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INTRODUCTION
As from 1993 with all petrol engines, and from 1997 with all diesel
engines, it became mandatory within European Community countries to
equip all new vehicles with catalytic injection systems.
This measure, contrary to the belief of most people, makes the exhaust
system one of the most sophisticated parts of the 4-stroke engine, because
the performance of this engine depends directly on the accuracy of
the back pressure levels produced from the exhaust system.
Using the correct exhaust system will ensure that the engine always works
with the right air-fuel mixture, always providing the maximum power while
maintaining minimum fuel consumption. It will also help to extend the working
life of other important parts of the engine – valving system, silencers, catalytic
converters, lambda sensors, etc.
Oscar F. Oskarsson
Training Manager
Tenneco Europe, Africa & Middle East
Introduction 2
• Biosil wool
6 - W
alker ® is a Leader in Emission Technologies
for Original Equipment 32
• Emission Technologies for Environmental Mandates 32
• More Original Equipment Products for Emission Control 33
• Our Original Equipment Customers 33
• Research 33
7 - W
alker ® Product Range 34
• Mufflers 34
• Catalytic Converter 34
• Complementary Products 34
8 - 4G AGAR 35
9 - 4T Program 35
DPF Muffler
* At the Euro1...4 stages, passenger vehicle > 2,500 kg were type approved as catagory n1 vehicles † Values in brackets are conformity of
production (COP) A Until 1999.09.30 (after that date DI engines must meet the IDI limits) B 2011.01 for all models C and NMCH = 0.068 g/km
D applicable only to vehicles using DI Engines E Proposed to be changed to 0.003 g/m using the PMP measurement procedure
The backpressure of the exhaust system varies depending on Compression Stroke : Once the piston reaches the lowest
the revolutions of the engine. Because of this, the manufacturers point of the stroke, the intake valve closes and the piston begins
have designed the exhaust system to maintain the ideal its compression stroke, so compressing the air-fuel mixture.
backpressure within the range of revolutions in which the engine
will normally run. Power Stroke : Once the piston reaches its highest point,
the air-fuel mixture is completely compressed and an explosion
The 4-stroke engine takes place (by means of a spark coming from a spark plug
Nowadays most cars and other transport vehicles seen on our in petrol engines, or by the high compression of the fuel in
roads (diesel or petrol) are equipped with 4-stroke engines. Due diesel engines). This will produce the stroke power.
to the particular way a 4-stroke engine works, the backpressure
becomes critical. Let’s see how a 4-stroke engine works to better Exhaust Stroke : Once all the air-fuel mixture is completely
understand why the backpressure is so important. burnt, the piston will be at the lowest part of the stroke,
the exhaust valve opens and the piston begins to rise pushing
The strokes of a 4-stroke engine are explained as follows: the burnt gases into the exhaust system via the exhaust valve,
with the sole purpose of completely emptying the combustion
Intake Stroke : The intake valve opens and the piston begins chamber, the exhaust valve will then close in order to begin
the downward stroke in order to let in the air-fuel mixture into the same process again.
the cylinders.
View of a Low
Backpressure exhaust
Exhaust broken due to vibrations due to worn out engine rubber supports.
Exhaust broken due to vibrations due to worn out exhaust rubber supports.
Exhaust damaged due to material fatigue in the housing area.
Exhaust broken due to vibrations of worn out exhaust rubber supports.
Exhaust manifold broken due to vibrations produced due to worn out engine rubber supports or elastic joining of the transmission.
The price of the aluminium is much higher than the cost of the
Are all Types of Aluminized Steel laminated steel, the lower the quality of aluminized steel (lower
the Same Quality ? quantity of aluminium) the cheaper it would be and the quicker it
The answer to this question is no, the level of resistance to would rust, putting other systems of the car in danger, and
corrosion depends on the thickness of the aluminium cover which decreasing the overall performance of the engine.
protects the laminated steel. To help us determine the quality
of the aluminized steel we have purchased, the manufacturers
describe it with a number, this tells us how many grams of Manufacturing Qualities of Aluminized Steel
aluminium there is covering each of the laminated steel layers
Aluminized Steel 80/m2
per square meter, followed by the word single-layer or 2-layer 6-12
one leaf 1.2 mm
indicating whether it is protected on one or both sides with
Aluminized Steel 120/m2
aluminium. As we said previously, on 120 gr/m2 2-layer, this 12-18
one leaf 1.2 mm
means that the aluminized steel is covered with 120 grams of
aluminium for each square meter on each of its sides, (This kind 18-24 Aluminized Steel 120/m2
two leafs (0.5 mm + 0.7 mm)
of steel is a high quality aluminized steel used by Original
Equipment manufacturers for their retail products as well as 30-36 Aluminized Steel 120/m2
the Aftermarket manufacturers for homologated production). two leafs (0,5 mm 150 gr/m2
+ 0.7 mm 150 gr/m2)
On the other hand, if the aluminized steel was 120 gr/m2
single-layer, this would tell us that it is covered with a 120 gr/m2 Working life in months
but only on one side (that means it would have half the
aluminium of the previous example.) It would leave one of the
sides of the laminated steel layer without any extra protection
against corrosion.
