Professional Documents
Culture Documents
107
CHAPTER 12
SOLUTIONS
Solution:
Solution:
Solution:
a. From http://www.gpo.gov/fdsys/search/home.action
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12-2
Given: 590 kg/wk of TCE added, never dumped, drag out = 3.8 L/h, 8 h/d, 5 d/wk
operation, sludge = 1.0% of incoming TCE, density = 1.460 kg/L
Solution:
Evaporation = ?
1% of in
Figures S-10-14: Mass balance
b. Sludge mass
c. Drag out
d. Mass balance
Solution:
GMW of methylene chloride (from Appendix A, Table A-8, note that methylene
chloride = dichloromethane) = 84.93 g/mole
d. Mass balance
Solution:
a. Efficiency
IN OUT
Efficiency 100%
IN
Solution:
a. Write reaction
GMWCa(OH)2 = 74 g/mole
From the reaction in "a" one mole of lime will neutralize two moles of HCl or 1/2
mole of lime will neutralize one mole of HCl or 1/2(0.0137) = 0.006849
moles/min of lime
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12-5
In mg/L
Solution:
a. Write reaction
GMWNaOH = 40 g/mole
GMWH2SO4 = 98 g/mole
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12-6
From the reaction in "a" one mole of sulfuric acid will neutralize two moles of
NaOH or 1/2 mole of sulfuric acid will neutralize one mole of NaOH or
1/2(0.075) = 0.0375 moles/min of sulfuric acid
In mg/L
Given: 1500 L of 5.00% H2SO4 by volume, 1500 L of 5.00% NaOH by weight, Specific
gravity of H2SO4 = 1.841, H2SO4 purity = 96%, NaOH purity = 100%
Solution:
at 96% purity
moles of H2SO4
132,552g
1,352.57moles
98 g mole
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12-7
moles of NaOH
75,000g
1,875moles
40 g mole
So, 2705.14 moles of NaOH are required to neutralize 1352.57 moles of H2SO4
830.14moles H
0.277 mole L
3000L
1
pH log 0.558 or 0.56
0.277
1875
937.5 moles of Na2SO4 formed
2
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12-8
830.14
415.07 moles H2SO4
2
TDS
937.5moles Na 2SO 4 142 g mole 415.07moles H 2SO 4 98 g mole
3000L
Solution:
Solution:
a. First step
NaCN O 3 NaCNO O 2
b. Second step
2NaCNO O3 H 2 O 2NaHCO3 N 2
Solution:
Solution:
a. Reaction
Cu 2OH CuOH2
c. Ksp equation
12
2 10 19
OH
1.3 mg L 10 g mg 63.54 g mole
3
e. Estimate of pH
pOH = 8.81
Solution:
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12-10
Zn 2.6 mg L
3.98 10 5 mole L
65.4 10 mg mole
3
d. Calculate pH
Zn Ca OH2 ZnOH2 Ca
GMWZn = 65.4
GMWCa(OH)2 = 74
Zinc to be removed
Moles to me removed
47.4 mg L
7.25 10 4 mole L
65.4 10 3 mg mole
Dose of lime
Given: 1.0 m3/d of metal plating sludge with solids concentration of 4%; filter press
yields solids concentration of 30%; dryer yields solids concentration of 80%.
Solution:
V2 P1 V2 0.04
3
V1 P2 1.0 m d 0.30
V2 = 0.133 m3/d
b. Dryer volume
V2 0.30
3
0.133 m d 0.80
V2 = 0.05 m3/d
Solution:
a. The concentration of Fe-CN is the mass of Fe-CN divided by the mass per unit volume
of solids. If the Fe-CN is part of the precipitate, then the reduction in solids volume
will increase the Fe-CN concentration.
