversion.
i. Anhydrous
ii. 87% by weight.
Due to which we are using the 87 weight percent solution of isopropyl alcohol.
Basis: 100 kgmol/hr of the isopropyl alcohol are entering in the reactor.
Since the solution used for the preparation of acetone is 87%. So the number of moles of water
entering in the reactor is calculated as:
𝑤𝑒𝑖𝑔ℎ𝑡 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑒
𝑤𝑒𝑖𝑔ℎ𝑡 𝑝𝑒𝑟𝑐𝑒𝑛𝑡 =
𝑇𝑜𝑡𝑎𝑙 𝑤𝑒𝑖𝑔ℎ𝑡 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛
𝑊𝑒𝑖𝑔ℎ𝑡 𝑜𝑓 𝐼𝑃𝐴
0.87 =
(𝑤𝑒𝑖𝑔ℎ𝑡 𝑜𝑓 𝐼𝑃𝐴 + 𝑤𝑒𝑖𝑔ℎ𝑡 𝑜𝑓 𝑤𝑎𝑡𝑒𝑟)
100 × 60
0.87 =
100 × 60 + 𝑤𝑒𝑖𝑔ℎ𝑡 𝑜𝑓 𝑤𝑎𝑡𝑒𝑟
𝐶𝑢/𝐶
𝐶𝐻3 − 𝐶𝐻𝑂𝐻 − 𝐶𝐻3 → 𝐶𝐻3 − 𝐶𝑂 − 𝐶𝐻3 + 𝐻2
= 49.8 𝑘𝑔𝑚𝑜𝑙/ℎ𝑟
90
𝑀𝑜𝑙𝑒 𝑓𝑟𝑎𝑐𝑡𝑖𝑜𝑛 𝑜𝑓 𝑎𝑐𝑒𝑡𝑜𝑛𝑒 𝑖𝑛 𝑠𝑡𝑟𝑒𝑎𝑚 5 = 𝑦𝑎𝑐𝑒𝑡𝑜𝑛𝑒,5 = = 0.375
239.8
Mass of water in + Mass of IPA in = Mass of water out + Mass of IPA out +
From the 100 kmol/hr of the isopropyl alcohol entering in the reactor the amount of the acetone
produced per year is 45700 tons, which is very close to the desired amount of the product. So we
are not applying the material balance again, but using these calculations in the process.
So,
By using 100 moles of the isopropyl alcohol per hour the amount of acetone produced is 45700
ton per year.
Temperature at outlet =
350 °C
Reference temperature = 25 °C
∆𝐻𝑖𝑛, 𝐼𝑃𝐴 = ∫ (32.427 + 1.886 × 10−1 𝑇 + 6.405 × 10−5 𝑇 2 − 9.261 × 10−8 𝑇 3 )𝑑𝑇
25
∆𝐻𝑖𝑛, 𝐼𝑃𝐴 = 20.014 𝐾𝐽/𝑔𝑚𝑜𝑙
350
∆𝐻𝑖𝑛, 𝑤𝑎𝑡𝑒𝑟 = ∫ (33.46 + 0.6880 × 10−2 𝑇 + 0.7640 × 10−5 𝑇 2 − 3.593 × 10−9 𝑇 3 )𝑑𝑇
25
Reference temperature = 25 °C
∆𝐻𝑜𝑢𝑡, 𝐼𝑃𝐴 = ∫ (32.427 + 1.886 × 10−1 𝑇 + 6.405 × 10−5 𝑇 2 − 9.261 × 10−8 𝑇 3 )𝑑𝑇
25
∆𝐻𝑜𝑢𝑡, 𝑤𝑎𝑡𝑒𝑟 = ∫ (33.46 + 0.688 × 10−2 𝑇 + 0.764 × 10−5 𝑇 2 − 3.593 × 10−9 𝑇 3 )𝑑𝑇
25
∆𝐻𝑜𝑢𝑡, 𝑎𝑐𝑒𝑡𝑜𝑛𝑒 = ∫ (71.96 + 20.1 × 10−2 𝑇 − 12.78 × 10−5 𝑇 2 + 34.76 × 10−9 𝑇 3 )𝑑𝑇
25
∆𝐻𝑜𝑢𝑡, ℎ𝑦𝑑𝑟𝑜𝑔𝑒𝑛
350
− 9.4514 × 106
∆𝐸 = −∆[ (𝐻 + 𝑃 + 𝐾) 𝑛] + 𝑄 − 𝑊
Here kinetic and potential energies are neglect able with no work done and no accumulation of
heat.
