Atmospheric Residue (High and Low Sulphur Content) Waxy Distillate/ Heavy Vacuum Gas Oil

Sheet No: STI2205 Material Name: Atmospheric Residue (high and low sulphur content)
ALIGN BP SDS Finals

Safety Data Sheet - SDS
GLIS Sheet No:STI2205 SDS Reference:

Paper Type: BP Helios Status: Active
Material Name: Atmospheric Residue (high and low sulphur content)
Waxy Distillate/ Heavy Vacuum Gas Oil
Language:English Country:OTI
Revision of Sheet Dated:02/09/98 Major Change: Hazard?:Yes
Hazardous Components: Physical Characteristics: Fuel oil Tox File: 279.10 Product Group:
Date of Issue: 17/07/2000
________________________________________________________________________________
SAFETY DATA SHEET
Atmospheric Residue (high and low sulphur

content)
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Identification of substance/preparation
Atmospheric Residue (high and low sulphur content)
Alternative Names: Heavy Vacuum Distillate
Application
Refinery feedstock
Fuel blending component
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
BP Oil International Limited
Britannic House
1 Finsbury Circus
London, EC2M 7BA
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Emergency Telephone Number

+44 (0) 20 7496 4411
_________________________________________________________________________________
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Composition
Complex hydrocarbon substance, one of the following:
Residues (petroleum), atm. tower. EINECS No: 265-045-2, CAS No: 64741-45-3
Residues (petroleum), atmospheric. EINECS No: 269-777-3, CAS No: 68333-22-2
Gas oils (petroleum), heavy vacuum. EINECS No: 265-058-3, CAS No: 64741-57-7
Hazardous Components
Hydrogen sulphide (H2S), an extremely toxic and highly flammable gas, and other flammable light hydrocarbon gases
may collect in vapour spaces where product is stored.
Polycyclic aromatic hydrocarbons will be present, some of which have been shown by experimental studies to induce
skin cancer.
_________________________________________________________________________________
3. HAZARDS IDENTIFICATION
Contact with hot product may cause burns.
May cause cancer, classified as a category 2 carcinogen.
This material may contain significant quantities of polycyclic aromatic hydrocarbons (PCAs), some of which have been
shown by experimental studies to induce skin cancer.
Repeated exposure may cause skin dryness or cracking.
Vapours containing hydrogen sulphide may accumulate during storage or transport and may also be vented during
filling of tanks. Hydrogen sulphide has a typical "bad egg" smell but at high concentrations the sense of smell is rapidly
lost, therefore do not rely on sense of smell for detecting hydrogen sulphide. Use specially designed measuring
instruments for determining its concentration.
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
_________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water, ensuring eyelids are held open. Obtain medical advice if any
pain or redness develops or persists.
If hot material enters the eye, flood immediately with cold water to dissipate the heat, if possible, ensuring eyelids are
held open. Take the casualty to hospital for examination and treatment without delay.
Skin
Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing
and wash underlying skin.
If hot product causes burns, the affected area should be flooded immediately with, or immersed in cold water for 10
minutes, or longer if pain persists. Burns should be covered with clean cotton or gauze, and the casualty taken to
hospital as soon as possible for examination and treatment.
Never use gasoline, kerosine or other solvents to remove fuel oil from skin or clothing.
Medical advice must be obtained urgently if product under high pressure has been injected through the skin.
Ingestion

If contamination of the mouth occurs, wash out thoroughly with water.

Except as a deliberate act, the ingestion of large amounts of product is unlikely. If it should occur, do not induce
vomiting; obtain medical advice.
Inhalation
If inhalation of mists, fumes or vapour causes irritation to the nose or throat, or coughing, remove to fresh air. If
symptoms persist obtain medical advice.
EXPOSURE TO HYDROGEN SULPHIDE:
Casualties suffering ill effects as a result of exposure to hydrogen sulphide should be immediately removed to fresh air
and medical assistance obtained without delay.
Unconscious casualties must be placed in the recovery position. Monitor breathing and pulse rate and if breathing has
failed, or is deemed inadequate, respiration must be assisted, preferably by the mouth to mouth method. Administer
external cardiac massage if necessary. Seek medical attention immediately.
It is advisable that all who are engaged in operations in which contact with H2S may reasonably be anticipated, should
be trained in the techniques of emergency resuscitation and in the care of an unconscious patient.
Medical Advice
If ingested, do not induce vomiting.
Inhalation of hydrogen sulphide may cause central respiratory depression leading to coma and death. It is irritant to the
respiratory tract causing chemical pneumonitis and pulmonary oedema. The onset of pulmonary oedema may be
delayed for 24 to 48 hours. Treat with oxygen and ventilate as appropriate. Administer broncho-dilators if indicated and
consider administration of corticosteroids. Keep casualty under surveillance for 48 hours in case pulmonary oedema
develops.
Note: High Pressure Applications

Injections through the skin resulting from contact with the product at high pressure constitute a major medical
emergency. Injuries may not appear serious at first but within a few hours tissue becomes swollen, discoloured and
extremely painful with extensive subcutaneous necrosis.
Surgical exploration should be undertaken without delay. Thorough and extensive debridement of the wound and
underlying tissue is necessary to minimise tissue loss and prevent or limit permanent damage. Note that high pressure
may force the product considerable distances along tissue planes.
_________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
For major fires call the Fire Service. Ensure an escape path is always available from any fire.
Use foam, dry powder or carbon dioxide. DO NOT USE water jets. Avoid spraying directly into storage containers
because of the danger of boil-over.
Fires in confined spaces should be dealt with by trained personnel wearing approved breathing apparatus.
Combustion Products
Toxic fumes may be evolved on burning or exposure to heat.
See Stability and Reactivity, Section 10 of this Safety Data Sheet.
_________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
Ensure good ventilation.
Evacuate all non essential personnel from the immediate area.
Wear protective clothing. See Exposure Controls/Personal Protection, section 8, of this Safety Data Sheet.
Depending upon its temperature the product may be liquid, semi-solid or solid.
Protect drains from spills and prevent entry of product, since this may result in blockage on cooling. Should blockage
occur, notify the appropriate authority immediately.
Scrape up bulk of solid material and remove liquid with sand or other suitable inert absorbent material. If necessary,
clean the contaminated area using hot water and detergent: absorb the washings - do not wash into drains.

Spilled material may make surfaces slippery.

Recovery of large spillages should be effected by specialist personnel.
It is advised that stocks of suitable absorbent material should be held in quantities sufficient to deal with any spillage
which may be reasonably anticipated.
Large and uncontained spillages should be smothered with foam to reduce the risk of ignition.
The foam blanket should be maintained until the area is declared safe.
Spillages of hot product in confined spaces may be especially hazardous because highly toxic hydrogen sulphide gas
may be present. For spillages in such confined spaces the use of approved breathing apparatus by personnel specially
trained in its use may be required.
Vapour may collect in any confined space.
In the case of spillage on water, prevent the spread of product by the use of suitable barrier equipment. Recover
product from the surface. Protect environmentally sensitive areas and water supplies.
The product may sink making recovery difficult.
In the case of spillage at sea approved dispersants may be used where authorised by the appropriate
government/regulatory authorities.
Regular surveillance on the location of the spillage should be maintained.
In the event of spillages contact the appropriate authorities.
_________________________________________________________________________________
7. HANDLING AND STORAGE

Storage Conditions
Store and dispense only in well ventilated areas away from heat and sources of ignition.
Store and use only in equipment/containers designed for use with this product.
Containers must be properly labelled and kept closed when not in use.
Do not remove warning labels from containers.
Empty packages may contain some remaining product. Retain hazard warning labels on empty packages as a guide to
the safe handling, storage and disposal of empty packaging.
Do not enter storage tanks without breathing apparatus unless the tank has been well ventilated and the tank
atmosphere has been shown to contain hydrocarbon vapour concentrations of less than 1% of the lower flammability
limit and an oxygen concentration of at least 20% volume.
Confined spaces contaminated with hydrogen sulphide must always be considered as constituting potentially life
threatening environments. Entry into such spaces must never be undertaken except under extreme emergency when
no alternative is possible and then only by trained operators wearing air-supplied breathing apparatus of an approved
type and following procedures strictly in accordance with the Statutory Regulations governing such entry. Please see
the comments in Section 8 (Exposure Controls/Personal Protection) of this data sheet.
Always have sufficient people standing by outside the tank with appropriate breathing apparatus and equipment to
effect a quick rescue.
It is advisable that all who are engaged in operations in which contact with hydrogen sulphide may be reasonably
anticipated, should be trained in the techniques of emergency resuscitation and in the care of an unconscious patient.
Handling Precautions
Ensure good ventilation and avoid as far as reasonably practicable the inhalation and contact with vapours, mists or
fumes which may be generated during use. If such vapour, mists or fumes are generated, their concentration in the
workplace air should be controlled to the lowest reasonably practicable level.
Avoid contact with skin and observe good personal hygiene.
Avoid contact with eyes. If splashing is likely to occur wear a full face visor or chemical goggles as appropriate.
Avoid inhalation of dust from combustion/exhaust spaces.
Whilst using do not eat, drink or smoke.
Wash hands thoroughly after contact.
Use disposable cloths and discard when soiled. Do not put soiled cloths into pockets.
Take all necessary precautions against accidental spillage into soil or water.

Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. These can cause flammability/explosion hazards
even at temperatures below the normal flash point (note: flash point must not be regarded as a reliable indicator of the
potential flammability of vapour in tank headspaces). Tank headspaces should always be regarded as potentially
flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling, ullaging
and sampling from storage tanks.
Will present a flammability hazard if heated above flash point but bulk liquids at normal storage temperatures will
present virtually no fire hazard. If fuel contacts hot surfaces, or leaks from high pressure fuel pipes, the vapour and/or
mists generated will create a flammability or explosion hazard.
When the product is pumped (e.g. during filling, discharge or ullaging) and when sampling, there is a risk of static
discharge. Ensure equipment used is properly earthed or bonded to the tank structure.
Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be
allowed to accumulate. Dispose of safely immediately after use.
Empty containers represent a fire hazard as they may contain some remaining flammable product and vapour. Never
cut, weld, solder or braze empty containers.
_________________________________________________________________________________
8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Limits
There is no appropriate occupational exposure limit for this material.
Avoid, as far as reasonably practicable, inhalation of vapour, mists or fumes generated during use.
If vapour, mists or fumes are generated, their concentration in the workplace air should be controlled to the lowest
reasonably practicable level.
Relevant exposure limits are:
Hydrogen sulphide
ACGIH (USA): TLV 10 ppm (8 hr TWA); 15ppm (15 min STEL)
Protective Clothing
Wear face visor or goggles in circumstances where eye contact can accidentally occur.
When handling heated material suitable protective clothing of an appropriate standard should be worn to prevent
thermal burns.
If skin contact is likely, wear impervious protective clothing and/or gloves.
Protective clothing should be regularly inspected and maintained; overalls should be dry-cleaned, laundered and
preferably starched after use.
Respiratory Protection
If operations are such that the excessive generation of vapour, mist or fume may be anticipated, to which operators
may unavoidably be exposed, then suitable approved respiratory equipment should be worn. Note: Approved air-
supplied breathing apparatus must be worn where there may be potential for inhalation of hydrogen sulphide gas.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
_________________________________________________________________________________
9. PHYSICAL AND CHEMICAL PROPERTIES

Typical Values

Grades: Atmospheric Waxy

Residue (high Distillate /
and low Heavy
sulphur Vacuum Gas
content) Oil
Test Method Units
Physical state liquid liquid
Colour black dark brown
Odour oily characteristic
Density @ 15°C ASTM D 1298 kg/m³ 900 900
Kinematic viscosity @ ASTM D 445 mm²/s 6 - 12
100°C
Boiling point/range ASTM D 86 °C >300
Flash point (PMC) ASTM D 93 °C >61 >100
Pour point ASTM D 97 °C 10 - 50
_________________________________________________________________________________
10. STABILITY AND REACTIVITY

Stable at ambient temperatures.
Hazardous polymerisation reactions will not occur.
Materials to Avoid
Avoid contact with strong oxidizing agents.
Hazardous Decomposition Products

Thermal decomposition products will vary with conditions.
Overheating in storage may cause partial vapourisation and decomposition with the production of toxic
hydrogen sulphide gas (H2S).
Incomplete combustion will generate smoke, carbon dioxide and hazardous gases, including carbon monoxide.
Fuel oil ash/dust can be hazardous if inhaled. Before working in combustion/exhaust spaces or handling fuel oil
ash/dust the area should be thoroughly damped down with water. If this is not possible, wear full breathing apparatus
or positive pressure filter sets. Protective clothing must always be worn. When inspecting combustion/exhaust spaces,
wear full face dust respirator and protective clothing.
_________________________________________________________________________________
11. TOXICOLOGICAL INFORMATION
Eyes
Unlikely to cause more than transient stinging or redness if accidental eye contact occurs.
Will cause burns if hot material contacts eyes.
Skin
Will cause burns if hot material contacts skin
As with all such products containing potentially harmful levels of PCAs, prolonged or repeated skin contact may
eventually result in dermatitis or more serious irreversible skin disorders including cancer.
Ingestion
Unlikely to be swallowed in view of the high handling temperatures.
Inhalation
May be irritating to eyes, nose and throat at high vapour concentrations.
May be toxic by inhalation when hydrogen sulphide is present in the vapour.

Hydrogen sulphide gas may in addition produce irritation of the eyes and respiratory tract.
Vapour, mists or fumes may contain polycyclic aromatic hydrocarbons some of which are known to produce skin
cancer. The inhalation of vapour, mists or fumes over long periods may therefore be hazardous.
Dusts generated during the removal of ash deposits from engine/boiler combustion surfaces or exhaust spaces, will be
harmful if inhaled and may cause nausea and eye, nose and throat irritation. Repeated contact may result in serious
irreversible disorders.
_________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages may penetrate the soil causing ground water contamination.
Persistence and degradability

This product is inherently biodegradable.
Bioaccumulative potential
This material may accumulate in sediments.
Aquatic toxicity
Harmful to aquatic organisms, may cause long term effects in the aquatic environment
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be
impaired.
German WGK Classification: Light fuel oil 2; Heavy fuel oil 1
_________________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
Dispose of by incineration or other suitable means under conditions approved by the local authority or via a licensed
waste disposal contractor.
At sea, used or unwanted product should be stored for eventual discharge into port approved waste oil disposal
facilities.
Empty packages may contain some remaining product. Hazard warning labels are a guide to the safe handling of
empty packaging and should not be removed.
_________________________________________________________________________________
14. TRANSPORT INFORMATION
Not classified as hazardous for transport (ADR, RID, UN , IMO, IATA/ICAO).
_________________________________________________________________________________
15. REGULATORY INFORMATION
EU Category of Danger
Carcinogenic category 2
Dangerous for the environment
EU Labelling
Symbol:
Skull and crossbones
Indication of danger:
None
Risk ( R ) Phrases:
R45 May cause cancer

R66 Repeated exposure may cause skin dryness or cracking

R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Safety ( S ) Phrases:
S53 Avoid exposure - obtain special instructions before use.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
S61 Avoid release into the environment. Refer to special instructions/Safety data sheets.
The label must carry the following additional information: "EC Label", Substance name, EINECS No.
Substance Name: Heavy Fuel Oil, EINECS No: 265-045-2, 265-058-3, 269-777-3
For non-fuel use only - "Restricted to professional users. Attention - Avoid exposure - obtain special instructions before
use." must be marked on packaging.
_________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the
date specified below. We have reviewed any information contained herein which we received from sources outside the
BP Amoco Group of Companies. However, no warranty or representation, express or implied is made as to the
accuracy or completeness of the data and information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable
laws and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or
authorization given or implied to practise any patented invention without a valid licence. The BP Amoco Group shall
not be responsible for any damage or injury resulting from abnormal use of the material, from any failure to adhere to
recommendations, or from any hazards inherent in the nature of the material.
Sheet Revisions
Date: Sections revised:
02/09/98 1, 4, 8, 11, 12, 15
17/07/2000 2, 3, 11, 8, 9, 13, 15
SHEET NO: STI2205

ISSUE DATE: 17/07/2000
REVISION OF SHEET DATED: 02/09/98
REPLACEMENT OF SHEET NO: STI2206 dated 21/09/98
______________________________________________________________________________

Sheet No: SUK2216 Date: 20/5/98 Name of Product: rBitumen or Vacuum residue
SAFETY DATA SHEET

___________________________________________________________________________
Bitumen or Vacuum residue
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF

THE COMPANY/UNDERTAKING
Bitumen or Vacuum residue
Application
Refinery stream
BP Oil UK Ltd, Coryton Refinery, The Manorway, Stanford-le-Hope, Essex SS17 9LL
BP Oil Grangemouth Refinery Ltd, Bo'Ness Road, Grangemouth, Stirlingshire FK3 9XQ

Coryton: +44 (0)1375 646000
Grangemouth: +44 (0)1324 483422
__________________________________________________________________________________
Asphalt. EINECS No. 232-490-9, CAS No. 8052-42-4
Residues (petroleum), vacuum. EINECS No: 265-057-8, CAS No: 64741-56-6
Asphalt, oxidised. EINECS No. 265-196-4, CAS No. 64742-93-4
Common refinery names: PDA, Asphalt,

__________________________________________________________________________________
This product can be delivered, stored and used at temperatures above 100 deg C.
Vapours containing hydrogen sulphide may accumulate during storage or transport and may also be vented during filling of
tanks. Hydrogen sulphide has a typical "bad egg" smell but at high concentrations the sense of smell is rapidly lost,
therefore do not rely on sense of smell for detecting hydrogen sulphide. Use specially designed measuring instruments for
determining its concentration.
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__________________________________________________________________________________
Eyes
Cold product - Wash eye thoroughly with copious quantities of water, ensuring eyelids are held open. Obtain medical
advice if any pain or redness develops or persists.
Hot product - Flood with water to dissipate heat. In the event of any product remaining, do not try to remove it other than
by continued irrigation with water. Obtain medical attention immediately.
Skin
Where skin burns occur the area should be immediately immersed in cold water until the bitumen is thoroughly cooled. Do
not attempt to remove the bitumen from the skin as it provides an airtight sterile covering over the burn which will
eventually fall away with the scab as the burn heals. If for any reason the bitumen must be removed, this can be done using
a slightly warmed medicinal liquid paraffin. Kerosene and other solvents should never be used. All burns should receive
medical attention. It should be noted that bitumen contracts on cooling and where a limb is encased care should be taken to
avoid the development of a tourniquet effect.
Ingestion
Except as a deliberate act, the ingestion of large amounts of product is unlikely. If it should occur, do not induce vomiting;
obtain medical advice.
Inhalation
If inhalation of mists, fumes or vapour causes irritation to the nose or throat, or coughing, remove to fresh air. If symptoms
persist obtain medical advice.
Casualties suffering ill effects as a result of exposure to hydrogen sulphide should be immediately removed to fresh air and
medical assistance obtained without delay.
Medical Advice
Treatment should in general be symptomatic and directed to relieving any effects.
respiratory tract causing chemical pneumonitis and pulmonary oedema. The onset of pulmonary oedema may be delayed
for 24 to 48 hours. Treat with oxygen and ventilate as appropriate. Administer broncho-dilators if indicated and consider
administration of corticosteroids. Keep casualty under surveillance for 48 hours in case pulmonary oedema develops.
__________________________________________________________________________________
Use foam, dry powder or water fog. DO NOT USE water jets.
FIRES IN CONFINED SPACES SHOULD BE DEALT WITH BY TRAINED PERSONNEL WEARING APPROVED
BREATHING APPARATUS.
Water may be used to cool nearby heat exposed areas/objects/packages. Avoid spraying directly into storage containers
Combustion Products

__________________________________________________________________________________
Scrape up bulk of solid material and remove liquid with sand or other suitable inert absorbent material. If necessary, clean
the contaminated area using hot water and detergent: absorb the washings - do not wash into drains.
It is advised that stocks of suitable absorbent material should be held in quantities sufficient to deal with any spillage which
may be reasonably anticipated.
If spillage has occurred in a confined space, ensure adequate ventilation and check that a safe, breathable atmosphere is
present before entry.
In the case of large spills contact the appropriate authorities. If spillage occurs call the Environment Agency Emergency
Hotline on 0800 807060 (24 hours a day, 7 days a week).
In the case of spillage on water, the product will sink and recovery may be difficult.
__________________________________________________________________________________
Avoid skin contact.
Good working practices, high standards of personal hygiene and plant cleanliness must be maintained at all times.
When product is heated to high temperatures, vapour, mists or fumes will be given off and may condense, contaminating
the skin or clothing of operatives. Prolonged or repeated contact with this condensate may give rise to dermatitis or other
skin conditions of a serious or irreversible nature.
Regular periodic self inspection of the skin is recommended, especially those areas subject to contamination. In the event
of any localised changes in appearance or texture of the skin being noticed, medical advice should be sought without delay.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. These can cause flammability/explosion hazards even at
temperatures below the normal flash point (note: flash point must not be regarded as a reliable indicator of the potential
flammability of vapour in tank headspaces). Tank headspaces should always be regarded as potentially flammable and care
should be taken to avoid static electrical discharge and all ignition sources during filling, ullaging and sampling from
storage tanks.
Product should not be over heated in storage because of the risk of fire. For advice on storage temperatures please contact
the local BP office.
Storage Conditions
Store under cover away from moisture and sources of ignition. Do not overheat in storage.
Under no circumstances should water be allowed to contact hot product because of the danger of boil-over. Particular care
should be taken to ensure that bulk storage tanks are watertight and that any steam heating coils are regularly checked for
leaks.
For bulk product, the storage temperature should not fluctuate above and below 100 deg C as this increases the risk of
water condensation leading to boil-over. Care must always be exercised when heating bitumen through 100 deg C.
Highly toxic hydrogen sulphide gas may be emitted from hot product and accumulate in enclosed spaces or tanks. Extreme
care must therefore be taken during venting of tanks and enclosed spaces which have at any time contained hot product.

Under no circumstances should entry be made into small enclosures without taking full precautions.
threatening environments. Entry into such spaces must never be undertaken except under extreme emergency when no
alternative is possible and then only by trained operators wearing air-supplied breathing apparatus of an approved type and
following procedures strictly in accordance with the Statutory Regulations governing such entry. Please see the comments
in Section 8 (Exposure Controls/Personal Protection) of this data sheet.
Always have sufficient people standing by outside the tank with appropriate breathing apparatus and equipment to effect a
quick rescue.
Pyrophoric (self-heating) deposits, which may cause fire or explosion, may be formed in storage. Avoid exposure of tank
vapour space to fresh air, and maintain stable storage temperatures. Regular inspection for such deposits will indicate when
tank cleaning is necessary.
__________________________________________________________________________________
Exposure Limits
Comply with current local occupational exposure limit. Where not established, the following limits are recommended.
Asphalt, petroleum fumes
UK publication EH40 (Occupational Exposure Limits):
Occupational Exposure Standard: Long-term exposure limit (8-hour TWA) 5 mg m-3
Short-term exposure limit (15 minute) 10 mg m-3

Hydrogen Sulphide
Occupational Exposure Standard: Long-term exposure limit (8hr TWA) 10 ppm, 14 mg/m3
Short-term exposure limit (15 min) 15ppm, 21 mg/m3
Protective Clothing
When handling hot product, suitable protective clothing of an appropriate standard should be worn. Depending on the type
of operation this may include:
- Visor to protect the face and head covering with neck flap.
- Gauntlets (heat resistant and impervious to bitumen)
- Overalls, impervious to bitumen, covering full body and limbs with legs worn over boots.
- Protective boots.
- Protective clothing should be regularly dry cleaned and laundered.
Change heavily contaminated clothing as soon as reasonably practicable; dry clean, launder and preferably starch before re-
use. Wash any contaminated underlying skin with soap and water.
If operations are such that the excessive generation of vapour, mist or fume may be anticipated, to which operators may
unavoidably be exposed, then suitable approved respiratory equipment should be worn. Note: Approved air-supplied
breathing apparatus must be worn where there may be potential for inhalation of hydrogen sulphide gas
__________________________________________________________________________________

Typical Values
Grades:Bitumen or Vacuum
residue
Test Method Units
Physical state solid
Colour black
Odour bituminous
Density @ 15°C ASTM D 1298 kg/m3 >1000
Flash point (COC) ASTM D 92 °C >200
Solubility in water g/l <0.1
Products of this type are stable and unlikely to react in a hazardous manner under normal conditions of use.
This material is combustible.
Materials to Avoid

Incomplete combustion will generate smoke, carbon dioxide and hazardous gases, including carbon monoxide, hydrogen
sulphide and oxides of sulphur.
__________________________________________________________________________________
Eyes
Skin
When product is heated to high temperatures, vapour, mists or fumes will be given off and may condense, contaminating
the skin or clothing of operatives. Prolonged or repeated contact with this condensate may give rise to dermatitis or other
skin conditions of a serious or irreversible nature.
Ingestion
Inhalation
At normal ambient temperatures this product will be unlikely to present an inhalation hazard because of its low volatility.
Vapour, mists or fumes may contain polycyclic aromatic hydrocarbons some of which are known to produce skin cancer.
The inhalation of vapour, mists or fumes over long periods may therefore be hazardous.

__________________________________________________________________________________
Mobility
Spillages are unlikely to penetrate the soil.

This material is not biodegradable.
This material is not expected to bioaccumulate.
Aquatic toxicity
Unlikely to cause long term effects in the aquatic environment.
__________________________________________________________________________________
Where possible, arrange for product to be recycled.
Dispose of by incineration or other suitable means under conditions approved by the local authority or via a licensed waste
disposal contractor.
__________________________________________________________________________________
COLD - Not classified as hazardous for transport (ADR, RID, UN, IATA/ICAO).
HOT - Conform to local requirements, if none exist recommend:-

ADR/RID: Elevated temperature liquid n.o.s., Class 9 Item 20 °(c), Hazard Identification No. 99
UN: Elevated temperature liquid n.o.s., Class 9, Packing Group III, UN No. 3257
IATA/ICAO: Forbidden for transport on passenger and cargo aircraft in molten state.
IMO: Elevated temperature liquid n.o.s., Class 9, Packing Group III
EMERGENCY ACTION CODE: 2W
Note
Under ADR emptied uncleaned tankers are classified as follows :-
Emptied container class 9, item 71 ADR Latest cargo 3257 Liquid elevated temperature NOS, item 20(c).
__________________________________________________________________________________
Not classified as hazardous for supply.Not classified as hazardous for supply. No Statutory label required.
__________________________________________________________________________________
Compiled by:
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN

This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the date
specified below. We have reviewed any information contained herein which we received from sources outside the BP
Group of Companies. However, no warranty or representation, express or implied is made as to the accuracy or
completeness of the data and information contained in this data sheet.
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable laws
and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or authorization
given or implied to practise any patented invention without a valid licence. The BP Group shall not be responsible for any
damage or injury resulting from abnormal use of the material, from any failure to adhere to recommendations, or from any
hazards inherent in the nature of the material.

Sheet No: STI2201 Material Name: Crude Oil Issue Date : 17/07/2000 Revision of Sheet Dated:25/09/98 Page:
ALIGN BP SDS Finals


Material Name: Crude Oil
Hazardous Components: Physical Characteristics: Fuel oil Tox File: 418 Product Group:
________________________________________________________________________________
SAFETY DATA SHEET
Crude Oil
COMPANY/UNDERTAKING
Crude Oil
Application
Refinery feedstock
Britannic House
1 Finsbury Circus
London, EC2M 7BA

+44 (0) 20 7496 4411
_________________________________________________________________________________
Crude Oil: complex hydrocarbon mixture comprising mainly of aliphatic, naphthenic and aromatic hydrocarbons. It may
also contain gases, sulphur and nitrogen compounds.
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EINECS No. : 232-298-5, CAS-No.: 8002-05-9
skin cancer.
The following components, considered by various legislative authorities to be hazardous, may be present:
Benzene, EINECS No. 200-753-7, CAS No. 71-43-2
Hydrogen sulphide CAS No. 7783-06-4, EINECS No. 231-977-3
_________________________________________________________________________________
Extremely flammable.
Contains Benzene. Prolonged or repeated exposure to benzene can cause anaemia and other blood diseases,
including leukaemia.
Harmful if swallowed - aspiration hazard. (If viscosity <7 cSt at 40°C)
_________________________________________________________________________________
Eyes
Skin
Product can be removed from the skin using warmed medicinal paraffin. Never use gasoline or kerosine to remove
product from skin or clothing.
In extreme situations of saturation with this product, drench with water, remove clothing as soon as possible and wash
skin with soap and water. Seek medical advice if skin becomes red, swollen or painful.
Ingestion
Inhalation
If exposure to vapour, mists or fumes causes drowsiness, headache, blurred vision or irritation of the eyes, nose or
throat, remove immediately to fresh air. Keep patient warm and at rest. If any symptoms persist obtain medical advice.

Medical Advice
develops.
If ingested, do not induce vomiting. Drinking milk or medicinal paraffin may be beneficial.
Aspiration of the product is unlikely to occur except as the result of ingestion, followed by vomiting or regurgitation in a
partially or totally unconscious individual, when immediate effects are most likely to result from the aspiration of acidic
stomach contents. If it should occur, transport casualty immediately to hospital.
_________________________________________________________________________________
There is a danger of flashback if sparks or hot surfaces ignite vapour.
Any spillage should be regarded as a potential fire risk.
Combustion Products
_________________________________________________________________________________
As this product has a very low flash point any spillage or leak is a severe fire and/or explosion hazard.
Isolate spillage from all ignition sources including road traffic.
Protect drains from potential spills to minimise contamination. Do not wash product into drainage system.
Vapour is heavier than air and may travel to remote sources of ignition (eg. along drainage systems, in basements
etc.).
If spillage has occurred in a confined space, ensure adequate ventilation and check that a safe, breathable
atmosphere is present before entry.
Any spillage which results in pollution at sea must be treated in accordance with the guidelines in MARPOL 73/78
Annex 1.
_________________________________________________________________________________


Storage Conditions
Do not siphon product by mouth.
Fire Prevention
Explosive air/vapour mixtures may form at ambient temperature.
_________________________________________________________________________________

Exposure Limits
Hydrogen sulphide
Benzene
ACGIH (USA): TLV 0.5ppm (8hr TWA); 2.5 ppm (15min STEL)
A1 - Confirmed human carcinogen
Skin Notation - Can be absorbed through skin
Protective Clothing


_________________________________________________________________________________

Typical Values
Grades: Crude Oil
Test Method Units
Physical state liquid
Colour brown
Odour pungent
Density @ 15°C ASTM D 1298 kg/m³ 750 - 1000
Kinematic viscosity @ ASTM D 445 mm²/s <7 to viscous
40°C liquid
Boiling point/range ASTM D 86 °C -10 to 800
Flash point (PMC) ASTM D 93 °C -50 to 100
Explosion limits % 0.6 - 8.0
Vapour pressure ASTM D 323 kPa 40 - 700
_________________________________________________________________________________

Conditions to Avoid
Sources of ignition
Materials to Avoid

_________________________________________________________________________________
Eyes

Skin
Unlikely to cause harm to the skin on brief or occasional contact but prolonged or repeated exposure may lead to
dermatitis.
Ingestion
Unlikely to cause harm if accidentally swallowed in small doses, though larger quantities may cause nausea and
diarrhoea.
Lower viscosity crude oils may injure the lungs if aspiration occurs, eg. during vomiting
Inhalation
Likely to be irritating to the respiratory tract if high concentrations of mists or vapour are inhaled.
May cause nausea, dizziness, headaches and drowsiness if high concentrations of vapour are inhaled.
ABUSE:
Under normal conditions of use the product is not hazardous; however, abuse involving deliberate inhalation of very
high concentrations of vapour, even for short periods, can produce unconsciousness and/or result in a sudden fatality.
Carcinogenicity/Chronic Toxicity
Exposure to benzene may result in affects to the hematopoietic system causing blood disorders including anaemia and
leukaemia.
Benzene is classified by EEC as a category 1 carcinogen - substances known to be carcinogenic to man.
IARC assessment: benzene - carcinogenic to humans ( Group 1)
_________________________________________________________________________________
Mobility

There is no evidence to suggest bioaccumulation will occur.
Aquatic toxicity
Harmful to aquatic organisms.
impaired.
May cause long term effects in the aquatic environment
_________________________________________________________________________________
Dispose of via an authorised person/ licensed waste disposal contractor in accordance with local regulations.
_________________________________________________________________________________
This information is provided for guidance only. The current legislative text for each mode of transport should be
referred to for definitive information.
** NOTE**, Transport Requirements depend on flash point, initial boiling point and vapour pressure.

Flash Point below minus 18 degrees Centigrade

ADR/RID: Petroleum Crude Oil, Flammable liquid, Class 3, Item 1a, 2a/b or 3b. Hazard Identification No 33
UN: PETROLEUM CRUDE OIL, Flammable liquid, Class 3, UN Number 1267
IATA/ICAO: Petroleum Crude Oil, Class 3, Packing group I/ II
IMO: PETROLEUM CRUDE OIL, Flammable liquid,: Class 3.1, Packing group I/II
EMERGENCY ACTION CODE: Flammable liquid, 3WE
Flash Point minus 18 to plus 23 degrees centigrade

ADR/RID:Petroleum Crude Oil, Flammable liquid, Class 3, Item 1a, 2a /b or 3b. Hazard Identification No 33
IATA/ICAO: Petroleum Crude Oil, Class 3, Packing group I/II
IMO: PETROLEUM CRUDE OIL, Flammable liquid,: Class 3.2, Packing group I/II
EMERGENCY ACTION CODE: Flammable liquid, 3WE
Flash Point plus 23 to 61 degrees centigrade

ADR/RID: Petroleum Crude Oil, Flammable liquid, Class 3, Item 31c. Hazard Identification No 30
IATA/ICAO: Petroleum Crude Oil, Class 3, Packing group III
IMO: PETROLEUM CRUDE OIL, Flammable liquid,: Class 3.3, Packing group III
EMERGENCY ACTION CODE: Flammable liquid, 3W
Flash Point plus 61 degrees centigrade

_________________________________________________________________________________
Extremely flammable or Highly Flammable or Flammable or unclassified for flammability (dependent on flash point and
initial boiling point)
Harmful (If viscosity <7 cSt at 40°C)
EU Labelling
Symbol:
Flame (for extremely flammable or highly flammable only)
EXTREMELY FLAMMABLE, or HIGHLY FLAMMABLE, or no indication of danger for flammability (dependent on flash
point and initial boiling point)
Risk ( R ) Phrases:
R12 Extremely flammable, or R11 Highly flammable, or R10 Flammable, or no risk phrase for flammability (dependent
on flash point and initial boiling point)
R65 Also Harmful: may cause lung damage if swallowed. (If viscosity <7 cSt at 50°C)

Substance Name: Crude oil , EINECS No: 232-298-5
_________________________________________________________________________________
Compiled by:
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
Sheet Revisions
25/09/98 1, 3, 8, 14, 15
SHEET NO: STI2201

______________________________________________________________________________

Sheet No: STI2109 Material Name: Heating Oil Issue Date : 17/07/2000 Revision of Sheet Dated:02/11/98 Page:
ALIGN BP SDS Finals


Material Name: Heating Oil
Hazardous Components: Physical Characteristics: Gas oil Tox File: 350.9 Product Group:
________________________________________________________________________________
SAFETY DATA SHEET
Heating Oil
COMPANY/UNDERTAKING
Heating Oil
Alternative Names: No. 2 Fuel Oil, Extra Light Fuel Oil (ELFO), Light Heating Oil, Furnace Oil, Domestic Fuel Oil
Application
Fuel for industrial or domestic boilers; fuel for compression ignition diesel engines.
Britannic House
1 Finsbury Circus
London, EC2M 7BA

+44 (0) 20 7496 4411
_________________________________________________________________________________
Complex mixture of middle distillate hydrocarbons, with carbon numbers in C10 to C28 range.
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Performance enhancing additives may be included.
Cracked components containing polycyclic aromatic hydrocarbon compounds may be present.
Fuels, diesel. EINECS No: 269-822-7, CAS No: 68334-30-5, Xn, R40 Possible risks of irreversible effects, R65
Harmful: may cause lung damage if swallowed, R66 Repeated exposure may cause skin dryness or cracking
(>90%)
_________________________________________________________________________________
Harmful if swallowed - aspiration hazard.
_________________________________________________________________________________
Eyes
Skin
Ingestion
Inhalation
Medical Advice
Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and
potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction
of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal
intubation. Monitor for cardiac dysrhythmias.

_________________________________________________________________________________
Combustion Products
_________________________________________________________________________________
In the event of spillage, remove all sources of ignition and ensure good ventilation.
Clean up spilled material immediately.
Contain and recover spilled material using sand or other suitable inert absorbent material.
etc.).

_________________________________________________________________________________

Storage Conditions


Fire Prevention
_________________________________________________________________________________

Exposure Limits
Protective Clothing
If operations are such that exposure to vapour, mist or fume may be anticipated, then suitable approved respiratory
equipment should be worn.
_________________________________________________________________________________

Typical Values
Grades: Heating Oil
Test Method Units


Colour amber
Odour gasoil-like
Boiling point/range ASTM D 86 °C 160 - 385
Flash point (PMC) ASTM D 93 °C 55 - 70
Vapour pressure ASTM D 323 kPa 4
Kinematic viscosity @ ASTM D 445 mm²/s 2-7
20°C
_________________________________________________________________________________

Conditions to Avoid
Sources of ignition
Materials to Avoid

_________________________________________________________________________________
Eyes
Skin
dermatitis.
Ingestion
diarrhoea.
Will injure the lungs if aspiration occurs, eg. during vomiting.
Inhalation
May cause irritation to eyes, nose and throat due to exposure to vapour, mists or fumes.
_________________________________________________________________________________
Mobility


Aquatic toxicity
impaired.
German WGK Classification: 2

_________________________________________________________________________________
_________________________________________________________________________________
ADR/RID: Gas oil, Flammable Liquid Class 3, Item 31(c) Hazard Identification No 30
UN: GAS OIL, Flammable liquid, Class 3, Packing Group III, UN Number 1202
IATA/ICAO: Gas oil, Flammable liquid, Class 3, Packing group III
IMO: GAS OIL, Flammable liquid, Class 3.3, Packing group III
EMERGENCY ACTION CODE: 3[Z]
_________________________________________________________________________________
Harmful
EU Labelling
Symbol:
St. Andrew's Cross
HARMFUL
Contains:
Fuels, Diesel
Risk ( R ) Phrases:
R40 Possible risks of irreversible effects
R65 Harmful: may cause lung damage if swallowed.
S2 Keep out of reach of children
S24 Avoid contact with skin
S43 In case of fire, use foam/dry powder/CO2. Never use water jets.

S36/37 Wear suitable protective clothing and gloves

S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
_________________________________________________________________________________
Compiled by:
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
Sheet Revisions
07/05/98 1, 2, 12, 15
02/11/98 1
17/07/2000 2, 3, 4, 9, 12, 15
SHEET NO: STI2102

______________________________________________________________________________

MATERIAL SAFETY DATA SHEET
MSDS No.
RS294 Ver. 3
HEAVY CRUDE OIL Rev. Date
06/28/2000
IMPORTANT: Read this MSDS before handling and disposing of this product and pass this information on to employees,
customers, and users of this product.
1. PRODUCT and COMPANY IDENTIFICATION
Material Identity Heavy Crude Oil
Trade Name(s) Thums, OCS (Outer Continental Shelf) Crude, Maya Crude
Other Name(s) Earth Oil, Petroleum Oil, Rock Oil

Chemical Description This material is a C1 to C50 hydrocarbon liquid which contains approximately 1.0
to 1.8 wt% sulfur compounds.
Manufacturer’s BP Amoco BP Amoco
Address Carson Business Unit Cherry Point Business Unit
1801 E. Sepulveda Boulevard 4519 Grandview Road
Carson, California 90749-6210 Blaine, Washington 98231
Telephone Numbers Emergency: 800-424-9300 CHEMTREC

Customer Service: 800-322-2726 INFO ONLY
2. COMPONENTS and EXPOSURE LIMITS
Exposure Limits
ACGIH OSHA
1 2 3
Component CAS No. % Composition By Volume TLV PEL Units Type
CRUDE OIL, PETROLEUM
8002-05-9 EQ 100 N/AP N/AP
Other applicable exposure guidelines:
(4)
COAL TAR PITCH VOLATILES, AS BENZENE SOLUBLES
65996-93-2 0.2 0.2 mg/m3 TWA
OIL MIST, MINERAL
8012-95-1 10 N/AP mg/m3 STEL
5 5 mg/m3 TWA
STODDARD SOLVENT
8052-41-3 100 100 ppm TWA
Stoddard Solvent exposure limits are listed as an exposure guideline for hydrocarbon vapors that may be similar
to those derived from crude oil.
Since specific exposure standards or control limits have not been established for this material, the exposure limits
shown here are suggested as minimum control guidelines.
1 (1) (2) (3) (4)
Carcinogen displayed after Component Name. Listed by NTP, IARC, OSHA, Other
2
See Abbreviations on last page
3
The OSHA exposure limits were changed in 1993 due to a federal court ruling. ARCO has chosen to list the 1989 OSHA exposure limits in this document as they are generally more
stringent and therefore more protective than the current exposure limits. (Refer to 29 CFR 1910.1000).
3. HAZARD IDENTIFICATION
IMMEDIATE HAZARDS
DANGER
HIGHLY FLAMMABLE! OSHA/NFPA Class 1B flammable liquid. KEEP AWAY FROM HEAT, SPARKS, AND
OPEN FLAME! CONTAINS PETROLEUM DISTILLATES! Avoid breathing vapors or mists. Use only with
adequate ventilation.
Print Date: 12/07/00 ***FOR “DISCLAIMER OF LIABILITY”, SEE THE STATEMENT ON LAST PAGE*** Page 1 of 6
HEAVY CRUDE OIL MSDS No. RS294 Ver. 3
If swallowed, do not induce vomiting since aspiration into the lungs may cause chemical pneumonia. Obtain
prompt medical attention.
May cause irritation or more serious skin disorders! May be harmful if inhaled! May cause irritation of the nose,
throat, and lungs, headache, dizziness, drowsiness, loss of coordination, fatigue, nausea and labored breathing.
May cause irregular heartbeats. Avoid prolonged or repeated liquid, mist, and vapor contact with eyes, skin, and
respiratory tract.
Wash hands thoroughly after handling.
Sulfur compounds in this material may decompose to release hydrogen sulfide gas which may accumulate to
potentially lethal concentrations in enclosed air spaces. Vapor concentrations of hydrogen sulfide above 50 ppm,
or prolonged exposure at lower concentrations, may saturate human odor perceptions so that the smell of gas
may not be apparent. DO NOT DEPEND ON THE SENSE OF SMELL TO DETECT HYDROGEN SULFIDE!
Long-term tests show that similar crude oils have produced skin tumors on laboratory animals.
Crude oils contain some polycyclic aromatic hydrocarbons which have been shown to be carcinogenic after
prolonged or repeated skin contact in laboratory animals.
ACUTE HEALTH HAZARDS

Routes of Exposure Signs and Symptoms
Inhalation Vapors or mists from this material, at concentrations greater than the recommended
(Primary) exposure limits in Section 2, can cause irritation of the nose, throat, and lungs, headache,
dizziness, drowsiness, loss of coordination, fatigue, nausea and labored breathing. Airborne
concentrations above the recommended exposure limits are not anticipated during normal
workplace activities due to the slow evaporation of this material at ambient temperatures.
Exposure to moderate airborne concentrations of hydrogen sulfide (less than 50 ppm) can
result in irritation of the eyes, nose and throat, headache, dizziness, shortness of breath,
nausea and nervousness. Exposure to hydrogen sulfide vapor above 200 ppm may cause
irritation of mucous membranes, inflammation of the lungs, accumulation of fluid in the
lungs, irregular heartbeats, unconsciousness with convulsions or impaired breathing with
suffocation. Exposure to higher concentrations of hydrogen sulfide vapor (above 500 ppm)
may cause rapid death.
Eye Contact May cause slight eye irritation.
Skin Contact Moderate skin irritation may occur upon short-term exposure.
Exposure to sunlight may increase the degree of skin irritation.
Absorption through the skin may occur and produce toxic effects (see Summary of Chronic
Hazards).
Ingestion May cause irritation of the mouth, throat and gastrointestinal tract leading to nausea,
vomiting, diarrhea, and restlessness. May cause headache, dizziness, drowsiness, loss of
coordination, fatigue, nausea and labored breathing.
ASPIRATION HAZARD: This material can enter the lungs during swallowing or vomiting and
may cause lung inflammation and damage which in severe cases may be fatal.
Summary of Personnel with preexisting central nervous system disease, skin disorders, or chronic
Chronic Hazards respiratory diseases should be evaluated by an appropriate health professional before
and Special exposure to this material.
Health Effects
Prolonged/repeated skin exposure, inhalation or ingestion of this material may result in
adverse dermal or systemic effects. Avoid prolonged or repeated exposure.
May be harmful if absorbed through the skin. Prolonged or repeated contact may create
cancer risk, organ damage, and adversely affect reproduction, fetal development and fetal
survival. Avoid all skin contact.
See Section 11 for Additional Toxicological Information.
4. EMERGENCY and FIRST AID
Inhalation Immediately remove personnel to area of fresh air. For respiratory distress, give oxygen,
rescue breathing, or administer CPR (cardiopulmonary resuscitation) if necessary. Obtain
Print Date: 12/07/00 Page 2 of 6

Eye Contact Flush eyes with clean, low-pressure water for at least 15 minutes, occasionally lifting the
eyelids. If pain or redness persists after flushing, obtain medical attention.
Skin Contact Immediately remove contaminated clothing. Wash affected skin thoroughly with soap and
water. If irritation persists, obtain medical attention.
Ingestion Do not induce vomiting since aspiration into the lungs may cause lipoid pneumonia. Obtain
Emergency See above procedures. Personnel with pre-existing central nervous system disease, skin
Medical disorders, chronic respiratory diseases, or impaired liver of kidney function should avoid
Treatment exposure to this product.
Procedures
5. FIRE and EXPLOSION
Flash Point (Method) * Based on NFPA Petroleum, Crude AP 20°F to 90°F NFPA Hazard Rating:
Autoignition Temperature (Method)* N/DA + Health: 2 = Moderate
Flammable Limits (% Vol. in Air) Lower AP 1 + Fire: 3 = High
* At Normal Atmospheric Temperature and Pressure Upper AP 8 Reactivity: 0 = Insignificant
+
Based on NFPA 325 Special: = ---
Fire and HIGHLY FLAMMABLE! This material releases flammable vapors at or below ambient
Explosion temperatures. When mixed with air in certain proportions and exposed to an ignition source,
Hazards these vapors can burn in the open or explode in confined spaces.
Flammable vapors may travel long distances along the ground before reaching a point of
ignition and flashing back.
Open top tanks involved in a fire have a potential for "boil-over" if water or water-in-oil
emulsion is at the bottom of the tank. Boil-over may result in a large expulsion of burning oil
from the tank, greatly increasing the fire area.
Extinguishing Foam, Dry chemical, Carbon dioxide (CO2)

Media
Water and water fog can cool the fire but may not extinguish the fire.
Special For fires involving this material, do not enter any enclosed or confined fire space without
Firefighting proper protective equipment. This may include self-contained breathing apparatus to protect
Procedures against the hazardous effects of combustion products and oxygen deficiencies. Cool tanks
and containers exposed to fire with water. If firefighters cannot work upwind to the fire,
respiratory protective equipment must be worn unless and until atmospheric monitoring
indicates that such protection is not required. Improper use of water and extinguishing
media containing water may cause frothing which can spread the fire over a larger area.
Water fog or spray are of value for cooling tank shells and surfaces exposed to fire, but may
not achieve extinguishment.
Precautions if Contain spill, evacuate non-essential personnel, and safely stop flow. On hard surfaces,
Material is Spilled spilled material may create a slipping hazard. Equip cleanup crews with proper protective
or Released equipment (as specified in Section 8) and advise of hazards. Clean up by recovering as
much spilled or contaminated materials as possible and placing into closed containers.
Consult with an environmental professional for the federal, state and local cleanup and
reporting requirements for spills and releases.
7. HANDLING and STORAGE
Handling, Store and transport in accordance with all applicable laws. KEEP AWAY FROM HEAT,
Storage and SPARKS, AND OPEN FLAME! KEEP CONTAINERS CLOSED, PLAINLY LABELED AND
Decontamination OUT OF CLOSED VEHICLES! Containers should be able to withstand pressures expected
Procedures from warming orocooling in storage. Ground all drums and transfer vessels when handling.
Store in cool (80 F or below), well-ventilated location. All electrical equipment in storage

and/or handling areas should be installed in accordance with applicable requirements of the
National Electrical Code (NEC).
KEEP OUT OF REACH OF CHILDREN!
Empty containers retain some liquid and vapor residues, and hazard precautions must be
observed when handling empty containers.
For determining National Electrical Code (NEC) Hazardous (Classified) location
requirements for electrical installations, consider this material Class 1, Group D.
Engineering Where possible, use adequate ventilation to keep vapor and mist concentrations of this
Controls material below the Occupational Exposure Limits shown in Section 2. Electrical equipment
should comply with National Electrical Code (NEC) standards (see Section 7).
Respiratory Where there is potential for exposure to hydrogen sulfide gas in excess of the permissible
exposure limit, a NIOSH/MSHA-approved supplied-air respirator operated in positive
pressure mode should be worn.
If hydrogen sulfide gas is not present in excess of permissible exposure limits, a
NIOSH/MSHA-approved air-purifying respirator with an organic vapor cartridge may be
permissible under certain circumstances where airborne concentrations of hydrocarbon
vapor may exceed the exposure limits in Section 2. Where work conditions may generate
airborne mists of the material, also use a high-efficiency particulate pre-filter. Consult a
health and safety professional for guidance in respirator selection. Respirator use should
comply with OSHA 29 CFR 910.134.
CAUTION: The protection provided by air-purifying respirators is limited. Use a positive
pressure air-supplied respirator if there is any potential for an uncontrolled release, if
exposure levels are not known, or if concentrations exceed the protection limits of the air-
purifying respirator.
Eyes Eye protection should be worn. If there is potential for splashing or spraying, chemical
protective goggles and/or a face shield should be worn. If contact lenses are worn, consult
an eye specialist or a safety professional for additional precautions. Suitable eye wash water
should be available in case of eye contact with this material.
Skin Avoid all skin contact with this material. If conditions of use present any potential for skin
contact, clean and impervious clothing such as gloves, apron, boots, and facial protection
should be worn. Neoprene, Nitrile, Butyl Rubber or Viton glove material is recommended.
When working around equipment or processes which may create the potential for skin
contact, full body coverage should be worn, which consist of impervious boots and oil-
resistant coated Tyvek suit or other impervious jacket and pants.
Non-impervious clothing which accidentally becomes contaminated with this material should
be removed promptly and not reworn until the clothing is washed thoroughly and the
contamination is effectively removed. Discard soaked leather goods.
Other Hygienic Use good personal hygiene practices. If skin contact should occur, material should be
and Work removed from the skin with a waterless hand cleaner, and the affected area should then be
Practices washed with a mild soap and water. Wash hands and other exposed areas thoroughly
before eating, drinking, smoking or using toilet facilities.
9. PHYSICAL and CHEMICAL PROPERTIES
Boiling Point: AP -54°F to 1100°F

Viscosity Units, Temp. (Method): N/DA
Dry Point: N/AP
Freezing Point: N/DA
Vapor Pressure, Temp. (Method): AP 2.6 to 6.4 at 100°F (REID-PSIA)
Volatile Characteristics: Appreciable
Specific Gravity (H2O = 1 @ 39.2°°C): AP 0.86 to 0.92

Vapor Sp. Gr. (Air = 1.0 @ 60°°F - 90°°F): N/DA

Solubility in Water: Negligible
PH: N/AP
Appearance and Odor: Thick light yellow to dark black colored liquid. Petroleum
hydrocarbon odor.
Other Physical and Chemical Properties: Total sulfur = approx. 1.6 wt%
Hydrogen Sulfide content is less than 5 ppm dissolved in
liquid
Vanadium = approx. 170 ppm
sp Grav = approx. 0.94
10. STABILITY and REACTIVITY
Stability Stable
Hazardous Polymerization Not expected to occur.
Other Chemical Reactivity N/AP
Conditions to Heat, sparks, and open flame.

Avoid
Materials to Strong acids, alkalis, and oxidizers such as liquid chlorine and oxygen.
Avoid
Hazardous or Burning or excessive heating may produce carbon monoxide and other harmful gases or
Decomposition vapors including oxides of sulfur and nitrogen.
Products
Toxicological The information found in this section is written for medical, toxicology, occupational health
Information and safety professionals. This section provides technical information on the toxicity testing
of this or similar materials or its components. If clarification of the technical content is
needed, consult a professional in the areas of expertise listed above.
Prolonged/ IARC has determined there is "limited evidence for the carcinogenicity in experimental
Repeated animals of crude oil" and "inadequate evidence for the carcinogenicity in humans of crude
Exposures oil." IARC concludes that "crude oil is not classifiable as to its carcinogenicity to humans
(Group 3)."
Crude oil administered orally to pregnant rats during gestation produced increased number
of resorptions and decrease in fetal weight and length.
Not Available
Waste Disposal Consult environmental professional to determine if state or federal regulations would classify
Methods spilled or contaminated materials as a hazardous waste. Use only approved transporters,
recyclers, treatment, storage or disposal facilities. Comply with all federal, state and local
laws pertaining to waste management.

