12th ABCD (Date: 03-10-2010) Review Test-5

PAPER-1
Code-A
ANSWER KEY
MATHS
SECTION-3
PART-A
Q.1 C
Q.2 B
Q.3 B
Q.4 A
Q.5 A
Q.6 A
Q.7 A
Q.8 C
Q.9 D
Q.10 B
Q.11 D
Q.12 C or D
Q.13 D
Q.14 B,C,D
Q.15 A,C
Q.16 A,B,D
PART-B
Q.1 (A) Q, R, S
(B) P
(C) Q
PART-C
Q.1 0013
Q.2 7560
Q.3 0006
Q.4 0025
CHEMSITRY
SECTION-1
PART-A
Q.1 B
Q.2 B
Q.3 D
Q.4 B
Q.5 D
Q.6 C
Q.7 A
Q.8 C
Q.9 D
Q.10 A
Q.11 D
Q.12 C
Q.13 D
Q.14 A,B,C,D
Q.15 B,C,D
Q.16 A,C,D
PART-B
Q.1 (A) Q,S
(B) R,S
(C) P,Q,S
PART-C
Q.1 0020
Q.2 0009
Q.3 0090
Q.4 2455
PHYSICS
SECTION-2
PART-A
Q.1 A
Q.2 B
Q.3 A
Q.4 C
Q.5 B
Q.6 B
Q.7 C
Q.8 A
Q.9 C
Q.10 D
Q.11 D
Q.12 A or C
Q.13 D
Q.14 C,D
Q.15 A,B,C
Q.16 A,B,C
PART-B
Q.1 (A) P
(B) Q
(C) R,S
PART-C
Q.1 0048
Q.2 0768
Q.3 0008
Q.4 0080
CHEMISTRY
Code-A Page # 1
PART-A
Q.1
[Sol. CA =
A0 C CB CC
x =
A0 C x x
or, 3x =
A0 C x =
3
C
A0
CA =
A0 C e ( 1 2 )t
or
3
C
A0
=
( )t
A
1 2
0
C e
or 3 e( 1 2 )t
or r
2
1
2 n 3
n 3
t
l
l
= 30 min. ]
Q.2
[Sol. (A) SiF4 < SiCl4
More electron density present on periphery so, more repulsion produce in between
two molecule
i.e london force decreases and B.P. decreases.
(B) Order of thermal stability
MgCO3 < SrCO3 < BaCO3
so MgCO3 gives more CO2
(C) Dipole moment XeF2 = XeF4 = zero
(D) XeF2 + F‾ XeF3‾
XeF4 + F‾ XeF5‾
The element of d-orbital contraction is more incase of XeF4 compared to XeF2. ]
Q.3
[Sol. Given interconversion can be achieved by any one i.e. LAH or SBH or 9BBN ]
Q.4
[Sol. A2B 2A+ + B2
4×10 5×0.25 2×4×10 5×0.75 0.75×4×10 5
10 5 (6×10 5 x) 3×10 5
A+ + H2O AOH + H+
(6×10 5 x) x x
9
14
5 10
10

=
(6 10 x)
x
5
2
or
5
10 5
=
(6 10 x)
x
5
2
or 5x2 = 6 × 10 10 x × 10 5
CHEMISTRY
Code-A Page # 2
or 5x2 + 10 5 x + 6 × 10 10 = 0
or
10
10 10 120 10
x
5 10 10
10
10 10 121
x
5 5
10
10 (11 1)
x
5

= 10 5
pH = 5 ]
Q.5
[Sol. (A) sp3 tetrahedral
(B) sp3 tetrahedral
(C) sp3 tetrahedral
(D) dsp2 square planar ]
Q.6
[Sol. (A) Victor mayer test is given by halide & alcohols both.
(B) Bielstein test is given by halogen containing compounds
(C) Benzene will be the major products due to dehydration and ring expansion.
(D) Monomer of polythene is ethene ]
Q.7
[Sol. Released energy = 3
3
20 10
1
57.5 10
= 1150 J ]
Q.8
[Sol.
(A) (B) (C) (D)
(E)
HBr H
aq.KOH
R O 2 2
N H 2 4
H O 2 2

