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SUMMARY
A two-zone model for the calculation of the closed cycle of a direct injection (DI) diesel engine is presented.
The cylinder contents are taken to comprise a non-burning zone of air and another homogeneous zone in
which fuel is continuously supplied from the injector holes during injection and burned with entrained air
from the air zone. The growth of the fuel spray zone, consisting of a number of fuel–air conical jets equal to
the injector nozzle holes, is carefully modelled by incorporating jet mixing to determine the amount of
oxygen available for combustion. Application of the mass, energy and state equations in each one of the
two zones yields local temperatures and cylinder pressure histories. For calculating the concentration of
constituents in the exhaust gases, a chemical equilibrium scheme is adopted for the C–H–O system of the 11
species considered, together with chemical rate equations for the calculation of nitric oxide (NO). A model
for the evaluation of soot formation and oxidation rates is incorporated. A comparison is made between
the theoretical results from the computer program implementing the analysis, with experimental results
from a vast experimental investigation conducted on a fully automated test bed, direct injection, standard
‘Hydra’, diesel engine located at the authors’ laboratory, with very good results, following a multi-
parametric study of the constants incorporated in the various sub-models. Pressure indicator diagrams and
plots of temperature, NO, soot density and of other interesting quantities are presented as a function of
crank angle, for various loads and injection timings, elucidating the physical mechanisms governing
combustion and pollutants formation. Copyright # 2003 John Wiley & Sons, Ltd.
n
Correspondence to: Professor C. D. Rakopoulos, Thermal Engineering Section, Mechanical Engineering Department,
NTUA, 9 Heroon Polytechniou Str., Zografou Campus, Athens 15780, Greece.
y
E-mail: cdrakops@central.ntua.gr
z
Professor Internal Combustion Engines.
}
Director of I.C. Engines Laboratory.
}
Research assistant.
k
Assistant professor of Combustion.
1. INTRODUCTION
Public concern for maintaining a clean environment has motivated extensive research into the
sources of pollution and ways to reduce it. One such major polluting contributor is the internal
combustion engine, either in the form of spark-ignition (Otto) or Diesel version. In parallel to
the environmental threat posed by these engines (Ferguson, 1986; Rakopoulos, 1991), their
main source of fuel, the crude oil, is being depleted at increasing rates, so that the development
of less polluting and more efficient engines is today of paramount importance for engine
manufacturers (Watson and Janota, 1982; Heywood, 1988; Rakopoulos, 1992). Also, to this end
corroborates the fact of increasing threat posed by the rivals of the internal combustion engine,
for smaller size engines, such as the electric motors, the hybrid engines, the fuel cells and the like
(Ferguson, 1986; Rakopoulos and Kyritsis, 2001).
Experimental work aimed at fuel economy and low pollutants emissions from Diesel (as well
as Otto) engines involves successive changes of each of the many parameters concerned, which is
both very demanding in terms of money and time. With the advent of digital computers, the
obvious alternative is today the simulation of the engine performance by a mathematical model,
where the effect of design and operation changes can be quickly and cheaply estimated by the
use of computers, provided that the main mechanisms are recognized and correctly modelled
(Benson and Whitehouse, 1979; Horlock and Winterbone, 1986; Ferguson, 1986; Heywood,
1988).
The process of diesel combustion is inherently very complex due to the transient and
heterogeneous character of combustion, which is mainly controlled by turbulent mixing of fuel
and air in the fuel jets issuing from the nozzle holes. High speed photography studies and in-
cylinder sampling have revealed some interesting features of combustion (Heywood, 1988). The
first attempts to simulate the diesel engine cycle substituted the ‘internal combustion’ by
‘‘external heat addition’’ (Ferguson, 1986). Apparent heat release rates were empirically
correlated to fuel injection rates and used in a thermodynamic cycle calculation to obtain
cylinder pressure, in a uniform mixture (Austen and Lyn, 1960–61). Models based on droplet
evaporation and combustion, while still in a mono-zone mixture, can only take partially into
account the heterogeneous character of diesel combustion (Whitehouse and Way, 1969–70).
The need for accurate predictions of exhaust emissions pollutants forced the researchers to
attempt developing two-zone combustion models (Khan et al., 1971; Whitehouse and Sareen,
1974; Kouremenos et al., 1989). Eventually, some multi-zone combustion models have appeared
(Shahed et al., 1975; Hodgetts and Shroff, 1975; Hiroyasu et al., 1983; Kouremenos et al., 1987),
carrying the expected drawbacks of the first attempts, where the detailed analysis of fuel–air
distribution permits the calculation of exhaust gas composition with reasonable accuracy, albeit
under the rising of computing time (cost) when compared to lower zones diesel combustion
models.
At this point it should be mentioned that multi-dimensional models are proving useful in
examining problems characterized by the need for detailed spatial information and complex
interactions of many phenomena simultaneously (Butler et al., 1981; Gosman and Harvey,
1982). However, these are limited by the relative inadequacy of sub-models for turbulence,
combustion chemistry and by computer size and cost of operation, to crude approximations to
the real flow and combustion problems (Hiroyasu et al., 1982; Heywood, 1988).