min 150 mm
Two single measurement points link
B B’ together to give only one value
A. Guideline 70/157/ EEC it is important that all the numbers are in a straight line one after the other. The “e” must be
small (not capital letter) and always appear inside the box together with a number, which identifies the country, if it is not
like that then the homologation code is false
03 0148
a ≥ 8 mm
2a /3 a /3
a
Homologation country
“1” Germany “6” Belgium “17” Finland
Homologation guideline Homologation number
“2” France “9” Spain “18” Denmark Guideline 70/157/EEC ‡ Nº 00
“3” Italy “11” UK “21” Portugal Guideline 77/212/EEC ‡ Nº 01
“4” Netherlands “12” Austria “23” Greece Guideline 84/424/EEC ‡ Nº 02
“5” Sweden “13” Luxembourg “Irl” Ireland Guideline 92/97/EEC ‡ Nº 03
B. Regulation 59 of the United Nations. This code is similar to the previous one with all the numbers in a specific position.
The number, which indicates the homologation country, is put in a circle together with the letter “E” which is always written
as a capital letter followed by 59, which means that this unit meets the Regulation 59 of the United Nations. This code is
completely legal but is rarely used nowadays because it is very old.
2a/3 a /3
E9 59 03 0148 a /3
A. Guideline 70/220/EEC : It is important that the numbers are placed in a straight line one after the other. The “e” must be
small (not capital letter) and always appear inside the box together with a number, which identifies the country, otherwise
the homologation code is false. This code is the old homologation code version for catalytic converters, and it is difficult to
find it nowadays.
030148
a ≥ 8 mm
2a /3 a /3
a
Homologation country
“1” Germany “6” Belgium “17” Finland
Homologation guideline Homologation number
“2” France “9” Spain “18” Denmark Guideline 70/157/EEC ‡ Nº 00
“3” Italy “11” UK “21” Portugal Guideline 77/212/EEC ‡ Nº 01
“4” Netherlands “12” Austria “23” Greece Guideline 84/424/EEC ‡ Nº 02
“5” Sweden “13” Luxembourg “Irl” Ireland Guideline 92/97/EEC ‡ Nº 03
B. Regulation 103 of the United Nations before it was approved for Europe. This code is similar to the second one shown
for the exhaust, with all the numbers in a specific position. The number which indicates the homologation country is put in a
circle together with the letter “E” which is always written as a capital letter followed by 103, which means that this unit
meets the Regulation 103 of the United Nations (the previous version before it was approved by the UN). This code was
used before the European countries approved the Regulation 103. It’s completely legal but is rarely used nowadays
2a /3 a/3
E1 103 030148 a/3
C. Regulation 103 of the United Nations (actual version). This code is similar to the last one shown. The number which
indicates the homologation country is put in a circle together with the letter “E” which is always written as a capital letter
followed by 103 which means that this unit meets the Regulation 103 of the United Nations. This code is the most common
one nowadays in all cars manufactured after February 23 1997, and the catalytic converter needs to show the code
related to the Regulation 103 (103R) stamped on the catalytic converter housing.
2a /3 a /3
E1 103R 030148 a/3
e1 00
0123 e1 1 01235 e1 103R 031235
Only appears on one line Number is composed of 2 digits + space + 4 digits Only capital E is valid
Types of Mufflers
Absorption Muffler
Picture of a Exhaust The name of these mufflers comes from the methodology used
Containing E-Glass Fibre to control the noise level. High frequency sound is attenuated
thanks to the material that covers the straight perforated tube
that crosses from side to side of the interior part of the muffler.
Main Components Of Modern Vehicles Exhaust System All About Emission Control 21
Reflection Muffler Semi Active Muffler (S.A.M.)
As the name indicates these mufflers use the reflection principle This is a special type of silencer that includes a revolutionary
to control low frequency noise. This muffler works on the principle valve; this allows the muffler to maintain an optimum
that when two equal and opposite sound waves meet head backpressure level at any phase of the revolutions. The way
on, they destroy each other on impact. this valve works is by controlling the flow of gases through one
of the internal muffler pipes. This action is achieved thanks to
In order to ensure that the reflection effect takes place inside the S.A.M. valve opening or closing the internal pipe section,
the muffler, the design is key. The internal design of a reflection thus controlling the backpressure level of the whole exhaust
muffler includes different chambers separated by baffles that system. Due to this innovative backpressure control, cars
are connected by perforated pipes. Due to the increased equipped with S.A.M. mufflers produces more power over all
resistance to flow of this design, the backpressure is higher the revolution range as well as an excellent noise attenuation
than that of the absorption muffler. at low frequencies. Due to its design, the volume of the exhaust
system can be reduced by approximately 30 %, which impacts
directly in a decrease of the total weight of the exhaust system,
and fuel consumption.
22 All About Emission Control Main Components Of Modern Vehicles Exhaust System
The Catalytic Converter Ceramic Monolith vs.
