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ww SUBJECT: CHEMISTRY ww ww ANSWER KEY ww MARKS ww
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24

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N i . N . etet
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24 i.N.N eteespecially
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N
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d saaslaalairon,aluminium, calcium, d a
d saaslaalacarbon and silicondisadsaused aslaalina
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aslala i aslaa
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N tet
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i N
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w ww
w ionisation w w
w w
isomerism. w ww
w w ww
w ww w
ww ww ww ww ww
An example of this type of isomerism is furnished by the red-violet,
27
i . N . etet 3)5Br]SO4
[Co(NH
N i . N . etet
N [Co(NH3)5iSO . N . 4e
N
tet
]Br i . N . etet
N
i i i i
d a
d saaslaalapentaamminebromocobalt(III)
d a
d saaslaalasulphate
d d saaslaala
pentaamminesulphatocobalt
a d d saaslaala
(III) bromide
a 1 ½ d a
d saaslaa
aa
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w ww
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SHRI VIDHYABHARATHI MAT.HR.SEC.SCHOOL,
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dasasKindly Download ThisdAnswer asaasaKeys From -- www.Padasalai.Net dasas dasas Websites dasas
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i . N . etet
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d a
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29
d
of
a
d
laalin
saasHI a gaseous phase - Opposing
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d saaslaala 1
d adsaaslaa
.P.P aa .P.P aa .P.P aa .P.P aa .P.P aa
w ww
w w ww
w w ww
w w wreaction
w w w w1w
w
ww c) ww
Hydrolysis of diester in the ww
presence of base - Consecutive ww ww
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i . N . e
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N
unchanged in mass and i .
inN . etet
N
chemical composition i . N . etet
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a i
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aslala i a
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aslala i aslaa
a sa a sa a sa a sa a sa
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adad quantity of catalyst.Pis.P
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a i . i . N a i . i . N a i . i . N a i . i . N
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a i a i a i a i
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d
l
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N e tet N e tet N e tet N e tet 1½
. N . N . N . N
a s
31aaslaaliai. a saaslaaliai. a saaslaaliai. a saaslaaliai. a saaslaa
d
aa d d
aa d aad d d
aa d d
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w
ww w ww w w w
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ww 1½
fumaric acid(trans ) is more stable than Maleic acid(cis) because of steric
i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
a
aslala i hindrance a
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a sa a sa a sa a sa a sa
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.phenyl .P.P adad .P.P adad .P.P adad
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32 CN Hte5CH=CH-CHO
6e t : 3-phenyl N eteprop
t - 2 en- 1- al .NN etet N etet 1
a i . i . N a i . i . N a i i . a i . i . N
a sa
l
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a sa
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d
a ad CH3COCH2.CH=CH d
a ad 2 : Pent - 4-ene - 2-one d
a ad d
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w .P.P
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a i .Ni . N Carboxylic acidslagive i .Ni . N effervescencelawith i .Ni . N bi-carbonate ldue a i .Ni . N 1
d a
d s
33aasla l a
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d a saas a l a
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d saas a l a
d a
d saas a l a
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ww w w w w w
acid itw w ester which is identified
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i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
i i i i
a saaslaala
Q.NO
a saaslaala SECTION-IV
a saaslaala a saaslaala MARKS salaa
s
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i . N . eteHydrogen
N t fluoride, iH . N -N
. eF.tet i . N . etet
N i . N . etet
N
a
aslala i a
aslala i a
aslala i a
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Intramolecular adad hydrogen bonding. .P.P adad .P.P adad .P
½w+w ½.Padad
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O-Nitrophenol ww ww ww
34 2 2 3
N tet
ii) eElectronic configuration of
N eteNitrogen
t - 1s 2s 2p
N etet N etet ½
a i . i . N a i . i . N a i . i . N a i . i . N
a sa
l
asal a N 2 molecule - 14
a sa
l
asal a
electrons
a sa
l
asal a
a sa
l
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SHRI VIDHYABHARATHI
alaala i MAT.HR.SEC.SCHOOL,lala i i
alaala -- only. Avoid Duplicate alaalaPagei alaa
dasasKindly Download ThisdAnswer asaasaKeys From -- www.Padasalai.Net dasas dasas Websites dasas
 s aslaalia. i.N a
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d saaslaala d adsaaslaala d a
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a
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l a a i
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asala a i l
asala a i l
asala a i ½ aslaa
d a sa d a d a sa d a sa d a sa
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i .N . etet
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a i a i a i a i
d a
d
l l a
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l l a
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w ww
w w w
w w w w
w w w w
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ww On moving ww down a group both atomic ww and ionic radii increase ww with increasing ww 1
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i . N . e
N i . N . e
N i . N . e
N i . N . etet
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i
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d saaslaala 1 d a
d saaslaa
aa
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.P2.P aa
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w ww
w K19 = (1sw)w w(2s
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i .ZN *N
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N etet i . N . etet
N
a i
aslala(1.00 total numberaofsaaelectrons a i
lala in the inner shells)] a
aslala i a
aslala i aslaa
a sa s a sa a sa a sa
adad
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.(8)
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a i . i . N a i . i . N a i . i . N a i . i . N
a sa
l
asal a Concentration: ore
a sis
a
l
asal a
concentrated by
a sa
l
froth-floatation
asal a process.