𝑄 = ∆𝐻𝑟
𝑄 = ∆𝐻𝑟 = ∑ ∆𝐻 𝑖 − ∑ ∆𝐻𝑖
𝑜𝑢𝑡 𝑖𝑛
This shows that in order to carry out the reaction we have to supply the 6.3111 ×106 KJ of heat on
the basis of 100 kg-mol of isopropyl alcohol entering in the reactor.
From the energy balance calculations, it is also seen that the reaction is endothermic and we have
to supply the heat to the process. This heat is supplied by the use of the molten salt:
Energy supplied by the molten salt = Energy absorbed by the reacting fluid
𝑄𝑠𝑢𝑝𝑝𝑙𝑖𝑒𝑑 = 𝑄𝑎𝑏𝑠𝑜𝑟𝑏𝑒𝑑
The mass flow rate and the temperature are selected and
optimized and that values of the flow rate and temperature
are selected which makes the process most efficient at
minimum cost.
The performance equation for the fixed bed plug flow reactor is:
𝑋𝐴
𝑊 𝑑𝑋𝑎
= ∫
𝐹𝐴𝑜 −𝑟𝐴
0
Where W is the weight of the catalyst. FAo is the flow rate of the isopropyl alcohol.−𝑟𝐴 is the rate
of the reaction. The weight of the catalyst is found from this performance equation.
−𝑟𝐼𝑃𝐴 = 𝐾 𝐶𝐼𝑃𝐴
In the form of conversion the rate equation becomes
Where
−𝐸
𝐾 = 𝐾𝑜 𝑒𝑥𝑝 [ 𝑅𝑇𝑎 ]
By putting the values of conversion from 0 to 1 in rate equation we obtain the values of−𝑟𝐴 . From
this we find the values of 1/−𝑟𝐴 . Plot the graph between and 1/−𝑟𝐴 , the weight of catalyst can be
calculated.
𝑋𝐴 −𝑟𝐴 1⁄
−𝑟𝐴
0 0.0061 163.9344
3500
3000
2500
2000
(1/-rA)
1500
1000
500
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
Conversion (XA)
So
𝑋𝐴
𝑑𝑋𝐴
∫ = 730
−𝑟𝐴
0
From the general gas equation the concentration of IPA = 𝐶𝐴𝑜 = 0.025 𝑚𝑜𝑙/𝑚3
The time needed to treat the one reactor volume is called the space time.
𝑊𝐶𝐴𝑜 𝑘𝑔. ℎ𝑟
𝜏= = 18.25
𝐹𝐴𝑜 𝑚3
The void fractions for the spherical particles is between 0.4 to 0.41
The diameter of the copper particles selected (from the literature) = 0.3 mm with the void fractions
(Porosity = φ) of 0.4
𝑉𝑐𝑎𝑡
𝑉𝑜𝑙𝑢𝑚𝑒 𝑜𝑓 𝑟𝑒𝑎𝑐𝑡𝑜𝑟 = 𝑉𝑟 =
1−𝜑
8.16
𝑉𝑜𝑙𝑢𝑚𝑒 𝑜𝑓 𝑟𝑒𝑎𝑐𝑡𝑜𝑟 = 𝑉𝑟 = = 13.6 𝑚3
1 − 0.4
13.9 Number of tubes
The preferred lengths of the tubes (according to the TEMA standard) should be is 6ft, 8ft, 12ft,
16ft, 20ft and 24ft (7.32 m).
𝐷𝑡
⁄𝐷 > 15
𝑝
𝐷𝑡
⁄𝐷 = 70⁄3 = 23.3 > 15
𝑝
𝜋 2 𝜋
𝑉𝑜𝑙𝑢𝑚𝑒 𝑜𝑓 𝑜𝑛𝑒 𝑡𝑢𝑏𝑒 = 𝐷 𝐿 = (0.07)2 × 7.32 = 0.028 𝑚3
4 4
𝑇𝑜𝑡𝑎𝑙 𝑣𝑜𝑙𝑢𝑚𝑒 13.6
𝑁𝑢𝑚𝑏𝑒𝑟 𝑜𝑓 𝑡𝑢𝑏𝑒𝑠 = = = 485 𝑡𝑢𝑏𝑒𝑠
𝑉𝑜𝑙𝑢𝑚𝑒 𝑜𝑓 𝑜𝑛𝑒 𝑡𝑢𝑏𝑒 0.028
For our system assuming the allowance for shell is 20% of the tube height.