Precious Metals
Nowadays, catalytic converters are one of the main parts of Metallic Monolith
our exhaust systems. These units are installed in all cars sold in The ceramic monolith, as its name
the European Community countries, and their use has been Wash Coat suggests, is made from a ceramic
mandatory since 1993 for petrol cars and 1997 for diesel compound. The most widely used is
cars. The function of these units inside the exhaust system is to a silicate called cordierite (2MgO2
transform the harmful gases (CO, HC, NOx) in the exhaust Monolith Al2 O3 SiO). The monolith has a
gases coming from the combustion chamber into other honeycomb-like structure with square
considered “clean” gases (CO2, H2O, N2), before these gases cells. In order to be shaped properly, the ceramic compound
leave the exhaust system into the atmosphere. This process is heated to over 1,300 ºC until its consistency becomes that of
takes place inside the catalytic converter with the help of a paste, and using an extrusion process the paste is forced
the catalytic metals: platinum, palladium and rhodium. These through a mould to produce its honeycomb shape. Usually,
metals are placed over the surface of the monolith (metallic or the monoliths have an oval or cylindrical shape, although the
ceramic) that is always in contact with the exhaust gases. The design is quite flexible since it only depends on the type of
monoliths used for automotive applications have a honeycomb- mould used during the extrusion process.
like shape, with a high number of cells through which the exhaust
gases pass on their way to the atmosphere.
Main Components Of Modern Vehicles Exhaust System All About Emission Control 23
On the otherhand we have the metallic catalytic converter, Having checked the mechanical characteristics of both types
which has a monolith constructed from basic metal alloy materials. of monolith, (metallic and ceramic) we are able to sum up a
(for example FeCrAlloy, Kantal, etc.) The most common way of few advantages and inconveniences of these systems, and
making these monoliths for the automotive industry is to combine their usefulness in our petrol and diesel cars.
flat and corrugated layers of this metal alloy in order to make
the spiral-shaped monolith. The channels from where the exhaust It will also help to understand why almost all catalytic
gases subsequently escape are formed between the flat plate converters (more than 90 % of total units), installed in Original
and the undulations of the corrugated one. Equipment, are ceramic catalytic converters.
Manufacturing
Advantages of metallic monolith
Procedure Used to Built The metallic monolith allows the manufacturers to produce
Metallic Monoliths smaller catalytic converters, because these units have thinner
cell walls. It also allows them to design monoliths with a higher
number of cells, allowing greater surface contact of exhaust
gases with precious metals, compared to ceramic monoliths.
Due to the fact that these units have thinner monolith walls,
the backpressure levels are generally lower compared to the
ceramic ones of the same size. It is essential that the backpressure
Once the spiral is formed, it is placed inside a metal cylinder level of a replacement catalytic converter needs to be more or
that serves as a support chassis. These monoliths are almost less equal to the level of the original Equipment unit in order to
always cylindrical due to their special manufacturing process. obtain the European homologation. This homologation process
In the specific case of metal monoliths with a higher quantity of is mandatory for all the after-market exhaust and catalytic
cells per square inch, the “wash coating” process can be converters produced for European Community countries, and
carried out before it is formed into a spiral, because if the ensures that the homologated units will maintain maximum
wash coating takes place once the monolith is formed (as in performance of the vehicle avoiding any other engine damage.
the case of the ceramic catalytic converters), it could create an
obstruction of some cells due to its smaller size. Better impact resistance :
When the catalytic converter receives
The mechanical characteristics of this type of monolith are : a strong impact, the metallic monolith
Shape : Generally cylindrical. does not break as the ceramic one
does, instead, the metallic monolith
Thickness of monolith walls : Approximately 25 Microns. deforms by changing its shape. When
Number of cells : Between 800 cpsi and the monolith is deformed, in most of the
situations the catalytic converter needs to be View of a Damaged
1,250 cpsi. Catalytic Converter
changed urgently because this deformity will Due to an Impact
Fusion point of the alloy : Approximately 1,600 ºC destroy some monolith cells which will produce with an External Object.
Resistance to impact High, it does not fracture. an increase of the backpressure levels in the
exhaust system. This situation could produce a significant loss
Coefficient of Thermal (Very high). of power and cause serious damage to the car engine.
Expansion (CTE) :
Metallic melting point is 150 ºC higher than the ceramic
monolith : As we saw, the melting point of the metallic
Internal View of a Metallic Catalytic monolith occurs at around 1,600 ºC, 150 ºC higher than the
Converter's Monolith melting point of the ceramic one which is approximately at
1,450 ºC. This quality gives the metallic monolith the capacity
to resist the temperature a little bit better, because of that, when
the engine has some problems (wrong backpressure, old spark
plugs, problems with lambda sensor, etc…) the metallic monolith
will remain working for a longer period than the ceramic one
before it melts. On the other hand, if the problems are big
(misfiring, broken spark plug, total failure of one cylinder, important
mixture problems, compression problems) the differences will be
very small, (minute) because the amount of petrol burning
24 All About Emission Control Main Components Of Modern Vehicles Exhaust System
inside the catalytic converter (over the monolith) is
very high, and the temperature generated when
the fuel burns is 1,800 ºC, which is far away
from the melting point of both monoliths. We
need to remember that the auto-ignition point of
the unleaded petrol is approximately 450 ºC,
and the working temperature rate of a catalytic
converter is around 500 ºC. It means that every unburnt fuel
particle leaving the combustion chamber with the exhaust
gases, will burn automatically as soon as it touch the monolith
surface. This petrol as we know produces temperatures over
1,800 ºC which will melt the monolith surface. The time that the
monolith (metallic or ceramic) will resist once the melting process Lower manufacturing cost : Due to the fact that ceramic
begins is directly related to the quantity of unburnt fuel monoliths are produced by an extrusion process, the
contained in the exhaust gases, and the temperature of manufacturing cost of these units is lower in comparison to the
the monolith. same units manufactured in metallic monoliths. On the other
hand, the quantity of precious metals (platinum, paladium and
Advantages of the ceramic monolith rhodium), which need to be included in the wash coating
Easy way to create different monolith shapes : Due to the process, is fixed by the European guidelines and is the same
way these monoliths are manufactured (by extrusion) the shape for both types of monolith.