Therefore, it is felt that a reasonable choice seems to be a two-zone model, which includes
the effect of changes in engine design and operation on the details of the combustion
Copyright # 2003 John Wiley & Sons, Ltd. Int. J. Energy Res. 2003; 27:1221–1249
DEVELOPMENT AND VALIDATION OF A COMPREHENSIVE TWO-ZONE MODEL 1223
process, through a phenomenological model where the geometric details are fairly well
approximated by detailed modelling of the various mechanisms involved, along the lines of
recent multi-zone models philosophies (Rakopoulos et al., 1995; Rakopoulos and Hountalas,
1998, 2000). This is going to have the advantage of relative simplicity and very reasonable
computer time cost.
Thus, the object of the present work is the development of a comprehensive two-zone model,
applied for a direct injection (DI) diesel engine, similar in broad outline to others, but with
several differences that one should expect from an independent research group. The present
paper gives a detailed description of such a model, which contains upgraded jet mixing, heat
transfer and chemistry sub-models, incorporating a multi-parametric study of the constants in
the various sub-models needed for increased accuracy. It keeps as simple as possible the
numerical analysis treatment of the governing differential and algebraic equations, thus leading
to good solution convergence with reduced computer time cost. Furthermore, the present work
is extensively verified using data from a vast experimental investigation, conducted at the
authors’ laboratory on a fully automated test bed, four-stroke, water cooled, standard ‘Hydra’,
direct injection, high speed, diesel engine, which offers the ability to have its operating
conditions varied very easily. Plots of pressure, temperatures in the two zones, nitric oxide (NO),
soot density and of other interesting quantities are presented as a function of crank angle (time),
for various loads and injection timings, providing insight into the physical mechanisms
governing combustion and pollutants formation.
The model deals with a bowl-in-piston combustion chamber (DI) into which fuel is injected, in a
predominant radial direction, from a number of holes (four in the present application) drilled
symmetrically on the injector tip. The model includes only those processes occurring during
the portions of compression and expansion strokes, when all valves are closed (closed cycle).
It incorporates the main processes taking place in the cylinder, i.e. the in-cylinder air motion,
the fuel spray development and mixing, the spray impingement on the walls, the turbulent
heat transfer and the chemistry of combustion. The droplets evaporation and the fuel
ignition delay are implicitly taken into account through the combustion sub-model. The fuel
considered is dodecane (C12H26), representing a common fuel for commercial diesel engines.
The main calculation procedure is based on the integration of the first law of thermodynamics
and the perfect gas state equation combined with the various sub-models, for each zone
separately.
Copyright # 2003 John Wiley & Sons, Ltd. Int. J. Energy Res. 2003; 27:1221–1249
1224 C. D. RAKOPOULOS, D. C. RAKOPOULOS AND D. C. KYRITSIS
where dQ is the heat loss to the chamber walls, Mch the charge molecular weight and V the
instantaneous cylinder volume given by,
V ¼ Vc‘ þ ðpD2 =4Þr ½1 þ l1 cos j ðl2 sin2 jÞ1=2 ð3Þ
where Vc‘ is the cylinder clearance volume and l the crank radius to piston rod length ratio.
During combustion and expansion, depending on the number of injector nozzle holes, an
equal number of zones constitute the entire burning section. In this case, apart from the perfect
gas state equation, the first law of thermodynamics for an open system is applied for each zone.
For the surrounding air zone, which only loses mass (air) to the burning zone, the first law is
written as (Benson and Whitehouse, 1979)
dQ ¼ dE þ p dV þ ha dma ð4Þ
while for the burning zone, which gains mass (air) from the air zone and also an enthalpic flow
from the fuel ready to be burned in the time step, the first law becomes
dQ ¼ dE þ p dV ha dma hf dmf ð5Þ
In the above equations, the internal energy E of the mixture is computed by knowing the
instantaneous composition and the specific internal energies of the constituents. The latter ones
are given as fourth order polynomial expressions of the absolute temperature T, including the
enthalpy of formation at absolute zero (Benson and Whitehouse, 1979). Similar expressions are
then derived for specific enthalpies and heat capacities, by applying the simple thermodynamic
relations connecting these quantities for a perfect gas.
Copyright # 2003 John Wiley & Sons, Ltd. Int. J. Energy Res. 2003; 27:1221–1249
DEVELOPMENT AND VALIDATION OF A COMPREHENSIVE TWO-ZONE MODEL 1225
At first, the parameters related to the point of jet break-up are computed. A mean value of
fuel injection rate is used:
m%’ f inj ¼ mf tot =ðz Djinj Þ ð7Þ
j
where index ‘j’ denotes each one of the z sprays and Djinj is the total duration of fuel injection in
degrees crank angle. Then, the mean spray velocity is given by
%’ f inj 6N =ðr‘ F Þ
u%inj ¼ m ð8Þ
j
where F ¼ pD2N =4: Therefore, the mean pressure drop in the nozzle is
Dp ¼ 0:5r‘ ðu%inj =cD Þ2 ð9Þ
where the discharge coefficient cD is taken to be equal to 0.39.