(Fe-CNin)(Qin) = (Fe-CNout)(Qout)
Fe CN out
400 mg
kg 1.0 m 3 d
3000 mg kg
0.133 m 3 d
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12-12
Solution:
6000 3.33 8.206 10 5 298 6000
1 8.069
ln
1.5
60 6.74 10 3
1.5
46.787m 3
A 7.798m 2
6m
d. Calculating a diameter
47.798
12
d 3.15m
NOTE: other column height/diameter combinations are possible within the constraints
that ZT < 6 m and d < 4 m
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12-13
Solution:
440 0.22 8.206 10 5 293 440
1 7.66
ln
0.2
15 100 10 4
0.2
129.4m 3
A 21.566m 2
6m
c. Calculating a diameter
421.566
12
d 5.24m
4.0
2
A 12.566m 2
4
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12-14
129.4m 3
ZT 10.29m
12.566m 2
This is too tall for one column but two columns in series each with a height of
5.15 m would work. NOTE: other column height/diameter combinations are
possible within the constraints that ZT < 6 m and d < 4 m.
Solution:
Molar rate =
7.13 kg s10 3 g kg 396.11mole s
18 g mole
1000 g/m
3
C1
35 g/m
3
C2
3
Hc 6.44E-03 m - atm/mole
o
Tg 20 C = 293.15 K
3
R 8.21E-05 atm-m /mole-K
KLa 1.60E-02 s
3
Mw 55600 moles/m
L 396.11 moles/s
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12-15
Compute H'
H' = 2.68E-01
Compute Rsf
Rsf = 5.4067792
For the following diameters with air flow rate = 8000 mole/s
Z
0.5 m 10.5 m Too tall for specification
2.0 m 0.66 m Columns are normally have Z>dia. This height is not very practical
3.0 m 0.24 m Columns are normally have Z>dia. This height is not very practical
4.0 m 0.14 m Columns are normally have Z>dia. This height is not very practical
Solution:
58.7
Equivalent weight = 29.35 mg meq
2
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12-16
55 mg L
C0 1.87 meq L
29.35 mg meq
100
y = 20.183e-3.1502x
10
C/C(o)-1
0.1
-0.5 0 0.5 1 1.5 2
Volume [L]
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12-17
b= ln 20.18 = 3.00
f. Calculate k
7.68 L d
k 3.1502 12.94 L d meq
1.87 meq L
h. Calculate q0
q0
3.007.68 0.4125 meq mg
12.944.316
i. Now calculate the mass of resin for the full scale system
Using the influent and allowable effluent concentrations, calculate the left hand
side of Equation 10-27
55
ln 1 3.00
2.6
V = (36,000)(5) = 180,000 L
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12-18
Solution:
108
Equivalent weight = 108 mg meq
1
10 mg L
C0 0.0926 meq L
108 mg meq
10000.00
1000.00
y = 7773.2e-6.8937x
100.00
C/C(o)-1
10.00
1.00
0.10
0.01
-0.5 0 0.5 1 1.5 2
Volume [L]
Figure S-12-21: Silver ion exchange
b = ln 7773 = 8.96
f. Calculate k
4.523 L d
k 6.89L1 336.54 L d meq
0.0926 meq L
h. Calculate q0
q0
8.964.523 0.0241meq mg
336.545.00
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12-20
i. Now calculate the mass of resin for the full scale system
Using the influent and allowable effluent concentrations, calculate the left hand
side of Equation 12-5
10
ln 1 3.7054
0.24
V = (3,600)(5) = 18,000 L
M = 7.10 x 104 g or 71 kg
Given: Ca = 107 mg/L as ion, Mg = 18 mg/L as ion, data on size of pilot column
Solution:
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12-21
107 mg L
5.35 meq L
20.0 mg meq
18 mg L
1.48 meq L
12.15 mg meq
1000000.0
y = 1E+06e-3.9481x
100000.0
10000.0
C/C(o)-1
1000.0
100.0
10.0
1.0
0.1
-1 1 3 5
3
Volume [m ]
Figure S-12-22: Hardness ion exchange
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12-22
b = ln (1 x 106) = 13.82
h d 10
2.25 L h6.24 m3 L
3
1
k 3.95 m 3 3.12 10 2 L d meq
83 meq L
q0
13.822.25 L h 24 h d 7.24 10 3 meq
3.12 10 2 L d meq 3.30kg kg
Using the influent and desired effluent concentrations, calculate the left hand side
of equation 10-27. Begin by converting 10 mg/L as CaCO3 to meq/L. The
equivalent weight of CaCO3 is 50 mg/meq.
