svori2 Entropy and the Second Law of Thermodynamics.
Entropy and the Second Law of Thermodynamics
The second law of thermodynamics (the entropy law or law of entropy) was formulated in
the middle of the last century by Clausius and Thomson following Carnot's earlier observation
that, like the fall or flow of a stream that turns a mill wheel, it is the "fall" or flow of heat
from higher to lower temperatures that motivates a steam engine. The key insight was that the
world is inherently active, and that whenever an energy distribution is out of equilibrium a
potential or thermodynamic "force" (the gradient of a potential) exists that the world acts
spontancously to dissipate or minimize. All real-world change or dynamics is scen to follow,
or be motivated, by this law. So whereas the first law expresses that which remains the same,
or is time-symmetric, in all real-world processes the second law expresses that which changes
and motivates the change, the fundamental time-asymmetry, in all real-world process.
Clausius coined the term "entropy" to refer to the dissipated potential and the second law, in
its most general form, states that the world acts spontaneously to minimize potentials (or
equivalently maximize entropy), and with this, active end-directedness or time-asymmetry
was, for the first time, given a universal physical basis. The balance equation of the second
law, expressed as S > 0, says that in all natural processes the entropy of the world always
increases, and thus whereas with the first law there is no time, and the past, present, and
future are indistinguishable, the second law, with its one-way flow, introduces the basis for
telling the difference.
The active nature of the second law is intuitively easy to grasp and empirically demonstrate. If
a glass of hot liquid, for example, as shown in Figure 3, is placed in a colder room a potential
exists and a flow of heat is spontaneously produced from the cup to the room until it is
minimized (or the entropy is maximized) at which point the temperatures are the same and all
flows stop.
T'>T
0
AQ; = AOE
Figure 3
A.glass of liquid at temperature TY Is placed in a room at temperature TI! such
that. The disequilibrium produces a field potential that results in a flow of
energy in the form of heat from the glass to the room so as to drain the
potential until it is minimized (the entropy is maximized) at which time
thermodynamic equilibrium is reached and all flows stop. refers to the
conservation of energy in that the flow from the glass equals the flow of heat
Into the room. (From Swenson, 1991a. Copyright 1991 Intersystems
Publications. Adapted by permission)
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Figure 4 shows various other potentials and the flows they would produce. Of important
theoretical interest for this paper is the fact that Joule's experiment (Figure 2) while designed
Figure 4
Further examples of potentials that follow from nonequilibrium distributions of
energy. Whenever energy (in whatever form) is out of equilibrium with its
surroundings, a potential exists for producing change that, following the second
law, Is spontaneously minimized.
show the first law unintentionally demonstrates the second too. As soon as the constraint is
removed the potential produces a flow from the falling weight through the moving paddle
through the thermometer. This is precisely the one-way action of the second law and the
experiment depends upon it entirely. The measurement of energy only takes place through the
lawful flow or time-asymmetry of the second law, and the point to underscore is that the
same is true of every measurement process. In addition, every measurement process also a
demonstrates the first law as well since the nomological relations that hold require something
that remains invariant over those relations (or else one could not get invariant or nomological
results). The first and second laws ate thus automatically given in every measurement process
for the simple fact, in accordance with the discussion above, that they are entailed in every
epistemic act (Swenson, in press a, b; see also Matsuno, 1989, in press on generalized
measurement).
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