The break-up time tbr is found now by equating the two expressions of Hiroyasu et al. (1980)
correlation before and after tbr, corresponding to the break-up length x=xbr,
qffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
x ¼ 0:39 2Dp=r‘ t for 05t tbr ð10Þ
pffiffiffiffiffiffiffiffiffiffiffiffi
x ¼ 2:95ðDp=ra Þ0:25 DN t for t tbr ð11Þ
so that qffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
tbr ¼ 28:61r‘ DN = ra Dp ð12Þ
where ra is the density of air inside the cylinder just before combustion begins and the break-up
length is, xbr ¼ u% inj tbr :
At this point we take into account the air swirl by modifying the above correlations, by
introducing the air swirl ratio RS=NS/N with NS the cylinder charge rotational speed. Then, the
break-up length with swirl is,
xbrs ¼ xbr ð1 þ p Rs N xbr =30 u% inj Þ1 ð13Þ
and the corresponding break-up time
tbrs ¼ xbrs =u%inj ¼ ðxbrs =xbr Þ tbr ð14Þ
We are now in a position to start our main calculations. At each crank angle step, the fuel
injection rate and the cumulative fuel injected in each spray are, respectively,
m’ f injj ¼ m’ f inj =z and mf injj ¼ mf inj =z ð15Þ
Similarly, the spray tip velocity and the pressure drop across the nozzle are, respectively,
uinj ¼ m’ f injj 6N =ðr‘ F Þ and Dp ¼ 0:5r‘ ðuinj =cD Þ2 ð16Þ
Now we discriminate the following cases, according to the value of time t, for the cases of
no-swirl and of presence of swirl (index s).
For t tbrs:
x ¼ uinj t and xs ¼ xð1 þ pRs N x=30uinj Þ1 ð17Þ
The spray angles are y=0 and ys=0, while the fuel inside the spray is effectively mfj=0.
For t>tbrs:
pffiffiffiffiffiffiffi
x ¼ 2:95ðDp=ra Þ0:25 DN tb and xs ¼ xð1 þ pRs N x=30uinj Þ1 ð18Þ
Copyright # 2003 John Wiley & Sons, Ltd. Int. J. Energy Res. 2003; 27:1221–1249
1226 C. D. RAKOPOULOS, D. C. RAKOPOULOS AND D. C. KYRITSIS
In the above relation, the exponent of time b=0.50 if xs D=2; that is before wall
impingement, while it is taken equal to 0.48 if xs D/2, that is after wall impingement. It is seen
that the same correlations are opted to be used both before and after wall impingement, using
different values for b. Thus, the complexities involved due to uncertainties in modelling the real
physical mechanisms existing in the spray picture after wall impingement are avoided (Khan
et al., 1971; Whitehouse and Sareen, 1974).
The spray angles (in rad) are
rffiffiffiffiffi pffiffiffi! 2
1 ra 3 x
y ¼ 2 arctan 0 4p and ys ¼ y ð19Þ
A r‘ 6 xs
where constant A0 is given by the empirical relation (LN is the nozzle hole length),
A0 =3+0.28(LN/DN).
The mass of entrained air in the spray (of conical shape) is, respectively,
p y 2
maj ¼ tan ra ðx xbr Þ3 ð20Þ
3 2
!2
p ys
majs ¼ tan ra ðxs xbrs Þ3 ð21Þ
3 2
where in the above relations it is considered that the volume taken by the fuel is negligible
against that of the air, as well as the paraboloid part at the base of the cone against that of the
pure cone.
The above relations for the mass entrained apply only in the case where tbrs 5t
ðDjinj =6N Þ þ tbrs : In the case where t > ðDjinj =6N Þ þ tbrs ; one has to subtract from the spray
volume a conical part at the tail (index t) of the spray. Then, the above equations become,
respectively,
p y 2 3 p yt 2
maj ¼ ra tan ðx xbr Þ ra tan ðxt xbr Þ3 ð22Þ
3 2 3 2
p ys 2 p yts 2
majs ¼ ra tan ðxs xbrs Þ3 ra tan ðxts xbrs Þ3 ð23Þ
3 2 3 2
where
pffiffiffiffiffiffiffi
xt ¼ 2:95ðDp=ra Þ0:25 DN ½t ðDjinj =6N Þ tbr bt ð24Þ
is the cone length to be subtracted in the case of no-swirl (for the exponent bt apply the same as
for the exponent b above), while
xts ¼ xt ð1 þ pRs N x=30uinj Þ1 ð25Þ
is the corresponding cone length to be subtracted when swirl exists.
The corresponding spray angles for the tail part of the cone to be subtracted are, respectively,
yt ¼ y and yts ¼ yt ðxt =xts Þ2 ð26Þ
Copyright # 2003 John Wiley & Sons, Ltd. Int. J. Energy Res. 2003; 27:1221–1249
DEVELOPMENT AND VALIDATION OF A COMPREHENSIVE TWO-ZONE MODEL 1227
For the fuel mass which is effectively inside the spray (the fuel starts to be considered inside
the spray only after the break-up length), we have:
mf j ¼ mf injj ðt tbrs Þ=t for t Dfinj =6N ð27Þ
mf injj
mf j ¼ ðt tbrs Þ for Dfinj =6N 5t ðDfinj =6N Þ þ tbrs ð28Þ
ðDfinj =6N Þ
In the above relations, mf inj is the total mass of injected fuel (cumulative) up to the present
crank angle j (time t), which is given by the following expression:
Z j
dmf inj
mf inj ¼ dj ð33Þ
o dj
where ðdmf inj =djÞ is the fuel mass injection rate. Furthermore,
Z j
mf up ¼ mf inj P dj ð34Þ
o
where mf up is the cumulative mass of not yet prepared fuel, N0 is the engine speed (in rps) and
pO2 is the partial pressure of oxygen (in bar) in the zone. Constants K, K0 , x, m and Ered are
evaluated as described in the following section.
