cng n tp hc k 2 Khi 10 - Trng HTK

Nm hc: 2010 - 2011

cng n tp mn ha hc k II Khi 10
A. Kin thc cn nm
1. Tnh cht vt l, tnh cht ha hc v phng php iu ch cc nguyn t nhm halogen, cc hidro halogenua v cc axit tng ng 2. Tnh cht ha hc v ng dng ca cc hp cht c ooxxi ca clo. 3. S bin i: + tnh oxi ha ca cc nguyn t nhm Halogen + tnh axit ca cc axit tng ng. 4. Tnh cht vt l, tnh cht ha hc v phng php iu ch: + Cc nguyn t nhm VIA tiu biu l Oxi v Lu hunh + Cc hp cht ca lu hunh 5. Phn bit Oxi v Ozon, cc ng dng thc tin ca chng 6. S bin i v tnh oxi ha v tnh kh ca cc hp cht ca lu hunh 7. Cc yu t nh hng n tc phn ng 8. Th no l cn bng ha hc v s chuyn dch cn bng ha hc.

B. Bi tp
Phn 1: Cc bi tp sch bi tp ha 10 nng cao Phn 2: Mt s bi tp tham kho

Dng 1: Chui phn ng, iu ch, vit phng trnh phn ng.
Cu 1: Vit cc phng trnh phn ng theo s :

Cu 2: Vit cc phn ng xy ra khi cho Fe, FeO, Fe3O4, Fe2O3 ln lt tc dng vi dung dch HCl v dung dch H2SO4 c nng.

Dng 2: Nhn bit

Cu 3: Ch dng 1 thuc th, phn bit: a. KCl, NaCl, HNO3 b. Na2CO3, Na2S, Na2SO4, K2SiO3 c. NaI, Na2S, NaNO3 d. Na2CO3, NaCl, CaCl2, AgNO3 e. NaF, NaCl, NaBr, BaI f. K2CO3, MgSO4, NH4HSO4, Al2(SO4)3, CuSO4

Dng 3: Bi tp ton
Cu 4: Ha tan hon ton 53,36 g Fe3O4 bng dung dch HCl 0,5M. Tnh khi lng mui thu c v tnh th tnh dung dch axit dng? Cu 5: Trn 2 V lt dung dch HCl 0,2M vi 3V lt dung dch HCl 0,5M a. Tnh nng mol/l ca dung dch HCl thu c? b. Cn bao nhiu ml dung dch HCl 2M pha trn vi 500 ml dung dch HCl 1M c dung dch HCl 1,2M? c. Trn 10 ml dung dch HCl 36% (d=1,18g/ml) vi 50 ml dung dch HCl 120% (d=1,1 g/ml). C% dung dch mui thu c? d. Cn bao nhiu ml dung dch H2SO4 2,5M v bao nhiu ml dung dch H2SO4 1M pha trn c 600 ml dung dch H2SO4 1,5M? e. Cn bao nhiu g dung dch H2SO4 20% trn vi 400 g dung dch H2SO4 10% c dung dch H2SO4 16% f. Tnh V H2O cn pha long 100 ml dung dch H2SO4 98% (D=1,84 g/ml) thnh dung dch H2SO4 20%? g. Tnh khi lng dung dch H2SO4 98% v H2O cn dng pha ch 500 g dung dch H2SO4 9,8%

Gio vin: Ths. Bi Quang Chnh. Khi 2 Ca Nam TP Vinh

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 cng n tp hc k 2 Khi 10 - Trng HTK

