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Mechanisms of Creep in metals: There are three basic mechanisms that can
contribute to creep in metals, namely:
(i) Dislocation slip and climb.
(ii) Grain boundary sliding.
(iii) Diffusional flow.
Dislocation slip and climb: Dislocations are line defects that slip through a
crystal lattice when a minimum shear stress is applied. Dislocations initially slip
along the closest packed planes in the closest packed directions since this
requires the least energy or applied stress. An edge dislocation consists of an
unfinished atomic plane, the edge of the plane being the line of the dislocation,
and it is characterised by a Burgers vector, or 'misfit strain' at 90o to the
dislocation line. Screw dislocations have a Burgers vector parallel to the
dislocation line and can slip on any close packed plane containing both line and
Burgers vector, whereas edge dislocations only slip on the plane defined by the
line and the perpendicular Burgers vector. Figure 13 shows an edge dislocation
slipping through a crystal lattice (simple cubic for simplicity) and producing a unit
of slip called a slip step, on the surface of the crystal.
l.
Figure 13: Showing slip of an edge dislocation.
When a polycrystalline metal is deformed many of the grains will have slip planes
suitably aligned to the applied stress, and slip will occur when the shear stress
exceeds the critical resolved shear stress. Dislocations multiply at sources,
e.g. Frank-Read sources, and as the dislocation density increases, more
dislocation interactions occur. Dislocations may entangle or cut through each
other, leaving slip steps on the dislocation lines called jogs, and if one of the
dislocations is sessile, or immobile, the jogs can hinder slip. Dislocations arriving
at grain boundaries may not be able to slip into the next grain due to a different
orientation, and consequently will form a 'pile-up' at the boundary. Any following
dislocation will be repelled by the pile-up because of the long-range elastic
forces between dislocations of a similar sign. The elastic strain energy per unit
length of a dislocation is given by: E ≅ 0.5Gb 2 ...(5) where G is the shear
modulus of elasticity and b is the Burgers vector. (Compare this with
macroscopic strain energy: U = 0.5σε = 0.5 Eε 2 where E is Young's modulus). If
two dislocations of the same sign were to be moved together, their associated
strain would double to 2 b , and the energy would quadruple to become
E ≅ 0.5G (2b ) = 2Gb 2 , hence the repulsion between dislocations which must be
2
overcome by the applied stress. This and the above mechanisms contributes to
work hardening of the metal, i.e. as the metal is deformed, plastic flow becomes
increasingly more difficult and more stress has to be applied to accomplish it. In
the primary stage of a creep test, the stress is constant and these mechanisms
lead to a decreasing strain rate.
During secondary or steady state creep, the increased strain energy stored in the
metal due to deformation, together with the high temperature, provides a driving
force for the process of recovery. There is therefore a balance between the
processes of work hardening and recovery. Recovery involves the reduction in
dislocation density and the rearrangement of dislocations into lower energy
arrays or sub-grain boundaries. In order for this to happen, dislocations have to
climb as well as slip, and this in turn requires atomic movement or self-diffusion
within the lattice. Self-diffusion is only possible in a close packed lattice if the
atoms have enough energy to jump into a neighbouring site and if there is a
vacancy at that site. As temperature increases atoms have more thermal
energy (proportional to RT) and the equilibrium concentration of vacancies in a
metal increases exponentially. The number of vacancies nv , is given by:
æQ ö
nV = n0 exp− ç v ÷ ...(6), where n0 is the number of lattice sites and Qv is the
è RT ø
activation energy for vacancy creation and movement, (or the activation energy
for self-diffusion). For copper, where
Qv is 0.7 eV per atom, (an electron volt, 1 eV = 1.6.10-19 Joules) the ratio nv no is
about 10-3 at 1300 K and about 10-12 at 300 K.
Note: If Qv is quoted in Joules per mole, then the gas constant R is used, where
R = 8.314 J K-1 mol-1, but if Qv is quoted in joules per atom, then the formula
æQ ö
nV = n0 exp− ç v ÷ is used where k is the Boltzmann Constant ( k =1.38.10-23 J K-
è kT ø
1
). This is because Qv in Joules per mole is N0 times Qv in Joules per atom,
where N0 is Avogadro's Number, the number of atoms in a gram-atom or gram-
mole (6.022.1023 mol-1). Since R = N0 k this gives the same ratio.
The rate of steady state creep increases exponentially with increasing
temperature, since its rate is controlled by vacancies, the numbers of which also
increase exponentially with temperature. Figure 14 shows the mechanism of
self-diffusion by vacancy movement.