Finally, the combustion rate is given by the relations:
dmf b =dj ¼ R if R5P and dmf b =dj ¼ P if R>P ð35Þ
Copyright # 2003 John Wiley & Sons, Ltd. Int. J. Energy Res. 2003; 27:1221–1249
1228 C. D. RAKOPOULOS, D. C. RAKOPOULOS AND D. C. KYRITSIS
pN 2 pO 2 pH 2 O pO 2 pCO pO2
2 2 2 2
pH 2O
pN pH pO
Kp4 ¼ 2 p
; Kp5 ¼ ; Kp6 ¼ ; K p7 ¼ ð36Þ
pH 2 O2 pN 2 pH 2 pO 2
where pi are the partial pressures of the species made non-dimensional with respect to the
standard atmospheric pressure patm ¼ 1 atm:
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DEVELOPMENT AND VALIDATION OF A COMPREHENSIVE TWO-ZONE MODEL 1229
dmsc
¼ Asc msn ðpO2 =pÞp n expðEsc =ðRmol T ÞÞ ð39Þ
dt
where pressures are expressed in bar and masses in kg, dmf is the unburned fuel vapour mass to
be burned in the time step dt and pO2 is the partial pressure of oxygen in the zone.
Therefore, the net soot formation is expressed as follows:
dmsn dmsf dmsc
¼ ð40Þ
dt dt dt
The exponent n, the constants Asf, Asc and the activation energies Esf, Esc in the above
equations are evaluated as described in the following section.
Copyright # 2003 John Wiley & Sons, Ltd. Int. J. Energy Res. 2003; 27:1221–1249
1230 C. D. RAKOPOULOS, D. C. RAKOPOULOS AND D. C. KYRITSIS
f ðEÞ ¼ E2 E1 þ dW dQ ¼ 0
Solve this equation with respect to T2 using the Newton–Raphson numerical method
(McCracken and Dorn, 1964), so that a better estimate of T2 is found.
(1.9) Calculate p2 for the revised value of T2, using the gas state equation at time moments
1 and 2.
(1.10) Repeat steps 5–9 until the error f(E) in the first law equation is negligible.
(1.11) Set conditions at the end of time step (index 2) as initial conditions for the next time
step (new state, index 1) and repeat all steps from 1.2 to 1.10 . Carry on this way, until j2 equals
the value at the start of fuel injection jsoinj.
(1.12) During the jet break-up period there is no combustion, so continue with the
compression phase calculations keeping also track of the fuel injection rate m’ f inj and the
cumulative injected fuel mf inj :
where biu and bib (i=1, . . . , 12) are the number of kmol of constituents (including fuel) per kmol
of wf tot ; at the beginning of the time step.
(2.2) Set conditions at the end of previous time step (old state, index 2) as initial conditions for
the current time step (new state, index 1) for both zones.
(2.3) For crank angle j2=j1+Dj, compute V2 from engine geometry.
(2.4) Calculate the fuel injection rate m’ f inj and cumulative injected fuel mf inj :
(2.5) Calculate the fuel inside each spray mf j and the corresponding entrained air majs :
(2.6) Estimate pressure p2 at the end of the time step, to be checked later on, by assuming
isentropic change (with g=1.35): p2 ¼ p1 ðV1 =V2 Þg :
(2.7) Define a mean temperature at the beginning and end of time step as:
P P P P
biu T1u þ bib T1b aiu T2u þ aib T2b
Tbulk1 ¼ P P ; Tbulk2 ¼ P P ð41Þ
biu þ bib aiu þ aib
where aiu and aib (i =1 , . . . , 12) are the number of kmol of constituents, per kmol of wf tot ;
at the end of the time step. Then, calculate total heat loss dQ for both zones from the
heat loss sub-model of Annand (1963) at conditions: (p1+p2)/2, (Tbulk1+Tbulk2)/2 and
(V1+V2)/2.
Copyright # 2003 John Wiley & Sons, Ltd. Int. J. Energy Res. 2003; 27:1221–1249
DEVELOPMENT AND VALIDATION OF A COMPREHENSIVE TWO-ZONE MODEL 1231
(2.8) Distribute total dQ in the two zones in proportion to their kmol and absolute
temperatures (Shahed et al., 1975):
P P
ð biu Þ T1u þ ð aiu Þ T2u
dQu ¼ P P P P dQ ð42Þ
ð biu Þ T1u þ ð aiu Þ T2u þ ð bib Þ T1b þ ð aib Þ T2b
P P
ð bib Þ T1b þ ð aib Þ T2b
dQb ¼ P P P P dQ ð43Þ
ð biu Þ T1u þ ð aiu Þ T2u þ ð bib Þ T1b þ ð aib Þ T2b
(2.9) Make computations in the unburned zone, as described in a following sub-section.
(2.10) Compute the isenthalpic mixing of the newly incoming air in the burning zone, as
described in a following sub-section.
(2.11) Make computations in the burning zone, as described in a following sub-section.
(2.12) Check temperatures of the two zones. If T2u0, T2b0 are the temperatures calculated up
to the present iteration step and T2u, T2b the same temperatures as found by executing steps
2.9–2.11, then relative errors eu=|(T2u0T2u)/ T2u0| and eb=|(T2b0T2b)/T2b0| must be less than
a specified accuracy, otherwise repeat steps 2.7–2.11 until temperatures convergence.