of the monolith can be varied very easily. As we have seen,
the shape of the monolith only depends on the mould used to The Chemical reactions
extrude the material. This shape can be cylindrical, elliptical, When the catalytic converters are working properly, two main
square or even asymmetric. This is one of the most appreciated chemical reactions take place inside:
qualities from the viewpoint of the car manufacturers.
Oxidizing : Is produced by adding oxygen to the chemical
Longer working life of the ceramic compounds. In this reaction, carbon monoxide (CO) and
catalytic converters : This is due to two the unburnt hydrocarbons (HC) are transformed into carbon
main factors; the first one concerns dioxide (CO2) and water (H2O). Following next reactions:
the roughness level of the monolith.
The roughness level of the ceramic 2 CO + O2 2 CO 2 (1)
monolith walls is significantly
higher than the roughness level CmHn + (m+n/4)O 2 m CO 2 + (n/2) H2O (2)
of the metallic monolith.
This fact makes the wash coating process better, and more
efficient in the ceramic monolith. The second and most critical
ture
factor is the Coefficient of Thermal Expansion (CTE). In the Lean Mix CO
ceramic monolith the CTE is very small compared to the Pt H2O
atio n
Pt Oxid
metallic ones, it means that the ceramic monolith size varies
very little with temperature variations. For the metallic monolith CO
the situation is the opposite, the CTE is much bigger, this fact HC
produces significant variations on the monolith size, depending
on the temperature level, increasing its size when it is hot
(remember that the working temperature rate for a catalytic The oxidizing reactions, which take place in the catalytic
converter is approximately 500 ºC) and decreasing when it is converter, are accelerated by the presence of the precious
cool. The explanation of why the CTE is so important is simple, metals platinum and palladium. In order to make the oxidizing
if we have a metallic painted surface, and we change the size reaction possible, the air/fuel ratio must be lean (lambda >1),
of this surface (increasing and decreasing it) several times, over that means that the mixture to be burnt in the cylinders will have
a period of time the surface will lose its paint cover. This is more air than needed to burn it correctly (Ideal mixture =1).
exactly what happens with the wash coat cover when submitted If the mixture is not lean, or the platinum and/or palladium
to high and continuous monolith size variations, and as soon are not in contact in the right amount with the exhaust gases,
as the monolith loses its wash coat cover, this unit completely the oxidizing reactions will not take place in the right way,
loses its functionality, and needs to be replaced. increasing the levels of CO and HC in the exhaust gases.
Main Components Of Modern Vehicles Exhaust System All About Emission Control 25
Reduction : This type of chemical reaction consists of
Intake System Catalytic Converter
separating the oxygen of a compound, in order to create a
new compound or molecule. The reduction reactions that take
place inside automotive catalytic converters are accelerated by
the presence of rhodium, and require rich air/fuel mixtures to
take place. Reduction reactions are a method of transforming
NOx molecules into nitrogen (N2), carbon dioxide (CO2) and
in some cases water (H2O).
3-way catalytic converter with air intake
2 CO + 2 NO N2 + 2 CO2 (3) This type of catalytic converter is exclusively used in rich air/fuel
mixture engines. Nowadays its use is effectively restricted to
CmHn + 2(m+n/4) NO (m+n/4) N2 + the US market. As its name indicates, these types of catalytic
converters are able to transform three different gases (CO, HC
mCO2 + (n/2 ) H2O (4) and NOx). The internal design of these units includes two
monoliths, each one of them with a very specific function in the
H2 + NO (1/2) N2 + H2O (5) transformation process. The first monolith in contact with the flow
of exhaust gases coming from the engine (with rich air/fuel
mixture) is a reduction monolith, and because of that, it is only
equipped with rhodium. Thanks to this monolith, the NOx is
ture
Rich Mix N2 transformed into N2, H2O and CO2. Unfortunately due to the
Rh CO2 type of air/fuel mixture (rich), oxidizing reactions (CO and HC)
ctio n
Rh Redu cannot take place in the same monolith due to the lack of
NOx oxygen. To solve the problem, the engineers add a second
monolith but this time an oxidizing one, equipped with platinum
and/or palladium inside the catalytic converter housing just after
the reduction one. To transform the rich mixture into a lean
Types of Catalytic Converters Depending on mixture before accessing the second monolith, the engineers
the Number of Ways left a small space between both monoliths where thanks to a
Catalytic converters can be classified in three groups based on hole and a small pump the system receives atmospheric air
the number of gases that each catalytic converter is able to (with 21 % of oxygen) which transforms the mixture present in
transform: 2-way catalytic converters (two gases, CO and HC), this area into lean, allowing the oxidizing reactions (1) and (2)
3-way catalytic converters with air intake (three gases CO, HC to take place.
