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SDS-RM-E-1007-01

Material Safety Data Sheet

Toluene 3
CAS No. 108-88-3
2 0
1. Product and company information

Trade Name Toluene

Chemical Name Toluene
Synonyms
CAS No.
2
Toluol; Methylbenzol; Monomethyl benzene; Methacide; Tolu-sol; Antisal 1a; Tol; Toluene
108-88-3
EC No. 203-625-9
EUEINECS/ELINICS No. 601-021-00-3
UN No. 1294 UN Class 3 (Flammable Liquid)
Chemical Formula C6H5CH3
Material use Petrochemical Feedstock
Manufacturer
Rayong Olefins Co., Ltd. (ROC) EMERGENCY CONTACT
271 Sukhumvit Road, Map Ta Phut ,Muang District. Rayong Olefins Co.,Ltd. Emergency Center
Rayong Province 21150
+66 3891 2222
Map Ta Phut Olefins Co.,Ltd (MOC) Map Ta Phut Olefins Co.,Ltd. Emergency Center
88/3 3191 Road, RIL Industrial Estate

+66 3893 7911
Map Ta Phut , Muang District.,Rayong Province 21150

: (ROC)+66 3868 5040, +66 3868 5050
Fax : 038-685-036,(MOC) +66 3893 7000

www.chemicals.scg.co.th

2. Hazard Identification

GHS Hazard Classification

Physical Hazard
Highly flammable liquid and vapors
Physical Hazard
May be harmful if swallowed
Toxic if swallowed
Cause skin irritation
Cause serious eye irritation
May damage fertility or the unborn child
Cause damage to organ (central nervous system, kidney, liver)
May cause respiratory irritation; or may cause drowsiness or dizziness
May be fatal if swallowed and enter airways
Environmental Hazard
Toxic to aquatic life
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Material Safety Data Sheet

Toluene 3
CAS No. 108-88-3
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Potential Health Effects

Inhalation:

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Inhalation of toluene vapor can affect the central nervous system (CNS), slight drowsiness and headache have been reported,
irritation of the nose, throat and respiratory tract, fatigue and dizziness; Higher concentrations (estimated at higher than 10000
ppm) can result in unconsciousness and death. Most serious incidences of exposure have occurred when the vapor has
accumulated in confined spaces

Ingestion:

Causing severe central nervous system (CNS) depression and death. Toluene is readily absorbed following ingestion producing
symptoms similar to those described for inhalation above. Toluene may be aspirated, which is the inhalation of a chemical into the
lungs during ingestion or vomiting. Severe lung irritation, damage to the lung tissues and death may result.

Skin contact:

Toluene is a moderate skin irritant. Prolonged contact can cause dermatitis (dry, red skin). Absorption of toluene through the skin
may contribute significantly to the overall exposure. Although no reports of harmful effects following skin absorption were located.

Eye contact:

Toluene is a very mild eye irritant, based on animal evidence. In people, very short exposure (3 to 5 minutes) to the vapors has
caused slight eye irritation at 300 ppm. Longer exposures (6 to 7 hours) to concentrations above 100 ppm or 150 ppm also caused
slight irritation.

3. Composition

Component CAS No. % by weight

Toluene 108-88-3 99.9%
Other hydrocarbon N/A 0.1%

Additional Information:
The actual weight % concentrations vary based on operating conditions.
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Material Safety Data Sheet

Toluene 3
CAS No. 108-88-3
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4. First Aid Measure

Inhalation:

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IMMEIDATELY remove from exposure. Give oxygen or artificial resuscitation if indicated. Get medical attention as soon as
possible even if no symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest)
develop.
Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing
Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective
Clothing

Ingestion:

DO NOT INDUCE VOMITING. Volatile chemicals have a high risk of being aspirated into the victim's lungs during vomiting which
increases the medical problems. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical. If
the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim
on his/her side with the head lower than the body. IMMEDIATELY get medical attention.

Skin Contact:

IMMEDIATELY wash the contaminated skin with soap and water at least 20 minutes. If this chemical penetrates the clothing,
immediately remove the clothing, wash the skin with soap and water. IMMEDIATELY get medical attention even if no symptoms
(such as redness or irritation) develop

Eye Contact:

First check the victim for contact lenses and remove if present. Flush eyes with water or normal saline solution for 20 to 30
minutes. DO NOT put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician.
IMMEDIATELY get medical attention even if no symptoms (such as redness or irritation) develop

5. Fire Fighting Measure

Extinguish Media

Small Fire: Dry chemical, CO2, water spray or regular foam.