10 mg L as CaCO 3
0.20 meq L
50 mg meq
Then
6.83
ln 1 3.50
0.20
3.12 10
L d meq 7.24 10 3 meq kg M
2
3.96 10 4 kg 1 M
570 m 3 d 10 3 L m 3
Where M is the unknown quantity of resin. Note the units conversions.
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12-23
3.12 10 2
L d meq 6.83 meq L 34,200m 3
12.79
570 m 3 d
M = 41,136 or 41,000 kg or 41 Mg
Given: Trichloroethylene = 18.9 m3; 1,1,1 Trichloroethane = 5.3 m3; Toluene = 21.3 m3,
o-Xylene = 4.8 m3
Solution:
Trichloroethylene
1,1,1 Trichloroethane
Toluene
o-Xylene
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12-24
Trichloroethylene
106.5
chlorine fraction = 0.811
131.29
1,1,1 Trichloroethane
106.5
chlorine fraction = 0.798
133.41
Toluene
contains no chlorine
o-Xylene
contains no chlorine
Trichloroethylene
1,1,1 Trichloroethane
Toluene
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12-25
o-Xylene
Total mass
d. Compute % chlorine
%Cl
0.81127,896.4 0.7987,096.7 100
57,683.03
The operator cannot achieve 30% chlorine by mixing these waste quantities.
Solution:
Carbon tetrachloride
Hexachlorobenzene
Pentachlorophenol
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12-26
Carbon tetrachloride
142.0
Chlorine fraction = 0.923
153.82
Hexachlorobenzene
213.0
Chlorine fraction = 0.748
284.79
Pentachlorophenol
177.5
Chlorine fraction = 0.667
266.34
Carbon tetrachloride
Hexachlorobenzene
Pentachlorophenol
Total mass
d. Compute % chlorine
%Cl
0.92319,446.8 0.748240,072.3 0.6674,945 0.759
264,464.1
%Cl = 75.9 %
The chlorine fraction of the combination must be 30%, so the weighted fraction would be
0.759264,464.1 0.0 M CH3OH
Chlorine fraction = 0.30
264,464.1 M CH3OH
MCH3OH = 404,630 kg
404,630kg
V 51.135 or 51 m3
7,913 kg m 3
Given: Methylene chloride concentration = 5,858 mg/L, flow rate of aqueous stream =
40.5 L/min
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12-28
Solution:
Given: Methylene chloride concentration = 211.86 g/L, flow rate of flue gas = 597.55
m3/min
Solution:
Solution:
237.25 0.1266
DRE 100 99.947%
237.25
Given: mass flow into incinerator = 481 kg/h, mass flow in stack = 72.2 g/h
Solution:
481 0.0722
DRE 100 99.985%
481
Given: Incinerator operating conditions and stack gas concentrations after APC
equipment
Solution:
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12-29
2249 g min
molar flow = 15.298 mole min
147.01g mole
Hydrogen Chloride
1,2 Dichlorobenzene
Hydrogen Chloride
without APC
with APC
c. Compliance computations
2249 0.136
DRE 100 99.994 Passes
2249
HCl
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12-30
After the APC the emission is 31.03 g/min. This exceeds the 1% limit. Therefore
the incinerator fails to comply with the HCl limits.
Particulates
The limit is 180 mg/dscm, therefore the incinerator emission of 181.6 mg/dscm
fails to comply with the particulate limits.