(2.13) Check volumes of the two zones and change pressure p2 if necessary, since the volume
constraint V2=V2b+V2u must be satisfied, where V2u and V2b were found from steps 2.9 and
2.11, respectively. If relative error ev=|(V2V2bV2u)/V2| is greater than a specified accuracy,
then set a new value in p2 as
p2 ¼ p2 ðV2b þ V2u Þ=V2
and repeat steps 2.7–2.12 until satisfaction of the volume constraint relation.
(2.14) Calculate various useful quantities, such as the gross and net heat release rates as well
as their cumulative values at each step (Heywood, 1988).
(2.15) Repeat steps 2.2–2.14 and carry on this way, until j reaches the EVO event, i.e. the end
of the closed cycle.
where the air loss due to entrainment by the fuel sprays is, wloss ¼ w1u w2u :
Thus, the mixture composition is:
aiu ¼ biu ; for i ¼ 1; . . . ; 12 except 5 and 6
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1232 C. D. RAKOPOULOS, D. C. RAKOPOULOS AND D. C. KYRITSIS
with
a5u ¼ b5u 0:21 wloss and a6u ¼ b6u 0:79 wloss
(3.4) Make a first estimate of T2u considering isentropic change.
(3.5) Calculate the internal energy E2 using its T2u relation and similarly for the heat capacity
cv(T2u) of air.
(3.6) Calculate V2u from the gas state equation,
V2u ¼ wf tot w2u Rmol T2u =p2
(3.7) Calculate the work in the step, dW ¼ 0:5ðp1 þ p2 ÞðV2u V1u Þ
(3.8) Apply the first law of thermodynamics for an open system:
f ðEÞ ¼ E2 E1 þ dW dQu þ wf tot wloss ‘1 ¼ 0
Solve this equation with respect to T2u using the Newton–Raphson numerical method, so that
a better estimate of T2u is found.
(3.9) Repeat steps 3.5–3.8 until the error f(E) in the first law equation is negligible.
3.5. Calculations for mixing air and fuel in the spray zone
Before proceeding with calculations in the burning zone, it is necessary to compute the
isenthalpic mixing of the newly incoming air into the burning zone (Horlock and Winterbone,
1986).
(4.1) Find the new composition which results from mixing wgain (where wgain=wloss) kmol of
entrained air per kmol of wf tot ; taking also into account the addition of dmf b kg of fuel to be
burned in the time step:
bibmix ¼ bib ; for i ¼ 1; . . . ; 12 except 5; 6 and 7
with
b5bmix ¼ b5b þ 0:21 wgain ; b6bmix ¼ b6b þ 0:79 wgain
and
b7bmix ¼ b7b þ ðdmf b =Mf Þ=wf tot
(4.2) Calculate the partial pressure of oxygen at state 1 after mixing, which is needed in the
Whitehouse and Way (1969–70) burning model,
X
pO21 ¼ p1 ðb5bmix =w1bmix Þ with w1bmix ¼ bibmix
the total kmol in the burning zone at state 1 after mixing per kmol of wf tot
(4.3) Calculate enthalpy H1b for the content of the burning zone before the current input of
air, from its relation at the initial temperature T1b.
(4.4) Similarly, calculate enthalpy H1u of the newly entered air of temperature T1u.
(4.5) Estimate temperature T1bmix after mixing, in relation to the kmol:
T1bmix ¼ ðw1b T1b þ wgain T1u Þ=ðw1b þ wgain Þ
(4.6) Calculate enthalpy H1bmix and heat capacity cp ðT1bmix Þ of the burning zone after mixing,
from their T1bmix relations.
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DEVELOPMENT AND VALIDATION OF A COMPREHENSIVE TWO-ZONE MODEL 1233
(4.7) Since isenthalpic mixing is assumed, it holds for the first law:
f ðH Þ ¼ H1bmix H1b H1u ¼ 0
Solve this equation with respect to T1bmix using the Newton–Raphson numerical method, so
that a better estimate of T1bmix is found.
(4.8) Repeat steps 4.6 and 4.7 until the error f(H) in the first law equation is negligible.
(4.9) Calculate the volume of the burning zone after mixing, using the perfect gas state
equation: V1bmix ¼ wftot w1bmix Rmol T1bmix =p1
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1234 C. D. RAKOPOULOS, D. C. RAKOPOULOS AND D. C. KYRITSIS
(5.12) Compute the quantity of NO in the burning zone through the chemical kinetics scheme
described in a previous section, by solving the relevant differential equation for NO with a
fourth-order Runge–Kutta numerical scheme (Conte, 1965), using typically a sub-step of 1/20th
the main time step.
(5.13) Compute the net soot formed in the burning zone through the relevant differential
equations scheme described in a previous section, using a simple Euler scheme (McCracken and
Dorn, 1964; Conte, 1965).
(5.14) Finally, calculate the work for the total change from state 1 (before mixing) to state 2
since this is the real work produced: dW ¼ 0:5ðp1 þ p2 ÞðV2b V1b Þ:
Copyright # 2003 John Wiley & Sons, Ltd. Int. J. Energy Res. 2003; 27:1221–1249
DEVELOPMENT AND VALIDATION OF A COMPREHENSIVE TWO-ZONE MODEL 1235
The engine has a re-entrant bowl-in-piston combustion chamber, with an injector nozzle
having four holes, 0.25 mm diameter each, drilled symmetrically around its tip, forming a spray
cone angle of 1608. The diesel fuel injection pump is fitted with an 11 mm diameter plunger. A
‘‘Bosch’’ injector body is used, which opens at a pressure of 250 bar. A range of 0–408 advance
(static) is provided.