UN Proper Shipping Name Petroleum crude oil

UN Hazard Class 3
UN Number UN1267
UN Packing Group PGI
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA), TITLE III

Section 311/312 Hazard Categories:
Immediate (acute) health hazard
Delayed (chronic) health hazard
Fire hazard
Section 313:
No chemicals in this product exceed the threshold reporting level established by SARA Title III, Section 313 and
40 CFR 372.
TOXIC SUBSTANCES CONTROL ACT (TSCA)
All components of this product are listed on the TSCA Inventory.
COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION AND LIABILITY ACT (CERCLA)
No chemicals in this product are subject to the reporting requirements of CERCLA.
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986 - PROPOSITION 65
PROP 65 WARNING LABEL:
Chemicals known to the State to cause cancer, birth defects, or other reproductive harm are found in gasoline,
crude oil, and many other petroleum products and their vapors, or result from their use. Read and follow label
directions and use care when handling or using all petroleum products.
This product contains the following chemical(s) listed by the state of California as known to cause cancer or birth
defects or other reproductive harm.
(C)
MINERAL OILS, UNTREATED
Other Prop 65 chemicals will result under certain conditions from the use of this material. For example, burning
fuels produces combustion products including carbon monoxide, a Prop 65 reproductive toxin.
(C)
= Carcinogen
General The information and conclusions herein reflect normal operating conditions and may be from
Comments sources other than direct test data on the mixture itself.
Abbreviations: EQ = Equal AP = Approximately N/P = No Applicable Information Found

LT = Less Than UK = Unknown N/AP = Not Applicable
GT = Greater Than TR = Trace N/DA = No Data Available
Disclaimer of Liability
The information in this MSDS was obtained from sources which we believe are reliable. HOWEVER, THE INFORMATION IS PROVIDED WITHOUT ANY
WARRANTY, EXPRESS OR IMPLIED, REGARDING ITS CORRECTNESS.
The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may be beyond our knowledge. FOR THIS AND
OTHER REASONS, WE DO NOT ASSUME RESPONSIBILITY AND EXPRESSLY DISCLAIM LIABILITY FOR LOSS DAMAGE OR EXPENSE ARISING OUT OF
OR IN ANY WAY CONNECTED WITH THE HANDLING, STORAGE, USE OR DISPOSAL OF THE PRODUCT.
This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be
applicable.

Sheet No: SSR2111 Material Name: Low Sulphur Fuel Oil Issue Date : 22/09/94 Revision of Sheet Dated:NA Page:

___________________________________________________________________________
Low Sulphur Fuel Oil

Low sulphur oil, Low sulphur fuel oil, LSFO, Heating Oil
Synonyms: No. 2 Fuel Oil, Extra Light Fuel Oil ( ELFO), Light Heating Oil, Furnace Oil, Domestic Fuel Oil,
Application
Fuel for industrial or domestic boilers; fuel for compression ignition diesel engines.
Singapore Refining Company Pte. Ltd.
Pulau Merlimau
Jurong
Singapore

Singapore 867 8844
__________________________________________________________________________________
Fuel Oil, No.2 EINECS No: 270-671-4, CAS No: 68476-30-2
Fuels, diesel. EINECS No: 269-822-7, CAS No: 68334-30-5
__________________________________________________________________________________
_______________________________________________________________________________
Eyes
Wash eye thoroughly with copious quantities of water, ensuring eyelids are held open. Obtain medical advice if any pain
or redness develops or persists.
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Skin
Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing and
wash underlying skin.
Ingestion
If contamination of the mouth occurs, wash out thoroughly with water. If larger amounts are swallowed, do not induce
vomiting; transport casualty together with the product container, its label or the safety data sheet urgently to hospital.
Inhalation
Medical Advice
Injections through the skin resulting from contact with the product at high pressure constitute a major medical emergency.
Injuries may not appear serious at first but within a few hours tissue becomes swollen, discoloured and extremely painful
with extensive subcutaneous necrosis.
underlying tissue is necessary to minimise tissue loss and prevent or limit permanent damage. Note that high pressure may
force the product considerable distances along tissue planes.
potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction of
vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotrachael intubation.
Monitor for cardiac disrhythmias.
__________________________________________________________________________________
Combustion Products
__________________________________________________________________________________

Vapour is heavier than air and may travel to remote sources of ignition (eg. along drainage systems, in basements etc.).
In the case of spillage on water, prevent the spread of product by the use of suitable barrier equipment. Recover product
from the surface. Protect environmentally sensitive areas and water supplies.
In the case of spillage at sea approved dispersants may be used where authorised by the appropriate government/regulatory
authorities.
__________________________________________________________________________________
Storage Conditions
Empty packages may contain some remaining product. Retain hazard warning labels on empty packages as a guide to the
safe handling, storage and disposal of empty packaging.
Do not enter storage tanks without breathing apparatus unless the tank has been well ventilated and the tank atmosphere
has been shown to contain hydrocarbon vapour concentrations of less than 1% of the lower flammability limit and an
oxygen concentration of at least 20% volume.
quick rescue.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. These can cause flammability/explosion hazards even
at temperatures below the normal flash point (note: flash point must not be regarded as a reliable indicator of the potential
storage tanks.
Product soaked rags, paper or material used to absorb spillages, represent a fire hazard, and should not be allowed to
accumulate. Dispose of safely immediately after use.
Empty containers represent a fire hazard as they may contain some remaining flammable product and vapour. Never cut,
weld, solder or braze empty containers.
__________________________________________________________________________________
Exposure Limits
Comply with current local occupational exposure limit.

Protective Clothing
Protective clothing should be regularly inspected and maintained; overalls should be dry-cleaned, laundered and preferably
starched after use.
The use of approved breathing apparatus in confined spaces, by trained personnel, must only be undertaken strictly in
accordance with Statutory Regulations governing such entry.
Typical Values
Grades:Low Sulphur Fuel Oil
Test Method Units
Colour amber
Odour oily
Density @ 15°C ASTM D 1298 kg/m3 805-890
Kinematic viscosity @ 20°C ASTM D 445 mm2/s 2-7
Vapour pressure °C ASTM D 323 kPa 4
Boiling point/range ASTM D 86 °C 160 -
385
Conditions to Avoid
Avoid temperatures at or near flash point.
Materials to Avoid

Thermal decomposition can produce a variety of compounds, the precise nature of which will depend on the
decomposition conditions.
Incomplete combustion/ thermal decomposition will generate smoke, carbon dioxide and hazardous gases,which will
include carbon monoxide.
__________________________________________________________________________________
Eyes

Skin
dermatitis.
This material contains significant quantities of polycyclic aromatic hydrocarbons (PCAs), some of which has been shown
by experimental studies to induce skin cancer.
Ingestion
Unlikely to cause harm if accidentally swallowed in small doses, though larger quantities may cause nausea and diarrhoea.
Inhalation

Mobility

Aquatic toxicity
May be harmful to aquatic organisms.
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be impaired.
__________________________________________________________________________________
Dispose of by incineration or other suitable means under conditions approved by the local authority or via a licensed waste
disposal contractor.
__________________________________________________________________________________
EMERGENCY ACTION CODE: Flammable liquid, 3[Z]
__________________________________________________________________________________
EC Labelling
Symbol: St Andrews Cross
Risk ( R ) Phrases:
R40 - Possible risks of irreversible effects

S24 - Avoid contact with skin
S36/37 - Wear suitable protective clothing and gloves
S43 - In case of fire, use foam/dry powder/CO2/halon. Never use water.
S62 - If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
__________________________________________________________________________________
Compiled by:
Chertsey Road
Sunbury-On-Thames
Middlesex, TW16 7LN
specified below. We have reviewed the information contained herein which we received from sources outside SRC .
However, no warranty or representation, expressed or implied is made as to the accuracy or completeness of the data and
information contained in this data sheet.
given or implied to practise any patented invention without a valid licence. SRC shall not be responsible for any damage or
injury resulting from abnormal use of the material, from any failure to adhere to recommendations, or from any hazards
inherent in the nature of the material

file:///C|/Documents%20and%20Settings/lanewg/My%20Documents/DATA...l/Marine%20Distillate%20Fuels%20Issue%20Date%20%2017-07-2000.htm
ALIGN BP SDS Finals


Material Name: Marine Distillate Fuels
________________________________________________________________________________
SAFETY DATA SHEET
Marine Distillate Fuels

COMPANY/UNDERTAKING
Marine Distillate Fuels
Alternative Names: BP Distillate Diesel Oil (Synonyms BPDDO, DMB, DB, LDO, Marine Diesel Oil)
BP Blended Diesel Oil (Synonyms BPBDO, DMC, DC MDO, Marine Diesel Oil, Blended Marine Diesel Oil)
Application
Fuel for diesel engines or heating/boiler plant
Britannic House
1 Finsbury Circus
London, EC2M 7BA

+44 (0) 20 7496 4411
_________________________________________________________________________________
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Complex mixture of mainly middle distillate hydrocarbons in the C10-C30 range. The resulting fuel can be paraffinic,
naphthenic or aromatic in nature. Performance additives may be added.
DDO may contain trace amounts of residual fuel oil. BDO will typically contain about 20% by volume of residual fuel oil.
skin cancer.
(>70%)
Fuel oil, residual. EINECS No: 270-675-6, CAS No: 68476-33-5, T, R45 May cause cancer, R66 Repeated exposure
may cause skin dryness or cracking, R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in
the aquatic environment
_________________________________________________________________________________
_________________________________________________________________________________
Eyes
Skin
Ingestion
Inhalation

Medical Advice
develops.

_________________________________________________________________________________
Combustion Products
Ash from combustion may contain potentially harmful components such as vanadium and other heavy metal oxides.
_________________________________________________________________________________
etc.).


_________________________________________________________________________________

Storage Conditions
Fire Prevention


_________________________________________________________________________________

Exposure Limits
Hydrogen sulphide
Protective Clothing
_________________________________________________________________________________

Typical Values
Grades: DDO BDO
Test Method Units
Physical state liquid liquid
Colour dark brown ->black
black [may be dyed
[may be dyed to comply
to comply with local
with local regulations /
regulations/ requirements]
requirements]
Odour characteristic characteristic
hydrocarbon hydrocarbon
Density @ 15°C ASTM D 1298 kg/m³ 900 max 920 max
Kinematic viscosity @ ASTM D 445 mm²/s 2.5 - 11 14 max
40°C
Flash point (PMC) ASTM D 93 °C 62 min 62 min

_________________________________________________________________________________

Conditions to Avoid
Avoid storage at or near flash point.
Materials to Avoid

_________________________________________________________________________________
Eyes
Skin
dermatitis.
Ingestion
diarrhoea.
Inhalation
_________________________________________________________________________________
Mobility


Aquatic toxicity
impaired.
_________________________________________________________________________________
facilities.
_________________________________________________________________________________
ADR/RID: Gas oil, Flammable Liquid Class 3, UN 1202, Item 31(c) Hazard Identification No 30,
Not classified as hazardous for transport ( UN , IMO, IATA/ICAO).
_________________________________________________________________________________
Harmful
EU Labelling
Symbol:
None
Contains:
Fuels, Diesel
Heavy fuel oil
Risk ( R ) Phrases:
R65 Also Harmful: may cause lung damage if swallowed.


_________________________________________________________________________________
Compiled by:
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
Sheet Revisions
02/11/98 1, 2, 8, 12, 15
17/07/2000 2, 3, 4, 7, 8, 12, 14, 15
SHEET NO: STI2105

______________________________________________________________________________

Sheet No: STI2107 Material Name: Marine Gas Oil Issue Date : 17/07/2000 Revision of Sheet Dated:02/11/98 Page:
ALIGN BP SDS Finals


Material Name: Marine Gas Oil
________________________________________________________________________________
SAFETY DATA SHEET
Marine Gas Oil

COMPANY/UNDERTAKING
Marine Gas Oil
Alternative Names: DMA, DA, MGO, Gas Oil
Application
Fuel for diesel engines or heating/boiler plant
Britannic House
1 Finsbury Circus
London, EC2M 7BA

+44 (0) 20 7496 4411
_________________________________________________________________________________
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(>90%)
_________________________________________________________________________________
_________________________________________________________________________________
Eyes
Skin
Ingestion
Inhalation
Medical Advice

_________________________________________________________________________________
Combustion Products
_________________________________________________________________________________
etc.).

_________________________________________________________________________________

Storage Conditions


Fire Prevention
_________________________________________________________________________________

Exposure Limits
Protective Clothing
_________________________________________________________________________________

Typical Values
Grades: Marine Gas
Oil

Test Method Units

Colour clear [may be
dyed to
comply with
local
regulations/
requirements]
Odour characteristic
hydrocarbon
Density @ 15°C ASTM D 1298 kg/m³ 890 max
Kinematic viscosity @ ASTM D 445 mm²/s 1.5 - 6
40°C
Flash point (PMC) ASTM D 93 °C 62 min
_________________________________________________________________________________

Conditions to Avoid
Sources of ignition
Materials to Avoid

_________________________________________________________________________________
Eyes
Skin
dermatitis.
Ingestion
diarrhoea.
Inhalation
_________________________________________________________________________________

Mobility

Aquatic toxicity
impaired.

_________________________________________________________________________________
_________________________________________________________________________________
ADR/RID: Gas oil, Flammable Liquid Class 3, UN 1202, Item 31(c) Hazard Identification No 30,
Not classified as hazardous for transport ( UN , IMO, IATA/ICAO).
_________________________________________________________________________________
Harmful
EU Labelling
Symbol:
St. Andrew's Cross
HARMFUL
Contains:
Fuels, Diesel
Risk ( R ) Phrases:


_________________________________________________________________________________
Compiled by:
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
Sheet Revisions
02/11/98 1, 2, 12, 15
17/07/2000 2, 3, 4, 9, 12, 14, 15
SHEET NO: STI2107

______________________________________________________________________________

Sheet No: STI2108 Material Name: Residual Fuel Oil Issue Date : 17/07/2000 Revision of Sheet Dated:02/11/98 Page:
ALIGN BP SDS Finals


Material Name: Residual Fuel Oil
________________________________________________________________________________
SAFETY DATA SHEET
Residual Fuel Oil

COMPANY/UNDERTAKING
Residual Fuel Oil
Alternative Names: BP40 to BP700, RMA to RML, A to K, Bunker C, Fuel Oil Nos 4, 5 or 6)
Application
Fuel for industrial, marine and commercial boilers and furnaces; fuel for low and medium speed diesel engines.
Britannic House
1 Finsbury Circus
London, EC2M 7BA

+44 (0) 20 7496 4411
_________________________________________________________________________________
Residues (petroleum), atm. tower. EINECS No: 265-045-2, CAS No: 64741-45-3
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skin cancer.
_________________________________________________________________________________
_________________________________________________________________________________
Eyes
If hot material enters the eye, flood immediately with cold water to dissipate the heat, if possible, ensuring eyelids are
held open. Take the casualty to hospital for examination and treatment without delay.
Skin
If hot product causes burns, the affected area should be flooded immediately with, or immersed in cold water for 10
minutes, or longer if pain persists. Burns should be covered with clean cotton or gauze, and the casualty taken to
hospital as soon as possible for examination and treatment.
Never use gasoline, kerosine or other solvents to remove fuel oil from skin or clothing.
Ingestion
Inhalation

Medical Advice
If ingested, do not induce vomiting.
develops.

_________________________________________________________________________________
Use foam, dry powder or carbon dioxide. DO NOT USE water jets. Avoid spraying directly into storage containers
Combustion Products
_________________________________________________________________________________
Scrape up bulk of solid material and remove liquid with sand or other suitable inert absorbent material. If necessary,
clean the contaminated area using hot water and detergent: absorb the washings - do not wash into drains.

_________________________________________________________________________________

Storage Conditions
Fire Prevention

_________________________________________________________________________________

Exposure Limits
Hydrogen sulphide
Protective Clothing
When handling heated material suitable protective clothing of an appropriate standard should be worn to prevent
thermal burns.
_________________________________________________________________________________

Typical Values
Grades: Residual Fuel
Oil
Test Method Units
Colour black
Odour characteristic
hydrocarbon
Density @ 15°C ASTM D 1298 kg/m³ 1010 max
Flash point (PMC) ASTM D 93 °C 62 min
Kinematic viscosity ASTM D 445 mm2/s 30 - 700
@ 50°C
_________________________________________________________________________________


Conditions to Avoid
Materials to Avoid

_________________________________________________________________________________
Eyes
Skin
Ingestion
Inhalation
May be irritating to eyes, nose and throat at high vapour concentrations.
_________________________________________________________________________________
Mobility


Aquatic toxicity
impaired.
German WGK Classification: Light fuel oil 2; Heavy fuel oil 1
_________________________________________________________________________________
facilities.
_________________________________________________________________________________
_________________________________________________________________________________
EU Labelling
Symbol:
None
Risk ( R ) Phrases:
Substance name: Fuel oil, residual, EINECS No: 270-675-6

_________________________________________________________________________________
Compiled by:
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
Sheet Revisions
08/05/98 2, 3, 4, 8, 12, 15
02/11/98 1
17/07/2000 3, 8, 11, 15
SHEET NO: STI2108

ISSUE DATE: 17/07/20000
______________________________________________________________________________

file:///C|/Documents%20and%20Settings/lanewg/My%20Documents/DA...mendments/MSDS/Black%20Oil/Rubber%20Solvent%20Long%20Range.htm
** MSDVIEW HEADER INDEX **

RUBBER SOLVENT LONG RANGE
Ashland(R)
ASHLAND CHEMICAL, INC.

Subsidiary Of Ashland Oil, Inc
P.O. BOX 2219
COLUMBUS, OHIO 43216
(614) 889-3333
24-HOUR Emergency Telephone

1(800) 274-5263 or 1(800) ASHLAND
000075
RUBBER SOLVENT LONG RANGE
THIS MSDS COMPLIES WITH 29 CFR 1910.1200 (THE HAZARD COMMUNICATION

STANDARD)
Product Name: RUBBER SOLVENT LONG RANGE

CAS NUMBER: 64742-89-8
Data Sheet No: 0014057-007.003

05 93 091 0153028-269 Prepared: 02/02/93
Supersedes: 12/18/92
ATI
ATTN: MICHELLE BRIGGS
1 PARK CENTRE PRODUCT:
SUITE 10 INVOICE: REQST
WADSWORTH OH 44281 INVOICE DATE: 09/11/93
TO:
SECTION I - PRODUCT IDENTIFICATION
General or Generic ID: ALIPHATIC HYDROCARBON

DOT Hazard Classification: FLAMMABLE LIQUID (173.115)
SECTION II - COMPONENTS
IF PRESENT IARC, NTP AND OSHA CARCINOGENS AND CHEMICALS SUBJECT TO THE
REPORTING REQUIREMENTS OF SARA TITLE III SECTION 313 ARE IDENTIFIED IN
THIS SECTION. SEE DEFINITION PAGE FOR CLARIFICATION
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INGREDIENT % (by WT) PEL TLV Note
ALIPHATIC PETROLEUM 100 400 PPM 400 PPM ( 1)

DISTILLATES
CAS #: 64742-89-8
Notes:
( 1) NIOSH RECOMMENDS A LIMIT OF 350 MG/CUM - 8 HOUR TIME WEIGHTED

AVERAGE, 1800 MG/CUM AS DETERMINED BY A 15 MINUTE SAMPLE.
THIS PRODUCT CONTAINS APPROXIMATELY 20-25% N-HEXANE (CAS# 110-54-3), 0-6%

TOLUENE (CAS# 108-88-3), AND 0-3% CYCLOHEXANE (CAS# 110-82-7). N-HEXANE
HAS AN OSHA PEL AND AN ACGIH TLV OF 50 PPM. TOLUENE EXPOSURE LIMITS ARE:
PEL OF 100 PPM, WITH A STEL OF 150 PPM; TLV OF 50 PPM-SKIN. PEL/TLV FOR
CYCLOHEXANE IS 300 PPM. TOLUENE AND CYCLOHEXANE ARE SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF SARA TITLE III.
SECTION III - PHYSICAL DATA
Boiling Point for PRODUCT

105.00 Deg F (40.55 Deg C) @ 760.00 mm Hg
Vapor Pressure for PRODUCT

152.00 mm Hg @ 68.00 Deg F (20.00 Deg C)
Specific Vapor Density AIR = 1

3.50
Specific Gravity
.713 @ 60.00 Deg F (15.55 Deg C)
Percent Volatiles
100.00%
Evaporation Rate (ETHER = 1)

3.10
SECTION IV - FIRE AND EXPLOSION INFORMATION
FLASH POINT (TCC)

-18.0 Deg F (-27.8 Deg C)
EXPLOSIVE LIMIT (PRODUCT)

LOWER - 1.3%
EXTINGUISHING MEDIA: REGULAR FOAM OR CARBON DIOXIDE OR DRY CHEMICAL

HAZARDOUS DECOMPOSITION PRODUCTS: MAY FORM TOXIC MATERIALS:, CARBON

DIOXIDE AND CARBON MONOXIDE, VARIOUS HYDROCARBONS, ETC.
FIREFIGHTING PROCEDURES: WEAR SELF-CONTAINED BREATHING APPARATUS WITH A

FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE DEMAND MODE WHEN FIGHTING
FIRES.
SPECIAL FIRE & EXPLOSION HAZARDS:
MATERIAL IS HIGHLY VOLATILE AND READILY GIVES OFF VAPORS WHICH MAY TRAVEL
ALONG THE GROUND OR BE MOVED BY VENTILATION AND IGNITED BY PILOT LIGHTS,
OTHER FLAMES, SPARKS, HEATERS, SMOKING, ELECTRIC MOTORS, STATIC DISCHARGE,
OR OTHER IGNITION SOURCES AT LOCATIONS DISTANT FROM MATERIAL HANDLING
POINT.
NEVER USE WELDING OR CUTTING TORCH ON OR NEAR DRUM (EVEN EMPTY) BECAUSE
PRODUCT (EVEN JUST RESIDUE) CAN IGNITE EXPLOSIVELY.
ALL FIVE GALLON PAILS AND LARGER METAL CONTAINERS INCLUDING TANK CARS AND
TANK TRUCKS SHOULD BE GROUNDED AND/OR BONDED WHEN MATERIAL IS TRANSFERRED.
SECTION V - HEALTH HAZARD DATA
PERMISSIBLE EXPOSURE LEVEL

400 PPM
THRESHOLD LIMIT VALUE

400 PPM
SEE SECTION II
EFFECTS OF ACUTE OVEREXPOSURE:
EYES - EXPOSURE TO LIQUID OR VAPOR MAY CAUSE MILD EYE IRRITATION. SYMPTOMS
MAY INCLUDE STINGING, TEARING, AND REDNESS.
SKIN - EXPOSURE MAY CAUSE MILD SKIN IRRITATION. PROLONGED OR REPEATED

EXPOSURE MAY DRY THE SKIN. SYMPTOMS MAY INCLUDE REDNESS, BURNING, DRYING
AND CRACKING, AND SKIN BURNS.
BREATHING - EXCESSIVE INHALATION OF VAPORS CAN CAUSE NASAL AND RESPIRATORY

IRRITATION, CENTRAL NERVOUS SYSTEM EFFECTS INCLUDING DIZZINESS, WEAKNESS,
FATIGUE, NAUSEA, HEADACHE AND POSSIBLE UNCONSCIOUSNESS, AND EVEN DEATH.
SWALLOWING - CAN CAUSE GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING, AND

DIARRHEA. ASPIRATION OF MATERIAL INTO THE LUNGS CAN CAUSE CHEMICAL
PNEUMONITIS WHICH CAN BE FATAL.

FIRST AID:
IF ON SKIN: REMOVE CONTAMINATED CLOTHING. WASH EXPOSED AREA WITH SOAP AND
WATER. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. IF SYMPTOMS PERSIST,
SEEK MEDICAL ATTENTION.
IF IN EYES: IF SYMPTOMS DEVELOP MOVE INDIVIDUAL AWAY FROM EXPOSURE AND

INTO FRESH AIR. FLUSH EYES WITH CLEAN WATER WHILE HOLDING EYELIDS APART.
IF SYMPTOMS PERSIST, SEEK MEDICAL ATTENTION.
IF SWALLOWED: DO NOT INDUCE VOMITING, KEEP PERSON WARM, QUIET, AND GET
MEDICAL ATTENTION. ASPIRATION OF MATERIAL INTO THE LUNGS DUE TO VOMITING
CAN CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL.
IF BREATHED: IF AFFECTED REMOVE INDIVIDUAL TO FRESH AIR. IF BREATHING IS

DIFFICULT, ADMINISTER OXYGEN. IF BREATHING HAS STOPPED GIVE ARTIFICIAL
RESPIRATION. KEEP PERSON WARM, QUIET AND GET MEDICAL ATTENTION.
PRIMARY ROUTE(S) OF ENTRY: INHALATION, SKIN CONTACT
EFFECTS OF CHRONIC OVEREXPOSURE:
PROLONGED AND REPEATED EXPOSURE TO N-HEXANE MAY DAMAGE PERIPHERAL NERVE

TISSUE (THAT OF THE ARMS AND LEGS) AND RESULT IN MUSCULAR WEAKNESS AND
LOSS OF SENSATION IN THE EXTREMITIES (PERIPHERAL NEUROPATHY). METHYL ETHYL
KETONE MAY POTENTIATE (SHORTEN THE TIME OF ONSET) PERIPHERAL NEUROPATHY
CAUSED BY N-HEXANE.
PROLONGED AND REPEATED INHALATION OF HIGH LEVELS OF MIXED ISOMERS OF

HEXANE RESULTED IN KIDNEY DAMAGE IN MALE RATS. THE EFFECTS OBSERVED ARE
THE SAME AS THOSE SEEN IN MALE RATS EXPOSED TO OTHER HYDROCARBONS. THE
MECHANISM BY WHICH THESE CHEMICALS CAUSE THE CHARACTERISTIC KIDNEY
TOXICITY IS UNIQUE TO THE MALE RAT AND THE KIDNEY EFFECTS ARE NOT EXPECTED
TO OCCUR IN MAN.
OVEREXPOSURE TO THIS MATERIAL (OR ITS COMPONENTS) HAS BEEN SUGGESTED AS A

CAUSE OF THE FOLLOWING EFFECTS IN HUMANS:, CENTRAL NERVOUS SYSTEM EFFECTS
SECTION VI - REACTIVITY DATA
HAZARDOUS POLYMERIZATION: CANNOT OCCUR

STABILITY: STABLE
INCOMPATIBILITY: AVOID CONTACT WITH:, STRONG OXIDIZING AGENTS
SECTION VII - SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:

SMALL SPILL:
ELIMINATE ALL SOURCES OF IGNITION SUCH AS FLARES, FLAMES (INCLUDING PILOT

LIGHTS), AND ELECTRICAL SPARKS.
ABSORB LIQUID ON VERMICULITE, FLOOR ABSORBENT, OR OTHER ABSORBENT MATERIAL

AND TRANSFER TO HOOD.
LARGE SPILL: ELIMINATE ALL IGNITION SOURCES (FLARES, FLAMES INCLUDING

PILOT LIGHTS, ELECTRICAL SPARKS). PERSONS NOT WEARING PROTECTIVE EQUIPMENT
SHOULD BE EXCLUDED FROM AREA OF SPILL UNTIL CLEAN-UP HAS BEEN COMPLETED.
STOP SPILL AT SOURCE. PREVENT FROM ENTERING DRAINS, SEWERS, STREAMS OR
OTHER BODIES OF WATER. PREVENT FROM SPREADING. IF RUNOFF OCCURS, NOTIFY
AUTHORITIES AS REQUIRED. PUMP OR VACUUM TRANSFER SPILLED PRODUCT TO CLEAN
CONTAINERS FOR RECOVERY. ABSORB UNRECOVERABLE PRODUCT. TRANSFER
CONTAMINATED ABSORBENT, SOIL AND OTHER MATERIALS TO CONTAINERS FOR
DISPOSAL.
WASTE DISPOSAL METHOD:
SMALL SPILL: DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL
REGULATIONS.
LARGE SPILL: DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND
FEDERAL REGULATIONS.
SECTION VIII - PROTECTIVE EQUIPMENT TO BE USED
RESPIRATORY PROTECTION: IF WORKPLACE EXPOSURE LIMIT(S) OF PRODUCT OR ANY

COMPONENT IS EXCEEDED (SEE SECTION II), A NIOSH/MSHA APPROVED AIR SUPPLIED
RESPIRATOR IS ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL. OSHA
REGULATIONS ALSO PERMIT OTHER NIOSH/MSHA RESPIRATORS (NEGATIVE PRESSURE
TYPE) UNDER SPECIFIED CONDITIONS (SEE YOUR INDUSTRIAL HYGIENIST).
ENGINEERING OR ADMINISTRATIVE CONTROLS SHOULD BE IMPLEMENTED TO REDUCE
EXPOSURE.
VENTILATION: PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST)

VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
PROTECTIVE GLOVES: WEAR RESISTANT GLOVES SUCH AS:, NITRILE RUBBER, NATURAL
RUBBER
EYE PROTECTION: CHEMICAL SPLASH GOGGLES IN COMPLIANCE WITH OSHA

REGULATIONS ARE ADVISED; HOWEVER, OSHA REGULATIONS ALSO PERMIT OTHER TYPE
SAFETY GLASSES. CONSULT YOUR SAFETY REPRESENTATIVE.

OTHER PROTECTIVE EQUIPMENT: TO PREVENT REPEATED OR PROLONGED SKIN CONTACT,

WEAR IMPERVIOUS CLOTHING AND BOOTS.
SECTION IX - SPECIAL PRECAUTIONS OR OTHER COMMENTS
CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTIED SINCE EMPTIED

CONTAINERS RETAIN PRODUCT RESIDUES (VAPOR, LIQUID, AND/OR SOLID), ALL
HAZARD PRECAUTIONS GIVEN IN THE DATA SHEET MUST BE OBSERVED.
WARNING!!! SUDDEN RELEASE OF HOT ORGANIC CHEMICAL VAPORS OR MISTS FROM

PROCESS EQUIPMENT OPERATING AT ELEVATED TEMPERATURE AND PRESSURE OR SUDDEN
INGRESS OF AIR INTO VACUUM EQUIPMENT MAY RESULT IN IGNITIONS WITHOUT
THE PRESENCE OF OBVIOUS IGNITION SOURCES. PUBLISHED "AUTOIGNITION" OR
"IGNITION" TEMPERATURE VALUES CANNOT BE TREATED AS SAFE OPERATING
TEMPERATURES IN CHEMICAL PROCESSES WITHOUT ANALYSIS OF THE ACTUAL PROCESS
CONDITIONS. ANY USE OF THIS PRODUCT IN ELEVATED TEMPERATURE PROCESSES
SHOULD BE THOROUGHLY EVALUATED TO ESTABLISH AND MAINTAIN SAFE OPERATING
CONDITIONS.
THE INFORMATION ACCUMULATED HEREIN IS BELIEVED TO BE ACCURATE BUT IS NOT

WARRANTED TO BE WHETHER ORIGINATING WITH THE COMPANY OR NOT. RECIPIENTS
ARE ADVISED TO CONFIRM IN ADVANCE OF NEED THAT THE INFORMATION IS
CURRENT, APPLICABLE, AND SUITABLE TO THEIR CIRCUMSTANCES.
LAST PAGE--SEE ATTACHMENT PAGE ENCLOSED--LAST PAGE
DEFINITIONS
This definition page is intended for use with Material Safety Data Sheets
supplied by the Ashland Chemical Company. Recipients of these data sheets
should consult the OSHA Safety and Health Standards (29 CFR 1910),
particularly subpart G - Occupational Health and Environmental Control,
and subpart I - Personal Protective Equipment, for general guidance on
control of potential Occupational Health and Safety Hazards.
SECTION I
PRODUCT IDENTIFICATION
GENERAL OR GENERIC ID: Chemical family or product description.
DOT HAZARD CLASSIFICATION: Product meets DOT criteria for hazards listed.
SECTION II
COMPONENTS
Components are listed in this section if they present a physical or health

hazard and are present at or above 1% in the mixture. If a component is
identified as a CARCINOGEN by NTP, IARC, or OSHA as of the date on the

MSDS, it will be listed and footnoted in this section when present at or

above 0.1% in the product. Negative conclusions concerning carcinogenicity
are not reported. Additional health information may be found in Section V.
Components subject to the reporting requirements of Section 313 of SARA
Title III are identified in the footnotes in this section, along with
typical percentages. Other components may be listed if deemed appropriate.
Exposure recommendations are for components. OSHA Permissible Exposure

Limits (PELS) and American Conference of Governmental Industrial
Hygienists (ACGIH) Threshold Limit Values (TLVs) appear on the line with
the component identification. Other recommendations appear as footnotes.
SECTION III
PHYSICAL DATA
BOILING POINT: Of product if known. The lowest value of the components is

listed for mixtures.
VAPOR PRESSURE: Of product if known. The highest value of the components

is listed for mixtures.
SPECIFIC VAPOR DENSITY: Compared to AIR = 1. If the Specific Vapor Density

of a product is not known, the value is expressed as lighter or greater
than air.
SPECIFIC GRAVITY: Compared to WATER = 1. If Specific Gravity of product is

not known, the value is expressed as less than or greater than water.
pH: If applicable.
PERCENT VOLATILES: Percentage of material with initial boiling point below

425 degrees Fahrenheit and vapor pressure above 0.1 mm Hg at 68 F.
EVAPORATION RATE: Indicated as faster or slower than ETHYL ETHER, unless

otherwise stated.
SECTION IV
FIRE AND EXPLOSION DATA
FLASH POINT: Method identified.
EXPLOSION LIMITS: For product if known. The value of the components is

listed for mixtures.
HAZARDOUS DECOMPOSITION PRODUCTS: Known or expected hazardous products

resulting from heating, burning or other reactions.
EXTINGUISHING MEDIA: Following National Fire Protection Association

criteria.
FIREFIGHTING PROCEDURES: Minimum equipment to protect firefighters from

toxic products of vaporization, combustion or decomposition in fire
situations. Other firefighting hazards may also be indicated.
SPECIAL FIRE AND EXPLOSION HAZARDS: States hazards not covered by other
sections.
NFPA CODES: Hazard ratings assigned by the National Fire Protection

Association.
SECTION V
HEALTH HAZARD DATA
PERMISSIBLE EXPOSURE LIMIT: For product.
THRESHOLD LIMIT VALUE: For product.
EFFECTS OF ACUTE OVEREXPOSURE: Potential local and systemic effects due to

single or short term overexposure to the eyes and skin or through
inhalation or ingestion.
EFFECTS OF CHRONIC OVEREXPOSURE: Potential local and systemic effects due

to repeated or long term overexposure to the eyes and skin or through
inhalation or ingestion.
FIRST AID: Procedures to be followed when dealing with accidental

overexposure.
PRIMARY ROUTE OF ENTRY: Based on properties and expected use.
SECTION VI
REACTIVITY DATA
HAZARDOUS POLYMERIZATION: Conditions to avoid to prevent hazardous

polymerization resulting in a large release of energy.
STABILITY: Conditions to avoid to prevent hazardous or violent

decomposition.
INCOMPATIBILITY: Materials and conditions to avoid to prevent hazardous

reactions.
SECTION VII
SPILL OR LEAK PROCEDURES
Reasonable precautions to be taken and methods of containment, clean-up

and disposal. Consult federal, state and local regulations for accepted
procedures and any reporting or notification requirements.
SECTION VIII
PROTECTIVE EQUIPMENT TO BE USED
Protective equipment which may be needed when handling the product.
SECTION IX
SPECIAL PRECAUTIONS OR OTHER COMMENTS
Covers any relevant points not previously mentioned.
ADDITIONAL COMMENTS
Containers should be either reconditioned by CERTIFIED firms or properly
disposed of by APPROVED firms. Disposal of containers should be in
accordance with applicable laws and regulations. "EMPTY" drums should not
be given to individuals. Serious accidents have resulted from the misuse
of "EMPTIED" containers (drums, pails, etc.). Refer to Sections IV and IX.

file:///C|/Documents%20and%20Settings/lanewg/My%20Documents/DATA/QA%20Amendments/MSDS/Black%20Oil/SourCrudeMSDS.txt
MSDS Document ViewerPETROLEUM CRUDE OIL-SOUR
PETROLEUM CRUDE OIL-SOUR
MSDS No. 0103701 US/ENGLISH
SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
MANUFACTURER/SUPPLIER: EMERGENCY HEALTH INFORMATION:

Amoco Oil Company 1 (800) 447-8735
200 East Randolph Drive
Chicago, Illinois 60601 U.S.A. EMERGENCY SPILL INFORMATION:
1 (800) 424-9300 CHEMTREC (USA)
OTHER PRODUCT SAFETY INFORMATION:

1 (630) 434-6377 (USA)
SUBSTANCE: PETROLEUM CRUDE OIL-SOUR
TRADE NAMES/SYNONYMS:
CRUDE OIL; SOUR CRUDE OIL; ROCK OIL; SENECA OIL; PROCESS STREAM; CONDENSATE;
S-041; CE2; AA3; 1037
CREATION DATE: Sep 20 1999

REVISION DATE: Jun 07 2000
SECTION 2 COMPOSITION, INFORMATION ON INGREDIENTS
COMPONENT: CRUDE OIL

EC NUMBER (EINECS): 232-298-5
PERCENTAGE: 100
COMPONENT: BENZENE
CAS NUMBER: 71-43-2
PERCENTAGE: 0-2
COMPONENT: HYDROGEN SULFIDE

PERCENTAGE: <1
(See Section 8, "Exposure Controls, Personal Protection", for exposure

guidelines)
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SECTION 3 HAZARDS IDENTIFICATION
NFPA RATINGS (SCALE 0-4): HEALTH=2 FIRE=3 REACTIVITY=0
EMERGENCY OVERVIEW:
COLOR: brown to black
PHYSICAL FORM: oil
ODOR: petroleum odor
SIGNAL WORD: DANGER!
MAJOR HEALTH HAZARDS: Extremely flammable. Inhalation of vapor/aerosol
concentrations above the recommended exposure limits causes headaches,
drowsiness, and nausea, and may lead to unconsciousness or death. Harmful or
fatal if liquid is aspirated into the lungs. Contains Benzene. Cancer hazard.
Can cause blood disorders. Harmful when absorbed through the skin. Prolonged or
repeated contact can defat the skin and lead to irritation and/or dermatitis.
May release hydrogen sulfide which can be harmful or fatal.
PHYSICAL HAZARDS: Extremely flammable liquid and vapor. Vapor may cause flash
fire.
POTENTIAL HEALTH EFFECTS:

INHALATION:
Inhalation of vapor/aerosol concentrations above the recommended exposure limits
causes headaches, drowsiness, and nausea, and may lead to unconsciousness or
death. Can cause respiratory irritation. Cancer hazard. Can cause blood
disorders. Vapors containing hydrogen sulfide may accumulate during storage or
transport. Harmful or fatal if inhaled.
SKIN CONTACT:
Prolonged or repeated contact can defat the skin and lead to irritation and /or
dermatitis. Cancer hazard. Can cause blood disorders. Possible cancer hazard
based on skin painting studies in laboratory animals.
EYE CONTACT:
No significant health hazards identified.
INGESTION:
Harmful or fatal if liquid is aspirated into lungs. Ingestion causes
gastrointestinal irritation and diarrhea.
SECTION 4 FIRST AID MEASURES
INHALATION: If adverse effects occur, remove to uncontaminated area. Give

artificial respiration if not breathing. Get immediate medical attention.
SKIN CONTACT: Wash exposed skin with soap and water. Remove contaminated
clothing and thoroughly clean and dry before reuse. Get medical attention if
irritation develops.
EYE CONTACT: Flush eyes with plenty of water. Get medical attention if
irritation persists.
INGESTION: If swallowed, drink plenty of water, do NOT induce vomiting. Get

immediate medical attention.
SECTION 5 FIRE FIGHTING MEASURES
FIRE AND EXPLOSION HAZARDS: Severe fire hazard. Vapor/air mixtures are explosive
above flash point. The vapor is heavier than air. Vapors or gases may ignite at
distant ignition sources and flash back.

EXTINGUISHING MEDIA: regular dry chemical, carbon dioxide, water, regular foam
Large fires: Use regular foam or flood with fine water spray.
FIRE FIGHTING: Move container from fire area if it can be done without risk.
Cool containers with water spray until well after the fire is out. Stay away
from the ends of tanks. For fires in cargo or storage area: Cool containers with
water from unmanned hose holder or monitor nozzles until well after fire is out.
If this is impossible then take the following precautions: Keep unnecessary
people away, isolate hazard area and deny entry. Let the fire burn. Withdraw
immediately in case of rising sound from venting safety device or any
discoloration of tanks due to fire. For tank, rail car or tank truck: Evacuation
radius: 800 meters (1/2 mile). Water may be ineffective. Water or foam may cause
frothing.
FIRE FIGHTING PROTECTIVE EQUIPMENT: Firefighters should wear full bunker gear,
including a positive pressure self contained breathing apparatus.
FLASH POINT: -45.0 to 212 F (-42.8 to 100 C)

HAZARDOUS COMBUSTION PRODUCTS:
Thermal decomposition products or combustion: hydrocarbons, hydrogen sulfide,
oxides of carbon, oxides of sulfur
SECTION 6 ACCIDENTAL RELEASE MEASURES
Avoid heat, flames, sparks and other sources of ignition. Stop leak if possible
without personal risk. Reduce vapors with water spray. Small spills: Absorb with
sand or other non-combustible material. Collect spilled material in appropriate
container for disposal. Large spills: Dike for later disposal. Remove sources of
ignition. Keep unnecessary people away, isolate hazard area and deny entry.
Notify Local Emergency Planning Committee and State Emergency Response
Commission for release greater than or equal to RQ (U.S. SARA Section 304). If
release occurs in the U.S. and is reportable under CERCLA Section 103, notify
the National Response Center at (800)424-8802 (USA) or (202)426-2675 (USA).
SECTION 7 HANDLING AND STORAGE
STORAGE: Avoid heat, flames, sparks and other sources of ignition. Grounding and
bonding required. Keep container tightly closed. Store in a well-ventilated
area.
HANDLING: Keep away from all ignition sources. Keep container tightly closed.
Use only with adequate ventilation. Ground and bond containers when transferring
materials. After this container has been emptied, it may contain product
residue; observe all warnings and precautions listed for this product. SPECIAL
PRECAUTIONS: Empty containers may contain toxic, flammable/combustible or
explosive residue or vapors. Do not cut, grind, drill, weld, reuse or dispose of
containers unless adequate precautions are taken against these hazards. Do not
eat, drink or smoke in areas of use or storage. Use good personal hygiene
practices. Wash hands before eating, drinking, smoking or using toilet
facilities. Remove contaminated clothing and thoroughly clean and dry before
reuse. Wash thoroughly after work using soap and water.
SECTION 8 EXPOSURE CONTROLS, PERSONAL PROTECTION

EXPOSURE LIMITS:
PETROLEUM CRUDE OIL-SOUR:
MINERAL OIL MIST:
5 mg/m3 OSHA TWA
5 mg/m3 ACGIH TWA
10 mg/m3 ACGIH STEL
5 mg/m3 MEXICO TWA
10 mg/m3 MEXICO STEL
BENZENE:
1 ppm OSHA TWA
5 ppm OSHA STEL 15 minute(s)
0.5 ppm OSHA action level
0.5 ppm ACGIH TWA (skin)
2.5 ppm ACGIH STEL (skin)
10 ppm (30 mg/m3) MEXICO TWA
25 ppm (75 mg/m3) MEXICO STEL
HYDROGEN SULFIDE:
20 ppm OSHA ceiling
50 ppm OSHA peak 10 minute(s) (once if no other measurable exposure occurs)
10 ppm (14 mg/m3) OSHA TWA (vacated by 58 FR 35338, June 30, 1993)
15 ppm (21 mg/m3) OSHA STEL (vacated by 58 FR 35338, June 30, 1993)
10 ppm ACGIH TWA
15 ppm ACGIH STEL
VENTILATION: Control airborne concentrations below the exposure guidelines.
EYE PROTECTION: None required; however, use of eye protection is good industrial
practice.
CLOTHING: Do not get on skin or clothing. Wear protective clothing, including

shoes that cannot be penetrated by chemicals or oil, if prolonged or repeated
contact is likely. Wash thoroughly after handling.
GLOVES: Wear gloves that cannot be penetrated by chemicals or oil.
RESPIRATOR: Use with adequate ventilation. Avoid breathing vapor and/or mist. If
ventilation is inadequate, use a NIOSH certified respirator with an organic
vapor cartridge and P95 particulate filter.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: liquid

TEXTURE: viscous
PHYSICAL FORM: oil
BOILING POINT: 0.0-1000.0 F (-17.8 to 537.8 C)
FREEZING POINT: -76 to -4 F (-60 to -20 C)
VAPOR PRESSURE: >0.36 kPa @ 20 C
VAPOR DENSITY (air=1): >1.0
SPECIFIC GRAVITY (water=1): 0.74-1.03
WATER SOLUBILITY: <0.1%
PH: Not available
VOLATILITY: variable
ODOR THRESHOLD: Not available

EVAPORATION RATE: Not available

VISCOSITY: 31-9000 SUS @ 20 C (varies)
COEFFICIENT OF WATER/OIL DISTRIBUTION: Not available
SOLVENT SOLUBILITY:
Soluble: benzene, chloroform, ether, organic solvents
Slightly Soluble: alcohol
SECTION 10 STABILITY AND REACTIVITY
REACTIVITY: Stable at normal temperatures and pressure.
CONDITIONS TO AVOID: Avoid heat, flames, sparks and other sources of ignition.
Containers may rupture or explode if exposed to heat. Keep out of water supplies
and sewers. Dangerous gases may accumulate in confined spaces.
INCOMPATIBILITIES: halogens, oxidizing materials
HAZARDOUS DECOMPOSITION:
POLYMERIZATION: Will not polymerize.
SECTION 11 TOXICOLOGICAL INFORMATION
EYE IRRITATION: Testing not conducted. See Other Toxicity Data.
SKIN IRRITATION: Testing not conducted. See Other Toxicity Data.
DERMAL LD50: Testing not conducted. See Other Toxicity Data.
ORAL LD50: Testing not conducted. See Other Toxicity Data.
INHALATION LC50: Testing not conducted. See Other Toxicity Data.
OTHER TOXICITY DATA:

Specific toxicity tests have not been conducted on this product. Our hazard
evaluation is based on information from similar products, the ingredients,
technical literature, and/or professional experience.
Crude oil is a naturally occurring complex mixture of hydrocarbons whose exact

composition and physical properties can vary widely depending upon its source.
SKIN: Repeated or prolonged contact may result in defatting, oil acne, redness,
itching, inflammation, cracking and possible secondary infections.
From skin-painting studies in laboratory animals, it has been concluded that

most, if not all, petroleum crudes, regardless of source, possess carcinogenic
activity to some degree. This means that workers who practice poor personal
hygiene and who are repeatedly exposed by direct skin contact to crude oil over
many years may potentially be at risk of developing skin cancer. However,
intermittent or occasional skin contact with petroleum crude oils is not
expected to have serious health effects as long as good personal hygiene
measures such as those outlined in this material safety data sheet are followed.
Crude oil has not been identified as a carcinogen by NTP, IARC or OSHA.
Hydrogen sulfide (H2S) gas may accumulate in storage tanks of bulk transport
compartments containing this material. Contact with eyes causes painful

conjunctivitis, sensitivity to light, tearing and clouding of vision. Inhalation

of low concentrations causes a runny nose with a loss of sense of smell, labored
breathing and shortness of breath. Direct contact with skin causes pain and
redness. Other symptoms of exposure include profuse salivation, nausea,
vomiting, diarrhea, giddiness, headache, dizziness, confusion, rapid breathing,
rapid heart rate, sweating, weakness, sudden collapse, unconsciousness and death
due to respiratory paralysis.Cardiac neurological effects have also been
reported. Prolonged breathing (greater than one hour) of concentrations of H2S
around 50 ppm can produce eye and respiratory tract irritation. Levels of 250 to
600 ppm will result in fluid in the lungs, and concentrations around 1,000 ppm
will cause unconsciousness and death in a short period oftime. Since the sense
of smell rapidly becomes insensitive to this toxic, colorless gas, odor cannot
be relied upon as an indicator of concentrations of the gas. Always exercise
caution when working around closed containers.
Aspiration of this product into the lungs can cause chemical pneumonia and can
be fatal. Aspiration into the lungs can occur while vomiting after ingestion of
this product.
Crude oils contain small, variable amounts of Benzene. Acute toxicity of benzene
results primarily from depression of the central nervous system (CNS).
Inhalation of concentrations over 50 ppm can produce headache,
lassitude,weariness, dizziness, drowsiness, or excitation. Exposure to very high
levels can result in unconsciousness and death. Long-term overexposure to
benzene has been associated with certain types of leukemia in humans. In
addition, the International Agency for Research on Cancer (IARC), the National
Toxicology Program, and OSHA consider benzene to be a human carcinogen. Chronic
exposures to benzene at levels of 100 ppm and below have been reported to cause
adverse blood effects including anemia. Benzene exposure can occur by inhalation
and absorption through the skin. Inhalation and forced feeding studies of
benzene in laboratory animals have produced a carcinogenic response in a variety
of organs, including possibly leukemia, other adverse effects on the
blood,chromosomal changes and some effects on the immune system. Exposure to
benzene at levels up to 300 ppm did not produce birth defects in animal studies;
however, exposure to the higher dosage levels (greater than 100 ppm) resulted in
a reduction of body weight of the rat pups (fetotoxicity). Changes in the testes
have been observed in mice exposed to benzene at 300 ppm, but reproductive
performance was not altered in rats exposed to benzene at the same level.
SECTION 12 ECOLOGICAL INFORMATION
Ecological testing has not been conducted on this product by BP Amoco.
SECTION 13 DISPOSAL CONSIDERATIONS
Dispose in accordance with all applicable regulations. Subject to disposal

regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): D001.
SECTION 14 TRANSPORT INFORMATION
U.S. DOT 49 CFR 172.101 SHIPPING NAME-ID NUMBER:

Petroleum crude oil-UN1267
U.S. DOT 49 CFR 172.101 HAZARD CLASS OR DIVISION:

3

U.S. DOT 49 CFR 172.101 PACKING GROUP:

II
U.S. DOT 49 CFR 172.101 AND SUBPART E LABELING REQUIREMENTS:

Flammable liquid
U.S. DOT 49 CFR 172.101 PACKAGING AUTHORIZATIONS:

EXCEPTIONS: 49 CFR 173.150
NON-BULK PACKAGING: 49 CFR 173.202
BULK PACKAGING: 49 CFR 173.242
U.S. DOT 49 CFR 172.101 QUANTITY LIMITATIONS:

PASSENGER AIRCRAFT OR RAILCAR: 5 L
CARGO AIRCRAFT ONLY: 60 L
CANADIAN TDG SHIPPING NAME-ID NUMBER:

CANADIAN TDG HAZARD CLASS OR DIVISION:

3
CANADIAN TDG PACKING GROUP:

II
LAND TRANSPORT ADR/RID:

SUBSTANCE NAME: Petroleum crude oil
ID NUMBER: UN1267
ADR/RID CLASS: 3
ITEM NUMBER: 2(b)
WARNING SIGN/LABEL: 3
HAZARD ID NUMBER: 33
AIR TRANSPORT IATA/ICAO:

SHIPPING NAME: Petroleum crude oil
ID NUMBER: UN1267
IATA/ICAO CLASS: 3
PACKAGING GROUP: II
LABEL: Flammable liquid
MARITIME TRANSPORT IMDG:

CORRECT TECHNICAL NAME: Petroleum crude oil
ID NUMBER: UN1267
IMDG CLASS: 3.1
PACKAGING GROUP: II
EmS No.: 3-07
MFAG Table No.: 311
IMDG CODE PAGE: 3141
SECTION 15 REGULATORY INFORMATION
CERCLA SECTIONS 102a/103 HAZARDOUS SUBSTANCES (40 CFR Part 302.4): This product
is reportable under 40 CFR Part 302.4 because it contains the following
substance(s):
HYDROGEN SULFIDE: 100 LBS RQ
Benzene: 10 LBS RQ
SARA TITLE III SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR Part 355):
HYDROGEN SULFIDE: 500 LBS TPQ

SARA SECTION 304 (40CFR355.40):

SARA TITLE III SECTION 311/312 HAZARDOUS CATEGORIZATION (40 CFR Part 370):
ACUTE: Y
CHRONIC: Y
FIRE: Y
REACTIVE: N
SUDDEN RELEASE: N
SARA TITLE III SECTION 313 (40 CFR Part 372): This product contains the
following substance(s), which is on the Toxic Chemicals List in 40 CFR Part 372:
HYDROGEN SULFIDE
Benzene
STATE REGULATIONS:
California Proposition 65: Y
Known to the state of California to cause the following:
Benzene
Cancer (Feb 27, 1987)
Developmental toxicity (Dec 26, 1997)
Male reproductive toxicity (Dec 26, 1997)
U.S. INVENTORY (TSCA): Listed on inventory.
EC INVENTORY (EINECS/ELINCS): In compliance.
JAPAN INVENTORY (MITI): Listed on inventory.
AUSTRALIA INVENTORY (AICS): Listed on inventory.
KOREA INVENTORY (ECL): Not determined.
CANADA INVENTORY (DSL): Listed on inventory.
PHILIPPINE INVENTORY (PICCS): Not determined.
CHINA INVENTORY (IECS): Not determined.
SECTION 16 OTHER INFORMATION
Prepared by: Product Stewardship and Toxicology
©Copyright 1984-2000 MDL Information Systems. All rights reserved.
This Material Safety Data Sheet conforms to the requirements of ANSI Z400.1.
NOTICE: The information presented herein is based on data considered to be
accurate as of the date of preparation of this Material Safety Data Sheet.
However, no warranty or representation, express or implied, is made as to the
accuracy or completeness of the foregoing data and safety information, nor is
any authorization given or implied to practice any patented invention without a
license. In addition, no responsibility can be assumed by vendor for any damage
or injury resulting from abnormal use, from any failure to adhere to recommended
practices, or from any hazards inherent in the nature of the product.

Sheet No: STI2214 Material Name: Straight-Run Gas Oil
ALIGN BP SDS Finals


Material Name: Straight-Run Gas Oil
Light Vacuum Gas Oil
________________________________________________________________________________
SAFETY DATA SHEET
Straight-Run Gas Oil

COMPANY/UNDERTAKING
Straight-Run Gas Oil
Alternative Names: Heavy Gas Oil, Light Gas Oil, Light Vacuum Distillate
Application
Britannic House
1 Finsbury Circus
London, EC2M 7BA

+44 (0) 20 7496 4411
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_________________________________________________________________________________
Gas oils (petroleum), straight-run. EINECS No: 265-043-1, CAS No: 64741-43-1
Gas oils (petroleum), light vacuum, EINECS No: 265-059-9, CAS No: 64741-58-8
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
May contain hydrogen sulphide.