H / Pt 2
Br OH
S 2 N FR addition E1
]
Q.10
[Sol. Cl2 / h gives 2° alkyl halide as major product ]
Q.11
[Sol. Work is a path function ]
Q.12
[Sol. Porous mass helps in reduction of metal oxide.]
CHEMISTRY
Code-A Page # 3
Q.13
[Sol. Me C CNa
is product ]
Q.14
[Sol. for adiabatic, Q = 0
U = W = nCvm T = text (v2 v1) ]
Q.16
[Sol. (B)
NH
is formed due to ring expansion ]
PART-C
Q.1
[Sol. [F‾] = 0.02 M
[Mg2+] = 2
sp
[F‾]
K
= 2
8
(0.02)
8 10
= 2 × 10 4
[CaCO3] = 2 × 10 4 mole/L
= 2 × 10 2 g/L
= 20 mg/L
= 20 ppm ( 1 mg/L = 1ppm for water) ]
Q.2
[Sol.
Fe
C C
C
C
C
C
N
N
N
N
N
N
9 atoms are present in a plane. Since 'C' atoms are sp hybridised 'C' and 'N' bo
th atoms are in the same
plane. ]
Q.3
[Sol. A + 2B C
t=0 500 1
t=t
2
0.1
500 0.1
500
rate = 10 4 PAPB
2
rate = 10 4 × 500 × PB
2
rate = 5 × 10 2 PB
2
or 2
1
dt
dPB = 5 × 10 2 PB
2
or
dt
dPB = 10 1PB
2
CHEMISTRY
Code-A Page # 4
For 2nd order, kt
P
1
P
1
0
B B
or 0.1 t
1
1
0.1
1
or 10 = 1 + 0.1 t
or t = 90 sec. ]
Q.4
[Sol.
C
O
OH
H
(ii)NH Cl
(i)PrMgBr (excess)
4
OH
HO
*R/S
(A)

H
E/2
E/2
(4) Product
Al O 2 3
CH2
CH3
(5 H)
Th O2
CH2
CH3
(5 H)
PHYSICS
Code-A Page # 1
PART-A
Q.2
[Sol. Electric field]
Q.3
[Sol.
k
M
2 At the mean position of plate A spring will be elongatd by
2A k
Q
0
2
]
Q.4
[Sol.
R0
x
=

100
Since null point remains unchanged
R'
x
=
60
40
R' = 6
and 6 = R 78
78R
t
t
Rt = 6.5
= R t
R R
0
t 0
= 8.3 × 10 4 k 1 ]
Q.6
[Sol. In steady state, P.D. across each capacitor is same, i.e. V/2 ]
Q.7
[Sol. EO =
0.01
0.02
= 2 V/m
Er = 2 5
EO = 4 5 4 = 4 V/m
Er = j
2
6
i
2
2 = j 2 3 i 2 ]
Q.8
[Sol. v1 wg = (v v) ig + v( m)g
v2 wg = (v v) ig + v( 'm)g
2
1
v
v
= '
i m
i m
(v v) v
(v v) v

=
'
i m
i m
1
v
v
1
v
v

=
1 0.9 1.9
20
1000
1 0.9 4.9
20
1000

=
46
49
Ans ]
Q.9
[Sol. Mass of cavity is more in cube A than in cube B. ]
Q.10
[Sol. So long as cubes are floating, respective water levels do not change.
Let at t = t0, cube A sinks.
v wg = (v v) ig + v mg
PHYSICS
Code-A Page # 2
v is volume of cube which is changing linerarly with time at t > t0.
v wg + NA = (v v) ig + v mg
after sinking water level decreases due to melting of ice,
10
1
dt
dv
= A
dt
dh1 ; A-cross-section of vessel
Let at t = t0', cube B sinks
v' wg = (v' v) ig + v 'mg
10
1
dt
dv'
= A
dt
dh2
dt
dv
=
dt
dv'
dt
dh1 =
dt
dh2 ; final heights are same in both reach. ]
Q.13
[Sol. By Kepler s law T2 R3 ]
Q.14
[Sol. 0 0
3
eA 4T0 T T kA T T
dt
dQ
Q.15
[Sol. Obrivation in 'A' can be explained only when we assume energy of incident
radiation to be in form some
packets. Observation in 'B' and 'C' can be explained by Einstein formula
hc
K which supports
particle nature.]
PART-B
Q.1
[Sol.
(A) r1 = 30° , r2 = 70°
c = 45°
(B) r1 = 30° , r2 = 0°
light emerges normally from surface QR.
(C) 1 sin 90 2 sin r1
r1 = 45°
1 sin e
2
1
2
e = 90°
Light emerges grazing from surface QR]
PART-C
Q.1
[Sol. (4 r2) (Intensity) = Power =
Time
Energy
So Time =
(4 (1.5 10 m) )(1400W/m )
(2 10 kg)(30 10 J / kg)
11 2 2
30 6