The diesel fuel used has a specific gravity at 158C of 0.834, cetane number of 53, kinematic
viscosity at 208C of 2.95 mm2 s1 and lower calorific value of 43 100 kJ kg1.
Copyright # 2003 John Wiley & Sons, Ltd. Int. J. Energy Res. 2003; 27:1221–1249
1236 C. D. RAKOPOULOS, D. C. RAKOPOULOS AND D. C. KYRITSIS
312.5 ksamples s1 from up to eight differential analogue inputs, also utilizing dual-channel
Direct Memory Access (DMA) operation. It is then appropriate for the recording of high
frequency engine signals, with the added advantage of high signal resolution (much less than
18C A, depending also on the number of simultaneous recorded signals). This high acquisition
rate capability also secures the nearly simultaneous sampling of all input signals.
Control of this high speed acquisition system is achieved by developing a computer code
based on the ‘‘TestPoint’’ control software (Rakopoulos and Mavropoulos, 1999). The resulted
program, specially designed for transient internal combustion engine applications, is an object-
oriented functional code. It allows the direct on-screen selection of the desired values of all
acquisition parameters, namely: engine type (two-stroke or four-stroke); engine speed (in rpm);
desired number of recorded cycles; selection of the acquired channels; sampling interval
(in 8C A).
After the selection of the above values, the resulting sampling rate per channel is displayed on
screen. When acquisition starts, data are initially stored in the computer’s memory. This secures
the continuous gap-free acquisition for the large amount of multi-channel input data. When the
desired amount of engine cycles is recorded, the data are transferred from the memory to a
corresponding file in the hard disk and directly displayed on-screen (as X–Y graphs). Special
warning signs and other secondary options are also available.
A comparison is made in this section between the measured values derived from the
experimental investigation and the ones calculated by the model, so that the model could
be tested performance- and emissionswise. To effect comparison it was necessary to calibrate the
model, following a multi-parametric analysis of the various sub-model constants applied for all
engine operating conditions examined. The tactics followed consisted of the three steps stated
below:
(i) Determine the values of heat transfer correlation constants so that the theoretical and
experimental compression curves best match. The constants b and c are set at their most usual
values b=0.75 and c=3.4 108 W m2 K1 and then a is found as a=0.375. The temperature
of the cylinder walls Tw is taken equal to 450 K.
(ii) Determine the values of the combustion sub-model constants so that maximum
combustion pressure, indicated mean effective pressure and NO concentration in the exhaust,
theoretical and experimental values, best match. The constants x, m, K0 and Ered are set at their
most usual values x=0.33, m=0.4, K0 =1.2 1010 K0.5 bar1deg1 and Ered=16 500 K and then
constant K is found as K=0.035 barm deg1.
(iii) Determine the constants in the net soot formation correlation so that exhaust soot
density, theoretical and experimental values, best match. The following values are found:
Asf=Asc=0.8 and the exponent of pressure in the soot formation equation n=2.5 is found to
better fit the data, instead of the value 1.8 suggested in the original paper. The corresponding
activation energies are set at their usual values, i.e. Esf=30 000 and Esc=50000 kJ kmol1.
The effect of the two major parameters of load and injection timing are examined in this
work, concerning both performance and exhaust emissions. Results are presented at an engine
speed of 2500 rpm, three loads corresponding to 40, 60 and 80% of full load and two static
injection timings of 15 and 208 crank angle before TDC.
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DEVELOPMENT AND VALIDATION OF A COMPREHENSIVE TWO-ZONE MODEL 1237
Figures 1 and 2 show the calculated and experimental pressure (indicator) diagrams at 80% of
full load, at static injection timings of 15 and 208C A BTDC, respectively. In both cases, a very
good coincidence is observed between calculated and experimental values. As expected, the
pressure values during combustion are higher for the higher injection timing case (Heywood,
1988).
Figures 3 and 4 show the calculated temperature crank angle diagrams at 80% of full load, at
static injection timings of 15 and 208C A BTDC, respectively, as provided by the two-zone
model. Each of these diagrams gives the temperature history of the unburned (air) zone, the
burning (spray) zone and the mean state. It is observed a sudden increase in the temperature
of the burning zone with the initiation of combustion, while the temperature of the unburned
zone changes slightly. As expected, the temperature values in the burning zone during
combustion are higher for the higher injection timing case. The high temperatures of the
burning zone are mainly responsible for the formation of NO and soot (Horlock and
Winterbone, 1986).
Figure 5 shows the comparison of calculated and experimental loads, for the three loads and
the two static injection timings examined. A very satisfactory coincidence exists, with all points
lying very close to the bisectrix of the diagram. It is to be noted that in this and some figures to
follow, the three loads examined of 40, 60 and 80% of full load are expressed as indicated mean
effective pressures, i.m.e.p. (in bar). The calculated i.m.e.p. are provided directly by the two-
zone model, while the available experimental brake torque values are firstly converted into
brake mean effective pressures, b.m.e.p., and then expressed as i.m.e.p. values by addition of the
corresponding friction mean effective pressures, f.m.e.p. (Heywood, 1988), which are provided
by the engine manufacturer.
80.00
40.00
20.00
0.00
Figure 1. Calculated and experimental pressure (indicator) diagram, at 80% of full load and a static
injection timing of 158C A BTDC.
