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Product name Formaldehyde solution about 37% stabilized with about 10% methanol
Ph Eur,BP,USP
REACH Registration Number This product is a mixture. REACH Registration Number see section 3.
1.2 Relevant identified uses of the substance or mixture and uses advised against
1.4 Emergency telephone Please contact the regional company representation in your country.
number
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 1 of 25
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
For the full text of the H-Statements mentioned in this Section, see Section 16.
Hazard pictograms
Signal word
Danger
Hazard statements
H350 May cause cancer.
H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H335 May cause respiratory irritation.
H341 Suspected of causing genetic defects.
H370 Causes damage to organs (Eyes).
Precautionary statements
Prevention
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 2 of 25
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Signal word
Danger
Hazard statements
H350 May cause cancer.
H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H341 Suspected of causing genetic defects.
H370 Causes damage to organs (Eyes).
Precautionary statements
P201 Obtain special instructions before use.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P308 + P310 IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 3 of 25
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
3.2 Mixture
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Page 4 of 25
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
For the full text of the H-Statements mentioned in this Section, see Section 16.
After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply
artificial respiration, if necessary also oxygen.
In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/
shower. Call a physician immediately.
After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove
contact lenses.
After swallowing: immediately make victim drink water (two glasses at most). Call a physician
immediately. Risk of perforation!
4.2 Most important symptoms and effects, both acute and delayed
Irritation and corrosion, Allergic reactions, Cough, Shortness of breath, inebriation, Dizziness,
Headache, Drowsiness, agitation, spasms, Impairment of vision, narcosis, Coma
Risk of blindness!
4.3 Indication of any immediate medical attention and special treatment needed
Mention methanol.
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 5 of 25
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Further information
Remove container from danger zone and cool with water. Prevent fire extinguishing water from
contaminating surface water or the ground water system.
Hygiene measures
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and
face after working with substance.
Storage conditions
Tightly closed. Protected from light. Keep in a well-ventilated place. Keep locked up or in an area
accessible only to qualified or authorised persons.
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Page 7 of 25
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Methanol (67-56-1)
Worker DNEL, acute Systemic effects dermal 40 mg/kg Body weight
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Page 8 of 25
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Methanol (67-56-1)
PNEC Fresh water 154 mg/l
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Page 9 of 25
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Engineering measures
Technical measures and appropriate working operations should be given priority over the use of
personal protective equipment.
Eye/face protection
Tightly fitting safety goggles
Hand protection
full contact:
Glove material: Nitrile rubber
Glove thickness: 0,40 mm
Break through time: > 480 min
splash contact:
Glove material: polychloroprene
Glove thickness: 0,65 mm
Break through time: > 240 min
The protective gloves to be used must comply with the specifications of EC Directive
89/686/EEC and the related standard EN374, for example KCL 730 Camatril® -Velours (full
contact), KCL 720 Camapren® (splash contact).
The breakthrough times stated above were determined by KCL in laboratory tests acc. to EN374
with samples of the recommended glove types.
This recommendation applies only to the product stated in the safety data sheet<(>,<)> supplied
by us and for the designated use. When dissolving in or mixing with other substances and under
conditions deviating from those stated in EN374 please contact the supplier of CE-approved
gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 10 of 25
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Respiratory protection
required when vapours/aerosols are generated.
Recommended Filter type: filter ABEK
The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective
devices are carried out according to the instructions of the producer. These measures have to be
properly documented.
Form liquid
Colour colourless
Odour stinging
pH 2,8 - 4,0
at 20 °C
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Page 11 of 25
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Flash point 62 °C
Method: c.c.
Water solubility at 20 °C
soluble
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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Stabilizer
Methanol
Nitromethane, performic acid, Acids, phenol, Nitric acid, hydrogen peroxide, peracetic acid,
nitrogen dioxide
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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Symptoms: If ingested, severe burns of the mouth and throat, as well as a danger of perforation
of the oesophagus and the stomach.
Symptoms: mucosal irritations, Cough, Shortness of breath, Inhalation may lead to the formation
of oedemas in the respiratory tract., Possible damages:, damage of respiratory tract
Acute toxicity estimate: 6,55 mg/l; 4 h ; vapour
Calculation method
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 14 of 25
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Skin irritation
Mixture causes burns.
Eye irritation
Mixture causes serious eye damage. Lacrimal irritation due to vapours. Risk of blindness!
Sensitisation
Mixture may cause an allergic skin reaction.