and NOx used in old US petrol vehicles) and 3-way catalytic
converter with lambda sensor (three gases CO, HC and NOx
used for petrol cars equipped with lambda sensor). CO
H2O
Pt N2
2-way catalytic converter
These units are used in lean mixture engines, like diesel, or
CO Rh
HC
direct injection petrol engines like GDI, FSI. The precious NOX
metals present in the monolith are generally platinum, but can
also be palladium, or even both at the same time. Platinum
and palladium are metals that accelerate the transformation of
the CO and HC by oxidizing reactions, transforming them into
CO2 and H2O (see oxidizing reactions (1) and (2)). The
reduction of NOx in these types of engines cannot take place
in the catalytic converter, because these types of engines run
all the time with lean air/fuel mixture and the reduction process
requires a rich mixture to allow the reduction reactions. The
reduction process in these engines takes place using other
methods, like EGR or selective catalytic reduction systems that
will be explained later. 2-way catalytic converters are also called
oxidizing catalytic converters, or diesel catalytic converters.
26 All About Emission Control Main Components Of Modern Vehicles Exhaust System
3-way Catalytic Converter with Lambda Sensor Close Coupled Converter
Contrary to 3-way catalytic converter with air intake system Under this name we can
that carry out the reduction reactions first and then the include all those catalytic
oxidation reactions in different monoliths, 3-way catalytic converters that are incorporated
converters with lambda sensor carries out the reduction in the exhaust manifold. This
reactions, and oxidation reactions on the same monolith thanks design enables a catalytic
to the lambda sensor and engine management system. That converter to reach the light
means that these types of catalytic converters are able to off point (temperature from which the
transform CO, HC and NOx into CO2, H2O and N2 on the catalytic converter starts to work
same monolith and at the same time. For its correct operation, properly) faster. This design contributes to Picture of a Close
it is necessary that the air/fuel mixture relation should be near optimum use of engine exhaust energy, and Coupled Converter
the Stoichiometric value (1:14,7). In order to allow the improves conversion efficiency
oxidizing reaction to take place, the system makes continuous
changes in the air/fuel ratio of the mixture. First the injection
system makes the mixture a little bit lean (>1) for some Diesel Particulate Filters (DPF)
moments, just after, the system changes the mixture again into A diesel particulate filter, (also called DPF) is a device designed
rich (<1) to allow the reduction reactions. This process of to remove diesel particulate matter, (soot), from the exhaust gas
continually changing the mixture is done very fast (At 2,000 of a diesel engine. The efficiency of these elements is very high,
rpm. Around 3 times per second) being directly proportional to often attaining efficiencies of over 90 %. A diesel-powered
the number of revolutions. vehicle with a DPF installed will emit no visible smoke from its
exhaust pipe. In order to collect the particulate matter, a
ΔUλ Uλ
E.C.U. method must be designed to get rid of it. Nowadays there are
Lambda Sensor three different methods of achieving this. Some filters are single
use (disposable), while others are designed to burn off the
Intake System
accumulated particulate, either through the use of a catalyst
Catalytic Converter (passive), or through an active technology, such as a fuel
burner, which heats the filter to soot combustion temperatures,
or through engine modifications (the engine is set to run a
Tubular Integrated Converter (TIC) specific way when the filter load reaches a pre-determined
Contrary to the standard manufacturing process of catalytic level, measured with sensors through the back pressure level,
converters, where the housing is made from two shells of and temperature of the unit, either to heat the exhaust gases,
stainless steel or other metal rust resistant, tubular integrated or to produce high amounts of NO2, which will oxidize the
converters are built in a one piece housing made from thin particulates at relatively low temperatures). This procedure is
walled stainless steel tube produced in a hot rolled process. known as “filter regeneration”. Fuel sulphur interferes with many
The manufacturing process controls the thickness of the material “regeneration” strategies, so almost all jurisdictions that are
at each critical point to obtain the maximum mechanical interested in reducing particulate emissions, are also passing
resistance, as well as a better connection to the pipes of the regulations governing fuel sulphur levels.
exhaust system. Due to its special design, these units are lighter,
and the durability is higher compared to the standard ones.
Main Components Of Modern Vehicles Exhaust System All About Emission Control 27
increase low temperature (sub -350 ºC) performance of zeolite
catalysts typically requires the use of an upstream oxidation
Controller
catalyst for NO to NO2, which in turn requires the use of fuels
T & Vol that are virtually sulphur-free to allow low-temperature oxidation
of NO to NO2, and to prevent formation of sulphate
particulate matter.