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l
asal a ½
a saaslaa
d
a ad d d with NaCN .PP
a aore d d d
a ad d
a ad
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w .P.P
w w . .P
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i . N . etet
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N
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i .N . etet
N i .N . etet
N i .N . etet
N
a i a i a i a i
d a
d
l l a
saasa Electrolytic refining d a
d
l
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d adsaasal l a
d a
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l
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d a
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w w ww
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i . N . etet
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N
i i i i
d a
d saaslaalab) (i) any three points d a
d saaslaala d adsaaslaala d a
d saaslaala d a
d saaslaa
aa
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.P.P aa
.P.P aa
.P.P
w ww
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i . N . etet
N i . N . etet
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N
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N
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N
a i a i a i a i
d a
d
l
saasa l a
d a
d
l
saasa l a
d adsaasal l a
d a
d
l
saasa l a
d a
d saaslaa
aa
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alaala i
SHRI VIDHYABHARATHI MAT.HR.SEC.SCHOOL,
lala i i
alaala -- only. Avoid Duplicate alaalaPagei alaa
dasasKindly Download ThisdAnswer asaasaKeys From -- www.Padasalai.Netdasas dasas Websites dasas
 s aslaalia. i.N www.Padasalai.Net
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wwor released during nuclear w w
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N N i. N . etet
N i . N . etet
N i . N . etet
N
i i i i
d a
d saaslaalaQvalue = (mp-mr) 931 d a
d saaslaala
MeV
d adsaaslaala d ad saaslaala 1
d a
d saaslaa
aa
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.P.P aa
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N e tet N e tet N e tet N e tet
. N . N . N . N
aslaaliab)i. In physical process, laaliai. laaliai. aslaaliai.
than the number of molecules of reactant entropy increases.
a sa a sa aswhen a solid changes a s
toaaliquid,
s when a liquid a sa
changes a saaslaa
adad
.P.P .P.P
dad
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N tet three points
eAny N etet N etet N etet
a i . i . N a i . i . N a i . i . N a i . i . N
a sa
l a
asal i) G is defined as (H-TS) a sa
l a
asal where H and S are the a sa s lal a
aenthalpy and entropy of the
a sa
l
asal a
a saaslaa
d
a ad system respectively. d
a ad T = temperature. Since d
a aHdand S are state functions, d
a adG d
a ad
w .P.P
w w w.P.P w w.P.P w w.P.P w .P.P
w
w
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ii) Gt is an extensive property twhile G = (G2-G1) whichtis the free energy
i N . e et between the initiali.(1)
N
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eand .N . N et becomes the i.N
esystem . etet
N
a i a i a i a i
d a
d
l l a
saasa intensive propertydawhen d
l l a
saasamass remains constant d ad
asal l
sabetween a
initial and finald ad
l
saasa
states
l a
d a
d saaslaa
aa
.P.P a a is a closed system..P.P
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.P aa aa
.P.P aa
.P.P
w ww
w (or) when w ww
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.iv)
N N t G values correspond
eGteand . N etetto the system only. iThere
N . N eteare
N t three cases of .NN etet
i i . i i . i . i i .
d a
d saaslaalaG in predicting dthe a
d
aslaala of the process. When,
sanature d ad
ala (negative), the salaala
saaslaG<0 d ad a s d a
d saaslaa
aa
.P.P .P.P
process is spontaneous aa and feasible; G .P.Pa=a0. The process is in equilibrium aa
.P.P aa
.P.P
w ww
w w www w www w ww
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ww and G ww> 0 (positive), the process wwis nonspontaneous andwnot w feasible. ww
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i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
a
aslala H
i = E + PV and E a
aslala= i
q – w. a
aslala i a
aslala i aslaa
a sa G = q – w +PPV a sa a sa a sa a sa
adad
.P.P . and
. adad– TS
P .P.Padad adad
.P.P adad
.P.P
www w But S ww
=q/Tw w TS = q = heat ww w w
involved in the process. www w www w
ww ww ww ww ww
G = q – w + PV – q = –w + PV
i . N .
