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Article history: High operating temperatures induce a loss of efficiency in solar photovoltaic and thermal panels. This
Received 21 January 2013 paper investigates the use of phase-change materials (PCM) to maintain the temperature of the panels
Accepted 27 February 2013 close to ambient. The main focus of the study is the computational fluid dynamics (CFD) modeling of
heat and mass transfers in a system composed of an impure phase change material situated in the back
Keywords: of a solar panel (SP). A variation of the enthalpy method allows simulating the thermo-physical change
Solar panel
of the material properties. The buoyancy term in Navier–Stokes’ momentum conservation equation is
Operating temperature
modified through an additional term which forces the velocity field to be non-existent when the PCM is
Phase change material
solid. For validation purposes, isotherms and velocity fields are calculated and compared to those from
an experimental set-up. Results show that adding a PCM on the back of a solar panel can maintain the
panel’s operating temperature under 40 ◦ C for 80 min under a constant solar radiation of 1000 W/m2 .
© 2013 Elsevier B.V. All rights reserved.
1. Introduction They absorb or reject heat in the process. The numerical simulation
of PCMs behavior has been extensively researched. Voller et al. [2]
The efficiency of solar panels depends on the three factors: the presented an enthalpy method for coupled convection and diffu-
intensity of the solar radiation flux, the quality of the semiconduc- sion phase change. They later applied their technique to the melting
tor in use, and the operating temperature of the semiconductor cell. of a pure metal [3]. Hu and Argylopoulos [4] made a review of the
The variations of solar radiation cannot be controlled. Therefore, existing mathematical methods to model PCMs melting or solidifi-
the ongoing research focuses either on new material like cop- cation. Bertrand et al. [5] presented a model for PCM melting driven
per, indium diselenium, cadmium tellurium and chalcopyrites, or only by natural convection.
on maintaining low operating temperatures. For photovoltaic (PV) The specific use of PCMs for thermal energy storage (TES) was
panels, high operating temperatures create a drop in the conversion reviewed by Setterwall [6] and Zalba et al. [7]. In buildings, PCMs are
rate of about 0.5%/◦ C over the nominal cell operating temperature being studied for free cooling or to enhance the building’s thermal
of 25 ◦ C [1], as defined by the industry standard STC (Standard Test inertia. Research on this subject mainly deals with PCMs incorpo-
Conditions). In summer, panel’s temperature typically ranges from rated in wallboards [8,9], roofs [10], windows [11], and ventilation
40 to 70 ◦ C which makes a 7.5–22.5% drop in the conversion rate. heat exchangers [12]. A review on these applications can be found
In the same way, the efficiency of solar thermal panels decreases in Tyagi and Buddhi [13], Zhang et al. [14], and Raj and Velraj
mainly because of radiation losses when the operating fluid tem- [15]. Regarding the materials used, paraffin waxes are very good
perature is above ambient. candidates as PCMs for TES applications in buildings because of
To lower the operating temperature, one can either improve the their low temperature of melting and their high heat of fusion.
free cooling on the back of the panel using natural or forced con- Rubitherm GmBH [16] technically graded the paraffin wax RT25
vection, or try to absorb the excess heat by modifying the panel’s by the use of thermo sensors and differential scanning calorimetry
architecture. The latter solution includes the use of PCMs situ- analysis.
ated on the back of solar panels. PCMs are materials that undergo Only a few studies have been specifically devoted to passive
reversible transition of phase depending on their temperature. cooling of solar panels by SP/PCM architectures. The hypothesis
driving the research is simple: when the panel’s temperature rises,
the excess heat must be absorbed until the PCM has completely
melted. When the panel’s temperature decreases, the solidification
∗ Corresponding author at: University of Nice Sophia-Antipolis, J-A Dieudonné
of the PCM should provide additional heat for the operating liquid in
Laboratory, UMR CNRS 7351, 06108 Nice, France. Tel.: +33 492965029;
fax: +33 492965071. solar thermal panels, provide heat to the building or act as an insu-
E-mail addresses: pascalbi@yahoo.fr, phbiwole@unice.fr (P.H. Biwole). lation material. The SP/PCM solution is expected to be very useful
0378-7788/$ – see front matter © 2013 Elsevier B.V. All rights reserved.
