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Variation of
Conductance with
Temperature in
Electrolytes
Index
1. Certificate.................................................................3
2. Acknowledgements.....................................................4
3. Aim..........................................................................5
4. Apparatus..................................................................6
5. Important Terms........................................................7
6. Conductivity...............................................................8
7. Factors Affecting Electrical Conductivity.........................9
8. Procedure.................................................................10
9. Physical Constants.....................................................11
10. Observation Set
1.....................................................12
11. Graph of Observation Set
1........................................13
12. Observation Set
2.....................................................14
13. Graph of Observation Set
2........................................15
14.
Result.....................................................................16
15.
Conclusion...............................................................17
16.
Precautions..............................................................18
17.
Bibliography.............................................................19
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Certificate
Acknowledgements
"There are times when silence speaks so much more loudly than
words of praise to only as good as belittle a person, whose words
do not express, but only put a veneer over true feelings, which
are of gratitude at this point of time."
Aim
Apparatus
Important Terms
Conductance: The property of ease of flow of electric
current through a body is called conductance.
Faraday's Laws:
First Law: The mass of a substance produced or
consumed in electrolysis is directly proportional to the
quantity of charge passing through it.
m Q
or, m = Z × I × t
where, Z is electrochemical equivalent; I is current; t is
time in seconds; Q is charge.
Conductivity
R=1/C
Κ=1/R*L/A
Procedure
Physical Constants
Voltage
Nature of electrodes
Size of electrodes
Separation between the electrodes
Concentration of the electrolytes
Nature of the electrolytes
Resistance in the circuit
Observation Set 1
For ZnSO4 electrolyte with Zn electrodes
I V R=V/I C=1/R
1 23 C 100 mA 1.0 V 10 Ω 0.100 Ω-1
2 26 C 100 mA 0.95 V 9.5 Ω 0.105 Ω-1
3 29 C 110 mA 0.89 V 8.09 Ω 0.120 Ω-1
4 32 C 110 mA 0.84 V 7.63 Ω 0.130 Ω-1
5 35 C 120 mA 0.80 V 6.66 Ω 0.150 Ω-1
6 38 C 125 mA 0.75 V 6.00 Ω 0.160 Ω-1
7 41 C 130 mA 0.71 V 7.6 Ω 0.180 Ω-1
8 44 C 130 mA 0.65 V 5.00 Ω 0.200 Ω-1
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0.2
0.2
Conductance (in Mho)
0.18
0.16
0.15
0.15
0.13
0.12
0.11
0.1
0.1
0.05
0
20 25 30 35 40 45 50
Temperature (in degree Celsius)
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Observation Set 2
For CuSO4 electrolyte
I V R=V/I C = 1/R
1 25 C 75 mA 1.4 V 18.67 Ω 0.053 Ω-1
2 28 C 75 mA 1.35 V 18.00 Ω 0.055 Ω-1
3 31 C 75 mA 1.3 V 17.33 Ω 0.057 Ω-1
4 34 C 75 mA 1.25 V 16.67 Ω 0.060 Ω-1
5 36 C 80 mA 1.2 V 15.00 Ω 0.066 Ω-1
6 38 C 80 mA 1.15 V 14.38 Ω 0.069 Ω-1
7 42 C 80 mA 1.10 V 13.75 Ω 0.072 Ω-1
8 44 C 85 mA 1.10 V 12.94 Ω 0.075 Ω-1
9 47 C 85 mA 1.05 V 12.35 Ω 0.080 Ω-1
10 49 C 90 mA 1.10 V 11.11 Ω 0.090 Ω-1
11 53 °C 90 mA 1.90 V 10.00 Ω 0.100 Ω-1
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0.1
0.1
0.09
0.08
0.08 0.08
Conductance (in Mho)
0.07
0.07
0.07
0.06
0.06 0.06
0.06
0.05
0.04
0.02
0
20 25 30 35 40 45 50 55
Temperature (in degree Celsius)
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Result
Conclusion
Precautions
Bibliography
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