= 48.05 centuries 48 Century]

PHYSICS
Code-A Page # 3
Q.2
[Sol. Potential difference across the capacitor is
VB O = C
q0 =
4
16
= 4 volt
E.M.F. of the battery = 24V , Y = 24
Time constant
= RC
= (4 ) (4 F)
= 16 s
Equation of discharge
q = q0e t/
4 µC = 16 µC

16
X
e
A C
B
D
4V
4 F
+ +
3 6
4 4
X = 32 ln2 ]
Q.3
[Sol. Since, A and B connected,
Hence |V1| = | V2 |
E1d1 = E2d2
+5µC
Q1 E1
A
10µC
B
+5µC
Q2
+Q2
+Q1
E0 2
2 2
0
1d1 d

1d1 = 2d2 or 5 1= 8 2
8
5
2
1
Ans. ]
Q.4
[Sol. 62.1 eV =
0
hc
=
0
1242eV nm

= 0 = 20 nm
Photoelectric emission takes place only for 1 and 2.
Now, for any wavelength
In time t Energy incident = Pt
In time t No. of photon incident = hc
Pt
hc
Pt

Number of photoelectrons emitted =

hc
pt
2
1
Charge developed =
(e)
hc
pt
2
1
Potential of sphere = 2hcr
pte
4
1
r
kq
0

Potential difference across the resistor = 2hcr

pte
4
1
0
 V1 =

2r
pte
4 hc
1 1
0
V2 =

2r
pte
4 hc
1 2
0
PHYSICS
Code-A Page # 4
V1 = ( 9 × 109) 3
3
2 10
(10 )t(e)
1242eV nm
12.42nm

= t
2
1
100
1
10 9 9

= 4.5 × 107 t
V2 = 3
3
9
2 10
(10 )(t)(e)
1242eV nm
6.21nm
(9 10 )

2
t
200
1
9 10 9
= 10 t
2
4.5 7
V = V1 + V2 = (4.5) 10 t
2
3 7
I =

6.75M
6.75 10 t
R
V 7
= 10 t
at t = 8 sec.
I = 10 × 8 = 80 Ampere Ans. ]
MATHEMATICS
Code-A Page # 1
PART-A
Q.1
[Sol. Consider a function, g(x) =
x
a
f (x)dx g ' (x) = f (x)
As f (x) continuous g is derivable.
Using L.M.V.T. for g in [a, b], there exists some c (a, b) such that
g ' (c) =
b a
g(b) g(a)

f (c) =
b a
f (x)dx 0
b
a
So,
b
a
f (x)dx = (b a) f(c). Ans.]
Q.2
[Sol. The distance between the given parallel lines (h) is
5
2 1
=
5
1
Length of the side of the triangle is =
3
2h
60°
15
P
Q R
y + 2x = 1
3y + 6x = 6
M
h
Area of triangle =
3
4h ·
4
3 2
=
3
h2
=
5 3
1
. Ans.]
Q.3
[Sol. The volume of tetrahedron =
6
1
OA OB OC =
6
1
0 1 1
1 1 0
1 0 0
=
6
1
Now area of base =
2
1
i
k
j i j i =
2
1
k
i
=
2
1 2 =
2
1
Hence, height =
Area of base
3 Volume
=
6
3 2
=
2
1
units.]
Q.4
[Sol. The given equation denotes that PA + PB = 13
x2 (y 12)2 (x 5)2 y2 = 13
(5, 0)
5
(0, 12)
P (x, y)
X
Y
(0, 0) O
B
A
Point P lies on line segment AB ]
Q.5
[Sol. Let I = cos(t e )dx
n t
n t
x
l
l
; Put tex = y t ex dx = dy
I =
t2
1 y
cos(y)dy
MATHEMATICS
Code-A Page # 2
y ' (t) = 0
t
(cos t ) 2t
dt
dI
2
2
=
t
2cos t 2
So, y '(1) = 2 cos 1. Ans.]
Q.6
[Sol. Vector perpendicular to k j i 2 and k j 3 i is
k
5 j i 2
1 3 1
2 1 1
k
j i

Any general point on the line is (1 + 2 , 1 + , 1 ) at their point of intersection.