_________________________________________________________________________________
Eyes
Skin
Ingestion
Inhalation
Medical Advice

develops.
_________________________________________________________________________________
Combustion Products
_________________________________________________________________________________
etc.).

_________________________________________________________________________________

Storage Conditions

Fire Prevention
_________________________________________________________________________________

Exposure Limits

Hydrogen sulphide

Protective Clothing
_________________________________________________________________________________

Typical Values
Grades: Straight-Run
Gas Oil,
Light
Vacuum Gas
Oil
Test Method Units
Colour amber
Odour gasoil-like
Kinematic viscosity @ ASTM D 445 mm²/s approx
40°C 2.5 - 13.5
Flash point (PMC) ASTM D 93 °C >55
_________________________________________________________________________________

Conditions to Avoid
Sources of ignition
Materials to Avoid

_________________________________________________________________________________


Eyes
Skin
dermatitis.
Ingestion
diarrhoea.
Inhalation
_________________________________________________________________________________
Mobility

Aquatic toxicity
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
impaired.
_________________________________________________________________________________
_________________________________________________________________________________
_________________________________________________________________________________

Harmful
EU Labelling
Symbol:
St. Andrew's Cross
Dead tree and fish
HARMFUL
DANGEROUS FOR THE ENVIRONMENT
Risk ( R ) Phrases:
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
The label must carry the Substance name.

Substance name: Gas oils (petroleum), straight-run
Substance name: Gas oils (petroleum), light vacuum
_________________________________________________________________________________
Compiled by:
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
Sheet Revisions


21/09/98 1, 3, 4, 7, 8, 11, 12, 15
17/07/2000 3, 4, 8, 15
SHEET NO: STI2214

______________________________________________________________________________

file:///C|/Documents%20and%20Settings/lanewg/My%20Documents/DATA/QA%20Amendments/MSDS/Black%20Oil/SweetCrudeMSDS.txt
MSDS Document ViewerPETROLEUM CRUDE OIL - SWEET
PETROLEUM CRUDE OIL - SWEET
MSDS No. 03885 US/ENGLISH
SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
MANUFACTURER/SUPPLIER: EMERGENCY HEALTH INFORMATION:

BP Oil Company 1 (800) 447-8735
200 East Randolph Drive
Chicago, Illinois 60601 U.S.A. EMERGENCY SPILL INFORMATION:
1 (800) 424-9300 CHEMTREC (USA)
OTHER PRODUCT SAFETY INFORMATION:

1 (630) 434-6377 (USA)
SUBSTANCE: PETROLEUM CRUDE OIL - SWEET
TRADE NAMES/SYNONYMS:
CRUDE OIL; SWEET CRUDE OIL; ROCK OIL; SENECA OIL; PROCESS STREAM; CONDENSATE;
S-041; CE2; AA3; 1037
CREATION DATE: Sep 20 1999

REVISION DATE: Jun 08 2000
SECTION 2 COMPOSITION, INFORMATION ON INGREDIENTS
COMPONENT: CRUDE OIL

PERCENTAGE: 100
COMPONENT: BENZENE
CAS NUMBER: 71-43-2
PERCENTAGE: 0-2
COMPONENT: HYDROGEN SULFIDE

PERCENTAGE: <1
(See Section 8, "Exposure Controls, Personal Protection", for exposure

guidelines)
SECTION 3 HAZARDS IDENTIFICATION
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NFPA RATINGS (SCALE 0-4): HEALTH=1 FIRE=3 REACTIVITY=0
EMERGENCY OVERVIEW:
PHYSICAL FORM: oil
SIGNAL WORD: DANGER!
MAJOR HEALTH HAZARDS: Extremely flammable. Inhalation of vapor/aerosol
concentrations above the recommended exposure limits causes headaches,
drowsiness, and nausea, and may lead to unconsciousness or death. Harmful or
fatal if liquid is aspirated into the lungs. Prolonged or repeated contact can
defat the skin and lead to irritation and/or dermatitis. Contains Benzene.
Cancer hazard. Can cause blood disorders. Harmful when absorbed through the
skin. May release hydrogen sulfide which can be harmful or fatal.
PHYSICAL HAZARDS: Extremely flammable liquid and vapor. Vapor may cause flash
fire.

INHALATION:
Inhalation of vapor/aerosol concentrations above the recommended exposure limits
causes headaches, drowsiness, and nausea, and may lead to unconsciousness or
death. Can cause respiratory irritation. Cancer hazard. Can cause blood
disorders. Vapors containing hydrogen sulfide may accumulate during storage or
transport. Harmful or fatal if inhaled.
SKIN CONTACT:
Prolonged or repeated contact can defat the skin and lead to irritation and /or
dermatitis. Cancer hazard. Can cause blood disorders. Possible cancer hazard
based on skin painting studies in laboratory animals.
EYE CONTACT:
No significant health hazards identified.
INGESTION:
Harmful or fatal if liquid is aspirated into lungs. Ingestion causes
gastrointestinal irritation and diarrhea.
SECTION 4 FIRST AID MEASURES
INHALATION: If adverse effects occur, remove to uncontaminated area. Give

artificial respiration if not breathing. Get immediate medical attention.
SKIN CONTACT: Wash exposed skin with soap and water. Remove contaminated
clothing and thoroughly clean and dry before reuse. Get medical attention if
irritation develops.
EYE CONTACT: Flush eyes with plenty of water. Get medical attention if
INGESTION: If swallowed, drink plenty of water, do NOT induce vomiting. Get

SECTION 5 FIRE FIGHTING MEASURES
FIRE AND EXPLOSION HAZARDS: Severe fire hazard. Vapor/air mixtures are explosive
above flash point. The vapor is heavier than air. Vapors or gases may ignite at
distant ignition sources and flash back.
EXTINGUISHING MEDIA: regular dry chemical, carbon dioxide, water, regular foam

Large fires: Use regular foam or flood with fine water spray.
FIRE FIGHTING: Move container from fire area if it can be done without risk.
Cool containers with water spray until well after the fire is out. Stay away
from the ends of tanks. For fires in cargo or storage area: Cool containers with
water from unmanned hose holder or monitor nozzles until well after fire is out.
If this is impossible then take the following precautions: Keep unnecessary
people away, isolate hazard area and deny entry. Let the fire burn. Withdraw
immediately in case of rising sound from venting safety device or any
discoloration of tanks due to fire. For tank, rail car or tank truck: Evacuation
radius: 800 meters (1/2 mile). Water may be ineffective. Water or foam may cause
frothing.
FIRE FIGHTING PROTECTIVE EQUIPMENT: Firefighters should wear full bunker gear,
including a positive pressure self contained breathing apparatus.
FLASH POINT: -45.0 to 212 F (-42.8 to 100 C)

SECTION 6 ACCIDENTAL RELEASE MEASURES
Avoid heat, flames, sparks and other sources of ignition. Stop leak if possible
without personal risk. Reduce vapors with water spray. Small spills: Absorb with
sand or other non-combustible material. Collect spilled material in appropriate
container for disposal. Large spills: Dike for later disposal. Remove sources of
ignition. Keep unnecessary people away, isolate hazard area and deny entry.
Notify Local Emergency Planning Committee and State Emergency Response
Commission for release greater than or equal to RQ (U.S. SARA Section 304). If
release occurs in the U.S. and is reportable under CERCLA Section 103, notify
the National Response Center at (800)424-8802 (USA) or (202)426-2675 (USA).
SECTION 7 HANDLING AND STORAGE
STORAGE: Avoid heat, flames, sparks and other sources of ignition. Grounding and
bonding required. Keep container tightly closed. Store in a well-ventilated
area.
HANDLING: Keep away from all ignition sources. Keep container tightly closed.
Use only with adequate ventilation. Ground and bond containers when transferring
materials. After this container has been emptied, it may contain product
residue; observe all warnings and precautions listed for this product. SPECIAL
PRECAUTIONS: Empty containers may contain toxic, flammable/combustible or
explosive residue or vapors. Do not cut, grind, drill, weld, reuse or dispose of
containers unless adequate precautions are taken against these hazards. Do not
eat, drink or smoke in areas of use or storage. Use good personal hygiene
practices. Wash hands before eating, drinking, smoking or using toilet
facilities. Remove contaminated clothing and thoroughly clean and dry before
reuse. Wash thoroughly after work using soap and water.
SECTION 8 EXPOSURE CONTROLS, PERSONAL PROTECTION
EXPOSURE LIMITS:

PETROLEUM CRUDE OIL - SWEET:

MINERAL OIL MIST:
5 mg/m3 OSHA TWA
5 mg/m3 ACGIH TWA
10 mg/m3 ACGIH STEL
5 mg/m3 MEXICO TWA
10 mg/m3 MEXICO STEL
BENZENE:
1 ppm OSHA TWA
5 ppm OSHA STEL 15 minute(s)
0.5 ppm OSHA action level
0.5 ppm ACGIH TWA (skin)
2.5 ppm ACGIH STEL (skin)
HYDROGEN SULFIDE:
20 ppm OSHA ceiling
50 ppm OSHA peak 10 minute(s) (once if no other measurable exposure occurs)
10 ppm (14 mg/m3) OSHA TWA (vacated by 58 FR 35338, June 30, 1993)
15 ppm (21 mg/m3) OSHA STEL (vacated by 58 FR 35338, June 30, 1993)
10 ppm ACGIH TWA
15 ppm ACGIH STEL
VENTILATION: Control airborne concentrations below the exposure guidelines.
EYE PROTECTION: None required; however, use of eye protection is good industrial
practice.
CLOTHING: Do not get on skin or clothing. Wear protective clothing, including

shoes that cannot be penetrated by chemicals or oil, if prolonged or repeated
contact is likely. Wash thoroughly after handling.
GLOVES: Wear gloves that cannot be penetrated by chemicals or oil.
RESPIRATOR: Use with adequate ventilation. Avoid breathing vapor and/or mist. If
ventilation is inadequate, use a NIOSH certified respirator with an organic
vapor cartridge and P95 particulate filter.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: liquid

TEXTURE: viscous
PHYSICAL FORM: oil
BOILING POINT: 0.0-1000.0 F (-17.8 to 537.8 C)
FREEZING POINT: -76 to -4 F (-60 to -20 C)
VAPOR PRESSURE: >0.36 kPa @ 20 C
VAPOR DENSITY (air=1): >1.0
SPECIFIC GRAVITY (water=1): 0.74-1.03
WATER SOLUBILITY: <0.1%
PH: Not available
VOLATILITY: variable
ODOR THRESHOLD: Not available
EVAPORATION RATE: Not available
VISCOSITY: 31-9000 SUS @ 20 C (varies)

COEFFICIENT OF WATER/OIL DISTRIBUTION: Not available

SOLVENT SOLUBILITY:
Soluble: benzene, chloroform, ether, organic solvents
Slightly Soluble: alcohol
SECTION 10 STABILITY AND REACTIVITY
REACTIVITY: Stable at normal temperatures and pressure.
CONDITIONS TO AVOID: Avoid heat, flames, sparks and other sources of ignition.
Containers may rupture or explode if exposed to heat. Keep out of water supplies
and sewers. Dangerous gases may accumulate in confined spaces.
INCOMPATIBILITIES: halogens, oxidizing materials
HAZARDOUS DECOMPOSITION:
POLYMERIZATION: Will not polymerize.
SECTION 11 TOXICOLOGICAL INFORMATION
EYE IRRITATION: Testing not conducted. See Other Toxicity Data.
SKIN IRRITATION: Testing not conducted. See Other Toxicity Data.
DERMAL LD50: Testing not conducted. See Other Toxicity Data.
ORAL LD50: Testing not conducted. See Other Toxicity Data.
INHALATION LC50: Testing not conducted. See Other Toxicity Data.
OTHER TOXICITY DATA:

Specific toxicity tests have not been conducted on this product. Our hazard
evaluation is based on information from similar products, the ingredients,
technical literature, and/or professional experience.
Crude oil is a naturally occurring complex mixture of hydrocarbons whose exact

composition and physical properties can vary widely depending upon its source.
SKIN: Repeated or prolonged contact may result in defatting, oil acne, redness,
itching, inflammation, cracking and possible secondary infections.
From skin-painting studies in laboratory animals, it has been concluded that

most, if not all, petroleum crudes, regardless of source, possess carcinogenic
activity to some degree. This means that workers who practice poor personal
hygiene and who are repeatedly exposed by direct skin contact to crude oil over
many years may potentially be at risk of developing skin cancer. However,
intermittent or occasional skin contact with petroleum crude oils is not
expected to have serious health effects as long as good personal hygiene
measures such as those outlined in this material safety data sheet are followed.
Crude oil has not been identified as a carcinogen by NTP, IARC or OSHA.
Hydrogen sulfide (H2S) gas may accumulate in storage tanks of bulk transport
compartments containing this material. Contact with eyes causes painful
conjunctivitis, sensitivity to light, tearing and clouding of vision. Inhalation
of low concentrations causes a runny nose with a loss of sense of smell, labored

breathing and shortness of breath. Direct contact with skin causes pain and
redness. Other symptoms of exposure include profuse salivation, nausea,
vomiting, diarrhea, giddiness, headache, dizziness, confusion, rapid breathing,
rapid heart rate, sweating, weakness, sudden collapse, unconsciousness and death
due to respiratory paralysis.Cardiac neurological effects have also been
reported. Prolonged breathing (greater than one hour) of concentrations of H2S
around 50 ppm can produce eye and respiratory tract irritation. Levels of 250 to
600 ppm will result in fluid in the lungs, and concentrations around 1,000 ppm
will cause unconsciousness and death in a short period oftime. Since the sense
of smell rapidly becomes insensitive to this toxic, colorless gas, odor cannot
be relied upon as an indicator of concentrations of the gas. Always exercise
caution when working around closed containers.
Aspiration of this product into the lungs can cause chemical pneumonia and can
be fatal. Aspiration into the lungs can occur while vomiting after ingestion of
this product.
Crude oils contain small, variable amounts of Benzene. Acute toxicity of benzene
results primarily from depression of the central nervous system (CNS).
Inhalation of concentrations over 50 ppm can produce headache,
lassitude,weariness, dizziness, drowsiness, or excitation. Exposure to very high
levels can result in unconsciousness and death. Long-term overexposure to
benzene has been associated with certain types of leukemia in humans. In
addition, the International Agency for Research on Cancer (IARC), the National
Toxicology Program, and OSHA consider benzene to be a human carcinogen. Chronic
exposures to benzene at levels of 100 ppm and below have been reported to cause
adverse blood effects including anemia. Benzene exposure can occur by inhalation
and absorption through the skin. Inhalation and forced feeding studies of
benzene in laboratory animals have produced a carcinogenic response in a variety
of organs, including possibly leukemia, other adverse effects on the
blood,chromosomal changes and some effects on the immune system. Exposure to
benzene at levels up to 300 ppm did not produce birth defects in animal studies;
however, exposure to the higher dosage levels (greater than 100 ppm) resulted in
a reduction of body weight of the rat pups (fetotoxicity). Changes in the testes
have been observed in mice exposed to benzene at 300 ppm, but reproductive
performance was not altered in rats exposed to benzene at the same level.
SECTION 12 ECOLOGICAL INFORMATION
Ecological testing has not been conducted on this product by BP Amoco.
SECTION 13 DISPOSAL CONSIDERATIONS
Dispose in accordance with all applicable regulations. Subject to disposal

regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): D001.
SECTION 14 TRANSPORT INFORMATION
U.S. DOT 49 CFR 172.101 SHIPPING NAME-ID NUMBER:

U.S. DOT 49 CFR 172.101 HAZARD CLASS OR DIVISION:

3
U.S. DOT 49 CFR 172.101 PACKING GROUP:

II
U.S. DOT 49 CFR 172.101 AND SUBPART E LABELING REQUIREMENTS:

Flammable liquid
U.S. DOT 49 CFR 172.101 PACKAGING AUTHORIZATIONS:

EXCEPTIONS: 49 CFR 173.150
NON-BULK PACKAGING: 49 CFR 173.202
BULK PACKAGING: 49 CFR 173.242
U.S. DOT 49 CFR 172.101 QUANTITY LIMITATIONS:

PASSENGER AIRCRAFT OR RAILCAR: 5 L
CARGO AIRCRAFT ONLY: 60 L
CANADIAN TDG SHIPPING NAME-ID NUMBER:

CANADIAN TDG HAZARD CLASS OR DIVISION:

3
CANADIAN TDG PACKING GROUP:

II
LAND TRANSPORT ADR/RID:

SUBSTANCE NAME: Petroleum crude oil
ID NUMBER: UN1267
ADR/RID CLASS: 3
ITEM NUMBER: 2(b)
WARNING SIGN/LABEL: 3
HAZARD ID NUMBER: 33
AIR TRANSPORT IATA/ICAO:

SHIPPING NAME: Petroleum crude oil
ID NUMBER: UN1267
IATA/ICAO CLASS: 3
PACKAGING GROUP: II
LABEL: Flammable liquid
MARITIME TRANSPORT IMDG:

CORRECT TECHNICAL NAME: Petroleum crude oil
ID NUMBER: UN1267
IMDG CLASS: 3.1
PACKAGING GROUP: II
EmS No.: 3-07
MFAG Table No.: 311
IMDG CODE PAGE: 3141
SECTION 15 REGULATORY INFORMATION
CERCLA SECTIONS 102a/103 HAZARDOUS SUBSTANCES (40 CFR Part 302.4): This product
is reportable under 40 CFR Part 302.4 because it contains the following
substance(s):
Benzene: 10 LBS RQ
SARA TITLE III SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR Part 355):
HYDROGEN SULFIDE: 500 LBS TPQ
SARA SECTION 304 (40CFR355.40):

SARA TITLE III SECTION 311/312 HAZARDOUS CATEGORIZATION (40 CFR Part 370):
ACUTE: Y
CHRONIC: Y
FIRE: Y
REACTIVE: N
SUDDEN RELEASE: N
SARA TITLE III SECTION 313 (40 CFR Part 372): This product contains the
following substance(s), which is on the Toxic Chemicals List in 40 CFR Part 372:
HYDROGEN SULFIDE
Benzene
STATE REGULATIONS:
California Proposition 65: Y
Known to the state of California to cause the following:
Benzene
Cancer (Feb 27, 1987)
Developmental toxicity (Dec 26, 1997)
Male reproductive toxicity (Dec 26, 1997)
U.S. INVENTORY (TSCA): Listed on inventory.
EC INVENTORY (EINECS/ELINCS): In compliance.
JAPAN INVENTORY (MITI): Listed on inventory.
AUSTRALIA INVENTORY (AICS): Listed on inventory.
KOREA INVENTORY (ECL): Not determined.
CANADA INVENTORY (DSL): Listed on inventory.
PHILIPPINE INVENTORY (PICCS): Not determined.
CHINA INVENTORY (IECS): Not determined.
SECTION 16 OTHER INFORMATION
Prepared by: Product Stewardship and Toxicology
©Copyright 1984-2000 MDL Information Systems. All rights reserved.
TThis Material Safety Data Sheet conforms to the requirements of ANSI Z400.1.
NOTICE: The information presented herein is based on data considered to be
accurate as of the date of preparation of this Material Safety Data Sheet.
However, no warranty or representation, express or implied, is made as to the
accuracy or completeness of the foregoing data and safety information, nor is
any authorization given or implied to practice any patented invention without a
license. In addition, no responsibility can be assumed by vendor for any damage
or injury resulting from abnormal use, from any failure to adhere to recommended
practices, or from any hazards inherent in the nature of the product.

file:///C|/Documents%20and%20Settings/lanewg/My%20Documents/DATA/QA%20Amendments/MSDS/Black%20Oil/Vacuum%20Gas%20Oil.htm

VACUUM GAS OIL
CITGO
CITGO Petroleum Corporation

P.O. Box 3758
Tulsa, Oklahoma 74102
Material Safety Data Sheet
Trade Name: Vacuum Gas Oil
Commodity Code: 07-201
Synonyms: Vacuum Distillates, VGO, Cat Feed
CAS No. (Refer to Section 1): 68955-27-1
CITGO Index No.: 1473
Date: March 19, 1992
Technical Contact: (609) 423-5400
Medical Emergency: (918) 495-4700
CHEMTREC Emergency: (800) 424-9300
Material Hazard Evaluation

(Per OSHA Hazard Communication Standard [29 CFR Part 1910.1200]) (OHCS)
Health: Cancer suspect agent. Similar products have been shown to cause
cancer in laboratory animals.
Precautionary Statement: WARNING: Avoid repeated or prolonged skin

contact.
HMIS Rating(1):
Health 0
Flammability 1
Reactivity 0
1.0 Generic Composition/Components
Components CAS # % Hazard Data
Vacuum Distillates* 68955-27-1 100 Oral LD50 (rat): > 5g/kg*
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Drml LD50 (rbt): > 5g/kg*

Eyes, Draize (rbt): 0-0-.33*
/110 in 24 hr test.
*For similar product.
*A complex combination of hydrocarbons produced by the vacuum distillation

of the residuum from the atmospheric distillation of crude oil. Chemical
Family: Petroleum Hydrocarbons
See also Environmental Section 9.0
(1) Hazard Rating: least-0; slight-1; moderate-2; high-3; extreme-4

CITGO assignment based on our evaluation per NFPA and NPCA guidelines.
NA - Not Applicable
ND - No Data
NE - Not Established
Vacuum Gas Oil (07-201, March 19, 1992 CIN #: 1473)
2.0 Physical Data
Physical Hazard Classification (Per 29 CFR Part 1910.1200)

No Combustible
No Flammable
No Pyrophoric
No Compressed Gas
No Organic Peroxide
No Reactivity
No Explosive
No Oxidizer
Yes Stable
Boiling Point, 760 mmHg, Deg. C (Deg. F): > 249 (> 480) (Wide Range)
Specific Gravity (60/60 Deg. F) (H2O = 1): 0.91-0.93
Vapor Density (Air=1): > 1
% Volatiles by Volume: None
Melting Point, Deg. C (Deg. F): ND
Vapor Pressure, mmHg, 25 Deg. C: < 0.01 (mmHg, 15 Deg. C)
Solubility in H2O, % by Weight: Not soluble

Evaporation Rate (Butyl Acetate=1): NA
pH of Undiluted Product: NA
Molecular Wt.: ND
Appearance and Odor: Straw colored to dark brown, petroleum odor.
3.0 Fire and Explosion Data
Flash Point, COC, Deg. C (Deg. F)

> 149 (> 300)
Flash Point, PM, Deg. C (Deg. F)

ND
Fire Point, COC, Deg. C (Deg. F)

ND
NFPA Rating(2)
Health: 0
Flammability: 1
Reactivity: 0
Flammable Limits (% by volume in air)

Lower: NA
Upper: NA
Auto-ignition Temperature, Deg. C (Deg. F)

approx. 370 approx. (700)
Flammability Class
IIIB
Extinguishing Media
CO2, dry chemical, foam
Special Fire Fighting Procedure

Wear self-contained breathing apparatus when in a confined area. Avoid
inhalation of fumes. Water or foam may cause frothing.
Unusual Fire or Explosion Hazard

Water may be ineffective.
(2) Hazard Rating: least-0; slight-1; moderate-2; high-3; extreme-4

CITGO assignment based on our evaluation per NFPA guidelines.
4.0 Reactivity Data

Stability: Stable
Conditions Contributing to Instability: Excessive heat
Incompatibility: Strong oxidizers
Hazardous Decomposition Products (thermal, unless otherwise specified):

CO2, (CO under incomplete combustion), Sulfur Oxides (SOx)
Conditions Contributing to Hazardous Polymerization: None
5.0 Spill or Leak Procedures
Procedures if Material is Spilled:
* Small spills: Take up with non-combustible absorbent such as Fuller's

earth or sand. Place into containers for later disposal.
* Large spills: Control spill in earthen dikes for later recovery. Control
ignition sources around spill area.
* Report spills as required to appropriate authorities.
Waste Disposal:
* It is the responsibility of the user to determine if the material is a

hazardous waste at the time of disposal. Check before disposing to be sure
of being in compliance with all applicable laws and regulations.
* RCRA Hotline Number: 800-424-9346.
Protective Measures During Repair and Maintenance of Contaminated

Equipment:
* Eliminate all ignition sources.
* Wash exposed skin thoroughly with soap and water.
* Remove soiled clothing.
* Use oil impervious gloves if extended direct contact with residues is

expected.
* Handle as a potential carcinogen.
6.0 Health Hazard Data
Health Hazard Classification (Per 29 CFR Part 1910.1200)

No Carcinogen
No Corrosive
Yes Animal Carcinogen*
No Irritant
No Suspect Carcinogen
No Sensitizer
No Mutagen
No Teratogen
No Highly Toxic
No Target Organ
No Toxic
Product listed as Carcinogen or Potential Carcinogen by:

NTP No
IARC Yes*
OSHA No
Other No
*For similar material.
Toxicity summary: This product is a mixture of petroleum hydrocarbons and

may contain significant amounts of polynuclear aromatic hydrocarbons which
have been shown to cause skin cancer after prolonged or frequent contact
with the skin of test animals. It must be assumed that cancer could also
occur in humans after repeated or prolonged skin contact, thus users must
use the appropriate skin protection when handling this product to reduce
exposure to a minimum. The International Agency for Research on Cancer
(IARC) has determined that there is sufficient evidence that heavy vacuum
distillates derived from refining crude oil cause cancer in laboratory
animals.
Acute Exposure Symptoms
Inhalation: The inhalation toxicity of this product has not been

determined. However, based on the toxicology of similar products,
breathing of fumes may cause central nervous system (CNS) effects and be
moderately toxic to internal organs. Signs and symptoms of CNS effects
include one or more of the following: dizziness, headache, loss of
appetite, weakness and loss of coordination. This product may also cause
respiratory irritation and chemical pneumonitis when inhaled. Signs and
symptoms of respiratory irritation and pneumonitis may include coughing,
shortness of breath, bronchial irritation, chest discomfort and diminished
pulmonary function.
Dermal Contact: The dermal toxicity of this product has not been
determined. However, based upon the toxicology of similar products this

product is not expected to cause prolonged or significant skin irritation,

but may produce mild transient skin irritation. It may be moderately toxic
to internal organs if it is absorbed through the skin. The severity of
injury will depend on the amount absorbed.
Eye Contact: The eye irritation potential of this product has not been
determined. However, based upon the toxicology of similar products this
product is not expected to cause prolonged or significant eye irritation.
Ingestion: The oral toxicity of this product has not been determined.
However, based on the toxicology of similar products, this product may be
slightly toxic to internal organs if swallowed. The severity of injury
will depend upon the amount absorbed from the gut. Typical signs and
symptoms from ingestion include gastro-intestinal disturbances, vomiting
and diarrhea, headache, and tiredness. This product may present a moderate
aspiration hazard.
Injection: NA
Chronic Exposure Symptoms
Inhalation: The prolonged or repeated inhalation exposure may cause cancer

and chemical pneumonitis.
Dermal Contact: Prolonged or repeated exposure may cause skin cancer.

Repeated and prolonged exposure may also cause drying, cracking,
dermatitis, or folliculitis.
Eye Contact: Symptoms of chronic eye contact are believed to be similar to

those discussed above in Acute Toxicity Symptoms, Eye Contact.
Ingestion: Symptoms of chronic ingestion are believed to be similar to

those discussed above in Acute Toxicity Symptoms, Ingestion.
First Aid and Emergency Procedures for Acute Effects
Inhalation: If any of the above signs or symptoms occur, remove victim to

fresh air. Seek medical aid if symptoms continue.
Dermal Contact: Remove contaminated clothing. Wash skin thoroughly with

soap and water. Seek medical advice if any signs or symptoms described
above occur. Discard contaminated shoes. Contaminated clothing may be
washed.
Eye Contact: Wash the eyes with large amounts of water for 15 minutes,
occasionally lifting upper and lower eyelids. Remove contact lenses if
worn. If irritation persists, seek medical advice.

Ingestion: If swallowed give milk or water to drink and telephone for

medical advice. Do not induce vomiting without obtaining medical advice
because this product presents an aspiration hazard. If medical advice
cannot be obtained, take the victim and the container to the closest
medical emergency center or hospital.
Injection: Use surgical debridement procedure.
Medical Conditions Aggravated by Exposure: Individuals with chronic skin

or respiratory problems may have these conditions aggravated by exposure
to this product.
Notes to Physician: Dilute with milk, water or demulcents and remove by

lavage to extent possible. The Saybolt viscosity of this material is
approximately 350 SUS at 100 Deg. F, thus aspiration into the lungs
following ingestion is unlikely to occur. Remove all residues because this
product contains potential human carcinogens.
7.0 Special Protection Information
Ventilation Requirements: As required to maintain personnel exposures

below workplace exposure limits.
Permitted Air Threshold Concentrations:
TLV (mg/m(3)) OSHA PEL (mg/m(3))
Mineral Oil Mist TWA: 5 5

STEL: 10 NE
Specific Personal Protective Equipment:
Respiratory: Normally none is required. However, if high vapor pressure

concentrations or mists are expected, use only NIOSH/MSHA approved organic
respirator or self-contained breathing apparatus.
Eyes: Use chemical splash goggles if splashing is anticipated.
Dermal Contact: Body covering protection should be worn when handling

liquid. Use protective covering and gloves made of Buna-N and Poly-D.
Other Clothing or Equipment: If garments become soaked with hydrocarbon

liquids, they must be immediately changed. Shower with soap and water to
remove hydrocarbon residues from the skin. Wash exposed skin with soap and
water to remove residues. Material is potential carcinogen.
8.0 Transportation and Special Precautions

Storage:
Material is classified as NFPA Class III B combustible liquid. Store

distant from fire and ignition sources.
Consult appropriate Federal, State and Local authorities before reusing,

reconditioning, reclaiming, recycling or disposing of empty containers
and/or waste residues of this product.
DOT Information
DOT/UN Shipping Name: Petroleum Oil, NOS
Hazard Class: Non-hazardous
Hazard Identification Number: NA
DOT Placard: Not Required
9.0 Environmental Data
Product Name
Vacuum Gas Oil
Commodity Code: 07-201
SARA TITLE III
Section 313 - Toxic Chemicals
This product does not contain toxic chemicals of Section 313 of Title III,
Superfund Amendments and Reauthorization Act of 1986 (SARA) and 40 CFR
Part 372.
Components CAS # %
None NA NA
Section 311 - Hazard Categories

No Not Applicable
No Acute (Immed. Health Haz.)
Yes Chronic (Delayed Health Hazard)
No Fire Hazard
No Sudden Pressure Release
No Reactivity Hazard
Section 302/(A) - Extremely Hazardous Substances

(RQ = Reportable Quantity)

(TPQ = Threshold Planning Quantity)
This product does not contain Extremely Hazardous Substances of Section

302/(A).
Component CAS # % RQ lbs. TPQ lbs.
None - - - -
Clean Water Act

Under Section 311(b)(4) of the Clean Water Act, discharges of crude oil
and petroleum products in any kind or form to surface waters must be
immediately reported to the National Response Center: 800-424-8802.
Comprehensive Environmental, Response, Compensation & Liability Act

(CERCLA) - Section 102 Hazardous Substances
Comment CAS # % RQ lbs.
NA - - -
Petroleum and petroleum fractions are excluded from the list of CERCLA
hazardous substances by Section 101(14) of CERCLA.
Federal Regulations
Reported in TSCA Inventory:

Product [ ] Yes [ ] No [X] NA
Components [X] Yes [ ] No [ ] NA
CALIFORNIA Proposition 65
Tradename: Vacuum Gas Oil
Contains components that occur on lists of:
Carcinogenic Materials [ ] Yes [X] No
Teratogenic Materials [ ] Yes [X] No
New Jersey Worker and Community Right-to-Know Act

Vacuum Distillates CAS #: 68955-27-1
10.0 Labeling
WARNING: CANCER SUSPECT AGENT

Similar products have been shown to cause cancer in laboratory animals.
Avoid prolonged or repeated skin contact with this material.
NOTE: Skin painting studies of petroleum products of similar composition

and processing have shown weak carcinogenic activity in laboratory

animals. Therefore, in the absence of good personal hygiene, there may be
potential risk of skin cancer from prolonged or repeated contact.
Occasional skin contact with this product is not expected to have serious
side effects. However, good personal hygiene should be practiced and
repeated skin contact limited to avoid the possibility of skin irritation.
Personal hygiene measures taken to prevent skin irritation are expected to
be adequate to prevent risk of cancer.
ALL STATEMENTS, INFORMATION, AND DATA PROVIDED IN THIS MATERIAL SAFETY

DATA SHEET ARE BELIEVED TO BE ACCURATE AND RELIABLE, BUT ARE PRESENTED
WITHOUT GUARANTEE, REPRESENTATION, WARRANTY, OR RESPONSIBILITY OF ANY
KIND, EXPRESSED OR IMPLIED. ANY AND ALL REPRESENTATIONS AND/OR WARRANTIES
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE ARE SPECIFICALLY
DISCLAIMED. USERS SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE
SUITABILITY OF THE INFORMATION OR PRODUCTS FOR THEIR PARTICULAR PURPOSE.
NOTHING CONTAINED HEREIN IS INTENDED AS PERMISSION, INDUCEMENT, OR
RECOMMENDATION TO VIOLATE ANY LAWS OR TO PRACTICE ANY INVENTION COVERED BY
EXISTING PATENTS, COPYRIGHTS OR INVENTIONS.

Sheet No: STI2210 Material Name: Vacuum Residue Issue Date : 17/07/2000 Revision of Sheet Dated:02/09/98 Page:
ALIGN BP SDS Finals


Material Name: Vacuum Residue
Revision of Sheet Dated:02/09/98 Major Change: Hazard?:No
________________________________________________________________________________
SAFETY DATA SHEET
Vacuum Residue
COMPANY/UNDERTAKING
Vacuum Residue
Application
Refinery stream
Britannic House
1 Finsbury Circus
London, EC2M 7BA

+44 (0) 20 7496 4411
_________________________________________________________________________________
Residues (petroleum), vacuum. EINECS No: 265-057-8, CAS No: 64741-56-6
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This product can be delivered, stored and used at temperatures above 100°C.
_________________________________________________________________________________
Eyes
Cold product - Wash eye thoroughly with copious quantities of water, ensuring eyelids are held open. Obtain medical
advice if any pain or redness develops or persists.
Hot product - Flood with water to dissipate heat. In the event of any product remaining, do not try to remove it other
than by continued irrigation with water. Obtain medical attention immediately.
Skin
Cold Product - Wash contaminated skin with soap and water. Remove contaminated clothing and wash underlying skin
as soon as reasonably practicable.
Hot Product - Flood skin with cold water to dissipate heat, cover with clean cotton or gauze, obtain medical advice
immediately.
Ingestion
Inhalation
Medical Advice
Where skin burns occur the area should be immediately immersed in cold water until the bitumen is thoroughly cooled.
Do not attempt to remove the bitumen from the skin as it provides an airtight sterile covering over the burn which will
eventually fall away with the scab as the burn heals. If for any reason the bitumen must be removed, this can be done
using a slightly warmed medicinal liquid paraffin. Kerosene and other solvents should never be used. All burns should
receive medical attention. It should be noted that bitumen contracts on cooling and where a limb is encased care
should be taken to avoid the development of a tourniquet effect.
develops.

_________________________________________________________________________________
Water may be used to cool nearby heat exposed areas/objects/packages. Avoid spraying directly into storage
containers because of the danger of boil-over.
Combustion Products
_________________________________________________________________________________
Scrape up bulk of material and remove remainder with sand or other suitable inert absorbent material.
In the case of large spills contact the appropriate authorities.
_________________________________________________________________________________

Avoid skin contact.
When product is heated to high temperatures, vapour, mists or fumes will be given off and may condense,
contaminating the skin or clothing of operatives. Prolonged or repeated contact with this condensate may give rise to
dermatitis or other skin conditions of a serious or irreversible nature.
Regular periodic self inspection of the skin is recommended, especially those areas subject to contamination. In the
event of any localised changes in appearance or texture of the skin being noticed, medical advice should be sought
without delay.
Fire Prevention
Product should not be over heated in storage because of the risk of fire.
Storage Conditions
Store under cover away from moisture and sources of ignition. Do not overheat in storage.
Under no circumstances should water be allowed to contact hot product because of the danger of boil-over. Particular

care should be taken to ensure that bulk storage tanks are watertight and that any steam heating coils are regularly
checked for leaks.
For bulk product, the storage temperature should not fluctuate above and below 100 deg C as this increases the risk of
water condensation leading to boil-over. Care must always be exercised when heating product through 100 deg C.
Highly toxic hydrogen sulphide gas may be emitted from hot product and accumulate in enclosed spaces or tanks.
Extreme care must therefore be taken during venting of tanks and enclosed spaces which have at any time contained
hot product. Under no circumstances should entry be made into small enclosures without taking full precautions.
Pyrophoric (self-heating) deposits, which may cause fire or explosion, may be formed in storage. Avoid exposure of
tank vapour space to fresh air, and maintain stable storage temperatures. Regular inspection for such deposits will
indicate when tank cleaning is necessary.
_________________________________________________________________________________

Exposure Limits
Asphalt (petroleum) fumes
ACGIH (USA): TLV 0.5 mg/m3 (8 hr TWA) benzene-soluble aerosol
A4 - Not classifiable as a human carcinogen
Hydrogen sulphide
Protective Clothing
When handling hot product, suitable protective clothing of an appropriate standard should be worn. Depending on the
type of operation this may include:
- Visor to protect the face and head covering with neck flap.
- Gauntlets (heat resistant and impervious to bitumen)
- Overalls, impervious to bitumen, covering full body and limbs with legs worn over boots.
- Protective boots.
Protective clothing should be regularly dry cleaned. Change heavily contaminated clothing as soon as reasonably
practicable; dry clean, launder and preferably starch before re-use. Wash any contaminated underlying skin with soap
and water.
_________________________________________________________________________________


Typical Values
Grades: Vacuum
Residue
Test Method Units
Colour black
Odour oily
Density @ 15°C ASTM D 1298 kg/m³ 960
Kinematic viscosity @ ASTM D 445 mm²/s 10 - 55
100°C
_________________________________________________________________________________

Products of this type are stable and unlikely to react in a hazardous manner under normal conditions of use.
This material is combustible.
Materials to Avoid

Incomplete combustion will generate smoke, carbon dioxide and hazardous gases, including carbon monoxide,
hydrogen sulphide and oxides of sulphur.
_________________________________________________________________________________
Eyes
Skin
When product is heated to high temperatures, vapour, mists or fumes will be given off and may condense,
contaminating the skin or clothing of operatives. Prolonged or repeated contact with this condensate may give rise to
dermatitis or other skin conditions of a serious or irreversible nature.
Ingestion
diarrhoea.
Inhalation
At normal ambient temperatures this product will be unlikely to present an inhalation hazard because of its low
volatility.

_________________________________________________________________________________
Mobility

This material is not biodegradable.
Aquatic toxicity
_________________________________________________________________________________
Where possible, arrange for product to be recycled.
_________________________________________________________________________________
COLD - Not classified as hazardous for transport (ADR, RID, UN, IATA/ICAO).
HOT - Conform to local requirements, if none exist recommend:-

ADR/RID: Elevated temperature liquid n.o.s., Class 9 Item 20 °(c), Hazard Identification No. 99
UN: Elevated temperature liquid n.o.s., Class 9, Packing Group III, UN No. 3257
IATA/ICAO: Forbidden for transport on passenger and cargo aircraft in molten state.
IMO: Elevated temperature liquid n.o.s., Class 9, Packing Group III
EMERGENCY ACTION CODE: 2W
Note
Under ADR emptied uncleaned tankers are classified as follows : Emptied container class 9, item 71 ADR Latest cargo
3257 Liquid elevated temperature NOS, item 20(c).
_________________________________________________________________________________
Not classified as hazardous for supply.
_________________________________________________________________________________
Compiled by:
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN

Sheet Revisions
02/09/98 1, 6, 7, 8
17/07/2000 1, 4, 8
SHEET NO: STI2210

REVISION OF SHEET DATED:02/09/98
______________________________________________________________________________

Sheet No: SUK2108 Date: 09/01/98 Revision of Sheet Dated: 01/09/94 (FLBU01) Name of Product: BP Butane
SAFETY DATA SHEET

___________________________________________________________________________
BP Butane
BP Commercial Butane, BP Butane Export Quality
Application
Multi-purpose product with applications including gaseous fuel for domestic, commercial and industrial uses; internal
combustion engine fuel; aerosol propellant; Chemical feedstock.
BP Oil UK Limited,
Witan Gate House
500-600 Witan Gate
Central Milton Keynes
MK9 1ES

0117 982 5576
__________________________________________________________________________________
Petroleum gas. A small quantity (typically up to 50 ppm) of ethyl mercaptan (stenching agent) is commonly added to assist
in leak detection. Contains <0.1% 1,3-butadiene
Hydrocarbon, C3-4-rich, petroleum distillate. EINECS No: 270-990-9, CAS No: 68512-91-4, F+, R12 Extremely
flammable (>90%)
__________________________________________________________________________________
Abuse involving wilful inhalation of very high concentrations of vapour, even for short periods, can produce
unconsciousness or might prove fatal.
__________________________________________________________________________________
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Eyes
Wash eye thoroughly with copious quantities of water. Obtain IMMEDIATE medical attention.
Skin
If cold burns are present drench with water and obtain immediate medical advice.
Keep contaminated clothes away from ignition sources.
Inhalation
If exposure to vapour, mists or fumes causes drowsiness, headache, blurred vision or irritation of the eyes, nose or throat,
remove immediately to fresh air. Keep patient warm and at rest. If any symptoms persist obtain medical advice.
Medical Advice
__________________________________________________________________________________
These materials are delivered, stored and used at temperatures above their flash point. Avoid all naked flames, sparks,
cigarettes, etc.
IN CASE OF FIRE, IMMEDIATELY ALERT THE FIRE BRIGADE.
Ensure an escape path is always available from any fire.
If gas has ignited, do not attempt to extinguish but stop gas flow and allow to burn out. Use water spray to cool heat-
exposed containers, and to protect surrounding areas and personnel effecting shut-off.
Every precaution must be taken to keep containers cool to avoid the possibility of a boiling liquid expanding vapour
explosion (BLEVE).
Pressurised containers are liable to explode violently when subjected to high temperatures.
Combustion Products
__________________________________________________________________________________
If a leak has not ignited, stop gas flow, isolate sources of ignition and evacuate personnel.
Liquid leaks generate large volumes of flammable vapour, heavier than air, which may travel to remote sources of ignition
(eg. along drainage systems).
Where appropriate, use water spray to disperse the gas or vapour and to protect personnel attempting to stop leakage.
Do not enter a vapour cloud except for rescue; self-contained breathing apparatus must be worn.
In the event of a leak, contact the appropriate authorities.
Small quantities of spilled liquid may be allowed to evaporate. Vapour should be dispersed by effective ventilation.

__________________________________________________________________________________
Storage Conditions
Do not enter storage tanks. If entry to tanks is necessary, contact the supplier.
Containers must be properly labelled.
Avoid inhalation of vapour.
Avoid contact with liquid and cold storage containers.
When handling cylinders wear protective footwear and suitable gloves.
Avoid contact with the eyes.
Fire Prevention
Ensure equipment is electrically bonded and earthed to prevent static accumulation.
Note: Product spilt on clothing may give rise to delayed evaporation and subsequent fire hazard.
__________________________________________________________________________________
Exposure Limits
Butane
Occupational Exposure Standard: Long-term exposure limit (8hr TWA) 600ppm, 1450 mg/m3
Short-term exposure limit (15 min) 750ppm, 1810mg/m3
Protective Clothing
Wear suitable gloves and overalls to prevent cold burns and frostbite.
In filling operations wear protective clothing including impervious gloves, safety goggles or face shield.
When handling cylinders wear protective footwear.
If operations are such that significant exposure to vapour, mist or fume may be anticipated, then suitable approved
respiratory equipment should be worn.
__________________________________________________________________________________
Note: National specifications may apply.
Typical Values

Grades:BP Butane UK
Test Method Units
Physical state gas
Colour colourless
Odour Distinctive when stenched
Density @ 15°C ASTM D 1657 kg/m3 580
Gauge vapour pressure 40°C BS3324 kPa <505
Vapour density rel. to air ASTM 1.9 -
D2463/D2421 2.1
Flammability Limits % 1.9 -
9.0
Flash point (PMC) ASTM D 93 °C <-50
Boiling point/range ASTM D 86 °C <-2
Materials to Avoid

Incomplete combustion will generate hazardous gases, including carbon monoxide.
__________________________________________________________________________________
Eyes
Will present a risk of serious damage to the eyes if contact with liquid occurs.
Skin
Will cause cold burns and frostbite if skin contact with liquid occurs.
Inhalation
Low vapour concentrations may cause nausea, dizziness, headaches and drowsiness.
May have a narcotic effect if high concentrations of vapour are inhaled.
High vapour concentrations may produce symptoms of oxygen deficiency which, coupled with central nervous system
depression, may lead to rapid loss of consciousness.
ABUSE:
Under normal conditions of use the product is not hazardous; however, abuse involving deliberate inhalation of very high
concentrations of vapour, even for short periods, can produce unconsciousness and/or result in a sudden fatality.
__________________________________________________________________________________
Mobility

Unlikely to cause long term adverse effects in the environment.
Aquatic toxicity
__________________________________________________________________________________
Do not dispose of any LPG container. Return all cylinders/vessels to your supplier.
Empty packages may contain some remaining product. Hazard warning labels are a guide to the safe handling of empty
packaging and should not be removed.
Empty containers represent a fire hazard as they may contain flammable product residues and vapour. Never weld, solder
or braze empty containers.
__________________________________________________________________________________
ADR/RID: Butane, Flammable gases, Class 2, Item 2°F, Hazard Identification Number 23.
UN: Butane, Flammable Gases, Class 2.1, UN Number 1011
IATA/ICAO: Butane, Flammable gas, Class 2.1. Forbidden for transport on passenger aircraft.
IMO: Butane, Flammable gas, Class 2.1.
Emergency Action Code: Flammable gas, 2WE
__________________________________________________________________________________
Extremely flammable
EU Labelling
Symbol: Flame
Indication of danger: EXTREMELY FLAMMABLE
Contains: Petroleum gas
Risk ( R ) Phrases:
R12 Extremely flammable
S3/9 Keep in a cool, well ventilated place.
S16 Keep away from sources of ignition - No smoking
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
__________________________________________________________________________________
Compiled by:


Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN

Sheet No: SUK2107 Date: 09/01/98 Revision of Sheet Dated: 01/09/94 (FLPR01) Name of Product: BP Propane
SAFETY DATA SHEET

___________________________________________________________________________
BP Propane
BP Commercial Propane, BP Premium Propane, BP Propane Export Quality
Application
Multi-purpose product with applications including gaseous fuel for domestic, commercial and industrial uses; internal
combustion engine fuel; aerosol propellant; Chemical feedstock.
BP Oil UK Limited,
Witan Gate House
500-600 Witan Gate
MK9 1ES

0117 982 5576
__________________________________________________________________________________
in leak detection. Contains <0.1% 1,3-butadiene
Hydrocarbon, C3-4-rich, petroleum distillate. EINECS No: 270-990-9, CAS No: 68512-91-4, F+, R12 Extremely
flammable (>90%)
__________________________________________________________________________________
__________________________________________________________________________________
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Eyes
Skin
Inhalation
Medical Advice
__________________________________________________________________________________
cigarettes, etc.
explosion (BLEVE).
Combustion Products
__________________________________________________________________________________

__________________________________________________________________________________
Storage Conditions
Fire Prevention
__________________________________________________________________________________
Exposure Limits
Propane
Simple asphyxiant.
Protective Clothing
__________________________________________________________________________________
Typical Values
Grades:BP Propane

Test Method Units

Physical state gas
Colour colourless
Gauge vapour pressure 40°C BS3324 kPa <1550
Vapour density rel. to air ASTM 1.5
D2463/D2421
Flammability Limits % 2.2 - 10
Boiling point/range ASTM D 86 °C <-45
Materials to Avoid

__________________________________________________________________________________
Eyes
Skin
Inhalation
ABUSE:
__________________________________________________________________________________
Mobility


Aquatic toxicity
__________________________________________________________________________________
__________________________________________________________________________________
ADR/RID: Propane, Flammable gases, Class 2, Item 2°F, Hazard Identification Number 23.
UN: Propane, Flammable Gases, Class 2.1, UN Number 1978
IATA/ICAO: Propane, Flammable gas, Class 2.1. Forbidden for transport on passenger aircraft.
IMO: Propane, Flammable gas, Class 2.1.
__________________________________________________________________________________
Extremely flammable
EU Labelling
Symbol: Flame
Contains: Petroleum gas
Risk ( R ) Phrases:
__________________________________________________________________________________
Compiled by:

Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN

Sheet No: SUK2218 Date: 20/5/98 Name of Product: Natural Gas
SAFETY DATA SHEET

___________________________________________________________________________
Natural Gas

Natural Gas
Application
Refinery stream

Coryton: +44 (0)1375 646000
Grangemouth: +44 (0)1324 483422
__________________________________________________________________________________
Natural gas, dried, EINECS No. 270-085-9, CAS No. 68410-63-9
__________________________________________________________________________________
This material contains hydrogen sulphide (H2S), an extremely toxic and highly flammable gas.
__________________________________________________________________________________
Eyes
Not hazardous under normal conditions of use. Obtain medical advice if any pain or redness develops or persists.
Inhalation
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Medical Advice
__________________________________________________________________________________
cigarettes, etc.
Combustion Products
__________________________________________________________________________________
In confined or poorly ventilated spaces the use of self-contained breathing apparatus may be necessary. See Exposure
Controls/ Personal Protection, Section 8 of this Safety Data Sheet.
Explosive air/vapour mixtures can occur, particularly in unventilated or confined spaces.
_________________________________________________________________________________
Storage Conditions

Fire Prevention
__________________________________________________________________________________
Exposure Limits
Methane / Ethane
UK publication EH40 (Occupational Exposure Standard):
Simple asphyxiant.
Hydrogen Sulphide
Respiratory protection is unnecessary, provided the concentration of vapour, mists or fumes is adequately controlled.
__________________________________________________________________________________
Typical Values
Grades:Natural Gas
Test Method Units
Physical state gas
Colour colourless
Odour odourless -> pungent
Boiling point/range °C -161.5
Vapour density rel. to air ASTM 0.6
D2463/D2421
Flash point °C -187.8
Explosion limits % 15/5.3
Solubility in water g/l Slight

Conditions to Avoid
Sources of ignition
Materials to Avoid
Avoid halogens

__________________________________________________________________________________
Eyes
Skin
Unlikely to cause harm to the skin on accidental contact.
Inhalation
__________________________________________________________________________________
Mobility
The product is volatile/gaseous and will partition to the air phase.

__________________________________________________________________________________
Note flash point if disposal by incineration is considered.
__________________________________________________________________________________
ADR/RID: Natural Gas, Compressed, Class 2, Item 1°F Hazard Identification No 23
UN: Natural Gas, Compressed, Flammable gas, Class 2.1. UN No. 1971.
IATA/ICAO: Natural gas,compressed, Flammable gas, Class 2.1.
IMO: Natural gas, compressed, Flammable gas, lighter than air. Class 2.1, Stowage category E.
EMERGENCY ACTION CODE: Flammable gas, 2SE
__________________________________________________________________________________
Extremely flammable

EU Labelling
Symbol: Flame
Risk ( R ) Phrases:
S33 Take precautionary measures against static discharges
The label must carry the following additional information: "EC Label", Substance name, EINECS No. Natural gas, dried,
EINECS No. 270-085-9, CAS No. 68410-63-9
__________________________________________________________________________________
Compiled by:
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN

Sheet No: SUK2217 Date: 19/5/98 Name of Product: Petroleum Gas
SAFETY DATA SHEET

___________________________________________________________________________
Petroleum Gas
Common refinery name: LPG

Petroleum Gas
Application
Refinery stream

Coryton: +44 (0)1375 646000
Grangemouth: +44 (0)1324 483422
__________________________________________________________________________________
in leak detection. Contains >0.1% 1,3-butadiene
Gases (petroleum), C3-4. EINECS No: 268-629-5, CAS No: 68131-75-9
Alkanes, C4-5, EINECS No: 270-654-1, CAS No: 68475-60-5
Hydrocarbons, C3-4. EINECS No: 270-681-9, CAS No: 68476-40-4
Hydrocarbons, C4-5. EINECS No: 270-682-4, CAS No: 68476-42-6
Petroleum gases, liquefied, sweetened, EINECS No. 270-705-8, CAS No. 68476-86-8
Common refinery names: Butane, Butane drag streams, propane, pentane

__________________________________________________________________________________
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Carcinogenic, category 2 ; contains 1,3 butadiene at > 0.1%.
__________________________________________________________________________________
Eyes
Skin
Inhalation
Medical Advice
__________________________________________________________________________________
cigarettes, etc.
explosion (BLEVE).
Combustion Products
__________________________________________________________________________________

__________________________________________________________________________________
Storage Conditions
Fire Prevention
__________________________________________________________________________________
Exposure Limits
Liquefied Petroleum Gas (LPG)
Propane
Simple asphyxiant.
Butane

Short-term exposure limit (15 min) 750ppm, 1810mg/m3
Protective Clothing
__________________________________________________________________________________
Typical Values
Grades:Petroleum Gas
Test Method Units
Physical state gas
Colour colourless
Density @ 15°C ASTM D 1657 kg/m3 500 - 580
Gauge vapour pressure 40°C BS3324 kPa 300 -
1550
Vapour density rel. to air ASTM 1.5 - 2.1
D2463/D2421
Flammability Limits % 1.9 - 11.1
Boiling point/range °C <-2

Materials to Avoid

__________________________________________________________________________________

Eyes
Skin
Inhalation
Contains > 0.1% 1,3-butadiene; animal studies have shown that 1,3 butadiene has a potential to cause cancer.
ABUSE:
__________________________________________________________________________________
Mobility

Aquatic toxicity
__________________________________________________________________________________
__________________________________________________________________________________
ADR/RID: Hydrocarbon gas mixture, liquefied, N.O.S. (technical name). Flammable gases, Class 2, Item 2°F,
Hazard Identification Number 23.
UN: Hydrocarbon gas mixture, liquefied, N.O.S. (technical name). Flammable Gases, Class 2.1, UN Number 1965.
IATA/ICAO: Hydrocarbon gas mixtures liquefied N.O.S. (technical name). Flammable gas, Class 2.1.
Forbidden for transport on passenger aircraft.
IMO: Hydrocarbon gas mixture, liquefied, N.O.S (technical name). Flammable gas, Class 2.1.