UCE
Dispensing
Ammonia or Urea, which is the best ?
pump UREA
While ammonia offers slightly better performance, it is toxic and
tank
is difficult to handle safely. Urea is safer to handle, but not quite
Injector as effective. It has, however, to date been a more popular
choice for engine manufacturers. In both cases, the reductant
NOx & T NOx & T
DOC must be extremely pure, because the impurities can affect
DPF
M ixer SCR Slip
negatively the SCR catalytic converters. Typically, SCR catalytic
catalytic catalytic
converter converter converters require frequent cleaning even with pure reductants,
as the reductant can cover the inlet surface of the catalytic
converter monolith, while the exhaust gas stream temperature is
too low for the SCR reaction to take place.
Selective Catalytic Reduction (SCR)
It is a process where a gaseous or liquid reductant (most Research into reductant technology
commonly ammonia or urea) is added to exhaust gas stream is continuing. A wide variety of
thanks to an injector connected to the exhaust pipe to later on suggestions have been made for
be transformed into the catalyst. The reductant reacts with NOx alternative reductants, In Europe,
contained in the exhaust gases into the selective catalytic SCR is a common choice for NOx
converter to form H2O (water vapour) and N2 (nitrogen gas). control technology by engine
Specialty selective catalytic converters for reduction are manufacturers, and a variety of
required to make an SCR system work, nowadays we can find ammonia and urea brands are
two possible options in the market, vanadium-based catalyst available, such as AdBlue
(for lower temperature applications like ships, power plants, for example.
etc), or a catalyst with iron or copper zeolites in the wash
coat. The performance of Fe- and Cu-exchanged zeolites Ammonia slip
urea-SCR is approximately equal to that of vanadium urea-SCR A common problem with all SCR systems is ammonia slip. The term
if the fraction of the NO2 is 20 % to 50 % of the total NOx. describes exhaust pipe emissions of ammonia that occur when:
Zeolites offer improved durability at high temperatures, 1- E xhaust gas temperatures are too cold for the SCR reaction
including an ability to withstand extended operation above to occur.
650 ºC and brief exposure to temperatures of 750 to 850 ºC. 2 - The injection device feeds too much reductant into the
Thermal durability is particularly important for mobile SCR exhaust gas stream for the amount of NOx.
applications that incorporate the use of a diesel particulate
filter (DPF) with forced regeneration. Vanadium catalysts are A variety of strategies have been developed to deal with
quickly deactivated at temperatures above 600 ºC. The reliance ammonia slip, including the use of extra catalysts after the SCR
on an increased fraction of NO2 within the total NOx to catalyst (also called : Slip Cat).
28 All About Emission Control Main Components Of Modern Vehicles Exhaust System
To ensure that the A dBlue is not affected by incorrect material Let us see in detail how each one of these units work:
specification, operators should refer to the DIN 70070
standard for production of A dBlue and CEFIC quality control Zirconium Dioxide Lambda Sensors
document AUS32. In the most widely used sensor, the active element is a ceramic
body made of zirconium dioxide covered internally and
externally by a thin porous platinum layer that works as an
The Lambda Sensor electrode. The internal part of the ceramic body is in contact
Lambda sensor is an oxygen sensor (O2) that measures the with atmospheric air, while the external part is in contact with
oxygen present in the air/fuel mixture leaving the combustion the exhaust gases.
chamber, and passes this information to the Electronic Control Ceramic body
Electrical Zirconium
Unit (ECU) Electrical contact protection dioxide
connection capsule
Main Components Of Modern Vehicles Exhaust System All About Emission Control 29
Common Wire Colour in Zirconium Dioxide Lambda Sensors
1 wire : Output 0.1 to 0.9 Volt
Colour Connection:
Black Signal
Depending on the number of wires (if they possess or not voltage is due to a variation of the internal resistance of
internal heating), we can differentiate several types of the circuit composed by the wires, the titanium elements, and
zirconium dioxide lambda sensors: the two platinum electrodes of the sensor. The working principle
of this sensor is quite simple; the ECU feeds this type of sensor
Single wire sensor : with levels around 1 Volt (except in some vehicles it is 5 Volts
• Black wire signal to ECU, Ground in sensor housing by - Nissan and Toyota 4x4), this voltage travels to the titanium
the exhaust system element, where two platinum electrodes are separated by a
very small space through which pass the exhaust gases.
2 wires sensor : The higher the amount of oxygen present in the exhaust gases,
• Black wire signal wire to ECU more oxygen ions will combine with the titanium ions creating
• Grey wire Ground through ECU titanium dioxide (TiO2). Resulting in an increase of resistance
between the platinum electrodes in this process, part of the voltage
3 wires sensor : (electrons) will be used to create titanium dioxide molecules (TiO)
• Black wire Signal to ECU decreasing the voltage, which returns through the circuit to
• 2x White wires Heating system (12 if goes to battery or the ECU. In lean mixtures, the resistance of the system can be
5 V if they receive the voltage through the ECU) increased up to 100,000 Ω (ohm), on the other hand, in the
• Ground in sensor housing by the exhaust system absence of oxygen (rich mixture) the resistance generated by
this system is lower than 1,000 Ω. The resistance change is
4 wires sensor : greater for values of lambda near 1.