This point satisfies
equation of plane (1 + 2 ) + 3(1 + ) (1 ) = 9 = 1
Point of intersection is (3, 2, 0).
Hence required line is k 5 j i 2 k j 2 i r 3
5
z
1
y 2
2
x 3

Ans.]
Q.7
[Sol. c = 20 ; = ab
2
1
s a = 7 and s b = 13
a b = 6 ....(1)
and a2 + b2 = 400
(a b)2 + 2ab = 400 ab = 182
Hence = ab
2
1
= 91 Ans.]
Paragraph for question nos. 8 to 10
[Sol. f (x) = x e x
f ' (x) = e x (1 x) = 0 x = 1 = 1 [12th, 03-09-2010, P-1]
Also, q p = L ........(1)
Now PN = QM
p e p = q e q
O
P Q
x=1
R
x
y
N
p
q
L
M
y=xe x
x=
p · eq p = q
p eL = q ........(2)
From (1) and (2)
p =
e 1
L
L
and q =
e 1
Le
L
L
Ans.(i)
Also maxima occurs at x = 1 = 1 and f "(x) = e x (1 x) e x
= e x ( 1 1 + x) = e x (x 2)
f "(x) = 0 x = 2 (which is the point of inflection)
Hence = 2
= 1 Ans.(ii)
Again RQ = (q 1) and PR = 1 p
(RQ PR) = (q 1) (1 p)
= q + p 2
MATHEMATICS
Code-A Page # 3
=
e 1
Le
L
L
+
e 1
L
L
2 =
e 1
Le L 2e 2
L
L L

Let g(L) = LeL + L 2eL + 2 (eL 1 > 0)

g '(L) = LeL + eL + 1 2 eL
= LeL + 1 eL = eL (L 1) + 1
g "(L) = eL + (L 1) eL = L eL > 0
g '(L) is increasing function
g '(L) > g '(0) (but g ' (0) = 0)
g '(L) > 0
g(L) is increasing function
g(L) > g(0)
g(L) > 0 Ans.(iii) ]
Q.11
[Sol. Statement-1: For example :

2 4
4 7 ,B 1 2
5 3 A A B =

2 3
2 3
det. (A B) = 0 but A B.
Statement-2: Suppose A is non-singular, then A 1 will exist.
AB = O A 1 AB = A 1 O B = O (which is not so.)
So, A must be singular. Ans. ]
Q.12
[Sol. f (x) = 3x 1 + x 105 is strictly increasing and so f (x) = 0 has at most o
ne solution
and f (5) = 19 < 0 and f (6) = 144 > 0, so f (x) has exactly one solution in (5,
6)
but x is an integer and hence no solution in (5, 6) (D)]
Q.13
[Sol. If three lines are concurrect then
p 2 2p 5 0
p 1 p 7 5
1 1 1
2

= 0
(p 3) (p2 p + 2) = 0
D < 0
p = 3 but at p = 3, all lines are parallel to each other. ]
Q.14
[Sol. v · u u · v w w v · v u · v u
= v · u u v w u·v w v u
= 0 which vanishes
(A) f '(1 ) = 1.
(B) is obviously zero.
(C) LHS (x2 3)2 0
RHS = x (3x2 + 5) 0 for x 0 LHS RHS for any x 0
Hence number of negative real solution of the equation is '0'. Ans.]
MATHEMATICS
Code-A Page # 4
Q.15
[Sol.(A) f "(x) > 0 x R f '(x) is a strictly increasing function hence f '(1) >
f '(0),
but given f '(0) = f '(1) = 1
Which is not possible.
(B) f "(x) > 0, x R f '(x) is increasing
f '(1) > f '(0) which is true. O
such a function is possible.
(C) f "(x) 0 f '(x) is increasing and y = f(x) must be concave up.
Since f(x) 100 for all x > 0 which means that a function always concave
up and increasing should also be asymptotic to a line y = 100 which is
not possible. (think !)
f ' (0) = 1 is not possible
O
100
fig. (C)
(D) Exists
consider f(x) = ex
O
(0,1)
]
Q.16
[Sol.
(A) The graph do not need to intersect (e.g. f(x) = e x and g (x) = e x).
So that f '(x) = e x and g(x) = e x
The graphs could intersect (e.g. f(x) = 2x and g(x) = x).
However, if they do intersect, they will intersect no more than once because f(x
) grows faster than g(x).
(B) We have f (x) =
4
x3
 sin x + 3
Now f ( 2) = 2 + 3 = 1
and f (2) = 2 + 3 = 5
By intermediate value theorem, there exists some c ( 2, 2) such that f (c) =
2
.
(C) l = cos45° = 2
1
, m = cos120° = 2
1
and n = cos
where is the angle which line makes with positive z -axis.
Now l2 + m2 + n2 = 1
2
1
+
4
1
+ cos2 = 1 cos2 =
4
1
cos =
2
1
( being acute.)
=
3
(D) f (x) = (x )p(x )q = ep ln (x ) + q ln (x ). [Rolle's theorem holds for f(x
f ' (x) = f (x)