NOTE: More specific technical name required in brackets e.g. (butane, propane)
__________________________________________________________________________________
Extremely flammable
EU Labelling
Symbol: Flame, Skull and crossbones
Risk ( R ) Phrases:
The label must carry the following additional information: "EC Label", Substance name, EINECS No. (as appropriate)
__________________________________________________________________________________
Compiled by:
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN


file:///C|/Documents%20and%20Settings/lanewg/My%20Documents/DATA/QA%20Amendments/MSDS/Gas/Refinery%20Fuel%20Gas.htm
SAFETY DATA SHEET

___________________________________________________________________________
Refinery Fuel Gas

Refinery Fuel Gas
Application
Refinery stream

Coryton: +44 (0)1375 646000
Grangemouth: +44 (0)1324 483422
__________________________________________________________________________________
in leak detection. Contains >0.1% 1,3-butadiene
Petroleum products, refinery gases. EINECS No: 271-750-6, CAS No: 68607-11-4
__________________________________________________________________________________
Carcinogenic, category 2 ; contains 1,3 butadiene at > 0.1%.
This material contains hydrogen sulphide (H2S), an extremely toxic and highly flammable gas.
__________________________________________________________________________________
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Eyes
Not hazardous under normal conditions of use. Obtain medical advice if any pain or redness develops or persists.
Inhalation
Medical Advice
__________________________________________________________________________________
cigarettes, etc.
Combustion Products
__________________________________________________________________________________
In confined or poorly ventilated spaces the use of self-contained breathing apparatus may be necessary. See Exposure
Controls/ Personal Protection, Section 8 of this Safety Data Sheet.
Explosive air/vapour mixtures can occur, particularly in unventilated or confined spaces.
_________________________________________________________________________________
Storage Conditions

Fire Prevention
__________________________________________________________________________________
Exposure Limits
Hydrogen / Methane / Ethane / Ethylene / Propylene
Simple asphyxiant.
Propane
Simple asphyxiant.
Hydrogen Sulphide
Respiratory protection is unnecessary, provided the concentration of vapour, mists or fumes is adequately controlled.
__________________________________________________________________________________
Typical Values
Grades:Refinery Fuel Gas
Test Method Units
Physical state gas

Colour colourless
Odour pungent
Boiling point/range ASTM D 86 °C < -73
Vapour density rel. to air ASTM <1
D2463/D2421
Flash point (COC) ASTM D 92 °C < -73
Explosion limits % 75.0/4.0
Solubility in water g/l Slight
Conditions to Avoid
Sources of ignition
Materials to Avoid
Avoid halogens

__________________________________________________________________________________
Eyes
Skin
Unlikely to cause harm to the skin on accidental contact.
Inhalation
Contains > 0.1% 1,3-butadiene; animal studies have shown that 1,3 butadiene has a potential to cause cancer.
ABUSE:
__________________________________________________________________________________
Mobility

__________________________________________________________________________________


Note flash point if disposal by incineration is considered.
__________________________________________________________________________________
ADR/RID: Compressed gases, Flammable n.o.s. (Hydrogen, Methane, Ethane), Class 2, Item 1°F Hazard Identification No
23
UN: Compressed gases, Flammable n.o.s.(Hydrogen, Methane, Ethane), Class 2.1. UN No. 1954.
IATA/ICAO: Compressed gases, Flammable n.o.s.(Hydrogen, Methane, Ethane), Flammable gas, Class 2.1.
IMO: Compressed gases, Flammable n.o.s.(Hydrogen, Methane, Ethane), Flammable gas, lighter than air. Class 2.1,
EMERGENCY ACTION CODE: Flammable gas, 2SE
__________________________________________________________________________________
Extremely flammable
EU Labelling
Risk ( R ) Phrases:
The label must carry the following additional information: "EC Label", Substance name, EINECS No. (271-750-6)
__________________________________________________________________________________
Compiled by:
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN


Sheet No: STI2116 Material Name: Refinery Grade Propylene Issue Date : 17/07/2000 Revision of Sheet Dated:06/01/99 Page:
ALIGN BP SDS Finals


Material Name: Refinery Grade Propylene
Hazardous Components: Physical Characteristics: LPG Tox File: 279.38 Product Group:
________________________________________________________________________________
SAFETY DATA SHEET
Refinery Grade Propylene

COMPANY/UNDERTAKING
Refinery Grade Propylene
Application
Chemical Feedstock
Britannic House
1 Finsbury Circus
London, EC2M 7BA

+44 (0) 20 7496 4411
_________________________________________________________________________________
Petroleum gas.
Contains <0.1% 1,3-butadiene
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A complex combination of hydrocarbons produced by the distillation of products from the gas and gasoline fractions of
a catalytic cracking process. It consists predominantly of propylene with some ethane and propane.
EINECS No: 270-772-3, CAS No: 68477-90-7
_________________________________________________________________________________
Eyes
Skin
Inhalation
Medical Advice
_________________________________________________________________________________
These materials are delivered, stored and used at temperatures above their flash point. Avoid all naked flames,
sparks, cigarettes, etc.
explosion (BLEVE).
Combustion Products
_________________________________________________________________________________
Liquid leaks generate large volumes of flammable vapour, heavier than air, which may travel to remote sources of

ignition (eg. along drainage systems).

_________________________________________________________________________________

Storage Conditions
Fire Prevention
_________________________________________________________________________________

Exposure Limits
Liquefied Petroleum Gas
ACGIH (USA): TLV 1000ppm (8 hr TWA)
Propylene
ACGIH (USA):
Simple asphyxiant.
Propane
ACGIH (USA): TLV 2500ppm (8 hr TWA)
Protective Clothing

_________________________________________________________________________________

Typical Values
Grades: Refinery
Grade
Propylene
Test Method Units
Physical state liquid (gas at
ambient
pressure)
Colour colourless
Odour odourless
Vapour density rel. to ASTM 1.48
air D2463/D2421
Boiling point/range ASTM D 86 °C -48.6
Solubility in water g/l low solubility
_________________________________________________________________________________

Materials to Avoid

_________________________________________________________________________________
Eyes
Skin
Inhalation

ABUSE:
_________________________________________________________________________________
Mobility

Aquatic toxicity
_________________________________________________________________________________
Empty containers represent a fire hazard as they may contain flammable product residues and vapour. Never weld,
solder or braze empty containers.
_________________________________________________________________________________
ADR/RID: Propylene. Flammable gases, Class 2, Item 2°F, Hazard Identification Number 23.
UN: Propylene. Flammable Gases, Class 2.1, UN Number 1077
IATA/ICAO: Propylene. Flammable gas, Class 2.1. Forbidden for transport on passenger aircraft.
IMO: Propylene. Flammable gas, Class 2.1.
_________________________________________________________________________________
Extremely flammable
EU Labelling
Symbol:
Flame
EXTREMELY FLAMMABLE
Risk ( R ) Phrases:


Substance name: Gases (petroleum), depropanizer dry, propene-rich, EINECS No: 270-772-3
_________________________________________________________________________________
Compiled by:
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
Sheet Revisions
06/01/99 2, 15
17/07/2000 8, 9
SHEET NO: STI 2116

______________________________________________________________________________

Sheet No: STI2216 Material Name: Alkylate Issue Date : 17/07/2000 Revision of Sheet Dated:14/09/98 Page:
ALIGN BP SDS Finals


Material Name: Alkylate
Hazardous Components: Physical Characteristics: Gasoline Tox File: 15.7 Product Group:
________________________________________________________________________________
SAFETY DATA SHEET
Alkylate
COMPANY/UNDERTAKING
Alkylate
Alternative Names: Low boiling point modified naphtha
Application
Refinery feedstock
Britannic House
1 Finsbury Circus
London, EC2M 7BA

+44 (0) 20 7496 4411
_________________________________________________________________________________
Naphtha (petroleum), full-range alkylate. EINECS No: 265-066-7, CAS No: 64741-64-6
file:///C|/Documents%20and%20Settings/lanewg/My...Oil/Alkylate%20Issue%20Date%20%2017-07-2000.htm (1 of 8) [29/01/2002 08:50:52]

Likely to cause skin irritation.
Vapours may cause drowsiness and dizziness.
_________________________________________________________________________________
Eyes
Skin
Ingestion
Inhalation
Medical Advice
_________________________________________________________________________________

Combustion Products
_________________________________________________________________________________
etc.).

_________________________________________________________________________________

Storage Conditions

Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. Tank headspaces should always be regarded as
potentially flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling,
ullaging and sampling from storage tanks.
Electrical equipment should not be used unless it is intrinsically safe (i.e. will not produce sparks).
If product comes into contact with hot surfaces, or leaks occur from pressurised fuel pipes, the vapour or mists
generated will create a flammability or explosion hazard.
_________________________________________________________________________________

Exposure Limits
Gasoline
ACGIH (USA) : TLV 300 ppm (8hr TWA); 500 ppm (15min STEL)
A3 - Animal Carcinogen
Benzene
Protective Clothing
_________________________________________________________________________________

Typical Values

Grades: Alkylate
Test Method Units
Physical state low viscosity
liquid
Colour colourless ->
amber
Odour gasoline-like
Flash point (PMC) ASTM D 93 °C below -18
Boiling point/range °C 25 - 220
_________________________________________________________________________________

Conditions to Avoid
Sources of ignition
Avoid excessive heat.
Materials to Avoid

_________________________________________________________________________________
Eyes
Skin
Likely to result in chemical burns following prolonged wetting of the skin. (eg. after a road traffic accident).
Ingestion
diarrhoea.
Inhalation
ABUSE:
leukaemia.


_________________________________________________________________________________
Mobility

Aquatic toxicity
impaired.

_________________________________________________________________________________
Materials contaminated with product should be treated as highly flammable. Disposal should be in accordance with
local regulations.
_________________________________________________________________________________
ADR/RID: Petroleum distillates, N.O.S, Flammable liquid, Class 3, Item 2(a), Hazard Identification No. 33
ADNR/ADN: Petroleum distillates N.O.S., Class 3, Item 2(a), Hazard Identification No. 33
UN: Petroleum distillates N.O.S., Flammable liquid, Class 3, Packing group I, UN No. 1268
IATA/ICAO: Petroleum distillates N.O.S. Flammable Liquid, Class 3 , Packing group I
IMO: Petroleum distillates N.O.S., Flammable liquid, Class 3.1, Packing group I
Emergency Action Code: 3[Y]E
_________________________________________________________________________________
Extremely flammable
Harmful
Irritant
EU Labelling
Symbol:
Flame

Dead tree and fish
EXTREMELY FLAMMABLE
Risk ( R ) Phrases:
R38 Irritating to skin
R67 Vapours may cause drowsiness and dizziness.
S23 Do not breathe vapour
S29 Do not empty into drains
Substance name:Naphtha (petroleum), full-range alkylate, EINECS No: 265-066-7
_________________________________________________________________________________
Compiled by:
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
Sheet Revisions


14/09/98 1, 3, 7, 8, 10, 12, 14, 15
17/07/2000 3, 4, 9, 15
SHEET NO: STI2216

______________________________________________________________________________

Sheet No: STI2101 Material Name: Automotive Diesel Fuel Issue Date : 17/07/2000 Revision of Sheet Dated:02/11/98 Page:
ALIGN BP SDS Finals


Material Name: Automotive Diesel Fuel
________________________________________________________________________________
SAFETY DATA SHEET
Automotive Diesel Fuel

COMPANY/UNDERTAKING
Automotive Diesel Fuel
Alternative Names: Automotive diesel oil, Derv, Diesel fuel oil, Ultra low sulphur diesel
Application
Fuel for compression ignition diesel engines
Britannic House
1 Finsbury Circus
London, EC2M 7BA

+44 (0) 20 7496 4411
_________________________________________________________________________________
file:///C|/Documents%20and%20Settings/lanewg/M...esel%20Fuel%20Issue%20Date%20%2017-07-2000.htm (1 of 7) [29/01/2002 08:50:58]

(>90%)
_________________________________________________________________________________
_________________________________________________________________________________
Eyes
Skin
Ingestion
Inhalation
Medical Advice

_________________________________________________________________________________
Combustion Products
_________________________________________________________________________________
etc.).

_________________________________________________________________________________

Storage Conditions


Fire Prevention
_________________________________________________________________________________

Exposure Limits
Protective Clothing
_________________________________________________________________________________

Typical Values
Grades: Automotive
Diesel Fuel

Test Method Units

Colour amber
Odour gasoil-like
Kinematic viscosity @ ASTM D 445 mm²/s 1-6
40°C
_________________________________________________________________________________

Conditions to Avoid
Sources of ignition
Materials to Avoid

_________________________________________________________________________________
Eyes
Skin
dermatitis.
Ingestion
diarrhoea.
Inhalation
_________________________________________________________________________________
Mobility


Aquatic toxicity
impaired.

_________________________________________________________________________________
_________________________________________________________________________________
IMO: GAS OIL, Flammable liquid, Class 3, Packing group III
_________________________________________________________________________________
Harmful
EU Labelling
Symbol:
St. Andrew's Cross
HARMFUL
Contains:
Fuels, Diesel
Risk ( R ) Phrases:


_________________________________________________________________________________
Compiled by:
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
Sheet Revisions
07/05/98 1, 2, 12, 15
02/11/98 1
17/07/2000 2, 3, 4, 9, 12, 15
SHEET NO: STI2101

______________________________________________________________________________

Sheet No: SAV2106 Material Name: AVCAT Issue Date : 02/11/2000 Revision of Sheet Dated:19/11/99 Page
ALIGN BP SDS Finals

GLIS Sheet No:SAV2106 SDS Reference:

Material Name: AVCAT
Language:English Country:OAV
Hazardous Components: Physical Characteristics: Basic Physical Characteristics Template Tox File: 458.16
Product Group:
________________________________________________________________________________
SAFETY DATA SHEET
AVCAT
COMPANY/UNDERTAKING
AVCAT
Alternative Names: (Synonyms F-44, AVCAT/FSII, JP5)
Application
Jet fuel
do not use for other purposes
Air BP International
Breakspear Park
Breakspear Way
Hemel Hempstead
Hertfordshire
HP2 4UL

+44 (0) 1442 22 5711
file:///C|/Documents%20and%20Settings/lanewg/M...20Oil/AVCAT%20Issue%20Date%20%2002-11-2000.htm (1 of 8) [29/01/2002 08:51:04]

Out of office hours:

+44 (0) 1202 590558
_________________________________________________________________________________
A mixture of kerosene streams
May contain small quantities of proprietary performance additives.
Kerosine - unspecified
Xn R38 Irritating to skin
(>90%)
_________________________________________________________________________________
_________________________________________________________________________________
Eyes
Wash eye thoroughly with copious quantities of water
ensuring eyelids are held open. Obtain medical advice if any pain or redness develops or persists.
Skin
Ingestion
If contamination of the mouth occurs
wash out thoroughly with water.
Except as a deliberate act
the ingestion of large amounts of product is unlikely. If it should occur
do not induce vomiting
Inhalation
If fumes are inhaled the patient should be removed to fresh air and if recovery is not immediate
medical assistance must be called without delay. If breathing has failed respiration must be assisted
preferably by mouth to mouth method.
Medical Advice
Product can be aspirated on swallowing or following regurgitation of stomach contents
and can cause severe and potentially fatal chemical pneumonitis
which will require urgent treatment. Because of the risk of aspiration
induction of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after
endotracheal intubation. Monitor for cardiac dysrhythmias.
_________________________________________________________________________________

Use foam
dry powder or water fog. DO NOT USE water jets.
Combustion Products
See Stability and Reactivity
Section 10 of this Safety Data Sheet.
_________________________________________________________________________________
In the event of spillage
remove all sources of ignition and ensure good ventilation.
Wear protective clothing. See Exposure Controls/Personal Protection
section 8
of this Safety Data Sheet.
Vapour is heavier than air and may travel to remote sources of ignition (eg. along drainage systems
in basements etc.).
If spillage has occurred in a confined space
ensure adequate ventilation and check that a safe
breathable atmosphere is present before entry.
In the case of spillage on water
prevent the spread of product by the use of suitable barrier equipment. Recover product from the surface. Protect
environmentally sensitive areas and water supplies.
_________________________________________________________________________________

Storage Conditions
the safe handling
storage and disposal of empty packaging.

Avoid
as far as reasonably practicable
inhalation of vapour
mists or fumes generated during use.
Whilst using do not eat
drink or smoke.
Fire Prevention
flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling
When the product is pumped (e.g. during filling
discharge or ullaging) and when sampling
there is a risk of static discharge. Ensure equipment used is properly earthed or bonded to the tank structure.
Product contaminated rags
paper or material used to absorb spillages
represent a fire hazard
and should not be allowed to accumulate. Dispose of safely immediately after use.
cut
weld
_________________________________________________________________________________

Exposure Limits
If vapour
mists or fumes are generated
their concentration in the workplace air should be controlled to the lowest reasonably practicable level.
Protective Clothing
If skin contact is likely
wear impervious protective clothing and/or gloves.
Protective clothing should be regularly inspected and maintained

overalls should be dry-cleaned

laundered and preferably starched after use.
If operations are such that exposure to vapour
mist or fume may be anticipated
then suitable approved respiratory equipment should be worn.
_________________________________________________________________________________

Typical Values
Grades: AVCAT
Test Method Units
liquid
Colour colourless
Odour kerosine-like
Boiling point/range ASTM D 86 °C 300 max
Solubility in water g/l low solubility
_________________________________________________________________________________

Conditions to Avoid
Sources of ignition
Materials to Avoid

Incomplete combustion will generate smoke
carbon dioxide and hazardous gases
including carbon monoxide.
_________________________________________________________________________________
Eyes
May be irritating to eyes at high concentrations of vapour
mists or fumes.

Skin
Ingestion
Unlikely to cause harm if accidentally swallowed in small doses
though larger quantities may cause nausea and diarrhoea.
Will injure the lungs if aspiration occurs
eg. during vomiting.
Inhalation
May cause irritation to eyes
nose and throat due to exposure to vapour
mists or fumes.
_________________________________________________________________________________
Mobility

Aquatic toxicity
Toxic to aquatic organisms.
May cause long term effects in the aquatic environment
impaired.
_________________________________________________________________________________
Dispose of product and container carefully and responsibly. Do not dispose of near ponds
ditches
down drains or onto soil.
At sea
used or unwanted product should be stored for eventual discharge into port approved waste oil disposal facilities.
_________________________________________________________________________________
ADR/RID: Kerosene
Flammable Liquid
Class 3
Item 31 (c)
Hazard Identification No 30
UN: KEROSENE
Flammable liquid
Class 3
Packing Group III
UN Number 1223

IATA/ICAO: Kerosene
Flammable liquid
Class 3
Packing Group III
IMO: KEROSENE
Flammable liquid
Class 3.3
Packing Group III
EMERGENCY ACTION CODE: Flammable liquid
3[Y]
_________________________________________________________________________________
Harmful
Irritant
EU Labelling
Symbol: St. Andrew's Cross
Indication of danger: HARMFUL (Xn)
Contains:
Risk ( R ) Phrases:
S43 - In case of fire use foam or dry powder. Never use water jets
S62 If swallowed
do not induce vomiting: seek medical advice immediately and show this container or label.
_________________________________________________________________________________
Compiled by:
Chertsey Road
Sunbury-on-Thames
Middlesex
TW16 7LN
This data sheet and the health

safety and environmental information it contains is considered to be accurate as of the date specified below. We have
reviewed any information contained herein which we received from sources outside the BP Amoco Group of
Companies. However
no warranty or representation
express or implied is made as to the accuracy or completeness of the data and information contained in this data
sheet.

laws and regulations. No statement made in this data sheet shall be construed as a permission
recommendation or authorization given or implied to practise any patented invention without a valid licence. The BP
Amoco Group shall not be responsible for any damage or injury resulting from abnormal use of the material
from any failure to adhere to recommendations
or from any hazards inherent in the nature of the material.
______________________________________________________________________________

Sheet No: SAV2104 Material Name: Avgas 100/130 (>0.1% Lead) Issue Date : 19/06/2000 Revision of Sheet Dated:30/03/98 Page
ALIGN BP SDS Finals


Material Name: Avgas 100/130 (>0.1% Lead)
________________________________________________________________________________
SAFETY DATA SHEET
Avgas 100/130 (>0.1% Lead)

COMPANY/UNDERTAKING
Avgas 100/130 (>0.1% Lead)
Application
Use only as a motor fuel for aviation. Should NOT be used as a solvent nor cleaning agent.
Breakspear Park
Breakspear Way
Hemel Hempstead
Hertfordshire
HP2 4UL

+44 (0) 1442 22 5711

+44 (0) 1202 590558
_________________________________________________________________________________
file:///C|/Documents%20and%20Settings/lanewg/...1%%20Lead)%20Issue%20Date%20%2019-06-2000.htm (1 of 10) [29/01/2002 08:51:08]

A complex mixture of volatile hydrocarbons containing paraffins
naphthenes
olefins and aromatics with carbon numbers predominantly between C4 and C12.
May contain oxygenates. May also contain small quantities of proprietary performance additives.
Contains lead compounds.
Lead alkyls
T+
N
R61 May cause harm to the unborn child.
R62 Possible risk of impaired fertility
R26/27/28 Very toxic by inhalation
in contact with skin and if swallowed
R33 Danger of cumulative effects
R50/53 Very toxic to aquatic organisms
may cause long-term adverse effects in the aquatic environment
(>0.1 - <0.5% Pb)
Benzene
EINECS No. 200-753-7
CAS No. 71-43-2 F
T
R11 Highly flammable
R48/23/24/25 Toxic: Danger of serious damage to health by prolonged exposure through inhalation
Gasoline
EINECS No: 289-220-8
CAS No: 86290-81-5 F+
T
N
R65 Harmful: may cause lung damage if swallowed
R67 Vapours may cause drowsiness and dizziness
R51/53 Toxic to aquatic organisms
(>90%)
_________________________________________________________________________________
May cause cancer
classified as a category 2 carcinogen.
Contains Benzene. Prolonged or repeated exposure to benzene can cause anaemia and other blood diseases

Toxic by inhalation
in contact with skin and if swallowed.
Danger of cumulative effects
May cause harm to the unborn child
_________________________________________________________________________________
Eyes
Skin
In extreme situations of saturation with this product
drench with water
remove clothing as soon as possible and wash skin with soap and water. Seek medical advice if skin becomes red
swollen or painful.
Ingestion
Inhalation
If exposure to vapour
mists or fumes causes drowsiness
headache
blurred vision or irritation of the eyes
nose or throat
Medical Advice
_________________________________________________________________________________

Use foam
dry powder or water fog. DO NOT use water jets.
Combustion Products
_________________________________________________________________________________
in basements etc.).

section 8
_________________________________________________________________________________

Storage Conditions
the safe handling

Special health precautions must be taken during cleaning or maintenance operations on storage tanks which may
have contained leaded product at any time.
Ensure good ventilation and avoid as far as reasonably practicable the inhalation and contact with vapours
mists or fumes which may be generated during use. If such vapour
Fire Prevention
potentially flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling
If product comes into contact with hot surfaces
or leaks occur from pressurised fuel pipes
the vapour or mists generated will create a flammability or explosion hazard.
cut
weld
_________________________________________________________________________________

Exposure Limits
If vapour
Comply with current local occupational exposure limit. Where not established
the following limits are recommended.
Gasoline
ACGIH (USA) : TLV 300 ppm (8hr TWA)
500 ppm (15min STEL)

Benzene
ACGIH (USA): TLV 0.5ppm (8hr TWA)
2.5 ppm (15min STEL)
Protective Clothing
_________________________________________________________________________________

Typical Values
Grades: Avgas
100/130
(>0.1% Lead)
Test Method Units
Colour green
Odour gasoline-like
Kinematic viscosity @ mm²/s 1
20°C
Flash point (PMC) ASTM D 93 °C -40
_________________________________________________________________________________

Conditions to Avoid
Conditions to Avoid
Sources of ignition

Materials to Avoid

_________________________________________________________________________________
Eyes
Skin
Toxic in contact with skin - contains lead.
Ingestion
Toxic if swallowed - contains lead.
Inhalation
Toxic by inhalation - contains lead
May cause nausea
dizziness
headaches and drowsiness if high concentrations of vapour are inhaled.
ABUSE:
Under normal conditions of use the product is not hazardous
however
abuse involving deliberate inhalation of very high concentrations of vapour
even for short periods
can produce unconsciousness and/or result in a sudden fatality.
leukaemia.
Lead is a cumulative poison. It can cause anaemia
central nervous system effects
gastro-intestinal symptoms and kidney damage.
_________________________________________________________________________________
Mobility

Aquatic toxicity
Toxic to aquatic organisms
impaired.
_________________________________________________________________________________
Empty containers represent a fire hazard as they may contain flammable product residues and vapour. Never weld
local regulations.
When cleaning storage tanks
sludges which may be contaminated with lead must be disposed of via a licensed waste disposal contractor
in accordance with local regulations.
_________________________________________________________________________________
ADR/RID: Motor spirit
Flammable liquid
Class 3
Item 3(b)
ADNR/ADN: Motor Spirit
Class 3
Item 3(b)
UN: MOTOR SPIRIT
Flammable liquid
Class 3. Packing Group II
UN Number 1203
IATA/ICAO: Motor spirit
Flammable liquid
Class 3
Packing group II
IMO: MOTOR SPIRIT
Flammable liquid
Class 3.1
Packing group II
MARINE POLLUTANT (Leaded Petrol)
3[Y]E
_________________________________________________________________________________

Extremely flammable
Toxic to reproduction category 3
Toxic
Irritant
Harmful
EU Labelling
Symbol:
Flame
EXTREMELY FLAMMABLE
TOXIC
Contains:
Low boiling point naphtha - unspecified
Lead alkyls
Risk ( R ) Phrases:
R23/24/25 Also Toxic by inhalation
in contact with skin
and if swallowed
R33 Danger of cumulative effects.
S45 In case of accident or if you feel unwell
seek medical advice immediately (show label where possible)
S43 In case of fire
use foam/dry powder/CO2. Never use water jets.
S62 If swallowed
_________________________________________________________________________________
Compiled by:


Chertsey Road
Sunbury-on-Thames
Middlesex
TW16 7LN

Companies. However
sheet.
Sheet Revisions
07/04/97 1
2
3
8
12
15
19/06/2000 1
2
3
4
7
8
10
12
15
SHEET NO: SAV2104
______________________________________________________________________________
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Sheet No: SAV2103A Material Name: Avgas 100LL (>0.1% benzene) Issue Date : 19/06/2000 Revision of Sheet Dated:11/03/98 Page
ALIGN BP SDS Finals

GLIS Sheet No:SAV2103A SDS Reference:

Material Name: Avgas 100LL (>0.1% benzene)
________________________________________________________________________________
SAFETY DATA SHEET
Avgas 100LL (>0.1% benzene)

COMPANY/UNDERTAKING
Avgas 100LL (>0.1% benzene)
Application
Breakspear Park
Breakspear Way
Hemel Hempstead
Hertfordshire
HP2 4UL

+44 (0) 1442 22 5711

+44 (0) 1202 590558
_________________________________________________________________________________
file:///C|/Documents%20and%20Settings/lanewg/...20benzene)%20Issue%20Date%20%2019-06-2000.htm (1 of 10) [29/01/2002 08:51:12]

naphthenes
Lead alkyls
T+
N
(0.05 - <0.1% Pb)
Benzene
CAS No. 71-43-2 F
T
Gasoline
CAS No: 86290-81-5 F+
T
N
(>90%)
_________________________________________________________________________________
May cause cancer

Harmful by inhalation
_________________________________________________________________________________
Eyes
Skin
drench with water
swollen or painful.
Ingestion
Inhalation
headache
nose or throat
Medical Advice
_________________________________________________________________________________


Use foam
Combustion Products
_________________________________________________________________________________
in basements etc.).

section 8
_________________________________________________________________________________

Storage Conditions
the safe handling


Fire Prevention
cut
weld
_________________________________________________________________________________

Exposure Limits
If vapour
Gasoline
Benzene


Protective Clothing
_________________________________________________________________________________

Typical Values
Grades: Avgas 100LL
Test Method Units
Colour blue
Odour gasoline-like
20°C
_________________________________________________________________________________

Conditions to Avoid
Conditions to Avoid
Sources of ignition
Materials to Avoid


_________________________________________________________________________________
Eyes
Skin
Harmful in contact with skin - contains lead.
Ingestion
Harmful if swallowed - contains lead.
Inhalation
Harmful by inhalation - contains lead
May cause nausea
dizziness
ABUSE:
however
leukaemia.
_________________________________________________________________________________
Mobility


Aquatic toxicity
impaired.
_________________________________________________________________________________
local regulations.
_________________________________________________________________________________
Flammable liquid
Class 3
Item 3(b)
Class 3
Item 3(b)
UN: MOTOR SPIRIT
Flammable liquid
UN Number 1203
Flammable liquid
Class 3
Packing group II
IMO: MOTOR SPIRIT
Flammable liquid
Class 3.1
Packing group II
3[Y]E
_________________________________________________________________________________
Extremely flammable
Irritant
Harmful

EU Labelling
Symbol:
Flame
EXTREMELY FLAMMABLE
Contains:
Lead alkyls
Risk ( R ) Phrases:
R20/21/22 Also Harmful by inhalation
in contact with the skin and if swallowed.
S43 In case of fire
S62 If swallowed
_________________________________________________________________________________
Compiled by:
Chertsey Road
Sunbury-on-Thames
Middlesex
TW16 7LN


Companies. However
sheet.
Sheet Revisions
11/11/97 1
2
3
8
12
15
19/06/2000 1
2
3
4
7
8
10
15
SHEET NO: SAV2103A
______________________________________________________________________________

Sheet No: SAV2103 Material Name: Avgas 100LL (low benzene) Issue Date : 19/06/2000 Revision of Sheet Dated:11/03/98 Page
ALIGN BP SDS Finals


Material Name: Avgas 100LL (low benzene)
________________________________________________________________________________
SAFETY DATA SHEET
Avgas 100LL (low benzene)

COMPANY/UNDERTAKING
Avgas 100LL (low benzene)
Alternative Names: Aviation gasoline low lead
Application
Breakspear Park
Breakspear Way
Hemel Hempstead
Hertfordshire
HP2 4UL

+44 (0) 1442 22 5711

+44 (0) 1202 590558

_________________________________________________________________________________
naphthenes
Lead alkyls
T+
N
(0.05 - <0.1% Pb)
Gasoline
CAS No: 86290-81-5 F+
Xn
N
(>90%)
_________________________________________________________________________________
Harmful by inhalation
_________________________________________________________________________________
Eyes

Skin
drench with water
swollen or painful.
Ingestion
Inhalation
headache
nose or throat
Medical Advice
_________________________________________________________________________________
Use foam
Combustion Products
_________________________________________________________________________________

in basements etc.).

section 8
_________________________________________________________________________________

Storage Conditions
the safe handling


Fire Prevention
cut
weld
_________________________________________________________________________________

Exposure Limits
If vapour
Gasoline
Protective Clothing

_________________________________________________________________________________

Typical Values
Grades: Avgas 100LL
(low benzene)
Test Method Units
Colour blue
Odour gasoline-like
20°C
_________________________________________________________________________________

Conditions to Avoid
Sources of ignition
Materials to Avoid

_________________________________________________________________________________
Eyes
Skin
Ingestion

Inhalation
May cause nausea
dizziness
ABUSE:
however

_________________________________________________________________________________
Mobility

Aquatic toxicity
impaired.
_________________________________________________________________________________
local regulations.
_________________________________________________________________________________
Flammable liquid
Class 3

Item 3(b)
Class 3
Item 3(b)
UN: MOTOR SPIRIT
Flammable liquid
UN Number 1203
Flammable liquid
Class 3
Packing group II
IMO: MOTOR SPIRIT
Flammable liquid
Class 3.1
Packing group II
3[Y]E
_________________________________________________________________________________
Extremely flammable
Irritant
Harmful
EU Labelling
Symbol:
Flame
St. Andrew's Cross
EXTREMELY FLAMMABLE
HARMFUL
Contains:
Lead alkyls
Risk ( R ) Phrases:
R20/21/22 Harmful by inhalation
in contact with the skin and if swallowed.
S43 In case of fire


S62 If swallowed
_________________________________________________________________________________
Compiled by:
Chertsey Road
Sunbury-on-Thames
Middlesex
TW16 7LN

Companies. However
sheet.
Sheet Revisions
03/09/96 2
3
8
12
14
15
19/06/2000 1
2
3
4
7
8
12
15
SHEET NO: SAV2103

______________________________________________________________________________

Sheet No: STI2115 Material Name: Aviation Gasoline (High Lead) Issue Date : 17/07/2000 Revision of Sheet Dated:02/11/98 Page:
ALIGN BP SDS Finals


Material Name: Aviation Gasoline (High Lead)
________________________________________________________________________________
SAFETY DATA SHEET
Aviation Gasoline (High Lead)

COMPANY/UNDERTAKING
Aviation Gasoline (High Lead)
Alternative Names: Avgas 100/130
Application
Britannic House
1 Finsbury Circus
London, EC2M 7BA

+44 (0) 20 7496 4411
_________________________________________________________________________________
A complex mixture of volatile hydrocarbons containing paraffins, naphthenes, olefins and aromatics with carbon
file:///C|/Documents%20and%20Settings/lanewg/M...igh%20Lead)%20Issue%20Date%20%2017-07-2000.htm (1 of 8) [29/01/2002 08:51:24]

numbers predominantly between C4 and C12.

Lead alkyls, T+, N, R61 May cause harm to the unborn child., R62 Possible risk of impaired fertility, R26/27/28 Very
toxic by inhalation, in contact with skin and if swallowed, R33 Danger of cumulative effects, R50/53 Very toxic to
aquatic organisms, may cause long-term adverse effects in the aquatic environment
(>0.1 - <0.5% Pb)
Benzene, EINECS No. 200-753-7, CAS No. 71-43-2 F, T, R45 May cause cancer, R11 Highly flammable,
R48/23/24/25 Toxic: Danger of serious damage to health by prolonged exposure through inhalation, in contact with
skin and if swallowed
Gasoline, EINECS No: 289-220-8, CAS No: 86290-81-5 F+,T, N, R12 Extremely flammable, R45 May cause cancer,
R65 Harmful: may cause lung damage if swallowed, R38 Irritating to skin, R67 Vapours may cause drowsiness and
dizziness, R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment,
(>90%)
_________________________________________________________________________________
Toxic by inhalation, in contact with skin and if swallowed.
_________________________________________________________________________________
Eyes
Skin
Ingestion

Inhalation
Medical Advice
_________________________________________________________________________________
Use foam, dry powder or water fog. DO NOT use water jets.
Combustion Products
_________________________________________________________________________________
etc.).

_________________________________________________________________________________


Storage Conditions
Fire Prevention
_________________________________________________________________________________

Exposure Limits
Gasoline

Benzene
Protective Clothing
_________________________________________________________________________________

Typical Values
Grades: Aviation
Gasoline
(High Lead)
Test Method Units
Colour green
Odour gasoline-like
20°C
_________________________________________________________________________________

Conditions to Avoid
Conditions to Avoid
Sources of ignition
Materials to Avoid


_________________________________________________________________________________
Eyes
Skin
Ingestion
Inhalation
ABUSE:
leukaemia.
Lead is a cumulative poison. It can cause anaemia, central nervous system effects, gastro-intestinal symptoms and
kidney damage.
_________________________________________________________________________________
Mobility

Aquatic toxicity
impaired.
_________________________________________________________________________________

local regulations.
When cleaning storage tanks, sludges which may be contaminated with lead must be disposed of via a licensed waste
disposal contractor, in accordance with local regulations.
_________________________________________________________________________________
ADR/RID: Motor spirit, Flammable liquid, Class 3, Item 3(b), Hazard Identification No 33
ADNR/ADN: Motor Spirit, Class 3, Item 3(b)
UN: MOTOR SPIRIT, Flammable liquid, Class 3. Packing Group II, UN Number 1203
IATA/ICAO: Motor spirit, Flammable liquid, Class 3, Packing group II
IMO: MOTOR SPIRIT, Flammable liquid, Class 3.1, Packing group II, MARINE POLLUTANT (Leaded Petrol)
EMERGENCY ACTION CODE: Flammable liquid, 3[Y]E
_________________________________________________________________________________
Extremely flammable
Toxic
Irritant
Harmful
EU Labelling
Symbol:
Flame
EXTREMELY FLAMMABLE
TOXIC
Contains:
Lead alkyls
Risk ( R ) Phrases:
R23/24/25 Also Toxic by inhalation, in contact with skin, and if swallowed

_________________________________________________________________________________
Compiled by:
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
Sheet Revisions
02/11/98 1
17/07/2000 2, 3, 4, 8, 15
SHEET NO: STI2115

______________________________________________________________________________

Sheet No: STI2114 Material Name: Aviation Gasoline (Low Lead) Issue Date : 17/07/2000 Revision of Sheet Dated:02/11/98 Page:
ALIGN BP SDS Finals


Material Name: Aviation Gasoline (Low Lead)
________________________________________________________________________________
SAFETY DATA SHEET
Aviation Gasoline (Low Lead)

COMPANY/UNDERTAKING
Aviation Gasoline (Low Lead)
Alternative Names: Avgas 100LL, Aviation Gasoline
Application
Britannic House
1 Finsbury Circus
London, EC2M 7BA

+44 (0) 20 7496 4411
_________________________________________________________________________________
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Lead alkyls, T+, N, R61 May cause harm to the unborn child., R62 Possible risk of impaired fertility, R26/27/28 Very
toxic by inhalation, in contact with skin and if swallowed, R33 Danger of cumulative effects, R50/53 Very toxic to
aquatic organisms, may cause long-term adverse effects in the aquatic environment
(0.05 - <0.1% Pb)
(>90%)
_________________________________________________________________________________
Harmful by inhalation, in contact with skin and if swallowed.
_________________________________________________________________________________
Eyes
Skin
Ingestion
Inhalation

Medical Advice
_________________________________________________________________________________
Combustion Products
_________________________________________________________________________________
etc.).

_________________________________________________________________________________

Storage Conditions
Fire Prevention
_________________________________________________________________________________

Exposure Limits
Gasoline
Benzene


Protective Clothing
_________________________________________________________________________________

Typical Values
Grades: Aviation
Gasoline
(Low Lead)
Test Method Units
Colour blue
Odour gasoline-like
20°C
_________________________________________________________________________________

Conditions to Avoid
Conditions to Avoid
Sources of ignition
Materials to Avoid


_________________________________________________________________________________
Eyes
Skin
Ingestion
Inhalation
ABUSE:
leukaemia.
Lead is a cumulative poison. It can cause anaemia, central nervous system effects, gastro-intestinal symptoms and
kidney damage.
_________________________________________________________________________________
Mobility

Aquatic toxicity
impaired.
_________________________________________________________________________________


local regulations.
_________________________________________________________________________________
_________________________________________________________________________________
Extremely flammable
Irritant
Harmful
EU Labelling
Symbol:
Flame
EXTREMELY FLAMMABLE
Contains:
Lead alkyls
Risk ( R ) Phrases:
R20/21/22 Also Harmful by inhalation, in contact with the skin and if swallowed.

_________________________________________________________________________________
Compiled by:
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
Sheet Revisions
02/11/98 1
17/07/2000 2, 3, 4, 7, 15
SHEET NO: STI2114

______________________________________________________________________________

Sheet No: STI2111 Material Name: Aviation Turbine Fuel Issue Date : 17/07/2000 Revision of Sheet Dated:02/11/98 Page:
ALIGN BP SDS Finals


Material Name: Aviation Turbine Fuel
________________________________________________________________________________
SAFETY DATA SHEET
Aviation Turbine Fuel

COMPANY/UNDERTAKING
Aviation Turbine Fuel
Alternative Names: AVTUR, JP-8, Jet A, Jet A-1 & Jet Kerosine
Application
Jet fuel, do not use for other purposes
Britannic House
1 Finsbury Circus
London, EC2M 7BA

+44 (0) 20 7496 4411
_________________________________________________________________________________
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Kerosine - unspecified, Xn R10 Flammable, R38 Irritating to skin, R65 Harmful: may cause lung damage if swallowed.
_________________________________________________________________________________
Flammable
_________________________________________________________________________________
Eyes
Skin
Ingestion
Inhalation
If fumes are inhaled the patient should be removed to fresh air and if recovery is not immediate, medical assistance
must be called without delay. If breathing has failed respiration must be assisted, preferably by mouth to mouth
method.
Medical Advice
_________________________________________________________________________________
Combustion Products
_________________________________________________________________________________


etc.).
_________________________________________________________________________________

Storage Conditions
Fire Prevention

_________________________________________________________________________________

Exposure Limits
Protective Clothing
_________________________________________________________________________________

Typical Values
Grades: Aviation
Turbine Fuel
Test Method Units
yellow
Odour kerosine-like
Kinematic viscosity @ ASTM D 445 mm²/s 3.5
20°C
_________________________________________________________________________________


Conditions to Avoid
Sources of ignition
Materials to Avoid

_________________________________________________________________________________
Eyes
May be irritating to eyes at high concentrations of vapour, mists or fumes.
Skin
Ingestion
diarrhoea.
Inhalation
_________________________________________________________________________________
Mobility

Aquatic toxicity
impaired.
_________________________________________________________________________________
Dispose of product and container carefully and responsibly. Do not dispose of near ponds, ditches, down drains or

onto soil.
facilities.
_________________________________________________________________________________
ADR/RID: Kerosene, Flammable Liquid, Class 3 , Item 31 (c), Hazard Identification No 30
UN: KEROSENE, Flammable liquid, Class 3, Packing Group III, UN Number 1223
IATA/ICAO: Kerosene, Flammable liquid, Class 3, Packing Group III
IMO: KEROSENE, Flammable liquid, Class 3.3, Packing Group III
EMERGENCY ACTION CODE: Flammable liquid, 3[Y]
_________________________________________________________________________________
Flammable
Harmful
Irritant
EU Labelling
Symbol:
St. Andrew's Cross
HARMFUL
Contains:
Risk ( R ) Phrases:
R10 Flammable
_________________________________________________________________________________
Compiled by:
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN

Sheet Revisions
11/05/98 2, 4, 12, 15
02/11/98 1
17/07/2000 2, 9, 15
SHEET NO: STI2111

______________________________________________________________________________

Sheet No: SAV2107 Material Name: Avtag Issue Date : 19/06/2000 Revision of Sheet Dated:03/11/98 Page
ALIGN BP SDS Finals


Material Name: Avtag
________________________________________________________________________________
SAFETY DATA SHEET
Avtag
COMPANY/UNDERTAKING
Avtag
Application
Wide cut aviation turbine fuel.
Breakspear Park
Breakspear Way
Hemel Hempstead
Hertfordshire
HP2 4UL

+44 (0) 1442 22 5711

+44 (0) 1202 590558
_________________________________________________________________________________
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A complex combination of volatile hydrocarbons consisting primarily of paraffins
cycloparaffins
aromatic and olefinic hydrocarbons having carbon numbers predominantly in the range C5 through C14 and boiling in
the range 20°C to 270°C.
Xn R10 Flammable
(<95%)

F+
T
N
may cause long-term adverse effects in the aquatic environment.
(<95%)
_________________________________________________________________________________
May cause cancer
_________________________________________________________________________________
Eyes
Skin
drench with water

swollen or painful.
Ingestion
Inhalation
headache
nose or throat
Medical Advice
_________________________________________________________________________________
Use foam
Combustion Products
_________________________________________________________________________________
in basements etc.).


section 8
_________________________________________________________________________________

Storage Conditions
the safe handling
Fire Prevention


cut
weld
_________________________________________________________________________________

Exposure Limits
If vapour
Gasoline
Benzene
Protective Clothing
_________________________________________________________________________________


Typical Values
Grades: Avtag
Test Method Units
Colour colourless
Odour gasoline-like
Freezing Point @ °C -58
_________________________________________________________________________________

Conditions to Avoid
Sources of ignition
Materials to Avoid

_________________________________________________________________________________
Eyes
Skin
Ingestion
Inhalation
May cause nausea

dizziness
ABUSE:
however
leukaemia.
_________________________________________________________________________________
Mobility

Aquatic toxicity
impaired.
_________________________________________________________________________________
local regulations.
_________________________________________________________________________________
ADR/RID: Petroleum distillates
n.o.s.
Flammable liquid
Class 3
Item 3(b)
Hazard Identification No. 33
UN: Petroleum distillates N.O.S.
Flammable liquid
Class 3

Packing group 1
UN No. 1268
IATA/ICAO: Petroleum Distillates N.O.S. Flammable Liquid
Class 3
Packing group 1
IMO: Petroleum Distillates N.O.S.
Flammable liquid
Class 3.1
Packing group 1
_________________________________________________________________________________
Extremely flammable
Harmful
Irritant
EU Labelling
Symbol:
Flame
EXTREMELY FLAMMABLE
Contains:
Risk ( R ) Phrases:
S43 In case of fire
S62 If swallowed

_________________________________________________________________________________
Compiled by:
Chertsey Road
Sunbury-on-Thames
Middlesex
TW16 7LN

Companies. However
sheet.
Sheet Revisions
19/06/2000 1
2
3
4
7
8
10
15
SHEET NO: SAV2107
______________________________________________________________________________

Sheet No: SAV2108 Material Name: Bolivian Avgas 100 Issue Date : 14/05/2001 Revision of Sheet Dated: Page
ALIGN BP SDS Finals


Material Name: Bolivian Avgas 100
Revision of Sheet Dated: Major Change: Hazard?:Yes
________________________________________________________________________________
SAFETY DATA SHEET
Bolivian Avgas 100

COMPANY/UNDERTAKING
Bolivian Avgas 100
Application
Breakspear Park
Breakspear Way
Hemel Hempstead
Hertfordshire
HP2 4UL

+44 (0) 1442-22-5711

+44 (0) 1202 590558
_________________________________________________________________________________
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naphthenes
Lead alkyls
T+
N
(>0.1 - <0.5% Pb)
Benzene
CAS No. 71-43-2 F
T
(~ 5%)
Toluene
CAS No. 108-88-3
F
Xn
R11 Highly Flammable
R20 Harmful by inhalation
(~ 20%)
Gasoline
CAS No: 86290-81-5 F+
T
N
(>90%)

_________________________________________________________________________________
May cause cancer
Toxic by inhalation
_________________________________________________________________________________
Eyes
Skin
drench with water
swollen or painful.
Ingestion
Inhalation
headache
nose or throat
Medical Advice


_________________________________________________________________________________
Use foam
Combustion Products
_________________________________________________________________________________
in basements etc.).

section 8
_________________________________________________________________________________

Storage Conditions

the safe handling
drink or smoke.
Fire Prevention
cut
weld
_________________________________________________________________________________

Exposure Limits
If vapour


Gasoline
Benzene
Toluene
ACGIH (USA): TLV 50 ppm (8 hr TWA)
A4 - Not Classifiable as a Human Carcinogen
Protective Clothing
_________________________________________________________________________________

Typical Values
Grades: Bolivian
Avgas 100
Test Method Units
Colour green
Odour gasoline
like

Vapour pressure @ ASTM D 323 kPa 37 - 48

37.8°C (100°F)
Vapour density rel. to ASTM 3-4
air D2463/D2421
Flash point (COC) ASTM D 92 °C <-40
Boiling point/range ASTM D 86 °C 170 max
_________________________________________________________________________________

Conditions to Avoid
Conditions to Avoid
Sources of ignition
Materials to Avoid

_________________________________________________________________________________
Eyes
Skin
Ingestion
Inhalation
May cause nausea
dizziness
ABUSE:
however


leukaemia.
_________________________________________________________________________________
Mobility

Aquatic toxicity
impaired.
_________________________________________________________________________________
local regulations.
_________________________________________________________________________________
Flammable liquid
Class 3
Item 3(b)
Class 3
Item 3(b)
UN: MOTOR SPIRIT

Flammable liquid
UN Number 1203
Flammable liquid
Class 3
Packing group II
IMO: MOTOR SPIRIT
Flammable liquid
Class 3
Packing group II
3[Y]E
_________________________________________________________________________________
Extremely flammable
Toxic
Irritant
Harmful
EU Labelling
Symbol:
Flame
EXTREMELY FLAMMABLE
TOXIC
Contains:
Lead alkyls
Risk ( R ) Phrases:
R23/24/25 Also Toxic by inhalation
in contact with skin
and if swallowed


S43 In case of fire
S62 If swallowed
_________________________________________________________________________________
Compiled by:
Chertsey Road
Sunbury-on-Thames
Middlesex
TW16 7LN

Companies. However
sheet.
______________________________________________________________________________
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GLIS No: SALB2101a Material Name: BP Unleaded Gasoline (Singapore) Issue Date : 04/30/2001 : Page::
GLIS BP SDS Finals

GLIS Sheet No:SALB2101a SDS Reference:

Paper Type: BP Status: Active
Material Name: BP Unleaded Gasoline (Singapore)
Language:English Country:ALB
Archived: No Printed: No
Hazardous Components: Physical Characteristics: Gasoline Tox File: 190.31 and 35
_________________________________________________________________________________
SAFETY DATA SHEET
BP Unleaded Gasoline (Singapore)

COMPANY/UNDERTAKING
BP Unleaded Gasoline (Singapore)
Alternative Names: Quantum 98, Quantum 95 and Quantum 92, BP Mogas 118, BP MogasPlus, Unleaded Motor
Gasoline, Super Unleaded, Extra Unleaded, Super Plus, Unleaded 98, 97 & 92
Application
Use only as a motor fuel for spark ignition engines. NOT for aviation use. Should NOT be used as a solvent nor
cleaning agent.
BP Asia Lubricants Business
BP Tower
21st Storey
396 Alexandra Road
Singapore 0511

+(65) 371 8999
SEE SECTION 16 OF THIS SDS FOR OTHER NATIONAL CONTACT DETAILS
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_________________________________________________________________________________
<5%
40 - 100%
Toluene, EINECS No. 203-625-9, CAS No. 108-88-3 F, Xn, R11 Highly flammable, R20 Harmful by inhalation.
40 - 50%
Xylene, EINECS No. 202-422-2, CAS No. 95-47-6 Xn, Xi, R10 Flammable, R20/21 Harmful by inhalation and in
contact with skin, R38 Irritating to skin.
10 - 20%
_________________________________________________________________________________
Harmful by inhalation.
_________________________________________________________________________________
Eyes
Skin
Ingestion

Inhalation
Medical Advice
_________________________________________________________________________________
Combustion Products
_________________________________________________________________________________
etc.).

_________________________________________________________________________________


Storage Conditions
Fire Prevention
_________________________________________________________________________________

Exposure Limits
Gasoline
Benzene


Toluene
ACGIH (USA): TLV 50 ppm (8 hr TWA)
Xylene
ACGIH (USA): TLV 100 ppm (8 hr TWA); 150 ppm (15 min STEL)
Protective Clothing
_________________________________________________________________________________

Typical Values
Grades:
Test Method Units
Physical state low
viscosity
liquid
Colour colourless -
may be
dyed
Odour gasoline
like
Vapour density rel. ASTM 3-4
to air D2463/D2421
Flash point (COC) ASTM D 92 °C -40
Kinematic viscosity mm²/s <1
@ 20°C
_________________________________________________________________________________

Conditions to Avoid

Sources of ignition
Materials to Avoid

_________________________________________________________________________________
Eyes
Skin
Harmful in contact with skin.
Ingestion
diarrhoea.
Inhalation
Harmful if vapour, mists or fumes generated during use are inhaled.
ABUSE:
leukaemia.
_________________________________________________________________________________
Mobility

Aquatic toxicity

impaired.
_________________________________________________________________________________
local regulations.
_________________________________________________________________________________
ADR/RID: Motor spirit, Flammable Liquid , Class 3, Item 3(b), Hazard Identification No 33
ADNR/ADN: Motor Spirit, Class 3, Item 3(b),
UN: MOTOR SPIRIT, Flammable liquid, Class 3, Packing Group II, UN Number 1203
IMO: MOTOR SPIRIT, Flammable liquid, Class 3.1, Packing group II
EMERGENCY ACTION CODE: 3[Y]E
_________________________________________________________________________________
Extremely flammable
Harmful
Irritant
EU Labelling
Symbol:
Flame
EXTREMELY FLAMMABLE
Contains:
Risk ( R ) Phrases:
R20 Also Harmful by inhalation

Other regulatory acts:

_________________________________________________________________________________
Compiled by:
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
NATIONAL CONTACT DETAILS AND EMERGENCY CALL NUMBERS
Tata BP Lubricants India Ltd. 75-77 Maker Chambers VI, Nariman Point, Mumbai 21, India
Tel: +91 22 288 0497/8 Fax: +91 22 288 0514
For other Middle East, Central Asia & Indian Sub Continent
BP Middle East, PO Box 1699 Dubai, United Arab Emirates
Tel: +(971) 4 331 8842 Pgr: +(971) 9 394 9520
BP Oil (Thailand) Ltd. 29th floor, Seng Thong Thani Tower, 82 North Sathorn Road, Silom, Bangrak, Bangkok 10500,
Thailand. Tel: +(662) 6392688 Tel: +(62) 21 78831123 (Office Hrs) Pgr: +(662) 162 222210
BP Indonesia. Kuningan Plaza, South Tower #401, Jl. H.R.Rasuna Said Kav C11-14, Jakarta 12940, Indonesia
Tel: +(62) 21 78831123 (Office Hrs) H/p: +(62) 0818 727 560 +(62) 0816 898927
BP PETCO. 141B Ly Chinh Thang, 3rd Dist. Ho Chi Minh City, Vietnam
Pgr: +(84) 107 082784 Tel: +(84) 8 8467890
BP Taiwan Limited. 7F-C, Hung Kuo Building, 167 Tun Hua North Road, Taipei 105, Taiwan
Pgr: +(886) 95762 8305 Tel: +(886) 2 2715 1280 (Office hrs)

BP Oil China. 21/F, Super Ocean Financial Centre, 2067 West Yan An Road, Shanghai 200335, P.R.China
Tel: +(86) 21 6278 4858
BP Oil Malaysia. Lot 197 II & 197 III, Jalan Pelabuhan Utara, P O Box 62 Port Klang 42000, Selangor, Malaysia
Tel: +(6) 03-3695300 (Office hours) +(6) 03 9870097 H/p: +(6) 011 341994
BP Lubricant Korea. Room 308, Leema Bldg. 146-1, Susong-dong, Chongro-ku, Seoul 110-140, Korea
Tel: +(82) 2 725 8966 H/p: +(82) 11 796 8966
______________________________________________________________________________

GLIS No: SALB2101 Material Name: BP Unleaded Gasoline Issue Date : 04/30/2001 : Page::
GLIS BP SDS Finals

GLIS Sheet No:SALB2101 SDS Reference:

Paper Type: BP Status: Active
Material Name: BP Unleaded Gasoline
Language:English Country:ALB
Archived: No Printed: No
Hazardous Components: Physical Characteristics: Gasoline Tox File: 190.31 and 35
_________________________________________________________________________________
SAFETY DATA SHEET
BP Unleaded Gasoline
COMPANY/UNDERTAKING
BP Unleaded Gasoline
Alternative Names: Quantum 98, Quantum 95 and Quantum 92, BP Mogas 118, Unleaded Motor Gasoline, Super
Unleaded, Extra Unleaded, Super Plus, Unleaded 98, 97 and 92
Application
cleaning agent.
BP Asia Lubricants Business
BP Tower
21st Storey
396 Alexandra Road
Singapore 0511

+(65) 371 8999
SEE SECTION 16 OF THIS SDS FOR OTHER NATIONAL CONTACT DETAILS
file:///C|/Documents%20and%20Settings/lanewg/M...%20Gasoline%20Issue%20Date%20%2004-30-2001.htm (1 of 8) [29/01/2002 08:51:52]

_________________________________________________________________________________
(>90%)
_________________________________________________________________________________
_________________________________________________________________________________
Eyes
Skin
Ingestion
Inhalation

Medical Advice
_________________________________________________________________________________
Combustion Products
_________________________________________________________________________________
etc.).

