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Gaseous State 257

1. Same mass of CH 4 and H 2 is taken in container. (a) 1.21 / 1 (b) 1.46 / 1


The partial pressure caused by H 2 is[IIT 1989; CPMT 1996] (c) 1.14 / 1 (d) 4 / 1
7. Which of the following volume (V) – temperature
(a) 8 / 9 (b) 1 / 9
(T) plots represents the behaviour of one mole of
(c) 1 / 2 (d) 1 an ideal gas at one atmospheric pressure[IIT Screening 200

2. The following graph illustrates [JIPMER 2000]


V(L) V(L)
(36.8 (28.6
(22.4 L (22.4 L
L 373 K) L 373 K)
V
273 K) 273 K)
(a) (b)

T(K) T(K)
Temp.
(oC) V(L) V(L)
(30.6
(a) Dalton's law (b) Charle's law (22.4 L (22.4
L 373 K) L
(c) Boyle's law (d) Gay-Lussac's law 273 K) 273 K) (14.2 L
373 K)
3. If the pressure and absolute temperature of 2 (c) (d)
litres of CO 2 are doubled, the volume of CO 2 T(K) T(K)
8. If the average velocity of N 2 molecule is 0.3 m / s
would become
at 27 o C , then the velocity will be 0.6 m / s at[Pb. CET 2001]
[CBSE PMT 1991]
(a) 1200 K (b) 600 K
(a) 2 litres (b) 4 litres
(c) 400 K (d) 1800 K
(c) 5 litres (d) 7 litres
9. Equal volumes of two gases which do not react
4. What is kinetic energy of 1 g of O 2 at 47 o C together are enclosed in separate vessels. Their
pressures at 100 mm and 400 mm respectively. If
[Orissa JEE 2004]
the two vessels are joined together, then what
(a) 1 .24  10 2 J (b) 2 .24  10 2 J will be the pressure of the resulting mixture
(temperature remaining constant) [CBSE PMT 1981]
(c) 1 .24  10 3 J (d) 3 .24  10 2 J
(a) 125 mm (b) 500 mm
5. The root mean square speeds at STP for the gases
(c) 1000 mm (d) 250 mm
H 2 , N 2 , O2 and HBr are in the order
10. A gas of volume 100 cc is kept in a vessel at
[Pb. CET 1994; CBSE PMT 1991]
pressure 10 4 Pa maintained at temperature 24 o C .
(a) H 2  N 2  O2  HBr If now the pressure is increased to 10 5 Pa, keeping
(b) HBr  O2  N 2  H 2 the temperature constant, then the volume of the
gas becomes [AFMC 1992]
(c) H2  N 2  O2  HBr
(a) 10 cc (b) 100 cc
(d) HBr  O2  H 2  N 2 (c) 1 cc (d) 1000 cc
11. If a gas is expanded at constant temperature[IIT 1986]
6. By what ratio the average velocity of the molecule
in gas change when the temperature is raised (a) The pressure increases

from 50 to 200 o C (b) The kinetic energy of the molecules remains


the same
[DCE 2003]
Gaseous State 253
(c) The kinetic energy of the molecules decreases (a) 1 : 2 (b) 1 : 32
(d) The number of molecules of the gas increases (c) 1 : 2 (d) 1 : 4
12. The rate of diffusion of SO 2 and O 2 are in the
ratio
[Assam JET 1991; EAMCET 1980]

(SET -6)

(a) N CH 4 = number of moles of CH 4 


m V1 T1 T 22 .4  373
1. 7. (c)   V2  V1 . 2   30 .6 L
16 V2 T2 T1 273
m
N H 2 = number of moles of H 2  3 RT
2 8. (a) Vrms  ; Vrms  T
fraction partial pressure of H 2 is M

m m Given, V1  V , T1  300 K
nH2 2 8
H2    2  V2  2V , T2  ?
n H 2  n CH 4 m m 9 m 9
 2
2 16 16 V1 T1  V  300
    
2. (b) According to Charle's Law V  T V2 T2  2 V  T2
Vt  Vo  Vot
T2  300  4  1200 K
compare it with Y = C + mx
PV T P 2T 9. (d) When two vessels are joined together, the
3. (a) V 2  1 1 . 2   2lt   2lt
T1 P2 2 P T volume will be doubled hence effective
pressure will be halved
3 3 1
4. (a) K.E.  nRT    8 .314  320 J . P1  P2 100  400
2 2 32 P   250 mm
2 2
 1 . 24  10 J
2

1 10. (a) P1 V1  P2 V2 at constant T


5. (b) Vrms 
m
10 4 .100  10 5  V2
1 1 1 1
U H 2 : U N 2 : U O2 : U HBr  : : : is V2  10 cc
2 20 32 81
UHBr  UO 2  U N 2  UH 2 11. (b) Kinetic energy will also remain constant if
Temperature is constant.
6. (c) T1  150  273  423 K ; T2  50  273  323 K
rSO 2 M O2 32 1
(Vav )1 T1 423 1.14 12. (a)   
Hence,    rO2 M SO 2 64 2
(Vav )2 T2 323 1

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