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SULIT

SULIT 4541/1
4541/1
Kimia
Kertas 1
Mei
2008
1¼ jam
BAHAGIAN SEKOLAH
KEMENTERIAN PELAJARAN MALAYSIA
______________________________________________
PEPERIKSAAN PERTENGAHAN TAHUN 2008
TINGKATAN 5

KIMIA

Kertas 1

Satu jam lima belas minit

JANGAN BUKA KERTAS SOALAN INI HINGGA DIBERITAHU

1. Kertas soalan ini mengandungi 50 soalan.


2. Jawab semua soalan
3. Jawab dengan menghitamkan ruangan yang betul pada kertas jawapan
4. Bagi setiap soalan hitamkan satu ruangan sahaja
5. Sekiranya anda hendak menukar jawapan, padamkan tanda yang telah
dibuat. Kemudian hitamkan jawapan yang baru.
6. Rajah yang mengiringi soalan tidak dilukiskan mengikut skala.
7. Anda dibenarkan menggunakan kalkulator saintifik yang tidak boleh
diprogramkan.

Kertas soalan ini mengandungi 23 halaman bercetak

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INFORMATION FOR CANDIDATES

1 This question paper consists of 50 questions.


2 Answer all questions.
3 Answer each question by blackening the correct space on the answer sheet.
4 Blacken only one space for each question.
5 If you wish to change your answer, erase the blackened mark that you have made. Then
blacken the space for the new answer.
6 The diagrams in the questions provided are not drawn to scale unless stated.
7 You may use a non-programmable scientific calculator.

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1 After making observations, a chemist should try to

A collect data
B make inference
C make hypothesis
D identify problems

2 The diagram shows a model of an atom.


Electron

Shell
Nucleus that contains
proton and neutrons

Who introduced this model?

A Neils Bohr
B J.J Thomson
C James Chadwick
D Ernest Rutherford

3 What is the relative molecular mass of hydrated magnesium sulphate, MgSO4.7H2O?


[Relative atomic mass: Mg, 24; S,32; O,16; H,1]

A 145
B 246
C 305
D 356

4 The table shows the properties of element Q.

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Element Properties
• Non-flammable
Q • Used as carrier gas in gas-liquid chromatography
• Filled in electric light bulbs

Which of the following elements is Q?

A Sodium
B Helium
C Argon
D Silver

5 The table shows the electron arrangement for elements M, N, P and Q.

Element Electron arrangement


M 2.4
N 2.8.2
P 2.6
Q 2.8.7

Which of the following elements react to form an ionic compound?

A M and P
B P and Q
C M and Q
D P and N

6 The diagram shows the electrolysis of molten lead(II) bromide using carbon
electrodes.

Carbon

Lead(II) bromide

heat

What are the products at the anode and the cathode?

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Anode Cathode
A Bromine Lead
B Oxygen Hydrogen
C Bromine Hydrogen
D Oxygen Lead
7 Which of the following is a weak alkali?

A Lithium hydroxide
B Aqueous ammonia
C Cooper(II) hydroxide
D Potassium hydroxide

8 Which of the following salts is prepared through precipitation process?

A Lead(II) chromate(VI)
B Ammonium chloride
C Potassium carbonate
D Barium chloride

9 The diagram shows the formation of ammonia through Haber process.

Hydrogen Nitrogen

Catalyst X
Temperature Y
Pressure Z

Ammonia

Which of the following represent catalyst X, temperature Y and pressure Z?

Catalyst X Temperature Y, oC Pressure Z / atm


A Vanadium(V) oxide 550 200
B Platinum 450 100
C Iron 200 450
D Iron 450 200

10 Which of the following is the meaning of activation energy?

A The maximum energy that the particles need to produce effective


collision
B The amount of energy used by the particles during a collision

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C The amount of kinetic energy of molecules during a collision


D The minimum amount of energy that particles must have in order to
react

11 Which of the following structural formulae shows an unsaturated hydrocarbon?

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12 The diagram shows the atomic symbol of element X.


7

X
3

Which of the following is true about the sub-atomic particles of element X?