_________________________________________________________________________________

Storage Conditions

Fire Prevention
_________________________________________________________________________________

Exposure Limits
Gasoline
Benzene
Protective Clothing


_________________________________________________________________________________

Typical Values
Grades: BP
Unleaded
Gasoline
Test Method Units
Colour colourless -
may be
dyed
Odour gasoline
like
Vapour density rel. ASTM 3-4
to air D2463/D2421
Kinematic viscosity mm²/s <1
@ 20°C
_________________________________________________________________________________

Conditions to Avoid
Sources of ignition
Materials to Avoid

_________________________________________________________________________________


Eyes
Skin
Ingestion
diarrhoea.
Inhalation
ABUSE:
leukaemia.
_________________________________________________________________________________
Mobility

Aquatic toxicity
impaired.
_________________________________________________________________________________
local regulations.

_________________________________________________________________________________
_________________________________________________________________________________
Extremely flammable
Harmful
Irritant
EU Labelling
Symbol:
Flame
EXTREMELY FLAMMABLE
Contains:
Risk ( R ) Phrases:
Other regulatory acts:

_________________________________________________________________________________
Compiled by:
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
NATIONAL CONTACT DETAILS AND EMERGENCY CALL NUMBERS
Tata BP Lubricants India Ltd. 75-77 Maker Chambers VI, Nariman Point, Mumbai 21, India
Tel: +91 22 288 0497/8 Fax: +91 22 288 0514
For other Middle East, Central Asia & Indian Sub Continent
BP Middle East, PO Box 1699 Dubai, United Arab Emirates
Tel: +(971) 4 331 8842 Pgr: +(971) 9 394 9520
BP Oil (Thailand) Ltd. 29th floor, Seng Thong Thani Tower, 82 North Sathorn Road, Silom, Bangrak, Bangkok 10500,
Thailand. Tel: +(662) 6392688 Tel: +(62) 21 78831123 (Office Hrs) Pgr: +(662) 162 222210
BP Indonesia. Kuningan Plaza, South Tower #401, Jl. H.R.Rasuna Said Kav C11-14, Jakarta 12940, Indonesia
Tel: +(62) 21 78831123 (Office Hrs) H/p: +(62) 0818 727 560 +(62) 0816 898927
BP PETCO. 141B Ly Chinh Thang, 3rd Dist. Ho Chi Minh City, Vietnam
Pgr: +(84) 107 082784 Tel: +(84) 8 8467890
BP Taiwan Limited. 7F-C, Hung Kuo Building, 167 Tun Hua North Road, Taipei 105, Taiwan
Pgr: +(886) 95762 8305 Tel: +(886) 2 2715 1280 (Office hrs)
BP Oil China. 21/F, Super Ocean Financial Centre, 2067 West Yan An Road, Shanghai 200335, P.R.China
Tel: +(86) 21 6278 4858
BP Oil Malaysia. Lot 197 II & 197 III, Jalan Pelabuhan Utara, P O Box 62 Port Klang 42000, Selangor, Malaysia
Tel: +(6) 03-3695300 (Office hours) +(6) 03 9870097 H/p: +(6) 011 341994
BP Lubricant Korea. Room 308, Leema Bldg. 146-1, Susong-dong, Chongro-ku, Seoul 110-140, Korea
Tel: +(82) 2 725 8966 H/p: +(82) 11 796 8966
______________________________________________________________________________

file:///C|/Documents%20and%20Settings/lanewg/My%20Documents/DATA/QA%20Amendments/MSDS/White%20Oil/condensate.htm

CONDENSATE
CONDENSATE
EXXON COMPANY, U.S.A.

A DIVISION OF EXXON CORPORATION
DATE ISSUED: 01/24/97

SUPERSEDES DATE: 07/29/96

P.O. BOX 2180
HOUSTON, TX 77252-2180
A. IDENTIFICATION AND EMERGENCY INFORMATION
PRODUCT NAME
CONDENSATE
PRODUCT CATEGORY
Condensate
PRODUCT APPEARANCE AND ODOR

Clear liquid, pale yellow color
Light hydrocarbon odor
MEDICAL EMERGENCY TELEPHONE NUMBER

(713) 656-3424
TRANSPORTATION EMERGENCY TELEPHONE NUMBERS:

(BAYTOWN) (281) 834-3296
(CHEMTREC) 1-800-424-9300
B. COMPONENTS AND HAZARD INFORMATION
CAS NO. OF APPROXIMATE

COMPONENTS COMPONENTS CONCENTRATION
A complex combination of 68919-39-1 100%

hydrocarbons separated and/or
condensed from natural gas during
transportation and collected at the
wellhead and/or from the production,
gathering, transmission, and
distribution pipelines in deeps,
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scrubbers, etc. It consists

predominantly of hydrocarbons having
carbon numbers predominantly in the
range of C2 through C8.
All components of this product are listed on the U.S. TSCA inventory.
See Section E for Health and Hazard Information.
See Section H for additional Environmental Information.
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (HMIS)

Health Flammability Reactivity BASIS
1 3 0 Recommended by Exxon
EXPOSURE LIMIT FOR TOTAL PRODUCT BASIS

EUSA's Occupational Exposure Limit Recommended by Exxon
(OEL) of 100 ppm or 300 mg/m3 for
an 8-hour workday recommended for
motor gasoline should be used until
a formal condensate/naphtha OEL is
established.
The airborne benzene level shall not OSHA Regulation 29 CFR 1910.1028
exceed 1 ppm for an 8-hour workday or
5 ppm STEL
945-0277(MWH001)
C. PRIMARY ROUTES OF ENTRY AND EMERGENCY AND FIRST AID PROCEDURES
EYE CONTACT
If splashed into the eyes, flush with clear water for 15 minutes or until
irritation subsides. If irritation persists, call a physician.
SKIN
In case of skin contact, remove any contaminated clothing and wash skin
with soap and water. Launder or dry-clean clothing before reuse. If
product is injected into or under the skin, or into any part of the body,
regardless of the appearance of the wound or its size, the individual
should be evaluated immediately by a physician as a surgical emergency.
Even though initial symptoms from high pressure injection may be minimal
or absent, early surgical treatment within the first few hours may
significantly reduce the ultimate extent of injury.
INHALATION
If overcome by vapor, immediately move to fresh air and call a physician.

If breathing is irregular or has stopped, start resuscitation, administer

oxygen, if available.
INGESTION
If ingested, DO NOT induce vomiting; call a physician immediately.
D. FIRE AND EXPLOSION HAZARD INFORMATION
UNUSUAL FIRE AND EXPLOSION HAZARD
EXTREMELY FLAMMABLE
VAPORS CAN TRAVEL AND EXPLODE
FLASH POINT (MINIMUM)

EXTREMELY FLAMMABLE - Per DOT 49 CFR 173.120
Approximately -38 Deg. C (-36 Deg. F)
ASTM D 93, Pensky Martens Closed Cup
AUTOIGNITION TEMPERATURE
Not determined
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) - HAZARD IDENTIFICATION

Health Flammability Reactivity BASIS
1 3 0 Recommended by Exxon
HANDLING PRECAUTIONS
This liquid is volatile and gives off invisible vapors. Either the liquid
or vapor may settle in low areas or travel some distance along the ground
or surface to ignition sources where they may ignite or explode.
Keep product away from ignition sources, such as heat, sparks, pilot
lights, static electricity, and open flames.
FLAMMABLE OR EXPLOSIVE LIMITS (APPROXIMATE PERCENT BY VOLUME IN AIR)

Estimated values: Lower Flammable Limit 1%
Upper Flammable Limit 8%
EXTINGUISHING MEDIA AND FIRE FIGHTING PROCEDURES

Foam, water spray (fog), dry chemical, carbon dioxide and vaporizing
liquid type extinguishing agents may all be suitable for extinguishing
fires involving this type of product, depending on size or potential size
of fire and circumstances related to the situation. Plan fire protection
and response strategy through consultation with local fire protection
authorities or appropriate specialists.
The following procedures for this type of product are based on the

recommendations in the National Fire Protection Association's "Fire

Protection Guide on Hazardous Materials", Tenth Edition (1991):
Use dry chemical, foam or carbon dioxide to extinguish the fire. "Water
may be ineffective", but water should be used to keep fire-exposed
containers cool. If a leak or spill has ignited, use water spray to
disperse the vapors and to protect persons attempting to stop a leak.
Water spray may be used to flush spills away from exposures. Minimize
breathing of gases, vapor, fumes or decomposition products. Use
supplied-air breathing equipment for enclosed or confined spaces or as
otherwise needed.
NOTE: The inclusion of the phrase "water may be ineffective" is to

indicate that although water can be used to cool and protect exposed
material, water may not extinguish the fire unless used under favorable
conditions by experienced fire fighters trained in fighting all types of
flammable liquid fires.
DECOMPOSITION PRODUCTS UNDER FIRE CONDITIONS

Fumes, smoke, carbon monoxide, sulfur oxides, hydrogen sulfide, aldehydes
and other decomposition products, in the case of incomplete combustion.
"EMPTY" CONTAINER WARNING

"Empty" containers retain residue (liquid and/or vapor) and can be
dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR
EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR
OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
Do not attempt to refill or clean containers since residue is difficult to

remove. "Empty" drums should be completely drained, properly bunged and
promptly returned to a drum reconditioner. All other containers should be
disposed of in an environmentally safe manner and in accordance with
governmental regulations.
For work on tanks refer to Occupational Safety and Health Administration

regulations, ANSI Z49.1, and other governmental and industrial references
pertaining to cleaning, repairing, welding, or other contemplated
operations.
E. HEALTH AND HAZARD INFORMATION
VARIABILITY AMONG INDIVIDUALS

Health studies have shown that many petroleum hydrocarbons pose potential
human health risks which may vary from person to person. As a precaution,
exposure to liquids, vapors, mists or fumes should be minimized.
EFFECTS OF OVEREXPOSURE (Signs and symptoms of exposure)

High vapor concentrations (greater than approximately 1000 ppm) are

irritating to the eyes and the respiratory tract, and may cause headaches,
dizziness, anesthesia, drowsiness, unconsciousness, and other central
nervous system effects, including death.
Prolonged or repeated liquid contact with the skin will dry and defat the
skin, leading to possible irritation and dermatitis.
NATURE OF HAZARD AND TOXICITY INFORMATION

Prolonged or repeated skin contact with this product tends to remove skin
oils, possibly leading to irritation and dermatitis; however, based on
human experience and available toxicological data, this product is judged
to be neither a "corrosive" nor an "irritant" by OSHA criteria.
Product contacting the eyes may cause eye irritation.
Condensate may contain benzene, CAS No. 71-43-2, as a natural constituent.
Benzene can cause anemia and other blood diseases, including leukemia
(cancer of the blood-forming system) after prolonged or repeated exposures
at high concentrations (e.g. 50-500 ppm). It has also caused fetal defects
in tests on laboratory animals.
Contains light hydrocarbon components similar to gasoline. Lifetime

studies by the American Petroleum Institute have shown that kidney damage
and kidney cancer can occur in male rats after prolonged inhalation
exposures at elevated concentrations of total gasoline. Kidneys of mice
and female rats were unaffected. The U.S. EPA Risk Assessment Forum has
concluded that the male rat kidney tumor results are not relevant for
humans. Total gasoline exposure also produced liver tumors in female mice,
only. The implication of this data for humans has not been determined.
Certain components, such as normal hexane, may also affect the nervous
system at high concentrations (e.g., 1000-1500 ppm).
The presence of n-hexane in this product as a natural constituent

represents a distinct hazard of producing peripheral polyneuropathy, a
progressive disorder of the nervous system, which, with sufficient high
exposure, has the potential of becoming irreversible. This disorder has
been observed in individuals exposed repeatedly to high vapor
concentrations (1000-1500 ppm) of n-hexane over a period of several
months. Exposure to this product should be controlled to keep the maximum
level below 100 ppm, which will result in n-hexane exposure of 50 ppm or
less. The OSHA 8-hour Time Weighted Average-Permissible Exposure Limit
(TWA-PEL) is 50 ppm for n-hexane.
Simultaneous exposure to the vapors of n-hexane and methyl ethyl ketone

(MEK) or to n-hexane and methyl isobutyl ketone (MIBK) increases the risk

of adverse effects from n-hexane. Evidence in laboratory animals and

humans indicates that in the presence of MEK or MIBK, the neuropathy
associated with n-hexane is produced in a shorter time or at lower
exposure concentrations. This interaction has been reported when the
exposure to n-hexane is below the American Conference of Governmental
Industrial Hygienists (ACGIH) limit of 50 ppm and MEK is below the ACGIH
limit of 200 ppm or when MIBK is below the ACGIH limit of 50 ppm.
Lifetime skin painting studies conducted by the American Petroleum

Institute, Exxon and others have shown that untreated naphthas and
distillates in the same boiling range as this product usually produced
skin tumors and/or skin cancer in laboratory mice. The degree of
carcinogenic response was weak to moderate with a relatively long latent
period. The implications of these results for humans have not been
determined.
Limited studies on oils of very active carcinogens have shown that washing
the animals' skin with soap and water between applications greatly reduces
tumor formation.
Potential risks to humans can be minimized by observing good work

practices and personal hygiene procedures generally recommended for
petroleum products. (See Section I for recommended protection and
precautions.)
Product has a low order of acute oral and dermal toxicity, but minute
amounts aspirated into the lungs during ingestion or vomiting may cause
mild to severe pulmonary injury and possibly death.
This product is judged to have an acute oral LD50 (rat) greater than 5
g/kg of body weight, and an acute dermal LD50 (rabbit) greater than 3.16
g/kg of body weight.
Concentrated, prolonged or deliberate inhalation of this product may cause

brain and nervous system damage. Prolonged and repeated exposure of
pregnant animals to high levels of toluene (levels greater than
approximately 1500 ppm) has been reported to cause adverse fetal
developmental effects. The American Conference of Governmental Industrial
Hygienists (ACGIH) Threshold Limit Value for toluene is 50 ppm (188 mg/m3)
as a Time Weighted Average for an 8-hour workday.
PRE-EXISTING MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY EXPOSURE

Benzene - Individuals with liver disease may be more susceptible to toxic
effects.
Hexane - Individuals with neurological disease should avoid exposure.

Petroleum Solvents/Petroleum Hydrocarbons - Skin contact may aggravate an

existing dermatitis.
F. PHYSICAL DATA
The following data are approximate or typical values and should not be
used for precise design purposes.
BOILING RANGE
Approximately -88 to 230 Deg. C
(-127 to 446 Deg. F)
VAPOR PRESSURE
Approximately 10-400 mm Hg @
20 Deg. C (68 Deg. F)
SPECIFIC GRAVITY (15.6 Deg. C/15.6 Deg. C)

0.7-0.8
VAPOR DENSITY (AIR = 1)

2-5
MOLECULAR WEIGHT
Complex mixture, components vary
PERCENT VOLATILE BY VOLUME

100
EVAPORATION RATE @ 1 ATM. AND 25 Deg. C

(77 Deg. F) (n-BUTYL ACETATE = 1)
Not determined
pH
Essentially neutral
SOLUBILITY IN WATER @ 1 ATM.

AND 25 Deg. C (77 Deg. F)
Negligible; less than 0.1%
POUR, CONGEALING OR MELTING POINT

Not determined
VISCOSITY
Not determined
G. REACTIVITY
This product is stable and will not react violently with water. Hazardous

polymerization will not occur. Avoid contact with strong oxidants such as
liquid chlorine, concentrated oxygen, sodium hypochlorite, calcium
hypochlorite, etc., as this presents a serious explosion hazard.
H. ENVIRONMENTAL INFORMATION
CLEAN WATER ACT / OIL POLLUTION ACT

This product may be classified as an oil under Section 311 of the Clean
Water Act, and under the Oil Pollution Act. Discharges or spills into or
leading to surface waters that cause a sheen must be reported to the
National Response Center (1-800-424-8802).
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED

Shut off and eliminate all ignition sources. Keep people away. Recover
free product. Add sand, earth or other suitable absorbent to spill area.
Minimize breathing vapors. Minimize skin contact. Ventilate confined
spaces. Open all windows and doors. Keep product out of sewers and
watercourses by diking or impounding. Advise authorities if product has
entered or may enter sewers, watercourses, or extensive land areas.
Assure conformity with applicable governmental regulations. Continue to

observe precautions for volatile, flammable vapors from absorbed material.
THE FOLLOWING INFORMATION MAY BE USEFUL IN COMPLYING WITH VARIOUS STATE

AND FEDERAL LAWS AND REGULATIONS UNDER VARIOUS ENVIRONMENTAL STATUTES:
REPORTABLE QUANTITY (RQ), EPA REGULATION 40 CFR 302 (CERCLA Section 102)
This product is exempt from CERCLA Reporting Requirements. Refer to Clean
Water Act/Oil Pollution Act.
THRESHOLD PLANNING QUANTITY (TPQ), EPA REGULATION 40 CFR 355 (SARA

Sections 301-304)
No TPQ for product or any constituent greater than 1% or 0.1%
(carcinogen).
TOXIC CHEMICAL RELEASE REPORTING, EPA REGULATION 40 CFR 372 (SARA Section
313)
This product may contain:
Approximately 0-5% benzene.
Approximately 0-2% cyclohexane.
Approximately 0-2% n-hexane.
Approximately 0-5% toluene.
Approximately 0-5% xylene.
HAZARDOUS CHEMICAL REPORTING, EPA REGULATION 40 CFR 370 (SARA Sections

311-312)
EPA Hazard Classification Codes: Acute, Chronic, Fire

I. PROTECTION AND PRECAUTIONS
VENTILATION
Use only with ventilation sufficient to prevent exceeding recommended
exposure limit or buildup of explosive concentrations of vapor in air. No
smoking, flame or other ignition sources.
RESPIRATORY PROTECTION
Use supplied-air respiratory protection in confined or enclosed spaces, if
needed.
PROTECTIVE GLOVES
Use chemical-resistant gloves, if needed, to avoid prolonged or repeated
skin contact.
EYE PROTECTION
Use splash goggles or face shield when eye contact may occur.
OTHER PROTECTIVE EQUIPMENT

Use chemical-resistant apron or other impervious clothing, if needed, to
avoid contaminating regular clothing, which could result in prolonged or
repeated skin contact.
WORK PRACTICES / ENGINEERING CONTROLS

To prevent fire or explosion risk from static accumulation and discharge,
effectively bond and/or ground product transfer system in accordance with
(THE) National Fire Protection Association PUBLICATIONS.
Keep containers closed when not in use. Do not store near heat, sparks,
flame or strong oxidants. Adequate ventilation is required in order to
prevent exceeding recommended exposure limit or buildup of explosive
concentrations of vapor in air. No smoking, flame or other ignition
sources.
To minimize fire or explosion risk from static charge accumulation and

discharge, effectively bond and/or ground product transfer system in
accordance with the National Fire Protection Association standard for
petroleum products.
In order to prevent fire or explosion hazards, use appropriate equipment.
Information on electrical equipment appropriate for use with this product

may be found in the latest edition of the National Electrical Code
(NFPA-70). This document is available from the National Fire Protection
Association, Batterymarch Park, Quincy, Massachusetts 02269.

PERSONAL HYGIENE
Minimize breathing vapor or mist. Avoid prolonged or repeated contact with
skin. Remove contaminated clothing; launder or dry-clean before re-use.
Remove contaminated shoes and thoroughly clean and dry before re-use.
Cleanse skin thoroughly after contact, before breaks and meals, and at end
of work period. Product is readily removed from skin by waterless hand
cleaners followed by washing thoroughly with soap and water.
J. TRANSPORTATION AND OSHA RELATED LABEL INFORMATION
TRANSPORTATION INCIDENT INFORMATION

For further information relative to spills resulting from transportation
incidents, refer to latest Department of Transportation Emergency Response
Guidebook for Hazardous Materials Incidents.
U.S. DOT HAZARDOUS MATERIALS SHIPPING DESCRIPTION

Know the flash point for each shipment to accurately classify it into the
appropriate category.
Petroleum Distillate, n.o.s., 3, UN1268, PG*
*PG I - Initial Boiling Point equal to or less than 95 Deg. F (35 Deg. C)
*PG II - Initial Boiling Point greater than 95 Deg. F (35 Deg. C);
Flash Point less than 73 Deg. F (23 Deg. C)
*PG III - Flash Point equal to or greater than 73 Deg. F (23 Deg. C) and
less than 100 Deg. F (37.78 Deg. C)
*PG III - Flash point equal to or greater than 100 Deg. F (37.78 Deg. C)
and equal to or less than 141 Deg. F (60.5 Deg. C) and Transported by air
or marine
(Bulk, greater than 119 gallons, and non-bulk packaging)
OR
Petroleum distillate, n.o.s., Combustible Liquid, UN1268, PG III
Flash Point equal to or greater than 100 Deg. F (37.78 Deg. C) and less
than 200 Deg. F (93.33 Deg. C) and Transported by highway or Rail in Bulk
packaging (greater than 119 gallons)
Non-bulk packaging, less than 119 gallons, not regulated in highway and
rail transportation
OSHA LABEL INFORMATION

In compliance with hazard and right-to-know requirements, where applicable
OSHA Hazard Warnings may be found on the label, bill of lading or invoice
accompanying this shipment.

DANGER!
EXTREMELY FLAMMABLE
LONG-TERM, REPEATED EXPOSURE MAY CAUSE CANCER, BLOOD AND NERVOUS SYSTEM
DAMAGE
CONTAINS: BENZENE
OVEREXPOSURE MAY CAUSE EYE, SKIN OR RESPIRATORY TRACT IRRITATION OR

DAMAGE, AND MAY CAUSE HEADACHES, DIZZINESS OR OTHER ADVERSE NERVOUS SYSTEM
EFFECTS OR DAMAGE, INCLUDING DEATH
The health and safety information presented herein must be used in

conjunction with the pertinent standards for training, work practices and
facilities design established by OSHA, NIOSH, NFPA, API, NEC, NSC,
UNDERWRITERS, BUREAU OF MINES, and similar organizations.
The information and recommendations contained herein are, to the best of

Exxon's knowledge and belief, accurate and reliable as of the date issued.
Exxon does not warrant or guarantee their accuracy or reliability, and
Exxon shall not be liable for any loss or damage arising out of the use
thereof.
The information and recommendations are offered for the user's

consideration and examination, and it is the user's responsibility to
satisfy itself that they are suitable and complete for its particular use.
If buyer repackages this product, legal counsel should be consulted to
insure proper health, safety and other necessary information is included
on the container.
The Environmental Information included under Section H hereof as well as

the Hazardous Materials Identification System (HMIS) and National Fire
Protection Association (NFPA) ratings have been included by Exxon Company,
U.S.A. in order to provide additional health and hazard classification
information. The ratings recommended are based upon the criteria supplied
by the developers of these rating systems, together with Exxon's
interpretation of the available data.
FOR ADDITIONAL INFORMATION ON HEALTH EFFECTS CONTACT:

First contact your supervisor. If unavailable, call Safety Advisor or
Industrial Hygiene.
Call 1-800-443-9966, Exxon Company, U.S.A., to obtain technical

information.

DESCRIPTION AND EXPLANATION OF TERMS
MATERIAL SAFETY DATA SHEETS
The following information is intended to assist the reader in

understanding the format and the material included in Exxon's Material
Safety Data Sheets (MSDS).
A. IDENTIFICATION AND EMERGENCY INFORMATION
This section includes the product name and category. Additional

information about components and CAS numbers is shown in Section B. The
"Product Code" is Exxon's internal product identification number. "Product
Appearance and Odor" includes a physical description of the product.
MEDICAL EMERGENCY TELEPHONE NUMBER - Exxon's 24-hour telephone number is

intended only for medical-related emergencies. After normal business hours
the caller should leave a short description of the emergency and the call
back number. The Exxon medical staff person on duty will respond as soon
as possible, normally within a few minutes. Routine MSDS questions should
be directed to Marketing Technical Services (713) 656-5949 during normal
business hours.
B. COMPONENTS AND HAZARD INFORMATION
COMPONENTS - The chemical or common names of the major constituents are

listed along with names of any ingredients believed to be health or
physical hazards and which are present in the product at a concentration
of 1% or more. Health effects and presence of carcinogens (at 0.1% or
greater) are discussed in Section E. The major constituents of most
petroleum products are refined petroleum fractions as defined in the
Inventory of Chemical Substances under the Toxic Substances Control Act. A
statement of U.S. TSCA inventory listing of components may be found in
this section.
CAS NUMBERS OF COMPONENTS - These are the Chemical Abstracts Service

Registry Numbers (CAS identification numbers) which are assigned to
individual component chemicals by the Chemical Abstracts Service, when
applicable. Some ingredients, particularly additives, are complex mixtures
to which single CAS numbers may not apply or for which detailed
composition information may not be available.
APPROXIMATE CONCENTRATION - This is the approximate concentration of the

component(s) in the product. In some cases, particularly where details are
proprietary, the total amount of several components is shown.

HAZARDOUS MATERIALS IDENTIFICATION SYSTEM(HMIS) - These recommendations

are for those organizations utilizing this system.
EXPOSURE LIMIT FOR TOTAL PRODUCT - The Occupational Safety and Health
Administration (OSHA) Permissible Exposure Limit (PEL), the American
Conference of Governmental Industrial Hygienists (ACGIH) Threshold Limit
Value (TLV), or Exxon's recommended Occupational Exposure Limit (OEL) is
shown. In some cases where carcinogens are present, a recommended limit
has not been established. For vapors, exposure limits are expressed in
parts per million (ppm) and in milligrams per cubic meter (mg/m3) of vapor
in air. For mists and fumes the limit is given in mg/m3. As noted in the
preface to published values adopted by the ACGIH, TLVs represent
"conditions under which it is believed that nearly all workers may be
repeatedly exposed day after day without adverse effect. Because of wide
variation in individual susceptibility, however, a small percentage of
workers may experience discomfort from some substances at concentrations
at or below the threshold limit; a smaller percentage may be affected more
seriously by aggravation of a preexisting condition or by development of
an occupational illness".
C. PRIMARY ROUTES OF ENTRY AND EMERGENCY AND FIRST AID PROCEDURES
EYE CONTACT - SKIN - INHALATION - INGESTION - These are primary routes of

entry along with recommended emergency and first aid procedures if an
individual is overexposed to the product.
D. FIRE AND EXPLOSION HAZARD INFORMATION
FLASH POINT (MINIMUM) - This is the temperature at which a liquid or solid

gives off enough flammable vapors, under conditions of the test, that a
source of ignition can ignite the vapor. The American Society for Testing
and Materials (ASTM) test method is also given.
AUTOIGNITION TEMPERATURE - This is the temperature at which a liquid or

solid may ignite spontaneously without the presence of a spark or other
source of ignition. Tests for autoignition temperature are not routinely
performed, so approximate or "greater than" values may be shown.
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) System - These recommendations

are included for those organizations utilizing this system.
HANDLING PRECAUTIONS - These provide guidance for use of product around

sources of ignition.
FLAMMABLE OR EXPLOSIVE LIMITS - These are the range of vapor

concentrations in air that may ignite or explode if an ignition source is

present; approximate or estimated values are shown.
EXTINGUISHING MEDIA AND FIRE FIGHTING PROCEDURES - These include

information recommended by the National Fire Protection Association.
DECOMPOSITION PRODUCTS UNDER FIRE CONDITIONS - These are by-products of

burning.
EMPTY PRODUCT CONTAINER WARNING - This is an important warning about

potential hazards associated with "empty" product containers.
E. HEALTH AND HAZARD INFORMATION - This information refers to the most

common biological effects that could be anticipated from a direct
overexposure to or contact with the product.
F. PHYSICAL DATA - Physical and chemical characteristics of the product

are presented in this section. The data are approximate or are typical
values and should not be used for precise design purposes.
G. REACTIVITY - This is the general chemical stability of the product and

some examples of conditions that should be avoided to prevent an unwanted
reaction.
H. ENVIRONMENTAL INFORMATION - This is information on product composition

and characteristics which may be required to be submitted under a variety
of local, state and federal regulations.
I. PROTECTION AND PRECAUTIONS - These are generally applicable precautions

recommended for the safe handling and use of the product, including
appropriate engineering controls, work practices, protective equipment,
and personal hygiene practices.
J. TRANSPORTATION AND OSHA RELATED LABEL INFORMATION - This is emergency

response information pertaining to transportation-related spills. In
addition, a Department of Transportation (DOT) Identification Number has
been assigned for reference, if applicable. This section also contains the
hazard language that would be incorporated onto the label, bill of lading
or shipping papers.
ADDENDUM - This includes a disclaimer, along with contacts and telephone

numbers for additional information, if needed.

Sheet No: STI2212 Material Name: Cracked Gas Oils Issue Date : 17/07/2000 Revision of Sheet Dated:16/09/98 Page:
ALIGN BP SDS Finals


Material Name: Cracked Gas Oils
________________________________________________________________________________
SAFETY DATA SHEET
Cracked Gas Oils

COMPANY/UNDERTAKING
Cracked Gas Oils
Alternative Names: Heavy Cycle Oil, Heavy Cracked Gas Oil, Light Cycle Oil, Light Cracked Gas Oil, Coker Visbreaker
Gas Oil, Combi Cracked Gas Oil
Application
Britannic House
1 Finsbury Circus
London, EC2M 7BA

+44 (0) 20 7496 4411
_________________________________________________________________________________
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Distillates (petroleum), light catalytic cracked. EINECS No: 265-060-4, CAS No: 64741-59-9
Distillates (petroleum), intermediate catalytic cracked. EINECS No: 265-062-5, CAS No:64741-60-2
Distillates (petroleum), light thermal cracked. EINECS No: 265-084-5, CAS No: 64741-82-8
Gas oils, paraffinic, EINECS No. 300-227-8, CAS No. 93924-33-5
_________________________________________________________________________________
Eyes
Skin
Ingestion
Inhalation
Medical Advice

develops.
_________________________________________________________________________________
Combustion Products
_________________________________________________________________________________
etc.).

_________________________________________________________________________________

Storage Conditions

Fire Prevention
_________________________________________________________________________________

Exposure Limits

Hydrogen sulphide

Protective Clothing
_________________________________________________________________________________

Typical Values
Grades: Cracked Gas
Oil
Gas Oil -
unspecified
Test Method Units
Colour amber
Odour gasoil-like
_________________________________________________________________________________

Conditions to Avoid
Sources of ignition
Materials to Avoid

_________________________________________________________________________________
Eyes

Skin
This material contains significant quantities of polycyclic aromatic hydrocarbons (PCAs), some of which has been
Ingestion
diarrhoea.
Inhalation
_________________________________________________________________________________
Mobility

Aquatic toxicity
impaired.
_________________________________________________________________________________
_________________________________________________________________________________
_________________________________________________________________________________

Harmful
Irritant
EU Labelling
Symbol:
Dead tree and fish
Risk ( R ) Phrases:
Substance name: Cracked gas oil, EINECS No: 265-060-4, 265-062-5, 265-084-5
Substance name: Gas oil - unspecified, EINECS No: 300-227-8
_________________________________________________________________________________
Compiled by:
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN

Sheet Revisions
16/09/98 1, 3, 4, 7, 8, 11, 12, 15
17/07/2000 4, 7, 8, 12, 15
SHEET NO: STI2212

______________________________________________________________________________

Sheet No: STI2220 Material Name: Cracked Naphtha Issue Date : 17/07/2000 Revision of Sheet Dated:11/09/98 Page:
ALIGN BP SDS Finals


Material Name: Cracked Naphtha
________________________________________________________________________________
SAFETY DATA SHEET
Cracked Naphtha
COMPANY/UNDERTAKING
Cracked Naphtha
Alternative Names: Light catalytic cracked naphtha, Light cat cracked spirit, Heavy catalytic cracked naphtha, Heavy
cat cracked spirit, Light hydrocracked naphtha, Heavy hydrocracked naphtha, Visbreaker cracked naphtha, Combi
Cracked naphtha
Application
Petroleum feedstock or fuel blending component
Britannic House
1 Finsbury Circus
London, EC2M 7BA

+44 (0) 20 7496 4411
_________________________________________________________________________________
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Naphtha (petroleum), light catalytic cracked. EINECS No: 265-056-2, CAS No: 64741-55-5
Naphtha (petroleum), heavy catalytic cracked. EINECS No: 265-055-7, CAS No: 64741-54-4
Naphtha (petroleum), light hydrocracked. EINECS No: 265-071-4, CAS No: 64741-69-1
Naphtha (petroleum), light thermal cracked. EINECS No. 265-075-6 CAS No. 64741-74-8,
Naphtha (petroleum), heavy hydrocracked. EINECS No: 265-079-8, CAS No: 64741-78-2
Naphtha (petroleum), heavy thermal cracked. EINECS No: 265-085-0, CAS No: 64741-83-9
_________________________________________________________________________________
Eyes
Skin
Ingestion
Inhalation

Medical Advice
develops.
_________________________________________________________________________________
Combustion Products
_________________________________________________________________________________
etc.).

_________________________________________________________________________________

Storage Conditions

Fire Prevention
_________________________________________________________________________________

Exposure Limits

Gasoline
Benzene
Hydrogen sulphide
Protective Clothing
_________________________________________________________________________________

Typical Values
Grades: Cracked
Naphtha
Test Method Units
liquid
amber
Odour gasoline-like /
pungent
Density @ 15°C ASTM D 1298 kg/m³ approx 750
Boiling point/range ASTM D 86 °C -20 to 230
_________________________________________________________________________________


Conditions to Avoid
Sources of ignition
Materials to Avoid

_________________________________________________________________________________
Eyes
Skin
Ingestion
diarrhoea.
Inhalation
ABUSE:
leukaemia.
_________________________________________________________________________________
Mobility


Aquatic toxicity
impaired.

_________________________________________________________________________________
local regulations.
_________________________________________________________________________________
_________________________________________________________________________________
Extremely flammable
Harmful
Irritant
EU Labelling
Symbol:
Flame
Dead tree and fish
EXTREMELY FLAMMABLE
Risk ( R ) Phrases:

Substance name: Low boiling point cat-cracked naphtha, EINECS No: 265-056-2, 265-055-7
Substance name: Low boiling point naphtha - unspecified, EINECS No: 265-071-4, 265-079-8
Substance name: Low boiling point thermally cracked naphtha, EINECS No: 265-075-6, 265-085-0
_________________________________________________________________________________
Compiled by:
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
Sheet Revisions
11/09/98 1, 3, 4, 7, 8, 10, 11, 12, 14, 15
17/07/2000 1, 3, 4, 9, 15
SHEET NO: STI2220

REVISION OF SHEET DATED: 11/09/98,
REPLACEMENT OF SHEET NO: STI2207, STI2215
______________________________________________________________________________

file:///C|/Documents%20and%20Settings/lanewg/My%20Documents/DATA/QA%20Amendments/MSDS/White%20Oil/Diesel%202.htm

26120 DIESEL 2
Date Issued: 04-15-96
Supersedes: 03-20-96
STAR Enterprise
TEXACO
NOTE: Read and understand Material Safety Data Sheet before handling or
disposing of product.
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
MATERIAL IDENTITY
Product Code and Name: 26120 DIESEL 2
Chemical Name and/or Family or Description: Diesel Fuel
Manufacturer's Name and Address:

TEXACO REFINING AND MARKETING, INC
P.O. Box 7812
Universal City, CA 91608
Telephone Numbers:
Transportation Emergency -Company : (914) 831-3400
CHEMTREC : (800) 424-9300
Health Emergency -Company : (914) 831-3400
General MSDS Assistance : (914) 838-7204
Technical Information -Fuels : (914) 838-7336
-Chemical : (512) 459-6543
-Lubricant/Antifreezes : (800) 782-7852
-Additives : (713) 235-6278
-Solvents : (800) 876-3738
This Material Safety Data Sheet may be used for the following products for
Hazard Communications purposes only; not intended to imply identical
performance/technical specifications:
00408 LOW POUR DIESEL 2

00417 HIGH SULFUR LOW POUR RR DIESEL 2
00421 HIGH SULFUR SPECIAL RAILROAD DIESEL 2
00424 TEXACO DIESEL 2
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00428 TEXACO LOW SULFUR DIESEL 2

00429 LOW SULFUR DIESEL 2
00430 TEXACO LOW SULFUR CARB DIESEL 2
00435 HIGH SULFUR DIESEL 2
00439 TEXACO PREMIUM DIESEL FUEL
00449 TEXACO HIGH SULFUR DIESEL 2
00450 DIESEL 2 LGLP
00454 RAILROAD DIESEL
00456 TEXACO HIGH SULFUR DIESEL 2
00460 HIGH SULFUR DIESEL 2
00461 ASTF LOW POUR DIESEL
00493 TEXACO HIGH SULFUR WINTERIZED PREMIUM DIESEL 2
00559 LOW SULFUR CARB DIESEL 2
00560 TEXACO LOW SULFUR PREMIUM DIESEL NO. 2
00571 LOW SULFUR PREMIUM DIESEL NO. 2
00578 HIGH SULFUR PREMIUM DIESEL 2
00634 TEXACO HIGH SULFUR (0.3%) DIESEL 2
00639 TEXACO LOW SULFUR WINTERIZED PREMIUM DIESEL 2
00643 LOW SULFUR LOW POUR DIESEL 2
00651 HIGH SULFUR (3.0%) DIESEL 2
00652 LOW SULFUR PREMIUM DIESEL 2
00667 TEXACO LOW SULFUR PREMIUM DIESEL 2
01467 TAX EXEMPT TEXACO LOW SULFUR DIESEL 2
01468 TAX EXEMPT LOW SULFUR DIESEL 2
01469 TAX EXEMPT TEXACO LOW SULFUR PREMIUM DIESEL 2
01470 TAX EXEMPT LOW SULFUR PREMIUM DIESEL 2
01471 TAX EXEMPT TEXACO LS WNTRZ'D 30/70 DIESEL 2
01472 TAX EXEMPT LOW SULFUR WINTERIZED 30/70 DIESEL 2
01473 TAX EXEMPT TEXACO LS WTZ'D 30/70 PREM DIESEL2
01475 TAX EXEMPT LOW SULFUR SINTERIZED 50/50 DIESEL 2
01476 TAX EXEMPT TEXACO LS W 50/50 PREM DIESEL 2
01479 TAX EXEMPT TEXACO LOW SULFUR CARB DIESEL 2
N.D. - NOT DETERMINED

N.A. - NOT APPLICABLE
N.T. - NOT TESTED
< - LESS THAN
> - GREATER THAN
01480 TAX EXEMPT LOW SULFUR CARB DIESEL 2

01483 TEXACO ALASKA TAXABLE HIGH SULFUR DIESEL 2
01484 ALASKA TAXABLE HIGH SULFUR DIESEL 2

01485 TAX EXEMPT LOW POUR LOW SULFUR DIESEL 2

02602 2602 DIESEL CHIEF
02624 2624 TEXACO DIESEL FUEL
02643 TEXACO LOW SULFUR WINTERIZED 70/30 DIESEL 2
02673 TEXACO LOW SULFUR WINTERIZED 50/50 DIESEL 2
02675 LOW SULFUR WINTERIZED 70/30 DIESEL 2
02685 TEXACO LOW SULFUR WINTERIZED DIESEL 2
THE CRITERIA FOR LISTING COMPONENTS IN THE COMPOSITION SECTION IS AS

FOLLOWS: CARCINOGENS ARE LISTED WHEN PRESENT AT 0.1% OR GREATER;
COMPONENTS WHICH ARE OTHERWISE HAZARDOUS ACCORDING TO OSHA ARE LISTED WHEN
PRESENT AT 1.0% OR GREATER; NON-HAZARDOUS COMPONENTS ARE LISTED AT 3.0% OR
GREATER. THIS IS NOT INTENDED TO BE A COMPLETE COMPOSITIONAL DISCLOSURE.
REFER TO SECTION 14 FOR APPLICABLE STATES' RIGHT TO KNOW AND OTHER
REGULATORY INFORMATION.
Product and/or Component(s) Carcinogenic According to:

OSHA [ ]
IARC [ ]
NTP [ ]
OTHER [X]
NONE [ ]
Composition: (Sequence Number and Chemical Name)
Seq. Chemical Name CAS Number Range in %
01 * A complex mixture of hydrocarbons 100.00

produced by crude oil distillation.
Consists predominantly of
hydrocarbons ranging from C-9 to
C-20, and boiling in the range of
325-675F. The hydrotreated or
hydrosulfurized product also
contains some hydrocarbons produced
by the distillation of the catalytic
cracking. The latter materials
contain bicyclic and tricyclic
aromatic hydrocarbons.
PRODUCT IS HAZARDOUS ACCORDING TO OSHA (1910.1200).
* COMPONENT IS HAZARDOUS ACCORDING TO OSHA.

Exposure Limits referenced by Sequence Number in the Composition Section
Seq. Limit
None
EMERGENCY OVERVIEW
Appearance: Bright and clear liquid (Tax Exempt Diesels - pale red liquid)
Odor: Petroleum odor
WARNING STATEMENT
WARNING!
MAY CAUSE DIZZINESS AND DROWSINESS
CAUSES SKIN IRRITATION
MAY CAUSE EYE IRRITATION
ASPIRATION HAZARD IF SWALLOWED - CAN ENTER LUNGS AND CAUSE DAMAGE
COMBUSTIBLE LIQUID AND VAPOR
USE ONLY AS A FUEL
MAY CAUSE DELAYED SKIN DAMAGE BASED ON ANIMAL DATA
ATTENTION!
CONTAINS MIDDLE DISTILLATES WHICH MAY CAUSE CANCER BASED ON ANIMAL DATA
HMIS
Health: 1
Flammability: 2
Reactivity: 0
Special: -
NFPA
Health: 1
Flammability: 2
Reactivity: 0
Special: -
POTENTIAL HEALTH EFFECTS
Primary Route of Exposure:

EYE [X]
SKIN [X]
INHALATION [X]
INGESTION [ ]

EFFECTS OF OVEREXPOSURE
Acute:
Eyes: May cause irritation, experienced as mild discomfort and seen as

slight excess redness of the eye.
Skin:
Causes irritation with discomfort or pain, and seen as marked local

redness and swelling, with possible blister formation.
Other than the potential skin irritation effects noted above, acute (short
term) adverse effects are not expected from brief skin contact; see other
effects, below, and Section 11 for information regarding potential long
term effects.
Prolonged, widespread, or repeated skin contact may result in the

absorption of potentially harmful amounts of material.
Inhalation:
Vapors or mist may cause irritation of the nose and throat.
Inhalation may cause dizziness, drowsiness, euphoria, loss of

coordination, disorientation, headache, nausea, and vomiting. In poorly
ventilated areas or confined spaces, unconsciousness and asphyxiation may
result. Prolonged or repeated overexposure may result in the absorption of
potentially harmful amounts of material.
Ingestion: If more than several mouthfuls are swallowed, abdominal

discomfort, nausea, and diarrhea may occur. Aspiration may occur during
swallowing or vomiting resulting in lung damage.
Sensitization Properties: Unknown.
Chronic:
NIOSH has recommended that whole diesel exhaust be regarded as a potential

occupational carcinogen, based on findings of carcinogenic responses in
laboratory animals exposed to whole diesel exhaust. The excess cancer risk
for workers exposed to diesel exhaust has not been calculated; the
probability of developing cancer should be decreased by minimizing
exposure to the lowest feasible limits.
Repeated skin contact may cause a persistent irritation or dermatitis.

Medical Conditions Aggravated by Exposure: Skin contact may aggravate an

existing dermatitis (skin condition).
Other Remarks: None
4. FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes.
Hold eyelids apart while flushing to rinse entire surface of eye and lids
with water. Get medical attention.
Skin: Immediately remove contaminated clothing and shoes. Under a safety

shower, flush skin thoroughly with large amounts of running water for at
least 15 minutes. Do not attempt to neutralize with chemical agents. Get
medical attention immediately. Discard or decontaminate clothing and shoes
before reuse.
Ingestion: If person is conscious and can swallow, give two glasses of

water (16 oz.) but do not induce vomiting. If vomiting occurs, give fluids
again. Have medical personnel determine if evacuation of stomach or
induction of vomiting is necessary. Do not give anything by mouth to an
unconscious or convulsing person.
Inhalation: If inhaled, remove to fresh air. If not breathing, clear

person's airway and give artificial respiration. If breathing is
difficult, qualified medical personnel may administer oxygen. Get medical
attention immediately.
Other Instructions:
Remove and dry-clean or launder clothing soaked or soiled with this

material before reuse. Dry cleaning of contaminated clothing may be more
effective than normal laundering. Inform individuals responsible for
cleaning of potential hazards associated with handling contaminated
clothing.
Aspiration of this product during induced emesis may result in severe lung
injury. If evacuation of stomach is necessary, use method least likely to
cause aspiration, such as gastric lavage after endotracheal intubation.
Contact a Poison Center for additional treatment information.
Ignition Temperature - AIT (degrees F): 500
Flash Point (degrees F): 125 (CC)

Flammable Limits (%):

Lower: .5
Upper: 4.1
Recommended Fire Extinguishing Agents And Special Procedures: Use water

spray, dry chemical, foam or carbon dioxide to extinguish flames. Use
water spray to cool fire-exposed containers.
Unusual or Explosive Hazards: None
Special Protective Equipment for Firefighters: Wear full protective

clothing and positive pressure breathing apparatus.
(Transportation Spills: CHEMTREC (800) 424-9300)
Procedures in Case of Accidental Release, Breakage or Leakage:
Ventilate area. Avoid breathing vapor. Wear appropriate personal

protective equipment, including appropriate respiratory protection.
Contain spill if possible. Wipe up or absorb on suitable material and
shovel up. Prevent entry into sewers and waterways. Avoid contact with
skin, eyes or clothing.
If more than 100,000 pounds of product is spilled, then report spill

according to SARA 304 and/or CERCLA 102(a) requirements, unless product
qualifies for the petroleum exemption (CERCLA Section 101(14)).
Precautions to be Taken in
Handling: Eye wash and safety shower should be available nearby when this
product is handled or used.
Storage: Store away from heat and open flame. Periods of exposure to high
temperatures should be minimized. Water contamination should be avoided.
Protective Equipment (Type)
Eye/Face Protection: Safety glasses, chemical type goggles, or face shield

recommended to prevent eye contact.
Skin Protection: Protective clothing such as coveralls or lab coats should

be worn. Launder or dry-clean when soiled. Gloves resistant to chemicals

and petroleum distillates required. When handling large quantities,

impervious suits, gloves, and rubber boots must be worn.
Respiratory Protection: Airborne concentrations should be kept to lowest

levels possible. If vapor, mist or dust is generated and the occupational
exposure limit of the product, or any component of the product, is
exceeded, use appropriate NIOSH or MSHA approved air purifying or air
supplied respirator after determining the airborne concentration of the
contaminant. Air supplied respirators should always be worn when airborne
concentration of the contaminant or oxygen content is unknown.
Ventilation: Local exhaust ventilation recommended if generating vapor,

dust, or mist. If exhaust ventilation is not available or inadequate, use
MSHA or NIOSH approved respirator as appropriate.
Exposure Limit for Total Product: None established for product; refer to
Section 2 for component exposure limits.
Appearance: Bright and clear liquid (Tax Exempt Diesels - pale red liquid)
Boiling Point (degrees F): 650
Melting/Freezing point (degrees F): Not applicable.
Specific Gravity (water=1): .8521
pH of undiluted product: Not applicable.
Vapor Pressure: .07 - .3 mmHg at 100.0
Viscosity: 3 cSt at 37.7 C
VOC Content: Not determined.
Vapor Density (air=1): Not determined.
Solubility in Water (%): < .1
Other: None
This Material Reacts Violently With:

(If Others is checked below, see comments for details)

Air [ ]
Water [ ]
Heat [X]
Strong Oxidizers [X]
Others [ ]
None of These [ ]
Comments: None
Products Evolved When Subjected to Heat or Combustion: Toxic levels of

carbon monoxide, carbon dioxide, irritating aldehydes and ketones.
Hazardous Polymerizations: DO NOT OCCUR
TOXICOLOGICAL INFORMATION (ANIMAL TOXICITY DATA)
Median Lethal Dose
Oral: LD50 Similar product 9.00 ml/kg (rat) practically non-toxic
Inhalation: Not determined.
Dermal: LD50 Similar product > 5.00 ml/kg (rabbit) practically non-toxic
Irritation Index, Estimation of Irritation (Species)
Skin: (Draize) Similar product 5.29/8.0 (rabbit) severely irritating
Eyes: (Draize) Believed to be > 15.00 - 25.00/110 (rabbit) slightly

irritating
Sensitization: Not determined.
Other:
Middle distillates have caused skin irritation and skin cancer in

laboratory animals when repeatedly applied and left in place between
applications. Studies to further evaluate the carcinogenic potential of
middle distillates are currently underway. Kidney damage has also been
observed in laboratory animals exposed to middle distillates.
Necrosis was seen on animals a few days after dermal application of this
product or a component of this product. However, the skin repaired itself
within the observation period.

Waste Disposal Methods

This product (as presently constituted) has the RCRA classification of
benzene toxicity and ignitability. If discarded in its present form, it
would have the hazardous waste numbers D018 and D001 respectively. Under
RCRA, it is the responsibility of the user of the product to determine at
the time of disposal, whether the product meets RCRA criteria for
hazardous waste. This is because product uses, transformations, mixtures,
processes, etc. may change the classification to non-hazardous, or
hazardous for reasons other than, or in addition to benzene toxicity and
ignitability.
Remarks
None
Transportation
DOT:
Proper Shipping Name: Fuel Oil
Hazard Class: Combustible liquid (LAND TRANSPORT ONLY-49CFR 173.120(b)(2))
Identification Number: NA 1993
Packing Group: III
Label Required: None
Marine pollutant: Not applicable
IMDG:
Proper Shipping Name: Not evaluated
ICAO:
TDG:
Federal Regulations:
SARA Title III:
Section 302/304 Extremely Hazardous Substances
None

Section 302/304 Extremely Hazardous Substances (CONT)
Seq. TPQ RQ
None
Section 311 Hazardous Categorization:

Acute [X]
Chronic [X]
Fire [X]
Pressure [ ]
Reactive [ ]
N/A [ ]
Section 313 Toxic Chemical
Chemical Name CAS Number Concentration
None
CERCLA 102(a)/DOT Hazardous Substances:

(+ indicates DOT Hazardous Substance)
01+ Benzene, (1-methylethyl)- 98-82-8 0.01-0.09

02+ Benzene 71-43-2 0.01-0.09
CERCLA/DOT Hazardous Substances (Sequence Numbers and RQ's):
Seq. RQ
01+ 5000
02+ 10
TSCA Inventory Status: This product, or its components, are listed on or

are exempt from the Toxic Substance Control Act (TSCA) Chemical Substance
Inventory.
Other: None.
State Regulations:
California Proposition 65:
The following detectable components of this product are substances, or

belong to classes of substances, known to the State of California to cause
cancer and/or reproductive toxicity.