Large Fire: Water spray, fog or regular foam.
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Material Safety Data Sheet

Toluene 3
CAS No. 108-88-3
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Fire Fighting Instruction

Position upwind.
Consider for immediate emergency isolation and evacuation for at least 300 meters.
If tank is involved in a fire, ISOLATE for 800 meters in all directions.
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Fire fighter should wear full-face, self-contained breathing apparatus and thermal protective clothing.
Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.
Cool containers with flooding quantities of water until fire are out.
IMMEDIATELY withdraw in case of rising sound from venting safety devices or discoloration of tank.
ALWAYS stay away from tanks engulfed in fire.
For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn.
Do not use straight streams.
Move containers from fire area if you can do it without risk.
Avoid inhaling any smoke and combustion materials.
Prevent water run-off for flammability, and enter to ditches, sewers, drains and waterway or other confined or underground spaces.

Fire and Explosion Hazard

All these products have a very low flash point.
Vapors are heavier than air and travel along the ground to some distant source of ignition and flash back.
Vapor may form explosive mixture with air.
Container explosion may occur under fire conditions.

6. Accidental Release Measure

Evacuation Material and Procedure

ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
All equipment used when handling the product must be grounded
Do not touch or walk through spilled material.
Stop leak if you can do it without risk
Prevent entry into waterways, sewers, basements or confined areas.
A vapor suppressing foam may be used to reduce vapors.
Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers.
Use clean non-sparking tools to collect absorbed material.
Dike far ahead of liquid spill for later disposal.
Water spray may reduce vapor; but may not prevent ignition in closed spaces.

Special Procedure
Wear appropriate protective equipment and clothing during cleanup.
Consider initial downwind evacuation for at least 300 meters
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Material Safety Data Sheet

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If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial
evacuation for 800 meters (1/2 mile) in all directions.

7. Handling and Storage 2

Handling Procedure

Handling with grounded, properly designed and approved equipment that suitable for flammable liquids.
Use with adequate ventilation.
No smoking or open flames permitted in storage, use or handling areas.
Use non-sparking tools to open containers which are effectively grounded and bonded prior to opening and pouring.
Do not breath product gas, fumes, vapor, or spray.
In case of insufficient ventilation, wear suitable respiratory equipment. Keep away from heat and incompatible material such as
oxidizing agents and acid.
After handling always wash hand thoroughly with soap and water.
Closed system, ventilation, explosion-proof electrical equipment and lighting.
Do NOT use compressed air for filling, discharging, or handling.
Use non-sparking hand tools. Prevent build-up of electrostatic charges (e.g., by grounding).

Storage Procedure

Store in tightly closed containers in a cool, well ventilated area.

Vapor may form explosive mixtures in air.
Use non-sparking tools when opening or closing containers.
Ensure fire extinguisher and absorbents capable in work area.
Storage tank should be above ground
Incompatible Material

Strong oxidizers and acids

8. Exposure Control and Personal Control

Engineering Controls

Provide mechanical ventilation (dilution and local exhaust) process or personal enclosure, remote and automated operation, control of
process conditions, leak detection and repair systems, and other process modifications.
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CAS No. 108-88-3
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Ensure all exhaust ventilation systems are discharged to outdoors, away from air intakes and ignition sources. Supply sufficient
replacement air to make up for air removed by exhaust systems.
Eyewash fountains should be provided in areas where there is any possibility that workers could be exposed to the substances.
Facilities for quickly drenching the body should be provided within the immediate work area for emergency use where there is a possibility

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of exposure. [Note: It is intended that these facilities provide a sufficient quantity or flow of water to quickly remove the substance from
any body areas likely to be exposed. The actual determination of what constitutes an adequate quick drench facility depends on the
specific circumstances. In certain instances, a deluge shower should be readily available, whereas in others, the availability of water from
a sink or hose could be considered adequate.]