(or) ete–G
N t = w – PV = network.
i . N . etet
N i . N . etet
N i . N . etet
N
l a a i
asal The decrease in free l a a i
asal –G, accompanying l al a
asaaprocessi l
asala a i aslaa
d a sa d a saenergy d a sa taking placed a
at sa d a sa
a ad
.P.P .P.P a ad .P.Pa ad a ad
.P.P a ad
.P.P
w w w constantw w w
temperature and pressure is w w w
equal to the maximum obtainable w w w work w w w
www from the
w
wwsystem other than work w
w
ofwexpansion. www www
i
This
N
.(w . etequantity
N t is called as the e
i . N .
tet work” of the systemNand
“net
N i . . eteitt is equal to
N i . N . etet
N
a i a i a i a i
d a
d
l
saasa l a – PV). Net work
d a
d
l l a
saasa = –G = w – PV. d adsaasal l a
d ad
l
saasa l a
d a
d saaslaa
a a 36
.P.P .P.P aa P.Paa
.(OR) aa
.P.P aa
.P.P
w ww
w w ww w w ww w w w
w w www w
ww b) (i)The wweffect of concentration on wwequivalent conductancewcan w be studied ww 1
fromt the plots of  C values versus square root of concentration of the
i . N . e et
N i . N . etebeen
N t
i . N . N
tet
etypes i . N . etet
N
i
electrolyte. By doing so, it i
has found that different i of plots are i
d a
d saaslaalaobtained depending d a
d son
a aalanature of electrolyte.
aslthe
d adsaaslaala d ad saaslaala d a
d saaslaa
aa
.P.P .P.P aa .P.Paa aa
.P.P aa
.P.P
w ww
w w www w www w ww
w wwww
ww For strong
ww electrolytes C decreases wwlinearly with increase in wwC while for weak ww
i . N . etet
electrolytes,
N there is a
i . N . etet
N i . N . etet
N i . N . etet
N
a i
aslalacurve type of non linear a la
asladecreasei of C with aCs.aslala a i a
aslala i 1 aslaa
a sa a sa a a sa a sa
adad
.P.P .P.P adad .P.Padad adad
.P.P adad
.P.P
www w ww w w ww w w www w www w
ww ww ww ww ww
1
e te t e te t e tet e te t
s aslaalia.Ni.N
s as laalia.N i.N
s as laalia.Ni.N
s aslaalia.Ni.N
s aslaa
d a
a ad a d
a ada a d
a ada a d
a ada a d a
a ad a
w .P.P
w w w.P.P w w.P.P w w.P.P w .P.P
w
w
www www w wwww w
www w
www
i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
1
i i i i
saaslaala(ii) pH = -log -2[H d]adsaaslaala saaslaala saaslaala saaslaa
+
d
aa a
d aa aad ad aad ad d
aa a
d
ww.P.P = - log w 10w.P.P ww .P.P ww .P.P w1w.P.P
w
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i . N . etet
N i . N . etet SAKKARAMPALAYAM.
N i . N. N
tet
e99655-31727 i . N . e5tet
N
alaala i
SHRI VIDHYABHARATHI MAT.HR.SEC.SCHOOL,
lala i i
alaala -- only. Avoid Duplicate alaalaPagei alaa
dasasKindly Download ThisdAnswer asaasaKeys From -- www.Padasalai.Net dasas dasas Websites dasas
 s aslaalia. i.N a
www.Padasalai.Net
s slaalia. i.N s aslaalia. i.N www.TrbTnpsc.com ala
s s
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w
ww w w w
wwConcentrated sulphuric acid w w
ww being more powerful acid w w
ww and ww w w
a) (i) a)
i . N . etet
dehydrating
N agent removesN
i . two
. etemolecules
N t of water forming
i . N . etet dioxan.