Proton Number Number of neutron Number of electron


A 7 7 10
B 7 7 7
C 3 4 3
D 3 4 2

13 What is the number of oxygen atom in 0.1 mole of water?


[Avogadro constant: 6.02 x 1023 mol-1]

A 6.02 x 1022
B 6.02 x 1023
C 60.2 x 1023
D 3.01 x 1023

14 X is an element that has the following properties;


• Soft solid
• Reacts with cold water to form alkaline solution
• Store in paraffin oil

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Among elements A, B, C and D in the Periodic Table of elements, which element


represent X?

15 The diagram shows the electron arrangement of a compound formed between


atoms P and Q. 2+ 2-

P Q

Which of the following statements is true about the compound?

A There is strong intermolecular force between particles P and Q


B The compound is formed by sharing the electrons
C The compound conduct electricity in molten state
D It is an covalent compound

16 The diagram shows the set-up of the apparatus used to electrolyses


0.1 mol dm-3 of copper(II) chloride solution by using carbon electrodes.

Carbon

Copper(II) chloride
solution

What is observed at the anode?

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A Colourless gas bubbles released


B Greenish yellow gas evolved
C Brown solution produced
D Brown solid deposited

17 Which of the following equations shows the neutralization process?

I CuO + H2SO4  CuSO4 + H2O


II Zn + 2HCl  ZnCl2 + H2
III NH3 + HNO3  NH4NO3
IV CaCO3 + H2SO4  CaSO4 + H2O + CO2

A I only
B II and IV only
C I and III only
D I, II and IV only

18 Which of the following ions form a white precipitate that does not dissolves in
excess sodium hydroxide solution but no change occur in aqueous ammonia
solution?

A Mg2+
B Pb2+
C Ca2+
D Al3+

19 The diagram shows the lead crystal glass.

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What are the major components used in the making of lead crystal glass?

A Copper(II) oxide and lead(II) oxide


B Aluminium silicate and silicon dioxide
C Silicon dioxide and lead(II) oxide
D Iron(III) oxide and boron oxide

20 Chemical equation shows the reaction between zinc and sulphuric acid.

H2SO4(aq) + Zn(s)  ZnSO4(aq) + H2(g)

Which of the following factors increases the rate of reaction?

A Increases of volume of sulphuric acid


B Use of lower concentration of sulphuric acid
C Addition of small amount of copper(II) sulphate
D Use bigger size of zinc

21 The diagram shows the cooking gas cylinder.

Which of the following gasses is filled in the gas cylinder?

A Methane
B Ethene
C Propene
D Butane
22 The graph shows the cooling curve of acetamide.

Temperature/ oC

T U

V
Time/ s

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Which of the following statements are true about the particles in acetamide from S
to V?

I Heat energy is released by particles


II The kinetic energy of the particles increase
III The particle are closer to one another
IV The movement of the particles becomes slower

A I and III only


B III and IV only
C II, III and IV only
D I, III and IV only

23 The chemical equation shows the burning process of ethene in excess air.

C2H4(g) + 3O2  2CO2(g) + 2H2O(l)

What is the maximum volume of carbon dioxide gas evolved when 0.5 mole of
ethene burns completely?
[1 mole of gas occupied 24 dm3 at room temperature and pressure]

A 12 dm3
B 24 dm3
C 36 dm3
D 48 dm3

24 The diagram shows the structure of atoms Q and R.

Atom Q Atom R

Which of the following is true about atoms Q and R?

A Q exists as a diatomic molecule


B Q and R have the same chemical properties

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C R reacts with Q to form an ionic compound


D Q reacts with water to release hydrogen

25 The electron arrangement of atom J is 2.6 and atom G has 4 valence electrons.
What type of bond and the chemical formula of the compound formed between
atoms J and G?

Type of bond Chemical formula


A Ion JG2
B Ion GJ2
C Covalent GJ2
D Covalent JG2

26 The diagram shows the set-up of apparatus for the electrolysis of silver nitrate
solution.

Silver Silver

Silver nitrate solution

What is formed at the cathode?