Exposure Limit

OSHA NIOSH ACGIH

PEL REL TLV
TWA 8 hours (ppm) 200 100 20
Ceiling (ppm) 300 - -
STEL 15 minutes(ppm) - 150 -
IDLH (ppm) - 500 -

BEI:

Metabolite Limit
O-Cresol in urine 0.5 mg/l
Hippuric acid in urine (end of shift) 1.6 g/g Creatinine

Personal Protective Equipment

Respiratory:

Use respirator approved by the National Institute for Occupational Safety and Health (NIOSH).
Cartridge or canisters must be replaced before the end of their service life, or the end of the shift,
whichever occurs first.
Eyes:
Wear safety glasses; chemical goggles are recommended if splashing is possible,
or to prevent eye irritation from heated vapors or mists.
Skin/Hands/Feet:
Wear chemical-resistant gloves when handling product.
Wear chemical-resistant safety footwear with good traction to prevent slipping.
Work clothing that sufficiently prevents skin contact should be worn, such as coveralls and/or long
sleeves and pants.
If splashing or contact with liquid material is possible consider for an impervious overcoat.
Fire resistant (i.e., Normed) or natural fiber clothing (i.e., cotton or wool) is recommended. Synthetic
clothing can generate static electricity and is not recommended where flammable vapor releases may
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Material Safety Data Sheet

Toluene 3
CAS No. 108-88-3
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9. Physical and Chemical Properties

Physical State/appearance : Colorless Liquid pH : Not applicable

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Odor : Aromatic, sweet Odor Threshold : 0.16 – 37 ppm

Melting Point : -95 °C at 1 atm Boiling Point : 111 °C at 1 atm

Flash point : 4 °C (Closed cup) Evaporation Rate : Not applicable

Flammability classification : Flammable Auto ignition temperature : 480 °C

Upper exposure limits : 7.1% Lower Exposure Limit : 1.1%

Vapor pressure: 3.8 kPa at 25 °C Vapor density : 1.01 at 20 °C (Air =1)

Specific gravity : 0.87 Critical Temperature : Not applicable

Water solubility : Not applicable n-octanol/H2O Coefficient : Log Pow=2.96

10. Stability and Reactivity Information

Chemical Stability

This product is stable in normal temperature and pressure. Conditions contributing to instability: Heat.

Hazardous polymerization
Not likely occur

Incompatibility/ Condition to Avoid

DANGER!! Keep away from heat, ignition source and flame

DANGER!! The material reacts violently with carbon tetrachloride, chlorine, mercury oxide, silver oxide, and copper at high
temperatures.

Hazardous Decomposition

Upon decomposition, This product emits carbon dioxide, carbon monoxide and low molecular weight hydrocarbons.
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Material Safety Data Sheet

Toluene 3
CAS No. 108-88-3
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11. Toxicological Information

ACUTE TOXICITY
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General Information

The CNS is the primary target organ for toluene toxicity in both humans and animals for acute and chronic exposures. CNS
dysfunction (which is often reversible) and narcosis have been frequently observed in humans acutely exposed to low or moderate
levels of toluene by inhalation; symptoms include fatigue, sleepiness, headaches, and nausea. CNS depression and death have
occurred at higher levels of exposure.

Cardiac arrhythmia has also been reported in humans acutely exposed to toluene

Following the ingestion of toluene a person died from a severe depression of the CNS. Constriction and necrosis of myocardial
fibers, swollen liver, congestion and hemorrhage of the lungs, and tubular kidney necrosis were also reported

LD50/LC50

Inhalation LC50 Rat: 8,000 ppm / 4H

Oral LD50 Rat: 2,500 mg/kg
Dermal LD50 Rabbit: 14,000 mg/kg

CHRONIC TOXICITY

General Information

The liquid defats the skin. The substance may have effects on the central nervous system . Exposure to the substance may enhance
hearing damage caused by exposure to noise. Animal tests show that this substance possibly causes toxicity to human reproduction
or development.

Carcinogenic

IARC : Group 3 – Not classified as human carcinogen

ACGIH : A4 – Not classified as a human carcinogen

Reproductive/Developmental Effects
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Material Safety Data Sheet

Toluene 3
CAS No. 108-88-3
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Toluene is not considered a reproductive hazard. No conclusions can be drawn based on the available human information.
Reproductive effects have not been observed in animal studies.

12. Ecological Information 2

Aquatic/Terrestrial Toxicity

Type Duration Value

LC50 Fish : Lepomis macrochirus (Bluegill) 24 hours 17 mg/l
LC50 Fish : Lepomis macrochirus (Bluegill) 96 hours 13 mg/l
EC50 Algae : Chlorella vulgaris 24 hours 245 mg/l
NOECs Algae : Chlorella vulgaris 10 days 250 mg/l

Environmental Fate/ Mobility

Industrial emissions of toluene can produce elevated concentrations in the atmosphere around the source. Because of its short life-
expectancy in the atmosphere, toluene is expected to be confined to the local area within which it is emitted. Toluene that makes its
way into the ground, and does not evaporate, may move through the ground and enter groundwater (bore water); it is degraded in
the water within days.

