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CHEMISTRY
Syllabus Objectives :
(a) Name natural gas, mainly methane, and petroleum as sources of energy.
(b) Describe petroleum as a mixture of hydrocarbons and its separation into
useful fractions by fractional distillation.
(c) Name the following fractions and state their uses
(i) Petrol (gasoline) as a fuel in cars;
(ii) Naphtha as feedstock for the chemical industry;
(iii) Paraffin (kerosene) as a fuel for heating and cooking and for
aircraft engines;
(iv) Diesel as a fuel for diesel engines;
(v) Lubricating oils as lubricants and as a source of polishes and
waxes;
(vi) Bitumen for making road surfaces.
(d) State that naphtha fraction from crude oil is the main source of
hydrocarbons used as the feedstock for the production of a wide range of
organic compounds.
(e) Describe the issues relating to the competing uses of oil as an energy
source and as a chemical feedstock.
♦ Coal, petroleum and natural gas are all known as fossil fuels.
♦ Fossil fuels are described as non- renewable energy sources – once they are used
up, they cannot be replaced (fossil fuels took millions of years to form).
♦ Coal –
Mainly carbon, with small amounts of other elements;
Formed from the remains of dead plants.
♦ Natural gas –
Found together with petroleum
Consists mainly of methane, CH4 (a hydrocarbon)
♦ Petroleum –
Also known as crude oil, found together with natural gas
Is a mixture of hydrocarbons (compounds containing ONLY the elements
hydrogen and carbon )
Of little use before it is refined;
used mainly (1) as fuel; (2) as raw materials for other products eg. plastics,
detergents
2
Properties & Uses of the different Fractions
♦ Some fractions are more useful than others – greater demand for petrol and diesel,
than for lubricating oils or bitumen.
♦ The process of converting the heavy fractions of larger molecules into smaller, more
useful lighter fractions is calledcracking ; suitable catalysts used for the process are
powdered aluminium oxide or silicon dioxide.
Eg. C6H14(l) → C4H10(g) + C2H4 (g)
Cracking can also produce hydrogen gas, and provides an important industrial source
of hydrogen : eg. C10H22(l) → H2(g) + C4H8 (g) + C6H12 (g)
♦ Only a limited amount of petroleum in the earth – wasteful to simply burn it away?
Reserved for making chemicals (plastics, drugs and other chemicals)?
♦ Possible solution – find alternative source of fuels.
Further Reading:
http://www.howstuffworks.com/oil-refining.htm