http://dx.doi.org/10.1016/j.enbuild.2013.02.059
60 P.H. Biwole et al. / Energy and Buildings 62 (2013) 59–67
Nomenclature
2.2. Mathematical model equation. However, to model the phase transition, the momentum
conservation equation was modified as follows:
2.2.1. Modeling heat transfers
∂u
Over the front plate surface, we considered conduction, convec- + (→ u · ∇ )u = −∇ P + Fb + Fa
− · ∇2u (9)
∂t
tion and radiation heat transfers as shown in Eq. (1). Long wave
radiation with the sky was neglected in the model. where Fb is buoyancy force given by the Boussinesq approximation:
∂T ∂T Fb = −liquid (1 − ˇ(T − Tm ))g (10)
Cp = −k + he (Te − T ) + ˛E(t) (1)
∂t ∂x
and
where ˛ is the aluminum thermal absorptivity and E the solar radi-
ation intensity. The heat transfers diffusion equation applies over Fa = −A(T ) · u
(11)
the PCM, the air layer and the aluminum domains:
with the expression of A(T) inspired from the Carman–Koseny rela-
Cp
∂T
+ ∇ · (−k∇ T ) + Cp u
· ∇T = 0 (2) tion in a porous medium and the expression of ∇ (P) from the
∂t Darcy’s law as presented in [23] and [24]:
The velocity field u in Eq. (2) is given by Navier–Stokes equa-
C(1 − B1 (T ))2
tions for incompressible fluids. To model the changes in PCM RT25 A(T ) = (12)
thermo-physical properties occurring during the phase transition, (B1 (T )3 + q)
we define function B0 as the liquid fraction in the PCM domain. Let If we assume that the flow is laminar:
Tm be the mean melt temperature and T the half range of melt
temperatures: −C(1 − B1 (T ))2
∇ (P) =
·u (13)
⎧ B1 (T )3
⎪ 0, T < (Tm − T )
⎪
⎨ The value of C depends on the morphology of the medium. In this
T − Tm + T
B0 (T ) = , (Tm − T ) ≤ T < (Tm + T ) (3) study, C is given the constant value 105 . This value is chosen arbi-
⎪
⎪ 2T
⎩ trarily high. Constant q is chosen very low in order to make Eq. (12)
1, T > (Tm + T ) valid even when B1 (T) is zero. The value of q was fixed at 10−3 . When
the temperature of the PCM is higher than Tm + T, the PCM is com-
Eq. (3) shows that B0 is zero when the PCM is in solid and 1 when
pletely liquid. Therefore, B1 is 1 and consequently A and Fa are zero.
it is in liquid phase. B0 linearly grows from zero to 1 between the
In this case, the usual momentum conservation equation applies.
two states. To ensure second order continuous differentiability of
During the transition state, 0 < B1 (T) < 1. A(T) increases along with
the liquid fraction over the temperature domain, B0 (T) is approx-
the melting process until the added force Fa becomes greater than
imated by a second order differentiable function B1 . B1 (T) is the
the convection and diffusion terms in Eq. (9). The momentum con-
sixth-degree polynomial whose seven coefficients are calculated
servation equation becomes similar to the Darcy law for fluid flow
using the following conditions:
in porous medium:
B1 (Tm − T ) = 0; B1 (Tm − T ) = 0; B1 (Tm − T ) = 0; B1 (Tm ) = 0.5
(4) K
B1 (Tm − T ) = 1; B1 (Tm − T ) = 0; B1 (Tm − T ) = 0
=−
u ∇ (P) (14)
where B1 and B1 are B1 (T) first and second derivatives. Function where the permeability K is a function of B1 (T). When B1 (T) dimin-
B1 (T) yields the same values as function B0 (T). The only difference ishes, the velocity field also diminishes until it reaches zero when
is that B1 is a second order continuously differentiable function. the PCM becomes completely solid. At that point, the PCM temper-
This scheme helps numerical convergence. B1 is used to model the ature is lower than Tm − T. Therefore, B1 is 0. Eq. (12) shows that
changes in the PCM thermo physical properties as follows: the value of A(T) becomes very high. Consequently, all the terms
(T ) = solid + (liquid − solid ) · B1 (T ) (5) in the momentum conservation equation are dominated by the
added force. The only solution of the Navier–Stokes equations is
k(T ) = ksolid + (kliquid − ksolid ) · B1 (T ) (6) u = 0 which corresponds to a solid medium.