Persistence/Degradability

Toluene quickly evaporates to a gas if released as a liquid. It evaporates from both water and soil when exposed to air. It breaks
down in the air in a few days into other chemicals (Benz aldehyde and cresol, which are harmful to humans). In soil and water,
bacteria break it down.
Toluene is readily degraded in sewage water, and is degraded by a variety of soil
microorganisms, especially when the microorganisms are adapted to toluene. At low
environmental concentrations the degradation rate is significantly reduced

Bioaccumulation /Accumulation

The log Know is <3 indicating limited bio concentration in aquatic organisms.

13. Disposal Consideration

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Material Safety Data Sheet

Toluene 3
CAS No. 108-88-3
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Product

DO NOT ATTEMPT TO DISPOSE OF BY UNCONTROLLED IGNITION

DO NOT RELEASE TO ENVIRONMENT WITHOUT TREATING
Burn in a chemical incinerator equipped with an afterburner and a scrubber.
Should review and follow national and local regulations before dispose.
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Container

Since emptied containers retain material residue, follow safe handling/label warnings even after container is emptied.

14. Transportation information

US DOT Information
Shipping Name : Toluene
UN No. : 1294
Hazard Class : 3
Packing Group : II
Require Label(s): FLAMMABLE LIQUID
Additional Information : Reportable Quantity 4.54 kg
2004 Emergency Response Guidebook # 116P

International Maritime Dangerous Goods: IMDG

Shipping Name : Toluene
UN No. : 1294
Hazard Class : 3
Packing Group : II
Require Label(s): FLAMMABLE LIQUID
IMDG EMS No. : No data available
IMDG 7 Marine pollution : No

International Air Transport Association : IATA

Shipping Name : Toluene
UN No. : 1294
Hazard Class : 3
Packing Group : II
Require Label(s): FLAMMABLE LIQUID
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Material Safety Data Sheet

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CAS No. 108-88-3
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15. Regulatory Information

INTERNATION REGULATION

 Classified as EU Directive 67/548/EEC (ANNEX I) 2

Index No. 601-021-00-3

 Classified as Appendix IX in Resource Conservation and Recovery Act (RCRA)

Waste code U220 Toluene and F005-spent solvents including toluene

 Classified as USA OSHA Hazard Communication Class 29 CFR 1910.1200

 Classified as CERCLA
Reportable quantity 4.54 kg.
EC Directive
Symbol : F, Xn
R-Phase : R11-38-48
R20-63-65-67

S-Phase : S 2-36
S 37-46-62

16. Other information

This material safety data sheet is prepared by

Rayong Olefins Co., Ltd
Map Ta Phut Olefins Co., Ltd.

Publish Since
01 January 2014

Key/Legend
CAS: Chemical Abstract Service
CFR: Code of Federal Regulations
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Material Safety Data Sheet

Toluene 3
CAS No. 108-88-3
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CNS: Central Nervous System

DOT: Department of Transportation
EC50 Effective concentration of a substance that causes 50% of the maximum response
EINECS: European Inventory of Existing Commercial Chemical Substances
EPA:
EU:
Environmental Protection Agency
European Union
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GHS: Globally Harmonized System of Classification and Labeling of Chemicals
HCS: Hazard Communication Standard
IARC: International Agency for the Research on Cancer
IARC: International Agency For Research On Cancer
LC50: Lethal Concentration cause death in 50% of a defined experimental animal population
LD50 : Lethal dose cause death in 50% of a defined experimental animal population
MSDS: Material Safety Data Sheet
NOEC : No observed effect concentration
NFPA: National Fire Protection Association
NIOSH: National Institute of Occupational Safety and Health
NTP: National Toxicology Program
OSHA: U.S. Occupational Safety & Health Administration
PEL: Permissible Exposure Limit (OSHA)
RCRA: Resource Conservation and Recovery Act
REL: Recommended Exposure Limit (NIOSH)
SCBA: Self-Contained Breathing Apparatus
STEL: Short-Term Exposure Limit (generally 15 minutes)
TLV: Threshold Limit Value (ACGIH)
TWA: Time Weighted Average (8 hr.)
UN: United Nations

END OF DOCUMENT