N i . N . etet
N 2
a i a i a i a i
d a
d
l
saasa l a
d a
d
l
saasa l a
d a
d saasal l a
d a
d
l
saasa l a (Without
d a
d saaslaa
aa
.P.P .P.Paa aa
.P.P aa
.P.P
catalyst aa
1)
.P.P
w ww
w w ww
w w ww
w w ww
w w ww
w
ww ww ww ww ww
i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
a
aslalab) i a
aslala i a
aslala i a
aslala i aslaa
a sa a sa a sa a sa a sa
adad
.P.P .P.Padad adad
.P.P adad
.P.P 2.P.Padad
www w www w www w www w w w
w w
ww ww ww ww ww (Without
catalyst 1)
i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
l
asala a i l
asala a i l
asala a i l
asala a i aslaa
d a sa d a sa d a sa d a sa d a sa
a ad
.P.P .P.Pa ad a ad
.P.P a ad
.P.P .P.Pa ad
w w w w w w w w w w w w w w w
www www www www www
37 i.N . etet
N i .N . etet
N i N
.OCH. etet
N i .N . etet
N
a i a i a i a i
d a
d
l
saasa l a (ii) CH 3 CH 2OH
d
is
a
d
l
saasa
more l a
water soluble than
d
CH
a
d
l
sa3asa 2
CH l a 3
d a
d
l
saasa l a
1 d a
d saaslaa
aa
.P.P Reason : Presence .P.Pa a of H - Bonding in Ethanol aa
.P.P aa
.P.P .P.Paa
w ww
w w ww
w w ww
w w w
w w w w
w w
ww ww ww (OR) ww ww
b) (i)t tet tet tet 1
. N e
N e t . N e
N . N e
N . N e
N
a saaslaaliai. a saaslaaliai. a sa aslaaliai. a saaslaaliai. 1 a saaslaa
d
aa d d
aa d aa d d aad d aad d
ww.P.P ww .P.P ww.P.P ww .P.P ww .P.P
w
ww w ww w w ww w w ww w w w
ww 1 w

i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
a
aslalaii) i a
aslala i a
aslala i a
aslala i 1 aslaa
a sa a sa a sa a sa a sa
adad
.P.P C2H5OC2H5 .+P.2HI Padad 2 C2H5I +.P a2Odad
H.P adad
.P.P .P.Padad
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ww ww ww ww ww
Zeisel’s
tet method of detection and estimation
i . N . ealkoxy
N i . N . etetgroup in natural products
N i . N . etetlike alkaloids.
N i . N . etet
N
a laal a i
of (especially
a
methoxy)
laal a i a laal a i a laal a i 1
aslaa
d a sa s d a sa s d a sa s d a sa s d a sa
a ad
.P.P .P.Pa ad a ad
.P.P a ad
.P.P .P.Pa ad
w w w a) (i) a)w w w w w w w w w w w 2w
www www www www www
i .N . etet
N i .N . etet
N i .N . etet
N i .N . etet
N
a i a i a i a i
d a
d
l
saasa l a
d a
d
l
saasa l a
d a
d saasal l a
d a
d
l
saasa l a 2
d a
d saaslaa
aa
.P.P b) .P.Paa aa
.P.P aa
.P.P .P.Paa
w ww
w w ww
w w ww
w w ww
w w ww
w
ww ww ww ww ww
ii) (CHtet 3)3N < CH3NH2 < (CH3)2NH
tet tet tet 1
. N e
N . N e
N (OR) lalia. i. N e
N . N e
N
a s
38
aaslaaliai. a saaslaaliai. a sa asa a saaslaaliai. a saaslaa
d
aa d b) The propulsion d
aa d
system in most space d d
vehicles
aa consists of rocket d d
engines
aa powered aad d
ww.P.P by chemical ww P.P
.propellants. These alsowcalled ww.P.P rocket propellants.ww ww .P.P w1w.P.P
w
ww w w w
ww are combustible compounds w
ww which on ignition undergo ww rapid ww w w
Propellants
i . N . etet
combustion
N to release large
i . N . etet
quantities
N of hot gases. A.Npropellant
i . etet
N is a combination
i . N . eoftet
N 1
a i
aslalaan oxidiser and a fuel. a
aslala i a
aslala i a
aslala i aslaa
a sa a sa a sa a sa a sa
adad
.P.P Working of a.P . adad : These gases then
P
propellant ad
.P.P ad out through the nozzle
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