where is the density and k the thermal conductivity of the PCM.
The modeling of the specific heat includes an additional term rep- 2.2.3. Numerical method
resenting the latent heat of fusion absorbed during the melting A 2D finite element model was used. The temperature and pres-
process: sure field were approximated using 2D linear Lagrangian elements
with three degrees of freedom:
Cp (T ) = Cp solid + (Cp liquid − Cp solid ) · B1 (T ) + LF · D(T ) (7)
3
where T= Ni Ti (15)
2 2
e(−T (T −Tm ) )/(T ) i=1
D(T ) = √ (8)
· T 2
3
Tm and its integral is 1. Its main role is to distribute the latent heat To satisfy the Brezzi–Babuska condition [22] an additional
equally around the mean melting point. degree of freedom was used by adding a node at the center of
mass of each triangular element to approximate the velocity field
2.2.2. Modeling of mass and momentum transfers for PCM as shown in Eq. (17) and Fig. 2.
domain
We assumed that the PCM in the liquid phase is a Newtonian
3
Since the use of standard Galerkin mesh might create numerical Table 2
Thermo-physical properties of the PCM used for validation.
instability when the convection term dominates the diffusion term
in Eq. (9), the maximum mesh size was defined using a condition solid = liquid 890 [kg m−3 ]
on the mass mesh Peclet number: Cp solid = Cp liquid 2110 [J kg−1 K−1 ]
LF 1.81 × 105 [J kg−1 ]
ux 1.1 × 10−5 [m2 s−1 ]
Pe = <2 (18) ˇ 3.09 × 10−3 [K−1 ]
ksolid = kliquid 0.182 [W m−1 K−1 ]
where x is the maximum length of mesh cell in a unit 2D sur- g 9.81 [m s−2 ]
Tm 25 [◦ C]
face. The maximum velocity in the PCM tank was experimentally
determined at 10−2 m/s. Therefore, Eq. (18) gives x ≈ 5e−4 m, Pe
was kept lower than 1. Consequently, the maximum mesh size 2.3. Elements of validation
was 4.10e−4 m. The mesh was refined at the borders of the PCM
domain (see Fig. 3). The final mesh had 135 240 elements and As shown in Fig. 4, the experimental set-up consisted of a Plex-
465 857 degrees of freedom. No significant change of the results iglas container without cooling fins and filled with a PCM whose
was observed when using a finer mesh. A Galerkin least-squares thermo-physical properties are listed in Table 2. An air layer was
stabilization method was employed. left at the top of the tank to prevent it from breaking due to the PCM
Fig. 4. Experimental apparatus: (1) phase change material, (2) heat exchangers, (3) PCM intake valve, (4) structure system, (5) flow meter, (6) air intake valve, (7) metal
stand, and (8) insulation material.
P.H. Biwole et al. / Energy and Buildings 62 (2013) 59–67 63
Fig. 7. Comparison of the PIV-measured and simulated velocity on horizontal cross-sections (1), (2), (3) and (4).