A Silver atoms
B Oxygen gas
C Hydrogen gas
D Silver ions

27 The distilled water is added to 20 cm3 of 1.0 mol dm-3 sodium hydroxide solution
to produce 250 cm3 of sodium hydroxide solution.
What is the concentration of the sodium hydroxide solution produced?

A 0.02 mol dm-3


B 0.04 mol dm-3
C 0.06 mol dm-3
D 0.08 mol dm-3

28 Ammonium sulphate is used as a chemical fertilizer. This fertilizer can be


prepared in the laboratory through the reaction between

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A aqueous of ammonia solution and dilute sulphuric acid


B aqueous of ammonia solution and sulphur dioxide
C ammonia gas and sulphur and oxygen
D ammonia gas and sulphur trioxide

29 The diagram shows the arrangement of atoms in steel.

Iron atom

X atom

What is X?

A Tin
B Zinc
C Carbon
D Copper

30 The graph shows the maximum volume of carbon dioxide gas evolved when
calcium carbonate react with hydrochloric acid.
Volume of CO2 gas/ cm3

35

Time/ s
120

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What is the rate of reaction at 120 s?

A 0.00 cm3 s-1


B 0.15 cm3 s-1
C 0.29 cm3 s-1
D 0.35 cm3 s-1

31 Steam/Catalyst
Compound X Compound Y

Process A Acidified potassium


dichromate (VI)

CH3COOH

What could be the organic compounds X and Y, Catalyst and Process A in the
diagram?

Compound X Compound Catalyst Process A


Y
A Ethene Ethanol Phosphoric acid Oxidation
B Ethane Ethene Nickel Hydrogenation
C Ethane Ethene Nickel Oxidation
D Ethene Ethanol Phosphoric acid Hydrogenation

32 The table shows the melting point and boiling point for substances P, Q, R
and S.

Substance Melting point/ oC Boiling point/ oC


P 79 108
Q -180 -120
R -95 69
S -160 -90

Which of the substances exists as a liquid at room temperature?


A Q
B R
C S
D P

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33 The equation shows the reaction of the extraction of iron from iron(III) oxide.

2Fe2O3  4Fe + 3O2

What is the mass of iron which can be extracted from 10.0 g of iron(III) oxide?
[Relative atomic mass: Fe,56; O,16]

A 3.5 g
B 4.5 g
C 6.0 g
D 7.0 g

34 The table shows the proton number for element M and N. Element N is more
electronegative than element M because

Element Proton number


M 8
N 9

A atomic size of N is smaller


B atom N releases electrons easier
C atom N has less valence electron
D atom N has larger number of neutron

35 The diagram shows the information of elements X and Y

7 16
X Y
3 8

Which of the following is the diagram of electron arrangement for the compound
formed when element X reacts with element Y?

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36 The diagram shows the voltaic cell.

Copper Magnesium

Copper(II) chloride Magnesium nitrate


solution solution

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Which of the following half-equations represent the reaction at the negative


terminal and positive terminal?

Negative Terminal Positive terminal


A Mg → Mg2+ + 2e Cu2+ + 2e → Cu
B Mg2+ + 2e → Mg Cu → Cu2+ + 2e
C Cu2+ + 2e → Cu Mg → Mg2+ + 2e
D Cu → Cu2+ + 2e Mg2+ + 2e → Mg

37 Which of the following solutions has the highest concentration of hydrogen ion?

A 50 cm3 of 1.0 mol dm-3 H2SO4 solution


B 50 cm3 of 2.0 mol dm-3 H2SO4 solution
C 100 cm3 of 1.0 mol dm-3 H2SO4 solution
D 150 cm3 of 1.0 mol dm-3 H2SO4 solution

38 The reaction between lead(II) nitrate and potassium iodide solution is represented
by the equation below

Pb(NO3)2 (aq) + 2KI (aq)  PbI2 (s) + 2KNO3 (aq)

10.0 cm3 of 1.0 mol dm-3 potassium iodide solution is mixed with 20.0 cm3 of 1.0
mol dm-3 lead(II) nitrate solution.
What is the maximum mass of lead(II) iodide produced in this reaction?
[Relative atomic mass: I ,127 and Pb, 207]
A 3.34 g
B 4.61 g
C 6.68 g
AD 9.22 g

39 The diagram shows a structural formula of a polymer.

H H
B C C

H Cl n

Which of the following is the monomer of the polymer?