• Black wire Signal to ECU
View of a Titanium
• 2x White wires Heating system (12 if goes to battery or
Oxide Lambda Sensor
5 V if they receive the voltage through the ECU)
• Grey wire Ground through ECU
30 All About Emission Control Main Components Of Modern Vehicles Exhaust System
Common Wire Colour in Titanium Dioxide Lambda Sensors
3 wires : Output 1 to 5 Volt
Colour Connection:
Red - Ref (in) and Heater (+)
Black - Ref (out)
White - Heater (-) 12 mm Thread 18 mm Thread
4 wires : Output 1 to 5 Volt
Colour Connection:
Red - Heater (+)
White - Heater (-)
Black - Ref (out)
Yellow - Ref (in) 12 mm Thread 18 mm Thread
This type of lambda sensor does not generate voltage; it only 450 mV, (lambda = 1). The value and direction of the current
varies its internal resistance. The operating temperature of this type used by the pump cell is directly proportional to the oxygen
of sensor is between 200 ºC and 700 ºC, if the sensor is content in the exhaust gases. Air/fuel ratios from 11/1 up to
submitted to temperatures higher than 850 ºC it may be destroyed. around 20/1 can be detected with great precision by this
instrument. The Wideband sensor generates a variable signal
The normal values we will be able to read in the yellow wire as opposed to the standard rich/lean signal of a zirconium
(signal) of the sensor with a tester are around 1 V for rich oxide oxygen sensor. Because the wideband signal varies both
mixtures, and around 0.2 V for lean mixtures. Titanium dioxide in strength and polarity it is impossible to see the signal with
lambda sensors do not need any reference air, because of anything except an oscilloscope. The wideband sensor its used
that they are smaller compared to the zirconium dioxide ones, always before the catalytic converter, together with a zirconium
also these units reach their operating temperature much faster. oxide sensor placed after the catalytic converter. This second
These types of sensors are always heated, and can be found sensor controls if the catalytic converter is working properly.
in two different wire configurations:
Schematic view of a Wideband Lambda Sensor
4 Wires - Types “A” & “B” Schematic view of
• Red wire (“A”) or Grey wire (B) Heating element (+) 3 an Oxygen “Pump” Cell
The way of working of the heated wideband sensor can be 4 - Measurement chamber
5 - Diffusion conduit
explained as follows. The sensor works like two zirconium
dioxide sensors, one acting as a measuring cell and the other
like a pump cell (nerst cell). The two cells are mounted in close Schematic view of a Wideband Lambda Sensor way of working
proximity with a small air gap between them (called measurement
Exhaust gases
chamber). One side of the measuring cell is exposed to air as 02 02
in the zirconium oxide sensor, and the other is in contact with
Pump cell
the exhaust gases pumped in the measurement chamber by Exhaust rea of A
the measurement area
the pump cell. Because the measuring chamber is small, by
adjusting the current flow to the pump cell, oxygen ions can be
moved into or out of the measuring chamber to vary the oxygen 02 450
concentrate, which is the principal on which this device works.
Measurement area 0
The control circuit for the pump cell is a closed loop, which is 02 2 02 mV
02
programmed to adjust the concentration of oxygen ions in
the measuring chamber to Pump tension
maintain the output readings 02 02 02
of the measuring cell at External air 02 02
Main Components Of Modern Vehicles Exhaust System All About Emission Control 31
Walker is a Leader in Emission ®
• Sound Engineering
• Advanced prediction tools used with leading car
manufacturers.
• Use of prediction tools like Gillaum, GT-Power, Wave.
technology is choosing
to protect the environment now
and for the future!”
32 All About Emission Control Main Components Of Modern Vehicles Exhaust System
More Original Equipment Products for Emission Control
Manifold Converters
Research
Tenneco provides full system engineering services for
automotive industry manufacturers, from the initial design
concept, through to the series production.
“Walker ® is the world’s
n 1 supplier
o
In the area of emission control, Walker ® research and
development centr e in Edenkoben, Germany, is the leader in
advanced technologies for emission systems with particular
competencies in the areas of:
• Exhaust gas treatment of Emission Control to both
• Gas flow dynamics Original Equipment and Aftermarket.”
• Thermal management
• Acoustics
• Lightweight designs
Main Components Of Modern Vehicles Exhaust System All About Emission Control 33
WALKER PRODUCT RANGE ®
Walker ® provides solutions for vehicle emission systems, and “Walker ® is a full-line exhaust
components including mufflers, pipes, catalytic converters,
exhaust manifolds, tubing and accessories for passenger cars.
supplier producing in excess of
Complementary Products
Mufflers Mounting components & accessories
• omologated range product equal to Original Equipment
H Full range of mounting components available including
production standards. • Clamps
• 2-layer aluminized steel to protect against corrosion. • Mounting, rubbers
• Stainless steel welding used in the Original Equipment design. • Exhaust gaskets
• Market leader in car part coverage, with constant range • Bolts
development. Over 3,500 references ensure Walker ® covers all your exhaust
mounting needs.
'6--:
)0.0-0("5&%
Flex pipes
•W
alker ® flex pipes are designed to comply with
Aftermarket needs.
•R
ange consists of different technologies non-lined,
Catalytic Converters
braid-lined and interlock flex.