Chemical Name CAS Number
Benzene 71-43-2
States Right-to-know Regulations:
Chemical Name State Right-to-know
Benzene, (1-methylethyl)- CT, FL, IL, MA, NJ, PA, RI, MI

Benzene CT, FL, IL, MA, NJ, PA, RI, MI
1,2,4-trimethylbenzene MA, NJ, PA
State list: CT (Connecticut), FL (Florida), IL (Illinois), MI (Michigan),

LA (Louisiana), MA (Massachusetts), NJ (New Jersey), PA (Pennsylvania),
RI (Rhode Island)
International Regulations:
WHMIS Classification: Not determined
Canada Inventory Status: Not determined.
EINECS Inventory Status: Not determined.
Australia Inventory Status: Not determined.
Japan Inventory Status: Not determined.
15. ENVIRONMENTAL INFORMATION
Aquatic Toxicity: Not determined.
Mobility: Not determined.
Persistence and Biodegradability: Not determined.
Potential to Bioaccumulate: Not determined.
Remarks: None
THIS PRODUCT IS INTENDED FOR USE AS A MOTOR FUEL ONLY.
This product is not intended for use in space heaters. Do not use in
agricultural sprays.
Texaco recommends that all exposures to this product be minimized by

strictly adhering to recommended occupational controls procedures to avoid

any potential adverse health effects.
THE INFORMATION CONTAINED HEREIN IS BELIEVED TO BE ACCURATE. IT IS

PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUCT FOR PURPOSE OF HAZARD
COMMUNICATION AS PART OF TEXACO'S PRODUCT SAFETY PROGRAM. IT IS NOT
INTENDED TO CONSTITUTE PERFORMANCE INFORMATION CONCERNING THE PRODUCT. NO
EXPRESS WARRANTY, OR IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A
PARTICULAR PURPOSE IS MADE WITH RESPECT TO THE PRODUCT OR THE INFORMATION
CONTAINED HEREIN. DATA SHEETS ARE AVAILABLE FOR ALL TEXACO PRODUCTS. YOU
ARE URGED TO OBTAIN DATA SHEETS FOR ALL TEXACO PRODUCTS YOU BUY, PROCESS,
USE OR DISTRIBUTE AND YOU ARE ENCOURAGED AND REQUESTED TO ADVISE THOSE WHO
MAY COME IN CONTACT WITH SUCH PRODUCTS OF THE INFORMATION CONTAINED
HEREIN.
TO DETERMINE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH RESPECT

TO THE PRODUCT, USER SHOULD CONSULT HIS LEGAL ADVISOR OR THE APPROPRIATE
GOVERNMENT AGENCY. TEXACO DOES NOT UNDERTAKE TO FURNISH ADVICE ON SUCH
MATTERS.
Date: 04-15-96
[ ] New
[X] Revised, Supersedes: 03-20-96
Date printed: 04-19-96
Inquiries regarding MSDS should be directed to:

Texaco Inc.
Manager, Product Safety
P.O. Box 509
Beacon, N.Y. 12508
PLEASE SEE NEXT PAGE FOR PRODUCT LABEL
17. PRODUCT LABEL
Label Date: 03-20-96
READ AND UNDERSTAND MATERIAL SAFETY DATA SHEET BEFORE HANDLING OR

DISPOSING OF PRODUCT. THIS LABEL COMPLIES WITH THE REQUIREMENTS OF THE
OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200) FOR USE IN THE
WORKPLACE. THIS LABEL IS NOT INTENDED TO BE USED WITH PACKAGING INTENDED
FOR SALE TO CONSUMERS AND MAY NOT CONFORM WITH THE REQUIREMENTS OF THE
CONSUMER PRODUCT SAFETY ACT OR OTHER RELATED REGULATORY REQUIREMENTS.
26120 DIESEL 2

WARNING STATEMENT
WARNING!
USE ONLY AS A FUEL
ATTENTION!
PRECAUTIONARY MEASURES
-Use only with adequate ventilation.
-Keep away from heat and flame.
-Avoid breathing vapor, mist, or gas.
-Avoid contact with eyes, skin, and clothing.
-Keep container closed.
-Never siphon by mouth.
-Wash thoroughly after handling.
FIRST AID
Eye Contact: Immediately flush eyes with plenty of water for at least 15
minutes. Hold eyelids apart while flushing to rinse entire surface of eye
and lids with water. Get medical attention.
Skin Contact: Immediately remove contaminated clothing and shoes. Under a

safety shower, flush skin thoroughly with large amounts of running water
for at least 15 minutes. Do not attempt to neutralize with chemical
agents. Get medical attention immediately. Discard or decontaminate
clothing and shoes before reuse.


Note to Physician: Aspiration of this product during induced emesis may

result in severe lung injury. If evacuation of stomach is necessary, use

method least likely to cause aspiration, such as gastric lavage after
endotracheal intubation. Contact a Poison Center for additional treatment
information.
FIRE
In case of fire, use water spray, dry chemical, foam or carbon dioxide.
Water may cause frothing. Use water spray to cool fire-exposed containers.

Chemical Name CAS Number Range in %
* A complex mixture of hydrocarbons produced 100.00

by crude oil distillation. Consists
predominantly of hydrocarbons ranging from
C-9 to C-20, and boiling in the range of
hydrosulfurized product also contains some
hydrocarbons produced by the distillation
of the catalytic cracking. The latter
materials contain bicyclic and tricyclic
Pennsylvania Special
Hazardous Substance(s) CAS Number Range in %
Benzene 71-43-2 0.01-0.09
HMIS
Health: 1
Flammability: 2
Reactivity: 0
Special: -
NFPA
Health: 1
Flammability: 2
Reactivity: 0
Special: -

Transportation
DOT:
Packing Group: III
CAUTION: Misuse of empty containers can be hazardous. Empty containers can

be hazardous if used to store toxic, flammable, or reactive materials.
Cutting or welding of empty containers might cause fire, explosion or
toxic fumes from residues. Do not pressurize or expose to open flame or
heat. Keep container closed and drum bungs in place.

P.O. Box 7812
TRANSPORTATION EMERGENCY
Company: (914) 831-3400
CHEMTREC: (800) 424-9300
HEALTH EMERGENCY
Company: (914) 831-3400

Sheet No: SSR2104 Material Name: Dual Purpose Kerosene Issue Date : 02/03/95 Revision of Sheet Dated:01/09/94 Page:

___________________________________________________________________________
Dual Purpose Kerosene

Dual Purpose Kerosene
Application
Fuel for domestic burners; low sulphur industrial process fuel; solvent for certain industrial processes. Only Premium grade
should be used as fuel for flueless space heaters.
For specific application advice see appropriate Technical Data Sheet or consult your SRC representative
Singapore Refining Company Pte. Ltd.
Pulau Merlimau
Jurong
Singapore

Singapore 867 8844
__________________________________________________________________________________
Petroleum distillate
__________________________________________________________________________________
Flammable
Will be irritating to the skin.
__________________________________________________________________________________
Eyes
Wash eye thoroughly with copious quantities of water, ensuring eyelids are held open. Obtain medical advice if any pain or
redness develops or persists.
Skin
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Ingestion
Inhalation
If fumes are inhaled the patient should be removed to fresh air and if recovery is not immediate, medical assistance must be
called without delay. If breathing has failed respiration must be assisted, preferably by mouth to mouth method.
Medical Advice
Monitor for cardiac disrhythmias.
__________________________________________________________________________________
Water may be used to cool nearby heat exposed areas/objects/packages. Avoid spraying directly into storage containers
Combustion Products
__________________________________________________________________________________
In the event of spillage, remove all sources of ignition including road traffic and ensure good ventilation.
It is advised that stocks of suitable absorbent material should be held in quantities sufficient to deal with any spillage which
may be reasonably anticipated.

authorities.
__________________________________________________________________________________
Storage Conditions
quick rescue.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. These can cause flammability/explosion hazards even at
temperatures below the normal flash point (note: flash point must not be regarded as a reliable indicator of the potential
storage tanks.
Product soaked rags, paper or material used to absorb spillages, represent a fire hazard, and should not be allowed to
__________________________________________________________________________________
Exposure Limits
Comply with current local occupational exposure limit.
Protective Clothing
starched after use.

Change heavily contaminated clothing as soon as reasonably practicable; dry clean, launder and preferably starch before re-
use. Wash any contaminated underlying skin with soap and water.
__________________________________________________________________________________
Typical Values
Grades:Dual Purpose Kerosene
Test Method Units
Colour light amber
Odour kerosine-like
Boiling point/range ASTM D 86 °C 150-
300
Kinematic viscosity @ 20°C ASTM D 445 mm /s2 2.0
Flash point (PMC) ASTM D 93 °C 50
Conditions to Avoid
Sources of ignition
Materials to Avoid

Thermal decomposition can produce a variety of compounds, the precise nature of which will depend on the decomposition
conditions.
Incomplete combustion/ thermal decomposition will generate smoke, carbon dioxide and hazardous gases,which will
include carbon monoxide.
__________________________________________________________________________________
Eyes
Skin
Unlikely to cause sensitization by skin contact

Ingestion
Inhalation
__________________________________________________________________________________
Mobility

Aquatic toxicity
May be harmful to aquatic organisms.
__________________________________________________________________________________

__________________________________________________________________________________
EC Labelling
FLAMMABLE - (No symbol)
Symbol: St Andrews Cross (Xn)

Contains Kerosine- unspecified
Risk (R) Phrases

R10 - Flammable
R22 - Harmful if swallowed

Safety (S) Phrases

S43 In case of fire use foam, dry powder or water fog. DO NOT USE water jets.
S62 - If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
__________________________________________________________________________________
Compiled by:
Chertsey Road
Sunbury-On-Thames
Middlesex, TW16 7LN
specified below. We have reviewed the information contained herein which we received from sources outside SRC .
However, no warranty or representation, expressed or implied is made as to the accuracy or completeness of the data and
information contained in this data sheet.
given or implied to practise any patented invention without a valid licence. SRC shall not be responsible for any damage or
injury resulting from abnormal use of the material, from any failure to adhere to recommendations, or from any hazards
inherent in the nature of the material

Sheet No: SAV2304 Material Name: Experimental Jet Fuel Additive (HiTTS) Issue Date : 9/6/99 Revision of Sheet Dated: Page:
SAFETY DATA SHEET

___________________________________________________________________________
Experimental Jet Fuel Additive (HiTTS)

Experimental Jet Fuel Additive (HiTTS)
Application
Experimental jet fuel additive.
Breakspear Park
Breakspear Way
Hemel Hempstead
Hertfordshire
HP2 4UL

+44 (0)1442-22-5711

+44 (0)1202 590558
__________________________________________________________________________________
Kerosine
Proprietary performance additives.
Kerosine - unspecified, Xn, R65 Harmful: may cause lung damage if swallowed. (>40%)
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2,6 - Di-tert - Butyl - 4 -Methylphenol, Xn R22 Harmful if swallowed, R36 Irritating to eyes. (<20%)
N, N' - disalicylidene - 1,2 - diaminopropane, Xn R22 Harmful if swallowed, R36/38 Irritating to eyes and skin., R43 May
cause sensitisation by skin contact, R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment (<10%)
__________________________________________________________________________________
This product is supplied for trial/research purposes only.
The hazard assessment has not been completed, the product should therefore be handled with care and exposure
kept to a minimum.

Likely to cause eye irritation.
May cause sensitisation by skin contact.
__________________________________________________________________________________
Eyes
Skin
Ingestion
Inhalation
Medical Advice
vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal intubation.
Monitor for cardiac dysrhythmias.
__________________________________________________________________________________
Fires in confined spaces should be dealt with by trained personnel wearing approved breathing apparatus
Combustion Products

__________________________________________________________________________________
In the case of large spills contact the appropriate authorities.
__________________________________________________________________________________
Avoid skin contact.
Ensure good ventilation and avoid as far as reasonably practicable the inhalation and contact with vapours, mists or fumes
which may be generated during use. If such vapour, mists or fumes are generated, their concentration in the workplace air
should be controlled to the lowest reasonably practicable level.
Fire Prevention
Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be allowed to
Storage Conditions
quick rescue.
__________________________________________________________________________________
Exposure Limits

Protective Clothing
starched after use.
__________________________________________________________________________________
Typical Values
Grades :Experimental Jet

Fuel Additive (HiTTS)
Test Method Units

Physical state low viscosity liquid
Colour dark brown
Odour kerosine-like
Kinematic viscosity @ ASTM D 445 mm2/s 5

40°C

Conditions to Avoid
Materials to Avoid


__________________________________________________________________________________
Eyes
Likely to cause eye irritation.
Skin
May cause sensitization by skin contact.
Ingestion
Inhalation
__________________________________________________________________________________
Mobility

Aquatic toxicity
__________________________________________________________________________________
Dispose of product and container carefully and responsibly. Do not dispose of near ponds, ditches, down drains or onto
soil.
__________________________________________________________________________________
__________________________________________________________________________________

Harmful
Irritant
EU Labelling
Symbol: St. Andrew's Cross,
Indication of danger: HARMFUL,
Contains: Kerosine - unspecified

N,N' - disalicylidene - 1,2 - diaminopropane
2,6 - Di-tert - Butyl - 4 -Methylphenol
Risk ( R ) Phrases:
R43 May cause sensitisation by skin contact
R36 Irritating to eyes.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S28 After contact with skin wash immediately with plenty of soap and water
__________________________________________________________________________________
Compiled by:
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
Amoco Group of Companies. However, no warranty or representation, express or implied is made as to the accuracy or
given or implied to practise any patented invention without a valid licence. The BP Amoco Group shall not be responsible
for any damage or injury resulting from abnormal use of the material, from any failure to adhere to recommendations, or
from any hazards inherent in the nature of the material.

Sheet No: STI2102 Material Name: Gasoline: Leaded Grades Issue Date : 17/07/2000 Revision of Sheet Dated:02/11/98 Page:
ALIGN BP SDS Finals


Material Name: Gasoline: Leaded Grades
________________________________________________________________________________
SAFETY DATA SHEET
Gasoline: Leaded Grades

COMPANY/UNDERTAKING
Gasoline: Leaded Grades
Alternative Names: Leaded Gasoline, premium and regular
Leaded Motor Gasoline, Leaded Motor Spirit, Leaded Petrol
Application
cleaning agent.
Britannic House
1 Finsbury Circus
London, EC2M 7BA

+44 (0) 20 7496 4411
_________________________________________________________________________________
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(>90%)
_________________________________________________________________________________
_________________________________________________________________________________
Eyes
Skin
Ingestion
Inhalation

Medical Advice
_________________________________________________________________________________
Combustion Products
_________________________________________________________________________________
etc.).

_________________________________________________________________________________

Storage Conditions


Fire Prevention
_________________________________________________________________________________

Exposure Limits
Gasoline
Benzene
Protective Clothing

_________________________________________________________________________________

Typical Values
Grades: Gasoline:
Leaded
Grades
Test Method Units
Colour light amber
Odour gasoline-like
air D2463/D2421
Kinematic viscosity @ mm²/s <1
20°C
_________________________________________________________________________________

Conditions to Avoid
Sources of ignition
Materials to Avoid

_________________________________________________________________________________
Eyes

Skin
Ingestion
diarrhoea.
Inhalation
ABUSE:
leukaemia.
_________________________________________________________________________________
Mobility

Aquatic toxicity
impaired.
_________________________________________________________________________________
local regulations.
_________________________________________________________________________________


_________________________________________________________________________________
Extremely flammable
Harmful
Irritant
EU Labelling
Symbol:
Flame
EXTREMELY FLAMMABLE
Contains:
Risk ( R ) Phrases:
_________________________________________________________________________________
Compiled by:


Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
Sheet Revisions
08/5/98 2, 7, 8, 12, 15
02/11/98 1
17/07/2000 2, 3, 4, 7, 8, 9, 13, 15
SHEET NO: STI2102

______________________________________________________________________________

Sheet No: STI2103 Material Name: Gasoline: Unleaded Grades Issue Date : 17/07/2000 Revision of Sheet Dated:02/11/98 Page:
ALIGN BP SDS Finals


Material Name: Gasoline: Unleaded Grades
________________________________________________________________________________
SAFETY DATA SHEET
Gasoline: Unleaded Grades

COMPANY/UNDERTAKING
Gasoline: Unleaded Grades
Alternative Names: Unleaded Gasoline, Motor gasoline, Motor Spirit, Petrol
Application
cleaning agent.
Britannic House
1 Finsbury Circus
London, EC2M 7BA

+44 (0) 20 7496 4411
_________________________________________________________________________________

(>90%)
_________________________________________________________________________________
_________________________________________________________________________________
Eyes
Skin
Ingestion
Inhalation
Medical Advice


_________________________________________________________________________________
Combustion Products
_________________________________________________________________________________
etc.).

_________________________________________________________________________________

Storage Conditions

Fire Prevention
_________________________________________________________________________________

Exposure Limits
Gasoline
Benzene
Protective Clothing

_________________________________________________________________________________

Typical Values
Grades: Gasoline:
Unleaded
Grades
Test Method Units
Colour light amber
Odour gasoline-like
air D2463/D2421
Kinematic viscosity @ mm²/s <1
20°C
Boiling point/range °C 25 - 220
_________________________________________________________________________________

Conditions to Avoid
Sources of ignition
Materials to Avoid

_________________________________________________________________________________
Eyes
Skin

Ingestion
diarrhoea.
Inhalation
ABUSE:
leukaemia.
_________________________________________________________________________________
Mobility

Aquatic toxicity
impaired.
_________________________________________________________________________________
local regulations.
_________________________________________________________________________________


_________________________________________________________________________________
Extremely flammable
Harmful
Irritant
EU Labelling
Symbol:
Flame
EXTREMELY FLAMMABLE
Contains:
Risk ( R ) Phrases:
_________________________________________________________________________________
Compiled by:
Chertsey Road
Sunbury-on-Thames

Middlesex, TW16 7LN
Sheet Revisions
07/05/98 1, 2, 7, 8, 10, 12, 15
02/11/98 1
17/07/2000 2, 3, 4, 8, 9, 15
SHEET NO: STI2103

______________________________________________________________________________

Sheet No: STI2213 Material Name: Hydrocarbon Condensate Issue Date : 17/07/2000 Revision of Sheet Dated:17/09/98 Page:
ALIGN BP SDS Finals


Material Name: Hydrocarbon Condensate
________________________________________________________________________________
SAFETY DATA SHEET
Hydrocarbon Condensate
COMPANY/UNDERTAKING
Hydrocarbon Condensate
Alternative Names: Natural gas condensate
Application
Refinery feedstock
Britannic House
1 Finsbury Circus
London, EC2M 7BA

+44 (0) 20 7496 4411
_________________________________________________________________________________
Natural gas condensates (petroleum) EINECS No: 265-047-3, CAS No: 64741-47-5
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_________________________________________________________________________________
Eyes
Skin
Ingestion
Inhalation
Medical Advice

develops.
_________________________________________________________________________________
Combustion Products
_________________________________________________________________________________
etc.).

_________________________________________________________________________________

Storage Conditions

Fire Prevention
_________________________________________________________________________________

Exposure Limits
Gasoline
Benzene

Hydrogen sulphide
Protective Clothing
_________________________________________________________________________________

Typical Values
Grades: Hydrocarbon
Condensate
Test Method Units
Colour amber
Odour gasoline-like
Kinematic viscosity @ mm²/s 0.64 - 3.09
20°C
Boiling point/range °C <0 - >500
_________________________________________________________________________________

Conditions to Avoid
Sources of ignition
Materials to Avoid


_________________________________________________________________________________
Eyes
Skin
Ingestion
diarrhoea.
Inhalation
ABUSE:
leukaemia.
_________________________________________________________________________________
Mobility

Aquatic toxicity
impaired.

_________________________________________________________________________________


local regulations.
_________________________________________________________________________________
_________________________________________________________________________________
Extremely flammable
Harmful
Irritant
EU Labelling
Symbol:
Flame
Dead tree and fish
EXTREMELY FLAMMABLE
Risk ( R ) Phrases:

Substance name: Natural gas condensates (petroleum), EINECS No: 265-047-3
_________________________________________________________________________________
Compiled by:
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
Sheet Revisions
17/09/98 1, 3, 4, 7, 8, 10, 11, 12, 14, 15
17/07/2000 3, 4, 9, 15
SHEET NO: STI2213

______________________________________________________________________________

Sheet No: STI2221 Material Name: Hydrocracked Gas Oils Issue Date : 17/07/2000 Revision of Sheet Dated:11/09/98 Page:
ALIGN BP SDS Finals


Material Name: Hydrocracked Gas Oils
________________________________________________________________________________
SAFETY DATA SHEET
Hydrocracked Gas Oils

COMPANY/UNDERTAKING
Hydrocracked Gas Oils
Application
Refinery stream
Britannic House
1 Finsbury Circus
London, EC2M 7BA

+44 (0) 20 7496 4411
_________________________________________________________________________________
Distillates (petroleum), light hydrocracked. EINECS No: 265-078-2, CAS No: 64741-77-1

_________________________________________________________________________________
Eyes
Skin
Ingestion
Inhalation
Medical Advice
_________________________________________________________________________________
Combustion Products
_________________________________________________________________________________

etc.).

_________________________________________________________________________________

Storage Conditions
Fire Prevention


_________________________________________________________________________________

Exposure Limits
Protective Clothing
_________________________________________________________________________________

Typical Values
Grades: Hydrocracked
Gas Oils
Test Method Units
Colour colourless
Odour gasoil-like
40°C
_________________________________________________________________________________


Conditions to Avoid
Sources of ignition
Materials to Avoid

_________________________________________________________________________________
Eyes
Skin
dermatitis.
Ingestion
diarrhoea.
Inhalation
_________________________________________________________________________________
Mobility

Aquatic toxicity
impaired.
_________________________________________________________________________________


_________________________________________________________________________________
_________________________________________________________________________________
Harmful
EU Labelling
Symbol:
St. Andrew's Cross
Dead tree and fish
HARMFUL
Risk ( R ) Phrases:
Substance name: Distillates (petroleum), light hydrocracked, EINECS No: 265-078-2
_________________________________________________________________________________
Compiled by:
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN

Sheet Revisions
11/09/98 1, 3, 12, 15
17/07/2000 3, 4, 15
SHEET NO: STI2221

______________________________________________________________________________

Sheet No: SAV2101 Material Name: Jet A-1
ALIGN BP SDS Finals


Material Name: Jet A-1
Jet A-1 containing FSII
Hazardous Components: Physical Characteristics: Gasoline Tox File: 346.7, 346.15 Product Group:
________________________________________________________________________________
SAFETY DATA SHEET
Jet A-1
COMPANY/UNDERTAKING
Jet A-1
Alternative Names: Aviation Kerosine, Aviation Turbine Fuel, ATK
Jet A-1 synonyms: Jet A, AVTUR, F-35,
Jet A-1 containing FSII synonyms: AVTUR/FSII, JP-8, F-34,
Application
Jet fuel
Breakspear Park
Breakspear Way
Hemel Hempstead
Hertfordshire
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HP2 4UL

+44 (0) 1442-22-5711

+44 (0) 1202 590558
_________________________________________________________________________________
Jet A-1 containing FSII - Contains small amounts of diethyleneglycol monomethyl ether
(DEGME
2-(2-methoxyethoxy)ethanol ) as a fuel icing inhibitor.
Xn R10 Flammable
(>90%)
_________________________________________________________________________________
Flammable
_________________________________________________________________________________
Eyes
Skin
Ingestion
Inhalation

Medical Advice
_________________________________________________________________________________
Use foam
Combustion Products
_________________________________________________________________________________
section 8
in basements etc.).

_________________________________________________________________________________

Storage Conditions
the safe handling
Avoid
drink or smoke.
Fire Prevention
cut
weld
_________________________________________________________________________________

Exposure Limits
If vapour
Protective Clothing
_________________________________________________________________________________

Typical Values
Grades: Jet A-1
Jet A-1 (FSII)
Test Method Units
liquid
yellow
Odour kerosine-like
Kinematic viscosity @ - mm²/s 3.5
20°C
_________________________________________________________________________________

Conditions to Avoid
Sources of ignition
Materials to Avoid


_________________________________________________________________________________
Eyes
mists or fumes.
Skin
Ingestion
Inhalation
mists or fumes.
_________________________________________________________________________________
Mobility

Aquatic toxicity
impaired.
_________________________________________________________________________________
ditches
At sea

_________________________________________________________________________________
ADR/RID: Kerosene
Flammable Liquid
Class 3
Item 31 (c)
UN: KEROSENE
Flammable liquid
Class 3
Packing Group III
UN Number 1223
IATA/ICAO: Kerosene
Flammable liquid
Class 3
Packing Group III
IMO: KEROSENE
Flammable liquid
Class 3.3
Packing Group III
3[Y]
_________________________________________________________________________________
Flammable
Harmful
Irritant
EU Labelling
Symbol:
St. Andrew's Cross
HARMFUL
Contains:
Risk ( R ) Phrases:
R10 Flammable
S43 In case of fire
S62 If swallowed

_________________________________________________________________________________
Compiled by:
Chertsey Road
Sunbury-on-Thames
Middlesex
TW16 7LN

Companies. However
sheet.
______________________________________________________________________________

Sheet No: STI2104 Material Name: Kerosene: Regular and Premium Grades Issue Date : 17/07/2000 Revision of Sheet Dated:02/11/98 Page:
ALIGN BP SDS Finals


Material Name: Kerosene: Regular and Premium Grades
________________________________________________________________________________
SAFETY DATA SHEET
Kerosene: Regular and Premium Grades

COMPANY/UNDERTAKING
Kerosene: Regular and Premium Grades
Alternative Names: Paraffin, Kerosine, Lamp Oil
Application
Fuel for domestic burners; low sulphur industrial process fuel; solvent for certain industrial processes. Premium grade
only can be used as fuel for flueless space heaters.
Britannic House
1 Finsbury Circus
London, EC2M 7BA

+44 (0) 20 7496 4411
_________________________________________________________________________________
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Kerosine - unspecified, Xn R10 Flammable, R38 Irritating to skin, R65 Harmful: may cause lung damage if swallowed.
_________________________________________________________________________________
Flammable
_________________________________________________________________________________
Eyes
Skin
Ingestion
Inhalation
If fumes are inhaled the patient should be removed to fresh air and if recovery is not immediate, medical assistance
must be called without delay. If breathing has failed respiration must be assisted, preferably by mouth to mouth
method.
Medical Advice
_________________________________________________________________________________
Combustion Products
_________________________________________________________________________________


etc.).
_________________________________________________________________________________

Storage Conditions
Fire Prevention

_________________________________________________________________________________

Exposure Limits
Protective Clothing
_________________________________________________________________________________

Typical Values
Grades: Kerosene:
Regular and
Premium
Grades
Test Method Units
Colour light amber
Odour kerosine-like
20°C
_________________________________________________________________________________


Conditions to Avoid
Sources of ignition
Materials to Avoid

_________________________________________________________________________________
Eyes
Skin
Ingestion
diarrhoea.
Inhalation
_________________________________________________________________________________
Mobility

Aquatic toxicity
impaired.
_________________________________________________________________________________


onto soil.
facilities.
_________________________________________________________________________________
_________________________________________________________________________________
Flammable
Harmful
Irritant
EU Labelling
Symbol:
St. Andrew's Cross
HARMFUL
Contains:
Risk ( R ) Phrases:
R10 Flammable
_________________________________________________________________________________
Compiled by:
Chertsey Road

Sunbury-on-Thames
Middlesex, TW16 7LN
Sheet Revisions
08/05/98 2, 12, 15
02/11/98 1
17/07/2000 2, 15
SHEET NO: STI2104

______________________________________________________________________________

Sheet No: SUK2104 Date: 07/01/98 Revision of Sheet Dated: 01/09/94 (FMSL02) Name of Product: Leaded 4 Star petrol
SAFETY DATA SHEET

___________________________________________________________________________
BP Leaded 4 Star petrol

This safety data sheet covers:
Leaded Gasoline
Leaded motor gasoline
Leaded Motor Spirit
PMS (Premium Motor Spirit)
Premium Grade UK
BP Super
97 Octane (RON)
National
Application
Use only as a motor fuel for spark ignition engines. NOT for aviation use. Should NOT be used as a solvent nor cleaning
agent.
BP Oil UK Limited,
Witan Gate House
500-600 Witan Gate
MK9 1ES

01908 853000
__________________________________________________________________________________
A complex mixture of volatile hydrocarbons containing paraffins, naphthenes, olefins and aromatics with carbon numbers
predominantly between C4 and C12.
Benzene, EINECS No. 200-753-7, CAS No. 71-43-2 F, T, R45 May cause cancer, R11 Highly flammable, R48/23/24/25
Toxic: Danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if
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swallowed
Gasoline. EINECS No: 289-220-8, CAS No: 86290-81-5 F+, T, N, R12 Extremely flammable, R45 May cause cancer,
R38 Irritating to skin, R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment,
R65 Harmful: may cause lung damage if swallowed. (>90%)
__________________________________________________________________________________
Contains Benzene. Prolonged or repeated exposure to benzene can cause anaemia and other blood diseases, including
leukaemia.
__________________________________________________________________________________
Eyes
Skin
In extreme situations of saturation with this product, drench with water, remove clothing as soon as possible and wash skin
with soap and water. Seek medical advice if skin becomes red, swollen or painful.
Ingestion
Inhalation
Medical Advice
__________________________________________________________________________________


Combustion Products
__________________________________________________________________________________

In the event of spillages contact the appropriate authorities. If spillage occurs call the Environment Agency Emergency
__________________________________________________________________________________
Storage Conditions
quick rescue.
Special health precautions must be taken during cleaning or maintenance operations on storage tanks which may have

contained leaded product at any time.
Fire Prevention
If product comes into contact with hot surfaces, or leaks occur from pressurised fuel pipes, the vapour or mists generated
will create a flammability or explosion hazard.
__________________________________________________________________________________
Exposure Limits
Gasoline
ACGIH (USA) :
TLV 300 ppm, 890 mg/m3 (8hr TWA)
500 ppm, 1480 mg/m3 (15min STEL)
Benzene
Maximum Exposure Limit Long-term exposure limit (8-hr TWA) 5ppm, 16mg/m3
Protective Clothing
starched after use.

__________________________________________________________________________________
Typical Values
Grades:Leaded 4 Star petrol
Test Method Units
Colour light amber
Odour gasoline-like
Density @ 15°C ASTM D 1298 kg/m3 695 - 790
Vapour pressure @ 37.8°C ASTM D 323 kPa 45 - 115
(100°F)
Vapour density rel. to air ASTM 3-4
D2463/D2421
Flash point (COC) ASTM D 92 °C <-40
Partition Coefficient (n- Log10Pow >3
octanol/water)

Conditions to Avoid
Sources of ignition
Materials to Avoid

__________________________________________________________________________________
Eyes

Skin
Ingestion
Inhalation
ABUSE:
Carcinogenicity/ Chronic Toxicity

leukaemia.
__________________________________________________________________________________
Mobility

Aquatic toxicity
Toxic to aquatic organisms. May cause long term effects in the aquatic environment

__________________________________________________________________________________
Materials contaminated with product should be treated as highly flammable. Disposal should be in accordance with local
regulations.
__________________________________________________________________________________


__________________________________________________________________________________
Extremely flammable
Irritant
Harmful
EU Labelling
Contains: Low boiling point naphtha - unspecified
Risk ( R ) Phrases:
__________________________________________________________________________________
Compiled by:
Chertsey Road

Sunbury-on-Thames
Middlesex, TW16 7LN

file:///C|/Documents%20and%20Settings/lanewg/My%20Documents/D...A%20Amendments/MSDS/White%20Oil/Low%20Sulfur%20Diesel%202.htm

Date Issued: 04-15-96
Supersedes: 03-20-96
STAR Enterprise
TEXACO
NOTE: Read and understand Material Safety Data Sheet before handling or
disposing of product.
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
MATERIAL IDENTITY
Product Code and Name: 00429 LOW SULFUR DIESEL 2
Chemical Name and/or Family or Description: Diesel Fuel

P.O. Box 7812
Telephone Numbers:
Transportation Emergency -Company : (914) 831-3400
CHEMTREC : (800) 424-9300
Health Emergency -Company : (914) 831-3400
General MSDS Assistance : (914) 838-7204
Technical Information -Fuels : (914) 838-7336
-Chemical : (512) 459-6543
-Lubricant/Antifreezes : (800) 782-7852
-Additives : (713) 235-6278
-Solvents : (800) 876-3738
THE CRITERIA FOR LISTING COMPONENTS IN THE COMPOSITION SECTION IS AS

FOLLOWS: CARCINOGENS ARE LISTED WHEN PRESENT AT 0.1% OR GREATER;
COMPONENTS WHICH ARE OTHERWISE HAZARDOUS ACCORDING TO OSHA ARE LISTED WHEN
PRESENT AT 1.0% OR GREATER; NON-HAZARDOUS COMPONENTS ARE LISTED AT 3.0% OR
GREATER. THIS IS NOT INTENDED TO BE A COMPLETE COMPOSITIONAL DISCLOSURE.
REFER TO SECTION 14 FOR APPLICABLE STATES' RIGHT TO KNOW AND OTHER
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REGULATORY INFORMATION.
Product and/or Component(s) Carcinogenic According to:

OSHA [ ]
IARC [ ]
NTP [ ]
OTHER [X]
NONE [ ]
Composition: (Sequence Number and Chemical Name)
01 * A complex mixture of hydrocarbons 100.00

produced by crude oil distillation.
Consists predominantly of
hydrocarbons ranging from C-9 to
C-20, and boiling in the range of
hydrosulfurized product also
contains some hydrocarbons produced
by the distillation of the catalytic
cracking. The latter materials
contain bicyclic and tricyclic
Exposure Limits referenced by Sequence Number in the Composition Section
Seq. Limit
None
EMERGENCY OVERVIEW
Appearance: Liquid
N.D. - NOT DETERMINED

N.A. - NOT APPLICABLE
N.T. - NOT TESTED
< - LESS THAN

> - GREATER THAN
WARNING STATEMENT
WARNING!
USE ONLY AS A FUEL
ATTENTION!
HMIS
Health: 1
Flammability: 2
Reactivity: 0
Special: -
NFPA
Health: 1
Flammability: 2
Reactivity: 0
Special: -
POTENTIAL HEALTH EFFECTS
Primary Route of Exposure:

EYE [X]
SKIN [X]
INHALATION [X]
INGESTION [ ]
Acute:
Eyes: May cause irritation, experienced as mild discomfort and seen as

slight excess redness of the eye.
Skin:
Causes irritation with discomfort or pain, and seen as marked local

redness and swelling, with possible blister formation.

Other than the potential skin irritation effects noted above, acute (short
term) adverse effects are not expected from brief skin contact; see other
effects, below, and Section 11 for information regarding potential long
term effects.
Prolonged, widespread, or repeated skin contact may result in the

absorption of potentially harmful amounts of material.
Inhalation:
Vapors or mist may cause irritation of the nose and throat.
Inhalation may cause dizziness, drowsiness, euphoria, loss of

coordination, disorientation, headache, nausea, and vomiting. In poorly
ventilated areas or confined spaces, unconsciousness and asphyxiation may
result. Prolonged or repeated overexposure may result in the absorption of
potentially harmful amounts of material.
Ingestion: If more than several mouthfuls are swallowed, abdominal

discomfort, nausea, and diarrhea may occur. Aspiration may occur during
swallowing or vomiting resulting in lung damage.
Sensitization Properties: Unknown.
Chronic:
NIOSH has recommended that whole diesel exhaust be regarded as a potential

occupational carcinogen, based on findings of carcinogenic responses in
laboratory animals exposed to whole diesel exhaust. The excess cancer risk
for workers exposed to diesel exhaust has not been calculated; the
probability of developing cancer should be decreased by minimizing
exposure to the lowest feasible limits.
Repeated skin contact may cause a persistent irritation or dermatitis.
Medical Conditions Aggravated by Exposure: Skin contact may aggravate an

existing dermatitis (skin condition).
Other Remarks: None
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes.
Hold eyelids apart while flushing to rinse entire surface of eye and lids
with water. Get medical attention.
Skin: Immediately remove contaminated clothing and shoes. Under a safety

shower, flush skin thoroughly with large amounts of running water for at
least 15 minutes. Do not attempt to neutralize with chemical agents. Get
medical attention immediately. Discard or decontaminate clothing and shoes
before reuse.


Other Instructions:
Remove and dry-clean or launder clothing soaked or soiled with this

material before reuse. Dry cleaning of contaminated clothing may be more
effective than normal laundering. Inform individuals responsible for
cleaning of potential hazards associated with handling contaminated
clothing.
Aspiration of this product during induced emesis may result in severe lung
injury. If evacuation of stomach is necessary, use method least likely to
cause aspiration, such as gastric lavage after endotracheal intubation.
Contact a Poison Center for additional treatment information.
Ignition Temperature - AIT (degrees F): 500
Flash Point (degrees F): 125 (CC)
Flammable Limits (%):

Lower: .5
Upper: 4.1
Recommended Fire Extinguishing Agents And Special Procedures: Use water

spray, dry chemical, foam or carbon dioxide to extinguish flames. Use
water spray to cool fire-exposed containers.
Unusual or Explosive Hazards: None
Special Protective Equipment for Firefighters: Wear full protective

clothing and positive pressure breathing apparatus.

(Transportation Spills: CHEMTREC (800) 424-9300)
Procedures in Case of Accidental Release, Breakage or Leakage:
Ventilate area. Avoid breathing vapor. Wear appropriate personal

protective equipment, including appropriate respiratory protection.
Contain spill if possible. Wipe up or absorb on suitable material and
shovel up. Prevent entry into sewers and waterways. Avoid contact with
skin, eyes or clothing.

Precautions to be Taken in
Handling: Eye wash and safety shower should be available nearby when this
product is handled or used.
Storage: Store away from heat and open flame. Periods of exposure to high
temperatures should be minimized. Water contamination should be avoided.
Protective Equipment (Type)
Eye/Face Protection: Safety glasses, chemical type goggles, or face shield

recommended to prevent eye contact.
Skin Protection: Protective clothing such as coveralls or lab coats should

be worn. Launder or dry-clean when soiled. Gloves resistant to chemicals
and petroleum distillates required. When handling large quantities,
impervious suits, gloves, and rubber boots must be worn.
Respiratory Protection: Airborne concentrations should be kept to lowest

levels possible. If vapor, mist or dust is generated and the occupational
exposure limit of the product, or any component of the product, is
exceeded, use appropriate NIOSH or MSHA approved air purifying or air
supplied respirator after determining the airborne concentration of the
contaminant. Air supplied respirators should always be worn when airborne
concentration of the contaminant or oxygen content is unknown.
Ventilation: Local exhaust ventilation recommended if generating vapor,

dust, or mist. If exhaust ventilation is not available or inadequate, use

MSHA or NIOSH approved respirator as appropriate.
Exposure Limit for Total Product: None established for product; refer to
Section 2 for component exposure limits.
Appearance: Liquid
Boiling Point (degrees F): 650
Melting/Freezing point (degrees F): Not applicable.
Specific Gravity (water=1): .8521
pH of undiluted product: Not applicable.
Vapor Pressure: .07 - .3 mmHg at 100.0
Viscosity: 3 cSt at 37.7 C
VOC Content: Not determined.
Vapor Density (air=1): Not determined.
Solubility in Water (%): < .1
Other: None
This Material Reacts Violently With:

(If Others is checked below, see comments for details)
Air [ ]
Water [ ]
Heat [ ]
Strong Oxidizers [X]
Others [ ]
None of These [ ]
Comments: None
Products Evolved When Subjected to Heat or Combustion: Toxic levels of

carbon monoxide, carbon dioxide, irritating aldehydes and ketones.

Hazardous Polymerizations: DO NOT OCCUR
TOXICOLOGICAL INFORMATION (ANIMAL TOXICITY DATA)
Median Lethal Dose
Oral: LD50 Similar product 9.00 ml/kg (rat) practically non-toxic
Inhalation: Not determined.
Dermal: LD50 Similar product > 5.00 ml/kg (rabbit) practically non-toxic
Irritation Index, Estimation of Irritation (Species)
Skin: (Draize) Similar product 5.29/8.0 (rabbit) severely irritating
Eyes:
(Draize) Believed to be > 15.00 - 25.00/110 (rabbit) slightly irritating
Sensitization: Not determined.
Other:
Middle distillates have caused skin irritation and skin cancer in

laboratory animals when repeatedly applied and left in place between
applications. Studies to further evaluate the carcinogenic potential of
middle distillates are currently underway. Kidney damage has also been
observed in laboratory animals exposed to middle distillates.
Necrosis was seen on animals a few days after dermal application of this
product or a component of this product. However, the skin repaired itself
within the observation period.
Waste Disposal Methods

This product (as presently constituted) has the RCRA classification of
benzene toxicity and ignitability. If discarded in its present form, it
would have the hazardous waste numbers D018 and D001 respectively. Under
RCRA, it is the responsibility of the user of the product to determine at
the time of disposal, whether the product meets RCRA criteria for
hazardous waste. This is because product uses, transformations, mixtures,
processes, etc. may change the classification to non-hazardous, or
hazardous for reasons other than, or in addition to benzene toxicity and
ignitability.

Remarks
None
Transportation
DOT:
Packing Group: III
IMDG:
ICAO:
TDG:
Federal Regulations:
SARA Title III:
Section 302/304 Extremely Hazardous Substances
None
Section 302/304 Extremely Hazardous Substances (CONT)
Seq. TPQ RQ
None
Section 311 Hazardous Categorization:

Acute [X]
Chronic [X]
Fire [X]
Pressure [ ]
Reactive [ ]

N/A [ ]
Section 313 Toxic Chemical
Chemical Name CAS Number Concentration
None
CERCLA 102(a)/DOT Hazardous Substances:

(+ indicates DOT Hazardous Substance)
01+ Benzene, (1-methylethyl)- 98-82-8 0.01-0.09

02+ Benzene 71-43-2 0.01-0.09
CERCLA/DOT Hazardous Substances (Sequence Numbers and RQ's):
Seq. RQ
01+ 5000
02+ 10
TSCA Inventory Status: This product, or its components, are listed on or

are exempt from the Toxic Substance Control Act (TSCA) Chemical Substance
Inventory.
Other: None.
State Regulations:
California Proposition 65:
The following detectable components of this product are substances, or

belong to classes of substances, known to the State of California to cause
cancer and/or reproductive toxicity.
Chemical Name CAS Number
Benzene 71-43-2
States Right-to-know Regulations:
Chemical Name State Right-to-know
Benzene, (1-methylethyl)- CT, FL, IL, MA, NJ, PA, RI, MI

Benzene CT, FL, IL, MA, NJ, PA, RI, MI
1,2,4-trimethylbenzene MA, NJ, PA
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State list: CT (Connecticut), FL (Florida), IL (Illinois), MI (Michigan),

LA (Louisiana), MA (Massachusetts), NJ (New Jersey), PA (Pennsylvania),
RI (Rhode Island)
International Regulations:
WHMIS Classification: Not determined
Canada Inventory Status: Not determined.
EINECS Inventory Status: Not determined.
Australia Inventory Status: Not determined.
Japan Inventory Status: Not determined.
15. ENVIRONMENTAL INFORMATION
Aquatic Toxicity: Not determined.
Mobility: Not determined.
Persistence and Biodegradability: Not determined.
Potential to Bioaccumulate: Not evaluated.
Remarks: Not evaluated.
THIS PRODUCT IS INTENDED FOR USE AS A MOTOR FUEL ONLY.
This product is not intended for use in space heaters. Do not use in
agricultural sprays.
Texaco recommends that all exposures to this product be minimized by

strictly adhering to recommended occupational controls procedures to avoid
any potential adverse health effects.
THE INFORMATION CONTAINED HEREIN IS BELIEVED TO BE ACCURATE. IT IS

PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUCT FOR PURPOSE OF HAZARD
COMMUNICATION AS PART OF TEXACO'S PRODUCT SAFETY PROGRAM. IT IS NOT
INTENDED TO CONSTITUTE PERFORMANCE INFORMATION CONCERNING THE PRODUCT. NO
EXPRESS WARRANTY, OR IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A
PARTICULAR PURPOSE IS MADE WITH RESPECT TO THE PRODUCT OR THE INFORMATION
CONTAINED HEREIN. DATA SHEETS ARE AVAILABLE FOR ALL TEXACO PRODUCTS. YOU
ARE URGED TO OBTAIN DATA SHEETS FOR ALL TEXACO PRODUCTS YOU BUY, PROCESS,

USE OR DISTRIBUTE AND YOU ARE ENCOURAGED AND REQUESTED TO ADVISE THOSE WHO
MAY COME IN CONTACT WITH SUCH PRODUCTS OF THE INFORMATION CONTAINED
HEREIN.
TO DETERMINE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH RESPECT

TO THE PRODUCT, USER SHOULD CONSULT HIS LEGAL ADVISOR OR THE APPROPRIATE
GOVERNMENT AGENCY. TEXACO DOES NOT UNDERTAKE TO FURNISH ADVICE ON SUCH
MATTERS.
Date: 04-15-96
[ ] New
[X] Revised, Supersedes: 03-20-96
Date printed: 04-20-96
Inquiries regarding MSDS should be directed to:

Texaco Inc.
Manager, Product Safety
P.O. Box 509
Beacon, N.Y. 12508
PLEASE SEE NEXT PAGE FOR PRODUCT LABEL
17. PRODUCT LABEL
Label Date: 03-20-96
READ AND UNDERSTAND MATERIAL SAFETY DATA SHEET BEFORE HANDLING OR

DISPOSING OF PRODUCT. THIS LABEL COMPLIES WITH THE REQUIREMENTS OF THE
OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200) FOR USE IN THE
WORKPLACE. THIS LABEL IS NOT INTENDED TO BE USED WITH PACKAGING INTENDED
FOR SALE TO CONSUMERS AND MAY NOT CONFORM WITH THE REQUIREMENTS OF THE
CONSUMER PRODUCT SAFETY ACT OR OTHER RELATED REGULATORY REQUIREMENTS.
WARNING STATEMENT
WARNING!
USE ONLY AS A FUEL

ATTENTION!
PRECAUTIONARY MEASURES
-Use only with adequate ventilation.
-Keep away from heat and flame.
-Avoid breathing vapor, mist, or gas.
-Avoid contact with eyes, skin, and clothing.
-Keep container closed.
-Never siphon by mouth.
-Wash thoroughly after handling.
FIRST AID
Eye Contact: Immediately flush eyes with plenty of water for at least 15
minutes. Hold eyelids apart while flushing to rinse entire surface of eye
and lids with water. Get medical attention.
Skin Contact: Immediately remove contaminated clothing and shoes. Under a

safety shower, flush skin thoroughly with large amounts of running water
for at least 15 minutes. Do not attempt to neutralize with chemical
agents. Get medical attention immediately. Discard or decontaminate
clothing and shoes before reuse.


Note to Physician: Aspiration of this product during induced emesis may

result in severe lung injury. If evacuation of stomach is necessary, use
method least likely to cause aspiration, such as gastric lavage after
endotracheal intubation. Contact a Poison Center for additional treatment
information.
FIRE
In case of fire, use water spray, dry chemical, foam or carbon dioxide.
Water may cause frothing. Use water spray to cool fire-exposed containers.


Chemical Name CAS Number Range in %
* A complex mixture of hydrocarbons produced 100.00

by crude oil distillation. Consists
predominantly of hydrocarbons ranging from
C-9 to C-20, and boiling in the range of
hydrosulfurized product also contains some
hydrocarbons produced by the distillation
of the catalytic cracking. The latter
materials contain bicyclic and tricyclic
Pennsylvania Special
Hazardous Substance(s) CAS Number Range in %
Benzene 71-43-2 0.01-0.09
HMIS
Health: 1
Flammability: 2
Reactivity: 0
Special: -
NFPA
Health: 1
Flammability: 2
Reactivity: 0
Special: -
Transportation
DOT:
Packing Group: III
CAUTION: Misuse of empty containers can be hazardous. Empty containers can

be hazardous if used to store toxic, flammable, or reactive materials.

Cutting or welding of empty containers might cause fire, explosion or
toxic fumes from residues. Do not pressurize or expose to open flame or
heat. Keep container closed and drum bungs in place.

P.O. Box 7812
TRANSPORTATION EMERGENCY
Company: (914) 831-3400
CHEMTREC: (800) 424-9300
HEALTH EMERGENCY
Company: (914) 831-3400

Sheet No: SME2102 Material Name: Mogas 90 and 97 Issue Date : 24/09/96 Revision of Sheet Dated:NA Page:

___________________________________________________________________________
Mogas 90 and 97
Mogas 90 and 97
Application
Use only as a motor fuel for spark ignition engines. NOT for aviation use. Should NOT be used as a solvent nor cleaning
agent.
BP Middle East Limited
PO Box 92
Mina Al Fahal 116
Sultanate of Oman
Tel: 561801
Fax: 561283

+ 971-4-317999 (Dubai)
__________________________________________________________________________________
A complex mixture of volatile hydrocarbons containing paraffins, naphthenes, olefins and aromatics with carbon numbers
predominantly between C4 and C12.
Benzene, EINECS No. 200-753-7, CAS No. 71-43-2 F, T, R45 May cause cancer, R11 Highly flammable, R48/23/24/25
Toxic: Danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if
swallowed
Gasoline. EINECS No: 289-220-8, CAS No: 86290-81-5 F+, T, R12 Extremely flammable, R45 May cause cancer, R38
Irritating to skin, R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment,
Note: R65 is expected to be introduced with the 22nd Adaptation to Technical Progress of the Dangerous Substances
Directive.
__________________________________________________________________________________
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Contains Benzene. Prolonged or repeated exposure to benzene can cause anaemia and other blood diseases, including
leukaemia.
__________________________________________________________________________________
Eyes
Skin
In extreme situations of saturation with this product, drench with water, remove clothing as soon as possible and wash skin
with soap and water. Seek medical advice if skin becomes red, swollen or painful.
Ingestion
Inhalation
Medical Advice
__________________________________________________________________________________
Combustion Products
__________________________________________________________________________________



__________________________________________________________________________________
Storage Conditions
quick rescue.
Fire Prevention


If product comes into contact with hot surfaces, or leaks occur from pressurised fuel pipes, the vapour or mists generated
will create a flammability or explosion hazard.
__________________________________________________________________________________
Exposure Limits
It is recommended that the current occupational exposure limit for gasoline is used:
Gasoline
ACGIH :
TLV 300 ppm, 890 mg/m3 (8hr TWA)
500 ppm, 1480 mg/m3 (15min STEL)
Benzene
ACGIH:
TLV 10ppm, 32mg/m3 (8hr TWA) A2 - Suspect human carcinogen
UK publication EH40 (Occupational Exposure Standard):
Maximum Exposure Limit (8-hr TWA) 5ppm, 16mg/m3
Protective Clothing
starched after use.
Typical Values
Grades:Leaded Motor Spirit
template
Test Method Units


Colour colourless
Odour gasoline-like
Vapour density rel. to air ASTM 3-4
D2463/D2421
Boiling point/range ASTM D 86 °C 25-220
Kinematic viscosity @ - 20°C ASTM D 445 mm /s2 <1
Conditions to Avoid
Sources of ignition
Materials to Avoid

__________________________________________________________________________________
Eyes
Skin
Ingestion
Inhalation
ABUSE:
Carcinogenicity/ Chronic Toxicity

leukaemia.


__________________________________________________________________________________
Mobility

Aquatic toxicity
Harmful to aquatic organisms. May cause long term effects in the aquatic environment

__________________________________________________________________________________
Materials contaminated with product should be treated as highly flammable. Disposal should be in accordance with local
regulations.
__________________________________________________________________________________

Extremely flammable
Irritant
Harmful
EU Labelling
Contains: Low boiling point naphtha (Gasoline)

Risk ( R ) Phrases:
also
Note: R65 is expected to be introduced with the 22nd Adaptation to Technical Progress of the Dangerous Substances
Directive.
S23 Do not breath spray
__________________________________________________________________________________
Compiled by:
Chertsey Road
Sunbury-On-Thames
Middlesex, TW16 7LN

Sheet No: STI2217 Material Name: MTBE Issue Date : 17/07/2000 Revision of Sheet Dated:03/11/98 Page:
ALIGN BP SDS Finals


Material Name: MTBE
Hazardous Components: Physical Characteristics: Gasoline Tox File: 183 Product Group:
________________________________________________________________________________
SAFETY DATA SHEET
MTBE
COMPANY/UNDERTAKING
MTBE
Alternative Names: methyl-tert-butyl ether, 2-methoxy-propyl propane, tert-butyl-methyl ether
Application
Gasoline octane enhancer
Britannic House
1 Finsbury Circus
London, EC2M 7BA

+44 (0) 20 7496 4411
_________________________________________________________________________________
tert-butyl methyl ether (MTBE), EINECS No. 216-653-1, CAS No. 1634-04-4
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Highly flammable
_________________________________________________________________________________
Eyes
Skin
Wash off immediately with soap and water. Change heavily contaminated clothing and wash underlying skin.
Ingestion
Inhalation
Medical Advice
_________________________________________________________________________________
Use alcohol resistant foam, dry powder or water fog. DO NOT USE water jets.
Combustion Products
_________________________________________________________________________________


etc.).