So
Diameter of the shell is calculated by using the Harvey equation. Harvey equation is:
𝐷𝑠 = 𝐷𝑖𝑎𝑚𝑒𝑡𝑒𝑟 𝑜𝑓 𝑠ℎ𝑒𝑙𝑙 = ?
𝑛 = 𝑁𝑢𝑚𝑏𝑒𝑟 𝑜𝑓 𝑝𝑎𝑠𝑠𝑒𝑠 = 1
All the values assumed can be verified from the length to diameter ratio of the given reactor and
the pressure drop calculations. If the value of length to diameter ratio and pressure drop lies within
the limit of the fixed bed plug flow reactor then the design is accepted, otherwise we have to
perform the calculations again with the different assumptions.
For the plug flow reactor the length to diameter ratio lies between 3-5.
Length = 10.248 m
Diameter = 2.15 m
= 4.766
For the desired reactor the length to diameter ratio is 4.766 lies between the allowable limit. So
the design is satisfactory.
For the fixed bed reactor to operate economically the pressure drop along the length of the reactor
should be less than the 10% of the operating pressure.
The pressure drop along the length of the packed bed is calculated by using the Ergun equation.
The Ergun equation is:
Where
∈= 𝜑 = 𝑝𝑜𝑟𝑜𝑠𝑖𝑡𝑦 = 0.4
𝑔 = 𝐺𝑟𝑎𝑣𝑖𝑡𝑎𝑡𝑖𝑜𝑛𝑎𝑙 𝑐𝑜𝑛𝑠𝑡𝑎𝑛𝑡
𝐾 = 𝑐𝑜𝑛𝑣𝑒𝑟𝑠𝑖𝑜𝑛 𝑓𝑎𝑐𝑡𝑜𝑟
∆𝑃 = 0.172 𝑏𝑎𝑟
The pressure drop along the length of the reactor is less than the 10% of the operating pressure. So
the design is accepted.
In plug flow reactor where the reacting fluid is inside the tubes, the volume of tubes should be
greater than the volume of the reactor. So
𝐷𝑖𝑎𝑚𝑒𝑡𝑒𝑟 𝑜𝑓 𝑡𝑢𝑏𝑒 = 70 𝑚𝑚
This is greater than the reactor volume. So all the conditions are satisfied and design is accepted.
1 5
1-2 7
2-2.5 9
2.5-3 10
3-3.5 12
Since the diameter of
the vessel is 2.15 m,
so from the above table the thickness of the shell is 9mm.
The ends of a cylindrical vessel are closed by heads of various shapes. The principal types used
are:
2. Hemispherical head
3. Ellipsoidal head
4. Torispherical head
𝑃𝑖 𝑅𝐶 𝐶𝑆
𝑒=
2𝐽𝑓 + 𝑃𝑖 (𝐶𝑠 − 0.2)
Where
𝑒 = 𝑇ℎ𝑖𝑐𝑘𝑛𝑒𝑠𝑠 𝑜𝑓 𝑠ℎ𝑒𝑙𝑙 = ?
1 𝑅𝐶
𝐶𝑆 = (3 + √ )
4 𝑅𝐾
So by putting the values of all the variables the value of thickness of head is:
𝑒 = 2.5 𝑚𝑚
The method used to support a vessel will depend on the size, shape, and weight of the vessel; the
design temperature and pressure and the vessel location and arrangement.
Types of supports:
Bracket Support
Equipment Reactor
Thickness of shell 9 mm
16. References
www.che.cemr.wvu.edu/publications/projects/acetone/acetone-a.PDF
http://www.owlnet.rice.edu/~ceng403/gr1998/acetone.html
http://www.scribd.com/doc/30134032/Isopropyl-Alcohol
www.annualreviews.org/doi/pdf/.../annurev.matsci.35.100303.12073
www.jbrwww.che.wisc.edu/home/jbraw/chemreacfun/.../slides-masswrxn.p
Gael D. Ulrich P. T. Vasudevan “A Guide to Chemical Engineering Process Design
and Economics” 2nd ed, Process publishing, 1993
Plant design and economics for chemical engineers by Timmerhaus 5th edition
Chemical engineering design by Coulson and Richardson’s volume 6, 4th edition