Given: Temperature = 1,100 oC, Qstack = 5.90 dscm/s, 10% oxygen, assume chlorine =
HCl, inlet and outlet emissions
Solution:
a. Calculate DRE’s
Benzene
913.98 0.2436
DRE 100 99.9733% Fails
913.98
Chlorobenzene
521.63 0.0494
DRE 100 99.9905% Passes
521.63
Xylenes
1378.91 0.5670
DRE 100 99.9589% Fails
1378.91
b. Calculate HCl
Emission rate of 4.85 kg/h exceeds emission limit of 1.8 kg/h. Now check % removal:
Inlet HCl
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12-31
= 169.24 kg/h
Removal efficiency
169.24 kg h 4.85 kg h
100 97.13%
169.24 kg h
c. Particulate emissions
14
Pc 499.53 635.76 mg m
3
21 10
Given: Incinerator operating conditions and stack gas concentrations after APC
equipment
Solution:
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12-32
2952 g min
molar flow = 22.485 mole min
131.29 g mole
Hydrogen chloride
2678 g min
molar flow = 20.07 mole min
133.41g mole
Hydrogen chloride
Hydrogen chloride
Trichloroethylene
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12-33
1,1,1 Trichloroethane
Toluene
HCl
without APC
with APC
c. Compliance computations
2952 0.0918
DRE 100 99.9968% Passes
2952
2678 0.190
DRE 100 99.9929% Passes
2678
1733.8 0.0151
DRE 100 99.9991% Passes
1733.8
HCl
After the APC the emission is 44.928 g/min. This is less than the 1% limit.
Therefore the incinerator complies with the HCl limits.
Particulates
The limit is 180 mg/dscm, therefore the incinerator emission of 123.4 mg/dscm
complies with the particulate limits.
Given: Incinerator operating conditions and stack gas concentrations after APC
equipment
Solution:
20,430 g min
molar flow = 71.74 mole min
284.79 g mole
Hydrogen chloride
25,754 g min
molar flow = 96.69 mole min
266.34 g mole
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12-35
Hydrogen chloride
Hydrogen Chloride
Hexachlorobenzene
Pentachlorophenol
Acetone
HCl
without APC
with APC
c. Compliance computations
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12-36
20,430 0.2889
DRE 100 99.9986% Passes
20,430
25,754 0.5998
DRE 100 99.9977% Passes
25,754
10,286 0.04758
DRE 100 99.9995% Passes
10,286
HCl
After the APC the emission is 141.37 g/min. This is less than the 1% limit.
Therefore the incinerator complies with the HCl limits.
Particulates
14
Pc 123.4 246.8
21 14
The limit is 180 mg/dscm, therefore the incinerator emission of 246.8 mg/dscm
fails to comply with the particulate limits.
Given: Retention time required = 1.0 h, diameter = 3.00 m, length = 6.00 m, slope =
2.00%, peripheral speed = 1.5 m/min
Solution:
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12-37
b. Slope
c. Time
0.196.00m 3.00m
t 119.4 min
0.02 m m0.159 rev min
This is > 1 hour so permit conditions have been met.
Solution:
5.0cm
2
A 19.64cm 2
4
QL
t
khAt
t
100.0cm 10cm
3
58.95 or 60 d
10 7
cm s 100cm 19.64cm 86400 s d
2
Solution:
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12-38
Note: there are many solutions that will work. I chose to double head to 2 m.
QL
t
khA
b. Area of sample
5.0cm
2
A 19.64cm 2
4
c. Solve for t
t
100.0cm 10cm
3
29.5d
10 7
cm s 200cm 19.64cm 86400 s d
2
Solution:
10.0cm
2
A 78.54cm 2
4
0.1cm
2
a 0.007854cm 2
4
2.30.00785425 100 9
K log 2.86 10 cm s
78.541,209,600 25
The nominal permeability acceptable for a hazardous waste landfill is 10-7 cm/s. Thus,
this is excellent.