D
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Cl

Cl

Cl

Cl Cl

40 The graph shows the volume of carbon dioxide gas released against time for the
reaction between 25 cm3 of hydrochloric acid with excess marble.

CaCO3 + 2HCl → CaCl2 + CO2 + H2O

Volume of CO2/ cm3

180

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Time/s

What is the concentration of acid used?


[Molar volume: 24 dm3 mol-1 at room temperature]

A 0.3 mol dm-3


B 0.4 mol dm-3
C 0.5 mol dm-3
D 0.6 mol dm-3

41
• 3.0 g of carbon reacts with 0.5 g of
hydrogen gas to form compound X.
• Relative molecular mass of
compound X is 42.

What is the molecular formula of compound X?


[Relative atomic mass: C,12; H,1]

A CH2
B C2H4
C C2H6
D C3H6

42 Magnesium ribbon reacts with element Q from group 17 in Periodic Table.


Which of the following chemical equations is correct?

A Mg + Q → MgQ
B Mg + Q2 → MgQ2
C 2Mg + Q2 → 2MgQ
D Mg + 2Q → MgQ2

43 Which of the following pairs show the correct uses of the isotopes?

Isotope Uses

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I Cobalt-60 To destroy bacteria in food


II Carbon-14 To estimate the age of artifacts
III Iodine-131 To detect the location of tumour
IV Sodium-24 To detect leaks in underground petroleum piping

A I and II only
B II and IV only
C I,II and III only
D I, II, III and IV

44 Sulphur dioxide gas, SO2 causes environmental pollution.


Which of the following environmental pollutions is affected by sulphur dioxide,
SO2?

I pH of the soil increases


II Lakes and rivers become acidic
III Salts are leached out of the top soil
IV Buildings and metal structures will corrode

A I and II only
B I and III only
C II, III and IV only
D I, II, III and IV

45 Which of the following diagrams is used to electroplate an iron spoon with silver?

Iron spoon Silver strip

Silver chloride

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Iron spoon Silver strip

Silver nitrate

Iron spoon Silver strip

Silver chloride

Iron spoon Silver strip

Silver nitrate

46 What is the volume of 0.2 mol dm-3sulphuric acid solution required to completely
neutralize 50 cm3 of 0.2 mol dm-3 potassium hydroxide solution?

A 25 cm3
B 30 cm3
C 45 cm3
D 50 cm3

47 The diagram shows the structural formula of compound X.

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Compound X

Which of the following is an isomer of X?

48 Which pair of the organic compounds below can be distinguished by using acidified
potassium manganate(VII)?

A C2H6 and C3H8

B C2H5OH and C3H6

C CH3CH2COOH and CH3CHCHOH

D CH3CH2CH2CH3 and CH2CHCH2CH2CH3

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49 Which of the following reactions represent the precipitation reactions?

I Pb(NO3)2 + Na2SO4 → PbSO4 + 2NaNO3


II Ba(NO3)2 + 2KCl → BaCl2 + 2KNO3
III Pb(NO3)2 + 2KCl → PbCl2 + 2KNO3
IV Ca(NO3)2 + Na2SO4 → CaSO4 + 2NaNO3

A I and III only


B I, II and III only
C I, III and IV only
D 1, II, III and IV

50 The diagram shows the graph of volume of oxygen gas against time. Curve I is
obtained from the decomposition of 20 cm3 of 0.2 mol dm-3 hydrogen peroxide
solution.
Volume of oxygen /cm3

2V II

V I

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Time/s
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Which of the following solutions will produce curve II?

A 40 cm3 0.1 mol dm-3 hydrogen peroxide solution


B 20 cm3 0.4 mol dm-3 hydrogen peroxide solution
C 30 cm3 0.2 mol dm-3 hydrogen peroxide solution
D 40 cm3 0.4 mol dm-3 hydrogen peroxide solution

END OF QUESTION PAPER

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