This product is miscible with water, but in the case of major spillage prompt action may enable recovery.
_________________________________________________________________________________

Storage Conditions
Fire Prevention

_________________________________________________________________________________

Exposure Limits
Methyl-tert butyl ether (MTBE)

ACGIH (USA): TLV 40ppm (8hr TWA)
A3 - Animal carcinogen.
Protective Clothing
_________________________________________________________________________________

Typical Values
Grades: MTBE
Test Method Units
Colour colourless
Odour pungent
Solubility in water g/l 48
Melting point ASTM D 127 °C -109
_________________________________________________________________________________


Conditions to Avoid
Sources of ignition
Materials to Avoid

_________________________________________________________________________________
Eyes
May be irritating to the eyes.
Skin
Ingestion
diarrhoea.
Inhalation
_________________________________________________________________________________
Mobility

This material is not readily biodegradable.
Aquatic toxicity
Unlikely to be harmful to aquatic organisms.
_________________________________________________________________________________

Incineration may be carried out under controlled conditions provided that local regulations for emissions are met.
onto soil.
_________________________________________________________________________________
ADR/RID - Methyl tert-butyl ether, Flammable Liquid, Class 3, Item 3(b) Hazard identification No33
UN - Methyl tert-butyl ether, Class 3, Pack Gp II, UN Number 2398
IMO - Methyl tert-butyl ether, Class 3.1, Flammable Liquid, Pack Gp II
IATA/ICAO - Methyl tert-butyl ether, Flammable Liquid , Class 3, Pack Gp II,
EMERGENCY ACTION CODE: 3(Y)E
_________________________________________________________________________________
Highly flammable
Harmful
Irritant
EU Labelling
Symbol:
Flame
St. Andrew's Cross
HIGHLY FLAMMABLE
HARMFUL
Risk ( R ) Phrases:
S24/25 Avoid contact with skin and eyes.
S28 After contact with skin, wash immediately with plenty of water.
The label must carry the following additional information: Substance name
Substance name: tert-butyl methyl ether (MTBE)
_________________________________________________________________________________
Compiled by:


Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
Sheet Revisions
17/07/2000 4, 5, 7, 8, 10, 15
SHEET NO: STI2217

______________________________________________________________________________

file:///C|/Documents%20and%20Settings/lanewg/My%20Documents/DATA/QA%20Amendments/MSDS/White%20Oil/Natural%20Gasoline.htm

NATURAL GASOLINE
Mobil
100000-00
MATERIAL SAFETY DATA BULLETIN
1. PRODUCT AND COMPANY IDENTIFICATION
APPROVAL DATE: 12/01/97
PRODUCT NAME: NATURAL GASOLINE
SUPPLIER:
MOBIL OIL CORP.
NORTH AMERICA MARKETING AND REFINING
3225 GALLOWS RD.
FAIRFAX, VA 22037
24 - Hour Emergency (call collect): 609-737-4411

Product and MSDS Information: 800-662-4525 609-224-4644
CHEMTREC: 800-424-9300 202-483-7616
CHEMICAL NAMES AND SYNONYMS: NATURAL GASOLINE..C5-8
INGREDIENTS CONSIDERED HAZARDOUS TO HEALTH:
Substance Name Wt%
NATURAL GASOLINE (68425-31-0) 100
COMPONENT(S) OF PRODUCT INGREDIENTS INCLUDE:
BENZENE (71-43-2) < 2
NOTE: This product may contain trace amounts of hydrogen sulfide.
See Section 8 for exposure limits (if applicable).
US OSHA HAZARD COMMUNICATION STANDARD: Product assessed in accordance with

OSHA 29 CFR 1910.1200 and determined to be hazardous.
EFFECTS OF OVEREXPOSURE: **** Warning: H2S a highly toxic gas may be
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present, see MSDB toxicology section. Gas is highly toxic and is absorbed
through the mucous membranes of the respiratory tract causing respiratory
paralysis and suffocation. Symptoms of overexposure include headache,
fatigue, insomnia, irritability and gastrointestinal problems. Loss of
sense of smell at 100 ppm, drowsiness, loss of consciousness, respiratory
failure or death can result from exposure above 100 ppm. Gasoline vapors
when administered in high concentrations over a prolonged period of time,
cause kidney damage and kidney cancer in rats and liver cancer in mice
(see MSDB toxicology section). Skin irritation. Respiratory irritation,
dizziness, nausea, loss of consciousness. Prolonged repeated skin contact
with low viscosity materials may defat the skin resulting in possible
irritation and dermatitis.
EMERGENCY RESPONSE DATA: Clear Liquid. Extremely flammable. Vapor

accumulation could flash and/or explode if in contact with open flame. DOT
ERG No. -128
EYE CONTACT: Flush thoroughly with water. If irritation occurs, call a

physician.
SKIN CONTACT: Wash contact areas with soap and water. Remove contaminated
clothing. Launder contaminated clothing before reuse.
INHALATION: Remove from further exposure. If respiratory irritation,

dizziness, nausea, or unconsciousness occurs, seek immediate medical
assistance. If breathing has stopped, assist ventilation with
bag-valve-mask device or use mouth-to-mouth resuscitation.
INGESTION: Seek immediate medical attention. Do not induce vomiting.
NOTE TO PHYSICIANS: Material if aspirated into the lungs may cause

chemical pneumonitis. Treat appropriately.
EXTINGUISHING MEDIA: Carbon dioxide, foam, dry chemical and water fog.
SPECIAL FIRE FIGHTING PROCEDURES: Use water to keep fire exposed

containers cool. If a leak or spill has not ignited, use water spray to
disperse the vapors and to protect personnel attempting to stop leak.
Water spray may be used to flush spills away from exposures. Prevent
runoff from fire control or dilution from entering streams, sewers, or
drinking water supply.
SPECIAL PROTECTIVE EQUIPMENT: For fires in enclosed areas, fire fighters

must use self-contained breathing apparatus.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Extremely flammable. Vapor

accumulation could flash and/or explode if in contact with open flame.
Flash Point C(F): -40(-40) (ASTM D-56). Flammable limits - LEL: 0.7%, UEL:
7.8%.
NFPA HAZARD ID: Health: 1, Flammability: 4, Reactivity: 0
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide.
NOTIFICATION PROCEDURES: In case of accident or road spill notify CHEMTREC

(800) 424-9300. Report spills as required to appropriate authorities. U.
S. Coast Guard regulations require immediate reporting of spills that
could reach any waterway including intermittent dry creeks. Report spill
to Coast Guard toll free number (800) 424-8802.
PROCEDURES IF MATERIAL IS RELEASED OR SPILLED: Adsorb on fire retardant

treated sawdust, diatomaceous earth, etc. Shovel up and dispose of at an
appropriate waste disposal facility in accordance with current applicable
laws and regulations, and product characteristics at time of disposal.
Eliminate all ignition sources. Runoff may create fire or explosion hazard
in sewer system.
ENVIRONMENTAL PRECAUTIONS: Prevent spills from entering storm sewers or

drains and contact with soil.
PERSONAL PRECAUTIONS: See Section 8
HANDLING: Trace amounts of H2S may be present. Keep face clear of tank
and/or tank car openings. Avoid contact with skin. Avoid inhalation of
vapors or mists. Use in well ventilated area away from all ignition
sources. Avoid sparking conditions. Ground and bond all transfer
equipment.
STORAGE: Drums must be grounded and bonded and equipped with self-closing
valves, pressure vacuum bungs and flame arresters. Store away from all
ignition sources in a cool area equipped with an automatic sprinkling
system. Outside or detached storage preferred. Storage containers should
be grounded and bonded.

VENTILATION: Use in well ventilated area with local exhaust ventilation.

Ventilation required and equipment must be explosion proof. Use away from
all ignition sources.
RESPIRATORY PROTECTION: Approved respiratory equipment must be used when

airborne concentrations are unknown or exceed the TLV.
EYE PROTECTION: Normal industrial eye protection practices should be

employed.
SKIN PROTECTION: If prolonged or repeated skin contact is likely,

impervious gloves should be worn. Good personal hygiene practices should
always be followed.
---TWA--- ---STEL--- NOTE

Substance Name (CAS-No.) Source ppm mg/m3 ppm mg/m3
NATURAL GASOLINE
(68425-31-0)
MOBIL 300 890
ACGIH 300 890 500 1480
BENZENE (71-43-2)
OSHA 1 5
Skin ACGIH 0.5 1.6 2.5 8
NOTE: Limits shown for guidance only. Follow applicable regulations.
Typical physical properties are given below. Consult Product Data Sheet
for specific details.
APPEARANCE: Liquid
COLOR: Clear
ODOR: Hydrocarbon
ODOR THRESHOLD-ppm: NE
pH: NA
BOILING POINT C(F): > 4(40)
MELTING POINT C(F): NE
FLASH POINT C(F): -40(-40) (ASTM D-56)
FLAMMABILITY: NE
AUTO FLAMMABILITY: NE
EXPLOSIVE PROPERTIES: NA
OXIDIZING PROPERTIES: NA
VAPOR PRESSURE-mmHg 20 C: < 1201.0

VAPOR DENSITY: 3.0

EVAPORATION RATE: NE
RELATIVE DENSITY, 15/4 C: 0.68
SOLUBILITY IN WATER: Negligible
PARTITION COEFFICIENT: NE
VISCOSITY AT 40 C, cSt: < 1.0
VISCOSITY AT 100 C, cSt: NA
POUR POINT C(F): NA
FREEZING POINT C(F): NE
VOLATILE ORGANIC COMPOUND: NE
NA=NOT APPLICABLE
NE=NOT ESTABLISHED
D=DECOMPOSES
FOR FURTHER TECHNICAL INFORMATION, CONTACT YOUR MARKETING REPRESENTATIVE
STABILITY (THERMAL, LIGHT, ETC.): Stable.
CONDITIONS TO AVOID: Heat, sparks, flame and build up of static

electricity.
INCOMPATIBILITY (MATERIALS TO AVOID): Halogens, strong acids, alkalies,

and oxidizers.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide.
HAZARDOUS POLYMERIZATION: Will not occur.
11. TOXICOLOGICAL DATA
---ACUTE TOXICOLOGY---
ORAL TOXICITY (RATS): Practically non-toxic (LD50: greater than 2000
mg/kg). ---Based on testing of similar products and/or the components.
DERMAL TOXICITY (RABBITS): Practically non-toxic (LD50: greater than 2000

mg/kg). ---Based on testing of similar products and/or the components.
INHALATION TOXICITY (RATS): Harmful (LC50: greater than 2 but 5 mg/l or

less). ---Based on testing of similar products and/or the components.
EYE IRRITATION (RABBITS): Practically non-irritating. (Draize score:

greater than 6 but 15 or less). ---Based on testing of similar products
and/or the components.
SKIN IRRITATION (RABBITS): Irritant. (Primary Irritation Index: 3 or

greater but less than 5). ---Based on testing of similar products and/or
the components.
OTHER ACUTE TOXICITY DATA: Inhalation of vapors/mists may cause

respiratory system irritation. H2S acts as a chemical asphyxiant,
preventing the body from utilizing oxygen in the tissue. It can be
irritating to the eyes at 10 ppm and to the respiratory tract at 50-100
ppm after 1-hour exposure. Sufficiently high concentrations can result in
immediate collapse and death.
---CHRONIC TOXICOLOGY (SUMMARY)---

Recent studies with laboratory animals have shown that gasoline vapors
when administered in high concentrations over a prolonged period of time,
caused kidney damage and kidney cancer in rats and liver cancer in mice.
As far as scientists know, low level or infrequent exposure to gasoline
vapors is unlikely to be associated with cancer or other serious diseases
in humans. Prolonged repeated skin contact with low viscosity materials
may defat the skin resulting in possible irritation and dermatitis.
---OTHER TOXICOLOGY DATA---

**** Keep face clear of tank and/or tank car openings. Hydrogen sulfide
(H2S) may collect in the vapor space of tanks or other enclosed vessels.
H2S is an extremely flammable, very highly toxic gas.
ENVIRONMENTAL FATE AND EFFECTS: Not established.
WASTE DISPOSAL: Product is suitable for burning in an enclosed, controlled

burner for fuel value or disposal by supervised incineration. Such burning
may be limited pursuant to the Resource Conservation and Recovery Act.
RCRA INFORMATION: Disposal of unused product may be subject to RCRA

regulations (40 CFR 261) due to the characteristic(s)/chemical(s) listed
below. Disposal of the used product may also be regulated due to
ignitability, corrosivity, reactivity, or toxicity as determined by the
Toxicity Characteristic Leaching Procedure (TCLP).
BENZENE: 1.9999 PCT (TCLP)

FLASH: -40 (-40) C(F)
USA DOT:
SHIPPING NAME: Gasoline

HAZARD CLASS & DIV: 3

ID NUMBER: UN1203
ERG NUMBER: 128
PACKING GROUP: PG II
STCC: NE
DANGEROUS WHEN WET: No
POISON: No
LABEL(s): Flammable Liquid
PLACARD(s): Flammable
PRODUCT RQ: NA
MARPOL III STATUS: NA
IMO:
HAZARD CLASS & DIV: 3.1
UN NUMBER: 1203
MARPOL III STATUS: NA
ICAO/IATA:
HAZARD CLASS & DIV: 3
ID/UN Number: 1203
SUBSIDIARY RISK: NA
Governmental Inventory Status: All components comply with TSCA and DSL.
U.S. Superfund Amendments and Reauthorization Act (SARA) Title III: This
product contains no "EXTREMELY HAZARDOUS SUBSTANCES".
SARA (311/312) REPORTABLE HAZARD CATEGORIES:

FIRE
CHRONIC
ACUTE
This product contains the following SARA (313) Toxic Release

Chemicals:
CHEMICAL NAME CAS NUMBER CONC.
BENZENE(COMPONENT ANALYSIS) 71-43-2 <2%

The following product ingredients are cited on the lists below:
CHEMICAL NAME CAS NUMBER LIST CITATIONS
BENZENE (COMPONENT ANALYSIS) 71-43-2 1, 2, 4, 6, 9, 10, 16, 17, 18

(<2.00%) 19, 20, 21, 22, 23, 24, 25,
26
NATURAL GASOLINE..C5-8 68425-31-0 1, 18, 19, 20, 21, 23, 25
--- REGULATORY LISTS SEARCHED ---

1=ACGIH ALL 6=IARC 1 11=TSCA 4 16=CA P65 CARC 21=LA RTK
2=ACGIH A1 7=IARC 2A 12=TSCA 5a2 17=CA P65 REPRO 22=MI 293
3=ACGIH A2 8=IARC 2B 13=TSCA 5e 18=CA RTK 23=MN RTK
4=NTP CARC 9=OSHA CARC 14=TSCA 6 19=FL RTK 24=NJ RTK
5=NTP SUS 10=OSHA Z 15=TSCA 12b 20 IL RTK 25=PA RTK
26=RI RTK
Code key: CARC=Carcinogen; SUS=Suspected Carcinogen; REPRO=Reproductive
Precautionary Label Text:
CONTAINS GASOLINE
WARNING!
EXTREMELY FLAMMABLE LIQUID AND VAPOR. HARMFUL OR FATAL IF SWALLOWED. VAPOR

HARMFUL. LOW VISCOSITY MATERIAL-IF SWALLOWED, MAY BE ASPIRATED AND CAN
CAUSE SERIOUS OR FATAL LUNG DAMAGE.
LONG-TERM EXPOSURE TO GASOLINE VAPOR HAS CAUSED KIDNEY AND LIVER CANCER IN
LABORATORY ANIMALS.
Keep away from heat, sparks, and flame. Avoid prolonged breathing of
vapor. Keep container closed. Use with adequate ventilation. Not to be
used as a solvent or skin cleaning agent. Never siphon by mouth. Avoid
contact with eyes and skin. Misuse of gasoline may cause serious injury or
illness.
FIRST AID: If inhaled, remove from further exposure. If respiratory

irritation, dizziness, nausea, or unconsciousness occurs, seek immediate
medical assistance. If breathing has stooped. assist ventilation with a
bag-valve-mask device or use mouth-to-mouth resuscitation. In case of
contact, wash skin with soap and water. Remove contaminated clothing.
Destroy or wash clothing before reuse. If swallowed, seek immediate

medical attention. Do not induce vomiting. Only induce vomiting at the

instruction of a physician.
Attention. Empty container may contain product residue, including

flammable or explosive vapors. Do not cut, puncture, or weld on or near
container. All label warnings and precautions must be observed until
container has been thoroughly cleaned or destroyed.
This warning is given to comply with California Health and Safety Code
25249.6 and does not constitute an admission or a waiver of rights. This
product contains a chemical known to the State of California to cause
cancer. Refer to product Material Safety Data Bulletin for further safety
and health information.
USE: PROCESS/FUEL INTERMEDIATE
NOTE: MOBIL PRODUCTS ARE NOT FORMULATED TO CONTAIN PCBS.
INGREDIENT CAS NUMBER
NATURAL GASOLINE 100.00 68425-31-0
For Internal Use Only: MHC: 1* 1* 2* 1* 2*, MPPEC: CF, REQ: HOUSTON GAS
LIQUIDS, SAFE USE: S
Information given herein is offered in good faith as accurate, but without

guarantee. Conditions of use and suitability of the product for particular
uses are beyond our control; all risks of use of the product are therefore
assumed by the user and WE EXPRESSLY DISCLAIM ALL WARRANTIES OF EVERY KIND
AND NATURE, INCLUDING WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A
PARTICULAR PURPOSE IN RESPECT TO THE USE OR SUITABILITY OF THE PRODUCT.
Nothing is intended as a recommendation for uses which infringe valid
patents or as extending license under valid patents. Appropriate warnings
and safe handling procedures should be provided to handlers and users.
Alteration of this document is strictly prohibited. Except to the extent
required by law, republication or retransmission of this document, in
whole or in part, is not permitted. Mobil assumes no responsibility for
accuracy of information unless the document is the most current available
from an official Mobil distribution system. Mobil neither represents nor
warrants that the format, content or product formulas contained in this
document comply with the laws of any other country except the United
States of America.
Copyright 1996 Mobil Corporation, All rights reserved
Mobil

Material Safety Data Bulletin
An Explanation of Terms - U.S. Products
Introduction
A Mobil Material Safety Data Bulletin (MSDB), commonly referred to as a

Material Safety Data Sheet (MSDS), is a compilation of health-related
information, procedures for emergency situations, physical properties, and
recommendations to help assure the safe handling of a particular Mobil
product.
The MSDB meets all of the requirements of the OSHA Hazard Communication
Standard (29 CFR 1910.1200). As an additional customer service, we provide
an MSDB for our non-hazardous products as well.
Mobil provides an MSDB upon initial purchase, within 3 months of a

significant change in hazardous product MSDB information, and upon first
purchase each year for products containing a SARA 313 regulated
ingredient. An MSDB may be requested at any time by calling the MSDS
information number indicated in Section 1 of the MSDB. Some MSDBs are
available on the Internet (www.mobil.com).
The following explanations of section contents are provided, ordered as

you will find them within the U.S. MSDB. Please refer to the MSDB as you
go through the following 16 sections which conform to the ANSI Z400.1-1993
standard and international formats.
Section 1. Product and Company Identification
Indicates if MSDB is based on supplier information. Identifies the product

trade name as it appears on the product container; our address and
telephone numbers; and the date the MSDB was last revised. Please use the
Product and MSDS Information phone number to request data regarding
product applications and to obtain an MSDB. The emergency number is for
urgent health, release, and transportation situations. The CHEMTREC number
is for reporting transportation emergencies.
Section 2. Composition/Information on Ingredients
Ingredients disclosure in this section is based upon exposure limits and

definitions of hazardous components considered relevant in the U.S.,
subject to applicable trade secret protections.
Chemical Names and Synonyms- A generic description of product components.
Ingredients Considered Hazardous to Health - Lists chemicals present above
file:///C|/Documents%20and%20Settings/lanewg/M...dments/MSDS/White%20Oil/Natural%20Gasoline.htm (10 of 19) [29/01/2002 08:54:37]

certain concentrations which either have exposure limits or have been

determined to be hazardous by Mobil. The Chemical Abstract Service (CAS)
number and approximate weight percentage is listed for each chemical. The
exposure limits for these chemicals are listed in Section 8 of the MSDB.
Other Potentially Hazardous Ingredients - Lists chemicals present above

certain concentrations which do not have regulatory exposure limits but
which are physical (combustible, flammable, etc.) or health (defat skin,
etc.) hazards. Includes CAS number and approximate weight percentage for
each chemical.
Footnotes - Provides other amplifying information.
Section 3. Hazards Identification
Summarizes key emergency response information including a statement of

whether or not the product is hazardous by the criteria in the OSHA Hazard
Communication Standard; effects of overexposure to the product; physical
appearance; unusual fire and explosion hazards; DOT Emergency Response
Guide (ERG) number; and for Mobil use, a numerical Safety Equipment Code
(SEC) which indicates hazard severity for MCC-CPD materials.
Section 4. First Aid Measures
Contains recommended first aid procedures for relevant types of exposure

(e.g., eye contact, skin contact, inhalation, or ingestion). Also includes
notes to treating physicians. The information is for emergency situations
only.
Section 5. Fire-Fighting Measures
Recommends suitable extinguishing media, gives fire fighting instructions

based on criteria established by the National Fire Protection Association
(NFPA), gives advice on any special protective equipment for fire fighters
(such as self-contained breathing apparatus), and identifies any unusual
fire and explosion hazards.
Flash Point - Temperature at which a material will generate sufficient

vapor to ignite in the presence of an ignition source. OSHA classifies a
material with a flash point below 100 Deg. F as flammable, and with a
flash point at or above 100 Deg. F and below 200 Deg. F as combustible.
The DOT defines materials with a flash point of 141 Deg. F or less as
flammable, and with a flash point between 141 Deg. F and below 200 Deg. F
as combustible. Both OSHA and DOT require that flash points be determined
using closed cup methods such as ASTM D-93 or ASTM D-56.
Flammable Limits - The range of gas and vapor concentrations (percent in

air) which will burn in the presence of an ignition source. Flammable

range is expressed as Lower Explosive Limit (LEL) and Upper Explosive
Limit (UEL). If the flash point is above 250 Deg. F, no flammable limits
are shown on the MSDB.
NFPA Hazard ID - Coding system developed by the NFPA. Codes of 0 to 4 are

assigned to the categories of Health, Flammability, and Reactivity. The
lowest level of hazard is 0, and the highest is 4. For non-fire
situations, the NFPA code and the Hazardous Material Information System
(HMIS) code are identical. For fire situations, the HMIS Health code may
differ from the NFPA Health code.
Hazardous Decomposition Products - Combustion byproducts which may be

formed if the product is burned.
Section 6. Accidental Release Measures
Recommends procedures and precautions to be taken in the event of an

accidental release or spill. Procedures for disposing of the product are
given in Section 13. The reporting requirements indicated are for federal
regulations. Since state and local reporting requirements may also exist,
consult state and local law for guidance.
Section 7. Handling and Storage
Recommends any special precautions to be followed during the handling and

storage of Mobil products. If a product is OSHA hazardous, the
precautionary warning label text will be shown in Section 16.
Section 8. Exposure Controls/Personal Protection
As a consequence of Mobil's Product Stewardship Program, many of our

products are non-hazardous. Product toxicity, or lack thereof, is
determined in our Toxicology Testing Program. When there is potential for
adverse health effects from direct exposure to the product as packaged for
sale, recommendations are made for general ventilation, and for
respiratory, eye and skin protection. Depending on customer use
conditions, need for protective measures may vary.
Regulated components of products are also shown in this section, along

with their airborne exposure limits. Terms associated with exposure limits
include:
Source - Indicates organization that established the exposure limit.
Mobil - Exposure values utilized by Mobil for its facilities are displayed
if they are = or < the corresponding ACGIH TLV.

ACGIH - American Conference of Governmental Industrial Hygienists

establishes Threshold Limit Values (TLV).
OSHA - Occupational Safety & Health Administration - establishes

Permissible Exposure Limits (PEL).
TWA - Time Weighted Average is the airborne concentration of a substance

averaged over a normal eight hour workday.
STEL - Short Term Exposure Limit is the airborne concentration of a

substance typically averaged over a 15 minute period. Used for substances
with potential health effects as a result of a brief exposure to a high
concentration.
ppm - Parts of gas or vapor per million parts of air. Common unit of
measure for exposure limits for gases or vapors.
mg/m(3) - Milligrams of a substance per cubic meter of air. Common unit of

measure for exposure limits for dusts or mists.
Note - Provides further exposure limit information such as Ceil for

ceiling limits which may not be exceeded during any part of the work day.
Section 9. Physical and Chemical Properties
The information in this section represents typical chemical and physical

properties - not product specifications. The purpose is to provide data
for health and safety assessments - not product performance. For technical
data on Mobil products, please contact your marketing representative, or
call the product information number indicated in Section 1 of the MSDB.
The less familiar terms used in this section are explained below. Some
properties are not addressed in the MSDB if they are not applicable (NA),
or if they have not been established for (NE), a given product.
pH - A measure of the acidity or alkalinity of an aqueous solution on a

scale of 0 to 14, with 7 considered neutral. Not applicable to most
lubricants since they are not aqueous solutions.
Flammability - A measure of how quickly a solid will burn. For a gas,

essentially equivalent to the flammable range defined by the UEL and LEL.
Autoflammability - A determination of the temperature at which a substance

will self-ignite. Essentially equivalent to autoignition temperature.
Explosive Properties - A test of whether a product presents a danger of

explosion when subjected to flame, shock or friction.

Oxidizing Properties - A measure of burning rate.
Vapor Pressure - A measure of volatility. The higher the vapor pressure,

the greater the potential to generate vapor; and for flammable materials,
the greater the potential fire hazard.
Relative Density - The density of the product compared to water. Indicates

whether product will sink (>1) or float (<1) in water. Essentially the
same as specific gravity.
Solubility - Degree of solubility in water at room temperature.
Term Solubility
Negligible 0.0 - 0.1%
Slight 0.1 - 1.0%
Moderate 1.0 - 10%
Appreciable >10%
Complete 100%
Partition Coefficient - The solubility of a substance in n-Octanol

compared to its solubility in water. Low partition coefficient indicates
product is not expected to accumulate in the fatty tissue of aquatic
organisms.
Viscosity - A Measure of resistance to flow. Some low viscosity

hydrocarbon oils (<15 Deg. Cs at 40 Deg. C) have been shown to defat the
skin and result in irritation or dermatitis on prolonged or repeated
contact.
D=Decomposes - Indicates that the product begins to change chemically

before reaching the test endpoint.
Section 10. Stability and Reactivity
Information is given on conditions and materials to avoid in order to

prevent creation of a hazardous situation. Hazardous substances which may
be formed during thermal or chemical breakdown of the product are also
listed.
Section 11. Toxicological Data
Toxicological testing is an important part of Mobil's Product Stewardship

Program. This section summarizes available test data and scientific
literature for ingredients in our products, and is the basis for
determining regulatory classification and labelling requirements for the
product as a whole.

Acute Tests - Determine the potential hazards of a product based on

short-term exposure. Results range from practically non-toxic or
non-irritating, to very toxic or severe irritant. Used to determine
emergency and first aid procedures.
Subchronic Tests - Used to determine potential hazards from periodic

exposure to one or more ingredients in a product.
Chronic Tests - Used to evaluate the potential long-term effects of

prolonged or repeated exposure to one or more ingredients in a product.
Mutagenic Tests - Used to evaluate the potential for one or more

ingredients in a product to cause genetic changes. Also used as a
predictor of cancer causing potential.
Reproductive Tests - Used to evaluate potential of one or more ingredients

in a product to have effects on the unborn, or the ability to conceive and
bear offspring.
Other Data - Any other information that has an impact on toxicological

properties, such as lubricant base oil properties, potential for skin
sensitization, etc.
Section 12. Ecological Information
Summarizes the environmental fate, effects, and behavior of the product,

if known.
Section 13. Disposal Considerations
Gives advice on recommended methods of disposing of product. In all cases,

products should be disposed of in accordance with current legal
requirements. A statement regarding status of the unused product pursuant
to RCRA regulations is included. The waste generator is responsible for
determining the hazard classification of used product. State and local
regulations may be more stringent than federal regulations. Because of the
complexity of disposal regulations, we suggest that you consult state and
local law for guidance.
Section 14. Transportation Information
This section contains information for classifying and labeling hazardous

materials in the U.S. (DOT), over the high seas (IMO), via air
(ICAO/IATA), in Canada (TDGR), and in Europe (RID/ADR). Combustible
products shipped in non-bulk quantities (less than 119 gallons) may be
exempt from transportation regulations. If a product is not classified as

a hazardous material for shipping purposes, not applicable will be

indicated. An ID number beginning with UN is required for shipments
outside of the North American continent.
MSDBs for products containing environmentally hazardous substances include

the pounds of product which must be spilled during transport to reach the
U.S. DOT reportable quantity (RQ) of the hazardous substance. This product
RQ should not be confused with the hazardous substance RQ.
Product ingredients classified as Marine Pollutants (MARPOL) when shipped

in bulk are identified in this section.
Section 15. Regulatory Information
As a customer service, some information regarding status of a product and

its ingredients with certain federal and state regulations may be included
in this section. However, customers are responsible for ensuring
compliance with all applicable regulations which may apply to use and
handling of our products.
Inventory Status - Status of product ingredient registration on national

chemical listings to include TSCA (U.S.), EINECS/ELINCS (Europe), AICS
(Australia), DSL (Canada), MITI (Japan), KECI (S. Korea), PICCS
(Philippines), and IECS/NEPA (China). For information regarding
registration on other chemical listings, please call the product
information number in Section 1 of the MSDB.
SARA - Provides information necessary for complying with the community

right-to-know (RTK), inventory reporting, and toxic release inventory
(TRI) reporting requirements under SARA. Product ingredients regulated
under SARA will be shown with CAS No. and weight percentage.
FDA/USDA - If the product meets FDA criteria, or has a USDA approval, the
specific criteria and approval rating will be shown.
Drug and Explosive Precursors - Certain chemicals are controlled by

various federal agencies due to their potential for use in manufacturing
illegal drugs and explosives. If these controlled ingredients are present
in a product, a statement regarding regulatory compliance will be shown.
European Hazard Warning Labels - If the product is hazardous by European

dangerous substances and preparations directives, appropriate risk (R) and
safety (S) label codes will be shown.
List Citations - Product ingredients are compared electronically to a

number of federal and state regulatory lists. If an ingredient is included
in one of the lists in the Regulatory Lists Searched code key, and if it

is present at levels above respective list thresholds, the ingredient,

along with its CAS No. and list code, will be shown. The criteria for
disclosing chemical components in this section are not necessarily the
same as the criteria used to disclose components in Section 2.
The following lists are included in the regulatory review process:
ACGIH All - All chemicals covered by the American Conference of

Governmental Industrial Hygienist TLV's.
ACGIH A1- List of materials which, in the opinion of ACGIH, are confirmed
to cause cancer in humans.
ACGIH A2 - List of materials which, in the opinion of ACGIH, are suspected

of causing cancer in humans.
NTP CARC - Materials classified in the National Toxicology Program annual

report as known carcinogens.
NTP SUS - Materials classified in NTP annual report as anticipated to be

carcinogenic.
IARC 1 - List of materials which the International Agency for Research on

Cancer believes cause cancer in humans.
IARC 2A - List of materials which IARC believes probably cause cancer in

humans.
IARC 2B - List of materials which IARC believes possibly cause cancer in

humans.
OSHA CARC - List of OSHA regulated carcinogens and potential carcinogens.
OSHA Z - List of all materials regulated by OSHA.
TSCA 4 - List of materials covered by an EPA test rule or order under

Section 4 of the Toxic Substance Control Act.
TSCA 5a2 - List of materials covered by an EPA Significant New Use Rule
under TSCA Section 5(a)(2).
TSCA 5e - List of materials covered by an EPA consent order under TSCA

Section 5(e).
TSCA 6 - List of materials covered by an EPA final risk management action

under TSCA Section 6.
TSCA 12b - List of materials subject to EPA export notification

requirements under TSCA Section 12(b).
CA P65 CARC - List of materials subject to warning requirements under

California Proposition 65 (Safe Drinking Water and Toxic enforcement Act
of 1986) due to cancer potential.
CA P65 REPRO - List of materials subject to warning requirements under

California Proposition 65 due to potential for affecting the reproductive
system.
CA RTK - The Director's List of Hazardous Substances, developed pursuant

to the California Hazardous Substances Disclosure to Employees Act.
FL RTK - The Florida Substance List, developed pursuant to the Florida

Toxic Substances in the Workplace Act.
IL RTK - The Toxic Substance List developed pursuant to the Illinois Toxic
Substance Disclosure to Employees Act.
LA RTK - The Louisiana State Right-to-Know Hazardous Chemicals List,

developed pursuant to the Hazardous Material Information Development,
Preparedness, and Response Act.
MI 293 - List of chemicals on the Michigan Critical Materials Register

(environmental groundwater hazardous substances).
MN RTK - List of Hazardous Substances, developed pursuant to the Minnesota

Employee Right-to-Know Act.
NJ RTK - Three lists developed pursuant to the New Jersey Worker and
Community Right-to-Know Act.
PA RTK - Three lists developed pursuant to the Pennsylvania Worker and

Community Right-to-Know Act.
RI RTK - List of chemicals on the Rhode Island State Hazardous Substances

register.
For status of compliance with other regulations, please call the

information number in Section 1 of the MSDB.
Section 16. Other Information
If a product is OSHA hazardous, the precautionary label text to be

included on container labels is shown in this section. This section also
includes a use description for the product. For some products, additional
ingredients are also disclosed.

Information intended for internal Mobil use includes:
MHC - Material Hazard Code determined by acute toxicological testing for

oral, dermal, inhalation, eyes, and skin routes of exposure. Codes range
from 0 to 4 with 4 being the most severe. An asterisk indicates that the
MHC is based on data from testing of a similar material. A code of 2 or
greater classifies the product as hazardous under both U.S. and European
criteria.
MPPEC - Mobil Personal Protective Equipment Code. Assumes direct exposure

to undiluted product.
Primary Codes:
A - Minimal protective equipment for a given facility's operations
(determined locally).
B - Code A + eye protection.
C - Code A + skin protection
D - Code A + eye and skin protection.
E - Protection from severe eye and skin hazard needed.
X - Special protective equipment needed.
Ancillary Codes:
P - Particulate respiratory protection.
V - Vapor respirator needed.
H - Noxious vapors released when heated.
F - Flash point <100 Deg. F (37.8 Deg. C)
REQ - Mobil affiliate that requested the MSDB.
Sale Use - Code used by Mobil's E&P facilities.
TRN - MSDB numerical identifier
Mobil Business Resources Corp.

Product Stewardship & Toxicology
P.O. Box 310
Paulsboro NJ 08066-0310
(C) Copyright 1987, 1990, 1994, 1996, 1998.

All rights reserved.
Mobil Material Safety Data Bulletin - An Explanation of Terms - U.S.
Products
GEN 0098023 (05-31-98)

============ CHEMICAL PRODUCT AND COMPANY IDENTIFICATION =============
TRADE NAME: #2 DIESEL FUEL

SYNONYM(S): PROCESS STREAM; NO. 2 DIESEL FUEL; FUEL OIL;
MIDDLE DISTILLATE; AB0/AA9-1; AG7; AG8
MSDS NUMBER: 1354
PRODUCT CODE: NA
HIERARCHY: NA
MANUFACTURER/SUPPLIER: BP Oil Company
ADDRESS: 200 Public Square, Cleveland, OH 44114-2375
TELEPHONE NUMBERS - 24 HOUR EMERGENCY ASSISTANCE:
BP America: 800-321-8642
CHEMTREC Assistance (In U.S.): 800-424-9300
CHEMTREC Assistance (Elsewhere): 703-527-3887
TELEPHONE NUMBERS - GENERAL ASSISTANCE: (Normal Office Hours):
(8:00-4:30 M-F, EST):
Technical: 216-586-6184
MSDS Contact: 216-586-8023
============== COMPOSITION/INFORMATION ON INGREDIENTS ================
COMPONENT:Diesel Fuel No. 2, A distillate having a minimum viscosity of 32.6

SUS at 100 degrees F to a maximum of 40.1 SUS at 100 degrees F
CAS NO.: 68476-34-6
% BY WT.: 99.9 - 100
EXPOSURE LIMITS: None Established
====================== HAZARDS IDENTIFICATION ========================
EMERGENCY OVERVIEW:
-------------------
Clear Liquid With Hydrocarbon Odor. May Be Dyed For Identification.
Danger! Harmful or Fatal If Swallowed. Aspiration Hazard If
Swallowed--Can Enter Lungs and Cause Damage. May Be Irritating To the
Eyes and Respiratory Tract. Causes Skin Irritation. Vapors May Be
Harmful. Possible Cancer Hazard - Contains Material Which May Cause
Cancer Based On Animal Data. Combustible Liquid & Vapor.

-------------------------
SKIN:
-----
Repeated or prolonged contact may result in defatting, redness,
itching, inflammation, cracking and possible secondary infection. May
cause allergic reactions in some individuals. Absorption from
prolonged or massive skin contact may cause poisoning. High pressure
skin injections are Serious Medical Emergencies. Injury may not
appear serious at first; within a few hours, tissue will become
swollen, discolored and extremely painful (see Notes to Physician
section).
EYE:
----
Exposure to vapors, fumes or mists may cause irritation.
INHALATION:
-----------
May cause respiratory tract irritation. Exposure may cause central
nervous system symptoms similar to those listed under "Ingestion"
(see Ingestion section). Degenerative changes in the liver, kidneys
and bone marrow may occur with prolonged, high concentrations.
Repeated or prolonged exposures may cause behavioral changes.
INGESTION:
----------
Aspiration into lungs may cause pneumonitis. May cause
gastrointestinal disturbances. Symptoms may include irritation,
nausea, vomiting and diarrhea. May cause harmful central nervous
system effects. Effects may include excitation, euphoria, headache,
dizziness, drowsiness, blurred vision, fatigue, tremors, convulsions,
loss of consciousness, coma, respiratory arrest and death.
SPECIAL TOXIC EFFECTS:

----------------------
Based on animal studies, repeated overexposure may produce skin
tumors upon repeated and prolonged skin contact in the absence of
good personal hygiene. However, long-term dermal application studies
of similar materials, i.e. middle distillates, in animals have shown
that skin tumors are produced only when marked and prolonged skin
irritation takes place during the study. Therefore, this product
should not present a significant hazard of skin tumor formation when
the "Skin Protection" recommendations are followed. IARC has
determined that diesel engine exhaust is probably carcinogenic to
humans. (IARC Class- 2A). Lifetime exposure to whole diesel exhaust
has been shown to cause cancer in laboratory animals. NIOSH
recommends that whole diesel exhaust be regarded as a potential
occupational carcinogen. Warning: The use of any hydrocarbon fuel in
an area without adequate ventilation may result in hazardous levels
of combustion products and inadequate oxygen levels. IARC has
determined that occupational exposures in petroleum refining are
probably carcinogenic to humans.
======================== FIRST AID MEASURES ==========================
SKIN:
-----
Remove contaminated clothing immediately. Wash area of contact
thoroughly with soap and water. Get medical attention if irritation
persists. High pressure skin injections are serious medical
emergencies. Thermal burns require immediate medical attention. Get
EYE:
----
Flush immediately with large amounts of water for at least 15
minutes. Eyelids should be held away from the eyeball to ensure
thorough rinsing. Get medical attention if irritation persists.
Thermal burns require immediate medical attention.
INHALATION:
-----------
Remove affected person from source of exposure. If not breathing,
ensure clear airway and institute cardiopulmonary resuscitation (CPR).
If breathing is difficult, administer oxygen if available. After
administration of oxygen, continue to monitor closely. Get medical
attention.
INGESTION:
----------
Do not induce vomiting because of danger of aspirating liquid into
lungs. Get immediate medical attention. If spontaneous vomiting
occurs, monitor for breathing difficulty.
NOTES TO PHYSICIAN:
-------------------
In case of ingestion, gastric lavage with activated charcoal can be
used promptly to prevent absorption. Consideration should be given to
the use of an endotracheal tube, to prevent aspiration. Individuals
intoxicated by Diesel Fuel No. 2 should be hospitalized immediately,
with acute and continuing attention to neurologic and cardiopulmonary
function. Positive pressure ventilation may be necessary. After the
initial episode, individuals should be followed for changes in blood
variables and the delayed appearance of pulmonary edema and chemical
pneumonitis. Such patients should be followed for several days or
weeks for delayed effects, including bone marrow toxicity, hepatic
and renal impairment. Individuals with chronic pulmonary disease will
be more seriously impaired, and recovery from inhalation exposure may
be complicated. In case of skin injection, prompt debridement of the
wound is necessary to minimize necrosis and tissue loss.
======================= FIREFIGHTING MEASURES ========================
FLASH POINT: 51.7 C (125.06 F)

AUTOIGNITION TEMPERATURE: ND
FLAMMABILITY LIMITS IN AIR (% BY VOL.) LOWER: > 0.7
FLAMMABILITY LIMITS IN AIR (% BY VOL.) UPPER: < 5

------------------------------
Combustion may produce CO, CO2 and reactive hydrocarbons.
BASIC FIRE FIGHTING PROCEDURES:

-------------------------------
Use water spray, dry chemical, foam or carbon dioxide to extinguish
fire. Use water spray to cool fire-exposed containers, structures and
to protect personnel. If leak or spill has not ignited, ventilate
area and use water spray to disperse gas or vapor and to protect
personnel attempting to stop leak. Use water to flush spills away
from sources of ignition. Do not flush down public sewers or other
drainage systems. Exposed firefighters must wear MSHA/NIOSH approved
positive pressure self-contained breathing apparatus with full face
mask and full protective clothing.
UNUSUAL FIRE & EXPLOSION HAZARDS:

---------------------------------
Irritating and/or toxic substances may be emitted upon thermal
decomposition. Dangerous when exposed to heat or flame. Runoff to
sewer may cause fire or explosion hazard. Containers may explode in
heat of fire.
==================== ACCIDENTAL RELEASE MEASURES =====================
If your facility or operation has an "Oil or Hazardous Substance

Contingency Plan", activate its procedures. Take immediate steps to
stop and contain the spill. Caution should be exercised regarding
personnel safety and exposure to the spilled material. For technical
advice and assistance related to chemicals, contact CHEMTREC
(800/424-9300) and your local fire department. Notify the National
Response Center, if required. Also notify appropriate state and local
regulatory agencies, the LEPC and the SERC. Contact the local Coast
Guard if the release is into a waterway. Keep unnecessary people
away; isolate hazard area and deny entry. Stay upwind; keep out of
low areas. (Also see Personal Protection Information section.)
Shut off ignition sources; no flares, smoking or flames in hazard
area. Stop leak if you can do it without risk. Water spray may reduce
vapor; but it may not prevent ignition in closed spaces. Small
Spills: Take up with sand or other noncombustible absorbent material
and place into containers for later disposal. Large Spills: Dike far
ahead of liquid spill for later disposal.
When reporting a spill to the National Response Center or the Coast

Guard, you may need to supply the Coast Guard Chemical Hazard
Response Information System (CHRIS) code:
Group Number: 33
CHRIS Code: OTD
Additional spill related information may be found in the U.S. Coast

Guard Chemical Hazard Response Information System (CHRIS) Manual.
During an accidental release, personal protection equipment may be

required (see Section EXPOSURE CONTROLS/PERSONAL PROTECTION).
Additional regulatory requirements may apply (see Section REGULATORY
INFORMATION).
======================= HANDLING AND STORAGE =========================
HANDLING:
---------
Use non-sparking tools. Ground lines and equipment used during
transfer to reduce the possibility of static spark-initiated fire or
explosion.
Empty containers may contain toxic, flammable/combustible or

explosive residue or vapors. Do not cut, grind, drill, weld, reuse
or dispose containers unless adequate precautions are taken against
these hazards.
STORAGE:
--------
Store in tightly closed containers in cool, dry, isolated,
well-ventilated area away from heat, sources of ignition and
incompatibles.
============== EXPOSURE CONTROLS / PERSONAL PROTECTION ===============
ENGINEERING CONTROLS:
---------------------
Ventilation may be used to control or reduce airborne concentrations.
PERSONAL PROTECTION EQUIPMENT (PPE):

------------------------------------
EYE PROTECTION:
---------------
Wear safety glasses or chemical goggles to prevent eye contact. Do
not wear contact lenses when working with this substance. Have eye
washing facilities readily available where eye contact can occur.
SKIN PROTECTION:
----------------
Wear impervious gloves and protective clothing to prevent skin
contact.
RESPIRATORY PROTECTION:
-----------------------
NIOSH/MSHA approved breathing equipment may be required for
non-routine and emergency use.
See Section COMPOSITION/INFORMATION ON INGREDIENTS For Exposure

Guidelines.
================= PHYSICAL AND CHEMICAL PROPERTIES ===================
BOILING POINT: 160 C (320 F)

SP. GRAVITY (Water=1): 0.84 - 0.88 @ 15.56 C (60.008
F)
MELTING POINT: NA
% VOLATILE: Negligible
VAPOR PRESSURE: 0.4 MM HG @ 20 C (68 F)
EVAPORATION RATE: Slower
VAPOR DENSITY (Air=1): 4.7
VISCOSITY: 1.2 - 4.6 CST @ 37.8 C (100.04
F)
% SOLUBILITY IN WATER: Negligible
POUR POINT: -12.22 C (10.004 F)
pH: NEUTRAL
MOLECULAR WEIGHT: NA
MOLECULAR FORMULA: Mixture
ODOR/APPEARANCE:
Clear Liquid With Hydrocarbon Odor. May Be Dyed For Identification.
===================== STABILITY AND REACTIVITY =======================
STABILITY/INCOMPATIBILITY:
--------------------------
Stable. Avoid contact with strong oxidizers.
HAZARDOUS REACTIONS/DECOMPOSITION PRODUCTS:

-------------------------------------------
Thermal decomposition or combustion may produce CO, CO2 and reactive
hydrocarbons.
===================== TOXICOLOGICAL INFORMATION ======================
OTHER:
------
An extensive profile which characterizes adverse health effects
information for this material has been prepared by the Agency for
Toxic Substances Disease Registry (ATSDR). Individuals interested in
a summary of the toxicology of this material should reference this
document. This profile can be obtained from the National Technical
Information Services (NTIS).
====================== DISPOSAL CONSIDERATIONS =======================
WASTE DISPOSAL (Resource Conservation & Recovery Act - RCRA):

-------------------------------------------------------------
This material, when discarded or disposed of, is a characteristic
hazardous waste according to Federal regulations (40 CFR 261). This
material exhibits the characteristic of ignitability and is assigned
the EPA Hazardous Waste Number of D001. The discarding or disposal of
this material must be done at a properly permitted facility in
accordance with the regulations of 40 CFR 262, 263, 264, and 268.
Additionally, the discarding or disposal of this material may be
further regulated by state, regional, or local regulations. Chemical
additions, processing or otherwise altering this material may make
the waste management information presented in this MSDS incomplete,
inaccurate, or otherwise inappropriate. The transportation, storage,
treatment and disposal of this waste material must be conducted in
compliance with all applicable Federal, state, and local regulations.
There may be specific current regulations at the local, regional, or

state level that pertain to this information. Chemical additions,
processing, or otherwise altering this material may make the waste
management information presented in this MSDS, incomplete,
inaccurate, or otherwise inappropriate.
======================= TRANSPORT INFORMATION ========================
U.S. DEPARTMENT OF TRANSPORTATION (D.O.T.):

-------------------------------------------
Proper Shipping Name (49 CFR 172.101): Fuel Oil (No. 2)
Hazard Class (49 CFR 172.101): 3
UN/NA Code (49 CFR 172.101): NA 1993
Packing Group (49 CFR 179.101): PG III
Bill Of Lading Desc. (49 CFR 172.101): Fuel Oil (No. 2), 3, NA 1993,
PG III
Labels Required (49 CFR 172.101): Not Regulated
Placards Required (49 CFR 172.101): Combustible
INTERNATIONAL AND DOMESTIC AIR TRANSPORTATION:

----------------------------------------------
IATA Proper Shipping Name: Diesel Fuel
Hazard Class: 3
Subsidiary Risk: NA
UN Code: UN 1202
Package Specification: 309, 310
Labels Required: Flammable Liquid, Orientation
Arrows
INTERNATIONAL WATER TRANSPORTATION:

-----------------------------------
IMDG Proper Shipping Name: Diesel Fuel
Hazard Class: 3.3
UN Code: UN 1202
IMDG Page Number: 3375
Labels Required: Flammable Liquid
Placards Required: Flammable
CANADIAN TRANSPORTATION OF DANGEROUS GOODS (T.D.G.):

----------------------------------------------------
Shipping Name: Fuel Oil, No. 2
PIN (UN/NA): UN 1202
Regulated Class: 3
Division: NA
Packaging Group: PG III
Labels Required: Flammable Liquid
Placards Required: Flammable
====================== REGULATORY INFORMATION ========================
NOTIFICATION:
-------------
Any spill or release, or substantial threat of release, of this
material to navigable water (virtually any surface water) sufficient
to cause a visible sheen upon the water must be reported immediately
to the National Response Center (800/424-8802), as required by U.S.
Federal Law. Failure to report may result in substantial civil and
criminal penalties. Also contact the Coast Guard and appropriate
state and local regulatory agencies.
US EPA TOXIC SUBSTANCE CONTROL ACT (TSCA):

------------------------------------------
All components of this product are listed on the TSCA inventory.
US EPA SUPERFUND AMENDMENTS & REAUTHORIZATION ACT (SARA) TITLE III

INFORMATION:
Listed below are the hazard catagories for SARA Section 311/312 (40
CFR 370):
Immediate Hazard: X
Delayed Hazard: X
Fire Hazard: X
Pressure Hazard: -
Reactivity Hazard: -
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA):

---------------------------------------------
All components of this product are listed on the Canadian DSL or
NDSL inventories.
CANADIAN WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS)

CATEGORIES:
The following WHMIS categories apply to this product:
Compressed Gas: - Other Toxic Effects: X
Flammable/Combustible: X Bio Hazardous: -
Oxidizer: - Corrosive: -
Acutely Toxic: X Dangerously Reactive: -
========================= OTHER INFORMATION ==========================
NFPA RATINGS: HMIS RATINGS:

Health: 0 Health: 0
Flammability: 2 Flammability: 2
Reactivity: 0 Reactivity: 0
Special Hazards: - Personal Protective Equipment:H
REVISION DATE: 27-sep-1996

REPLACES SHEET DATED: 17-feb-1995
COMPLETED BY: BP OIL HSEQ DEPARTMENT
REVISION SUMMARY: The following section(s) have been revised since
the previous issue of this MSDS:
HAZARDS IDENTIFICATION
FIRST AID MEASURES
EXPOSURE CONTROLS / PERSONAL PROTECTION
STABILITY AND REACTIVITY
TOXICOLOGICAL INFORMATION
DISPOSAL CONSIDERATIONS
TRANSPORT INFORMATION
REGULATORY INFORMATION
OTHER INFORMATION
NOTICE: The information presented herein is based on data

considered to be accurate as of the date of preparation of this
Material Safety Data Sheet. However, no warranty or representation,
express or implied, is made as to the accuracy or completeness of
the foregoing data and safety information, nor is any authorization
given or implied to practice any patented invention without a
license. In addition, no responsibility can be assumed by vendor
for any damage or injury resulting from abnormal use, from any
failure to adhere to recommended practices, or from any hazards
inherent in the nature of the product.
ND: No Data NA: Not Applicable *See specific note or section

Conforms to 93/112/EC and ISO 11014-1 United Kingdom SDS EU CONTEXTUAL / ENGLISH / ENGLISH
SAFETY DATA SHEET

PYROLYSIS GASOLINE, CRUDE (KRACKBENZIN, ROH)
1. Identification of the substance/preparation and of the company/undertaking

Product name PYROLYSIS GASOLINE, CRUDE (KRACKBENZIN, ROH)
SDS # 0000000031
Historic SDS#: 745786 (ERDÖLCHEMIE)
Manufacturer : EC Erdölchemie GmbH
Postfach 750212
D-50754 Cologne
GERMANY
Supplier : BP Chemicals Ltd.
European Customer Service Centre
Chertsey Road
Sunbury-on-Thames
Middlesex TW16 7LL
UNITED KINGDOM
EMERGENCY TELEPHONE NUMBER : 01482-896251 (BPC Hull)
OTHER PRODUCT INFORMATION : Tel.: +44-(0)1932-767300
Fax: +44-(0)1932-767801
e-mail: bpcares@bp.com
2. Composition/information on ingredients
Chemical name* CAS No. % EC Number Symbol R-Phrases
1) NAPHTHA (PETROLEUM), LIGHT STEAM-CRACKED 64742-83-2 100 265-187-5 F, T R11, R22, R45, R65
Contains:
2) Benzene 71-43-2 10-50 200-753-7 F, T R11, R45, R48/23/24/25
* Occupational Exposure Limit(s), if available, are listed in Section 8
3. Hazards identification
Physical/chemical Hazards : Highly flammable.
Human health hazards : Inhalation of vapour/aerosol concentrations above the recommended exposure limits causes headaches, drowsiness, and
nausea, and may lead to unconsciousness or death. Aspiration of this material into the lungs may cause chemical pneumonia
and can be fatal. Aspiration into the lungs can occur while vomiting after ingestion of this material.
Causes eye irritation. Causes skin irritation. CANCER HAZARD.
CAN CAUSE CANCER. Harmful if absorbed through the skin. Repeated or prolonged exposure to the substance can produce
blood disorders.
Effects and symptoms
Eyes : Causes eye irritation.
Skin : Causes skin irritation. CANCER HAZARD.
CAN CAUSE CANCER. Repeated or prolonged exposure to the substance can produce blood disorders.
Inhalation : Inhalation of vapour/aerosol concentrations above the recommended exposure limits causes headaches, drowsiness, and
nausea, and may lead to unconsciousness or death. Causes respiratory tract irritation. CANCER HAZARD.
Ingestion : Aspiration of this material into the lungs may cause chemical pneumonia and can be fatal. Aspiration into the lungs can occur
while vomiting after ingestion of this material.
Ingestion may cause gastrointestinal irritation and diarrhoea. CANCER HAZARD.
Date of issue : 8/31/2001. Page: 1/5

PYROLYSIS GASOLINE, CRUDE
(KRACKBENZIN, ROH)
4. First-aid measures
First-Aid measures
Eye Contact : In case of contact, immediately flush eyes with a copious amount of water for at least 15 minutes. Obtain medical attention
immediately.
Skin contact : In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing
before reuse. Contaminated leather, particularly footwear, must be discarded. Note that contaminated clothing may be a fire
hazard. Get medical attention if irritation develops.
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Obtain
medical attention immediately.
Ingestion : If swallowed, do NOT induce vomiting. Never give anything by mouth to an unconscious person. If large quantities of this
material are swallowed, call a physician immediately.
5. Fire-fighting measures
Extinguishing Media
Suitable : In case of fire, use water spray (fog), foam, dry chemical, or CO2.
Hazardous decomposition products : These products are carbon oxides (CO, CO2).
Unusual fire/explosion Hazards : Highly flammable liquid and vapour. Vapours may form explosive mixtures with air. Vapour may cause flash fire. Vapours
may accumulate in low or confined areas, travel a considerable distance to a source of ignition and flash back. Runoff to sewer
may create fire or explosion hazard. Container explosion may occur under fire conditions or when heated.
Special fire-fighting procedures : None identified.
Protection of fire-fighters : Fire fighters should wear self-contained positive pressure breathing apparatus (SCBA) and full turnout gear. Firefighters'
protective clothing will provide limited protection. DO NOT FIGHT FIRE WHEN IT REACHES MATERIAL. Withdraw from fire
and let it burn. Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire.
6. Accidental release measures

Large Spill and Leak : Eliminate all ignition sources. Immediately contact emergency personnel. Keep unnecessary personnel away. Use suitable
protective equipment (Section 8). Follow all fire fighting procedures (Section 5). Do not touch or walk through spilled material.
For small spills add absorbent (soil may be used in the absence of other suitable materials) and use a non-sparking or explosion
proof means to transfer material to a sealed, appropriate container for disposal. For large spills dike spilled material or otherwise
contain material to ensure runoff does not reach a waterway. Place spilled material in an appropriate container for disposal.
Minimize contact of spilled material with soils to prevent runoff to surface waterways. See Section 13 for Waste Disposal
Information.
Personal Protection in Case of a Large : Splash goggles. Full suit. Boots. Gloves. A self-contained breathing apparatus should be used to avoid inhalation of the
Spill product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product.
7. Handling and storage

Handling : Keep away from heat, sparks and flame. Keep container closed. Use only with adequate ventilation. To avoid fire or
explosion, dissipate static electricity during transfer by earthing and bonding containers and equipment before transferring
material. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Wash thoroughly after handling.
Storage : Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep container tightly closed and
sealed until ready for use. Avoid all possible sources of ignition (spark or flame).
Packaging materials
Recommended use : Not applicable.
8. Exposure controls/personal protection

Engineering measures : Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapours below their respective
threshold limit value. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures : Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking, using lavatory, and at the
end of day.
Ingredient Name Occupational Exposure Limits
1) BENZENE EH40-MEL (United Kingdom (UK), 2001).
MEL: 3 ppm
MEL: 10 mg/m3
Personal protective equipment
Respiratory system : Use with adequate ventilation. Avoid breathing vapour or mist. If operating conditions cause high vapour concentrations or
TLV is exceeded, use supplied-air respirator.