x
q
x
p
f ' (c) = 0 p(c ) + q(c ) = 0 (c,0)
p q
c(p + q) = q + p
c = p q
p q

]
MATHEMATICS
Code-A Page # 5
PART-B
Q.1
[Sol.
(A) 3 distinct x intercepts x3 3x2 + k = 0
Let y = x3 3x2 and y = k
y' = 3x2 6x = 3x (x 2)
y" = 6x 6
O
y
x
2
3
4
y = k
Hence k ( 4, 0)
k (0, 4)
k = 1, 2, and 3. Ans.]
(B) We have, sin 1x + tan 1x = k
As range of the function sin 1 x + tan 1x is

4
3
,
4
3
(domain is [ 1, 1] )
Integral values of k are five i.e., 2, 1, 0, 1 and 2 5 Ans.]
(C) Take dot with ) k j i ( × ) k ( j to get the equation of the plane is 2x +
= 0
Now find p1 =
6
1
and p2 = 6 to get pq = 1. Ans.]
PART-C
Q.1
[Sol. Clearly, (a 2) 2 + (b 3) + c = 0
(a 2) 2 + (b 3) + c = 0 (As x, y and (x y)
are non coplanar.)
and (a 2) 2 + (b 3) + c = 0
The equation (a 2) x2 + (b 3) x + c = 0 has 3 distinct roots.
Above equation will be an identity
a 2 = 0 a = 2
b 3 = 0 b = 3
c = 0
a2 + b2 + c2 = 13 Ans.]
Q.2
[Sol. Digits are 1, 2, 3, ............, 7, 8, 9.
For 5 digits numbers, we need 3 digits which can be selected in 9C3 ways say (1,
2, 3).
Out of these 3 digits, one is to be used once and other two twice.
To be used once can be taken in 3C1 (say 1)
Hence the number is 12233
Number of 5 digit numbers = 2 ! 2 !
5 !
Total = 9C3 · 3C1 · 2 ! 2 !
5 !
= 84 · 3 · 30 = 84 · 90 = 7560. Ans.]
Q.3
[Sol. 2v v a b
...(1) (Where j 2 i a and k
i
b 2
, b a · = 2 )
dot with a
gives,
2 V · a 0 a · b 2
V · a
= 1
Again cross with a
gives,
MATHEMATICS
Code-A Page # 6
2 V a V a a b a

2 [b 2V] V· a a a · a V b a

2 b 2V a 5V b a

or 9V 2b a b a
.......(2)
Now b a
=
1 2 0
2 0 1
k
j i
= ) 4 ( k ) 1 ( j ) 2 ( i = k 4 j i 2 ......(3)
2b a
= k 2 j 0 i 4 + k 0 j 2 i = k 2 j 2 i 5 ......(4)
Now (4) (3) given
k 6 j i 7 k 4 j i 2 k 2 j 2 i 5
Hence k 2 j i 9V 7
9 V 54
9 V 3 6
3 V 6
m = 6. Ans.]
Alternatively : Let k z j y i v x
Now putting v
in the equation k
i
2 ) j 2 i 2v v ( , we get
k z 2 j y 2 i x 2 + k ) y x 2 ( j z i z 2 = k
i
2
On comparing, we get
2(x z) = 2 ; 2y + z = 0 ; 2z + 2x y = 1
So, on solving we get
9
2
, z
9
1
, y
9
7
x
.
k 2 j i 9v 7
9 v 54 3 6
3 v 6
m = 6. Ans.]
Q.4
[Sol.

1 7 x 8
(x 6) 5 x 7
1 4 x 5
(x 3) 2 x 4
1 1 x 2
x 1 x 1
f (x)
2
2
2
for r 6
for r 3
for r 0

1 2 3 4 5
x
y
1 0
From the graph of f(x), it is clear that f(x) is periodic with period 3.
Now,
45
0
dx ) x ( f = 15
3
0
f (x) dx = 15
2
1
f (x) dx = 15
2
1
1
1
x2 dx 1·dx
= 15

1
3
2
= 25 Ans.]