• ince 1963 Walker ® have pioneered
S •S
tainless steel material to provide long-term high
catalytic converter technology. corrosion resistance.
•B
road range of sizes available now.
• alker ® products are homologated to
W
the correct European emission regulations.
• Market leading coverage.
34 All About Emission Control Main Components Of Modern Vehicles Exhaust System
4G AGAR (Advanced Gas Analyser Reader)
Main Components Of Modern Vehicles Exhaust System All About Emission Control 35
YOUR HEALTH IS AT RISK
Exhaust gases = DANGER Nitrogen Oxide (NOx) and Acid Rain
Particulate Matter = DANGER In conditions of extreme heat and pressure in the combustion
chamber, part of nitrogen molecules combined with air become
Soot = DANGER nitrogen oxides. Nitrogen oxides combined with water generate
acid, which, together with sulphur acids, is the main contributor
to the phenomenon of acid rain. Acid rain causes the acidification
Walker ®’s Mission: of lakes and streams, and contributes to the damage caused to
A Cleaner and Safer Environment trees at high elevations, and many of our sensitive forest soils.
Walker ® has been actively working to reduce the following Many scientific studies have identified a relationship between
harmful gases to a minimum: elevated levels of fine oxide particles (like NOx), and
• Carbon monoxide (CO) increased illnesses, and premature death from heart and lung
• Unburnt Hydro Carbons (HC) disorders, such us asthma and bronchitis.
• Nitrogen oxides (NOx)
• Particulate matter (PM) Walker ® solution:
Millions of 3-way catalytic converters have been delivered
Diesel Emissions and Particulate Matter (PM) by Walker ® in the Original Equipment and Aftermarket helping
In diesel emissions, the most carcinogenic compound is to decrease the NOx levels in petrol cars. For diesel cars,
3-nitrobentrazone, that is directly linked to a high increase a new line of products, like SCR and NOx trap catalytic
in lung cancer in congested cities.(1) converters have been developed in order to decrease those
harmful gases to the minimum.
Recent studies demonstrate that diesel emissions produce
changes in heart activity, and the relationship between The Acoustic Contamination
arteriosclerosis, thrombosis and the inhalation of solid Acoustic contamination is provoked by human activities,
particulate matter (smaller than 2.5 microns).(2) including traffic. High noise levels produce negative effects on
auditory, physical and mental health. Noise level above 50 dB
Walker ® solution: is harmful. (3)
Walker ® has been working for years with the design of
more efficient oxidizing catalytic converters and diesel Walker ® solution:
particulate filters (DPF) obtaining over 98 % efficiency in By using Walker ® homologated exhaust systems, users can
eliminating dangerous particulate matter. ensure that their vehicle will have controlled noise levels,
and thus contribute to a quieter and healthier environment.
Carbon Monoxide (CO) and Unburnt
Hydrocarbons (HC)
Carbon Monoxide (CO) is one of the most toxic substances we
can come into contact with in our daily life. You cannot smell it,
see it or taste it, but it could be in the air now. CO is captured by
the haemoglobin of the blood in our lungs preventing its function
of transporting oxygen. If we breathe CO in concentrations of
only 0.3 % during a period of 30 minutes it can cause death due
to the lack of oxygen in our cells. CO is formed due to a rich air
to fuel mixture in the combustion chamber.
Unburnt Hydrocarbons (HC) emissions are those fuel particles
which remain without burning in exhaust gases. These
emissions are one of the main components of smog present in
big cities. It is very important to realise that these unburnt fuel
pollutants are proven to be dangerous to human health, and
even highly carcinogenic.
Walker ® solution:
(1) Source: National Institute of Public Health of Tokyo
The new and more effective oxidizing catalytic converters
(2) Source: New England Medical Journal
transform the harmful CO and HC, that remain after the (3) Source: World Health Organization (WHO)
combustion process in the cylinders, into CO2 and water.
'6-
)0
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Why a homologated
"5&
%
exhaust system?
(silencer & catalytic converter)
10 good REASONS!
1. the backpressure and noise levels equal those of the Original Equipment.
3. Its consumption level will be equivalent to one equipped with an original system.
5. A
wrong backpressure produces a leakage of unburnt hydrocarbons and
oxygen causing small fusion areas in the catalytic converter’s monolith surface
and damaging it.
6. M
aintaining it this way melts the monolith and produces knocking noise
under the vehicle.
7. A
wrong backpressure also causes loss of petrol and oxygen in each intake
stroke, and consequently loss of power of the vehicle.
8. A
wrong backpressure produces a leakage of unburnt hydrocarbons caused
by a wrong backpressure that means that part of the emitted gases are
not transformed and remain harmful for the environment and human health.
9. N
on homologated exhaust systems cause premature failure and damage the expensive
and sophisticated exhaust systems (DPF, SCR, slip catalytic converters, NOx sensors,
wideband lambda sensors, etc...) of newer vehicles.
10. F inally, non-homologated exhaust systems are prohibited and illegal in the European
Community and the installation of them is penalized by the local authorities.
€ 12. 95 A6174 GB
Reasons to Choose
Walker ®
Online catalogue
www.taec.nl/walker
www.walker-eu.com