(KRACKBENZIN, ROH)
Skin and body : Avoid contact with skin. Wear clothing and footwear that cannot be penetrated by chemicals or oil.
Hands : Wear gloves that cannot be penetrated by chemicals or oil.
Eyes : Avoid contact with eyes. Chemical splash goggles.
9. Physical and chemical properties

Autoignition temperature : 240°C (464°F)
Flash point : OPEN CUP: <-20°C (-4°F).
Fire Hazards in Presence of Various : Highly flammable in presence of open flames, sparks and static discharge, of heat.
Substances
Explosion Limits : LOWER: 0.6% UPPER: 8%
Colour : Colourless to light yellow.
Odour : Petrol
Physical state : Liquid.
Boiling point : 40 to 220°C (104 to 428°F)
Melting point : May start to solidify at 5.61°C (42.1°F) based on data for: (Benzene)
Density : 0.75 to 0.95 g/cm3 at 20°C
Vapour density (Air = 1) : The highest known value is 2.77 (Air = 1) (Benzene)
Vapour pressure : 40-70 kPa at 38C
Evaporation Rate : 3.5 (Benzene) compared to (n-BUTYL ACETATE=1)
Solubility : Insoluble in cold water.
Viscosity : Dynamic: 0.45 to 0.65 cP at 20°C
10. Stability and reactivity

Conditions to Avoid : Keep away from sources of ignition. Keep away from heat, sparks and flame. Keep container tightly closed and in a
well-ventilated place.
Incompatibility with Various Substances : Highly reactive with oxidizing agents.
Hazardous Polymerization : Will not occur.
11. Toxicological information

Acute toxicity : Acute oral toxicity (LD50): 3800 mg/kg [Rat]. (Benzene).
Acute toxicity of the vapour (LC50): 10000 ppm 4 hours [Rat]. (Benzene).
Benzene: Acute toxicity of benzene results primarily from depression of the central nervous system (CNS). Inhalation of
concentrations over 50 ppm can produce headache, lassitude, weariness, dizziness, drowsiness, or excitation. Exposure to very
high levels can result in unconsciousness and death.
Chronic toxicity : Benzene: Long-term overexposure to benzene has been associated with certain types of leukemia in humans. In addition, the
International Agency for Research on Cancer (IARC), the National Toxicology Program, and OSHA consider benzene to be a
human carcinogen. Chronic exposures to benzene at levels of 100 ppm and below have been reported to cause adverse blood
effects including anemia. Benzene exposure can occur by inhalation and absorption through the skin.
Inhalation and forced feeding studies of benzene in laboratory animals have produced a carcinogenic response in a variety of
organs, including possibly leukemia, other adverse effects on the blood, chromosomal changes and some effects on the
immune system. Exposure to benzene at levels up to 300 ppm did not produce birth defects in animal studies; however,
exposure to the higher dosage levels (greater than 100 ppm) resulted in a reduction of body weight of the rat pups (fetotoxicity).
Changes in the testes have been observed in mice exposed to benzene at 300 ppm, but reproductive performance was not
altered in rats exposed to benzene at the same level.
Carcinogenic effects : CANCER HAZARD
CONTAINS MATERIAL WHICH CAN CAUSE CANCER Risk of cancer depends on duration and level of exposure.
Classified A1 (Confirmed for humans.) by ACGIH, 1 (Proven for humans.) by IARC, 1 (Known To Be Human Carcinogens.) by
NTP, + (Proven.) by OSHA, + (Proven.) by NIOSH, 1 (Proven for humans.) by European Union [Benzene].
EU Category 1: Known to be carcinogenic to humans.

(KRACKBENZIN, ROH)
12. Ecological information

Ecotoxicity :
(EC50): 200 mg/l, 48 hours [Daphnia].
Mobility : This product is not likely to move rapidly with surface or groundwater flows because of its low water solubility of:< 0.1%.
This product is likely to volatise rapidly into the air because of its high vapour pressure.
13. Disposal considerations

Methods of disposal ; Waste of residues ; : Dispose of in accordance with all applicable local and national regulations. Empty containers may contain harmful,
Contaminated packaging flammable/combustible or explosive residue or vapours. Do not cut, grind, drill, weld, reuse or dispose of containers unless
adequate precautions are taken against these hazards.
Waste Classification : Not applicable.
14. Transport information

International transport regulations
Land - Road/Railway
UN number : UN3295
Proper shipping name : Hydrocarbons, liquids, n.o.s. (Contains Benzene)
ADR/RID Class : 3
Packing group : II
CEFIC Tremcard Number: : Not available.
UK Emergency Action Code: : Not available.
Sea
IMDG Class : 3
UN number : UN3295
Packing group : II
Medical First Aid Guide (MFAG) : 310 312
Emergency Schedules (EmS) : 3-07

Marine pollutant : Not pollutant.
Air
IATA-DGR Class : 3
UN/ID number : UN3295
Packing group : II
Inland waterways
UN/ID number : UN3295
ADNR Classification : 3
15. Regulatory information

EU Regulations
Hazard symbol(s) :
Classification : Highly flammable, Toxic

(KRACKBENZIN, ROH)
Risk Phrases : R11- Highly flammable.
R22- Harmful if swallowed.
R45- May cause cancer.
R48/23/24/25- Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if
swallowed.
R65- Harmful: may cause lung damage if swallowed.
Safety Phrases : S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
S53- Avoid exposure - obtain special instructions before use.
S62- If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
Contains : Benzene
Product Use : Classification and labelling have been performed according to EU directives 67/548/EEC, 88/379/EEC, including amendments
and the intended use.
- Industrial applications.
P99- Restricted to professional users. Attention - Avoid exposure - obtain special instructions before use.
Other Regulations
Regulatory Lists : AUSTRALIAN INVENTORY (AICS): Listed on inventory.
CANADA INVENTORY (DSL): Not listed.
CHINA INVENTORY (IECS): Not listed.
EC INVENTORY (EINECS/ELINCS): Listed on inventory.
JAPAN INVENTORY (ENCS): Not listed.
KOREA INVENTORY (ECL): Listed on inventory.
PHILIPPINE INVENTORY (PICCS): Not listed.

US Regulations
US INVENTORY (TSCA): Listed on inventory.
16. Other information

HISTORY
Date of issue : 8/31/2001.
Date of previous issue : 8/31/2001.
Version : 1
Prepared by : Product Stewardship and Toxicology
Notice to Reader
NOTICE : This Material Safety Data Sheet is based upon data considered to be accurate at the time of its preparation. Despite our efforts, it may not be up to date or
applicable to the circumstances of any particular case. We are not responsible for any damage or injury resulting from abnormal use, from any failure to follow appropriate
practices or from hazards inherent in the nature of the product. This Material Safety Data Sheet conforms with the requirements of Directive 93/112/EC.
Version 1 Page: 5/5
062 22 1
Sheet No: STI2211 Material Name: Pyrolysis Gasoline Issue Date : 17/07/2000 Revision of Sheet Dated:15/09/98 Page:
ALIGN BP SDS Finals


Material Name: Pyrolysis Gasoline
________________________________________________________________________________
SAFETY DATA SHEET
Pyrolysis Gasoline
COMPANY/UNDERTAKING
Pyrolysis Gasoline
Application
Britannic House
1 Finsbury Circus
London, EC2M 7BA

+44 (0) 20 7496 4411
_________________________________________________________________________________
Gasoline, pyrolysis, debutanizer bottoms, EINECS No. 271-726-5, CAS No: 68606-10-0

_________________________________________________________________________________
Eyes
Skin
Ingestion
Inhalation
Medical Advice
_________________________________________________________________________________


Combustion Products
_________________________________________________________________________________
etc.).

_________________________________________________________________________________

Storage Conditions


Fire Prevention
_________________________________________________________________________________

Exposure Limits
Gasoline
Benzene
Protective Clothing


_________________________________________________________________________________

Typical Values
Grades: Pyrolysis
Gasoline
Test Method Units
Colour amber
Odour gasoline-like
Vapour pressure ASTM D 323 kPa 20 - 80
Vapour density rel. to ASTM >1
air D2463/D2421
_________________________________________________________________________________

Conditions to Avoid
Sources of ignition
Materials to Avoid

_________________________________________________________________________________
Eyes
Skin


Ingestion
diarrhoea.
Inhalation
ABUSE:
leukaemia.
_________________________________________________________________________________
Mobility

Aquatic toxicity
impaired.

_________________________________________________________________________________
local regulations.
_________________________________________________________________________________


_________________________________________________________________________________
Extremely flammable
Harmful
Irritant
EU Labelling
Symbol:
Flame
Dead tree and fish
EXTREMELY FLAMMABLE
Risk ( R ) Phrases:
Substance name: Gasoline, pyrolysis, debutanizer bottoms, EINECS No: 271-726-5
_________________________________________________________________________________

Compiled by:
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
Sheet Revisions
15/09/98 1, 3, 7, 8, 10, 12, 14, 15
17/07/2000 3, 4, 7, 8, 11, 15
SHEET NO: STI2211

______________________________________________________________________________

Sheet No: STI2219 Material Name: Reformate Issue Date : 17/07/2000 Revision of Sheet Dated:15/09/98 Page:
ALIGN BP SDS Finals


Material Name: Reformate
________________________________________________________________________________
SAFETY DATA SHEET
Reformate
COMPANY/UNDERTAKING
Reformate
Application
Britannic House
1 Finsbury Circus
London, EC2M 7BA

+44 (0) 20 7496 4411
_________________________________________________________________________________
Naphtha (petroleum), light catalytic reformed. EINECS No: 265-065-1, CAS No: 64741-63-5
file:///C|/Documents%20and%20Settings/lanewg/My...il/Reformate%20Issue%20Date%20%2017-07-2000.htm (1 of 8) [29/01/2002 08:55:03]

_________________________________________________________________________________
Eyes
Skin
Ingestion
Inhalation
Medical Advice
_________________________________________________________________________________
Combustion Products


_________________________________________________________________________________
etc.).

_________________________________________________________________________________

Storage Conditions

Fire Prevention
_________________________________________________________________________________

Exposure Limits
Gasoline
Benzene
Protective Clothing
_________________________________________________________________________________

Typical Values
Grades: Reformate

Test Method Units

liquid
amber
Odour gasoline-like
air D2463/D2421
_________________________________________________________________________________

Conditions to Avoid
Sources of ignition
Materials to Avoid

_________________________________________________________________________________
Eyes
Skin
Ingestion
diarrhoea.
Inhalation
ABUSE:

leukaemia.
_________________________________________________________________________________
Mobility

Aquatic toxicity
impaired.

_________________________________________________________________________________
local regulations.
_________________________________________________________________________________
_________________________________________________________________________________
Extremely flammable
Harmful
Irritant
EU Labelling
Symbol:
Flame


Dead tree and fish
EXTREMELY FLAMMABLE
Risk ( R ) Phrases:
Substance name: Naphtha (petroleum), light catalytic reformed, EINECS No: 265-065-1
_________________________________________________________________________________
Compiled by:
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
Sheet Revisions


15/09/98 1, 3, 7, 8, 10, 12, 14, 15
17/07/2000 3, 4, 9, 15
SHEET NO: STI2219

______________________________________________________________________________

file:///C|/Documents%20and%20Settings/lanewg/My%20Documents/DA...QA%20Amendments/MSDS/White%20Oil/Straight%20Run%20Gasoline.htm

STRAIGHT RUN GASOLINE
CITGO
CITGO Petroleum Corporation

P. O. Box 3758
Tulsa, Oklahoma 74102
Material Safety Data Sheet
Trade Name: Straight Run Gasoline
Date: February 24 1998
CAS No.: 68606-11-1
Commodity Code No.: 07-001
Synonyms: Naphtha - SRG; Petroleum Naphtha; Straight Run Gasoline, SRG
CITGO Index No.: 0996
Technical Contact: (609) 224-7405

Medical Emergency: (918) 495-4700
CHEMTREC Emergency: (800) 424-9300
MATERIAL HAZARD EVALUATION

(Per OSHA Hazard Communication [29 CFR 1910.1200])
Health Precautions:
DANGER: BENZENE CANCER HAZARD. Harmful if swallowed. Do not ingest. If
swallowed, do not induce vomiting - call physician immediately. Inhalation
of vapors may result in blood abnormalities and central nervous system
depression. Material may be absorbed through the skin. This material may
contain Hydrogen Sulfide (H2S). At elevated concentrations, H2S acts as a
systemic poison and causes unconsciousness and death by respiratory
paralysis.
Safety Precautions:
DANGER: HIGHLY VOLATILE, FLAMMABLE LIQUID. Vapors are heavier than air and
may travel some distance to an ignition source and flash back.
HMIS Rating(1):
Health: 2*
Flammability: 3
Reactivity: 0
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1.0 GENERIC COMPOSITION / COMPONENTS
Refinery Stream CAS No. % Hazard Data
Gasoline, Straight Run 68606-11-1 100 Inhalation: Respiratory tract

[A complex combination irritant.
of hydrocarbons produced Eye: irritant
from the topping plant Dermal: Irritant
by the distillation of May cause anesthesia and
crude oil.] narcosis.
See specific component
information below.
(1) Hazard Rating: least-0; slight-1; moderate-2; high-3; extreme-4.
CITGO assigned these values based on an evaluation conducted pursuant to

NPCA guidelines. Use of an asterisk (*) indicates that the material may
present chronic health effects.
NA-Not Applicable
ND-No Data
NE-Not Established
Straight Run Gasoline (07-001; February 24, 1998; CIN: 0996)
Components CAS No. %
Hydrogen Sulfide 7783-06-4 ND
Benzene 71-43-2 0 - 1
Hexane, normal 110-54-3 0 - 2

(n-hexane)
Hexane isomers, mixed Mixture 0 - 7

(other than n-hexane)
Heptanes Mixture 0 - 12
Pentanes 109-66-0 and 0 - 5

78-78-4
Toluene 108-88-3 0 - 1
Xylenes, mixed isomers 1330-20-7 1 - 7
Octanes Mixture 1 - 15

Components Hazard Data
Hydrogen Sulfide Eye irritation (human): 4 to 100 ppm

Respiratory irritation
(human): 50 to 500 ppm
(potential pulmonary edema)
Bronchitis (human): 250 ppm
Severely toxic (human): 200 ppm
Coma and death (human): 500 to 1,000 ppm
Inhalation LC50 (rat): 444 ppm.
Inhalation LC50 (mouse): 673 ppm/1 hr.
Benzene Oral LD50 (mouse): 4,700 mg/kg

Oral LD50 (rat): 3,306 mg/kg
Inhalation LC50 (Acute-rat): 10,000 ppm/7 H
Inhalation LC50 (Acute-mouse):9,980 ppm
Eye: Irritant
Skin: Irritant
May be absorbed through skin.
Leukemogen, animal and suspected human
carcinogen.
Hexane, normal Inhalation TCLo (human): 190 ppm/8 wk.

(n-hexane) Inhalation LCLo (mouse): 120 g/M(3)
Dermal: Irritant
Peripheral nervous system effects
Hexane isomers, mixed Inhalation TCLo (human): 2,000 ppm/10 min.

(other than n-hexane) Oral, Acute (human): Low
Dermal: Irritant
Narcotic effects
Heptanes Inhalation LCLo (human): 1,000 ppm/6 min.

(CNS effects
reported.)
Inhalation LCLo (human): 4.8%/3 min.
Oral LD50 (human): 15 g/kg
Narcotic effects
Pentanes Inhalation LCLo (mouse): 325 g/M(3)/2 hr.

Dermal: Irritant
Narcotic effects
Toluene Inhalation LC50 (mouse): 5,320 ppm/8 hr.


Dermal LD50 (rabbit): 12,124 mg/kg

Dermal: Irritant
May be absorbed through skin.
Xylenes, mixed isomers Inhalation LC50 (rat): 5,000 ppm/4 hr.

Inhalation TCLo (human): 100 - 460 ppm (eye
and respiratory
tract effects)
Oral LDLo (human): 50 mg/kg
Dermal LD50 (rabbit): 14,100 mg/kg
Dermal: Irritant
Octanes Inhalation LC50 (RAT): 118 GM/m(3)/4 H

Dermal: Irritant
Narcotic effects
2.0 PHYSICAL DATA
PHYSICAL HAZARD CLASSIFICATION (Per 29 CFR 1910.1200)
Combustible No
Flammable Yes
Pyrophoric No
Compressed Gas No
Organic Peroxide No
Reactive No
Explosive No
Oxidizer No
Stable Yes
Boiling Range, 760 mm Hg, Deg. C (Deg. F): 38(100) - 196(384)
Melting Point, 760 mm Hg, Deg. C (Deg. F) ND
Specific Gravity (60/60 Deg. F) (H2O = 1): 0.78
Vapor Density (Air = 1): 3 - 4
% Volatiles by Volume: 100
Reid Vapor Pressure, mm Hg: ND
Solubility in Water: No
Evaporation Rate (n-butyl acetate = 1): ND
pH of Undiluted Product: NA

Appearance and Odor: Clear to straw color liquid with a gasoline-type

odor. The material may smell like rotten eggs when H2S is present in low
concentrations.
3.0 FIRE AND EXPLOSION DATA
Flash Point, CC, Deg. C (Deg. F)

<-18 (<0) (estimate based upon component data)
Autoignition Temperature, Deg. C (Deg. F)

280 (536) (estimate based upon component data)
NFPA Rating(2)
Health: 2
Flammability: 3
Reactivity: 0
Flammable Limits
Lower: 1.0
Upper: 7.6
(LFL and UFL estimates are based upon component information)
Extinguishing Media
Use dry chemical, foam or carbon dioxide. Water may be ineffective as an
extinguishing media but may be used to cool containers exposed to fire.
Special Fire Fighting Procedure

Wear self-contained breathing apparatus when in a confined area.
Unusual Fire or Explosion Hazard

Material is highly volatile and emits vapors which are heavier than air.
Vapors may travel along the ground and be ignited by remote ignition
sources. Use water spray to disperse vapors. This material may evolve
hydrogen sulfide. At elevated concentrations, H2S acts as a systemic
poison and causes unconsciousness and death by respiratory paralysis.
(2) Hazard Rating: least-0: slight-1; moderate-2; high-3; extreme-4.

CITGO assigned these values based upon an evaluation conducted pursuant to
NFPA guidelines.
4.0 REACTIVITY DATA
Stability: Stable.
Conditions Contributing to Instability: Heat, flame.
Incompatibility: Oxidizing agents.

Hazardous Decomposition and/or Combustion Products: CO2, CO, fumes, smoke,

and trace oxides of nitrogen and sulfur.
Hazardous Polymerization: Hazardous polymerization is not expected to

occur.
5.0 SPILL, LEAK AND DISPOSAL PROCEDURES
Procedure if Material is Spilled:
Remove sources of heat or ignition; provide ventilation; contain leak.
Small Spills: Absorb released material with non-combustible absorbent.

Place into containers for later disposal. (See Waste Disposal section
below.)
Large Spills: Evacuate area in the event of significant spills. Adequately

ventilate area and determine potential exposure conditions. Exposure
potential may require the use of respiratory protection. Use protective
clothing. Contain spill in temporary dikes to avoid product migration and
to assist in recovery. Do not allow material to escape into sewers, ground
water, drainage ditches or surface waters.
Control ignition sources around spill area. Use of a fire fighting foam
blanket on spilled material will reduce vapor release and fire potential.
OSHA HAZWOPER regulations may require establishing a regulated area with

site control.
Report spills as required to appropriate federal, state and local

authorities.
Waste Disposal:
It is the responsibility of the user to determine if the material is a

hazardous waste at the time of disposal.
Recovered non-usable material may be regulated by US EPA as a hazardous

waste due to its ignitability characteristics (D001) and/or its benzene
content (D018).
Transportation, treatment, storage and disposal of waste material must be

conducted in accordance with RCRA regulations (see 40 CFR 260 through 40
CFR 271).
State and/or local regulations may be more restrictive.

Contact the RCRA/Superfund Hotline at (800) 424-9346 or your regional US

EPA office for guidance concerning case specific disposal issues.
Protective Measures During Repair and Maintenance of Contaminated

Equipment:
Refer to Section 7.0 - Special Protection Information.
Drain and purge equipment as necessary to remove material residues.
Use nitrile gloves and protective clothing if direct contact is

anticipated.
Provide ventilation to maintain exposures below applicable workplace

exposure limits.
Eliminate heat and ignition sources.
Remove contaminated clothing.
Wash exposed skin thoroughly with soap and water.
Keep unnecessary persons from hazard area.
6.0 HEALTH HAZARD DATA
Health Hazard Classification (Per 29 CFR 1910.1200):

(Health Classifications are based upon component information.)
Highly Toxic No
Sensitizer No
Toxic Yes(a)
Reproductive Effects No
Corrosive No
Mutagen No
Irritant Yes
Target Organ (central nervous
system, hematopoietic system,
respiratory system, and
peripheral nervous system) Yes
(a) Toxic designation is based upon the H2S component.
Carcinogen:
Product/Component CAS No. Conc. (%) NTP IARC
Gasoline, Straight Run 68606-11-1 100 No 2B

Benzene 71-43-2 0 - 1 Group 1 Group 1
Product/Component OSHA Other
Gasoline, Straight Run No No
Benzene Yes A1 (ACGIH)

A (US EPA)
Toxicity Summary:
Subchronic inhalation of a component of this material, benzene, by rats
produced decreased white blood cell counts, decreased bone marrow cell
activity, increased red blood cell activity and cataracts. Chronic
inhalation or oral administration of benzene in rats produced cancers of
the liver, mouth and glands.
In humans, acute inhalation of benzene has caused nerve inflammation

(polyneuritis), central nervous system depression and cardiac
sensitization. The anesthetic action of benzene is similar to that of
other anesthetic gases, consisting of a preliminary stage of excitation
followed by depression and, if exposure is continued, death through
respiratory failure.
A component of this material, n-hexane, may cause damage to the peripheral

and central nervous systems. This component may be absorbed through the
skin and by inhalation.
This material may contain hydrogen sulfide (H2S). At elevated

concentrations, H2S acts as a systemic poison and causes unconsciousness
and death by respiratory paralysis.
Major Route(s) of Entry: Vapor inhalation and liquid skin contact.
Acute Exposure Symptoms:
Inhalation: Inhalation of vapors above applicable workplace exposure

levels may cause respiratory irritation. Inhalation to elevated
concentrations may cause euphoria, giddiness, headache, nausea, staggering
gait, weakness, central nervous system depression, dizziness, drowsiness,
pulmonary edema, convulsions, coma and paralysis. Human exposure to very
high concentrations may be fatal.
This material contains xylene. Xylene is irritating to the eyes, skin, and
mucous membranes. Over exposure to xylene can cause shortness of breath,
loss of appetite, nausea, vomiting, dermatitis, fatigue, headache,
dizziness, loss of coordination, irritability, slowed reaction time,

sleepiness and a decrease in red blood cells. In severe cases,

unconsciousness and death can occur.
Hydrogen sulfide (H2S) causes respiratory irritation. At low

concentrations, H2S has an odor of rotten eggs. At high concentrations,
H2S odor is not apparent. At concentrations above 500 ppm, H2S causes
unconsciousness and death by respiratory paralysis. NIOSH has determined
that atmospheres containing 100 ppm or more of H2S are immediately
dangerous to life and health.
Dermal: This material can cause skin irritation, inflammation and

blistering. The components benzene, n-hexane and toluene can be absorbed
through the skin.
Eye: May cause eye irritation with corneal injury. Small areas of
superficial cornea necrosis may also be noted. Liquid material entering
the eye may cause clouding of the cornea.
Ingestion: Symptoms may include a burning sensation of the mouth and

esophagus, nausea, vomiting, dizziness, staggering gait, somnolence, loss
of consciousness and delirium. Central nervous system effects include
visual disturbances and convulsions, excitement and euphoria with sudden
onset of weariness, fatigue and sleepiness followed by coma.
If swallowed, this material can enter the lungs by aspiration. Aspiration

can cause severe lung damage. Cardiovascular effects include shallow rapid
pulse and pallor followed by flushing. Progressive central nervous system
depression, respiratory insufficiency and ventricular fibrillation may
result in death.
Injection: Injection under the skin, in muscle or into the blood stream
can cause irritation, inflammation, swelling, fever, and systemic effects,
including pulmonary edema, pneumonia and mild central nervous system
depression. Injection of pressurized hydrocarbons can cause severe,
permanent tissue damage.
Chronic Exposure Symptoms:
Inhalation: Chronic exposure to the component benzene may result in

adverse effects of the blood, including anemia, decreased white blood cell
count, decreased platelets, aplastic anemia and leukemia. In addition,
chronic inhalation of vapors of the component benzene may cause fatigue,
nervousness, irritability, blurred vision and labored breathing.
Inhalation of the component n-hexane may cause severe degeneration of the

peripheral nervous system.

This material contains toluene. Laboratory animals demonstrated limited

evidence of fetal toxicity when exposed to elevated levels of toluene
during pregnancy. These effects include decreased fetal body weight and
increased skeletal variations. Developmental effects from massive exposure
to toluene in humans has been purported in cases of substance abuse.
Skin: Prolonged and repeated contact with the skin may cause redness,
blistering, dryness and/or scaly dermatitis. Overexposure of the component
n-hexane can cause peripheral nervous system damage and central nervous
system depression.
Other Special Effects:

The component n-hexane may cause damage to the peripheral nerves from
acute and chronic exposure. This effect may be characterized by numbness
in the arms and legs.
Medical Conditions Aggravated by Exposure:

Individuals with chronic skin or respiratory disorders may have their
condition aggravated by overexposure to this material.
First Aid and Emergency Procedures for Acute Effects:
Inhalation: Move victim to fresh air. If victim is not breathing,

immediately begin rescue breathing. If breathing is difficult, 100 percent
humidified oxygen should be administered by a qualified individual. Seek
medical attention immediately.
Dermal: Remove contaminated clothing. Wash exposed skin with soap and
water. Launder clothing before use. Seek medical attention if tissue
appears damaged or if irritation persists.
Eyes: Flush eyes with cool water while occasionally lifting and lowering
eyelids. Seek medical attention if excessive tearing, irritation or pain
persists.
Ingestion: Do not induce vomiting. If spontaneous vomiting is about to

occur, place victim's head below knees. Never give anything by mouth to a
person who is not fully conscious. Seek medical attention immediately.
Injection: Injection under the skin, in muscle or into the blood stream is
a medical emergency. Seek medical attention immediately.
Notes to Physician:
Inhalation: Toxic effects are produced by vapor inhalation. Monitor for

respiratory distress. If cough or difficulty in breathing develops,
evaluate for respiratory tract irritation, bronchitis, or pneumonitis.

Administer 100 percent humidified supplemental oxygen with assisted

ventilation as required. Obtain chest x-ray and liver function tests.
Monitor arterial blood gases with severe exposure. Monitor cardiac
function.
Exposure to high concentrations of this material may be associated with

cardiac arrhythmia. Epinephrine and other sympathomimetic drugs may
initiate cardiac arrhythmias in persons exposed to this material. The use
of other drugs with less arrhythmogenic potential should be considered. If
sympathomimetic drugs are administered, observe for the development of
cardiac arrhythmia
Ingestion: This material presents a high aspiration hazard. Aspiration may

produce chemical pneumonitis. Treatment may involve careful gastric lavage
if performed soon after ingestion, or in patients who are comatose or at
risk of convulsing. Protect airway by placement in Trendelenburg and left
lateral decubitus position or by cuffed endotracheal intubation.
7.0 SPECIAL PROTECTION INFORMATION
Applicable Workplace Exposure Levels:
ACGIH ACGIH TLV ACGIH

TLV TWA STEL/ TLV
ppm Ceiling (C) Skin
Chemical Component (mg/M(3)) ppm (mg/M(3)) notation?
Benzene 0.5 (1.6) 2.5 (8) Yes
Heptane 400 (1640) 500 (2050) No

(n-heptane)
Hexane isomers, 500 (1760) 1000 (3500) No

mixed (other
than n-hexane)
Hexane, normal 50 (176) NE No

(n-hexane)
Hydrogen Sulfide 10 (14) 15 (21) No
Octane (n-octane) 300 (1400) 375 (1750) No
Pentane (n-pentane) 600 (1770) 750 (2210) No
Toluene 50 (188) NE Yes
Xylenes, 100 (434) 150 (651) No

mixed isomers
OSHA OSHA PEL OSHA

PEL TWA STEL/ PEL
ppm Ceiling (C) Skin
Chemical Component (mg/M(3)) ppm (mg/M3) notation?
Benzene 1 (3) 5 (15) No
Heptane 500 (2000) NE No

(n-heptane)
Hexane isomers, NE NE No
mixed (other
than n-hexane)
Hexane, normal 500 (1800) NE No

(n-hexane)
Hydrogen Sulfide NE 20 (50)(C)10 No

min Peak/8H
Octane (n-octane) 500 (2350) NE No
Pentane (n-pentane) 1000 (2950) NE No
Toluene 200 (750) 300 (500)(C)10 No

min Peak/8H
Xylenes, 100 (435) NE No

mixed isomers
Ventilation Requirements: Use in well ventilated area. In confined space,

mechanical ventilation may be required to keep levels of certain
components below applicable workplace exposure levels as evaluated by
designated and properly trained personnel.
Specific Personal Protective Equipment: Personal protective equipment

should be selected based upon the conditions under which this material is
used. A hazard assessment of the work area for PPE requirements should be
conducted by a qualified professional pursuant to OSHA regulations.
Respirator: Only NIOSH or MSHA approved equipment should be used.

Respiratory protection is required if airborne concentrations of any
components are above the applicable workplace exposure levels listed
above. If H2S concentrations are anticipated above applicable workplace
exposure levels use only supplied air respiratory protection.

When considering benzene concentrations, selection and use of respiratory

equipment must be in accordance with OSHA Benzene Standard 29 CFR
1910.1028.
Eyes: Use chemical splash goggles to prevent contact with the eyes.
Dermal: Full body impervious clothing should be worn when handling

material. Use gloves constructed of impervious materials such as neoprene
or heavy nitrile rubber when direct contact is anticipated.
Clothing or Equipment: Wear body-covering work clothes to avoid prolonged

or repeated exposure. Launder contaminated work clothes before reuse.
8.0 TRANSPORTATION AND SPECIAL PRECAUTIONS
Storage: Do not use or store this product near heat, flame or other
potential ignition sources. Do not store with oxidizers. Do not store this
product in unlabeled containers. Keep container closed.
Danger: Flammable Liquid. Vapors are heavier than air and may travel some
distance to an ignition source and flash back. Use only in a well
ventilated area. Never siphon by mouth. Empty containers may contain
product residues which can ignite with explosive force. Consult
appropriate federal, state and local authorities before reusing,
reconditioning, reclaiming, recycling or disposing of empty containers
and/or residues of this product.
DOT Information:
Proper Shipping Name: Gasoline
Hazard Class: 3
Packaging Group: II
Hazard identification No.: UN 1203
Placard: Flammable Liquid
9.0 ENVIRONMENTAL DATA
Title III of the Superfund Amendments and Reauthorization Act of 1986

(SARA)
Section 313 - Toxic Chemicals:

This product is believed to contains the following components in
concentrations above de minimis levels that are listed as toxic chemicals
in 40 CFR Part 372 pursuant to the requirements of Section 313 of SARA:
Components CAS Nos. Concentration (%)

Benzene 71-43-2 0 - 1
n-hexane 110-54-3 0 - 2
Toluene 108-88-3 0 - 1
Xylenes 1330-20-7 1 - 7
Hydrogen Sulfide 7783-06-4 ND
Section 311/312 - Hazard Categories:
This product meets the criteria of one or more of the Hazard Categories as
defined by 40 CFR Part 370 as established by Sections 311 and 312 of SARA:
Acute (Immediate Health Hazard) Yes
Sudden Release of Pressure Hazard No
Chronic (Delayed Health Hazard) Yes
Reactive Hazard No
Fire Hazard Yes
Section 302 - Extremely Hazardous Substances:

This product may contain the following chemical components in
concentrations greater than one percent that are listed as Extremely
Hazardous Substances in 40 CFR Part 355 as established by Section 302 of
SARA
Component CAS No. Concentration (%) RQ (lb.) TPQ (lb.)
Hydrogen Sulfide 7783-06-4 ND 100 500
Clean Water Act (CWA):

Pursuant to Section 311(b) (4) of the CWA, discharges of crude oil and
petroleum products in any kind to surface waters must be immediately
reported to the National Response Center: (800) 424-8802.
Comprehensive Environmental Response Compensation & Liability Act (CERCLA)

- Hazardous Substances:
The following chemical components are identified as Hazardous Substances
in 40 CFR Part 302 as required by Section 102(a) of CERCLA. As defined in
CERCLA, the term "hazardous substance" does not include petroleum,
including crude oil or any fraction thereof which is not otherwise
specifically listed or designated as a hazardous substance.
Component CAS No. Concentration (%) RQ (lb.)
Benzene 71-43-2 0 - 1 10
Xylenes (mixed) 1330-20-7 1 - 7 100
Hydrogen Sulfide 7783-06-4 ND 100
Toluene 108-88-3 0 - 2 1,000
Toxic Substances Control Act (TSCA):

Reported in TSCA Inventory as: Product Components
Gasoline, Straight Run X
10.0 LABELING
DANGER:
CONTAINS BENZENE - CANCER HAZARD
FLAMMABLE LIQUID.
POISONOUS - CONTAINS H2S
Harmful or fatal if swallowed - can enter the lungs and cause damage.
Can cause skin, eye or respiratory tract irritation.
Target Organ(s): Hematopoietic system, respiratory system, and central
nervous system, peripheral nervous system.
HANDLING:
Keep away from heat, sparks and flames.
Keep container closed.
Do not breathe vapors or mists.
Prevent direct eye or skin contact with liquid or mists.
Use gloves, safety goggles, chemical resistant clothing and boots.
Use only with adequate ventilation.
FIRST AID:
Inhalation: Move victim from exposure. If breathing is interrupted,
provide CPR. Seek medical attention immediately.
Ingestion: If swallowed, do not induce vomiting. Seek medical attention

immediately.
Dermal: Wash exposed skin with soap and water. Seek medical attention if
Eyes: Flush immediately with large amounts of water. Seek medical

attention if pain or irritation persists.
ALL STATEMENTS, INFORMATION, AND DATA PROVIDED IN THIS MATERIAL SAFETY

DATA SHEET ARE BELIEVED TO BE ACCURATE AND RELIABLE, BUT ARE PRESENTED
WITHOUT GUARANTEE, REPRESENTATION, WARRANTY, OR RESPONSIBILITY OF ANY
KIND, EXPRESSED OR IMPLIED. ANY AND ALL REPRESENTATIONS AND/OR WARRANTIES
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE ARE SPECIFICALLY
DISCLAIMED. USERS SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE
SUITABILITY OF THE INFORMATION OR PRODUCTS FOR THEIR PARTICULAR PURPOSE.
NOTHING CONTAINED HEREIN IS INTENDED AS PERMISSION, INDUCEMENT OR
RECOMMENDATION TO VIOLATE ANY LAWS OR TO PRACTICE ANY INVENTION COVERED BY
EXISTING PATENTS, COPYRIGHTS OR INVENTIONS.

Sheet No: SUK2208 Date: 14/05/98 Name of Product: Straight run Kerosine
SAFETY DATA SHEET

___________________________________________________________________________
Straight Run Kerosine

Straight Run Kerosine
Application
Refinery stream

Coryton: +44 (0)1375 646000
Grangemouth: +44 (0)1324 483422
__________________________________________________________________________________
Kerosine (petroleum). EINECS No: 232-366-4, CAS No: 8008-20-6
Common refinery name: Light kero,
__________________________________________________________________________________
Flammable
__________________________________________________________________________________
Eyes
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Skin
Ingestion
Inhalation
If fumes are inhaled the patient should be removed to fresh air and if recovery is not immediate, medical assistance must
be called without delay. If breathing has failed respiration must be assisted, preferably by mouth to mouth method.
Medical Advice
__________________________________________________________________________________
Combustion Products
__________________________________________________________________________________
Spilled material may make surfaces slippery. Clean up spilled material immediately.

authorities.
In the event of spillages contact the appropriate authorities. If spillage occurs call the Environment Agency Emergency
__________________________________________________________________________________
Storage Conditions
quick rescue.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. These can cause flammability/explosion hazards even
at temperatures below the normal flash point (note: flash point must not be regarded as a reliable indicator of the potential
storage tanks.
__________________________________________________________________________________
Exposure Limits

Protective Clothing
starched after use.
__________________________________________________________________________________
Typical Values
Grades:Straight run Kerosine
Test Method Units
Physical state low viscosity liquid
Colour colourless --> pale yellow
Odour kerosine-like
approx
Flash point (Abel) ASTM D 3828 °C 21 - 55
Solubility in water g/l <0.02
Partition Coefficient (n- Log10Pow >3
octanol/water)
Conditions to Avoid
Materials to Avoid

__________________________________________________________________________________
Eyes

Skin
Ingestion
Inhalation
__________________________________________________________________________________
Mobility

Aquatic toxicity
Toxic to aquatic organisms. May cause long term effects in the aquatic environment

__________________________________________________________________________________
Dispose of product and container carefully and responsibly. Do not dispose of near ponds, ditches, down drains or onto
soil.
__________________________________________________________________________________
__________________________________________________________________________________
Flammable
Harmful

Irritant
EU Labelling
Symbol: St. Andrew's Cross, Dead tree and fish
Indication of danger: FLAMMABLE, HARMFUL, DANGEROUS FOR THE ENVIRONMENT
Risk ( R ) Phrases:
R10 Flammable
The label must carry the following additional information: "EC Label", Substance name, EINECS No. (232-366-4)
__________________________________________________________________________________
Compiled by:
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN

Sheet No: STI2218 Material Name: Straight-Run Naphtha Issue Date : 17/07/2000 Revision of Sheet Dated:22/09/98 Page:
ALIGN BP SDS Finals


Material Name: Straight-Run Naphtha
________________________________________________________________________________
SAFETY DATA SHEET
Straight-Run Naphtha
COMPANY/UNDERTAKING
Straight-Run Naphtha
Alternative Names: Light straight-run naphtha, Heavy straight-run naphtha, Full-range straight-run naphtha
Application
Petroleum feedstock or fuel blending component
Britannic House
1 Finsbury Circus
London, EC2M 7BA

+44 (0) 20 7496 4411
_________________________________________________________________________________

Naphtha (petroleum), heavy straight-run. EINECS No: 265-041-0, CAS No: 64741-41-9
Naphtha (petroleum), full-range straight-run. EINECS No: 265-042-6, CAS No: 64741-42-0
Naphtha (petroleum), light straight-run. EINECS No: 265-046-8, CAS No: 64741-46-4
_________________________________________________________________________________
Eyes
Skin
Ingestion
Inhalation
Medical Advice

develops.
_________________________________________________________________________________
Combustion Products
_________________________________________________________________________________
etc.).

_________________________________________________________________________________

Storage Conditions

Fire Prevention
_________________________________________________________________________________

Exposure Limits
Gasoline

Benzene
Hydrogen sulphide
Protective Clothing
_________________________________________________________________________________

Typical Values
Grades: Straight-Run
Naphtha
Test Method Units
liquid
amber
Odour gasoline-like /
pungent
Density @ 15°C ASTM D 1298 kg/m³ Approx 750
Boiling point/range ASTM D 86 °C 20 to 220
_________________________________________________________________________________

Conditions to Avoid
Sources of ignition

Materials to Avoid

_________________________________________________________________________________
Eyes
Skin
Ingestion
diarrhoea.
Inhalation
ABUSE:
leukaemia.
_________________________________________________________________________________
Mobility

Aquatic toxicity

impaired.

_________________________________________________________________________________
local regulations.
_________________________________________________________________________________
_________________________________________________________________________________
Extremely flammable
Harmful
Irritant
EU Labelling
Symbol:
Flame
Dead tree and fish
EXTREMELY FLAMMABLE
Risk ( R ) Phrases:


Substance name: Low boiling point naphtha, EINECS No: 265-041-0, 265-042-6, 265-046-8
_________________________________________________________________________________
Compiled by:
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
Sheet Revisions
22/09/98 1, 3, 4, 7, 8, 10, 11, 12, 14, 15
17/07/2000 1, 2, 3, 4, 9, 15
SHEET NO: STI2218

______________________________________________________________________________

Sheet No: STI2208 Material Name: Toluene Issue Date : 17/07/2000 Revision of Sheet Dated:28/12/95 Page:
ALIGN BP SDS Finals


Material Name: Toluene
________________________________________________________________________________
SAFETY DATA SHEET
Toluene
COMPANY/UNDERTAKING
Toluene
Application
Chemical feedstock
Britannic House
1 Finsbury Circus
London, EC2M 7BA

+44 (0) 20 7496 4411
_________________________________________________________________________________
Toluene, EINECS No. 203-625-9, CAS No. 108-88-3
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Highly flammable
May be irritating to eyes
May be irritating to the skin
_________________________________________________________________________________
Eyes
Skin
Wash off immediately with soap and water. Change heavily contaminated clothing and wash underlying skin.
Ingestion
Inhalation
Medical Advice
_________________________________________________________________________________
Combustion Products
_________________________________________________________________________________

etc.).

_________________________________________________________________________________

Storage Conditions
Fire Prevention


_________________________________________________________________________________

Exposure Limits
Toluene
ACGIH (USA): TLV 50ppm (8hr TWA)
A4 - Not classifiable as a human carcinogen
Skin Notation - Can be absorbed through skin.
BEI (Biological Exposure Indice) Substance
Protective Clothing
_________________________________________________________________________________

Typical Values
Grades: Toluene
Test Method Units
Colour colourless
Odour aromatic
Explosion limits % 1.3 - 7
Flash point (COC) ASTM D 92 °C 16
Boiling point/range °C 111
Melting point ASTM D 127 °C -95
_________________________________________________________________________________


Conditions to Avoid
Sources of ignition
Materials to Avoid

_________________________________________________________________________________
Eyes
May be irritating to the eyes
Skin
Can be absorbed via intact skin. Repeated or prolonged contact may cause skin irritation.
Ingestion
diarrhoea.
Inhalation
ABUSE:
_________________________________________________________________________________
Mobility

Aquatic toxicity
Harmful to aquatic organisms.
impaired.
_________________________________________________________________________________


Incineration may be carried out under controlled conditions provided that local regulations for emissions are met.
onto soil.
_________________________________________________________________________________
ADR/RID: Toluene, Flammable liquid, Class 3, Item 3(b), Hazard identification No 33
UN: Toluene, Flammable liquid, Class 3, Packing Group II, UN Number 1294
IATA/ICAO: Toluene, Flammable liquid, Class 3, Packing Group II
IMO: Toluene, Flammable liquid, Class 3.2, Packing Group II
HAZCHEM: Flammable liquid, 3[Y] E
_________________________________________________________________________________
Highly flammable
Harmful
EU Labelling
Symbol:
Flame
St. Andrew's Cross
HIGHLY FLAMMABLE
HARMFUL
Risk ( R ) Phrases:
R20 Harmful by inhalation
S25 Avoid contact with eyes.
S33 Take precautionary measures against static discharges
Substance name: Toluene, EINECS No: 203-625-9
_________________________________________________________________________________
Compiled by:


Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
Sheet Revisions
17/07/2000
SHEET NO: STI2208

REVISION OF SHEET DATED: 3, 4, 7, 8, 9, 11, 13, 14, 15
______________________________________________________________________________

Sheet No: SAV2105 Material Name: TS-1 Issue Date : 02/11/2000 Revision of Sheet Dated:12/11/99 Page
ALIGN BP SDS Finals


Material Name: TS-1
Hazardous Components: Physical Characteristics: Kero Tox File: 346.21 Product Group:
________________________________________________________________________________
SAFETY DATA SHEET
TS-1
COMPANY/UNDERTAKING
TS-1
Application
Jet fuel
Breakspear Park
Breakspear Way
Hemel Hempstead
Hertfordshire
HP2 4UL

+44 (0) 1442-22-5711

+44 (0) 1202 590558
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_________________________________________________________________________________
Xn R10 Flammable
(>90%)
_________________________________________________________________________________
Flammable
_________________________________________________________________________________
Eyes
Skin
Ingestion
Inhalation
Medical Advice
_________________________________________________________________________________

Use foam
Combustion Products
_________________________________________________________________________________
section 8
in basements etc.).
_________________________________________________________________________________

Storage Conditions
the safe handling

Avoid
drink or smoke.
Fire Prevention
cut
weld
_________________________________________________________________________________

Exposure Limits
If vapour
Protective Clothing


_________________________________________________________________________________

Typical Values
Grades: TS-1
Test Method Units
Colour yellow
Odour kerosine-like
Density @ 15°C ASTM D 1298 kg/m³ 775 min
Kinematic viscosity @ ASTM D 445 mm²/s 1.25 min
20°C
Freezing Point @ °C -60 max
_________________________________________________________________________________

Conditions to Avoid
Sources of ignition
Materials to Avoid

_________________________________________________________________________________
Eyes
mists or fumes.

Skin
Ingestion
Inhalation
mists or fumes.
_________________________________________________________________________________
Mobility

Aquatic toxicity
impaired.
_________________________________________________________________________________
ditches
At sea
_________________________________________________________________________________
ADR/RID: Kerosene
Flammable Liquid
Class 3
Item 31 (c)
UN: KEROSENE
Flammable liquid
Class 3
Packing Group III
UN Number 1223

IATA/ICAO: Kerosene
Flammable liquid
Class 3
Packing Group III
IMO: KEROSENE
Flammable liquid
Class 3.3
Packing Group III
3[Y]
_________________________________________________________________________________
Flammable
Harmful
Irritant
EU Labelling
Symbol:
St. Andrew's Cross
HARMFUL
Contains:
Risk ( R ) Phrases:
R10 Flammable
S43 In case of fire
S62 If swallowed
_________________________________________________________________________________
Compiled by:
Chertsey Road
Sunbury-on-Thames
Middlesex
TW16 7LN


Companies. However
sheet.
______________________________________________________________________________

file:///C|/Documents%20and%20Settings/lanewg/My%20Documents/DATA/QA%20Amendments/MSDS/White%20Oil/VM&P%20Naptha.htm

(Approved by U.S. Department of Labor ("Essentially Similar" to Form LSB-
OOS-4)
NPVLA 6-70
Section I
MANUFACTURER'S NAME
PARKS CORPORATION
STREET ADDRESS
ONE MAIN STREET
CITY, STATE, AND ZIP CODE

SOMERSET, MA. 02726
EMERGENCY TELEPHONE NO.

(617) 679-5938
CHEMICAL NAME AND SYNONYMS

PETROLEUM SOLVENT
TRADE NAME
VM&P NAPHTHA
CHEMICAL FAMILY
PETROLEUM HYDROCARBON
FORMULA
Complex mixture of petroleum hydrocarbons
Section II - HAZARDOUS INGREDIENTS

PAINTS, PRESERVATIVES, & SOLVENTS
PIGMENTS % TLV SOLVENTS % TLV
(Units) (Units)
100 300 ppm
CATALYST ADDITIVES
VEHICLE OTHERS
HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES % TLV
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(Units)
Section III - PHYSICAL DATA

BOILING POINT (DEG. F.)
IBP-Dry Pt. (244-282 Deg. F)
118-139 Deg. F
VAPOR PRESSURE (mm Hg.) @ 25 Deg. C

45
VAPOR DENSITY (AIR=1)

4.0
SOLUBILITY IN WATER
Negligible
APPEARANCE AND ODOR

Water-white Liquid. Mild, pleasant hydrocarbon odor.
SPECIFIC GRAVITY (H2O=1)

0.76
PERCENT VOLATILE BY VOLUME (%)

100
EVAPORATION RATE ( =1)

2.0
Section IV - FIRE AND EXPLOSION HAZARD DATA

FLASH POINT (METHOD USED)
Tag CLosed Cup 7 Deg. C (45 Deg. F)
FLAMMABLE LIMITS
1.0% Lel
6.0% Uel
EXTINGUISHING MEDIA
Foam, dry chemical, CO2, or water fog or spray.
SPECIAL FIRE FIGHTING PROCEDURES

Use air-supplied breathing equipment for enclosed areas. Cool exposed
containers with water spray. Avoid breathing vapor or fumes.
UNUSUAL FIRE AND EXPLOSION HAZARDS

Do not mix or store with strong oxidants like liquid chlorine or
concentrated oxygen. FLAMMABLE LIQUID.

Section V - HEALTH HAZARD DATA

THRESHOLD LIMIT VALUE
300 ppm for 8 hour workday. 40 hour workweek, est. by Am. Conf. of
Gov't Ind. Hygienists
Inhalation of high vapor concentrations may have results ranging from
dizziness and headaches to unconsciousness. Prolonged or repeated
liquid contact with the skin will dry and defat the skin leading to
irritation and dermatitis.
EMERGENCY AND FIRST AID PROCEDURES

If overcome by vapor, remove from exposure immediately; call a
physician. If breathing is irregular or stopped, start resuscitation,
administer oxygen. If ingested, DO NOT induce vomiting; call a
physician. In case of skin contact, remove any contaminated clothing,
and wash skin with soap and warm water. If splashed into the eyes,
flush eyes with clear water for 15 minutes or until irritation subsides.
Section VI - REACTIVITY DATA

STABILITY UNSTABLE
STABLE X
CONDITIONS TO AVOID
INCOMPATABILITY (Materials to avoid)

Strong oxidants like: liquid chlorine, concentrated oxygen, sodium - or
calcium hypochlorite.
HAZARDOUS DECOMPOSITION PRODUCTS

Fumes, smoke and carbon monoxide, in the case of incomplete combustion.
HAZARDOUS POLYMERIZATION
WILL OCCUR
WILL NOT OCCUR X
CONDITIONS TO AVOID
Section VII - SPILL OR LEAK PROCEDURES

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all ignition sources. Keep people away. Recover free liquid.
Add absorbent (sand, earth, sawdust, etc.) to spill area. Avoid
breathing vapors. Ventilate confined spaces. Open windows and doors.
Keep petroleum products out of sewers and watercourses by diking or
impounding.

WASTE DISPOSAL METHOD

Assure conformity with applicable disposal regulations. Dispose
absorbed material at an approved disposal site or facility.
Section VIII - SPECIAL PROTECTION INFORMATION

RESPIRATORY PROTECTION (Specify type)
Use hydrocarbon vapor canister or supplied air respiratory protection in
confined or enclosed spaces if needed.
VENTILATION
LOCAL EXHAUST
Face velocity >60 FPM
SPECIAL
Use only with adequate ventilation
MECHANICAL
Use explosion-proof equipment.
OTHER
No smoking or open lights.
PROTECTIVE GLOVES
Use chemical-resistant gloves to avoid repeated or prolonged skin
contact.
EYE PROTECTION
Use splash goggles or face shield when eye contact may occur.
OTHER PROTECTIVE EQUIPMENT

Use chemical-resistant apron or other clothing if needed to avoid
repeated or prolonged skin contact.
Section IX - SPECIAL PRECAUTIONS

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING
Keep containers closed when not in use. Do not handle or store near
heat, sparks, flame, or strong oxidant. Adequate ventilation required.
OTHER PRECAUTIONS
Avoid breathing vapors. Avoid prolonged or repeated contact with skin.
Remove contaminated clothing. Remove contaminated shoes and dry before
reuse. Wash with soap and water after contact.

Atmospheric Residue (High and Low Sulphur Content) Waxy Distillate/ Heavy Vacuum Gas Oil

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Sheet No: STI2205 Material Name: Atmospheric Residue (high and low sulphur content)

ALIGN BP SDS Finals

GLIS Sheet No:STI2205 SDS Reference:

Atmospheric Residue (high and low sulphur

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Emergency Telephone Number

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If contamination of the mouth occurs, wash out thoroughly with water.

Note: High Pressure Applications

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Spilled material may make surfaces slippery.

7. HANDLING AND STORAGE

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8. EXPOSURE CONTROLS/PERSONAL PROTECTION

9. PHYSICAL AND CHEMICAL PROPERTIES

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Grades: Atmospheric Waxy

10. STABILITY AND REACTIVITY

Hazardous Decomposition Products

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Persistence and degradability

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R66 Repeated exposure may cause skin dryness or cracking

SHEET NO: STI2205

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SAFETY DATA SHEET

Bitumen or Vacuum residue

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF

Emergency Telephone Number

Common refinery names: PDA, Asphalt,

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Relevant exposure limits are:

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9. PHYSICAL AND CHEMICAL PROPERTIES

Hazardous Decomposition Products

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Persistence and degradability

HOT - Conform to local requirements, if none exist recommend:-

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ALIGN BP SDS Finals

GLIS Sheet No:STI2201 SDS Reference:

Emergency Telephone Number

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EINECS No. : 232-298-5, CAS-No.: 8002-05-9

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7. HANDLING AND STORAGE

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

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If skin contact is likely, wear impervious protective clothing and/or gloves.

9. PHYSICAL AND CHEMICAL PROPERTIES

10. STABILITY AND REACTIVITY

Hazardous Decomposition Products

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Persistence and degradability

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Flash Point below minus 18 degrees Centigrade

Flash Point minus 18 to plus 23 degrees centigrade

Flash Point plus 23 to 61 degrees centigrade