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1238 C. D. RAKOPOULOS, D. C. RAKOPOULOS AND D. C. KYRITSIS
100.00
60.00
40.00
20.00
0.00
Figure 2. Calculated and experimental pressure (indicator) diagram, at 80% of full load and a static
injection timing of 208C A BTDC.
3000.00
2000.00
1000.00
0.00
Figure 3. Calculated temperature of the unburned zone, the burning zone and the mean state versus crank
angle, at 80% of full load and a static injection timing of 158C A BTDC.
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DEVELOPMENT AND VALIDATION OF A COMPREHENSIVE TWO-ZONE MODEL 1239
3000.00
2000.00
1000.00
0.00
Figure 4. Calculated temperature of the unburned zone, the burning zone and the mean state versus crank
angle, at 80% of full load and a static injection timing of 208C A BTDC.
10.00
6.00
4.00
Figure 5. Comparison of calculated and experimental indicated mean effective pressures, i.m.e.p.,
for the three loads examined of 40, 60 and 80% of full load and the two static injection timings of 15 and
208C A BTDC.
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1240 C. D. RAKOPOULOS, D. C. RAKOPOULOS AND D. C. KYRITSIS
Figure 6 shows the calculated and experimental peak combustion pressures versus load, for
the two static injection timings examined. It can be observed a very good coincidence between
calculated and experimental values. As is well known for this kind of engines, the peak pressure
increases with either the increase in load or the injection timing (Watson and Janota, 1982).
Figure 7 shows the calculated and experimental indicated efficiency versus load, for the two
static injection timings examined. It is to be noted that the calculated indicated efficiency values
are provided directly by the two-zone model, while the available experimental (brake) fuel
consumption values are firstly converted into brake efficiency values (by also knowing the
experimental brake power and the fuel calorific value) and then expressed as indicated efficiency
from the direct analogy between brake and indicated values for load and efficiency (Ferguson,
1986). It can be observed a very good coincidence between calculated and experimental values.
As is well known, the indicated efficiency increases with decreasing load.
Figure 8 shows the NO concentration history (in ppm) calculated when considering chemical
equilibrium or chemical kinetics conditions, at 80% of full load and a static injection timing of
158C A BTDC. It is seen that when considering chemical kinetics, which is the correct case, the
maximum NO value is lower than the chemical equilibrium case and furthermore that it is
frozen at nearly this value during the expansion phase when temperature drops (Lavoie et al.,
1971).
Figure 9 shows the calculated NO concentration history (in ppm) for various loads and a
static injection timing of 158C A BTDC. It can be seen that NO formation values increase with
increasing load. This is expected since NO formation is favoured for near stoichiometric
conditions towards the lean side, which are approached by the higher loads in a diesel engine,
110.00
SPEED = 2500 rpm
100.00
calculated , st. inj. -20 deg.
experimental , st. inj. -20 deg.
90.00
80.00
70.00
Figure 6. Calculated and experimental peak combustion pressures versus load (expressed as i.m.e.p.), for
the two static injection timings examined.
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DEVELOPMENT AND VALIDATION OF A COMPREHENSIVE TWO-ZONE MODEL 1241
60.00
52.00
48.00
44.00
Figure 7. Calculated and experimental indicated efficiency versus load (expressed as i.m.e.p.), for the two
static injection timings examined.
2000.00
1200.00
NO (ppm)
800.00
400.00
0.00
Figure 8. Nitric oxide (NO) concentration history calculated when considering chemical equilibrium or
chemical kinetics conditions, at 80% of full load and a static injection timing of 158C A BTDC.
Copyright # 2003 John Wiley & Sons, Ltd. Int. J. Energy Res. 2003; 27:1221–1249
1242 C. D. RAKOPOULOS, D. C. RAKOPOULOS AND D. C. KYRITSIS
1000. 00
800.00
LOAD = 40 %
LOAD = 60 %
600.00 LOAD = 80 %
NO (ppm)
400.00
200.00
0.00
Figure 9. Calculated nitric oxide (NO) concentration history, for the three loads of 40, 60 and 80% of full
load and a static injection timing of 158C A BTDC.
and high temperatures (Benson and Whitehouse, 1979). The latter ones are higher the higher the
load.
Figure 10 shows the comparison of calculated and experimental nitric oxide concentration
values at the exhaust, for the three loads and the two static injection timings examined. A very
satisfactory coincidence is observed between calculated and experimental values. As expected,
the NO values increase with increasing load, due to approaching stoichiometric conditions and
getting higher temperatures. By the same token, the NO values are higher for the higher
injection timing case, since then temperatures in the cylinder are higher as seen in Figures 3
and 4 (Khan et al., 1971).
Figure 11 shows the calculated soot density history (in mg m3) for various loads and a static
injection timing of 158C A BTDC. It can be seen that soot density values increase with
increasing load. This is expected since soot formation is favoured under pyrolysis conditions, i.e.
at rich conditions and high temperatures which are approached by the higher loads (Khan et al.,
1972). During the expansion phase, the soot density values fall sharply due to the end of soot
formation and the increase of the total cylinder volume.
Figure 12 shows the comparison of calculated and experimental soot density values at the
exhaust, for the three loads and the two static injection timings examined. A very satisfactory
coincidence is observed between calculated and experimental values. As expected, the values
increase with increasing load, due to approaching richer conditions and getting higher
temperatures. The soot values are lower for the higher injection timing case, since then the
higher temperatures involved in the cylinder have a higher impact on the soot oxidation than
formation (Watson and Janota, 1982).