3.1. SP/PCM system without cooling fins 3.2. SP/PCM system with cooling fins
The simulated temperature and velocity fields in the SP/PCM The simulated temperature and velocity fields in the SP/PCM
system (e) without cooling fins at different instant times are pre- system (c) with cooling fins at different instants of time are pre-
sented in Figs. 9 and 10. The melted PCM goes upward close to sented in Figs. 11 and 12. There is a circulation of the liquid PCM
the heated aluminum plates, and downward along the solid PCM through the three parts of the container. Convection of the liquid
which is blue colored. The melting process gets accelerated after PCM is observed upward close to the heated panel, and down-
40 min when the melted PCM touches the back plate because it gets ward close to the liquid–solid boundary through the space between
warmer than the melt temperature. Then the remaining solid PCM the fins and the back plate. As shown in Fig. 12, the PCM veloc-
is progressively separated from the back plate and another upward ity close to the front plate increases with time. The velocity is
flow is observed from the bottom of the back plate to the top of 40e−03 m/s when the PCM is completely melted with a mean value
the still solid PCM. The PCM is completely melted after 104 min. At of 18e−03 m/s during the melting process.
this time, the mean temperature of the front plate is 48 ◦ C. After- The Rayleigh number in the liquid PCM was calculated as:
wards its temperature rises more quickly. As shown in Fig. 10, the
mean velocity of the liquid PCM is 7.3e−03 m/s on the front plate,
gˇ(Tplate − Tliquid ) · l3
3.5e−03 m/s on the solid PCM surface, and 1.8e−03 m/s on the back Ra =
·a
plate.
The Rayleigh number in the liquid PCM was calculated as:
where the characteristic length l was taken as the height of each
section of the PCM tank which is 0.04 m at the middle section and
gˇ(Tplate − Tliquid ) · H3
Ra = 0.042 m at the bottom and upper sections. The value of Ra was cal-
·a culated as 5e06 at melt start and 5.3e07 at melt end. In spite of
these medium Rayleigh numbers, the velocity streamlines plot-
where Tplate is the temperature of the left (heated) plate, Tliquid is the ted in Fig. 11 suggest that the flow in each section of the tank
mean temperature of the liquid PCM and a its thermal diffusivity. is weakly turbulent. Like [4], we also numerically observe a sus-
The value of Ra was found equal to 9.5e06 at melt start and 4.8e07 pended solid PCM mass when the melting is nearly over. This is
at melt end. This result is coherent with our initial assumption of a due to the mechanical resistance created by the fin and the liquid
laminar flow and confirms the observation of [4]. PCM under the solid mass.
P.H. Biwole et al. / Energy and Buildings 62 (2013) 59–67 65
Fig. 9. Simulated transient isotherms and velocity fields in the SP/PCM system without cooling fins. H = 132 mm, L = 20 mm.
66 P.H. Biwole et al. / Energy and Buildings 62 (2013) 59–67
Fig. 11. Simulated transient isotherms and velocity fields and streamlines in the SP/PCM system with cooling fins.
Between the first and the second inflexion point, the PCM acts less constant until the PCM has completely melted. The graph for
like an insulation material for the panel and heat transfer is domi- case (b) shows that the simulated panel temperature may be over-
nated by conduction. The second inflexion point indicates the start estimated by more than 20% after 3600 s when conduction only is
of the convection heat transfer which balances conduction heat considered in the numerical model.
transfer in the PCM. The operating temperature remains more or The last inflexion point marks the end of the melting pro-
cess. Heat transfer in the container is dominated by convection.
Afterwards the temperature rises with a smaller slope than at the
beginning of the process when the PCM was completely solid. This is
due to the higher specific heat capacity of the liquid PCM in compar-
ison with the specific heat capacity of the solid PCM. Nevertheless,
the front plate temperature quickly rises toward its maximum since
heat is no longer absorbed by the solid PCM.
Table 4 sky temperature was not included in the numerical model, due
Drop percentage of the panel’s external temperature with respect to time and PCM
to experimental validation difficulties. Despite these limitations,
layout by comparison with case (a).
the observed results remain relevant. Future work should include
(c) (d) (e) experimental validations of this first numerical model using real
After 1 h 56.9% 57.2% 55% solar panels under real climate conditions.
After 2 h 21% 33.3% 36.6%
After 3 h 0% 12.6% 16.6% References