Carcinogenicity
This information is not available.
Reproductive toxicity
This information is not available.
Teratogenicity
This information is not available.
CMR effects
Carcinogenicity:
Possible carcinogen.
Mutagenicity:
Evidence of genetic defects.
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 15 of 25
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Aspiration hazard
This information is not available.
Components
formaldehyde
Acute oral toxicity
LD50 Rat: 100 mg/kg
(Lit.)
Methanol
Acute oral toxicity
LDLO human: 143 mg/kg
(RTECS)
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 16 of 25
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Skin irritation
Rabbit
Result: No skin irritation
(ECHA)
Eye irritation
Rabbit
Result: No eye irritation
(ECHA)
Sensitisation
Sensitisation test: Guinea pig
Result: negative
Method: OECD Test Guideline 406
Subacute toxicity
Rat
male and female
Inhalation
365 d
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
daily
NOAEL: 0,13 mg/l
LOAEL: 1,3 mg/l
OECD Test Guideline 453
Genotoxicity in vitro
Ames test
Salmonella typhimurium
Result: negative
Method: OECD Test Guideline 471
Mixture
12.1 Toxicity
No information available.
12.2 Persistence and degradability
No information available.
12.3 Bioaccumulative potential
No information available.
12.4 Mobility in soil
No information available.
12.5 Results of PBT and vPvB assessment
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 18 of 25
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Substance(s) in the mixture do(es) not meet the criteria for PBT or vPvB according to Regulation
(EC) No 1907/2006, Annex XIII, or a PBT/vPvB assessment was not conducted.
12.6 Other adverse effects
Additional ecological information
Caustic even in diluted form. Disinfectant effect. Endangers drinking-water supplies if allowed
to enter soil and/or waters in large quantities.
Discharge into the environment must be avoided.
Components
formaldehyde
Substance does not meet the criteria for PBT or vPvB according to Regulation (EC) No 1907/2006, Annex XIII.
Methanol
Toxicity to fish
flow-through test LC50 Lepomis macrochirus (Bluegill sunfish): 15.400 mg/l; 96 h
US-EPA
Toxicity to algae
static test EC50 Pseudokirchneriella subcapitata (green algae): ca. 22.000 mg/l; 96 h
OECD Test Guideline 201
Toxicity to bacteria
static test IC50 activated sludge: > 1.000 mg/l; 3 h
Analytical monitoring: yes
OECD Test Guideline 209
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 19 of 25
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
(External MSDS)
Biodegradability
99 %; 30 d
OECD Test Guideline 301D
Readily biodegradable
Ratio BOD/ThBOD
BOD5 76 %
Closed Bottle test
Substance does not meet the criteria for PBT or vPvB according to Regulation (EC) No 1907/2006, Annex XIII.
Stability in water
2,2 yr
reaction with hydroxyl radicals (IUCLID)
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 20 of 25
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
14.3 Class 8
Not relevant
14.3 Class 8
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Page 21 of 25
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
14.3 Class 8
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not relevant
SEVESO III
Methanol
22
Quantity 1: 500 t
Quantity 2: 5.000 t
Occupational restrictions Take note of Dir 94/33/EC on the protection of young people at
work. Observe work restrictions regarding maternity protection in
accordance to Dir 92/85/EEC or stricter national regulations where
applicable.
Substances of very high concern (SVHC) This product does not contain substances
of very high concern according to
Regulation (EC) No 1907/2006 (REACH),
Article 57 above the respective regulatory
concentration limit of ≥ 0.1 % (w/w).
National legislation
Storage class 6.1C
A Chemical Safety Assessment has been carried out according to regulation (EC) No.
1907/2006 (REACH) for this substance.
Training advice
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 23 of 25
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Labelling
Hazard pictograms
Signal word
Danger
Hazard statements
H227 Combustible liquid.
H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H335 May cause respiratory irritation.
H341 Suspected of causing genetic defects.
H350 May cause cancer.
H370 Causes damage to organs (Eyes).
Precautionary statements
Prevention
P201 Obtain special instructions before use.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
Response
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P308 + P310 IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 24 of 25
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Further information
Key or legend to abbreviations and acronyms used in the safety data sheet
Regional representation
This information is given on the authorised Safety Data Sheet for your country.
The information contained herein is based on the present state of our knowledge. It characterises the product with
regard to the appropriate safety precautions. It does not represent a guarantee of any properties of the product.
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
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