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DEVELOPMENT AND VALIDATION OF A COMPREHENSIVE TWO-ZONE MODEL 1243
3000.00
SPEED = 2500 rpm
1000.00
0.00
Figure 10. Calculated and experimental exhaust nitric oxide (NO) concentration values versus load
(expressed as i.m.e.p.), for the two static injection timings examined.
1200. 00
800.00
SOOT (mg/m**3)
400.00
0.00
Figure 11. Calculated soot density history, for the three loads of 40, 60 and 80% of full load and a static
injection timing of 158C A BTDC.
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1244 C. D. RAKOPOULOS, D. C. RAKOPOULOS AND D. C. KYRITSIS
160.00
40.00
0.00
Figure 12. Calculated and experimental exhaust soot density values versus load (expressed as i.m.e.p.), for
the two static injection timings examined.
5000. 00
HEAT TRANSFER COEFFICIENT (W/m**2/K)
3000. 00
2000. 00
1000. 00
0.00
Figure 13. Calculated gas heat transfer coefficient versus crank angle, for the three loads of 40, 60 and 80%
of full load and a static injection timing of 158C A BTDC.
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DEVELOPMENT AND VALIDATION OF A COMPREHENSIVE TWO-ZONE MODEL 1245
20.00
12.00
injected
8.00 prepared
reacted
burned
4.00
0.00
Figure 14. Calculated cumulative fuel injected, prepared, reacted and burned versus crank angle, at 80%
of full load and a static injection timing of 158C A BTDC.
Figure 13 shows the variation with crank angle of calculated gas heat transfer coefficient
in the cylinder, for various loads and a static injection timing of 158C A BTDC. As
expected, heat transfer coefficients become very high during the combustion period. They
increase with increasing load, due to higher temperatures in the cylinder (Benson and
Whitehouse, 1979).
Figure 14 gives a sample example of the calculated cumulative fuel injected, prepared, reacted
and burned as a function of crank angle, at 80% of full load and static injection timing of
158C A BTDC. This picture follows closely the description of the fuel burning sub-model
(Whitehouse and Way, 1969–70) exposed in a previous section.
6. CONCLUSIONS
Copyright # 2003 John Wiley & Sons, Ltd. Int. J. Energy Res. 2003; 27:1221–1249
1246 C. D. RAKOPOULOS, D. C. RAKOPOULOS AND D. C. KYRITSIS
parameters of load and injection timing upon cylinder pressures, efficiency, NO and soot
concentration values is well verified for a wide spectrum of variation of these parameters.
It is important to note that the same values of the set of calibration constants of the various
sub-models are used here for all conditions examined, performance- and emissionwise, following
a judicious multi-parametric analysis for their optimum choice.
It is concluded that the analysis model used here predicts the performance and emission
aspects of a DI diesel engine with success and in a theoretically sound way, thus forming a
serious rival to its multi-zone counterpart due to the much lower computer time cost and effort
needed by it.
NOMENCLATURE
ai =number of kmol of species i, at the end of time step, per kmol of fuel to be
injected totally in the cycle
AFR =air–fuel ratio (by mass)
bi =number of kmol of species i, at the beginning of time step, per kmol of fuel to
be injected totally in the cycle
cp =molar specific heat capacity under constant pressure (J kmol1 K1)
cv =molar specific heat capacity under constant volume (J kmol1 K1)
D =cylinder diameter (m)
DN =injector nozzle hole diameter (m)
E =internal energy, (J), or activation energy (J kmol1)
Ered =reduced activation energy (K)
F =surface (m2)
h =specific enthalpy (J kg1)
H =enthalpy (J)
kf =forward reaction rate constant
Kp =chemical equilibrium constant
m =mass (kg)
M =molecular weight (kg kmol1)
N =engine rotational speed (rpm)
p =pressure (Pa)
Q =heat (J)
Ri =one-way equilibrium rate for reaction i
Rmol =universal gas constant, 8314.3 (J kmol1 K1)
Rs =swirl ratio
t =time (s)
T =absolute temperature (K)
u =spray velocity (ms1)
V =volume (m3)
w =number of kmol of cylinder charge or of the contents of each zone, per kmol
of fuel to be injected totally in the cycle
watot =total kmol of air trapped in the cylinder
wf tot =total kmol of fuel to be injected in the cycle
W =work (J)
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DEVELOPMENT AND VALIDATION OF A COMPREHENSIVE TWO-ZONE MODEL 1247
Greek letters
Superscripts
} =mean value
=time derivative
Subscripts
a =air
b =burning zone
br =spray break-up
e =chemical equilibrium
f =fuel
g =gas
i =species number
inj =injected
j =spray number
‘ =liquid fuel
mix =state at the beginning of time step after mixing
O2 =oxygen
s =swirl
sc =soot oxidized
sf =soot formed
sn =soot net
spr =spray
t =spray tail
tot =total
u =unburned zone
up =unprepared
w =wall
0 =initial value
1 =state at the beginning of time step
2 =state at the end of time step
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1248 C. D. RAKOPOULOS, D. C. RAKOPOULOS AND D. C. KYRITSIS
Abbreviations
A =after
B =before
BDC =bottom dead centre
EVO =exhaust valve opening
IVC =inlet valve closing
i.m.e.p. =indicated mean effective pressure
rpm =revolutions per minute
TDC =top dead centre
8C A =degree of crank angle
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