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INTERNAL USE ONLY

Liquid Bio Fuels

Vesa Riihimäki, Vice President


Presented by Kristoffer Sandelin
Power Plant Technology

© Wärtsilä
INTERNAL USE ONLY
Wärtsilä Fuel Versatility

High Viscosity HFO


Emulsified Fuels
Liquid Biofuels (LBF)
Crude Oil (CRO)
Natural Gas (NG)
Heavy Fuel Oil (HFO)
Diesel Oil (LFO)

1970 1980 1990 2000 2010

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The LBF Portfolio

Plant ranges & Engine portfolio

W20 6, 9L

W32 6, 9L, 12, 16, 18, (20V)

W32DF (6L,12V) 18V

W46 6, 9L, 12, 16, 18

W50DF 6, (8, 9L) (12, 16) 18V

1 5 10 50 100 200 300


Plant size
= Biodiesel approved as pilot and back-up fuel
Bio oils not approved and to be checked case by case

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The Variety of Liquid Bio Fuels

ƒ Liquid Bio Fuels


ƒ

„ A great varation of bio fuels can


be found
„ Approved by Wärtsilä are:
„ Vegetable based bio fuels:
Palm oil, Palm stearin, Rape
seed oil, etc.
„ Transesterified bio oils
(biodiesel)

„ Animal based not approved


„ DME (Di-Methyl Ether) not
approved
„ Methanol & Ethanol not approved
„ Bio oil – alcohol mixes not
approved

„ Lower Heating value => Output


reduction

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Sources of Liquid Bio Fuels

ƒ Sources of vegetable oils (2003)


„ Palm oil (28.3M tons/year)
28.3 Mtons is „ Malaysia
enough (47%)continous
for 14000MW
„ Indonesia
power (37%)
generation
„ Soy Bean (31M tons)
„ USA
„ Sourth Europe
„ Rapeseed (12.3M tons)
„ North Europe
„ Sunflower (8.6M tons)
„ South Europe

ƒ Total Oils&Fat production


„ 2003: 123.5 million tonnes
„ Animal fats 23M tons
Source:Oil World, Hamburg

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Prices of Liquid Bio Fuels

1400
ƒ Price development
„ Palm oil price development
1200
has been positive over long
term trend 1000
SOYBEAN OIL ,U.S.
„ With HFO at 250 … 300 $/ton SOYBEAN OIL ,ROTT

and Palm oil at 400$/ton, the PALM OIL ,MALAYSIA 800


power generation market RAPESEED OIL ,ROTT

$/ton
requires subsidies to become PEANUT OIL ,U.S. 600

commercially attractive PEANUT OIL ,ROTT

„ CO2 trading and incentives in COCONUT OIL ,ROTT 400


CORN OIL ,U.S.
Italy, Holland and Germany
200
have created local markets
for LBF power plants
0

94

96

98

00

02

04
19

19

19

20

20

20
Source: United States Department of Agriculture

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INTERNAL USE ONLY
Characteristics of vegetable oils

Palm Oil 22°C Palm Oil 60°C


ƒ Varying characteristics
„ Ash content
„ Clear oil & dark oils have
different level of ash
„ Influence on particulate
emissions
„ Viscosity is highly
temperature dependant
„ Too cold -> wax
„ Too hot -> polymerization
„ Phosphorus content
„ Lifetime of DeNOx &
OxiCat
„ Acid number
„ Influence on fuel oil system
wear & tear
Palm Stearin 22°C Palm Stearin 60°C

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Emissions and Liquid Bio Fuels

Refined Palm Olive


Emission Unit LFO HFO Palm Oil Stearin Olein

NOx ppm, dry 15 % O2 860 970 1050 960 930 SCR for NOx control
CO ppm, dry 15 % O2 40 40 30 40 40 Oxidation Catalyst for
THC (as CH 4) ppm, dry 15 % O2 170 80 30 20 15 CO and HC control
SO2 ppm, dry 15 % O2 118 463 <2 <2 <2
CO2 vol % 5.3 5.46 0.0 0.0 0.0
3
Particulates mg/Nm , dry 15% O2 <25 40-60 <10 <10 70

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Wärtsilä LBF experience

Val Senales

Unigra

Pentesilea
Monopoli

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MW in operation

ƒ MW development 200

„ The introduction of incentives 180

in Italy has created a fast 160


growing installed base of LBF
140
plants
„ Projected estimates suggest 120

that up to 500MW of LBF 100


plants could be in operation 80
by end of this decade
60

40

20

May-03

May-04

May-05

May-06

May-07
Jan-03

Sep-03
Jan-04

Sep-04
Jan-05

Sep-05
Jan-06

Sep-06
Jan-07
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INTERNAL USE ONLY
LBF business models

ƒ Four models
„ Crudel Vegetable Oils
„ The primary model for using
LBF.
„ Bio diesel
„ Today very expensive, not
really feasible for power
generation
„ Waste oils from food industry
„ Karlburg plant model, but was
later changed to by products.
Problem: Emissions
„ Waste or fuel? Which EU
directives are to be used?
„ By-products
„ Main customers are companies
operating in Bio-oil refinery
business

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HFO to BIO Future proof concept?

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