Nm hc: 2010 - 2011

Cu 6: Trn 50 ml dung dch HCl 0,5M vi 50 ml dung dch NaOH 1M. a. Tm CM cc cht trong dung dch thu c? b. Trn 300 ml dung dch HCl 0,05M vi 200 ml dung dch NaOH a mol/l. Tm nng mol cc cht trong dung dch thu c? c. 200 ml dung dch HCl 0,5M vo 500 ml dung dch Ca(OH)2 0,2M. Nhng giy qu tm vo dung dch thu c th giy qu chuyn sang mu no? Cu 7: Cho 4,8 g 1 hn hp A thuc nhm IIA vo 200 g dung dch HCl 020% th thu c 4,48 l kh (ktc). a. Xc nh tn kim loi A b. Tnh nng % cc cht trong dung dch thu c sau phn ng. Cu 8: Cho 10,8 g 1 kim loi R nhm IIIA tc dng ht vi 500 ml dung dch HCl thu c 13,44 lt kh (ktc). a. Xc nh tn kim loi R b. Tm nng mol/l dung dch HCl cn dng? Cu 9: Cho 1,35 g 1 kim loi kim X tan ht trong dung dch HCl thu c dung dch c khi lung ln hn dung dch HCl dng l 1,33 g. Tm tn X Cu 10: Ha tan hon ton 1,7 g hn hp X gm Zn v kim loi (A) nhm IIA vo dung dch Axit HCl thu c 0,672 lt kh H2 (ktc). Mt khc, nu ha tan ht 1,9 g (A) th dng khng ht 200 ml dung dch HCl 0,5M. Tm tn A. Cu 11: Cho hn hp gm 3 kim loi A, B, C c khi lng l 2,17 g tc dng ht vi dung dch HCl to ra 1,68 lt kh H2 (ktc). Tm khi lng mui clorua trong dung dch sau phn ng Cu 12: Ha tan ht m gam hn hp A gm c Fe v 1 kim loi (M) bng dung dch HCl thu c 1,008 lt H2 (ktc) v dung dch B. C cn dung dch B thu c 4,575 g hn hp mui khan. Tm gi tr ca m Cu 13: Cho 6,72 lt kh hn hp A gm H2 v Cl2 phn ng vi nhau, sau phn ng thu c hn hp kh B trong th tch sn phm chim 2/3 th tch hn hp B v lng kh H2 gim i 50% so vi u. Cho ton b B vo V ml dung dch AgNO3 1M va thi c m gam kt ta, th tch kh ktc. a. Tnh th tch tng kh trong hn hp A, B b. Tnh Hiu sut phn ng gia H2 v Cl2. Tnh V v m? Cu 14: Ha tan hon ton 1 lng kim loi R ha tr n bng dung dch H2SO4 long ri c cn dung dch, sau phn ng thu c 1 lng mui khan c khi lng gp 5 ln khi lng kim loi R ban u em ha tan. Tm kim loi R? Cu 15: Ha tan 2,32 g hn hp 2 mui NaX v NaY c s mol bng nhau (X, Y l 2 nguyn t halogen) vo dung dch AgNO3 va thu c 6,63 g kt ta v dung dch A. C cn dung dch A c m g mui khan, cc phn ng xy ra hon ton. Tnh m v xc nh cng thc ca 2 mui Cu 16: em 200 g dung dch HCl v H2SO4 tc dng vi BaCl2 d to ra 46,6 g kt ta v dung dch B, trung ha dung dch B cn 500 ml dung dch NaOH 1,6M. Tnh C% ca 2 axit trong dung dch u Cu 17: Cho 1040 g dung dch BaCl2 10% v 200 g dung dch H2SO4. Lc b kt ta. trung ha nc lc, ngi ta phi dng 250 ml dung dch NaOH 25% (D = 1,28 g/ml). Tnh nng % ca H2SO4 trong dung dch u. Cu 18: Cho 17,6 g hn hp Fe v kim loi R vo dung dch H2SO4 long d. Sau phn ng thu c 4,48 lt kh (ktc) phn khng tan cho vo dung dch H2SO4 c nng th gii phng ra 2,24 l kh (ktc). Tm kim loi R Cu 19: Dung dch A l H2SO 98% (d=1,84g/ml). a. Hy i sang nng mol/l b. Thm nc vo dung dch A theo t l khi lng th no thu c dung dch H2SO4 50% Cu 20: Cho 22,5 g hn hp Zn v Cu tc dng va dung dch H2SO4 98% nng thu c 7,84 lt kh SO2 (ktc). a. Tnh % khi lng mi kim loi trong hn hp b. Tnh khi lng dung dch H2SO4 90% dng Cu 21: Ha tan V lit SO2 (ktc) trong H2O d. Cho nc Brom vo dung dch cho n khi xut hin mu nc brom, sau cho thm dung dch BaCl2 cho n d, lc v lm kh kt ta th thu c 2,33 g cht rn. Tm V? Cu 22: Cho 1,84 g hn hp Fe v Cu vo 40 g dung dch H2SO4 c nng d thu c kh SO2. Dn ton b kh SO2 vo dung dch brom d c dung dch A. Cho ton b dung dch A tc dng vi dung dch BaCl2 d c 1,855 g kt ta. a. Tnh % khi lng ca mi kim loi trong hn hp u b. Tnh C% dung dch H2SO4 lc u bit lng axit tc dng vi kim loi ch 25% so vi lng H2SO4 trong dung dch Cu 23: Ha tan 11,5 g hn hp Cu, Al, Mg vo dung dch HCl d th thu c 5,6 l kh (ktc) v phn khng tan. Cho phn khng tan vo dung dch H2SO4 c nng d th thu c 2,24 l l kh (ktc). Xc nh khi lng mi kim loi trong hn hp. Cu 24: Cho hn hp FeS v Fe tc dng vi dung dch HCl d thu c 2,464 l hn hp kh ktc. Dn hn hp kh ny qua dung dch Pb(NO3)2 (d) sinh ra 23,9 g kt ta en. a. Hn hp kh thu c gm nhng cht no? Tnh s mol mi kh trong hn hp b. Tnh thnh phn % theo khi lng hn hp rn ban u? Cu 25: Chia m g hn hp Ag, Al lm 2 phn bng nhau: Phn 1: Tc dng vi dung dch H2SO4 long d c 6,72 lt kh H2 (ktc). Phn 2: Tc dng vi dung dch H2SO4 c nng d c 8,96 lt kh (ktc). Tm m Cu 26: Vit biu thc vn tc phn ng din ra trong h ng th theo phng trnh A + 2B AB2. Xc nh vn tc phn ng tng ln bao nhiu ln nu: a. Nng cht A tng ln 2 ln b. Nng cht B tng ln 2 ln c. Nng ca c 2 cht u tng ln 2 ln Cu 27: Cho phn ng 2A + B C. Nng ban u ca A l 6M, B l 5M. Hng s vn tc K = 0,5 a. Tnh vn tc phn ng lc u b. Tnh vn tc phn ng kh c 55 % cht B tham gia phn ng Cu 28: Xt phn ng: 3O2 2O3 nng ban u ca Oxi l 0,024 mol/l, sau 5 giy, nng ca oxi cn li l 0,02 mol/l. Hy tnh vn tc ca phn ng trong thi gian ?

Gio vin: Ths. Bi Quang Chnh. Khi 2 Ca Nam TP Vinh

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