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12-39
Solution:
b. Calculate flow
Solution:
SOIL A
a. Hydraulic gradient
H T 0.3m 3m
i 1.10
T 3m
b. Darcy velocity
c. Seepage velocity
1.98 10 7 cm s
v' 3.60 10 7 cm s
0.55
d. Travel time
t
3.0m100 cm m
3.60 10 7 cm s86400 s d 9645d
SOIL B
a. Hydraulic gradient
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12-40
H T 0.3m 3m 10m
i 1.33
T 10m
b. Darcy velocity
c. Seepage velocity
2.93 10 5 m s
v' 1.17 10 4 m s
0.25
d. Travel time
t
10.0m
1.17 10 m s86400 s d 0.99d
4
SOIL C
a. Hydraulic gradient
b. Darcy velocity
c. Seepage velocity
1.12 10 4 mm s
v' 3.19 10 4 mm s
0.35
d. Travel time
t
12.0m1000 mm m 435d
3.19 10 4 mm s86400 s d
TOTAL TIME
Given: PQL for trichloroethylene = 5 g/L, 0.12 m3 barrel leaks to ground water
Solution:
1.7712 1011 g
35,424,000 or 3.54 x 107 m3
5 g L 10 L m
3 3
12-40 Travel time with retardation
Given: Hydraulic gradient = 8.6 x 10-4, hydraulic conductivity = 200 m/d, porosity =
0.23, retardation factor = 2.3
Solution:
v 0.172
v' 0.748 m d
n 0.23
v' 0.748 m d
v' R 0.325 m d
R 2.3
d. Travel time
dis tan ce 100m
t 307.55 or 308 d
speed 0.325 m d
12-41 Pumping rate for purge well
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12-42
Given: Depth of unconfined aquifer = 60.00 m, permeability = 6.4 x 10-3 m/s, plume
depth at 130 m from center of leak is 0.1 m and plume does not extend beyond
150 m.
Solution:
Computing h1 and h2
Q
6.4 10 3 m s 60.00m 59.90m
2 2
1.68 m 3 s
150
ln
130
Given: 0.12 m3 of CCl4, K = 7 x 10-4 cm/s, n = 0.38, GWT = 3.0 m, i = 0.002, aquifer =
28 m, Qw = 0.014 m3/s
Solution:
Q 0.014 m 3 s
357.14 or 360 m
D( v) 28.0m 1.40 10 6 m s
12-43 Location of well
Solution:
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12-43
x sp
0.014 m s3
228.0m 1.40 10 6
ms 56.8 or 57 m
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12-44
DISCUSSION QUESTIONS
Solution:
Times Beach residents suffered from a dual disaster of hazardous waste and flood. The
dioxin and PCB contaminated soil resulted in the EPA recommending the town to be
abandoned. Most of the residents were left homeless, without jobs and with fear of how
the contamination would affect their health. The town was destroyed and the residents of
it with little hope for the future.
Solution:
The LD50 toxicity is based on oral intake for a particular species. This statement may be
misleading if it is assumed to be the same for humans, the route of exposure is not orally,
and because toxicity may manifest itself in forms other than death, i.e the slope of the
dose-response curve may yield greater effects at lower doses but have a higher LD50.
Solution:
He cannot accumulate for 6 months. The time limit for accumulation of a hazardous
waste is 90 days.
From http://www.gpo.gov/fdsys/search/home.action
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12-45
Given: Does "land ban” actually ban the disposal of hazardous waste?
Solution:
The "land ban” only prohibits land disposal of hazardous waste if there are no
concentration levels or methods of treatment of waste established by EPA. A better term
is "Land Disposal Restrictions (LDR).
Solution:
This is correct because CERCLA and courts have established strict, joint, and several
liability.
Solution:
The best first step is to prevent the generation of pollution in the first place. Waste
exchange and then recycling are logic follow-on steps.
Solution:
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may be displayed, reproduced or distributed in any form or by any means, without the prior written permission of
the publisher, or used beyond the limited distribution to teachers and educators permitted by McGraw-Hill for their
individual course preparation. If you are a student using this Manual, you are using it without permission.
12-46
Solution:
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may be displayed, reproduced or distributed in any form or by any means, without the prior written permission of
the publisher, or used beyond the limited distribution to teachers and educators permitted by McGraw-Hill for their
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