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Applications of methanol
Product (in w.%) 1988 1996 2005
Formaldehyde 39 35 38
Acetic acid 6 7 11
Methyl halides 7 7 7
MTBE 12 27 20
Dimethyl terephthalate 3 2 2
Methyl amines 4 4 4
Methyl methacrylate 3 3 4
Solvents 9 4 4
Others 17 11 13
Sum (in mio t/a) 17,3 24,3 32,1
Methanol from syngas
CO + 2H2 ⇌ CH3OH (ΔH = -92 kJ/mol)
Cu/ZnO/Al2O3 catalysts
CuO (wt %) > 55
ZnO (wt %) 21-25
Al2O3 (wt %) 8-10
H2 H2 : H2O = 1 : 3 H2 : CO = 95 : 5
Equilibrium CO conversion to methanol
Zn/Cr2O3
Cu/ZnO/Al2O3
ATR
H2 – CO2
Module M = 2 =
CO + CO2
Purification of syngas
Industrial processes
Natural
Compression Distillation
gas Reforming
(a)
• Cooling with water bath; (b)cooling with water coils; (c) cooling with cold feed;
(d) feed gas quench; (e) feed–effluent heat exchange by periodic flow reversal;
(f) lateral flow; (g) fluidised bed.
99.9% MeOH
• Temperature: 350°C
• Pressure: 300 bar
• Catalyst: ZnO-Cr2O3
→ similar conditions like in the BASF process
Difference:
Lower partial pressure for CO (13 bar) used:
• Reactor can be built from steal as Fe(CO)5 is not produced
• Purity of methanol very good
New industrial developments